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At least 127 records · Page 7Linked to original sources

Groundwater level trends and drivers in two northern New England glacial aquifers

We evaluated long-term trends and predictors of groundwater levels by month from two well-studied northern New England forested headwater glacial aquifers: Sleepers River, Vermont, 44 wells, 1992-2013; and Hubbard Brook, New Hampshire, 15 wells, 1979-2004. Based on Kendall Tau tests with Sen slope determination, a surprising number of well-month combinations had negative trends (decreasing water levels) over the respective periods. Sleepers River had slightly more positive than negative trends overall, but among the significant trends ( p < 0.1), negative trends dominated 67 to 40. At Hubbard Brook, negative trends outnumbered positive trends by a nearly 2:1 margin and all seven of the significant trends were negative. The negative trends occurred despite generally increasing trends in monthly and annual precipitation. This counterintuitive pattern may be a result of increased precipitation intensity causing higher runoff at the expense of recharge, such that evapotranspiration demand draws down groundwater storage. We evaluated predictors of month-end water levels by multiple regression of 18 variables related to climate, streamflow, snowpack, and prior month water level. Monthly flow and prior month water level were the two strongest predictors for most months at both sites. The predictive power and ready availability of streamflow data can be exploited as a proxy to extend limited groundwater level records over longer time periods.

New Hampshire, Vermont↗

Temporal greenness trends in stable natural land cover and relationships with climatic variability across the conterminous United States

Assessment of temporal trends in vegetation greenness and related influences aids understanding of recent change in terrestrial ecosystems and feedbacks from weather, climate, and environment. We analyzed 1-km normalized difference vegetation index (NDVI) timeseries data (1989–2016) derived from the Advanced Very High Resolution Radiometer (AVHRR) and developed growing season time-integrated NDVI (GS-TIN) for estimating seasonal vegetation activity across stable natural land cover in the conterminous United States (CONUS). After removing areas from analysis that had experienced land cover conversion or modification, we conducted a monotonic trend analysis on the GS-TIN timeseries and found that significant positive temporal trends occurred over 35% of the area, while significant negative trends were observed over only 3.5%. Positive trends were prevalent in the forested lands of the eastern third of CONUS and far northwest, as well as in grasslands in the north central plains. We observed negative and nonsignificant trends mainly in the shrublands and grasslands across the northwest, southwest, and west central plains. To understand the relationship of climate variability with these temporal trends, we conducted partial and multiple correlation analyses on GS-TIN, growing season temperature, and water-year precipitation timeseries. The GS-TIN trends in northern forests were positively correlated with temperature. The GS-TIN trends in the central and western shrublands and grasslands were negatively correlated with temperature and positively correlated with precipitation. Our results revealed spatial patterns in vegetation greenness trends for different stable natural vegetation types across CONUS, enhancing understanding gained from prior studies based on coarser 8-km AVHRR data.

Earth Interactions↗

Great Lakes prey fish populations: a cross-basin overview of status and trends based on bottom trawl surveys, 1978-2013

The assessment of Great Lakes prey fish stocks have been conducted annually with bottom trawls since the 1970s by the Great Lakes Science Center, sometimes assisted by partner agencies. These stock assessments provide data on the status and trends of prey fish that are consumed by important commercial and recreational fishes. Although all these annual surveys are conducted using bottom trawls, they differ among the lakes in the proportion of the lake covered, seasonal timing, trawl gear used, and the manner in which the trawl is towed (across or along bottom contours). Because each assessment is unique, population indices were standardized to the highest value for a time series within each lake for the following prey species: Cisco (Coregonus artedi), Bloater (C. hoyi), Rainbow Smelt (Osmerus mordax), Alewife (Alosa pseudoharengus), and Round Goby (Neogobius melanostomus). In this report, standardized indices are presented in graphical form along with synopses to provide a short, informal cross-basin summary of the status and trends of principal prey fishes. There was basin-wide agreement in the trends of age-1 and older biomass for all prey species, with the highest concordance occurring for coregonids and Rainbow Smelt, and weaker concordance for Alewife. For coregonids, the highest biomass occurred from the mid-1980s to the mid-1990s. Rainbow Smelt biomass declined slowly and erratically during the last quarter century. Alewife biomass was generally higher from the early 1980s through 1990s across the Great Lakes, but since the early 1990s, trends have been divergent across the lakes, though there has been a downward trend in all lakes since 2005. Recently, Lake Huron has shown resurgence in biomass of Bloater, achieving 75% of its maximum record in 2012 due to recruitment of a succession of strong and moderate year classes that appeared in 2005-2011. Also, strong recruitment of the 2010 year class of Alewife has led to a sharp increase in biomass of Alewife in Lake Michigan. In general, trends in year-class strengths were less concordant across the basin and only coregonids showed statistical agreement across the upper Great Lakes. The appearance of strong and moderate year-classes of Bloater in Lake Huron in 2005- 2011 countered the trend of continuing weak year-classes of coregonids in Lakes Michigan and Superior. Not shown in our analysis is the appearance of the 2013 year-class of Bloater in Huron, the largest to date. There was no agreement in cross-basin trends in year-class strengths for Rainbow Smelt and Alewife, although there was agreement between pairs of lakes. Although there was statistical agreement in trends of age-0 and older Round Goby biomass among lakes where this species has successfully invaded (Michigan, Huron, Erie and Ontario), temporal patterns of biomass in each lake were different. Round Goby may be approaching equilibrium in Lake Erie, peaking in Lake Huron, and expanding in Lake Michigan. The trend in Lake Ontario remains unclear. Declining abundance in Lake Erie has corresponded with evidence that Round Goby have become increasingly incorporated into piscivore diets, e.g., Lake Trout, Walleye, Smallmouth Bass, Yellow Perch, and Burbot in Lakes Michigan, Huron, Erie, and Ontario. Round Goby continue to be absent from spring bottom trawl assessments in Lake Superior, but their presence in the harbors and embayments of Duluth and Thunder Bay (U.S. Geological Survey and Ontario Ministry of Natural Resources, unpublished data), suggests that there is potential for future colonization.

Great Lakes↗

Sources and preparation of data for assessing trends in concentrations of pesticides in streams of the United States, 1992&ndash;2010

This report updates a previously published water-quality dataset of 44 commonly used pesticides and 8 pesticide degradates suitable for a national assessment of trends in pesticide concentrations in streams of the United States. Water-quality samples collected from January 1992 through September 2010 at stream-water sites of the U.S. Geological Survey (USGS) National Water-Quality Assessment (NAWQA) Program and the National Stream Quality Accounting Network (NASQAN) were compiled, reviewed, selected, and prepared for trend analysis. The principal steps in data review for trend analysis were to (1) identify analytical schedule, (2) verify sample-level coding, (3) exclude inappropriate samples or results, (4) review pesticide detections per sample, (5) review high pesticide concentrations, and (6) review the spatial and temporal extent of NAWQA pesticide data and selection of analytical methods for trend analysis. The principal steps in data preparation for trend analysis were to (1) select stream-water sites for trend analysis, (2) round concentrations to a consistent level of precision for the concentration range, (3) identify routine reporting levels used to report nondetections unaffected by matrix interference, (4) reassign the concentration value for routine nondetections to the maximum value of the long-term method detection level (maxLT-MDL), (5) adjust concentrations to compensate for temporal changes in bias of recovery of the gas chromatography/mass spectrometry (GCMS) analytical method, and (6) identify samples considered inappropriate for trend analysis. Samples analyzed at the USGS National Water Quality Laboratory (NWQL) by the GCMS analytical method were the most extensive in time and space and, consequently, were selected for trend analysis. Stream-water sites with 3 or more water years of data with six or more samples per year were selected for pesticide trend analysis. The selection criteria described in the report produced a dataset of 21,988 pesticide samples at 212 stream-water sites. Only 21,144 pesticide samples, however, are considered appropriate for trend analysis.

Data Series↗

Summary of trends and status analysis for flow, nutrients, and sediments at selected nontidal sites, Chesapeake Bay basin, 1985-99

Water-quality and flow data from 31 sites in nontidal portions of the Chesapeake Bay Basin were analyzed to document annual nutrient and sediment loads and trends for the period 1985 through 1999 as part of an annual reevaluation and reporting for the Chesapeake Bay Program. Annual loads were estimated by use of the U.S. Geological Survey ESTIMATOR model. Trends were estimated using linear regression. Trends were reported for monthly mean flow, monthly load, flow-adjusted concentration, and flow-weighted concentration. Median yields and concentrations were calculated to help facilitate comparisons between basins. The drought of 1999 had pronounced effects on trend results. The trend in flow increased at 4 of the 31 sites, 8 fewer sites than in 1998. Ten less significant trends were estimated for nutrient and sediment loads compared to 1985-98. Trends in flow-weighted and flow-adjusted concentrations varied little by nutrient species and geographic location. Trends were generally downward or not significant for both the nitrogen and phosphorus species throughout the Chesapeake Bay Basin. Trends in flow-adjusted concentration indicated downward trends at most sites for nutrients and about half the sites for sediments, an indication that management actions are reducing nutrient and sediment concentrations.

Open-File Report↗

Factors affecting long-term trends in surface-water quality in the Gwynns Falls watershed, Baltimore City and County, Maryland, 1998–2016

Factors affecting water-quality trends in urban streams are not well understood, despite current regulatory requirements and considerable ongoing investments in gray and green infrastructure. To address this gap, long-term water-quality trends and factors affecting these trends were examined in the Gwynns Falls, Maryland, watershed during 1998–2016 in cooperation with Blue Water Baltimore. Data on water-quality constituents and potential factors of influence were obtained from multiple sources and compiled for analysis, with a focus on data collected as part of the National Science Foundation funded Long-Term Ecological Research project, the Baltimore Ecosystem Study. Variability in climate (specifically, precipitation) and land cover can overwhelm actions taken to improve water quality and can present challenges for meeting regulatory goals. Analysis of land cover during 2001–11 in the Gwynns Falls watershed indicated minimal change during the study time frame; therefore, land-cover change is likely not a factor affecting trends in water quality. However, a modest increase in annual precipitation and a significant increase in winter precipitation were apparent in the region. A higher proportion of runoff producing storms was observed in the winter and a lower proportion in the summer, indicating that climate change may affect water quality in the watershed. The increase in precipitation was not reflected in annual or seasonal trends of streamflow in the watershed. Nonetheless, these precipitation changes may exacerbate the inflow and infiltration of water to gray infrastructure and reduce the effectiveness of green infrastructure. For streamflow and most water-quality constituents examined, no discernable trends were noted over the timeframe examined. Despite the increases in precipitation, no trends were observed for annual or seasonal discharge at the various sites within the study area. In some locations, nitrate, phosphate, and total nitrogen show downward trends, and total phosphorus and chloride show upward trends. Sanitary sewer overflows (gray infrastructure) and best management practices (green infrastructure) were identified as factors affecting water-quality change. The duration of sanitary sewer overflows was positively correlated with annual loads of nutrients and bacteria, and the drainage area of best management practices was negatively correlated with annual loads of phosphate and sulfate. Results of the study indicate that continued investments in gray and green infrastructure are necessary for urban water-quality improvement. Although this outcome is not unexpected, long-term datasets such as the one used in this study, allow the effects of gray and green infrastructures to be quantified. Results of this study have implications for the Gwynns Falls watershed and its residents and Baltimore City and County managers. Moreover, outcomes are relevant to other watersheds in the metropolitan region that do not have the same long-term dataset. Further, this study has established a framework for ongoing statistical analysis of primary factors affecting urban water-quality trends as regulatory programs mature.

Maryland↗

Analysis of phosphorus trends and evaluation of sampling designs in the Quinebaug River Basin, Connecticut

A time-series analysis approach developed by the U.S. Geological Survey was used to analyze trends in total phosphorus and evaluate optimal sampling designs for future trend detection, using long-term data for two water-quality monitoring stations on the Quinebaug River in eastern Connecticut. Trend-analysis results for selected periods of record during 1971?2001 indicate that concentrations of total phosphorus in the Quinebaug River have varied over time, but have decreased significantly since the 1970s and 1980s. Total phosphorus concentrations at both stations increased in the late 1990s and early 2000s, but were still substantially lower than historical levels. Drainage areas for both stations are primarily forested, but water quality at both stations is affected by point discharges from municipal wastewater-treatment facilities. Various designs with sampling frequencies ranging from 4 to 11 samples per year were compared to the trend-detection power of the monthly (12-sample) design to determine the most efficient configuration of months to sample for a given annual sampling frequency. Results from this evaluation indicate that the current (2004) 8-sample schedule for the two Quinebaug stations, with monthly sampling from May to September and bimonthly sampling for the remainder of the year, is not the most efficient 8-sample design for future detection of trends in total phosphorus. Optimal sampling schedules for the two stations differ, but in both cases, trend-detection power generally is greater among 8-sample designs that include monthly sampling in fall and winter. Sampling designs with fewer than 8 samples per year generally provide a low level of probability for detection of trends in total phosphorus. Managers may determine an acceptable level of probability for trend detection within the context of the multiple objectives of the state?s water-quality management program and the scientific understanding of the watersheds in question. Managers may identify a threshold of probability for trend detection that is high enough to justify the agency?s investment in the water-quality sampling program. Results from an analysis of optimal sampling designs can provide an important component of information for the decision-making process in which sampling schedules are periodically reviewed and revised. Results from the study described in this report and previous studies indicate that optimal sampling schedules for trend detection may differ substantially for different stations and constituents. A more comprehensive statewide evaluation of sampling schedules for key stations and constituents could provide useful information for any redesign of the schedule for water-quality monitoring in the Quinebaug River Basin and elsewhere in the state.

Scientific Investigations Report↗

Variability of differences between two approaches for determining ground-water discharge and pumpage, including effects of time trends, Lower Arkansas River Basin, southeastern Colorado, 1998-2002

In the mid-1990s, the Colorado Division of Water Resources (CDWR) adopted rules governing measurement of tributary ground-water pumpage for the Arkansas River Basin. The rules allowed ground-water pumpage to be determined using one of two approaches?power conversion coefficient (PCC) or totalizing flowmeters (TFM). In addition, the rules allowed a PCC to be applied to the electrical power usage up to 4 years in the future to estimate ground-water pumpage. As a result of concerns about potential errors in applying the PCC approach forward in time, a study was done by the U.S. Geological Survey, in cooperation with CDWR and Colorado Water Conservation Board, to evaluate the variability in differences in pumpage between the two approaches, including the effects of time trends. This report compared measured ground-water pumpage using TFMs to computed ground-water pumpage using PCCs by developing statistical models of relations between explanatory variables, such as site, time, and pumping water level, and dependent variables, which are based on discharge, PCC, and pumpage. When differences in pumpage (diffP) were computed using PCC measurements and power consumption for the same year (1998-2002), the median diffP, depending on the year, ranged from +0.1 to -2.9 percent; the median diffP for the entire period was -1.5 percent. However, when diffP was computed using PCC measurements applied to the next year's power consumption, the median diffP was -0.3 percent; and when PCC measurements were applied 2, 3, or 4 years into the future, median diffPs were +1.8 percent for a 2-year forward lag and +5.3 percent for a 4-year forward lag, indicating that pumpage computed with the PCC approach, as generally applied under the ground-water pumpage measurement rules by CDWR, tended to overestimate pumpage as compared to pumpage using TFMs when PCC measurement was applied to future years of measured power consumption. Analyses were done to better understand the causes of the time trend; an estimate of the overall trend with time (uncorrected for pumping water-level changes) yielded a trend of about 2.2 percent per lag year for diffP. A separate analysis that incorporated a surface-water diversion term in the statistical model rendered the time-trend term insignificant, indicating that the time trend in the models served as a surrogate for other variables, some of which reflect underlying hydrologic conditions. A more precise explanation of the potential causes of the time trend was not obtained with the available data. However, the model results with the surface-water diversion term indicate that much of the trend of 2.2 percent per lag year in diffP resulted from applying a PCC to estimate pumpage under hydrologic conditions different from those under which the PCC was measured. Although there is no evidence to conclude that the upward time trend determined in the data for this 5-year period would hold in the future, historical static ground-water levels in the study area generally have exhibited small variations over multidecadal time scales. Therefore, the approximately 2 percent per lag year trend determined in these data is expected to be a reasonable guideline for estimating potential errors in the PCC approach resulting from temporally varying hydrologic conditions between time of PCC measurement and pumpage estimation. Comparisons also were made between total, or aggregated, pumpage for a network of wells as computed by the PCC approach and the TFM approach. For 100 wells and a lag of 4 years between PCC measurement and pumpage estimation, there was a 95-percent probability that the difference between total network pumpage measured by the PCC approach and that measured using a TFM would be between 5.2 and 14.4 percent. These estimates were based on a bias of 2.2 percent per lag year estimated for the period 1998-2002 during which hydrologic conditions were known to have changed. Using the same assumptions, the estimated d

Scientific Investigations Report↗

Summary and trend analysis of water-quality data for the Oakes Test Area, southeastern North Dakota, 1984-2004

The Oakes Test Area is operated and maintained by the Garrison Diversion Conservancy District, under a cooperative agreement with the Bureau of Reclamation, to evaluate the effectiveness and environmental consequences of irrigation. As part of the evaluation, the Bureau of Reclamation collected water-quality samples from seven sites on the James River and the Oakes Test Area. The data were summarized and examined for trends in concentration. A nonparametric statistical test was used to test whether each concentration was increasing or decreasing with time for selected physical properties and constituents, and a trend slope was estimated for each constituent at each site. Trends were examined for two time periods, 1988-2004 and 1994-2004. Results varied by site and by constituent. All sites and all constituents tested had at least one statistically significant trend in the period 1988-2004. Sulfate, total dissolved solids, nitrate, and orthophosphate have significant positive trends at multiple sites with no significant negative trend at any site. Alkalinity and arsenic have single significant positive trends. Hardness, calcium, magnesium, sodium, sodium-adsorption ratio, potassium, and chloride have both significant positive and negative trends. Ammonia has a single significant negative trend. Fewer significant trends were identified in 1994-2004, and all but one were positive. The contribution to the James River from Oakes Test Area drainage appears to have little effect on water quality in the James River.

North Dakota↗

Sources, transport, and trends for selected trace metals and nutrients in the Coeur d'Alene and Spokane River Basins, Idaho, 1990-2013

Data collected at 18 streamflow-gaging and water-quality sampling sites in the Coeur d&rsquo;Alene and Spokane River Basins of northern Idaho were used to estimate mean streamflow‑weighted concentrations and annual loads of total and dissolved cadmium, lead, and zinc, and total phosphorus (TP) and nitrogen (TN) for water years (WYs) 2009&ndash;13. Chronic Ambient Water Quality Criteria (AWQC) and AWQC ratios also were calculated to evaluate Idaho aquatic life criteria for chronic exposure to cadmium and zinc in streams. At four sites with a longer period of record, a Seasonal Kendall trend test was used to assess historical trends in the concentrations of total cadmium, lead, and zinc, and chronic AWQC ratios for cadmium and zinc during WYs 1990&ndash;2013. Concentrations of dissolved and total cadmium, lead, and zinc varied widely both at and among sites. At most sites, dissolved cadmium and zinc constituted most of the total concentrations; dissolved lead generally constituted less than 10 percent of the total lead concentration. Trace metal concentrations increased by 2 to 4 orders of magnitude along the South Fork Coeur d&rsquo;Alene River (SFCDR) from near Mullan (site 2) downstream to near Pinehurst (site 13). The mean streamflow-weighted concentrations of total cadmium, lead, and zinc in the SFCDR near Pinehurst for WYs 2009&ndash;13 were 3.71, 61.4, and 514 micrograms per liter (&mu;g/L), respectively. In the Coeur d&rsquo;Alene River (CDR) near Harrison (site 15), downstream of the confluence of the metal-enriched SFCDR and the relatively dilute North Fork Coeur d&rsquo;Alene River (NFCDR), the mean streamflow-weighted concentrations of total cadmium, lead, and zinc were 1.58, 125, and 236 &mu;g/L, respectively. Trace‑metal concentrations were smaller in the Spokane River than in the CDR because of dilution and retention of trace metals in Coeur d&rsquo;Alene Lake. The mean streamflow-weighted concentrations of total cadmium, lead, and zinc in the Spokane River near Post Falls (site 18) were 0.231, 2.91, and 48.9 &mu;g/L, respectively. AWQC ratios indicate that cadmium and zinc concentrations met the chronic criteria (ratio of less than 1.0) for the protection of aquatic life at only three sites: the NFCDR at Enaville (site 1), the upper SFCDR near Mullan (site 2), and the St. Joe River near St. Maries (site 16). Cadmium and zinc concentrations at sites on the Spokane River (sites 17 and 18) generally were close to the chronic AWQC values. The sites with the largest chronic AWQC ratios in the Coeur d&rsquo;Alene and Spokane River Basins for both cadmium and zinc were in the Canyon and Ninemile Creek basins (sites 3&ndash;6). Concentrations of TP and TN generally were low along the SFCDR downstream to Kellogg. From the SFCDR near Kellogg (site 9) downstream to the SFCDR above Pine Creek (site 11), the mean streamflow-weighted concentration of the nutrients TP and TN increased by 0.036 milligram per liter (mg/L) (200 percent) and 0.124 mg/L (78 percent), respectively. The increases in nutrient concentrations along the SFCDR likely are in response to discharge from wastewater‑treatment facilities. Mean streamflow-weighted concentrations for TP and TN (0.054 and 0.284 mg/L, respectively) were the highest in the sampling network in the SFCDR above Pine Creek (site 11). LOADEST modeling was used to relate mass transport, or load, of trace metals and nutrients to variations in streamflow and time. Results indicate that most of the cadmium and zinc load in the Coeur d&rsquo;Alene and Spokane Rivers is derived from the SFCDR, and that most of the lead load is derived from the Coeur d&rsquo;Alene River downstream of the confluence of the NFCDR and SFCDR. Major tributary sources of trace metals to the SFCDR are Canyon Creek and Ninemile Creek. Combined, these two tributaries contributed estimated mean loads of about 0.575 ton per year (ton/yr) of total cadmium, 5.29 ton/yr of total lead, and 90.9 ton/yr of total zinc to the SFCDR during WYs 2009&ndash;13. Groundwater discharge and tributaries near the Central Impoundment Area between SFCDR near Kellogg (site 9) and SFCDR near Smelterville (site 10) were other primary sources of cadmium and zinc. Combined, these sources contributed an estimated 1.39 ton/yr of total cadmium and 143 ton/yr of total zinc to the SFCDR during WYs 2009&ndash;13. Erosion and transport of sediment-bound lead contained in the CDR flood plain and on the river bottom between Cataldo (site 14) and Harrison (site 15) were the primary source of lead. During WYs 2009&ndash;13, the mean load of trace metals delivered to Coeur d&rsquo;Alene Lake included about 4.66 ton/yr of total cadmium, 398 ton/yr of total lead, and 698 ton/yr of total zinc. About 99 percent of the trace-metal load to the lake was from the CDR as measured near site 15 at Harrison. During WYs 2009&ndash;13, about 1.48 ton/yr of cadmium, 18 ton/yr of lead, and 350 ton/yr of zinc were transported from Coeur d&rsquo;Alene Lake into the Spokane River as measured at the lake outlet (site 17). During WYs 2009&ndash;13, the loads of TP and TN delivered from the Coeur d&rsquo;Alene and St. Joe Rivers to Coeur d&rsquo;Alene Lake were about equivalent. On average, the CDR transported about 93.6 tons of TP and 369 tons of TN, and the St. Joe River transported about 92.9 tons of TP and 360 tons of TN to the lake during 2009&ndash;13. About 52.9 ton/yr of TP and 628 ton/yr of TN were transported from Coeur d&rsquo;Alene Lake to the Spokane River during WYs 2009&ndash;13. Results from Seasonal Kendall trend tests indicate statistically significant downward temporal trends during WYs 1990&ndash;2013 for total cadmium, lead, zinc, and chronic AWQC ratios of cadmium and zinc in the SFCDR at Elizabeth Park (site 8) and near Pinehurst (site 13), and in the CDR near Harrison (site 15). Statistically significant downward temporal trends for total lead, zinc, and the chronic AWQC ratio of zinc also occurred in the Spokane River near Post Falls (site 18) during WYs 1991&ndash;2013. Seasonal Kendall trend tests for WYs 2003&ndash;13 indicated statistically significant downward trends for total cadmium, zinc, and chronic AWQC ratios of cadmium and zinc in the SFCDR at Elizabeth Park (site 8). The Spokane River near Post Falls (site 18) had a statistically significant downward trend for total zinc during WYs 2003&ndash;13, and a significant upward trend for the chronic AWQC ratio of cadmium. No significant trends were found in trace-metal concentrations or chronic AWQC ratios in the SFCDR near Pinehurst (site 13) and the CDR near Harrison (site 15) during WYs 2003&ndash;13. Results from this study indicate that remedial activities conducted since the 1990s have been successful in reducing the concentrations and loads of trace metals in streams and rivers in the Coeur d&rsquo;Alene and Spokane River Basins. Soils, sediment, surface water, and groundwater in areas of the Coeur d&rsquo;Alene and Spokane River Basins are contaminated, and the hydrological relations between these media are complex and difficult to characterize. Trace metals have variable source areas, are transported differently depending on hydrologic conditions, and behave differently in response to remedial activities in upstream basins. Based on these findings, no single remedial action would be completely effective in reducing all trace metals to nontoxic concentrations throughout the Coeur d&rsquo;Alene and Spokane River Basins. Instead, unique cleanup activities targeted at specific media and specific source areas may be necessary to achieve long-term water-quality goals.

Idaho↗

Water-quality trends and constituent-transport analysis for selected sampling sites in the Milltown Reservoir/Clark Fork River Superfund Site in the upper Clark Fork Basin, Montana, water years 1996–2015

During the extended history of mining in the upper Clark Fork Basin in Montana, large amounts of waste materials enriched with metallic contaminants (cadmium, copper, lead, and zinc) and the metalloid trace element arsenic were generated from mining operations near Butte and milling and smelting operations near Anaconda. Extensive deposition of mining wastes in the Silver Bow Creek and Clark Fork channels and flood plains had substantial effects on water quality. Federal Superfund remediation activities in the upper Clark Fork Basin began in 1983 and have included substantial remediation near Butte and removal of the former Milltown Dam near Missoula. To aid in evaluating the effects of remediation activities on water quality, the U.S. Geological Survey began collecting streamflow and water-quality data in the upper Clark Fork Basin in the 1980s. Trend analysis was done on specific conductance, selected trace elements (arsenic, copper, and zinc), and suspended sediment for seven sampling sites in the Milltown Reservoir/Clark Fork River Superfund Site for water years 1996–2015. The most upstream site included in trend analysis is Silver Bow Creek at Warm Springs, Montana (sampling site 8), and the most downstream site is Clark Fork above Missoula, Montana (sampling site 22), which is just downstream from the former Milltown Dam. Water year is the 12-month period from October 1 through September 30 and is designated by the year in which it ends. Trend analysis was done by using a joint time-series model for concentration and streamflow. To provide temporal resolution of changes in water quality, trend analysis was conducted for four sequential 5-year periods: period 1 (water years 1996–2000), period 2 (water years 2001–5), period 3 (water years 2006–10), and period 4 (water years 2011–15). Because of the substantial effect of the intentional breach of Milltown Dam on March 28, 2008, period 3 was subdivided into period 3A (October 1, 2005–March 27, 2008) and period 3B (March 28, 2008–September 30, 2010) for the Clark Fork above Missoula (sampling site 22). Trend results were considered statistically significant when the statistical probability level was less than 0.01. In conjunction with the trend analysis, estimated normalized constituent loads (hereinafter referred to as “loads”) were calculated and presented within the framework of a constituent-transport analysis to assess the temporal trends in flow-adjusted concentrations (FACs) in the context of sources and transport. The transport analysis allows assessment of temporal changes in relative contributions from upstream source areas to loads transported past each reach outflow. Trend results indicate that FACs of unfiltered-recoverable copper decreased at the sampling sites from the start of period 1 through the end of period 4; the decreases ranged from large for one sampling site (Silver Bow Creek at Warm Springs [sampling site 8]) to moderate for two sampling sites (Clark Fork near Galen, Montana [sampling site 11] and Clark Fork above Missoula [sampling site 22]) to small for four sampling sites (Clark Fork at Deer Lodge, Montana [sampling site 14], Clark Fork at Goldcreek, Montana [sampling site 16], Clark Fork near Drummond, Montana [sampling site 18], and Clark Fork at Turah Bridge near Bonner, Montana [sampling site 20]). For period 4 (water years 2011–15), the most notable changes indicated for the Milltown Reservoir/Clark Fork River Superfund Site were statistically significant decreases in FACs and loads of unfiltered-recoverable copper for sampling sites 8 and 22. The period 4 changes in FACs of unfiltered-recoverable copper for all other sampling sites were not statistically significant. Trend results indicate that FACs of unfiltered-recoverable arsenic decreased at the sampling sites from period 1 through period 4 (water years 1996–2015); the decreases ranged from minor (sampling sites 8–20) to small (sampling site 22). For period 4 (water years 2011–15), the most notable changes indicated for the Milltown Reservoir/Clark Fork River Superfund Site were statistically significant decreases in FACs and loads of unfiltered-recoverable arsenic for sampling site 8 and near statistically significant decreases for sampling site 22. The period 4 changes in FACs of unfiltered-recoverable arsenic for all other sampling sites were not statistically significant. Trend results indicate that FACs of suspended sediment decreased at the sampling sites from period 1 through period 4 (water years 1996–2015); the decreases ranged from moderate (sampling site 8) to small (sampling sites 11–22). For period 4 (water years 2011–15), the changes in FACs of suspended sediment were not statistically significant for any sampling sites. The reach of the Clark Fork from Galen to Deer Lodge is a large source of metallic contaminants and suspended sediment, which strongly affects downstream transport of those constituents. Mobilization of copper and suspended sediment from flood-plain tailings and the streambed of the Clark Fork and its tributaries within the reach results in a contribution of those constituents that is proportionally much larger than the contribution of streamflow from within the reach. Within the reach from Galen to Deer Lodge, unfiltered-recoverable copper loads increased by a factor of about 4 and suspended-sediment loads increased by a factor of about 5, whereas streamflow increased by a factor of slightly less than 2. For period 4 (water years 2011–15), unfiltered-recoverable copper and suspended-sediment loads sourced from within the reach accounted for about 41 and 14 percent, respectively, of the loads at Clark Fork above Missoula (sampling site 22), whereas streamflow sourced from within the reach accounted for about 4 percent of the streamflow at sampling site 22. During water years 1996–2015, decreases in FACs and loads of unfiltered-recoverable copper and suspended sediment for the reach generally were proportionally smaller than for most other reaches. Unfiltered-recoverable copper loads sourced within the reaches of the Clark Fork between Deer Lodge and Turah Bridge near Bonner (just upstream from the former Milltown Dam) were proportionally smaller than contributions of streamflow sourced from within the reaches; these reaches contributed proportionally much less to copper loading in the Clark Fork than the reach between Galen and Deer Lodge. Although substantial decreases in FACs and loads of unfiltered-recoverable copper and suspended sediment were indicated for Silver Bow Creek at Warm Springs (sampling site 8), those substantial decreases were not translated to downstream reaches between Deer Lodge and Turah Bridge near Bonner. The effect of the reach of the Clark Fork from Galen to Deer Lodge as a large source of copper and suspended sediment, in combination with little temporal change in those constituents for the reach, contributes to this pattern. With the removal of the former Milltown Dam in 2008, substantial amounts of contaminated sediments that remained in the Clark Fork channel and flood plain in reach 9 (downstream from Turah Bridge near Bonner) became more available for mobilization and transport than before the dam removal. After the removal of the former Milltown Dam, the Clark Fork above Missoula (sampling site 22) had statistically significant decreases in FACs of unfiltered-recoverable copper in period 3B (March 28, 2008, through water year 2010) that continued in period 4 (water years 2011–15). Also, decreases in FACs of unfiltered-recoverable arsenic and suspended sediment were indicated for period 4 at this site. The decrease in FACs of unfiltered-recoverable copper for sampling site 22 during period 4 was proportionally much larger than the decrease for the Clark Fork at Turah Bridge near Bonner (sampling site 20). Net mobilization of unfiltered-recoverable copper and arsenic from sources within reach 9 are smaller for period 4 than for period 1 when the former Milltown Dam was in place, providing evidence that contaminant source materials have been substantially reduced in reach 9.

Montana↗

Status and trends of total nitrogen and total phosphorus concentrations, loads, and yields in streams of Mississippi, water years 2008–18

To assess the status and trends of conditions of surface waters throughout Mississippi, the U.S. Geological Survey, in cooperation with the Mississippi Department of Environmental Quality (MDEQ), summarized concentrations and estimated loads, yields, trends, and spatial and temporal patterns of total nitrogen (TN) and total phosphorus (TP) at 20 stream sites in MDEQ’s ambient water-quality monitoring network and 2 stream sites in the U.S. Geological Survey’s National Water-Quality Assessment Project’s monitoring network. Comparison of streamflow at the time of water-quality sample collection to flow-duration curves for each site showed that samples were relatively evenly spread over a wide range of flows, indicating that load estimations were representative of a wide range of flows. Relation of streamflow to concentrations of TN and TP varied among sites and land use. Sites with high agriculture land use in the drainage basin tended to have a positive correlation between streamflow and concentration, suggesting influence of event-driven nonpoint-source runoff. Sites near urban (developed) areas tended to have a negative correlation between streamflow and concentration, suggesting chronic point-source influences during low-flow conditions. Sites with high forest land use and lower agriculture and urban (developed) land use showed little to no association between streamflow and concentration. Seasonal distributions of concentrations of TN and TP also corresponded closely with variations in land use. Sites near urban (developed) land had the highest concentrations in late summer and fall, sites with a high percentage of agricultural land had the highest concentrations in the spring, and sites that were primarily forested or with little developed land did not exhibit substantial changes in concentration across seasons. Eight sites had statistical likelihoods for upward trends of TN loads, and seven sites had statistical likelihoods for downward trends. Trends in TN loads at six sites were considered “about as likely as not,” meaning that a site has an equal chance of having an upward or downward trend. Trend results of mean annual flow-normalized loads of TP for the period of analysis (2008–18) showed that 16 sites had upward trends, 3 sites had downward trends, and 2 sites were considered “about as likely as not.” Results from our study were compared to results from existing regional models to assess accuracy of predictions at a local scale. Comparisons of yields predicted from 2012 regional-scale SPAtially Referenced Regressions on Watershed attributes (SPARROW) to results from this study showed the 2012 SPARROW-predicted estimates varied in consistency with results from this study. The 2012 SPARROW-prediction model underestimated TN yields, more often and by a slightly larger degree, more than it overestimated TN yields. The 2012 SPARROW-predicted model tended to underestimate yields at study sites with higher yields. All four sites in the predominantly agricultural area of northwest Mississippi, locally known as the Mississippi Delta, were underestimated by 2012 SPARROW. For TP, yield comparisons at sites with lower yields were consistent, yields at sites with midrange yields tended to be overestimated by SPARROW, and yields at sites with high yields tended to be underestimated by SPARROW. TP yields at four sites in the Mississippi Delta were underestimated by the 2012 SPARROW-predicted model. Results of select sites from our study were also compared to other published load estimates from an earlier time period to evaluate possible trends. Comparison of TN yields at four sites and TP yields at three sites from the study-derived estimates to estimates made from data spanning 1993–2004 showed decreasing TN yields at all four sites and decreasing TP yields at two of three sites, with increasing yields of TP at the Yazoo River lower site. Also, a third comparison of the TN and TP yields of the Yazoo River lower site of this study to estimates made from data spanning 1996–97 showed decreasing TN yields but similar TP yields. This suggests that TN yields may have decreased over the last 20–30 years, but TP yields remain constant or are increasing.

Mississippi↗

Analysis of water-quality trends at two discharge stations — One within Big Cypress National Preserve and one near Biscayne Bay — Southern Florida, 1966-94

An analysis of water-quality trends was made at two U.S. Geological Survey daily discharge stations in southern Florida. The ESTREND computer program was the principal tool used for the determination of water-quality trends at the Miami Canal station west of Biscayne Bay in Miami and the Tamiami Canal station along U.S. Highway 41 in the Big Cypress National Preserve in Collier County. Variability in water quality caused by both seasonality and streamflow was compensated for by applying the nonparametric Seasonal Kendall trend test to unadjusted concentrations or flow-adjusted concentrations (residuals) determined from linear regression analysis. Concentrations of selected major inorganic constituents and physical characteristics; pH and dissolved oxygen; suspended sediment; nitrogen, phosphorus, and carbon species; trace metals; and bacteriological and biological characteristics were determined at the Miami and Tamiami Canal stations. Median and maximum concentrations of selected constituents were compared to the Florida Class III freshwater standards for recreation, propagation, and maintenance of a healthy, well-balanced population of fish and wildlife. The median concentrations of the water-quality constituents and characteristics generally were higher at the Miami Canal station than at the Tamiami Canal station. The maximum value for specific conductance at the Miami Canal station exceeded the State standard. The median and maximum concentrations for ammonia at the Miami and Tamiami Canal stations exceeded the State standard, whereas median dissolved-oxygen concentrations at both stations were below the State standard. Trend results were indicative of either improvement or deterioration in water quality with time. Improvement in water quality at the Miami Canal station was reflected by downward trends in suspended sediment (1987-94), turbidity, (1970-78), total ammonia (1971-94), total phosphorus (1987-94), barium (1978-94), iron (1969-94), and fecal coliform (1976-94). Deterioration in water quality at the same station was indicated by upward trends in specific conductance (1966-94), dissolved solids (1966-94, 1976-94, and 1987-94), chloride (1966-94), potassium (1966-94), magnesium (1966-94), sodium (1966-94), sulfate (1966-94), silica (1966-94), suspended sediment (1974-94), total organic carbon (1970-81), and fecal streptococcus (1987-94). The downward trend in pH (1966-94) was indicative of deterioration in water quality at the Miami Canal station. Improvement in water quality at the Tamiami Canal station was reflected by downward trends in fluoride (1967-93), total ammonia (1970-92), total nitrite plus nitrate (1975-85), and barium (1978-93). Deterioration in water quality at the same station was statistically significant by upward trends in specific conductance (1967-93), dissolved solids (1967-93), chloride (1967-93), sodium (1967-93), potassium (1967-93), magnesium (1967-93), strontium (1967-93), and suspended sediment (1976-93). The downward trend in dissolved oxygen (1970-93) was indicative of deterioration in water quality.

Florida↗

Summary statistics and trend analysis of water-quality data at sites in the Gila River basin, New Mexico and Arizona

Summary statistics and temporal trends for 19 water-chemistry constituents and for turbidity were computed for 13 study sites in the Gila River basin, Arizona and New Mexico. A nonparametric technique, the seasonal Kendall tau test for flow-adjusted data, was used to analyze temporal changes in water-chemistry data. For the 19 selected constituents and turbidity, decreasing trends in concentrations outnumbered increasing trends by more than two to one. Decreasing trends in concentrations of constituents were found for 49 data sets at the 13 study sites. Gila River at Calva and Gila River above diversions, at Gillespie Dam (eight each) had the most decreasing trends for individual sites. The largest number of decreasing trends measured for a constituent was six for dissolved lead. The next largest number of decreasing trends for a constituent was for dissolved solids and total manganese (five each). Hardness, dissolved sodium, and dissolved chloride had decreasing trends at four of the study sites. Increasing trends in concen- trations of constituents were found for 24 data sets at the 13 study sites. The largest number of increasing trends measured for a single constituent was for pH (four), dissolved sulfate (three), dissolved chromium (three) and total manganese (three). Increased concentrations of constituents generally were found in three areas in the basin-at Pinal Creek above Inspiration Dam, at sites above reservoirs, and at sites on the main stem of the Gila River from Gillespie Dam to the mouth.

Water-Resources Investigations Report↗

Spatial and temporal trends in Potomac River fish abundance linked to species traits

Analysis of species abundance trends can inform an understanding of the underlying mechanisms. We evaluated spatial and temporal trends in fish species abundance in the non-tidal Potomac River (USA) from a dataset comprising 2841 seine-hauls with > 250,000 individual fish records across 10 sites and 43 years (1975-2017). The dataset contained 47 species from 7 taxonomic families, with species richness and abundance dominated by leuciscids, centrarchids, and percids (85% and 95% of the total dataset, respectively). We used linear modeling and bootstrapping techniques to estimate spatial and temporal trends in abundance (CPUE) for 38 species, excluding the rarest taxa (< 30 individuals). Spatial trends in abundance were detected for 22 species (58%), of which 15 were more abundant downstream than upstream and 7 were more abundant upstream than downstream. Temporal trends in abundance were detected for 25 species (66%), of which 15 increased over time and 10 decreased over time. Spatial trends were associated with reproductive life history strategies: egg-attachers and viviparous fishes generally increased in a downstream direction, whereas species with other reproductive modes and relatively short spawning durations (< ~2 months) showed the opposite spatial trend. Temporal trends were associated with reproductive guilds and range area (a surrogate for environmental tolerance): egg-attachers and nest-associates generally increased in abundance over time, whereas broadcast spawners, clean-gravel spawners, and nest-guarders with relatively small range areas (< ~ 1.2 million km2) tended to decrease over time. This study provides an analysis of one of the largest systematic collections of freshwater fishes to our knowledge and provides a framework to evaluate mechanisms underlying observed trends.

Potomac River↗

Trend analyses with river sediment rating curves

Sediment rating curves, which are fitted relationships between river discharge (Q) and suspended-sediment concentration (C), are commonly used to assess patterns and trends in river water quality. In many of these studies it is assumed that rating curves have a power-law form (i.e., C = aQb, where a and b are fitted parameters). Two fundamental questions about the utility of these techniques are assessed in this paper: (i) How well to the parameters, a and b, characterize trends in the data? (ii) Are trends in rating curves diagnostic of changes to river water or sediment discharge? As noted in previous research, the offset parameter, a, is not an independent variable for most rivers, but rather strongly dependent on b and Q. Here it is shown that a is a poor metric for trends in the vertical offset of a rating curve, and a new parameter, &acirc;, as determined by the discharge-normalized power function [C = &acirc; (Q/QGM)b], where QGM is the geometric mean of the Q values sampled, provides a better characterization of trends. However, these techniques must be applied carefully, because curvature in the relationship between log(Q) and log(C), which exists for many rivers, can produce false trends in &acirc; and b. Also, it is shown that trends in &acirc; and b are not uniquely diagnostic of river water or sediment supply conditions. For example, an increase in &acirc; can be caused by an increase in sediment supply, a decrease in water supply, or a combination of these conditions. Large changes in water and sediment supplies can occur without any change in the parameters, &acirc; and b. Thus, trend analyses using sediment rating curves must include additional assessments of the time-dependent rates and trends of river water, sediment concentrations, and sediment discharge.

Hydrological Processes↗

Effects of lek count protocols on greater sage-grouse population trend estimates

Annual counts of males displaying at lek sites are an important tool for monitoring greater sage-grouse populations ( Centrocercus urophasianus ), but seasonal and diurnal variation in lek attendance may increase variance and bias of trend analyses. Recommendations for protocols to reduce observation error have called for restricting lek counts to within 30&thinsp;minutes of sunrise, but this may limit the number of lek counts available for analysis, particularly from years before monitoring was widely standardized. Reducing the temporal window for conducting lek counts also may constrain the ability of agencies to monitor leks efficiently. We used lek count data collected across Wyoming during 1995&minus;2014 to investigate the effect of lek counts conducted between 30&thinsp;minutes before and 30, 60, or 90&thinsp;minutes after sunrise on population trend estimates. We also evaluated trends across scales relevant to management, including statewide, within Working Group Areas and Core Areas, and for individual leks. To further evaluate accuracy and precision of trend estimates from lek count protocols, we used simulations based on a lek attendance model and compared simulated and estimated values of annual rate of change in population size (&lambda;) from scenarios of varying numbers of leks, lek count timing, and count frequency (counts/lek/year). We found that restricting analyses to counts conducted within 30&thinsp;minutes of sunrise generally did not improve precision of population trend estimates, although differences among timings increased as the number of leks and count frequency decreased. Lek attendance declined >30&thinsp;minutes after sunrise, but simulations indicated that including lek counts conducted up to 90&thinsp;minutes after sunrise can increase the number of leks monitored compared to trend estimates based on counts conducted within 30&thinsp;minutes of sunrise. This increase in leks monitored resulted in greater precision of estimates without reducing accuracy. Increasing count frequency also improved precision. These results suggest that the current distribution of count timings available in lek count databases such as that of Wyoming (conducted up to 90&thinsp;minutes after sunrise) can be used to estimate sage-grouse population trends without reducing precision or accuracy relative to trends from counts conducted within 30&thinsp;minutes of sunrise. However, only 10% of all Wyoming counts in our sample (1995&minus;2014) were conducted 61&minus;90&thinsp;minutes after sunrise, and further increasing this percentage may still bias trend estimates because of declining lek attendance.

Journal of Wildlife Management↗

Short-term trends in sulfate deposition at selected bulk precipitation stations in New York

Trends in rainfall-adjusted sulfate concentration were assessed for 5-yr subrecords of the 14.5–17 yr of monthly bulk-deposition data from five stations in New York by using the seasonal Kendall test. For the 5-yr subrecord from 1978 to 1982, the trends for the bulk deposition were similar to those for weekly wet-only deposition for adjacent stations of the National Atmospheric Deposition Program (NADP). The long-term trend at each of the bulk-precipitation sites was downward and statistically significant at P < 0.02, whereas 26% of the 69 subrecords had trends that were statistically significant only at P < 0.2. Of these statistically significant subrecord trends, 10% were positive (opposite to the long-term trend). Furthermore, the slopes of the subrecord trends tended to be much steeper than those of the whole record. These 5-yr trends, consequently, are poor indicators of the trends that occur over much longer periods in the same record.

New York↗