Geology topics

William C. Evans

Publications and source records attributed to William C. Evans.

At least 73 records · Page 4Linked to original sources

USGS2006

Carbon dioxide emissions from vegetation-kill zones around the resurgent dome of Long Valley caldera, eastern California, USA

A survey of diffuse CO 2 efflux, soil temperature and soil-gas chemistry over areas of localized vegetation-kill on and around the resurgent dome of Long Valley caldera California was performed to evaluate the premise that gaseous and thermal anomalies are related to renewed intrusion of magma. Some kill sites are long-lived features and others have developed in the past few years. Total anomalous CO 2 emissions from the thirteen areas average around 8.7 t per day; but the majority of the emissions come from four sites west of the Casa Diablo geothermal power plant. Geochemical analyses of the soil-gases from locations west and east of the plant revealed the presence of isobutane related to plant operations. The δ 13 C values of diffuse CO 2 range from − 5.7‰ to − 3.4‰, similar to values previously reported for CO 2 from hot springs and thermal wells around Long Valley. At many of the vegetation-kill sites soil temperatures reach boiling at depths ≤ 20 cm. Soil temperature/depth profiles at two of the high-emissions areas indicate that the conductive thermal gradient in the center of the areas is around 320 °C m − 1 . We estimate total heat loss from the two areas to be about 6.1 and 2.3 MW. Given current thinking on the rate of hydrothermal fluid flow across the caldera and using the CO 2 concentration in the thermal fluids, the heat and CO 2 loss from the kill areas is easily provided by the shallow hydrothermal system, which is sourced to the west of the resurgent dome. We find no evidence that the development of new areas of vegetation kill across the resurgent dome are related to new input of magma or magmatic fluids from beneath the resurgent dome. Our findings indicate that the areas have developed as a response to changes in the shallow hydrologic system. Some of the changes are likely related to fluid production at the power plant, but at distal sites the changes are more likely related to seismicity and uplift of the dome.

California↗

USGS2006

Geochemistry of low-temperature springs northwest of Yellowstone caldera: Seeking the link between seismicity, deformation, and fluid flow

A comprehensive geochemical survey of springs outside the northwest margin of the Yellowstone caldera was undertaken in 2003 and 2004. This survey was designed to detect: (1) active leakage from a huge reservoir of CO 2 gas recently postulated to extend from beneath the caldera into this area; and (2) lingering evidence for subsurface flow of magmatic fluids into this area during the 1985 seismic swarm and concomitant caldera subsidence. Spring temperatures are low (< 15 °C), but two large-discharge springs contain 14 C-dead carbon that can be identified as magmatic from calculated end-member values for δ 13 C (dead) and 3 He/C (dead) of − 4&permil; and 1 × 10 − 10 , respectively, similar to values for intra-caldera fumarolic and hot-spring gases. However, the combined discharge of magmatic C is only 5.4 tonnes/day, < 0.1% of the total output from Yellowstone. The two springs have slightly elevated 3 He/ 4 He ratios near 1 R A and anomalous concentrations of Cl, Li, and B, and appear to represent minor leakage of gas-depleted, thermal waters out of the caldera. The small CO 2 signal detected in the springs is difficult to reconcile with a large underlying reservoir of gas in faulted and seismically active terrain. When considered with analyses from previous decades, the results provide no evidence to associate the ten-year period of caldera deflation that began in 1985 with expulsion of magmatic fluids through the caldera rim in this area.

Montana, Wyoming↗

USGS2006

USGS-NoGaDat - A global dataset of noble gas concentrations and their isotopic ratios in volcanic systems

The database (Version 1.0) is a MS-Excel file that contains close to 5,000 entries of published information on noble gas concentrations and isotopic ratios from volcanic systems in Mid-Ocean ridges, ocean islands, seamounts, and oceanic and continental arcs (location map). Where they were available we also included the isotopic ratios of strontium, neodymium, and carbon. The database is sub-divided both into material sampled (e.g., volcanic glass, different minerals, fumarole, spring), and into different tectonic settings (MOR, ocean islands, volcanic arcs). Included is also a reference list in MS-Word and pdf from which the data was derived. The database extends previous compilations by Ozima (1994), Farley and Neroda (1998), and Graham (2002). The extended database allows scientists to test competing hypotheses, and it provides a framework for analysis of noble gas data during periods of volcanic unrest.

Data Series↗

USGS2005

Degassing Lakes Nyos and Monoun: Defusing certain disaster

Since the catastrophic releases of CO 2 in the 1980s, Lakes Nyos and Monoun in Cameroon experienced CO 2 recharge at alarming rates of up to 80 mol/m 2 per yr. Total gas pressures reached 8.3 and 15.6 bar in Monoun (2003) and Nyos (2001), respectively, resulting in gas saturation levels up to 97%. These natural hazards are distinguished by the potential for mitigation to prevent future disasters. Controlled degassing was initiated at Nyos (2001) and Monoun (2003) amid speculation it could inadvertently destabilize the lakes and trigger another gas burst. Our measurements indicate that water column structure has not been compromised by the degassing and local stability is increasing in the zones of degassing. Furthermore, gas content has been reduced in the lakes ≈12-14%. However, as gas is removed, the pressure at pipe inlets is reduced, and the removal rate will decrease over time. Based on 12 years of limnological measurements we developed a model of future removal rates and gas inventory, which predicts that in Monoun the current pipe will remove ≈30% of the gas remaining before the natural gas recharge balances the removal rate. In Nyos the single pipe will remove ≈25% of the gas remaining by 2015; this slow removal extends the present risk to local populations. More pipes and continued vigilance are required to reduce the risk of repeat disasters. Our model indicates that 75-99% of the gas remaining would be removed by 2010 with two pipes in Monoun and five pipes in Nyos, substantially reducing the risks.

Lakes Nyos and Monoun↗

USGS2004

Magmatic intrusion west of Three Sisters, central Oregon, USA: The perspective from spring geochemistry

A geochemical investigation of springs near Three Sisters volcanoes was conducted in response to the detection of crustal uplift west of the peaks. Dilute, low-temperature springs near the center of uplift show 3 He/ 4 He ratios ≥7 R A ( R A is the ratio in air), and transport in total ∼16 MW of heat and ∼180 g/s of magmatic carbon (as CO 2 ). These anomalous conditions clearly reflect the influence of magma, but they seemingly predate the onset of the present uplift and derive from a previous event. Episodes of intrusion may thus be more common in this area than the age of eruptive vents would imply.

Geology↗

USGS2003

Excess nitrogen in selected thermal and mineral springs of the Cascade Range in northern California, Oregon, and Washington: Sedimentary or volcanic in origin?

Anomalous N 2 /Ar values occur in many thermal springs and mineral springs, some volcanic fumaroles, and at least one acid-sulfate spring of the Cascade Range. Our data show that N 2 /Ar values are as high as 300 in gas from some of the hot springs, as high as 1650 in gas from some of the mineral springs, and as high as 2400 in gas from the acid-sulfate spring on Mt. Shasta. In contrast, gas discharging from hot springs that contain nitrogen and argon solely of atmospheric origin typically exhibits N 2 /Ar values of 40–80, depending on the spring temperature. If the excess nitrogen in the thermal and mineral springs is of sedimentary origin then the geothermal potential of the area must be small, but if the nitrogen is of volcanic origin then the geothermal potential must be very large. End-member excess nitrogen (δ 15 N) is +5.3‰ for the thermal waters of the Oregon Cascades but is only about +1‰ for fumaroles on Mt. Hood and the acid-sulfate spring on Mt. Shasta. Dissolved nitrogen concentrations are highest for thermal springs associated with aquifers between 120 and 140°C. Chloride is the major anion in most of the nitrogen-rich springs of the Cascade Range, and N 2 /Ar values generally increase as chloride concentrations increase. Chloride and excess nitrogen in the thermal waters of the Oregon Cascades probably originate in an early Tertiary marine formation that has been buried by the late Tertiary and Quaternary lava flows of the High Cascades. The widespread distribution of excess nitrogen that has been generated in low to moderate-temperature sedimentary environments is further proof of the restricted geothermal potential of the Cascade Range.

Cascade Range↗

USGS2003

Scrubbing masks magmatic degassing during repose at Cascade-Range and Aleutian-Arc volcanoes

Between 1992 and 1998, we sampled gas discharges from ≤173°C fumaroles and springs at 12 quiescent but potentially restless volcanoes in the Cascade Range and Aleutian Arc (CRAA) including Mount Shasta, Mount Hood, Mount St. Helens, Mount Rainier, Mount Baker, Augustine Volcano, Mount Griggs, Trident, Mount Mageik, Aniakchak Crater, Akutan, and Makushin. For each site, we collected and analyzed samples to characterize the chemical (H2O, CO2, H2S, N2, CH4, H2, HCl, HF, NH3, Ar, O2, He) and isotopic (δ13C of CO2, 3He/4He, 40Ar/36Ar, δ34S, δ13C of CH4, δ15N, and δD and δ18O of water) compositions of the gas discharges, and to create baseline data for comparison during future unrest. The chemical and isotopic data show that these gases contain a magmatic component that is heavily modified from scrubbing by deep hydrothermal (150° - 350°C) water (primary scrubbing) and shallow meteoric water (secondary scrubbing). The impact of scrubbing is most pronounced in gas discharges from bubbling springs; gases from boiling-point fumaroles and superheated vents show progressively less impact from scrubbing. The most effective strategies for detecting gas precursors to future CRAA eruptions are to measure periodically the emission rates of CO2 and SO2, which have low and high respective solubilities in water, and to monitor continuously CO2 concentrations in soils around volcanic vents. Timely resampling of fumaroles can augment the geochemical surveillance program by watching for chemical changes associated with drying of fumarolic pathways (all CRAA sites), increases in gas geothermometry temperatures (Mount Mageik, Trident, Mount Baker, Mount Shasta), changes in δ13C of CO2 affiliated with magma movement (all CRAA site), and increases in 3He/4He coupled with intrusion of new magma (Mount Rainier, Augustine Volcano, Makushin, Mount Shasta). Repose magmatic degassing may discharge substantial amounts of S and Cl into the edifices of Mount Baker and several other CRAA volcanoes that is trapped by primary and secondary scrubbing. The consequent acidic fluids produce ongoing alteration in the 0.2- to 3-km-deep hydrothermal systems and in fields of boiling-point fumaroles near the surface. Such alteration may influence edifice stability and contribute to the formation of more-hazardous cohesive debris flows. In particular, we recommend further investigation of the volume, extent, and hazards of hydrothermal alteration at Mount Baker. Other potential hazards associated with the CRAA volcano hydrothermal systems include hydrothermal eruptions and, for deeper systems intruded by magma, deep-seated edifice collapse.

Alaska;British Columbia;California;Oregon;Washingt↗

USGS2003

Mantle and Crustal Sources of Carbon, Nitrogen, and Noble gases in Cascade-Range and Aleutian-Arc Volcanic gases

Here we report anhydrous chemical (CO2, H2S, N2, H2, CH4, O2, Ar, He, Ne) and isotopic (3He/4He, 40Ar/36Ar, δ13C of CO2, δ13C of CH4, δ15N) compositions of virtually airfree gas samples collected between 1994 and 1998 from 12 quiescent but potentially restless volcanoes in the Cascade Range and Aleutian Arc (CRAA). Sample sites include ≤173°C fumaroles and springs at Mount Shasta, Mount Hood, Mount St. Helens, Mount Rainier, Mount Baker, Augustine Volcano, Mount Griggs, Trident, Mount Mageik, Aniakchak Crater, Akutan, and Makushin. The chemical and isotopic data generally point to magmatic (CO2, Ar, He), shallow crustal sedimentary (hereafter, SCS) (CO2, N2, CH4), crustal (He), and meteoric (N2, Ar) sources of volatiles. CH4 clearly comes from SCS rocks in the subvolcanic systems because CH4 cannot survive the higher temperatures of deeper potential sources. Further evidence for a SCS source for CH4 as well as for non-mantle CO2 and non-meteoric N2 comes from isotopic data that show wide variations between volcanoes that are spatially very close and similar isotopic signatures from volcanoes from very disparate areas. Our results are in direct opposition to many recent studies on other volcanic arcs (Kita and others, 1993; Sano and Marty, 1995; Fischer and others, 1998), in that they point to a dearth of subducted components of CO2 and N2 in the CRAA discharges. Either the CRAA volcanoes are fundamentally different from volcanoes in other arcs or we need to reevaluate the significance of subducted C and N recycling in convergent-plate volcanoes.

Alaska;British Columbia;California;Oregon;Washingt↗

USGS2003

Shallow soil CO2 flow along the San Andreas and Calaveras Faults, California

We evaluate a comprehensive soil CO2 survey along the San Andreas fault (SAF) in Parkfield, and the Calaveras fault (CF) in Hollister, California, in the context of spatial and temporal variability, origin, and transport of CO2 in fractured terrain. CO2 efflux was measured within grids with portable instrumentation and continously with meteorological parameters at a fixed station, in both faulted and unfaulted areas. Spatial and temporal variability of surface CO2 effluxes was observed to be higher at faulted SAF and CF sites, relative to comparable background areas. However, ??13C (-23.3 to - 16.4???) and ??14C (75.5 to 94.4???) values of soil CO2 in both faulted and unfaulted areas are indicative of biogenic CO2, even though CO2 effluxes in faulted areas reached values as high as 428 g m-2 d-1. Profiles of soil CO2 concentration as a function of depth were measured at multiple sites within SAF and CF grids and repeatedly at two locations at the SAF grid. Many of these profiles suggest a surprisingly high component of advective CO2 flow. Spectral and correlation analysis of SAF CO2 efflux and meteorological parameter time series indicates that effects of wind speed variations on atmospheric air flow though fractures modulate surface efflux of biogenic CO2. The resulting areal patterns in CO2 effluxes could be erroneously attributed to a deep gas source in the absence of isotopic data, a problem that must be addressed in fault zone soil gas studies.

Journal of Geophysical Research B: Solid Earth↗

USGS2002

Tracing and quantifying magmatic carbon discharge in cold groundwaters: Lessons learned from Mammoth Mountain, USA

A major campaign to quantify the magmatic carbon discharge in cold groundwaters around Mammoth Mountain volcano in eastern California was carried out from 1996 to 1999. The total water flow from all sampled cold springs was ??? 1.8 ?? 107 m3/yr draining an area that receives an estimated 2.5 ?? 107 m3/yr of recharge, suggesting that sample coverage of the groundwater system was essentially complete. Some of the waters contain magmatic helium with 3He/4He ratios as high as 4.5 times the atmospheric ratio, and a magmatic component in the dissolved inorganic carbon (DIC) can be identified in virtually every feature sampled. Many waters have a 14C of 0-5 pmC, a ??13C near -5???, and contain high concentrations (20-50 mmol/1) of CO2(aq); but are otherwise dilute (specific conductance = 100-300 ??S/cm) with low pH values between 5 and 6. Such waters have previously escaped notice at Mammoth Mountain, and possibly at many other volcanoes, because CO2 is rapidly lost to the air as the water flows away from the springs, leaving neutral pH waters containing only 1-3 mmol/1 HCO-3. The total discharge of magmatic carbon in the cold groundwater system at Mammoth Mountain is ~ 20 000 t/yr (as CO2), ranging seasonally from about 30 to 90 t/day. Several types of evidence show that this high discharge of magmatic DIC arose in part because of shallow dike intrusion in 1989, but also demonstrate that a long-term discharge possibly half this magnitude (~ 10 000 t/yr) predated that intrusion. To sustain a 10 000 t/yr DIC discharge would require a magma intrusion rate of 0.057 km3 per century, assuming complete degassing of magma with 0.65 wt% CO2 and a density of 2.7 t/m3. The geochemical data also identify a small ( < 1 t/day) discharge of magmatic DIC that can be traced to the Inyo Domes area north of Mammoth Mountain and outside the associated Long Valley caldera. This research, along with recent studies at Lassen Peak and other western USA volcanoes, suggests that the amount of magmatic carbon in cold groundwaters is important to constraining rates of intrusion and edifice weathering at individual volcanoes and may even represent a significant fraction of the global carbon discharge from volcanoes. ?? 2002 Elsevier Science B.V. All rights reserved.

Journal of Volcanology and Geothermal Research↗

USGS2002

Report of hydrologic investigations in the Three Sisters area of central Oregon, Summer 2001

An ongoing episode of crustal uplift centered in the Separation Creek drainage of the Three Sisters area, central Oregon Cascades, may result from a magmatic intrusion that began in 1998. An investigation of springs in this drainage in summer 2001 revealed slightly elevated water temperatures and chloride (Cl - ) concentrations of up to about 5°C and 20 milligrams per liter (mg/L), respectively, above background. The total discharge of anomalous Cl - in Separation Creek was 9.2 grams per second, which in combination with the temperature-Cl - relation in the springs results in a total advective heat discharge of 16 MW (megawatts). Comparison with similar findings obtained a decade earlier suggests that total Cl - and heat discharges in the groundwater drainage are unaffected by the current uplift. However, the isotopic composition of the dissolved inorganic carbon (DIC) in the spring waters (delta carbon-13 ( 13 C) = -9.03 to -11.6‰; carbon-14 ( 14 C) <25 pmC) combined with helium-3/helium-4 ( 3 He/ 4 He) ratios near 8 R A and C/ 3 He ratios <10 10 in two of the springs are indicative of a magmatic source. The high 3 He/ 4 He ratios indicate that the magmatic gas is derived from a relatively recent, if not ongoing, intrusion. The concentration of magmatic carbon is low, a few millimoles per liter (mmol/L) at most, with an average value of 1.53 mmol/L for all the springs sampled in the drainage. Combining this average with the late-summer water flow in Separation Creek suggests a discharge of 21 tonnes/day of magmatic carbon dioxide (CO 2 ). The presence of magmatic carbon in the shallow groundwater system, and the fact that DIC is uncorrelated with Cl - , suggests that some magmatic gas could escape diffusely through the soils.

Oregon↗

USGS2002

Mantle helium and carbon isotopes in Separation Creek geothermal springs, Three Sisters area, central Oregon: Evidence for renewed volcanic activity or a long term steady state system?

Here we present the helium and carbon isotope results from the initial study of a fluid chemistry-monitoring program started in the summer of 2001 near the South Sister volcano in central Oregon. The Separation Creek area which is several miles due west of the volcano is the locus of strong crustal uplift currently occurring at a rate of 4-5 cm/yr (Wicks, et. al. , 2001). Helium [R C /R A = 7.44 and 8.61 R A (R C /R A = ( 3 He/ 4 He) sample-air corrected /( 3 He/ 4 He) air ))] and carbon (δ 13 C = -11.59 to -9.03 ‰ vs PDB) isotope data and CO 2 / 3 He (5 and 9 x 10 9 ) show that bubbling cold springs in the Separation Creek area near South Sister volcano carry a strong mantle signal, indicating the presence of fresh basaltic magma in the volcanic plumbing system. There is no evidence though, to directly relate this signal to the crustal uplift that is currently taking place in the area, which started in 1998. The geothermal system in the area is apparently much longer lived and shows no significant changes in chemistry compared to data from the early 1990s. Hot springs in the area, which are relatively far removed from the volcanic edifice, do not carry a strong mantle signal in helium isotope ratios (2.79 to 5.08 R A ), unlike the cold springs, and also do not show any significant changes in helium isotope ratios compared to literature data for the same springs of over two decades ago. The cold springs of the Separation Creek area form a very diffuse but significant low temperature geothermal system, that should, due to its close vicinity to the center of up uplift, be more sensitive to changes in the deeper volcanic plumbing system than the far removed hot springs and therefore require much more study and consideration when dealing with volcano monitoring in the Cascade range or possibly with geothermal exploration in general.

Oregon↗

USGS2001

High CO2 emissions through porous media: Transport mechanisms and implications for flux measurement and fractionation

Diffuse emissions of CO 2 are known to be large around some volcanoes and hydrothermal areas. Accumulation-chamber measurements of CO 2 flux are increasingly used to estimate the total magmatic or metamorphic CO 2 released from such areas. To assess the performance of accumulation chamber systems at fluxes one to three orders of magnitude higher than normally encountered in soil respiration studies, a test system was constructed in the laboratory where known fluxes could be maintained through dry sand. Steady-state gas concentration profiles and fractionation effects observed in the 30-cm sand column nearly match those predicted by the Stefan-Maxwell equations, indicating that the test system was functioning successfully as a uniform porous medium. Eight groups of investigators tested their accumulation chamber equipment, all configured with continuous infrared gas analyzers (IRGA), in this system. Over a flux range of ∼200–12,000 g m −2 day −1 , 90% of their 203 flux measurements were 0–25% lower than the imposed flux with a mean difference of −12.5%. Although this difference would seem to be within the range of acceptability for many geologic investigations, some potential sources for larger errors were discovered. A steady-state pressure gradient of −20 Pa/m was measured in the sand column at a flux of 11,200 g m −2 day −1 . The derived permeability (50 darcies) was used in the dusty-gas model (DGM) of transport to quantify various diffusive and viscous flux components. These calculations were used to demonstrate that accumulation chambers, in addition to reducing the underlying diffusive gradient, severely disrupt the steady-state pressure gradient. The resultant diversion of the net gas flow is probably responsible for the systematically low flux measurements. It was also shown that the fractionating effects of a viscous CO 2 efflux against a diffusive influx of air will have a major impact on some important geochemical indicators, such as N 2 /Ar, δ 15 N–N 2 , and 4 He/ 22 Ne.

Chemical Geology↗

USGS2001

Radiocarbon studies of plant leaves and rings from mammoth mountain, CA: A long-term record of magmatic CO2 release

Evaluation of 14C in tree rings provides a measure of the flux of magmatic CO2 from Mammoth Mountain both before and after 1994 when copious diffuse emissions were first discovered and linked to tree kill. We analyzed the annual rings of trees with two main purposes: (1) to track changes in the magnitude of magmatic CO2 emission over time, and (2) to determine the onset of magmatic CO2 emission at numerous sites on Mammoth Mountain. The onset of CO2 emission at different areas of tree kill was determined to be in 1990, closely following the seismic events of 1989. At Horseshoe Lake (HSL), CO2 emission was found to have peaked in 1991 and to have subsequently declined by a factor of two through 1998. The tree-ring data also show that emissions of magmatic carbon from cold springs below the tree-kill areas occurred well before 1989. Trees located on the margins of the kill areas or otherwise away from zones of maximum gas discharge were found to be better integrators of magmatic CO2 emission than those located in the center of tree kills. Although quantitative extrapolations from our data to a flux history will require that a relationship be established between 14C depletion in tree rings and average annual magmatic CO2 flux, the pattern of 14C depletion in tree rings is likely to be the most reliable indicator of the long-term changes in the magnitude of CO2 release from Mammoth Mountain. ?? 2001 Elsevier Science B.V. All rights reserved.

Chemical Geology↗

USGS2000

Invisible CO2 gas killing trees at Mammoth Mountain, California

Since 1980, scientists have monitored geologic unrest in Long Valley Caldera and at adjacent Mammoth Mountain, California. After a persistent swarm of earthquakes beneath Mammoth Mountain in 1989, geologists discovered that large volumes of carbon dioxide (CO2 ) gas were seeping from beneath this volcano. This gas is killing trees on the mountain and also can be a danger to people. The U.S. Geological Survey (USGS) continues to study the CO2 emissions to help protect the public from this invisible potential hazard.

Fact Sheet↗

USGS2000

Hydrothermal activity and carbon-dioxide discharge at Shrub and upper Klawasi mud volcanoes, Wrangell Mountains, Alaska

Shrub mud volcano, one of three mud volcanoes of the Klawasi group in the Copper River Basin, Alaska, has been discharging warm mud and water and CO 2 –rich gas since 1996. A field visit to Shrub in June 1999 found the general level of hot-spring discharge to be similar, but somewhat more widespread, than in the previous two years. Evidence of recent animal and vegetation deaths from CO 2 exposure were confined to localized areas around various gas and fluid vents. Maximum fluid temperatures in each of three main discharge areas, ranging from 48-54°C, were equal to or higher than those measured in the two previous years; such temperatures are significantly higher than those observed intermittently over the past 30 years. At Upper Klawasi mud volcano, measured temperatures of 23-26°C and estimated rates of gas and water discharge in the summit crater lake were also similar to those observed in the previous two years. Gas discharging at Shrub and Upper Klawasi is composed of over 98% CO 2 and minor amounts of meteoric gases (N 2 , O 2 , Ar) and gases partly of deeper origin (CH 4 and He). The rate of CO 2 discharge from spring vents and pools at Shrub is estimated to be ~10 metric tonnes per day. This discharge, together with measured concentrations of bicarbonate, suggest that a total CO 2 upflow from depth of 20-40 metric tonnes per day at Shrub. Measurements were made of diffuse degassing rates from soil at one ~300 m 2 area near the summit of Shrub that included vegetation kill suggestive of high CO 2 concentrations in the root zone. Most of measured gas flow rates in this area were significantly higher than background values, and a CO 2 concentration of 26 percent was measured at a depth of 10 cm where the gas flow rate was highest. Although additional measurements of diffuse gas flow were made elsewhere at Shrub, no other areas of vegetation kill related to diffuse degassing and high soil-gas CO 2 concentrations could be seen from the air. Chemical and isotopic compositions of the gas and water discharging at Shrub and Upper Klawasi indicate derivation from a combination of mantle (magmatic) and crustal (marine sedimentary rock) sources and suggest a common fluid reservoir at depth. In particular, both the total dissolved carbon and values of 13 C in CO 2 are similar for fluids and gas sampled at each area, and do not appear to have changed with the onset of increased spring temperatures and fluid discharge at Shrub. This suggests that the underlying cause of the recent changes in discharge rate and temperature at Shrub is not an increase in the rate of input of magmatic heat and volatiles, but rather increases in the permeability of the upflow conduits that connect the gas-rich reservoir to the surface.

Alaska↗

USGS1999

Geochemistry and hydromechanical interactions of fluids associated with the San Andreas fault system, California

18 O values establish that waters are predominantly of meteoric origin. The chemical compositions of water and gases are controlled mainly by the ambient rock types, and chemical geothermometry gives reservoir temperatures of 80-150 degrees C indicating shallow to moderate circulation depths of up to 6 km. However, compositions and isotope abundances of noble gases and delta 13 C values of HCO 3 indicate a significant (up to 50%) mantle component for the volatiles. The relatively high fluxes of CO 2 (C/ 3 He nearly equal 10 10 ) and other volatiles of mantle origin support a deep continuous flow model, especially at depths >6 km. Numerical simulations indicate that these high fluxes of CO 2 of mantle and deep crustal origin are sufficient to generate lithostatic fluid pressures, and thus a weakened fault, in time scales comparable to those of earthquake cycles.

California↗

USGS1998

Carbon dioxide and helium emissions from a reservoir of magmatic gas beneath Mammoth Mountain, California

Carbon dioxide and helium with isotopic compositions indicative of a magmatic source ( δ 13 C = −4.5 to −5‰, 3 He/ 4 He = 4.5 to 6.7 R A ) are discharging at anomalous rates from Mammoth Mountain, on the southwestern rim of the Long Valley caldera in eastern California. The gas is released mainly as diffuse emissions from normal‐temperature soils, but some gas issues from steam vents or leaves the mountain dissolved in cold groundwater. The rate of gas discharge increased significantly in 1989 following a 6‐month period of persistent earthquake swarms and associated strain and ground deformation that has been attributed to dike emplacement beneath the mountain. An increase in the magmatic component of helium discharging in a steam vent on the north side of Mammoth Mountain, which also began in 1989, has persisted until the present time. Anomalous CO 2 discharge from soils first occurred during the winter of 1990 and was followed by observations of several areas of tree kill and/or heavier than normal needlecast the following summer. Subsequent measurements have confirmed that the tree kills are associated with CO 2 concentrations of 30–90% in soil gas and gas flow rates of up to 31,000 g m −2 d −1 at the soil surface. Each of the tree‐kill areas and one area of CO 2 discharge above tree line occurs in close proximity to one or more normal faults, which may provide conduits for gas flow from depth. We estimate that the total diffuse CO 2 flux from the mountain is approximately 520 t/d, and that 30–50 t/d of CO 2 are dissolved in cold groundwater flowing off the flanks of the mountain. Isotopic and chemical analyses of soil and fumarolic gas demonstrate a remarkable homogeneity in composition, suggesting that the CO 2 and associated helium and excess nitrogen may be derived from a common gas reservoir whose source is associated with some combination of magmatic degassing and thermal metamorphism of metasedimentary rocks. Furthermore, N 2 /Ar ratios and nitrogen isotopic values indicate that the Mammoth Mountain gases are derived from sources separate from those that supply gas to the hydrothermal system within the Long Valley caldera. Various data suggest that the Mammoth Mountain gas reservoir is a large, low‐temperature cap over an isolated hydrothermal system, that it predates the 1989 intrusion, and that it could remain a source of gas discharge for some time.

Journal of Geophysical Research B: Solid Earth↗