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Geology topics

William C. Evans

Publications and source records attributed to William C. Evans.

At least 91 records · Page 5Linked to original sources
USGS1996

Invisible CO2 gas killing trees at Mammoth Mountain, California

Since 1980, scientists have monitored geologic unrest in Long Valley Caldera and at adjacent Mammoth Mountain, California. After a persistent swarm of earthquakes beneath Mammoth Mountain in 1989, earth scientists discovered that large volumes of carbon dioxide (CO 2 ) gas were seeping from beneath this volcano. This gas is killing trees on the mountain and also can be a danger to people. The USGS continues to study the CO 2 emissions to help protect the public from this invisible potential hazard.

California↗
USGS1995

Forest-killing diffuse CO2 emission at Mammoth Mountain as a sign of magmatic unrest

Mammoth Mountain, in the western United States, is a large dacitic volcano with a long history of volcanism that began 200 kyr ago and produced phreatic eruptions as recently as 500 ± 200 yr BP. Seismicity, ground deformation and changes in fumarole gas composition suggested an episode of shallow dyke intrusion in 1989–90. Areas of dying forest and incidents of near asphyxia in confined spaces, first reported in 1990, prompted us to search for diffuse flank emissions of magmatic CO 2 , as have been described at Mount Etna and Vulcano . Here we report the results of a soil-gas survey, begun in 1994, that revealed CO 2 concentrations of 30–96% in a 30-hectare region of killed trees, from which we estimate a total CO 2 flux of ≥1,200 tonnes per day. The forest die-off is the most conspicuous surface manifestation of magmatic processes at Mammoth Mountain, which hosts only weak fumarolic vents and no summit activity. Although the onset of tree kill coincided with the episode of shallow dyke intrusion, the magnitude and duration of the CO 2 flux indicates that a larger, deeper magma source and/or a large reservoir of high-pressure gas is being tapped.

California↗
USGS1994

In search of earthquake-related hydrologic and chemical changes along Hayward Fault

Flow and chemical measurements have been made about once a month, and more frequently when required, since 1976 at two springs in Alum Rock Park in eastern San Jose, California, and since 1980 at two shallow wells in eastern Oakland in search of earthquake-related changes. All sites are on or near the Hayward Fault and are about 55 km apart. Temperature, electric conductivity, and water level or flow rate were measured in situ with portable instruments. Water samples were collected for later chemical and isotopic analyses in the laboratory. The measured flow rate at one of the springs showed a long-term decrease of about 40% since 1987, when a multi-year drought began in California. It also showed several increases that lasted a few days to a few months with amplitudes of 2.4 to 8.6 times the standard deviations above the background rate. Five of these increases were recorded shortly after nearby earthquakes of magnitude 5.0 or larger, and may have resulted from unclogging of the flow path and increase of permeability caused by strong seismic shaking. Two other flow increases were possibly induced by exceptionally heavy rainfalls. The water in both wells showed seasonal temperature and chemical variations, largely in response to rainfall. In 1980 the water also showed some clear chemical changes unrelated to rainfall that lasted a few months; these changes were followed by a magnitude 4 earthquake 37 km away. The chemical composition at one of the wells and at the springs also showed some longer-term variations that were not correlated with rainfall but possibly correlated with the five earthquakes mentioned above. These correlations suggest a common tectonic origin for the earthquakes and the anomalies. The last variation at the affected well occurred abruptly in 1989, shortly before a magnitude 5.0 earthquake 54 km away. ?? 1993.

California↗
USGS1994

Six years of change in Lake Nyos, Cameroon, yield clues to the past and cautions for the future

The catastrophic release of gas from Lake Nyos, Cameroon, in 1986 caused substantial but incomplete mixing of the stratified water column. The post-release evolution of water-column structure has been monitored through April 1992. Changes began immediately after the event as rainfall and inflow brought dilute fluid into the surface layer. Inflow and surface mixing have gradually deepened the chemocline. The Total Dissolved Solids (TDS) values in the upper 40 m of the water column have dropped from a few hundred mg/kg just after the release to <100 mg/kg. The chemocline is presently strongest at 50 m depth; 5 m below this, the TDS = 570 mg/kg. From 55 to 150 m depth is a gentle gradient in which TDS reaches 920 mg/kg. Little change in water-column chemistry has occurred in this depth interval since the release. Between 150 m depth and lake bottom at 210 m depth, a strong secondary chemocline has formed. Temperature, CO 2 concentration ([CO 2 ]), and TDS have all increased in the deepest layer in response to recharge by warm, mineralized water, reaching values of 25.0°C, 320 mmol/kg, and 1800 mg/kg, respectively, 1 m above lake bottom. Considering all these changes in part as a “recovery” process, it is possible to construct a model of the pre-release water column. The data indicate that the pre-release chemocline was at least 50 m deep. Above the chemocline was a dilute layer containing a seasonal thermocline; below the chemocline was probably a gradient zone(s) with correlated increases in TDS and [CO 2 ] and a secondary chemocline near lake bottom. Maximum values of TDS and [CO 2 ] calculated for pre-release bottom water are 2400 mg/kg and 430 mmol/kg, respectively, based on tritium data. From this pre-release structure, a model of the gas release is proposed that is consistent with available chemical and observational data. An important feature of the model is that disruption of the pre-existing stratification was much more extensive than previously proposed, and even the deepest water layers were involved in the event. This model is not intended to limit possible gas release mechanisms, and thus complete re-establishment of pre-1986 water-column conditions is not a prerequisite for a future release. Spontaneous instability could occur at lake bottom in <20 yr if dissolved gas pressures continue to increase in this zone by 0.5–1 bar/yr as they have for the last 6 yr.

Lake Nyos↗
USGS1994

Chemical, isotopic, and dissolved gas compositions of the hot springs of the Owyhee Uplands, Malheur County, Oregon

Hot springs along the Owyhee River in southeastern Oregon between Three Forks and Lake Owyhee could be part of a north flowing regional system or a series of small separate geothermal systems Heat for the waters could be from a very young (Holocene) volcanic activity (basalt flows) of the Owyhee Uplands or the regional heat flow. The springs discharge warm to hot, dilute, slightly alkaline, sodium bicarbonate water. Chemically they are similar to the dilute thermal water at Bruneau Grand View and Twin Falls, Idaho. Maximum aquifer temperatures in the Owyhee Uplands, estimated from chemical geothermometry, are about 100°C. Dissolved helium concentrations, carbon 14 activity, and chemical and isotope data are examined fro systematic trends which would indicate a geothermal system of regional extent.

Oregon↗
USGS1993

Geothermometry and water-rock interaction in selected thermal systems in the Cascade Range and Modoc Plateau, western United States

The sulfate—water isotope geothermometer indicates higher equilibrium temperatures than the silica or cation ratio geothermometers for the Na—Cl and Na—Ca—Cl thermal waters of the Cascade Range, Oregon and the Na—SO 4 thermal waters of the Modoc Plateau, northeastern California. Sulfate concentrations in the Na—Ca—Cl waters decrease as σ 18 O values of the dissolved sulfate become more depleted; conversely, sulfate concentrations in the Na—SO 4 waters increase as σ 18 O values of the sulfate become more depleted. Calculations show that the thermal waters are theoretically saturated with respect to anhydrite (CaSO 4 ) at temperatures very close to those calculated from the sulfate—water isotope geothermometer.

Geothermics↗
USGS1992

Thermal waters along the Konocti Bay fault zone, Lake County, California: a re-evaluation

The Konocti Bay fault zone (KBFZ), initially regarded by some as a promising target for liquid-dominated geothermal systems, has been a disappointment. At least five exploratory wells were drilled in the vicinity of the KBFZ, but none were successful. Although the Na-K-Ca and Na-Li geothermometers indicate that the thermal waters discharging in the vicinity of Howard and Seigler Springs may have equilibrated at temperatures greater than 200??C, the spring temperatures and fluid discharges are low. Most thermal waters along the KBFZ contain >100 mg/l Mg. High concentrations of dissolved magnesium are usually indicative of relatively cool hydrothermal systems. Dissolution of serpentine at shallow depths may contribute dissolved silica and magnesium to rising thermal waters. Most thermal waters are saturated with respect to amorphous silica at the measured spring temperature. Silica geothermometers and mixing models are useless because the dissolved silica concentration is not controlled by the solubility of either quartz or chalcedony. Cation geothermometry indicates the possibility of a high-temperature fluid (> 200??C) only in the vicinity of Howard and Seigler Springs. However, even if the fluid temperature is as high as that indicated by the geothermometers, the permeability may be low. Deuterium and oxygen-18 values of the thermal waters indicate that they recharged locally and became enriched in oxygen-18 by exchange with rock. Diluting meteoric water and the thermal water appear to have the same deuterium value. Lack of tritium in the diluted spring waters suggest that the diluting water is old. ?? 1992.

Journal of Volcanology and Geothermal Research↗
USGS1989

Geochemistry of thermal water from selected wells, Boise, Idaho

Samples of thermal water from selected wells in the Boise area were analyzed for chemical composition; stable isotopes of hydrogen, oxygen, and dissolved carbon; radioactive carbon; and dissolved-gas concentrations. Chemically, the waters are virtually identical to those of the adjacent Idaho batholith. Isotopically, the thermal waters are more depleted in deuterium and oxygen-18 than coldwater springs in the presumed recharge area. Chemical and isotopic data indicate the presence of two separate geothermal systems. Radioactive carbon and dissolved helium concentrations are interpreted to indicate recharge during the Pleistocene. Hot water in or southeast of Boise probably recharged 20,000 to 30,000 years ago, and warm water 2.5 miles northwest of Boise probably recharged at least 15,000 years ago.

Conference Paper↗
USGS1989

The evolution of thermal structure and water chemistry in Lake Nyos

We collected a time series of physical and chemical data to gain a better understanding of the dynamics of Lake Nyos. Measurements of water and gas chemistry, and temperature made during January, March, and May 1987 are compared to data taken in September 1986 just after the initial CO2 gas release. There is no pattern of change in overall heat content of the lake, although heat input to bottom waters (185-208 m) has occurred at a rate of 1600 mW m-2. This increase in heat content translates to a change from 23.38 to 24.12??C at 200 m and can be explained by geothermal heat flow and addition of thermal spring water. Concentrations of Ca2+, Mg2+, Na+, K+, Fe2+ and alkalinity have increased only in bottom waters. In situ lake processes such as sulfate and iron reduction are unable to account for the changes in alkalinity. Observed chemical changes are consistent with a scenario where slightly thermal soda water is being input to the bottom of the lake. Measurements of pCO2 at depth ranged from 18 to 28% of saturation and exhibited horizontal variability. Overall recharge of CO2 in bottom waters is negligible. Mainly because of increasing ion concentrations in bottom water, total stability of the water column increased 33% from 48,800 J m-2 in September 1986 to 64,700 J m-2 in May 1987. As long as CO2 concentrations remain the same, this level of stability is higher than could be disrupted by common limnologic or meteorologic processes. There is thermal and chemical evidence that a buildup of dissolved iron and CO2 in bottom waters must have preceded the August 1986 gas release. In addition, a survey of all crater lakes in Cameroon indicates that only Lakes Nyos and Monoun contain high concentrations of dissolved iron and CO2. Thus there is a low probability of any other Cameroonian lake releasing a substantial volume of CO2. ?? 1989.

Journal of Volcanology and Geothermal Research↗
USGS1988

The role of mantle CO2 in volcanism

Carbon dioxide is the propellant gas in volcanic eruptions and is also found in mantle xenoliths. It is speculated that CO2 occurs as a free gas phase in the mantle because there is no reason to expect CO2 to be so universally associated with volcanic rocks unless the CO2 comes from the same source as the volcanic rocks and their xenoliths. If correct, the presence of a free gas in the mantle would lead to physical instability, with excess gas pressure providing the cause of both buoyancy of volcanic melts and seismicity in volcanic regions. Convection in the mantle and episodic volcanic eruptions are likely necessary consequences. This suggestion has considerable implications for those responsible for providing warnings of impending disasters resulting from volcanic eruptions and earthquakes in volcanic regions.

Applied Geochemistry↗
USGS1987

Liquid carbon dioxide of magmatic origin and its role in volcanic eruptions

Natural liquid carbon dioxide is produced commercially from a 2.5-km-deep well near the 4,500-yr-old maar volcano, Mount Gambier, South Australia. The carbon dioxide has accumulated in a dome that is located on the extension of a linear chain of volcanic activity. A magmatic origin for the fluid is suggested by the geological setting, δ 13 C PDB of –4.0‰, for the CO 2 (where PDB represents the carbon-isotope standard), and a relatively high 3 He component of the contained helium and high 3 He/C ratio (6.4 x 10 −10 ). The 3 He/ 4 He and He/Ne ratios are 3.0 and > 1,370 times those of air, respectively. The CO 2 , as collected at the Earth's surface at 29.5 °C and 75 bar, expands more than 300-fold to form a gas at 1 atm and 22 °C. We suggest that liquid CO 2 or high-density CO 2 fluid (the critical point is 31.1 °C, 73.9 bar) of volcanic origin that expands explosively from shallow levels in the Earth's crust may be a major contributor to 'phreatic' volcanic eruptions and maar formation. Less violent release of magmatic CO 2 into crater lakes may cause gas bursts with equally disastrous consequences such as occurred at Lake Nyos, Cameroon, in August 1986.

Nature↗
USGS1982

Chemical and isotopic composition of water from thermal springs and mineral springs of Washington

Water from thermal springs of Washington range in chemical composition from dilute NaHC03, to moderately saline C02-charged NaHC03-Cl waters. St. Martin 's Hot Spring which discharges a slightly saline NaCl water, is the notable exception. Mineral springs generally discharge a moderately saline C02-charged NaHC03-Cl water. The dilute Na-HC03 waters are generally associated with granite. The warm to hot waters charged with C02 issue on or near the large stratovolcanoes and many of the mineral springs also occur near the large volcanoes. The dilute waters have oxygen isotopic compositions which indicate relatively little water-rock exchange. The C02-charged waters are usually more enriched in oxygen-18 due to more extensive water-rock reaction. Carbon-13 in the C02-charged thermal waters is more depleted (-10 to -12 permil) than in the cold C02-charged soda springs (-2 to -8 permil) which are also scattered throughout the Cascades. The hot and cold C02-charged waters are supersaturated with respect to CaC03, but only the hot springs are actively depositing CaC03. Baker, Gamma, Sulphur , and Ohanapecosh seem to be associated with thermal aquifers of more than 100C. (USGS)

Open-File Report↗
USGS1977

Hot springs of the central Sierra Nevada, California

Thermal springs of the central Sierra Nevada issue dilute to slightly saline sodium chloride, sodium bicarbonate, or sodium mixed-anion waters ranging in pH from 6.4 to 9.3. The solubility of chalcedony appears to control the silica concentration in most of the spring waters. Fales Hot Springs may be associated with a higher temperature aquifer, 150 degrees Celsius or more, in which quartz is controlling the silica concentration. Carbon dioxide is the predominant gas escaping from Fales Hot Springs, the unnamed hot spring on the south side of Mono Lake, and the two thermal springs near Bridgeport. Most of the other thermal springs issue small amounts of gas consisting principally of nitrogen. Methane is the major component of the gas escaping from the unnamed spring on Paoha Island in Mono Lake. The deuterium and oxygen isotopic composition of most of the thermal waters are those expected for local meteoric water which has undergone minor water-rock reaction. The only exceptions are the hot spring on Paoha Island in Mono Lake and perhaps the unnamed warm spring (south side of Mono Lake) which issues mixtures of thermal water and saline lake water. (Woodard-USGS)

Open-File Report↗
USGS1977

Chemical, isotopic, and gas compositions of selected thermal springs in Arizona, New Mexico, and Utah

Twenty-seven thermal springs in Arizona, New Mexico, and Utah were sampled for detailed chemical and isotopic analysis. The springs issue sodium chloride, sodium bicarbonate, or sodium mixed-anion waters of near neutral (6.2) to alkaline (9.2) pH. High concentrations of fluoride, more than 8 milligrams per liter, occur in Arizona in waters from Gillard Hot Springs, Castle Hot Springs, and the unnamed spring of Eagle Creek, and in New Mexico from springs along the Gila River. Deuterium compositions of the thermal waters cover the same range as those expected for meteoric waters in the respective areas. The chemical compositions of the thermal waters indicate that Thermo Hot Springs in Utah and Gillard Hot Springs in Arizona represent hydrothermal systems which are at temperatures higher than 125 deg C. Estimates of subsurface temperature based on the quartz and Na-K-Ca geothermometer differ by up to 60 deg C for Monroe, Joseph, Red Hill, and Crater hot springs in Utah. Similar conflicting estimates of aquifer temperature occur for Verde Hot Springs, the springs near Clifton and Coolidge Dam, in Arizona; and the warm springs near San Ysidro, Radium Hot Springs, and San Francisco Hot Springs, in New Mexico. Such disparities could result from mixing, precipitation of calcium carbonate, or perhaps appreciable concentrations of magnesium. (Woodard-USGS)

Open-File Report↗