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William C. Evans

Publications and source records attributed to William C. Evans.

At least 55 records · Page 3Linked to original sources
USGS2012

Insights from fumarole gas geochemistry on the origin of hydrothermal fluids on the Yellowstone Plateau

The chemistry of Yellowstone fumarole gases shows the existence of two component waters, type MC, influenced by the addition of deep mantle fluid, and type CC, influenced by crustal interactions (CC). MC is high in 3 He/ 4 He (22 Ra) and low in 4 He/ 40 Ar (∼1), reflecting input of deep mantle components. The other water is characterized by 4 He concentrations 3–4 orders of magnitude higher than air-saturated meteoric water (ASW). These high He concentrations originate through circulation in Pleistocene volcanic rocks, as well as outgassing of Tertiary and older (including Archean) basement, some of which could be particularly rich in uranium, a major 4 He source. Consideration of CO 2 –CH 4 –CO–H 2 O–H 2 gas equilibrium reactions indicates equilibration temperatures from 170 °C to 310 °C. The estimated temperatures highly correlate with noble-gas variations, suggesting that the two waters differ in temperature. Type CC is ∼170 °C whereas the MC is hotter, at 340 °C. This result is similar to models proposed by previous studies of thermal water chemistry. However, instead of mixing the deep hot component simply with cold, meteoric waters we argue that addition of a 4 He-rich component, equilibrated at temperatures around 170 °C, is necessary to explain the range in fumarole gas chemistry.

Wyoming↗
USGS2012

Avian mortality associated with a volcanic gas seep at Kiska Island, Aleutian Islands, Alaska

We identified natural pits associated with avian mortality at the base of Kiska Volcano in the western Aleutian Islands, Alaska in 2007. Living, moribund, and dead birds were regularly found at low spots in a canyon between two lava flows during 2001–2006, but the phenomenon was attributed to natural trapping and starvation of fledgling seabirds (mostly Least Auklets, Aethia pusilla ) at a colony site with >1 million birds present. However, 302 birds of eight species, including passerines, were found dead at the site during 2007–2010, suggesting additional factors were involved. Most carcasses showed no signs of injury and concentrations of dead birds had accumulated in a few distinctive low pits in the canyon. Gas samples from these locations showed elevated CO 2 concentrations in late 2010. Analysis of carcasses indicated no evidence of blunt trauma or internal bleeding. Volcanic gases accumulating at these poorly ventilated sites may have caused the observed mortality, but are temporally variable. Most auklets breeding in the Aleutian Islands do so in recent lava flows that provide breeding habitat; our study documents a cost of this unusual habitat selection.

Alaska↗
USGS2012

Water chemistry and electrical conductivity database for rivers in Yellowstone National Park, Wyoming

Chloride flux has been used to estimate heat flow in volcanic environments since the method was developed in New Zealand by Ellis and Wilson (1955). The method can be applied effectively at Yellowstone, because nearly all of the water discharged from its thermal features enters one of four major rivers (the Madison, Yellowstone, Snake, and Falls Rivers) that drain the park, and thus integration of chloride fluxes from all these rivers provides a means to monitor the total heat flow from the entire Yellowstone volcanic system (Fournier and others, 1976; Fournier, 1979). Fournier (1989) summarized the results and longterm heat-flow trends from Yellowstone, and later efforts that applied the chloride inventory method to estimate heat flow were described by Ingebritsen and others (2001) and Friedman and Norton (2007). Most recently, the U.S. Geological Survey (USGS), in conjunction with the National Park Service, has provided publicly accessible reports on solute flux, based on periodic sampling at selected locations (Hurwitz and others, 2007a,b). While these studies have provided a wealth of valuable data, winter travel restrictions and the great distances between sites present significant logistical challenges and have limited collection to a maximum of 28 samples per site annually. This study aims to quantify relations between solute concentrations (especially chloride) and electrical conductivity for several rivers in Yellowstone National Park (YNP), by using automated samplers and conductivity meters. Norton and Friedman (1985) found that chloride concentrations and electrical conductivity have a good correlation in the Falls, Snake, Madison, and Yellowstone Rivers. However, their results are based on limited sampling and hydrologic conditions and their relation with other solutes was not determined. Once the correlations are established, conductivity measurements can then be used as a proxy for chloride concentrations, thereby enabling continuous heat-flow estimation on a much finer timescale and at lower cost than is currently possible with direct sampling. This publication serves as a repository for all data collected during the course of the study from May 2010 through July 2011, but it does not include correlations between solutes and conductivity or recommendations for quantification of chloride through continuous electrical conductivity measurements. This will be the object of a future document.

Wyoming↗
USGS2011

Monitoring CO2 emissions in tree kill areas near the resurgent dome at Long Valley Caldera, California

We report results of yearly measurements of the diffuse CO 2 flux and shallow soil temperatures collected since 2006 across two sets of tree-kill areas at Long Valley Caldera, California. These data provide background information about CO 2 discharge during a period with moderate seismicity, but little to no deformation. The tree kills are located at long-recognized areas of weak thermal fluid upflow, but have expanded in recent years, possibly in response to geothermal fluid production at Casa Diablo. The amount of CO 2 discharged from the older kill area at Basalt Canyon is fairly constant and is around 3-5 tonnes of CO 2 per day from an area of about 15,000 m 2 . The presence of isobutane in gas samples from sites in and around Basalt Canyon suggests that geothermal fluid production directly effects fluid upflow in the region close to the power plant. The average fluxes at Shady Rest are lower than average fluxes at Basalt Canyon, but the area affected by fluid upflow is larger. Total CO 2 discharged from the central portion of the kill area at Shady Rest has been variable, ranging from 6 to11 tonnes per day across 61,000 m 2 . Gas collected at Shady Rest contains no detectable isobutane to link emissions chemically to geothermal fluid production, but two samples from 2009-10 have detectable H 2 S and suggest an increasing geothermal character of emitted gas. The appearance of this gas at the surface may signal increased drawdown of water levels near the geothermal productions wells.

California↗
USGS2010

Tree-ring 14C links seismic swarm to CO2 spike at Yellowstone, USA

Mechanisms to explain swarms of shallow seismicity and inflation-deflation cycles at Yellowstone caldera (western United States) commonly invoke episodic escape of magma-derived brines or gases from the ductile zone, but no correlative changes in the surface efflux of magmatic constituents have ever been documented. Our analysis of individual growth rings in a tree core from the Mud Volcano thermal area within the caldera links a sharp ~25% drop in 14C to a local seismic swarm in 1978. The implied fivefold increase in CO2 emissions clearly associates swarm seismicity with upflow of magma-derived fluid and shows that pulses of magmatic CO2 can rapidly traverse the 5-kmthick brittle zone, even through Yellowstone's enormous hydrothermal reservoir. The 1978 event predates annual deformation surveys, but recognized connections between subsequent seismic swarms and changes in deformation suggest that CO2 might drive both processes. ?? 2010 Geological Society of America.

Geology↗
USGS2010

River solute fluxes reflecting active hydrothermal chemical weathering of the Yellowstone Plateau Volcanic Field, USA

In the past few decades numerous studies have quantified the load of dissolved solids in large rivers to determine chemical weathering rates in orogenic belts and volcanic areas, mainly motivated by the notion that over timescales greater than ~100kyr, silicate hydrolysis may be the dominant sink for atmospheric CO2, thus creating a feedback between climate and weathering. Here, we report the results of a detailed study during water year 2007 (October 1, 2006 to September 30, 2007) in the major rivers of the Yellowstone Plateau Volcanic Field (YPVF) which hosts Earth's largest "restless" caldera and over 10,000 thermal features. The chemical compositions of rivers that drain thermal areas in the YPVF differ significantly from the compositions of rivers that drain non-thermal areas. There are large seasonal variations in river chemistry and solute flux, which increases with increasing water discharge. The river chemistry and discharge data collected periodically over an entire year allow us to constrain the annual solute fluxes and to distinguish between low-temperature weathering and hydrothermal flux components. The TDS flux from Yellowstone Caldera in water year 2007 was 93t/km2/year. Extensive magma degassing and hydrothermal interaction with rocks accounts for at least 82% of this TDS flux, 83% of the cation flux and 72% of the HCO3- flux. The low-temperature chemical weathering rate (17t/km2/year), calculated on the assumption that all the Cl- is of thermal origin, could include a component from low-temperature hydrolysis reactions induced by CO2 ascending from depth rather than by atmospheric CO2. Although this uncertainty remains, the calculated low-temperature weathering rate of the young rhyolitic rocks in the Yellowstone Caldera is comparable to the world average of large watersheds that drain also more soluble carbonates and evaporates but is slightly lower than calculated rates in other, less-silicic volcanic regions. Long-term average fluxes at Yellowstone are likely ~20% higher than those in the abnormally dry water year 2007, but the protocol used in this study can be easily adaptable to track future changes in low-temperature weathering and hydrothermal flux components, which could provide better monitoring of magmatic unrest. ?? 2010.

Chemical Geology↗
USGS2009

Diffuse gas emissions at the Ukinrek Maars, Alaska: Implications for magmatic degassing and volcanic monitoring

Diffuse CO2 efflux near the Ukinrek Maars, two small volcanic craters that formed in 1977 in a remote part of the Alaska Peninsula, was investigated using accumulation chamber measurements. High CO2 efflux, in many places exceeding 1000 g m−2 d−1, was found in conspicuous zones of plant damage or kill that cover 30,000–50,000 m2 in area. Total diffuse CO2 emission was estimated at 21–44 t d−1. Gas vents 3-km away at The Gas Rocks produce 0.5 t d−1 of CO2 that probably derives from the Ukinrek Maars basalt based on similar δ13C values (∼−6‰), 3He/4He ratios (5.9–7.2 RA), and CO2/3He ratios (1–2 × 109) in the two areas. A lower 3He/4He ratio (2.7 RA) and much higher CO2/3He ratio (9 × 1010) in gas from the nearest arc-front volcanic center (Mount Peulik/Ugashik) provide a useful comparison. The large diffuse CO2 emission at Ukinrek has important implications for magmatic degassing, subsurface gas transport, and local toxicity hazards. Gas–water–rock interactions play a major role in the location, magnitude and chemistry of the emissions.

Alaska↗
USGS2009

Long-term changes in quiescent degassing at Mount Baker Volcano, Washington, USA; Evidence for a stalled intrusion in 1975 and connection to a deep magma source

Long-term changes have occurred in the chemistry, isotopic ratios, and emission rates of gas at Mount Baker volcano following a major thermal perturbation in 1975. In mid-1975 a large pulse in sulfur and carbon dioxide output was observed both in emission rates and in fumarole samples. Emission rates of CO2 and H2S were ∼ 950 and 112 t/d, respectively, in 1975; these decreased to ∼ 150 and < 1 t/d by 2007. During the peak of the activity the C/S ratio was the lowest ever observed in the Cascade Range and similar to magmatic signatures observed at other basaltic–andesite volcanoes worldwide. Increases in the C/S ratio and decreases in the CO2/CH4 ratio since 1975 suggest a long steady trend back toward a more hydrothermal gas signature. The helium isotope ratio is very high (> 7 Rc/RA), but has declined slightly since the mid-1970s, and δ13C–CO2 has decreased by ≥ 1‰ over time. Both trends are expected from a gradually crystallizing magma. While other scenarios are investigated, we conclude that magma intruded the mid- to shallow-crust beneath Mount Baker during the thermal awakening of 1975. Since that time, evidence for fresh magma has waned, but the continued emission of CO2 and the presence of a long-term hydrothermal system leads us to suspect some continuing connection between the surface and deep convecting magma.

Washington↗
USGS2008

The 2005 catastrophic acid crater lake drainage, lahar, and acidic aerosol formation at Mount Chiginagak volcano, Alaska, USA: Field observations and preliminary water and vegetation chemistry results

A mass of snow and ice 400-m-wide and 105-m-thick began melting in the summit crater of Mount Chiginagak volcano sometime between November 2004 and early May 2005, presumably owing to increased heat flux from the hydrothermal system, or possibly from magma intrusion and degassing. In early May 2005, an estimated 3.8??10 6 m 3 of sulfurous, clay-rich debris and acidic water, with an accompanying acidic aerosol component, exited the crater through a tunnel at the base of a glacier that breaches the south crater rim. Over 27 km downstream, the acidic waters of the flood inundated an important salmon spawning drainage, acidifying Mother Goose Lake from surface to depth (approximately 0.5 km 3 in volume at a pH of 2.9 to 3.1), killing all aquatic life, and preventing the annual salmon run. Over 2 months later, crater lake water sampled 8 km downstream of the outlet after considerable dilution from glacial meltwater was a weak sulfuric acid solution (pH = 3.2, SO 4 = 504 mg/L, Cl = 53.6 mg/L, and F = 7.92 mg/L). The acid flood waters caused severe vegetation damage, including plant death and leaf kill along the flood path. The crater lake drainage was accompanied by an ambioructic flow of acidic aerosols that followed the flood path, contributing to defoliation and necrotic leaf damage to vegetation in a 29 km 2 area along and above affected streams, in areas to heights of over 150 m above stream level. Moss species killed in the event contained high levels of sulfur, indicating extremely elevated atmospheric sulfurcontent. The most abundant airborne phytotoxic constituent was likely sulfuric acid aerosols that were generated during the catastrophic partial crater lake drainage event. Two mechanisms of acidic aerosol formation are proposed: (1) generation of aerosol mist through turbulent flow of acidic water and (2) catastrophic gas exsolution. This previously undocumented phenomenon of simultaneous vegetationdamaging acidic aerosols accompanying drainage of an acidic crater lake has important implications for the study of hazards associated with active volcanic crater lakes. Copyright 2008 by the American Geophysical Union.

Geochemistry, Geophysics, Geosystems↗
USGS2008

Volatile emissions and gas geochemistry of Hot Spring Basin, Yellowstone National Park, USA

We characterize and quantify volatile emissions at Hot Spring Basin (HSB), a large acid-sulfate region that lies just outside the northeastern edge of the 640 ka Yellowstone Caldera. Relative to other thermal areas in Yellowstone, HSB gases are rich in He and H2, and mildly enriched in CH4 and H2S. Gas compositions are consistent with boiling directly off a deep geothermal liquid at depth as it migrates toward the surface. This fluid, and the gases evolved from it, carries geochemical signatures of magmatic volatiles and water-rock reactions with multiple crustal sources, including limestones or quartz-rich sediments with low K/U (or 40*Ar/4*He). Variations in gas chemistry across the region reflect reservoir heterogeneity and variable degrees of boiling. Gas-geothermometer temperatures approach 300 C and suggest that the reservoir feeding HSB is one of the hottest at Yellowstone. Diffuse CO2 flux in the western basin of HSB, as measured by accumulation-chamber methods, is similar in magnitude to other acid-sulfate areas of Yellowstone and is well correlated to shallow soil temperatures. The extrapolation of diffuse CO2 fluxes across all the thermal/altered area suggests that 410 ?? 140??t d- 1 CO2 are emitted at HSB (vent emissions not included). Diffuse fluxes of H2S were measured in Yellowstone for the first time and likely exceed 2.4 t d- 1 at HSB. Comparing estimates of the total estimated diffuse H2S emission to the amount of sulfur as SO42- in streams indicates ~ 50% of the original H2S in the gas emission is lost into shallow groundwater, precipitated as native sulfur, or vented through fumaroles. We estimate the heat output of HSB as ~ 140-370 MW using CO2 as a tracer for steam condensate, but not including the contribution from fumaroles and hydrothermal vents. Overall, the diffuse heat and volatile fluxes of HSB are as great as some active volcanoes, but they are a small fraction (1-3% for CO2, 2-8% for heat) of that estimated for the entire Yellowstone system.

Journal of Volcanology and Geothermal Research↗
USGS2008

A landslide in Tertiary marine shale with superheated fumaroles, Coast Ranges, California

In August 2004, a National Forest fire crew extinguished a 1.2 ha fire in a wilderness area ~40 km northeast of Santa Barbara, California. Examination revealed that the fire originated on a landslide dotted with superheated fumaroles. A 4 m borehole punched near the hottest (262 °C) fumarole had a maximum temperature of 307 °C. Temperatures in this borehole have been decreasing by ~0.1 °C/d, although the cooling rate is higher when the slide is dry. Gas from the fumaroles and boreholes is mostly air with 3–8 vol% carbon dioxide and trace amounts of carbon monoxide, methane, ethane, and propane. The carbon dioxide is 14 C-dead. The ratios of methane to ethane plus propane [C 1 /(C 2 + C 3 )] range from 3.6 to 14. Carbon isotope values for the CO 2 range from −14‰ to −23‰ δ 13 C. 3 He/ 4 He values range from 0.96 to 0.97 times that of air. The anomalous heat is interpreted to be due to rapid oxidation of iron sulfide augmented by combustion of carbonaceous matter within the formation.

Geology↗
USGS2008

Evolution of CO2 in Lakes Monoun and Nyos, Cameroon, before and during controlled degassing

Evolution of CO 2 in Lakes Monoun and Nyos (Cameroon) before and during controlled degassing is described using results of regular monitoring obtained during the last 21 years. The CO 2(aq) profiles soon after the limnic eruptions were estimated for Lakes Monoun and Nyos using the CTD data obtained in October and November 1986, respectively. Based on the CO 2(aq) profiles through time, the CO 2 content and its change over time were calculated for both lakes. The CO 2 accumulation rate calculated from the pre-degassing data, was constant after the limnic eruption at Lake Nyos (1986-2001), whereas the rate appeared initially high (1986-1996) but later slowed down (1996-2003) at Lake Monoun. The CO 2 concentration at 58 m depth in Lake Monoun in January 2003 was very close to saturation due to the CO 2 accumulation. This situation is suggestive of a mechanism for the limnic eruption , because it may take place spontaneously without receiving an external trigger. The CO 2 content of the lakes decreased significantly after controlled degassing started in March 2001 at Lake Nyos and in February 2003 at Lake Monoun. The current content is lower than the content estimated soon after the limnic eruption at both lakes. At Monoun the degassing rate increased greatly after February 2006 due to an increase of the number of degassing pipes and deepening of the pipe intake depth. The current CO 2 content is ∼40% of the maximum content attained just before the degassing started. At current degassing rates the lower chemocline will subside to the degassing pipe intake depth of 93 m in about one year. After this depth is reached, the gas removal rate will progressively decline because water of lower CO 2(aq) concentration will be tapped by the pipes. To keep the CO 2 content of Lake Monoun as small as possible, it is recommended to set up a new, simple device that sends deep water to the surface since natural recharge of CO 2 will continue. Controlled degassing at Lake Nyos since 2001 has also reduced the CO 2 content. It is currently slightly below the level estimated after the limnic eruption in 1986. However, the current CO 2 content still amounts to 80% of the maximum level of 14.8 giga moles observed in January 2001. The depth of the lower chemocline may reach the pipe intake depth of 203 m within a few years. After this situation is reached the degassing rate with the current system will progressively decline, and it would take decades to remove the majority of dissolved gases even if the degassing system keeps working continuously. Additional degassing pipes must be installed to speed up gas removal from Lake Nyos in order to make the area safer for local populations.

Lake Monoun, Lake Nyos↗
USGS2008

Pre- and post-eruptive investigations of gas and water samples from Mount St. Helens, Washington, 2002 to 2005

Samples of gas and water from thermal springs in Loowit and Step canyons and creeks that drain the crater at Mount St. Helens have been collected since October 2004 to monitor the flux of dissolved magmatic volatiles in the hydrologic system. The changing composition of the waters highlights a trend that began as early as 1994 and includes decreasing SO 4 and Cl concentrations and large increases in HCO 3 . Geochemical models indicate that mineral sources and sinks are not the main controls on the changing water chemistry, and carbon and helium isotopes indicate that their sources in the gases and waters have remained unchanged during this time. The present-day molar ratios of C, S, and Cl in the springs approximate ratios measured in plume emissions in August 2005 and provide supporting evidence that changes in water chemistry most likely reflect changes in the release rates of sulfur gases, HCl, and CO 2 from the magma and a varying degree of efficiency of gas scrubbing by the overlying water. Results from coupled chemical analyses and discharge measurements on the creeks yield an estimate of the dissolved flux of magmatic HCl, SO 2 , and CO 2 of around 5.2, 4.7, and 22 metric tons per day, respectively.

Washington↗
USGS2008

Isotopic constraints on the chemical evolution of geothermal fluids, Long Valley, CA

A spatial survey of the chemical and isotopic composition of fluids from the Long Valley hydrothermal system was conducted. Starting at the presumed hydrothermal upwelling zone in the west moat of the caldera, samples were collected from the Casa Diablo geothermal field and a series of monitoring wells defining a nearly linear, ~14 km long, west-to-east trend along the proposed fluid flow path (Sorey et al., 1991). Samples were analyzed for the isotopes of water, Sr, Ca, and noble gases, the concentrations of major cations and anions and total CO 2 . Our data confirm earlier models in which the variations in water isotopes along the flow path reflect mixing of a single hydrothermal fluid with local groundwater. Variations in Sr data are poorly constrained and reflect fluid mixing, multiple fluid-pathways or water-rock exchange along the flow path as suggested by Goff et al., (1991). Correlated variations among total CO 2 , noble gases and the concentration and isotopic composition of Ca suggest progressive fluid degassing (loss of CO 2 , noble gases) driving calcite precipitation as the fluid flows west-to-east across the caldera. This is the first evidence that Ca isotopes may trace and provide definitive evidence of calcite precipitation along fluid flow paths in geothermal systems.

California↗
USGS2007

Boiling water at Hot Creek— The dangerous and dynamic thermal springs in California’s Long Valley Caldera

The beautiful blue pools and impressive boiling fountains along Hot Creek in east-central California have provided enjoyment to generations of visitors, but they have also been the cause of injury or death to some who disregarded warnings and fences. The springs and geysers in the stream bed and along its banks change location, temperature, and flow rates frequently and unpredictably. The hot springs and geysers of Hot Creek are visible signs of dynamic geologic processes in this volcanic region, where underground heat drives thermal spring activity.

California↗
USGS2006

Comparison of circulation times of thermal waters discharging from the Idaho batholith based on geothermometer temperatures, helium concentrations, and 14C measurements

Circulation times of waters in geothermal systems are poorly known. In this study, we examine the thermal waters of the Idaho batholith to verify whether maximum system temperatures, helium concentrations, and 14C values are related to water age in these low-to-moderate temperature geothermal systems. He/N2 values of gas collected from thermal waters that circulate solely through distinct units of the Idaho batholith correlate linearly with Na-K-(4/3)Ca geothermometer temperatures, showing that both variables are excellent indicators of relative water age. Thermal waters that circulate in early Tertiary (45-50 Ma) granite of the Sawtooth batholith have 3.5 times more helium than thermal waters of the same aquifer temperature that circulate through the main Cretaceous granite (average 91 Ma). Hot spring waters circulating in hydrothermally altered parts of the batholith have very little dissolved helium and no correlation between He/N2 values and geothermometer temperatures. Thermal waters discharging from the Idaho batholith are more depleted in deuterium than modern precipitation in the area. Recharge to these geothermal systems occurred from at least 10,000 BP for the cooler systems up to about 33,000 BP for the hotter systems.

Geothermics↗