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Geographical and geological data from caves and mines infected with white-nose syndrome (WNS) before September 2009 in the eastern United States

Since 2006, a white fungus named Geomyces destructans has been observed on the muzzles, noses, ears, and (or) wings of bats in the eastern United States, and bat colonies that are infected with this fungus have experienced dramatic incidences of mortality. Although it is not exactly certain how and why these bats are dying, this condition has been named white-nose syndrome (WNS). WNS appears to have spread from an initial infection site at a cave that is connected to a commercial cave in New York, and by the end of August 2009 was identified in at least 74 other sites in the eastern United States. Although detailed geographical and geological data are limited, a review of the available data shows that sites infected with WNS before September 2009 include both natural caves and mines. These infected sites extend from New Hampshire to Virginia, and known site elevations range from 84 to 2693 feet above sea level. In terms of geological setting, the infected sites include sedimentary, metamorphic, and igneous rocks of ages ranging from Precambrian to Jurassic. However, by the end of August 2009, no infected sites had been identified in strata of Mississippian, Cretaceous, or Triassic age. Meteorological data are sparse, but most of the recorded air temperatures in the known WNS-infected caves and mines range from 0 to 13.9 degrees C, and humidity measurements range from 68 to 100 percent. Although it is not certain which environmental parameters are important for WNS, it is hoped that the geographical and geological information presented in this paper will inform and clarify some of the debate about WNS, lead to greater understanding of the environmental parameters associated with WNS, and highlight the paucity of scientific data from caves in the eastern United States.

Journal of Cave and Karst Studies

Lower Keweenawan volcanic rocks of Michigan and Wisconsin

Unconformable sequences of Keweenawan volcanic rocks occur in Michigan and adjacent Wisconsin. The sequences differ in types of rocks, magnetic properties, metamorphic grade, and pattern of structural deformation; they had different vent areas and were deposited in basins that were only partly overlapping. The older sequence includes the Bessemer Quartzite and two newly named formations that are here assigned to the lower Keweenawan. The younger sequence includes the well-known Portage Lake Volcanics and a younger unnamed formation, both of middle Keweenawan age. Formerly the older rocks were interpreted as a fault-repeated part of the Portage Lake Volcanics, but new evidence indicates that these older rocks had been metamorphosed and tilted and were being eroded in middle Keeweenawan time.

Michigan, Wisconsin

Paleoproterozoic metamorphism in the northern Wyoming province: Implications for the assembly of Laurentia

U-Pb ages measured on zircons from the Tobacco Root Mountains and monazite from the Highland Mountains indicate that the northwestern Wyoming province experienced an episode of high-grade metamorphism at ???1.77 Ga. Leucosome emplaced in Archean gneisses from the Tobacco Root Mountains contains a distinctive population of zircons with an age of 1.77 Ga but also contains zircons to ???3.5 Ga; it is interpreted to have been derived primarily by anatexis of nearby Archean schist. A granulite facies mafic dike that cuts across Archean gneissic banding in the Tobacco Root Mountains contains two distinct populations of zircons. A group of small (<50 ??m) nonprismatic grains is interpreted to be metamorphic and yields an age of 1.76 Ga; a group of slightly larger prismatic grains yields an age of 2.06 Ga, which is interpreted to be the time of crystallization of the dike. Monazite from a leucogranite from the Highland Mountains yields a well-defined age of 1.77 Ga, which is interpreted as the time of partial melting and emplacement of the leucogranite. These results suggest that the northwestern Wyoming province, which largely lies within the western part of the Great Falls tectonic zone, experienced a metamorphic maximum at 1.77 Ga. This age is ???100 m.yr. younger than the proposed time of Wyoming-Hearne collision in the central Great Falls tectonic zone (1.86 Ga) and suggests that the northwestern Wyoming province may have been involved in a separate, younger collisional event at ???1.77 Ga. An event at this time is essentially coeval with collisions proposed for the eastern and southeastern margins of the province and suggests a multiepisodic model for the incorporation of the Wyoming craton into Laurentia. ?? 2005 by The University of Chicago. All rights reserved.

Journal of Geology

Assembling and disassembling california: A zircon and monazite geochronologic framework for proterozoic crustal evolution in southern California

The Mojave province in southern California preserves a comparatively complete record of assembly, postorogenic sedimentation, and rifting along the southwestern North American continental margin. The oldest exposed rocks are metasedimentary gneisses and amphibolite, enclosing intrusive suites that range from tonalite and quartz mon-zodiorite to granite with minor trondhjemite. Discrete magmatic episodes occurred at approximately 1790-1730 and 1690-1640 Ma. Evidence from detrital and premagmatic zircons indicates that recycling of 1900-1790 Ma Paleopro-terozoic crust formed the unique isotopic character of the Mojave province. Peak metamorphic conditions in the Mojave province reached middle amphibolite to granulite facies; metamorphism occurred locally from 1795 to 1640 Ma, with widespread evidence for metamorphism at 1711-1689 and 1670-1650 Ma. Structures record early, tight to isoclinal folding and penetrative west-vergent shear during the final metamorphic event in the west Mojave province. Proterozoic basement rocks are overlain by siliciclastic-carbonate sequences of Mesoproterozoic, Neoproterozoic, and Cambrian age, recording environmental change over the course of the transition from stable Mojave crust to the rifted Cordilleran margin. Neoproterozoic quartzites have diverse zircon populations inconsistent with a southwest North American source, which we infer were derived from the western conjugate rift pair within Rodinia, before establishment of the miogeocline. Neoproterozoic-Cambrian miogeoclinal clastic rocks record an end to rifting and establishment of the Cordilleran miogeocline in southern California by latest Neoproterozoic to Early Cambrian time. ?? 2009 by The University of Chicago.

Journal of Geology

Pre-Eocene rocks of Java, Indonesia

The exposed pre-Eocene rocks of Java can be divided into two compound units for purposes of reconnaissance mapping and structural interpretation: a sedimentary sequence and melange. The sedimentary sequence consists of moderately deformed and little-metamorphosed conglomerate, sandstone, mudstone, claystone, chert, and limestone. The melange consists of a chaotic mechanical mixture of rocks identical to those of the sedimentary sequence and their metamorphic equivalents, such as schist, phyllite, quartzite, and marble. In addition, it contains a large proportion of quartz porphyry and smaller amounts of granite, basalt, gabbro, peridotite, pyroxenite, and serpentinite. The sedimentary sequence is at least partly of Early Cretaceous age and the melange is of Early Cretaceous to very early Paleocene age. They are overlain unconformably by Eocene rocks. The presence in the melange of blocks of quartz porphyry and granite is not easily reconcilable with current plate tectonic concepts in which the sites of formation of melange and plutonic rocks should be hundreds of kilometres apart.

Java

Microprobe analyses of sericite, chlorite, and epidote from Jerome, Arizona

Volcanic rocks in the vicinity of the massive sulfide deposits at the United Verde mine, Jerome, Ariz., have been modified in several periods of hydrothermal alteration and greenschist metamorphism. Chlorite, 2M, mica (sericite), and epidote are characteristic alteration products. Microprobe analyses for sericite, chlorite, and epidote are recalculated to structural formulas by the method employing oxygen anion equivalents. The sericite has the general composition of muscovite, but is moderately phengitic, and two samples have 6-12 percent paragonite in solid solution. Most of the chlorite is ripidolite with approximately one-third of the tetrahedral sites filled by aluminum; octahedral aluminum slightly exceeds tetrahedral. Fe:Fe+Mg+Mn ratios range from 0.34 to 0.66; low values are associated with sulfide minerals; higher values occur in a sample peripheral to the massive sulfide deposit. The epidote is a solid solution of 70 percent epidote, 30 percent clinozoisite.

Arizona

Potassium-argon geochronology of some metamorphic, igneous, and hydrothermal events in Puerto Rico and the Virgin Islands

Potassium-argon ages of hornblende, biotite, and whole rocks in Puerto Rico include the following: 126 m.y. for amphibolites in the southwest part of the island; 109 m.y. for the oldest known quartz diorite plutons; 88 to 65 m.y. for emplacement of various quartz diorite and granodiorite batholiths and stocks; 38 to 46 m.y. for intrusions of quartz diorite porphyry stocks and their hydrothermal alteration and mineralization. These intrusions are the youngest known igneous rocks in Puerto Rico. In addition, a 35-m.y. age was determined for hornblende and biotite from the Virgin Gorda batholith. Although widespread hydrothermal alteration as old as 75 m.y. is known in Puerto Rico, all important copper deposits are related to the 38- to 46-m.y. old intrusions.

Puerto Rico

Metallogeny of the Great Basin: Crustal evolution, fluid flow, and ore deposits

The Great Basin physiographic province in the Western United States contains a diverse assortment of world-class ore deposits. It currently (2006) is the world’s second leading producer of gold, contains large silver and base metal (Cu, Zn, Pb, Mo, W) deposits, a variety of other important metallic (Fe, Ni, Be, REE’s, Hg, PGE) and industrial mineral (diatomite, barite, perlite, kaolinite, gallium) resources, as well as petroleum and geothermal energy resources. Ore deposits are most numerous and largest in size in linear mineral belts with complex geology. U.S. Geological Survey (USGS) scientists are in the final year of a research project initiated in the fall of 2001 to increase understanding of relations between crustal evolution, fluid flow, and ore deposits in the Great Basin. Because of its substantial past and current mineral production, this region has been the focus of numerous investigations over the past century and is the site of ongoing research by industry, academia, and state agencies. A variety of geoinformatic tools was used to organize, reinterpret, and display, in space and time, the large amounts of geologic, geophysical, geochemical, and hydrologic information deemed pertinent to this problem. This information, in combination with concentrated research on (1) critical aspects of the geologic history, (2) an area in northern Nevada that encompasses the major mineral belts, and (3) important mining districts and deposits, is producing new insights about the interplay between key tectonic events, hydrothermal fluid flow, and ore genesis in mineral belts. The results suggest that the Archean to Holocene history of the Great Basin was punctuated by several tectonic events that caused fluids of different origins (sea water, basinal brine, meteoric water, metamorphic water, magmatic water) to move through the crust. Basement faults reactivated during these events localized deformation, sedimentation, magmatism, and hydrothermal fluid flow in overlying rocks to form mineral belts that contain ore deposits of different types and ages that are locally superimposed (demonstrating inheritance). Fluid flow in these systems also was influenced by the distribution of permeable lithologies and paleotopographic highs and lows. Hydrothermal fluids evolved from their initial chemistries towards compositions that reflect the ƒ O 2 and ƒ S 2 buffering capacity of, and the ligands and metals present in, the rocks (±older mineralization) through which they moved. In northern Nevada, where gold deposits are relatively common, carbonaceous, pyritic strata buffered fluids of diverse origins to H 2 S-rich compositions so they could transport gold repeatedly over Paleozoic-Cenozoic time (convergent evolution). Ore formed where metal-laden fluids encountered effective physicochemical traps. Maps of Neogene basin fill and erosion surfaces identify areas where preexisting ore deposits have been progressively exposed or concealed. Comparisons with analogous terrains and deposit types in other parts of the world provide global context. The initial findings and some of the databases, geologic maps, sections, reconstructions, hydrogeologic models, topical syntheses, regional overviews, short courses, field guides, and deposit comparisons produced by project staff and associated managers, contractors, and collaborators have been presented in numerous abstracts, symposia, USGS publications, and professional journals over the last 5 years (see the extensive bibliography). Notable among these was the 2005 Geological Society of Nevada symposium in Reno, Nevada, and the 2005 Geological Society of America annual meeting in Salt Lake City, Utah, where project results were presented to audiences from around the nation and world. The final results of the project will be submitted for publication in 2007 to appropriate USGS and professional journals. A special issue of GEOSPHERE, scheduled for publication in 2007, will be devoted to the results of this project and related work. This special issue will reach an international audience and be available worldwide on the internet. Much of the research for this project has concentrated on areas that will receive the focused attention of the mining industry in the future. As such, the data and interpretations generated by this project have direct use for land-use managers in Federal, State, and local agencies. Improved hydrogeologic models developed by this project will considerably enhance ongoing and future water resource investigations in the region. The increased understanding of when, where, and how hydrothermal systems produce significant economic deposits has direct uses for mineral exploration and for future USGS mineral resource assessments in the Great Basin and other parts of the world.

Great Basin

Contact metamorphism adjacent to a teschenite intrusion

Shale adjacent to the upper contact of an annular teschenite intrusion was converted to andalusite hornfels in an aureole 2–4 feet wide. At some points along the contact there is no evidence of anhydrous recrystallization. Rarely, magmatic reaction with small shale xenoliths resulted in formation of cordierite‐sillimanite (?) hornfelses, and locally a very small‐scale movement of magmatic constituents took place across the contact before consolidation of the teschenite. Very severe deuteric alteration of teschenite adjacent to the contact resulted in large losses of Si, Fe, Mg, alkalis, and probably Ca, some of which were recombined in clays and carbonates in the more porous shales and in joints, but analyses of uniformly fine‐grained shales indicate little change in bulk composition. Mineralogical evidence indicates a maximum contact temperature within the range 500°‐600° C, and a maximum intrusion temperature within the range 1000°‐1200° C.

Journal of the Geological Society of Australia

Photomosaics of the cathodoluminescence of 60 sections of meteorites and lunar samples

Cathodoluminescence (CL) petrography provides a means of observing petrographic and compositional properties of geological samples not readily observable by other techniques. We report the low-magnification CL images of 60 sections of extraterrestrial materials. The images we report include ordinary chondrites (including type 3 ordinary chondrites and gas-rich regolith breccias), enstatite chondrites, CO chondrites and a CM chondrite, eucrites and a howardite, lunar highland regolith breccias, and lunar soils. The CL images show how primitive materials respond to parent body metamorphism, how the metamorphic history of EL chondrites differs from that of EH chondrites, how dark matrix and light clasts of regolith breccias relate to each other, how metamorphism affects eucrites, the texture of lunar regolith breccias and the distribution of crystallized lunar spherules ("lunar chondrules"), and how regolith working affects the mineral properties of lunar soils. More particularly, we argue that such images are a rich source of new information on the nature and history of these materials and that our efforts to date are a small fraction of what can be done. Copyright 2004 by the American Geophysical Union.

Journal of Geophysical Research E: Planets

Introduction to the special section northeast Japan: A case history of subduction

Subduction-related tectonic events such as strike-slip faulting, uplift of high-pressure metamorphic rocks in the forearc, back arc spreading, arc magmatism, and continental collisions have shaped northeast Japan, making it a case history for subduction. Much of the record of these events is preserved and can be used to reconstruct the tectonic history of the region. Although many geological, geophysical, and geochemical data have been collected in Japan for the last 30 years, interpretation of these data into a plate tectonic context did not really begin until about 10 years ago. Much of the data and interpretation on northeast Japan have been published in Japanese or as individual local studies. The primary goal of this special section is to present new investigations covering a wide range of topics and scales and place them in a tectonic framework. The papers in this special section focus on three main subjects: Mesozoic aspects of northeast Japan; the relation of Japan Sea opening with the tectonics and geochemistry of northeast Japan in the Tertiary; and the geophysical setting. The purpose of this overview is to link these subjects and provide a tectonic framework for north- east Japan and eastern Asia since the Mesozoic.

Journal of Geophysical Research B: Solid Earth

Did the Middlesboro, Kentucky, bolide impact event influence coal rank?

The Middlesboro Basin, southeastern Kentucky, occurs on the Cumberland Overthrust Sheet and includes a ca. 5.5-km diameter impact structure. The Lower and Middle Pennsylvanian coal-bearing strata are faulted, with some evidence for shock metamorphism. The event post-dated the latest-Pennsylvanian-early-Permian thrusting and was likely prior to late-Mesozoic entrenchment of drainages. The impact of a 0.5-km meteor traveling at ca. 60,000??km/h would release about 1??EJ, the approximate equivalent of the instantaneous combustion of 30??Mt of coal. The coal rank, while increased slightly above the regional level, still is within the upper portion of the high volatile A bituminous rank range. This helps to constrain the depth of burial at the time of the impact. The coal would have had to have been at a depth of a few kilometers to have avoided a more substantial rank increase. In addition, it is possible that some of the coal rank increase might be attributable to movements along the cross-cutting Rocky Face fault, unrelated to the impact. ?? 2009 Elsevier B.V. All rights reserved.

International Journal of Coal Geology

Chronologic and isotopic framework for early Proterozoic crustal evolution in the eastern Mojave Desert region, SE California

The Early Proterozoic geologic evolution of the eastern Mojave Desert region, as defined by characteristics of its supracrustal rocks, granitoids, metamorphism, structural history, and Pb and Nd isotopic signature, contrasts sharply with other Proterozoic provinces of the southwestern United States. The oldest supracrustal rocks of the Mojave Desert region contain zircons over 2.0 Ga, corroborating Nd isotopic evidence for a much older crust here than elsewhere in the southwestern United States. Granitoids widely emplaced within these supracrustal rocks range from 1.76 to 1.64 Ga. The earlier plutons and surrounding supracrustal rocks were metamorphosed to granulite and high amphibolite facies throughout the province at about 1705 Ma in a migmatite-producing event that we term (informally) the Ivanpah orogeny. Subsequent granitoids, emplaced from 1.69 to 1.67 Ga, were voluminous along a north trending belt in the middle of the Mojave province. Younger plutons were emplaced at about 1.66 Ga in several places and at about 1.64 Ga along the extreme southern part of the province. Commonalities between the Proterozoic evolutions of the Mojave and Arizona crustal provinces do not conclusively establish the time that the provinces were juxtaposed; the data only suggest that the juxtaposition occurred between about 1.76 and 1.64 Ga.

Journal of Geophysical Research

Lead and strontium isotopes and related trace elements as genetic tracers in the Upper Cenozoic rhyolite-basalt association of the Yellowstone Plateau volcanic field

Supported by various field geologic and petrologic data, the contents of Pb, U, Th, Rb, and Sr and the isotopic compositions of Pb and Sr for upper Cenozoic volcanic rocks of the Yellowstone Plateau volcanic field are consistent with the hypothesis of derivation of the basaltic and rhyolitic magmas by partial melting of distinct source regions in the upper mantle and lower crust, respectively. All the basalt samples analyzed but one have systematically lower values of 207 Pb/ 204 Pb and 87 Sr/ 86 Sr than the rhyolites. The values of 206 Pb/ 204 Pb are smaller, and 87 Sr/ 86 Sr are mostly larger than known values in oceanic basalts. In all but one case, the values of 207 Pb/ 204 Pb are higher than expected from an extrapolation of known values in oceanic basalts to less radiogenic values of 206 Pb/ 204 Pb. Because there are no xenoliths, phenocrysts are only moderate to sparse in abundance, REE patterns are low and flat at the radiogenic end of lead isotopic compositions, several values of Rb/Sr are low, and 80% of the basalt samples form a well-developed secondary isochron separate from the rhyolites, we favor an interpretation for basalt genesis wherein isotopic signatures of most mafic magmas were attained in a continental ‘keel’ of mantlelike character about 2.6 b.y. old or somewhat older attached to the crust, and these signatures were unaltered by magma passage through the crust. At the very least, the current data continue to cast serious doubt as to the inevitability of crustal contamination for basaltic magma intruding the continental environment and postulate that much can be learned about the mantle under continents through the study of continental basalts. One basalt unit with an unusually low value of 207 Pb/ 204 Pb and an 87 Ar/ 86 Ar less than 0.704 may represent subcontinental ‘keel’-derived magma that rose unaltered to the surface. Our data also are not consistent with formation of this rhyolite-basalt association primarily by such processes as crystal fractionation, separation of immiscible silicate liquids from a common parental magma, or fractional melting of a homogeneous source. Rather as a conceptual model, we envision large mafic intrusions to have been injected into the lower crust resulting in rhyolite generation through partial anatexis of the adjacent wall rocks which probably had a 206 Pb/ 204 Pb < 17 and 87 Sr/ 86 Sr > 0.709; a model that has much in common with that proposed by Holmes (1931). All the other hypotheses listed have the necessary added complication that either the basalt or the rhyolite or both become contaminated after the two magma types separated, have problems accounting for the lack of igneous rocks of intermediate compositions or production of such large volumes of rhyolitic material (∼5000 km 3 ), and fail to explain why rhyolitic magma is not a more common occurrence in the ocean basin. We appeal to bouyancy of rhyolites to generate a barrier for basalt magma migration and account for the great preponderance of rhyolite relative to basalt at the surface. Furthermore, the complex isotopic picture in the rhyolites indicates that many of these magmas interacted with the upper crustal geologic units that they traversed. The interactions involved diverse processes, probably including reacton with hydrothermal fluids or hydrothermally altered rocks at high levels as well as by contamination with Phanerozoic sedimentary and Precambrian crystalline rocks at deeper levels. At the very least, we feel our study adds a cautionary note to the currently increasingly popular hypothesis that differentiation of basalt or gabbro magmas to rhyolite or granite (as distinct from tonalite or dacite) is a common occurrence and is therefore an important continential building process. Models for formation of rhyolite and granite predominantly by reworking of crust (anatexis) must still be considered. The primitive Archean mantle of the region was characterized by higher Rb/Sr, U/Pb, and Th/U values than are typical of modern suboceanic mantle. The mantle residuum within the continental subcrustal lithosperic ‘keel’ that resulted from the Archean crustal differentiation event probably was depleted in Rb/Sr and U/Pb, and the crust was correspondingly enriched in these ratios. The crust probably was further differentiated by an Archean high-grade metamorphism, during or after the primary event, into a granulitic lower crust depleted in U/Pb and Rb/Sr and a lower-grade upper crust enriched in these ratios.

Journal of Geophysical Research Solid Earth

Geochemical and petrological studies of a uraniferous granite from the Granite Mountains, Wyoming

Granite rocks from the Granite Mountains, Wyo. have been proposed as the source of uranium deposits in the Crooks Gap, Gas Hills and Shirley Basin uranium districts, Wyoming. We have divided these granitic rocks into four units: (1) a biotitic phase which forms the dominant unit at the western end of the Granite Mountains, (2) a leucocratic phase which was found from 215 to 405 metres in drill hole GM-1, (3) silicified zones which crosscut the granitic rocks and form topographic highs, and (4) fractured zones, in drill hole GM-1, which seem to have been hydrothermally altered. The biotitic phase is hypidiomorphic-granular to xenomorphic-granular alkali granite with anomalously high contents of U (10 parts per million), Th (50 ppm), and Pb (50 ppm). Fission-track studies show that uranium is located in zircon, sphene, apatite, monzite, xenotime, biotite, chlorite, epidote, and magnetite; no intergranular uranium was found. The leucocratic phase is mineralogically similar to the biotitic phase, but contains less than half as much iron. It is xenomorphic granular and commonly contains rounded and retrograded garnets, which suggests that this phase is either metamorphic or contaminated with metamorphic materials. The leucocratic phase has anomalously high contents of U (8 ppm) and Pb (55 ppm), but has a low Th content (10 ppm). The silicified phase and fracture zones exhibit cataclastic and crystalloblastic textures and are highly variable in mineralogy. Potassium-bearing minerals are generally absent. Microcline is replaced by albite and (or) quartz, and biotite is replaced by clinozoisite. Uranium values may be anomalously high in the fracture zones. One sample contains 1100 ppm radium-equivalent uranium. In this and other uranium-rich samples from the fracture zones, the uranium is associated with iron oxides which commonly fill microfractures. According to our model and currently available data, an alkali granite is the best crystalline source rock for uranium, especially if it is unmetamorphosed and rapidly exposed to near-surface conditions for the first time when a favorable basin existed nearby.

Wyoming

Geology and geochemistry of epithermal precious metal vein systems in the intra-oceanic arcs of Palau and Yap, western Pacific

The Palau and Yap arcs are part of an intra-oceanic island-arc-trench system which separates the Pacific and Philippine plates in the western Pacific Ocean. The 350-km-long Palau arc consists of over 200 islands while the 400-km-long Yap arc located to the north has only four major islands exposed. Four of the largest islands in Palau are composed primarily of early Eocene to mid-Miocene volcanic rocks and the four islands comprising Yap contain only Miocene volcanic rocks. Basalt and basaltic andesites of the Babelthuap Formation are the oldest volcanic rocks in Palau and are characterized by high MgO, Ni and Cr and low TiO 2 and have a boninitic affinity. They form the central and southeastern parts of Babelthuap Island. Oligocene arc tholeiite flows having an age of 34–35.5 Ma comprise most of the three smaller volcanic islands in Palau and the western part of Babelthuap. The youngest volcanic rocks are dacitic intrusions having an age of 22.7–23.2 Ma. The Yap arc is unusual in that metamorphic rocks up to amphibolite grade form most of the islands. These are underlain by a melange composed of igneous and volcanic clasts as well as clasts from a dismembered copper-gold skarn deposit. Miocene volcanic rocks consisting of flows and volcaniclastic deposits overlie the melange and metamorphic complex.

Journal of Geochemical Exploration

Proterozoic tectonostratigraphy and paleogeography of central Madagascar derived from detrital zircon U-Pb age populations

Detrital zircon U‐Pb ages determined by SHRIMP distinguish two clastic sequences among Proterozoic metasedimentary rocks from central Madagascar. The Itremo Group is older: zircon data, stromatolite characteristics, and carbon isotope data all point to a depositional age around 1500–1700 Ma. The Molo Group is younger, deposited between ∼620 Ma (the age of the youngest zircon) and ∼560 Ma (the age of metamorphic overgrowths on detrital cores). Geochronologic provenance analysis of the Itremo Group points to sources in East Africa as well as local sources in central and southern Madagascar but provides no evidence for a detrital contribution from northern and eastern Madagascar nor from southern India. Detrital zircon and sedimentologic similarities between rocks of the Itremo Group and the Zambian Muva Supergroup suggest a lithostratigraphic correlation between the two. The Molo Group has a strong 1000–1100 Ma detrital signature that also indicates an east African provenance and suggests a Neoproterozoic geographic connection with Sri Lanka but shows no indication of input from the Dharwar craton and eastern Madagascar. Central Madagascar was probably juxtaposed with the Tanzanian craton in the Paleo‐ and Mesoproterozoic, whereas northern and eastern Madagascar were connected to India. Internal assembly of Madagascar postdates Neoproterozoic Molo Group sedimentation and is likely to have occurred at about 560 Ma.

Journal of Geology

Mesoproterozoic graphite deposits, New Jersey Highlands: Geologic and stable isotopic evidence for possible algal origins

Graphite deposits of Mesoproterozoic age are locally abundant in the eastern New Jersey Highlands, where they are hosted by sulphidic biotite–quartz–feldspar gneiss, metaquartzite, and anatectic pegmatite. Gneiss and metaquartzite represent a shallow marine shelf sequence of locally organic-rich sand and mud. Graphite from massive deposits within metaquartzite yielded δ13C values of –26 ± 2‰ (1σ), and graphite from massive deposits within biotite–quartz–feldspar gneiss yielded δ13C values of –23 ± 4‰. Disseminated graphite from biotite–quartz–feldspar gneiss country rock was –22 ± 3‰, indistinguishable from the massive deposits hosted by the same lithology. Anatectic pegmatite is graphitic only where generated from graphite-bearing host rocks; one sample gave a δ13C value of –15‰. The δ34S values of trace pyrrhotite are uniform within individual deposits, but vary from 0 to 9‰ from one deposit to another. Apart from pegmatitic occurrences, evidence is lacking for long-range mobilization of carbon during Grenvillian orogenesis or post-Grenvillian tectonism. The field, petrographic, and isotope data suggest that massive graphite was formed by granulite-facies metamorphism of Proterozoic accumulations of sedimentary organic matter, possibly algal mats. Preservation of these accumulations in the sedimentary environment requires anoxic basin waters or rapid burial. Anoxia would also favour the accumulation of dissolved ferrous iron in basin waters, which may explain some of the metasediment-hosted massive magnetite deposits in the New Jersey Highlands.

New Jersey