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Atlas of ground-water resources in Puerto Rico and the U.S. Virgin Islands

This atlas presents an overview of the ground-water resources of the main island of Puerto Rico; two of its larger offshore islands, Isla de Culebra and Isla de Vieques; and the three principal islands of the U.S. Virgin Islands, St. Thomas, St. John, and St. Croix. The atlas presents the most important ground-water information available for these islands, and is written for water managers and the general public. It describes, through the use of maps, graphs, and hydrogeologic sections, the most important aspects of the geohydrology, ground-water flow system, and groundwater withdrawals for the principal aquifers in these islands. Most of the information presented in the atlas is from published reports, although unpublished data from ongoing studies by the U.S. Geological Survey were used to prepare parts of the atlas. This report provides a useful compilation of information concerning major aquifers in Puerto Rico and the U.S. Virgin Islands and provides a first step in gaining a general knowledge of these aquifers. More detailed information is available from the primary sources referenced in the report. The atlas contains an introductory section and 15 sections describing the ground-water resources of 12 regions within the 7 ground-water areas of the main island of Puerto Rico, Isla de Culebra and Isla de Vieques (described in a single section of the atlas), and the U.S. Virgin Islands (St. Thomas and St. John are described in one section of the atlas and St. Croix in another), and a concluding section describing present and potential problems related to the development of ground-water resources. Information presented in each of 15 descriptive sections of the atlas include the (1) location and major geographic features of the area covered by that section, (2) population and estimated (4) hydrogeology of the area, (5) ground-water levels and movements, and (6) a description of soil permeabilities.

Water-Resources Investigations Report↗

Arsenic in ground-water under oxidizing conditions, south-west United States

Concentrations of dissolved arsenic in ground-water in alluvial basins of Arizona commonly exceed 50 μg L −1 and reach values as large as 1,300 μg L −1 . Arsenic speciation analyses show that arsenic occurs in the fully oxidized state of plus 5 (As+5), most likely in the form of HAsO4 ∼2 , under existing oxidizing and pH conditions. Arsenic in source areas presumably is oxidized to soluble As before transport into the basin or, if after transport, before burial. Probable sources of arsenic are the sulphide and arsenide deposits in the mineralized areas of the mountains surrounding the basins. Arsenic content of alluvial material ranged from 2 to 88 ppm. Occurrence and removal of arsenic in ground-water are related to the pH and the redox condition of the ground-water, the oxidation state of arsenic, and sorption or exchange. Within basins, dissolved arsenic correlates (P<0.01) with dissolved molybdenum, selenium, vanadium, and fluoride and with pH, suggesting sorption of negative ions. The sorption hypothesis is further supported by enrichment of teachable arsenic in the basin-fill sediments by about tenfold relative to the crustal abundance and by as much as a thousandfold relative to concentrations found in ground-water. Silicate hydrolysis reactions, as defined within the alluvial basins, under closed conditions cause increases in pH basinward and would promote desorption. Within the region, large concentrations of arsenic are commonly associated with the central parts of basins whose chemistries evolve under closed conditions. Arsenic does not correlate with dissolved iron (r = 0.09) but may be partly controlled by iron in the solid phase. High solid-phase arsenic contents were found in red clay beds. Large concentrations of arsenic also were found in water associated with red clay beds. Basins that contain the larger concentrations are bounded primarily by basalt and andesite, suggesting that the iron content as well as the arsenic content of the basin fill may play a role in the occurrence of arsenic in ground-water. Under oxidizing conditions in Arizona, arsenic in ground-water appears to be controlled in part by sorption or desorption of HAsO4 ∼2 on active ferric oxyhydroxide surfaces.

Arizona, California, Nevada, New Mexico↗

Ground water in the Eugene-Springfield area, southern Willamette Valley, Oregon

The cities of Eugene and Springfield and their outlying suburban and rural districts constitute an area of rapid population growth where progressively greater volumes of ground water are being required for irrigation and industrial and public supplies. The area is also one of diverse geologic and hydrologic conditions. As used in this report, the Eugene-Springfield area covers about 450 square miles and includes a part of the lower foothills of the Coast and Cascade Ranges and a strip of the main valley plain of the southern Willamette Valley. Volcanic and sedimentary rock units exposed in the foothills range in age from Eocene to Miocene. In the main valley plain the older units are overlain by Pleistocene and Holocene alluvial deposits. Marine-deposited sandstone, siltstone, shale, and mudstone of the older sedimentary units are fine grained and poorly permeable and yield water slowly to wells. The volcanic rocks, primarily of dacitic and andesitic composition, yield small quantities of water that are generally adequate only for domestic use. The alluvial deposits (sand and gravel) of the valley plain (central lowland) contain the most productive aquifers in the area and are considered to be the only ground-water reservoir for which large-scale development of ground-water supplies is feasible. Aquifers in the area are recharged principally by direct infiltration of precipitation. Most of the precipitation, which averages about 4C inches per year, occurs during late autumn and winter. Minimum recharge by infiltration of precipitation to the alluvial aquifers beneath the valley plain is estimated to be about 100,000 acre-feet. Ground water is discharged naturally from the central lowland by seepage and spring flow to small streams, by subsurface outflow to adjacent areas, and by evapotranspiration. Storage capacity of the central lowland in the Eugene-Springfield area is estimated to be about 2.1 million acre-feet in the zone 10-150 feet below land surface. The quantity of ground water available annually from this area is far greater than the 23,000 acre-feet pumped for all uses in 1968. This pumpage was about 23 percent of the perennial yield (100,000 acre-ft), and about 77,000 acre-feet of water was left available for additional withdrawal. If annual withdrawals of water were increased to 100,000 acre-feet per year, the levels in the ground-water reservoir would be lowered. Once new equilibriums are established, increased withdrawals could be accommodated without progressive losses in aquifer storage or excessive losses in flow of the larger streams. Ground water from the alluvial deposits of the valley plain is chemically suitable for irrigation and other uses, as is most of the water obtained from perched-water bodies in the sedimentary and volcanic rocks. However, the mineral content of water from the older sedimentary rocks, particularly from deeper producing zones, is greater than the mineral content of water from the alluvial deposits. Locally, some of the water from the older rocks is too saline for most uses. Increased use of ground water may result in certain problems pertaining to waste-disposal practices, local overdraft of aquifers, well interference, and well construction. Present data are adequate to evaluate some of the factors relating to foreseeable problems but allow only tentative conclusions to be drawn about other factors, which include local direction of flow, rate of ground-water movement, and areas of possible ground-water contamination. Additional information obtained through systematic study will be needed to deal with these problems.

Oregon↗

Geochemistry of Surface and Ground Water in Cement Creek from Gladstone to Georgia Gulch and in Prospect Gulch, San Juan County, Colorado

In San Juan County, Colo., the effects of historical mining continue to contribute metals to ground water and surface water. Previous research by the U.S. Geological Survey identified ground-water discharge as a significant pathway for the loading of metals to surface water in the upper Animas River watershed from both acid-mine drainage and acid-rock drainage. In support of this ground-water research effort, Prospect Gulch was selected for further study and the geochemistry of surface and ground water in the area was analyzed as part of four sampling plans: (1) ten streamflow and geochemistry measurements at five stream locations (four locations along Cement Creek plus the mouth of Prospect Gulch from July 2004 through August 2005), (2) detailed stream tracer dilution studies in Prospect Gulch and in Cement Creek from Gladstone to Georgia Gulch in early October 2004, (3) geochemistry of ground water through sampling of monitoring wells, piezometers, mine shafts, and springs, and (4) samples for noble gases and tritium/helium for recharge temperatures (recharge elevation) and ground-water age dating. This report summarizes all of the surface and ground-water data that was collected and includes: (1) all sample collection locations, (2) streamflow and geochemistry, (3) ground-water geochemistry, and (4) noble gas and tritium/helium data.

Colorado↗

Simulation of ground-water flow in the Shenandoah Valley, Virginia and West Virginia, using variable-direction anisotropy in hydraulic conductivity to represent bedrock structure

Ground-water flow was simulated using variable-direction anisotropy in hydraulic conductivity to represent the folded, fractured sedimentary rocks that underlie the Shenandoah Valley in Virginia and West Virginia. The anisotropy is a consequence of the orientations of fractures that provide preferential flow paths through the rock, such that the direction of maximum hydraulic conductivity is oriented within bedding planes, which generally strike N30 deg E; the direction of minimum hydraulic conductivity is perpendicular to the bedding. The finite-element model SUTRA was used to specify variable directions of the hydraulic-conductivity tensor in order to represent changes in the strike and dip of the bedding throughout the valley. The folded rocks in the valley are collectively referred to as the Massanutten synclinorium, which contains about a 5-km thick section of clastic and carbonate rocks. For the model, the bedrock was divided into four units: a 300-m thick top unit with 10 equally spaced layers through which most ground water is assumed to flow, and three lower units each containing 5 layers of increasing thickness that correspond to the three major rock units in the valley: clastic, carbonate and metamorphic rocks. A separate zone in the carbonate rocks that is overlain by colluvial gravel - called the western-toe carbonate unit - was also distinguished. Hydraulic-conductivity values were estimated through model calibration for each of the four rock units, using data from 354 wells and 23 streamflow-gaging stations. Conductivity tensors for metamorphic and western-toe carbonate rocks were assumed to be isotropic, while conductivity tensors for carbonate and clastic rocks were assumed to be anisotropic. The directions of the conductivity tensor for carbonate and clastic rocks were interpolated for each mesh element from a stack of 'form surfaces' that provided a three-dimensional representation of bedrock structure. Model simulations were run with (1) variable strike and dip, in which conductivity tensors were aligned with the strike and dip of the bedding, and (2) uniform strike in which conductivity tensors were assumed to be horizontally isotropic with the maximum conductivity direction parallel to the N30 deg E axis of the valley and the minimum conductivity direction perpendicular to the horizontal plane. Simulated flow penetrated deeper into the aquifer system with the uniform-strike tensor than with the variable-strike-and-dip tensor. Sensitivity analyses suggest that additional information on recharge rates would increase confidence in the estimated parameter values. Two applications of the model were conducted - the first, to determine depth of recent ground-water flow by simulating the distribution of ground-water ages, showed that most shallow ground water is less than 10 years old. Ground-water age distributions computed by variable-strike-and-dip and uniform-strike models were similar, but differed beneath Massanutten Mountain in the center of the valley. The variable-strike-and-dip model simulated flow from west to east parallel to the bedding of the carbonate rocks beneath Massanutten Mountain, while the uniform-strike model, in which flow was largely controlled by topography, simulated this same area as an east-west ground-water divide. The second application, which delineated capture zones for selected well fields in the valley, showed that capture zones delineated with both models were similar in plan view, but differed in vertical extent. Capture zones simulated by the variable-strike-and-dip model extended downdip with the bedding of carbonate rock and were relatively shallow, while those simulated by the uniform-strike model extended to the bottom of the flow system, which is unrealistic. These results suggest that simulations of ground-water flow through folded fractured rock can be constructed using SUTRA to represent variable orientations of the hydraulic-conductivity tensor and produce a

Virginia, West Virginia↗

Hydrogeology and simulation of ground-water flow at Dover Air Force Base, Delaware

Dover Air Force Base in Kent County, Delaware, has many contaminated sites that are in active remediation. To assist in this remediation, a steady-state model of ground-water flow was developed to aid in understanding the hydrology of the system, and for use as a ground-watermanagement tool. This report describes the hydrology on which the model is based, a description of the model itself, and some applications of the model.Dover Air Force Base is underlain by unconsolidated sediments of the Atlantic Coastal Plain. The primary units that were investigated include the upper Calvert Formation and the overlying Columbia Formation. The uppermost sand unit in the Calvert Formation at Dover Air Force Base is the Frederica aquifer, which is the deepest unit investigated in this report. A confining unit of clayey silt in the upper Calvert Formation separates the Frederica aquifer from the lower surficial aquifer, which is the basal Columbia Formation. North and northwest of Dover Air Force Base, the Frederica aquifer subcrops beneath the Columbia Formation and the upper Calvert Formation confining unit is absent. The Calvert Formation dips to the southeast. The Columbia Formation consists predominately of sands, silts, and gravels, although in places there are clay layers that separate the surficial aquifer into an upper and lower surficial aquifer. The areal extent of these clay layers has been mapped by use of gamma logs. Long-term hydrographs reveal substantial changes in both seasonal and annual ground-water recharge. These variations in recharge are related to temporal changes in evaporation, transpiration, and precipitation. The hydrographs show areas where extensive silts and clays are present in the surficial aquifer. In these areas, the vertical gradient between water levels in wells screened above and below the clays can be as large as several feet, and local ground-water highs typically form during normal recharge conditions. When drought conditions persist, water drains off these highs and the vertical gradients decrease. At the south end of Dover Air Force Base, hydrographs of water levels in the Frederica aquifer show that off-Base pumping can cause the water levels to decline below sea level during part of the year.A 4-layer, steady-state numerical model of ground-water flow was developed for Dover Air Force Base and the surrounding area. The upper two layers represent the upper and lower surficial aquifers, which are in the Columbia Formation. In some areas of the model, a semi-confining unit is used to represent an intermittent clay layer between the upper and lower surficial aquifer. This semi-confining unit causes the local groundwater highs in the surficial aquifer. The third model layer represents the upper part of the Calvert Formation, a confining unit. The fourth model layer represents the Frederica aquifer. The model was calibrated to hydraulic heads and to ground-water discharge in Pipe Elm Branch, both of which were measured in September 1997. For the calibrated model, the root-mean-squared errors for the hydraulic heads and the ground-water discharge in the Pipe Elm Branch were 9 percent of the range of head and 3 percent of discharge, respectively. Heads simulated by use of the model were consistent with a map showing average water levels in the region. The U.S. Geological Survey?s MODPATH program was used to simulate ground-water-flow directions for several areas on the Base. This analysis showed the effects of the local groundwater highs. In these areas, ground water can flow from the highs and then dramatically change flow direction as it enters the lower surficial aquifer. The steady-state model has several limitations. The entire ground-water system is under transient hydraulic conditions, due mainly to seasonal and yearly changes in recharge and to withdrawal from irrigation wells. Yet this steady-state model is still considered to be an effective tool for understanding the ground-water-flow system u

Water-Resources Investigations Report↗

Simulation of ground-water flow in the Albuquerque Basin, central New Mexico, 1901-95, with projections to 2020

The ground-water-flow model of the Albuquerque Basin (Kernodle, J.M., McAda, D.P., and Thorn, C.R., 1995, Simulation of ground-water flow in the Albuquerque Basin, central New Mexico, with projections to 2020: U.S. Geological Survey Water-Resources Investigations Report 94-4251, 114 p.) was updated to include new information on the hydrogeologic framework (Hawley, J.W., Haase, C.S., and Lozinsky, R.P., 1995, An underground view of the Albuquerque Basin: Proceedings of the 39th Annual New Mexico Water Conference, November 3-4, 1994, p. 37-55). An additional year of ground-water-withdrawal data was appended to the simulation of the historical period and incorporated into the base for future projections to the year 2020. The revised model projects the simulated ground-water levels associated with an aerally enlarged occurrence of the relatively high hydraulic conductivity in the upper part of the Santa Fe Group east and west of the Rio Grande in the Albuquerque area and north to Bernalillo. Although the differences between the two model versions are substantial, the revised model does not contradict any previous conclusions about the effect of City of Albuquerque ground-water withdrawals on flow in the Rio Grande or the net benefits of an effort to conserve ground water. Recent revisions to the hydrogeologic model (Hawley, J.W., Haneberg, W.C., and Whitworth, P.M., in press, Hydrogeologic investigations in the Albuquerque Basin, central New Mexico, 1992-1995: Socorro, New Mexico Bureau of Mines and Mineral Resources Open- File Report 402) of the Albuquerque Basin eventually will require that this model version also be revised and updated.

Open-File Report↗

Ground-water quality in the western part of the Cambrian-Ordovician aquifer in the Western Lake Michigan Drainages, Wisconsin and Michigan

Ground-water samples were collected during the summer of 1995 from 29 wells in the western part of the Cambrian-Ordovician aquifer in the Western Lake Michigan Drainages study unit of the National-Water Quality Assessment Program. Analyses of ground-water samples from these wells were used to provide an indication of waterquality conditions in this heavily used part of the aquifer. Ground-water samples from domestic, institutional, and public-supply wells were analyzed for major ions, nutrients, dissolved organic carbon (DOC), pesticides, volatile organic compounds (VOCs), radon-222, and tritium, as well as field measurements of temperature, pH, specific conductance, dissolved oxygen, and bicarbonate. The results of water-quality analyses indicate that the presence of the Maquoketa-Sinnipee confining unit has an important effect on the ground-water quality in the study area. Where the study area is overlain by the confining unit (that is, where it is regionally confined) sampled water was older (based on tritium analyses) and often contained relatively high concentrations of dissolved solids, up to 2,800 mg/L. Additionally, contaminants such as nitrate and pesticides were typically detected at lower concentrations and detected less frequently in samples from the regionally confined part of the study area. The dominant ions in samples from the study area were calcium, magnesium, and bicarbonate which resulted from the dissolution of carbonate minerals such as dolomite and calcite. Sulfate was also a dominant ion in water from some of the deeper wells in the regionally confined part of the study area. Radon-222 was detected in all samples and 66 percent (19 of 29) had concentrations that exceed the U.S Environmental Protection Agency (USEPA) proposed maximum concentration level of 300 pCi/L. Concentrations greater than 300 pCi/L were detected in samples from wells throughout most of the study area except the southwest. The higher concentrations were found in samples from a variety of geohydrologic conditions and do not appear to correlate to a particular formation or location. Dissolved nitrate and ammonium were the most commonly detected nutrients. Dissolved nitrate concentrations were significantly higher in ground-water samples from the regionally unconfined part of the study area. The highest concentrations were detected in samples from the agricultural southwestern part of the study area from relatively shallow wells that produced modern water. Dissolved ammonium concentrations were significantly higher in samples from the regionally confined part of the study area and probably resulted from nitrate reduction. Seven pesticides or metabolites were detected in ground-water samples, and at least one pesticide was detected in samples from 24 percent (7 of 29) of wells. Most of the pesticides were detected at low concentrations and were from wells in the regionally unconfined, agricultural, southwest part of the study area. Atrazine was the most commonly detected pesticide and was typically detected in samples from wells that produced modern water.

Wisconsin↗

Hydrogeology and Ground-Water Quality of Brunswick County, North Carolina

Brunswick County is the southernmost coastal county in North Carolina and lies in the southeastern part of the Coastal Plain physiographic province. In this report, geologic, hydrologic, and chemical data were used to investigate and delineate the hydrogeologic framework and ground-water quality of Brunswick County. The major aquifers and their associated confining units delineated in the Brunswick County study area include, from youngest to oldest, the surficial, Castle Hayne, Peedee, Black Creek, upper Cape Fear, and lower Cape Fear aquifers. All of these aquifers, with the exception of the Castle Hayne aquifer, are located throughout Brunswick County. The Castle Hayne aquifer extends across only the southeastern part of the county. Based on available data, the Castle Hayne and Peedee confining units are missing in some areas of Brunswick County, which allows direct hydraulic contact between the surficial aquifer and underlying Castle Hayne or Peedee aquifers. The confining units for the Black Creek, upper Cape Fear, and lower Cape Fear aquifers appear to be continuous throughout Brunswick County. In examining the conceptual hydrologic system for Brunswick County, a generalized water budget was developed to better understand the natural processes, including precipitation, evapotranspiration, and stream runoff, that influence ground-water recharge to the shallow aquifer system in the county. In the generalized water budget, an estimated 11 inches per year of the average annual precipitation of 55 inches per year in Brunswick County is estimated to infiltrate and recharge the shallow aquifer system. Of the 11 inches per year that recharges the shallow system, about 1 inch per year is estimated to recharge the deeper aquifer system. The surficial aquifer in Brunswick County is an important source of water for domestic supply and irrigation. The Castle Hayne aquifer is the most productive aquifer and serves as the principal ground-water source of municipal supply for the county. The upper part of the Peedee aquifer is an important source of ground-water supply for domestic and commercial use. Ground water in the lower part of the Peedee aquifer and the underlying aquifers is brackish and is not known to be used as a source of supply in Brunswick County. Most of the precipitation that recharges the surficial aquifer is discharged to local streams that drain into the Waccamaw River, Cape Fear River, and Atlantic Ocean. Recharge to the Castle Hayne aquifer occurs primarily from the surficial aquifer. Recharge to the Peedee aquifer occurs primarily from the surficial and Castle Hayne aquifers, with some upward leakage of water also occurring from the underlying Black Creek aquifer. Discharge from the Castle Hayne and Peedee aquifers occurs to local streams, the Cape Fear River, and the Atlantic Ocean. Evaluation of water-level data for the period January 1970 through May 2002 indicated no apparent long-term temporal trends in water levels in the surficial and Castle Hayne aquifers and in the upper part of the Peedee aquifer. The most significant water-level trends were noted for wells tapping the lower part of the Peedee aquifer and tapping the Black Creek aquifer where water levels have declined as much as 41 and 37 feet, respectively. These ground-water-level declines are attributed to regional ground-water pumping in areas outside of Brunswick County. Water-level data for Brunswick County wells tapping the upper Cape Fear and lower Cape Fear aquifers tend to fluctuate within a fairly uniform range with no apparent temporal trend noted. Analysis of vertical hydraulic gradients during this same period primarily indicate downward flow of ground water within and among the surficial, Castle Hayne, and Peedee aquifers. The vertical flow of ground water in the Black Creek aquifer is upward into the overlying Peedee aquifer. Upward flow also is noted for the upper and lower Cape Fear aquifers. Historic and recent analytic data were evaluated to better understand the sources of water contained in Brunswick County aquifers and the suitability of the water for consumption. Based on analytical results obtained for recent samples collected during this study, ground water from the surficial aquifer, Castle Hayne aquifer, and upper part of the Peedee aquifer appears to be generally suitable for drinking water. Although concentrations of iron and manganese commonly exceeded the drinking-water standards, the concern generally associated with the occurrence of these analytes in a water supply is one of aesthetics. In all samples, nitrate, nitrite, and sulfate were detected at concentrations less than drinkingwater standards. Based on historic analytical data, the brackish water in the lower part of the Peedee aquifer and in the Black Creek, upper Cape Fear, and lower Cape Fear aquifers is classified as a sodium-chloride type water. The presence of brackish water in these deeper systems combined with upward vertical gradients presents the potential for upward migration of brackish water into overlying aquifers, or upconing beneath areas of pumping. The current (2001) location of the boundary between freshwater and brackish water in Brunswick County aquifers is unknown.

North Carolina↗

Summary of hydrogeologic and ground-water-quality data and hydrogeologic framework at selected well sites, Adams County, Pennsylvania

Rapid population growth in Adams County has increased the demand for ground water and led Adams County planning officials to undertake an effort to evaluate the capabilities of existing community water systems to meet future, projected growth and to begin wellhead-protection programs for public-supply wells. As part of this effort, this report summarizes ground-water data on a countywide scale and provides hydrogeologic information needed to delineate wellheadprotection areas in three hydrogeologic units (Gettysburg Lowland, Blue Ridge, and Piedmont Lowland). Reported yields, specific capacities, well depths, and reported overburden thickness can vary by hydrogeologic unit, geologic formation, water use (domestic and nondomestic), and topographic setting. The reported yields of domestic wells drilled in the Gettysburg Lowland (median reported yield of 10 gallons per minute) are significantly greater than the reported yields from the Blue Ridge, Piedmont Lowland, and Piedmont Upland (median reported yields of 7.0, 8.0, and 7.0 gallons per minute, respectively). Reported yields of domestic wells completed in the diabase and the New Oxford Formation of the Gettysburg Lowland, and in the metarhyolite and metabasalt of the Blue Ridge, are significantly lower than reported yields of wells completed in the Gettysburg Formation. For nondomestic wells, reported yields from the Conestoga Formation of the Piedmont Lowland are significantly greater than in the diabase. Reported yields of nondomestic wells drilled in the Gettysburg, New Oxford, and Conestoga Formations, and the metarhyolite are significantly greater than those for domestic wells drilled in the respective geologic formations. Specific capacities of nondomestic wells in the Conestoga and Gettysburg Formations are significantly greater than their domestic counterparts. Specific capacities of nondomestic wells in the Conestoga Formation are significantly greater than the specific capacities of nondomestic wells in the metarhyolite, diabase, and Gettysburg and New Oxford Formations.Well depths do not vary considerably by hydrogeologic unit; instead, the greatest variability is by water use. Nondomestic wells drilled in the metarhyolite, Kinzers, Conestoga, Gettysburg, and New Oxford Formations are completed at significantly greater depths than their domestic counterparts. The reported thickness of overburden varies significantly by geologic formation and water use, but not by topographic setting. The median overburden thickness of the Blue Ridge (35 feet) is greater than in any other hydrologic unit. Except where adversely affected by human activities, ground water in Adams County is suitable for most purposes. Calcium and magnesium are the dominant cations, and bicarbonate is the dominant anion. In general, the pH and hardness of ground water is lower in areas that are underlain by crystalline rocks (Blue Ridge and Piedmont Upland) than in areas underlain by sedimentary rocks, especially where limestone or dolomite is dominant (Piedmont Lowland). Dissolved nitrate (as N) and dissolved nitrite (as N) concentrations in the water from 9 of 69 wells and 3 of 80 wells sampled exceeded the U.S. Environmental Protection Agency (USEPA) maximum contaminant levels (MCL) of 10 and 1.0 mg/L (milligrams per liter), respectively. Sulfate concentrations greater than the proposed USEPA MCL of 500 mg/L were reported from the water in 3 of 110 wells sampled. Iron concentrations in the water from 13 of 67 wells sampled and manganese in the water from 9 of 64 wells sampled exceeded the USEPA secondary maximum contaminant level (SMCL) of 300 and 50 mg/L (micrograms per liter), respectively. Aluminum concentrations in the water from 16 of 22 wells sampled exceeded the lower USEPA SMCL threshold of 50 µg/L. Pesticides were detected in the water from seven wells but at concentrations that did not exceed USEPA MCL's. Most volatile organic compounds detected in the ground water were confined to USEPA Superfund sites or the immediate area around the sites. The hydrogeologic framework in the vicinity of four public-supply well fields (Gettysburg, Abbottstown, Fairfield, and Littlestown) consists of two zones—an upper zone and a lower zone. In general, the upper zone is thin (5 to 60 feet or more) and dominated by saturated regolith and deeply weathered bedrock. The upper zone is bounded at the top by the water table and below by bedrock in which secondary porosity and permeability are considerably lower. Ground water is generally unconfined, and recharge rates are rapid. Ground-water flow is influenced more strongly by the topography of the ground surface and bedrock surface than by geologic structure. The lower zone is relatively thick (400 to 1,000 feet) and consists of slightly weathered to highly competent bedrock. Ground-water flow paths in the lower zone are generally greater and recharge rates are longer than in the upper zone; confined conditions are common, especially at depth.

Water-Resources Investigations Report↗

Hydrogeology and ground-water availability in the carbonate aquifer system of Frederick County, Virginia

The carbonate aquifer system of the northern Shenandoah Valley provides an important water supply to local communities, including Frederick County, Va., which depends on ground water as a source of water supply. The county and surrounding area are undergoing increased urbanization, and increased demands on the carbonate aquifer system are expected. A study was conducted between October 2000 and March 2004 by the U.S. Geological Survey (USGS), in cooperation with the County of Frederick, Va., to describe the hydrogeology and ground-water availability in the carbonate aquifer system underlying the county. The study area encompasses about 25 percent (105 square miles) of the county that is underlain by carbonate bedrock. The carbonate aquifer system of Frederick County is in the Shenandoah Valley region of the Valley and Ridge Physiographic Province. Approximately 10,000 feet of folded and fractured Middle Cambrian to Upper Ordovician sedimentary rocks are exposed and are overlain by Pleistocene (?) and Holocene surficial deposits. All geologic units in the study area are considered to be aquifers. The geologic units are generally unconfined, fractured-rock aquifers that are recharged by precipitation and discharge locally to streams and springs, and by evapotranspiration. Stream density in the carbonate study area is less than in the remainder of the county, which is underlain by siliciclastic rock units. Most streams flow normal to strike (from the northwest towards the southeast) across the study area. These streams are characterized by shallow incisement and are usually limited to a single stream channel. In the southern third of the study area, streams flow parallel to strike (from the northeast towards the southwest) towards the deeply intrenched Cedar Creek. Springs are commonly located at the start of flows for all streams in the carbonate study area, and spring discharges are often a large portion of the streamflow (especially during drought conditions). The general direction of ground-water flow is from the hills in the west of the study area into and across the carbonate valley. A ground-water divide may occur north of Round Hill in the vicinity of the Apple Pie Ridge fault where the North Mountain fault zone cuts out the resistant Silurian and Devonian sandstone units and results in surface drainage from the carbonate rocks toward the west and out of the carbonate valley. Estimates of effective ground-water recharge for 2001-02 range from 5.8 to 6.2 inches in the Cedar Creek Basin, with base flow accounting for between 60 and 64 percent of streamflow, and from 3.2 to 3.8 inches in the Opequon Creek Basin, with base flow accounting for between 86 and 92 percent of streamflow. Water budgets calculated for 2001, a year of below-normal precipitation (33.1 inches), and 2002, a year of above-normal precipitation (41.2 inches), include a streamflow of 9.0 inches in 2001 and 9.2 inches in 2002 in Cedar Creek. Evapotranspiration ranged from 25.9 to 30.7 inches, and ground-water storage decreased 1.8 inches in 2001 and increased 1.3 inches in 2002. Streamflow was 3.7 inches in 2001 and 2002 in Opequon Creek. Evapotranspiration ranged from 29.8 to 37.5 inches, and ground-water storage decreased 0.4 inch in 2001 and did not change in 2002.

Scientific Investigations Report↗

Geohydrology of the French Creek Basin and simulated effects of drought and ground-water withdrawals, Chester County, Pennsylvania

This report describes the results of a study by the U.S. Geological Survey, in cooperation with the Delaware River Basin Commission, to develop a regional ground-water-flow model of the French Creek Basin in Chester County, Pa. The model was used to assist water-resource managers by illustrating the interconnection between ground-water and surface-water systems. The 70.7-square mile French Creek Basin is in the Piedmont Physiographic Province and is underlain by crystalline and sedimentary fractured-rock aquifers. Annual water budgets were calculated for 1969-2001 for the French Creek Basin upstream of streamflow-measurement station French Creek near Phoenixville (01472157). Average annual precipitation was 46.28 in. (inches), average annual streamflow was 20.29 in., average annual base flow determined by hydrograph separation was 12.42 in., and estimated average annual ET (evapotranspiration) was 26.10 in. Estimated average annual recharge was 14.32 in. and is equal to 31 percent of the average annual precipitation. Base flow made up an average of 61 percent of streamflow. Ground-water flow in the French Creek Basin was simulated using the finite-difference MODFLOW-96 computer program. The model structure is based on a simplified two-dimensional conceptualization of the ground-water-flow system. The modeled area was extended outside the French Creek Basin to natural hydrologic boundaries; the modeled area includes 40 square miles of adjacent areas outside the basin. The hydraulic conductivity for each geologic unit was calculated from reported specific-capacity data determined from aquifer tests and was adjusted during model calibration. The model was calibrated for above-average conditions by simulating base-flow and water-level measurements made on May 1, 2001, using a recharge rate of 20 in/yr (inches per year). The model was calibrated for below-average conditions by simulating base-flow and water-level measurements made on September 11 and 17, 2001, using a recharge rate of 6.2 in/yr. Average conditions were simulated by adjusting the recharge rate until simulated streamflow at streamflow-measurement station 01472157 matched the long-term (1968-2001) average base flow of 54.1 cubic feet per second. The recharge rate used for average conditions was 15.7 in/yr. The effect of drought in the French Creek Basin was simulated using a drought year recharge rate of 8 in/yr for 3 months. After 3 months of drought, the simulated streamflow of French Creek at streamflow-measurement station 01472157 decreased 34 percent. The simulations show that after 6 months of average recharge (15.7 in/yr) following drought, streamflow and water levels recovered almost to pre-drought conditions. The effect of increased ground-water withdrawals on stream base flow in the South Branch French Creek Subbasin was simulated under average and drought conditions with pumping rates equal to 50, 75, and 100 percent of the Delaware River Basin Commission Ground Water Protected Area (GWPA) withdrawal limit (1,393 million gallons per year) with all pumped water removed from the basin. For average recharge conditions, the simulated streamflow of South Branch French Creek at the mouth decreased 18, 28, and 37 percent at a withdrawal rate equal to 50, 75, and 100 percent of the GWPA limit, respectively. After 3 months of drought recharge conditions, the simulated streamflow of South Branch French Creek at the mouth decreased 27, 40, and 52 percent at a withdrawal rate equal to 50, 75, and 100 percent of the GWPA limit, respectively. The effect of well location on base flow, water levels, and the sources of water to the well was simulated by locating a hypothetical well pumping 200 gallons per minute in different places in the Beaver Run Subbasin with all pumped water removed from the basin. The smallest reduction in the base flow of Beaver Run was from a well on the drainage divide between the French Creek Basin and the Marsh Creek Basin to the south; the simulated base flow of Beaver Run at the mouth was reduced 1 percent. The greatest reduction in the base flow of Beaver Creek was from a well close to Beaver Run; the simulated base flow of Beaver Run at the mouth was reduced 8 percent. The simulations showed that (1) if the contributing area of a well is in a basin, pumping will affect stream base flow and water levels in that basin whether the well is inside or outside that basin; (2) wells in different areas of a basin away from a divide produce a similar reduction in base flow; (3) a well within a basin will derive more water from diverted base flow and less water from storage than a well on or near a basin divide; and (4) the reduction in base flow at the mouth of the stream is the same for a well in the headwaters and a well downstream near the confluence. Model simulations illustrate some of the typical analyses and results that can be produced. The model was calibrated using annual values for recharge and ground-water ET and then was run using the annual values in a seasonally independent transient mode to show changes with time. The timing and relative magnitude of some of the changes simulated with the model when viewed in terms of a normal climatic year may be subject to considerable uncertainty because of the variability in seasonal recharge and ground-water ET rates. Transient model simulations for short-term periods are indicative of possible hydrologic system response and are considered an approximation.

Pennsyvlania↗

Evaluation of ground-water resources From available data, 1992, East Molokai Volcano, Hawaii

Available ground-water data for East Molokai Volcano consist of well-construction information and records of ground-water pumpage, water levels, and chloride concentrations. Ground-water pumpage records are available for ten wells. Seventeen long-term (10 years or more) records of water-level and/or chloride concentration are available for eleven wells; however, only seven of these records are for observation wells. None of the available data show significant long-term changes in water level or chloride concentration; however, short-term changes due to variations in the quantity of water pumped, and rainfall are evident. Evaluation of the historical distribution and rates of ground-water pumpage, and variations in water levels and chloride concentrations is constrained by the scanty distribution of spatial and temporal data. Data show a range in water levels from greater than 850 feet above mean sea level in wells located in the windward valley of Waikolu to about 10 feet in wells located east of Kualapuu to 1 to 5 feet in the wells located along the south shore of East Molokai Volcano. An accurate contour map of water levels and chloride concentrations at the surface of the basal-water body cannot be constructed for any time period. Because water-level and chloride data are not collected at regular time intervals, many long-term records are incomplete. Information on the variation in chloride concentration with depth through the freshwater part of the basal-water body and into the zone of transition between freshwater and saltwater does not exist.

Hawaii↗

Occurrence, quality, and use of ground water in Orcas, San Juan, Lopez, and Shaw Islands, San Juan County, Washington

Ground water, which supplies most of San Juan County 's water needs, occurs in both bedrock and glacial drift. Water in the bedrock occurs in fractures in the otherwise dense, poorly permeable rock. Deposits of sand and gravel in the glacial drift provide the best yields to wells drilled into unconsolidated materials. Specific capacities of bedrock wells are typically low, and those of glacial-drift wells considerably higher. Ground water is high in dissolved solids and hardness; 29 of 56 wells sampled had water classified as very hard. Sixteen percent of the 171 ground-water sites tested for indicator bacteria had positive counts of one or more of these bacteria: total coliform , fecal coliform, fecal streptococcus. Nine percent of the 279 wells sampled for chloride in September 1981, appear to be affected by seawater intrusion. All of these wells are located within a mile of the coast; 60 percent of these wells are on Lopez Island. In 1980 an estimated total of 220 million gallons of ground water was withdrawn for all uses. Ninety percent of all ground-water use is for domestic and public supply purposes. Heavy pumpage on northern and southern Lopez Island correlates with areas having high chloride concentrations. (USGS)

Water-Resources Investigations Report↗

Ground-water resources of the Lambayeque Valley, Department of Lambayeque, northern Peru

Ground water in the Lambayeque Valley has been developed mainly for irrigation of sugarcane and rice. The locality is on the coastal plain of northern Peru, about 650 km (kilometers) northwest of Lima, the national capital. The area considered in this study is about 1,670 sq km (square kilometers) and is mainly on the alluvial fan of Rio Chancay and entirely in the Department of Lambayeque. Chiclayo, the departmental capital and largest city, has a population, of about 46,000. The climate is hot and virtually rainless. Agriculture is dependent on irrigation. The available water, whether in stream s or underground, is introduced from the Andean highlands by Rio Chancay. Rocks in the area range in age from Cretaceous, or possibly Jurassic, to Quaternary and in lithology from dense and hard igneous, sedimentary, and metamorphic rocks to unconsolidated sediments. The bedrock contains and yields water only in small quantities, if at all. The principal water-bearing strata are in the alluvium comprising the fan of Rio Chancay. Where ground water in the alluvium has been most intensively developed, the productive zone is within 20 m (meters) of the land surface and is composed approximately as follows: (1) relatively impermeable soil, clay, and clayey sand, 5 to 10 m thick, (2) permeable sand and gravel, 6 to 10 m thick, at places including one or more layers of clay, so that several water-bearing beds are distinguishable, and (3) relatively impermeable mixtures of clay, sand, and gravel extending below the bottom of wells. Unit 3 in the deepest test continued to 102 m. Unit 2 is the principal source of water tapped by irrigation wells. In the northern part of the area wells locally yield water rather freely from strata as deep as 73 m, but elsewhere in the area the strata deeper than 20 m are not very productive. Wells at and near Chiclayo yield only small amounts, and the deepest well disclosed, in 100 m of material, only 5.5 m of material that can be considered as possibly water bearing. Water in the alluvium of the eastern part of the area occurs under water-table conditions at depths from 1 to 8 m below the land surface. The water table declines during pumping for irrigation and rises when pumping is stopped. Recharge comes mainly from infiltration on irrigated fields and from irrigation ditches and probably varies greatly from year to year at any given place. The ground-water reservoir is replenished when pumps are idle; therefore, it is concluded that the recharge is sufficient to offset withdrawal at a rate comparable to that of 1957, which was about 81 million cum (cubic meters). A study of the effect of protracted pumping on yields of wells suggests that the rate of recharge locally, and for a short period, was more than 76,000 cu m per day. This recharge presumably declined rapidly to zero when irrigation was suspended in the locality. A pumping test showed the transmissivity to be about 950 cu m per day per m and the storage coefficient to be about 0.07. Based on these coefficients, the drawdown caused by one well discharging 10 lps (liters per second) for 6 months would be only 0.066 m at points 4,000 m distant, but 50 wells at the same rate and distance would create 3.3 m of drawdown. As actual distances between wells range from 100 to 300 m where the wells are most numerous and as the average discharge rate is nearer to 20 than to 10 lps, the cumulative effect of the actual pumping is certain to be considerable. If it were not for the recharge resulting from infiltration of irrigation water, the pumping of so many wells probably could not be long sustained. The waters from wells of the Lambayeque Valley compare favorably, in most respects, with the standards established by the U.S. Public Health Service for water for human consumption. Chemical analyses of 10 samples of ground water show that the dissolved solids, silica, bicarbonate, sulfate, and sodium increase in the downstream direction, where

Water Supply Paper↗

Ground-water flow paths and traveltime to three small embayments within the Peconic Estuary, eastern Suffolk County, New York

The Peconic Estuary, at the eastern end of Long Island, has been plagued by a recurrent algal bloom that has caused the severe decline of local marine resources. Although the onset, duration, and cessation of the bloom remain unpredictable, ground-water discharge has been shown to affect surface-water quality in the western part of the estuary. Results from a study on the North Fork of Long Island indicate that local hydrogeologic factors cause differences in ground-water age and characteristics of discharge to the estuary. The need for information on the local patterns and rates of ground-water discharge to the Peconic Estuary prompted analysis of ground-water flow paths and traveltime to three small embayments within the estuary. Meetinghouse Creek, near the west end of the North Fork; Sag Harbor Cove, in the central part of the South Fork; and West Neck Bay, on Shelter Island. Ground-water-flow models were developed, and particle-tracking procedures were applied to the results of each model, to define the flow paths and traveltime of ground water to the three embayments. The steady-state flow models represent the two-dimensional ground-water-flow system along a vertical section through the uplands of each embayment and simulate long-term hydrologic conditions. The particle-tracking procedure used model-generated ground-water levels and flow rates to calculate the water-particle pathlines and times-of-travel through each flow system from the point of entry (recharge) to the point of exit at streams, the shore, or subsea-discharge areas. Results for the Meetinghouse Creek study area indicate that about 50 percent of the total recharge that enters the system flows southward to Meetinghouse Creek; half of this amount discharges as base flow to the fresh-water reach of the creek, and half as shoreline underflow to the estuarine reach. About 85 percent of the total discharge to Meetinghouse Creek has flowed entirely within the upper glacial aquifer, and about 15 percent has flowed through the Magothy aquifer. The average age of all ground water discharged to Meetinghouse Creek is about 60 years; the average age of base flow to the freshwater reach of the creek is about 7 years, and the average age of shoreline underflow to the estuarine reach is about 120 years. The results for the Sag Harbor Cove study area indicate that about 30 percent of the total recharge that enters the system flows northward to Sag Harbor Cove; about half of this amount discharges as shoreline underflow, and half as subsea underflow. About 40 percent of the total discharge to Sag Harbor Cove has flowed entirely within the upper glacial aquifer, and about 60 percent has flowed through the Pleistocene marine clay unit, Pleistocene(?) sand unit, or Magothy aquifer. The average age of all ground water discharged to Sag Harbor Cove is about 110 years; the average age of shoreline underflow is about 25 years, and the average age of subsea underflow is about 190 years. Results for the West Neck Bay study area indicate that about 65 percent of the total recharge that enters the system flows westward to West Neck Bay; virtually all of this amount discharges as shoreline underflow, but a negligible percentage discharges as subsea underflow. Virtually all discharge to West Neck Bay has flowed entirely within the upper glacial aquifer, although a minor amount has flowed through the Pleistocene marine clay unit. The average age of shoreline underflow to West Neck Bay is about 15 years, and the average age of subsea underflow is about 1,800 years. Ground water that discharges to streams and the shores represented in the models is mostly relatively young water that has flowed entirely within the shallow zones of the flow systems, whereas ground water that discharges to the subsea-discharge areas is mostly old water that has flowed through the deep zones. Data obtained from these models allows evaluation of each embayment.s vulnerability to contaminants introduced at the water table and can guide the development of source-area-protection strategies for the corresponding watersheds.

New York↗

Hydrogeology, simulation of regional ground-water flow, and saltwater intrusion, Potomac-Raritan-Magothy Aquifer System, Northern Coastal Plain of New Jersey

The Potomac-Raritan-Magothy aquifer system in Middlesex and Monmouth Counties in the northern Coastal Plain of New Jersey consists primarily of unconsolidated Cretaceous sediments, which are divided into the upper and middle aquifers and confining units. These units, which strike northeastsouthwest along the Fall Line, dip and thicken to the southeast. The upper aquifer consists primarily of the Old Bridge Sand Member of the Magothy Formation, which is composed of coarse-grained sands, localized thin clay beds, and younger surficial sands and gravels in and near the outcrop. Transmissivity ranges from 1,760 to 19,400 ft 2 /d (feet squared per day) and tends to be higher in updip areas. Estimated withdrawals from the upper aquifer in the northern Coastal Plain were approximately 42 Mgal/d (million gallons per day) in 1986. Cones of depression whose centers range from 36 to 42 ft (feet) below sea level have developed as a result of these withdrawals. The upper aquifer is confined throughout most of the northern New Jersey Coastal Plain by clays and silts of the Cretaceous Woodbury Clay and Merchantville Formation and younger sediments of the Magothy Formation. This confining unit generally is greater than 200 ft thick. The simulated vertical hydraulic conductivity for the confining unit ranges from 8.4 x 10 -5 to 5.6 x 10 -3 feet per day; interpreted vertical hydraulic conductivities generally are lower except in southwestern Middlesex County, where the vertical hydraulic conductivities of the confining unit are higher. The middle aquifer consists primarily of the Farrington Sand Member of the Cretaceous Raritan Formation and surficial Holocene and Miocene sands and gravels in its outcrop area. It also can include the uppermost sands of the Cretaceous Potomac Group in parts of Monmouth County. The middle aquifer is composed of fine to coarse sand that contains some lignite and pyrite, and, locally, some clay beds. It pinches out in the northern part of Sayreville Township, near Raritan River. The transmissivity of the aquifer ranges from 2,140 to 13,800 ft 2/ d and tends to decrease in the northern part of the northern Coastal Plain of New Jersey where the aquifer thins. A poorly permeable confining unit composed mostly of clays and silts of the Woodbridge Clay Member of the Raritan Formation overlies the aquifer in most of this area. The confining unit generally is greater than 100 ft thick, although it thins and is sandy in the southwestern part of Middlesex County, where a good hydraulic connection exists between the middle and upper aquifers. Estimated withdrawals from the middle aquifer in the northern Coastal Plain were about 22 Mgal/d in 1986. These withdrawals have caused cones of depression whose centers range from 77 to 93 ft below sea level. A finite-difference, quasi-three-dimensional ground-water flow model was developed to simulate ground-water flow in the aquifer system. The confined and unconfined areas of the upper and middle aquifers were modeled as separate layers. The model was calibrated primarily by adjusting vertical hydraulic conductivity in the confining units and horizontal hydraulic conductivity in the aquifers, then matching simulated and measured groundwater levels for the period 1896-1986 and simulated and interpreted potentiometric surfaces under predevelopment conditions and in 1984. For the predevelopment period, the total flow into and out of the upper and middle aquifers is 35 and 21 Mgal/d, respectively. Recharge to the aquifer system is from direct recharge in the unconfined areas and from vertical leakage through overlying confining units. The main recharge areas are the topographically high areas in southwestern Middlesex County for both aquifers, in the eastern Sayreville area for the upper aquifer, and north of the Raritan River for the middle aquifer. Most ground water discharges to low-lying regional surface-water drains (streams), which flow into the South River. For 1984 transient conditions, the total ground-water flow into and out of the upper and middle aquifers is 61 and 34 Mgal/d, respectively. The largest amount of recharge is from direct recharge in the unconfined areas, but some recharge also is derived from vertical leakage through the Merchantville-Woodbury confining unit, captured ground-water discharge to streams, and induced inflow at artificial-recharge facilities. Regional flow is from recharge areas toward major cones of depression. Sensitivity analysis showed that the model was useful for representing flow in the system, especially in the confined-aquifer areas. Model representation of lateral and vertical boundary conditions was judged acceptable. Simulation results were less sensitive to changes in aquifer properties in the unconfined areas of the aquifers and to changes in storage in the confining units. Sensitivity analysis and calibration of hydraulic parameters and conditions showed that the distribution of hydraulic head was sensitive to changes in horizontal hydraulic conductivity in the aquifers, vertical hydraulic conductivity in the confining units, magnitudes of ground-water withdrawals, and initial hydraulic head in aquifer outcrop areas. Two scenarios were simulated to determine the effects of ground-water withdrawals from 1986 through 2019. For the scenario in which ground-water withdrawals increase to about 69 Mgal/d in the upper aquifer and 37 Mgal/d in the middle aquifer, centers of cones of depression are as deep as 100 ft below sea level in the upper aquifer and 170 ft below sea level in the middle aquifer. For this scenario, most of the additional water comes from captured surface-water discharge, induced cross-formational flow from overlying aquifers, and increases in induced flow from artificial-recharge areas. Induced flow from Raritan Bay also increases. For the scenario in which ground water withdrawals are reduced to 42.5 Mgal/d in the upper aquifer and 15 Mgal/d in the middle aquifer, water levels recover to above sea level nearly everywhere. In each aquifer, ground-water discharge to streams increases and induced flow through the confining units and from the overlying sediments decreases, and discharge of ground water to Raritan Bay in the upper aquifer exceeds the induced recharge from Raritan Bay. Reversal of ground-water gradients has caused saltwater intrusion in the two aquifers. Chloride concentrations in water from the upper aquifer in Keyport and Union Beach Boroughs were as high as 2,100 mg/L (milligrams per liter) in 1986. The intrusion has not increased significantly since well fields in the area were closed in the late 1970's. Elevated chloride concentrations also were measured in Keanesburg Borough in 1986. In both of these areas, saltwater has entered the upper aquifer from the Bay because of movement of the freshwater-saltwater interface in response to increasing ground-water withdrawals. Chloride concentrations in well-water samples from the middle aquifer were as high as 6,000 mg/L in Sayreville Borough in 1987; concentrations in samples from drive-point wells from the same aquifer near the Washington Canal, the main source of saltwater, were as high as 7,100 mg/L. The migration of the saltwater front at about 470 feet per year to the southeast is influenced mainly by a thinning of the middle aquifer, which constrains flow, and by the locations of regional cones of depression caused by groundwater withdrawals.

New Jersey↗

Geologic Setting, Geohydrology, and Ground-Water Quality near the Helendale Fault in the Mojave River Basin, San Bernardino County, California

The proximity of the Mojave River ground-water basin to the highly urbanized Los Angeles region has resulted in rapid population growth and, consequently, an increase in the demand for water. The Mojave River, the primary source of surface water for the region, normally is dry--except for periods of flow after intense storms; therefore, the region relies almost entirely on ground water to meet its agricultural and municipal needs. The area where the Helendale Fault intersects the Mojave River is of particular hydrogeologic interest because of its importance as a boundary between two water-management subareas of the Mojave Water Agency. The fault is the boundary between the upper Mojave River Basin (Oeste, Alto, and Este subareas) and the lower Mojave River Basin (Centro and Baja subareas); specifically, the fault is the boundary between the Alto and the Centro subareas. To obtain the information necessary to help better understand the hydrogeology of the area near the fault, multiple-well monitoring sites were installed, the surface geology was mapped in detail, and water-level and water-quality data were collected from wells in the study area. Detailed surficial geologic maps and water-level measurements indicate that the Helendale Fault impedes the flow of ground water in the deeper regional aquifer, but not in the overlying floodplain aquifer. Other faults mapped in the area impede the flow of ground water in both aquifers. Evidence of flowing water in the Mojave River upgradient of the Helendale Fault exists in the historical record, suggesting an upward gradient of ground-water flow. However, water-level data from this study indicate that pumping upstream of the Helendale Fault has reversed the vertical gradient of ground-water flow since predevelopment conditions, and the potential now exists for water to flow downward from the floodplain aquifer to the regional aquifer. Sixty-seven ground-water samples were analyzed for major ions, nutrients, and stable isotopes of oxygen and hydrogen from 34 wells within the study area between May 1990 and November 1999. Dissolved-solids concentrations in water samples from 14 wells in the floodplain aquifer ranged from 339 to 2,330 milligrams per liter (mg/L) with a median concentration of 825 mg/L. Concentrations in water from 11 of these wells exceeded the U.S. Environmental Protection Agency (USEPA) Secondary Maximum Contaminant Level (SMCL) of 500 mg/L. Dissolved-solids concentrations of water from nine wells sampled in the regional aquifer ranged from 479 to 946 mg/L with a median concentration of 666 mg/L. Concentrations in at least one sample of water from each of the wells in the regional aquifer exceeded the USEPA SMCL for dissolved solids. Arsenic concentrations in water from 14 wells in the floodplain aquifer ranged from less than the detection limit of 2 micrograms per liter (?g/L) to a maximum of 34 ?g/L with a median concentration of 6 ?g/L. Concentrations in water from six of the 14 wells exceeded the USEPA Maximum Contaminant Level (MCL) for arsenic of 10 ?g/L. Arsenic concentrations in water from nine wells in the regional aquifer ranged from less than the detection limit of 2 to 130 ?g/L with a median concentration of 11 ?g/L. Concentrations in water from five of these nine wells exceeded the USEPA MCL for arsenic. Dissolved-solids concentrations in water from seven wells completed in the igneous and metamorphic basement rocks that underlie the floodplain and regional aquifers ranged from 400 to 3,190 mg/L with a median concentration of 1,410 mg/L. Concentrations in water from all but one of the seven wells sampled exceeded the USEPA SMCL for dissolved solids. Concentrations in water from the basement rocks exceeded the USEPA SMCL for arsenic of 10 ?g/L in five of the seven wells. The high concentrations of arsenic, dissolved solids, and other constituents probably occur naturally. Stable isotopes of oxygen and hydrogen indicate that before pumping began in

Water-Resources Investigations Report↗