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381 records · Page 6Linked to original sources
USGS2026

Microplastics undergo fragmentation during pressurized membrane filtration

Low-micrometer microplastics (<10 μm) have been detected in drinking water, driving growing interest in using pressure-driven membrane filtration to remove these particles and ensure drinking water safety. However, little attention is paid to the fate of microplastics concentrated in the filtration byproduct. In this study, using well-defined polystyrene (PS) and poly(methyl methacrylate) microspheres as model particles, we observed microplastic fragmentation during nanofiltration and the subsequent release of smaller fragments. After operating for 3 h at 20 bar, 67.9 ± 8.0% of the PS spheres in the concentrate, based on particles counted in selected fields of view, were transformed into fractured particles. The characteristic Raman band signals of microplastics were significantly weakened after fragmentation, leading to detection challenges. To address this, a data processing algorithm was developed to identify PS fragments as small as 1 μm. Preliminary statistical analysis reveals that within the tested pressure range, operation time has a stronger influence on fragmentation than pressure magnitude alone and that fragmentation is further governed by the intrinsic mechanical properties of the tested model polymers. This work provides direct evidence that pressure-driven membrane processes induce microplastic fragmentation and highlights the environmental risks associated with the discharge of fragmented microplastics into the concentrate.

Environmental Science & Technology Letters↗
USGS2024

Rock sample photogrammetry

This step-by-step protocol describes the photogrammetry process used by the U.S. Geological Survey Spokane Imaging Lab (SPIMG) lab to create 3D models of geologic samples. Steps related to photographing small objects are applicable to photogrammetry in general, however, SPIMG-specific steps involving lab hardware and software may not be.

Protocols.io↗
USGS2025

The feasibility of using lidar-derived digital elevation models for gravity data reduction

Gravity data require submeter elevation accuracy for data processing, and differential global navigation satellite system (dGNSS) equipment is commonly used to acquire three-dimensional positional data to achieve such accuracy. However, lidar (light detection and ranging) data are commonly used to develop digital elevation models (DEMs) of Earth’s surface. Therefore, using elevations from lidar-derived DEMs for gravity-data acquisition and reduction may improve field efficiency and reduce cost. This study examines the feasibility of using DEMs for gravity-data reduction by comparing dGNSS elevation data from 435 gravity stations in Michigan, Wyoming, and Colorado with their respective DEM elevations. The results show that the average difference between DEM and dGNSS elevations is 13 centimeters (cm) and that 93 percent of those differences are less than 50 cm, even in areas with steep terrain. Because an elevation discrepancy of 50 cm corresponds to an error of roughly 0.1 milligals (mGal) in the simple Bouguer gravity anomaly, the results suggest that lidar-derived DEMs are a viable source for acquiring the elevation data needed to process gravity data, thus improving both the cost and efficiency of data collection for regional surveys where an accuracy of less than 1.0 mGal is desired.

Open-File Report↗
USGS2025

Enhancing mineral systems exploration through geochronology, thermochronology, and isotope analysis: USGS Geochron and USGS Isotope databases

A mineral systems approach to mineral exploration provides a comprehensive framework for understanding ore deposit formation by examining the geodynamic, magmatic, hydrothermal, and sedimentary processes responsible for mineralization, alteration, and remobilization of economic mineral deposits. Temporal and thermal constraints on ore genesis are crucial for refining mineral system models and guiding predictive exploration strategies. Geochronology and thermochronology offer invaluable insights into the timing and thermal evolution of ore-forming processes, whereas isotopic analyses provide critical information on the source and geochemical history of ore-forming fluids. Combining these methodologies have proven highly effective for mineral exploration in regions like Australia, however, their combined application has been limited in the United States. To apply these tools to mineral systems-based exploration, the U.S. Geological Survey (USGS) has developed two products: (1) The USGS Geochron Database, and (2) the USGS Isotope Database. These databases provide centralized repositories of geo/thermochronological dates and data (Geochron Database) and both radiogenic and stable isotope data (Isotope Database) generated by the USGS and partners over the past decades. Integrating these datasets together and with traditional exploration approaches provides the mineral exploration community with powerful tools for determining the temporal and thermal histories of ore systems and identifying metallogenic source provinces.

Continental United States↗
USGS2025

Probing lower-crustal fault properties with frequency-dependent tidal tremor triggering

The way seismicity responds to periodic stress perturbations offers crucial insights into the processes that can trigger an earthquake. Laboratory and theoretical analyses have shown that the period of imposed forcing and source properties affect the sensitivity to triggering, but frequency-dependent triggering of tectonic faults is poorly understood. The rate of low-frequency earthquakes (LFEs) near Parkfield, California has been found to be strongly correlated with solid earth tides. Tidal forcing acts over multiple frequencies, and the sensitivity to tidal triggering of LFEs therefore provides a unique opportunity to probe the physics of earthquake triggering and underlying fault properties. Here, we find that the response of LFEs to solid earth tides at diurnal and semi-diurnal frequencies is highly variable but spatially coherent along the San Andreas Fault. Using rate-state friction modeling, we find that the variation of the amplitude of tidal modulation is mainly affected by the spatial variation of the background effective normal stress, whereas the spatially varied tidal modulation at diurnal and semi-diurnal frequencies is mainly affected by the fault frictional property. The spatial variations of the LFE response reveal a heterogeneous lower-crustal geologic structure and complex physical faulting processes below the rupture zone of eventual great earthquakes.

California↗
USGS2024

Unscrambling the Proterozoic supercontinent record of northeastern Washington State, USA

The time interval from Supercontinent Nuna assembly in the late Paleoproterozoic to Supercontinent Rodinia breakup in the Neoproterozoic is considered by some geologists to comprise the “Boring Billion,” an interval possibly marked by a slowdown in plate tectonic processes. In northeastern Washington State, USA, similar to much of western Laurentia, early workers generally thought the tectonostratigraphic framework of this interval of geologic time consisted of two major sequences, the (ca. 1480–1380 Ma) Mesoproterozoic Belt Supergroup and unconformably overlying (<720 Ma) Neoproterozoic Windermere Supergroup. However, recent research indicates that strata considered by early workers as Belt Supergroup equivalents are actually younger, and a post-Belt, pre-Windermere record is present within the <1360 Ma Deer Trail Group and <760 Ma Buffalo Hump Formation. Thus, the northeastern Washington region perhaps comprises the most complete stratigraphic record of the “Boring Billion” time interval in the northwestern United States and holds important insights into global Proterozoic supercontinent tectonic processes. In light of these exciting developments, this field guide will address the early historic economic geology and original mapping of these Proterozoic sequences in the northeastern Washington region, and from that foundation explore more recent isotopic provenance data and their regional to global context. Finally, the guide will end with a discussion of remaining questions with a goal of stimulating interest in these relatively understudied, yet important, rocks.

Washington↗
USGS2000

Storm impact scale for barrier islands

A new scale is proposed that categorizes impacts to natural barrier islands resulting from tropical and extra-tropical storms. The proposed scale is fundamentally different than existing storm-related scales in that the coupling between forcing processes and the geometry of the coast is explicitly included. Four regimes, representing different levels of impact, are defined. Within each regime, patterns and relative magnitudes of net erosion and accretion are argued to be unique. The borders between regimes represent thresholds defining where processes and magnitudes of impacts change dramatically. Impact level 1 is the 'swash' regime describing a storm where runup is confined to the foreshore. The foreshore typically erodes during the storm and recovers following the storm; hence, there is no net change. Impact level 2 is the 'collision' regime describing a storm where the wave runup exceeds the threshold of the base of the foredune ridge. Swash impacts the dune forcing net erosion. Impact level 3 is the 'overwash' regime describing a storm where wave runup overtops the berm or, if present, the foredune ridge. The associated net landward sand transport contributes to net migration of the barrier landward. Impact level 4 is the 'inundation' regime describing a storm where the storm surge is sufficient to completely and continuously submerge the barrier island. Sand undergoes net landward transport over the barrier island; limited evidence suggests the quantities and distance of transport are much greater than what occurs during the 'overwash' regime.

Journal of Coastal Research↗
USGS2024

Editorial: From cold seeps to hydrothermal vents: Geology, chemistry, microbiology, and ecology in marine and coastal environments

This Research Topic compiles contemporary studies on cold seeps, hydrothermal vents, mud volcanoes, and related seafloor features that are associated with focused fluid emissions and the transfer of carbon, other chemical species, and sometimes heat from the geosphere to the ocean. Because these features sometimes tap fluids and gas originating kilometers below the seafloor, they provide an important window into deep processes that are otherwise inaccessible to scientists. At the shallow portion of their journey, migrating fluids nearing the seafloor contribute to a range of unique biological, physical, and chemical processes within the sediments themselves and at the sediment-water interface. Seafloor fluid emissions play a critical role in global biogeochemical cycles, ocean chemistry, and possibly even climate change. Seafloor leakage points often emit hydrocarbon gases (especially methane and CO 2 ) and are sometimes the loci for deposition of seafloor minerals that have economic value. A burgeoning area of research focuses on natural products generated at these features, seeking compounds with potential pharmaceutical or other applications. Multidisciplinary studies have become routine for characterization of seafloor fluid emission sites, attesting to the inseparability of geologic, physical, chemical, and biological processes in these settings. It is increasingly common for researchers to combine in a single research cruise: subbottom imaging and seafloor mapping; porewater and water column geochemistry and gas sampling; sediment retrieval for lithologic, biostratigraphic, and solid phase analyses; and studies of benthic and subseafloor communities at the microbial to macrofaunal scales. This multidisciplinary approach has the advantage of ensuring the spatial and temporal coincidence of surveys and samples, an important factor at highly dynamic seafloor fluid emission sites. In addition, researchers often use remotely operated vehicles (ROVs), autonomous underwater vehicles (AUVs), or human-occupied vehicles (HOVs) to record video of the seafloor, compile photomosaics, collect targeted samples, and survey with high-resolution geophysical near-seafloor systems, providing a degree of detail about seafloor fluid emission sites that is unprecedented compared to most areas of the deep ocean. While rarer, long-term cabled observatories or shorter-term deployments of portable observatories are also used at some loci for seafloor fluid flux and are particularly helpful for capturing temporal variations at these dynamic features. Here we summarize the Research Topic’s contribution to multidisciplinary seafloor emission studies in the categories of cold seeps, mud volcanoes, and hydrothermal vents. Figure 1 shows the geographic distribution of the studies in this Research Topic and key features referred to in this Introduction.

Frontiers in Earth Science↗
USGS2025

Tracing metal sources and groundwater flow paths in the Upper Animas River watershed using rare earth elements and stable isotopes

Groundwater flow paths and processes that govern metal mobility and transport are difficult to characterize in mountainous bedrock watersheds. Despite the difficulty in holistic characterization, conceptual understanding of subsurface hydrologic and geochemical processes is key to developing remediation plans for locations affected by acid mine drainage, such as the Upper Animas River watershed in southwestern Colorado, USA. Stable isotopes of water and rare earth elements were utilized to evaluate groundwater flow and metal sources within this complex catchment. Stable isotope samples collected from draining mine adits and springs display systematic spatial variation wherein sample sites at higher elevations have greater seasonal variability than sites at lower elevations. The Upper Cement Creek watershed, where multiple draining mines are present, displays the lowest seasonal variation in stable isotopic signatures, potentially indicating the presence of a large, well-mixed volume of groundwater storage or interbasin groundwater flow. Rare earth elements display statistically significant variation between different alteration styles in the catchment. Overprinting of regional propylitic alteration is evident based on enrichment of middle rare earth elements in acidic springs and mines that are not spatially associated with surficial exposures of acid generating alteration styles. Europium anomaly and middle rare earth enrichment signatures from two flooded mine tunnels on opposite sides of a watershed divide indicate connections to the same subsurface flooded mine workings.

Colorado↗
USGS2025

Systematic approach to prioritize wells for effective groundwater monitoring and management in the Arkansas Headwaters Basin, Colorado, USA

Study region The Arkansas Headwaters Basin, an intermountain basin in the Southern Rocky Mountains of North America. Study focus Our specific focus is choosing a set of wells to support a possible future regional groundwater-surface water model that would support water management. We present a three-step process using multiple criteria to score, predict, and choose prioritized wells that capture the full distribution of data including extremes. The three-step process provides accessible visualizations, fiscally efficient well prioritization, and screening useful for subsequent groundwater modeling. The novelty of the proposed methodology is the systematic approach integrating a scoring and a predictive approach to support a selection path. The systematic approach may be broadly adapted for other basins. New hydrological insights for the region Understanding regional hydrology hinges on efficient collection of hydrologic data that captures the relevant dynamics including extremes. The present study, a case study for a particular basin in the Southern Rocky Mountains, is the first use of a scripted (R software) strategy to select an economical and representative set of monitoring wells. Our findings suggest caution when using proximity as a proxy for correlation, because proximal wells in the same geologic formation and similar depths are not always correlated. In the Arkansas Headwaters Basin, subsurface geology may be less influential on groundwater elevations than broader hydrologic influences, such as regional drought.

Colorado↗
USGS2024

Ambient flow and transport in long-screened, sand-packed wells: Insights into cross contamination and wellbore flow

The presence of long-screened wells with a surrounding sand pack can have a major effect on the redistribution of contaminants in groundwater, particularly when the wells are set in low-hydraulic conductivity aquifers. Such redistribution, or cross contamination, can occur through vertical flow and advective transport or by in-well mixing via multiple non-advective transport processes. A multi-method approach, including the use of single borehole dilution tracer (SBDT) logging, was undertaken to estimate vertical transport of trichloroethylene (TCE) in 8 discontinued remedial extraction wells, all constructed with long screens (100 ft, or 30.6 m long) and surrounding sand packs, at Site 25, Edwards Air Force Base, California. The site is within an enclosed drainage basin that is underlain primarily by quartz-monzonite-granitic rocks in various states of weathering. Prior to this study, little information was available on the depths of fracture zones intersecting the wellbores. Results indicate that because of in-well mixing processes, a potential redistribution of TCE of up to 9 g/d per well occurs as a consequence of leaving the wells inactive (unpumped) and unsealed, as measured by SBDT logging. Simulations of flow made with a generic model of the site show that if the wells were to be sealed with well liners, with the intent of reducing vertical TCE transport but the sand pack left intact, TCE transport decreases by 53% overall compared to leaving the wells unlined.

Environmental Earth Sciences↗
USGS2025

Assessment of coastal and fluvial morphodynamic changes using Structure-for-Motion: A case study of the Sfȃntu Gheorghe Mouth (Danube Delta, Romania)

The ability to accurately map erosion, flooding, and habitat loss in coastal environments is crucial for formulating national strategies aimed at preventing and mitigating the impacts of natural disasters. A fundamental component of this process is the implementation of coastal morphodynamics monitoring through Structure-from-Motion (SfM) techniques, utilizing high-resolution 2D/3D data obtained from aerial photogrammetry. To assess morphodynamic changes over a three-year period (2022 – 2024), several SfM-based photogrammetric studies were conducted, each year, in the Romanian sector of the Danube-Black Sea coastal zone, specifically at the mouth of one of the Danube River distributaries (Sf Gheorghe branch) into the Black Sea, and along the left bank, near Sf Gheorghe locality, located within the Danube Delta Biosphere Reserve (DDBR). The essential equipment for aerial photogrammetry comprises Unmanned Aerial Vehicles (UAVs) and Global Navigation Satellite Systems (GNSS). In this study, the UAV used was a DJI Mavic 3T (Enterprise/Thermal) drone, complemented by two Trimble R12i and R4 GNSS systems, as well as approximately 10 Ground Control Points (GCPs). Data acquisition and processing were carried out using specialized photogrammetric software (Agisoft Metashape) along with various GIS tools (e.g., Blue Marble Geographics Global Mapper and ESRI ArcMap). The photogrammetric products generated for the study, as detailed in this paper, include Digital Elevation Models (DEMs), Digital Terrain Models (DTMs), orthomosaics (orthophotos), and others. At Sfântu Gheorghe beach, a comparison between 2023 and 2024 photogrammetric surveys revealed that the left bank of the Sf. Gheorghe Arm, at the river mouth into the Black Sea, suffered from a twist (erosion) of up to 64 metres. Additionally, on the selected perimetre (total area of 31,910 square meters ) from the beach and dune zone of Sf. Gheorghe, an area of up to 16,202 square meters was eroded between 2023 and 2024. This contrasts with the period between 2022 and 2023, during which deposition predominated. Erosion at the Danube mouths and the adjacent Black Sea coastline is driven by a complex interaction of natural and anthropogenic factors. Natural processes, including subsidence, sea-level rise, and episodic extreme storm events, contribute significantly to coastal dynamics. Meanwhile, human-induced factors, such as upstream hydrotechnical works that limits sediment transport, cutting of navigation canals, as well as the exacerbating effects of climate change, further accelerate erosion. The recent Structure-from-Motion (SfM) surveys provide essential quantitative data, enabling a detailed analysis of both short-term and long-term morphodynamic changes influenced by seasonal variations and extreme hydrometeorological events in this highly dynamic coastal system.

Sfȃntu Gheorghe Mouth (Danube Delta)↗
USGS2025

Review: The hydrogeology of critical mineral resources relevant to the energy transition

Attaining the goals of the international treaty on climate change (the Paris Agreement) will greatly increase the demand for the critical minerals required to implement clean-energy technologies. This poses both challenges and opportunities to the hydrogeologic community from several perspectives. Here, important insights that the hydrogeological sciences have to offer for mineral exploration, mineral production, and addressing environmental issues related to mining and mine decommissioning are summarized. This study focuses on copper, cobalt, lithium, and rare earths to represent the broad spectrum of critical minerals and illustrate their relevance by referring to projected demands and production rates. The current understanding of the hydrogeologic processes that form major deposits of these minerals are then summarized. Ore is defined as the naturally occurring material from which minerals of economic value can be extracted, where most ore deposits are the products of complex hydrogeologic couplings between fluid flow, heat transport, solute transport, chemical reactions, and mechanical deformation. Exploration models for the discovery of deeper, hidden deposits are potentially informed by hydrogeologic theory and hydrogeochemical processes. Hydrogeologic understanding and methods are also essential to production and recovery. Longstanding challenges are mine dewatering and (conversely) mine water supply, as well as mineral-extraction practices such as spoil heap leaching and in situ mining. New challenges arise from element extraction from subsurface brines. Finally, the quantity of water use and potential environmental impacts of mining on water quality are at the core of ‘social license’: the approval and acceptance of society to mining activities.

Hydrogeology Journal↗
USGS2026

Hydrothermal manganese-oxide mineralization of a carbonate ooze, Samoan hotspot region, South Pacific Ocean

Low-temperature hydrothermal manganese oxides occur throughout the global oceans. However, the hydrothermal replacement of a carbonate ooze by manganese oxides is described here for the first time. The 24 samples dredged from three locations around the Territory of American Samoa in the South Pacific Ocean include six samples with remnant carbonate and volcaniclastic sediments, which we refer to as “low Mn,” and 18 samples in which the mineralization is pervasive and has replaced most original sediment, termed “high Mn.” The 18 high-Mn samples exhibit a mean Mn content of 51 wt.%. Higher Li and Mn contents and lower Fe contents in the high-Mn samples indicate a hydrothermal origin and distinguish these samples from hydrogenetic ferromanganese crusts. Mn-oxide layers are up to 90 mm thick, some with columns to 44 mm long and 10 mm wide, the magnitude of which has not been described previously. Samples are composed of birnessite and 10 Å phyllomanganate minerals. Textures of the thickest Mn layers indicate mineralization below the seabed from ascending fluids during multiple hydrothermal pulses. Mineralization took place by complete to partial replacement and cementation of foraminiferal sediments intermixed with volcaniclastic sediments in varying amounts. Our results highlight the production of carbonate sediment-hosted hydrothermal Mn oxides from multiple hydrothermal sources within the Samoan volcanic chain. The potential extensive distribution on the regional scale of this newly described mineralization process and unique element enrichments raise questions about its broader distribution globally and potential importance to hydrothermal processes, element mass balance, and seabed mineral resources.

Geochemistry, Geophysics, Geosystems↗
USGS2024

From exploration to production: Understanding the development dynamics of lithium mining projects

Recently, there has been considerable recent controversy whether current and new lithium mines will be able to supply the rapidly growing needs of the electromobility transition. Mineral exploration projects are typically active for many years, and only some become operational mines. From exploration to production, the projects go through several stages of characterisation and evaluation. At each stage, decisions are made by companies and stakeholders to advance, continue or stop the project. This is a complex process, and even projects with very similar geological and technical characteristics may take very different trajectories, depending on external factors such as global market conditions and local regulatory environments. The present study investigates the dynamics of this process for lithium exploration projects. A global database of 397 lithium projects was compiled, covering their progression through major development stages between 2004 and 2022. Ordinal logistic regression was used for the statistical analysis of this data. Different explanatory variables were tested, including economic, geological, technical, and geographic factors, to identify the best predictors for project progress at each development stage. The results suggest an essential role for lithium carbonate prices, and a variable role for other factors at each stage. Critically, the already elapsed lead time and project economics, which are traditionally considered important for the prediction of the start-up of individual mines, do not appear to be relevant in all cases. The results provide important insights into the dynamics of lithium supply and may eventually allow more realistic forecasts to be made for future lithium market dynamics.

Resources Policy↗
USGS2025

Generalized Bancroft algorithm for locating earthquakes with P- and S-wave arrival times

Because of similarities between locating an earthquake with seismic stations and locating a Global Positioning System (GPS) receiver from satellites, the Bancroft algorithm developed for GPS processing can be used to locate earthquakes. Such an approach to earthquake location differs from the conventional method of choosing an initial or trial solution and then iteratively improving the solution until convergence. The Bancroft algorithm has the advantage of being a direct, noniterative solution but with the disadvantage of only being able to accommodate a homogeneous velocity model. An additional limitation of the standard Bancroft algorithm is that it considers arrival times in a medium with a single propagation velocity. This poses no problem for GPS processing because electromagnetic waves travel at the speed of light; however, for seismic waves it means the algorithm can be applied to collections of either P ‐ or S ‐wave arrival times. Here, I show how the Bancroft algorithm can be generalized to handle both P ‐ and S ‐wave arrival‐time measurements simultaneously. I also show how to accommodate depth‐varying P ‐ and S ‐wave velocity models. I apply the generalized Bancroft algorithm to microearthquakes beneath Tanaga Volcano in Alaska and compare standard locations from the widely used HYPOINVERSE location code to Bancroft locations and to the output of HYPOINVERSE when setting the trial location to the Bancroft location. I find the Bancroft locations outperform the results from the other methods for shallow earthquakes near sea level, where a quantity known as the geometric dilution of precision is large and linearized approaches such as HYPOINVERSE are expected to struggle.

Alaska↗
USGS2024

Prioritizing US Geological Survey science on salinization and salinity in candidate and selected priority river basins

The US Geological Survey (USGS) is selecting and prioritizing basins, known as Integrated Water Science basins, for monitoring and intensive study. Previous efforts to aid in this selection process include a scientifically defensible and quantitative assessment of basins facing human-caused water resource challenges (Van Metre et al. in Environmental Monitoring and Assessment , 192(7), 458 2020). In the present work, we explore this ranking process based on water quality considerations, specifically salinity and salinization. We selected top candidate basins to study salinity and salinization issues in 18 hydrologic regions that include 163 candidate basins. Our prioritization is based on quantitative assessment of sources of salinity, drivers of change, and receptors that must respond to those sources and drivers. Source terms represented in the prioritization include geology, depth to brackish groundwater, stream conductivity, chloride in precipitation, urban and agricultural land use, application of road salt as a deicer, and irrigation. Drivers represented in prioritization include changes in chemical weathering as a result of changes in rainwater chemistry. Receptors include measures of water stress, measurements of stream ecological health, and socioeconomic factors. In addition, we present research activities for the USGS on salinity and salinization that can be pursued in these basins including assessment of sources, pathways, and loadings; predicting and understanding changes in sources, peaks, and trends; understanding the components of salinity and mobilization of contaminants; understanding the relationship between salinization and changing ecosystems; and developing knowledge on the causes and distribution of groundwater salinity, brackish water resources, and challenges related to desalination.

Enviornmental Monitoring and Assessment↗
USGS2024

Stream nitrate dynamics driven primarily by discharge and watershed physical and soil characteristics at intensively monitored sites: Insights from deep learning

We developed a suite of models using deep learning to make hindcast predictions of the 7‐day average backward‐looking nitrate concentration at 46 predominantly agricultural sites across the midwestern and eastern United States. The models used daily observations of discharge and meteorological variables and watershed attributes describing anthropogenic modification to hydrology, nitrogen application, climate, groundwater, land use, watershed physiographic attributes, and soils. Across all sites, discharge and watershed soil and physiographic attributes showed a strong influence on model performance. Analysis of drivers across sites revealed considerable regional differences related to controlling processes such as groundwater contributions. We tested several ways to pool data across sites to develop accurate models and make the most effective use of available data. Single‐site models, in which models are trained and tested at a single location, showed generally strong predictive performance (median Kling‐Gupta Efficiency = 0.66), and accuracy at poorly performing sites could be improved by grouping sites with similar characteristics. Developing a single model for all sites reduced performance at several locations with distinct characteristics, suggesting that there is a threshold of dissimilarity beyond which more data does not improve the model. While many deep learning studies have shown that national or even global models can outperform local models, it is not clear that this is true for water quality constituents. This study demonstrates how data can be combined effectively, using deep learning to develop accurate and interpretable models of instream nitrate at sites where varying processes are responsible for changes in nitrate concentration.

Water Resources Research↗