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At least 109 records · Page 6Linked to original sources
USGS2013

Contribution of calcium oxalate to soil-exchangeable calcium

Acid deposition and repeated biomass harvest have decreased soil calcium (Ca) availability in many temperate forests worldwide, yet existing methods for assessing available soil Ca do not fully characterize soil Ca forms. To account for discrepancies in ecosystem Ca budgets, it has been hypothesized that the highly insoluble biomineral Ca oxalate might represent an additional soil Ca pool that is not detected in standard measures of soil-exchangeable Ca. We asked whether several standard method extractants for soil-exchangeable Ca could also access Ca held in Ca oxalate crystals using spike recovery tests in both pure solutions and soil extractions. In solutions of the extractants ammonium chloride, ammonium acetate, and barium chloride, we observed 2% to 104% dissolution of Ca oxalate crystals, with dissolution increasing with both solution molarity and ionic potential of cation extractant. In spike recovery tests using a low-Ca soil, we estimate that 1 M ammonium acetate extraction dissolved sufficient Ca oxalate to contribute an additional 52% to standard measurements of soil-exchangeable Ca. However, in a high-Ca soil, the amount of Ca oxalate spike that would dissolve in 1 M ammonium acetate extraction was difficult to detect against the large pool of exchangeable Ca. We conclude that Ca oxalate can contribute substantially to standard estimates of soil-exchangeable Ca in acid forest soils with low soil-exchangeable Ca. Consequently, measures of exchangeable Ca are unlikely to fully resolve discrepancies in ecosystem Ca mass balance unless the contribution of Ca oxalate to exchangeable Ca is also assessed.

Soil Science↗
USGS2021

The demographic contributions of connectivity versus local dynamics to population growth of an endangered bird

Conservation and management increasingly focus on connectivity, because connectivity driven by variation in immigration rates across landscapes is thought to be crucial for maintaining local population and metapopulation persistence. Yet, efforts to quantify the relative role of immigration on population growth across the entire range of species and over time have been lacking. We assessed whether immigration limited local and range‐wide population growth of the endangered snail kite Rostrhamus sociabilis in Florida, USA, over 18 years using multi‐state, reverse‐time modelling that accounts for imperfect detection of individuals and unobservable states. Demographic contributions of immigration varied depending on the dynamics and geographic position of the local populations, were scale‐dependent and changed over time. By comparing the relative contributions of immigration versus local demography for periods of significant change in local abundance, we found empirical evidence for a disproportionately large role of immigration in facilitating population growth of a centrally located population—a connectivity ‘hub’. The importance of connectivity changed depending of the spatial scale considered, such that immigration was a more important driver of population growth at small versus large spatial scales. Furthermore, the contribution of immigration was much greater during time periods when local population size was small, emphasizing abundance‐dependent rescue effects. Our findings suggest that efforts aimed at improving local breeding habitat will likely be most effective at increasing snail kite population growth. More broadly, our results provide much needed information on the role of connectivity for population growth, suggesting that connectivity conservation may have the greatest benefits when efforts focus on centrally located habitat patches and small populations. Furthermore, our results highlight that connectivity is highly dynamic over time and that interpreting the effects of connectivity at local scales may not transfer to region‐wide dynamics.

Florida↗
USGS2013

Relative contribution of lipid sources to eggs of lesser scaup

Studies of how birds mobilize nutrients to eggs have traditionally considered a continuum of possible allocation strategies ranging from income breeding (rely on food sources found on the breeding grounds) to capital breeding (rely on body reserves stored prior to the breeding season). For capital breeding, stored body reserves can be acquired either on or away from the breeding grounds, but it has been difficult to quantify the relative contribution of each, precluding identification of key habitats for acquiring nutrients for clutch formation. During 2006–2009, we explored the importance of spring-staging habitats versus breeding-area habitats for egg-lipid formation in female lesser scaup Aythya affinis using stable carbon (δ 13 C) isotope analyses. Although δ 13 C values for abdominal lipid reserves brought to the breeding grounds overlapped those of local amphipods, we were able to quantify the importance of local plant carbohydrates (seeds of emergent wetland plants) to the production of eggs. We compared the importance of local wetland seeds (overall δ 13 C: −29.1 ± 0.9‰ SD) to combined lipid stores and lipids from local amphipods (overall δ 13 C: −23.8 ± 2.2‰). Local seeds and stored body lipids contributed equally to egg lipid formation across years but we found evidence of annual variation in their relative importance. Wetland seeds contributed 39% (SE = 10%) to egg lipid production, and the importance of this source varied by year (90% CI = 47–75% in 2006, 13–42% in 2007, 29–65% in 2008, and 7–30% in 2009). In contrast to earlier studies that suggest lesser scaup predominantly employ a capital breeding strategy, our results suggest that in some years females may attain half of their energy for clutch formation from foods on the breeding grounds.

Journal of Avian Biology↗
USGS2005

Two- and three-dimensional pathline analysis of contributing areas to public-supply wells of Cape Cod, Massachusetts

Steady-state two- and three-dimensional ground-water-flow models coupled with particle tracking (fluid-particle pathline analysis) have been evaluated to determine their relative effectiveness in delineating contributing areas and particle traveltimes to public-supply wells in two contrasting stratified-drift aquifers of Cape Cod, Massachusetts. Several contributing areas delineated by the three-dimensional pathline analysis do not conform to simple ellipsoidal shapes that are typically delineated by use of two-dimensional analytical and numerical modeling techniques. They also include discontinuous areas of the water table and do not surround the supply wells. Because two-dimensional area! models do not account for vertical flow, they cannot adequately represent many of the hydrogeologic and well-design variables that complicate the delineation of contributing areas in three-dimensional flow systems on Cape Cod, including the presence and continuity of discrete zones of low hydraulic conductivity, large anisotropic ratios of horizontal to vertical hydraulic conductivity, partially penetrating supply wells, shallow streams and lakes, and low (less than about 0.1 million gallons per day) pumping rates.

Groundwater↗
USGS2004

Vulnerability of drinking-water wells in La Crosse, Wisconsin, to enteric-virus contamination from surface water contributions

Human enteric viruses can contaminate municipal drinking-water wells, but few studies have examined the routes by which viruses enter these wells. In the present study, the objective was to monitor the municipal wells of La Crosse, Wisconsin, for enteric viruses and determine whether the amount of Mississippi River water infiltrating the wells was related to the frequency of virus detection. From March 2001 to February 2002, one river water site and four wells predicted by hydrogeological modeling to have variable degrees of surface water contributions were sampled monthly for enteric viruses, microbial indicators of sanitary quality, and oxygen and hydrogen isotopes. 18O/ 16O and 2H/1H ratios were used to determine the level of surface water contributions. All samples were collected prior to chlorination at the wellhead. By reverse transcription-PCR (RT-PCR), 24 of 48 municipal well water samples (50%) were positive for enteric viruses, including enteroviruses, rotavirus, hepatitis A virus (HAV), and noroviruses. Of 12 river water samples, 10 (83%) were virus positive by RT-PCR. Viable enteroviruses were not detected by cell culture in the well samples, although three well samples were positive for culturable HAV. Enteroviruses detected in the wells by RT-PCR were identified as several serotypes of echoviruses and group A and group B coxsackieviruses. None of the well water samples was positive for indicators of sanitary quality, namely male-specific and somatic coliphages, total coliform bacteria, Escherichia coli, and fecal enterococci. Contrary to expectations, viruses were found in all wells regardless of the level of surface water contributions. This result suggests that there were other unidentified sources, in addition to surface water, responsible for the contamination.

Applied and Environmental Microbiology↗
USGS2025

Reproductive contribution of lake sturgeon transferred upstream of dams on a Great Lakes tributary

Dam construction contributes to declines in the distribution and abundance of many fishes. Increasing connectivity through adult transfer can be demographically and genetically beneficial, but assessing the effects resulting from transfer can be difficult if resident fish exist upstream. Genotypes of adult and larval lake sturgeon ( Acipenser fulvescens ) were used to quantify contributions to larval recruitment from adults transferred upstream of dams on the Menominee River, USA. We evaluated whether transfer timing, sex, and adult size were associated with the odds of reproduction. Elevator transfer operations in Fall 2019, Fall 2020, and Spring 2021 resulted in 152 male and 81 female lake sturgeon transferred upstream. In 2020 and 2021, 580 and 518 larvae were genotyped. We found that 86% (201/233) of adults reproduced and 62.3% (684/1098) of offspring had transferred parents. In total, we estimated that 392 resident adults contributed to offspring production. Mixed matings accounted for 53% of offspring genotyped, increasing levels of offspring genetic diversity relative to offspring produced from resident-only matings. Transferring adults may be a viable restoration alternative for other iteroparous fish in river systems where connectivity to spawning areas has been impeded.

Michigan, Wisconsin↗
USGS2012

Source rock contributions to the Lower Cretaceous heavy oil accumulations in Alberta: a basin modeling study

The origin of the immense oil sand deposits in Lower Cretaceous reservoirs of the Western Canada sedimentary basin is still a matter of debate, specifically with respect to the original in-place volumes and contributing source rocks. In this study, the contributions from the main source rocks were addressed using a three-dimensional petroleum system model calibrated to well data. A sensitivity analysis of source rock definition was performed in the case of the two main contributors, which are the Lower Jurassic Gordondale Member of the Fernie Group and the Upper Devonian–Lower Mississippian Exshaw Formation. This sensitivity analysis included variations of assigned total organic carbon and hydrogen index for both source intervals, and in the case of the Exshaw Formation, variations of thickness in areas beneath the Rocky Mountains were also considered. All of the modeled source rocks reached the early or main oil generation stages by 60 Ma, before the onset of the Laramide orogeny. Reconstructed oil accumulations were initially modest because of limited trapping efficiency. This was improved by defining lateral stratigraphic seals within the carrier system. An additional sealing effect by biodegraded oil may have hindered the migration of petroleum in the northern areas, but not to the east of Athabasca. In the latter case, the main trapping controls are dominantly stratigraphic and structural. Our model, based on available data, identifies the Gordondale source rock as the contributor of more than 54% of the oil in the Athabasca and Peace River accumulations, followed by minor amounts from Exshaw (15%) and other Devonian to Lower Jurassic source rocks. The proposed strong contribution of petroleum from the Exshaw Formation source rock to the Athabasca oil sands is only reproduced by assuming 25 m (82 ft) of mature Exshaw in the kitchen areas, with original total organic carbon of 9% or more.

Alberta↗
USGS1994

Problems of stock definition in estimating relative contributions of Atlantic striped bass to the coastal fishery

Stock contribution studies of mixed‐stock fisheries rely on the application of classification algorithms to samples of unknown origin. Although the performance of these algorithms can be assessed, there are no guidelines regarding decisions about including minor stocks, pooling stocks into regional groups, or sampling discrete substocks to adequately characterize a stock. We examined these questions for striped bass Morone saxatilis of the U.S. Atlantic coast by applying linear discriminant functions to meristic and morphometric data from fish collected from spawning areas. Some of our samples were from the Hudson and Roanoke rivers and four tributaries of the Chesapeake Bay. We also collected fish of mixed‐stock origin from the Atlantic Ocean near Montauk, New York. Inclusion of the minor stock from the Roanoke River in the classification algorithm decreased the correct‐classification rate, whereas grouping of the Roanoke River and Chesapeake Bay stock into a regional (“southern”) group increased the overall resolution. The increased resolution was offset by our inability to obtain separate contribution estimates of the groups that were pooled. Although multivariate analysis of variance indicated significant differences among Chesapeake Bay substocks, increasing the number of substocks in the discriminant analysis decreased the overall correct‐classification rate, Although the inclusion of one, two, three, or four substocks in the classification algorithm did not greatly affect the overall correct‐classification rates, the specific combination of substocks significantly affected the relative contribution estimates derived from the mixed‐stock sample, Future studies of this kind must balance the costs and benefits of including minor stocks and would profit from examination of the variation in discriminant characters among all Chesapeake Bay substocks.

Maryland↗
USGS1916

Contributions to economic geology (short papers and preliminary reports), 1915: Part I. - metals and nonmetals except fuels

This volume is the thirteenth of a series that includes Bulletins 213, 225, 260, 285, 315, 340, 380, 430, 470, 530, 540, and 580, "Contributions to economic geology" for 1902, 1903, 1904, 1905, 1906 (Pt. I), 1907 (Pt. I), 1908 (Pt. I), 1909 (Pt. I), 1910 (P t. I), 1911 (Pt. I) , 1912 (Pt. I), and 1913 (Pt. I), respectively . These bulletins are prepared primarily to insure prompt publication of the economic results of investigations made by the United States Geological Survey. Beginning with the present volume the year included in the title will be the year of publication 1 instead of the year in which the field work reported was done. This volume is therefore dated 1915, and there will be no volume entitled "Contributions to economic geology, 1914." As the subtitle indicates, the papers included are of two classes -(1) short papers giving comparatively detailed description of occurrences that have economic interest but are not of sufficient importance to warrant a more extended description; (2) preliminary reports on economic investigations the results of which are to be published later in more detailed form. These papers are such only as have a direct economic bearing, all topic of purely scientific interest being excluded. Each paper has been issued as an advance chapter as soon as it was ready. Brief abstracts of the publications of the year are given in the annual report of the Director. The complete list of Survey publications affords, by means of finding list of subjects and of authors, further aid in ascertaining the extent of the Survey's work in economic geology. Since 1905 the annual economic bulletin has been printed in two parts, the second part comprising paper on mineral fuels. These volumes for 1906, 1907, 190 , 1909, 1910, 1911, 1912, and 1913 are Bulletins 316, 341, 381, 431, 471, 531, 541, and 581. Bulletin 621 forms Part II of the "Contributions" for 1915. The reports on work in Alaska have been printed in a separate series since 1904, the volume so far issued being Bulletins 259, 284, 314, 345, 379, 442, 480, 520, 542, 592, and 622.

Bulletin↗
USGS1919

Contributions to economic geology, 1918, Part I, Metals and nonmetals except fuel

The Survey's "Contributions to economic geology " have been published annually since 1902. In 1906 the increase in the number of papers coming under this (Classification made it necessary to divide the contributions into two parts, one including, papers on metals and nonmetals except fuels and the other including papers on mineral fuels. In 1915 the year included in the title was changed from the year in which the field work reported in these papers was done to the year of publication, and in consequence there was no volume entitled "Contributions to economic geology, 1914.” The subjoined table gives a summary of these bulletins. As the subtitle indicates, the papers included in these volumes are of two classes (1) short papers giving comparatively detailed descriptions of occurrences that have economic interest but are not of sufficient importance to warrant a more extended description; (2) preliminary reports on economic investigations the results of which are to be published later in more detailed form. These papers are such only as Have a direct economic bearing, all topics of purely scientific interest being excluded. Brief abstracts of the publications of the year are given in the annual report of the Director. The complete list of Survey publications affords, by means of finding lists of subjects and of authors, further aid in ascertaining the extent of the Survey's work in economic geology. The reports on work in Alaska have been printed in a separate series since 1904, the volumes so far issued being Bulletins 259, 284, 314, 345, 379, 442, 480, 520, 542, 592, 622, 642, and 662.

Bulletin↗
USGS1998

Estimating areas contributing recharge to wells, lessons from previous studies

Factors relating to the estimation of areas contributing recharge to wells, such as complexity of the ground-water flow system, effects of changing hydrologic conditions, and effects of well-screen locations and pumping rates, are reviewed. The point of view that simulation is the best means to obtain physically based estimates of contributing areas is emphasized. An extensive list of USGS reports that include estimation of contributing areas is provided.

Circular↗
USGS2014

Delineation of contributing areas to selected wells in Ingham County, Michigan

A groundwater-flow model that was constructed in 2009 was updated to reflect recent (2011–12) pumping conditions in the Tri-County region, which consists of Clinton, Eaton, and Ingham Counties, Michigan. As part of local wellhead protection area programs, areas contributing water to local production wells must be periodically updated, because groundwater-flow paths depend in part on the stresses, such as groundwater withdrawals, to the groundwater-flow system. For this current (2013) study, withdrawals from selected city of Lansing production wells were updated, and simulated heads and flows under the new pumping conditions compared favorably to previously measured values. Results of flow simulations indicate that 10-year time-of-travel contributing areas cover approximately 19.4 square miles, and 40-year time-of-travel contributing areas cover approximately 39 square miles.

Michigan↗
USGS2020

Simulation of the probabilistic plume extent for a potential replacement wastewater-infiltration lagoon, and probabilistic contributing areas for supply wells for the Town of Lac du Flambeau, Vilas County, Wisconsin

An existing two-dimensional, steady-state groundwater-flow model of the shallow groundwater-flow system of the Lac du Flambeau Reservation in Vilas County, Wisconsin, originally developed by the U.S. Geological Survey, was used to simulate the potential for wastewater from a proposed relocation of a wastewater lagoon to contaminate the Lac du Flambeau Band of Lake Superior Chippewa’s drinking-water-supply wells. This simulation was completed by the U.S. Geological Survey in cooperation with the Lac du Flambeau Band of Lake Superior Chippewa and Indian Health Service. The simulated scenarios consisted of removing wastewater infiltration from existing lagoons and re-applying that infiltration at the proposed location. Two analyses were performed for the scenarios. First, the probable extent of the plume discharging from the proposed infiltration lagoons was mapped with a Monte Carlo algorithm that used uncertainty identified during the calibration process to simulate thousands of possible outcomes. Second, the Monte Carlo method was again used to simulate a probabilistic contributing area for the Tribe’s nearby “Main Pumphouse” supply wells. The purpose of the simulations was to evaluate the potential for infiltrated wastewater to be captured by the public-supply wells. Most features of the previously developed model remained unchanged, including calibrated parameters such as hydraulic conductivity and recharge. Thus, the same covariance distributions that were generated during calibration of the regional model (Juckem and others, 2014) remained unchanged and were used to inform the Monte Carlo simulations for the scenario simulations described in this report. The reader is encouraged to read the full report by Juckem and others (available at https://doi.org/10.3133/sir20145020 ) for a detailed description of the model design and calibration, as well as a description of the Monte Carlo method, its limitations, and the original results. Results for these new scenarios indicate that the probabilistic plume extent for the proposed infiltration lagoons does not reach the Main Pumphouse wells using pumping rates and wastewater volumes estimated for 2010. Similarly, the contributing area for the Main Pumphouse wells does not capture water from within the proposed infiltration lagoon footprint. However, at higher pumping rates and wastewater volumes, as projected by the Tribe for about 2035, the contributing area for the Main Pumphouse wells do include particles that originated within the proposed lagoon footprint, albeit at low probabilities. That is, for a few of the thousands of simulations that represented a range of calibration-informed parameter covariances, some amount of infiltrated wastewater was captured by the Main Pumphouse wells under projected 2035 conditions.

Wisconsin↗
USGS1994

Particle-tracking analysis of contributing areas of public-supply wells in simple and complex flow systems, Cape Cod, Massachusetts

Steady-state, two-and three-dimensional, ground-water flow models coupled with a particle- tracking program were evaluated to determine their effectiveness in delineating contributing areas of existing and hypothetical public-supply wells pumping from two contrasting stratified-drift aquifers of Cape Cod, Mass. Several of the contri- buting areas delineated by use of the three- dimensional models do not conform to simple ellipsoidal shapes that are typically delineated by use of a two-dimensional analytical and numerical modeling techniques, include dis- continuous areas of the water table, and do not surround the wells. Because two-dimensional areal models do not account for vertical flow, they cannot adequately represent many of the hydro- geologic and well-design variables that were shown to complicate the delineation of contributing areas in these flow systems, including the presence of discrete lenses of 1ow hydraulic conductivity, large ratios of horizontal to ver- tical hydraulic conductivity, shallow streams, partially penetrating supply wells, and 1ow pumping rates (less than 0.1 million gallons per day). Nevertheless, contributing areas delineated for two wells in the simpler of the two flow systems--a thin (less than 100 feet), single- layer, uniform aquifer with near-ideal boundary conditions--were not significantly different for the two- or three-dimensional models of the natural system, for a pumping rate of 0.5 million gallons per day. Use of particle tracking helped identify the source of water to simulated wells, which included precipitation recharge, wastewater return flow, and pond water. Pond water and wastewater return flow accounted for as much as 73 and 40 percent, respectively, of the water captured by simulated wells.

Massachusetts↗
USGS2004

Hydrogeology and water quality of the Pepacton Reservoir Watershed in southeastern New York. Part 4. Quantity and quality of ground-water and tributary contributions to stream base flow in selected main-valley reaches

Estimates of the quantity and quality of ground-water discharge from valley-fill deposits were calculated for nine valley reaches within the Pepacton watershed in southeastern New York in July and August of 2001. Streamflow and water quality at the upstream and downstream end of each reach and at intervening tributaries were measured under base-flow conditions and used in mass-balance equations to determine quantity and quality of ground-water discharge. These measurements and estimates define the relative magnitudes of upland (tributary inflow) and valley-fill (ground-water discharge) contributions to the main-valley streams and provide a basis for understanding the effects of hydrogeologic setting on these contributions. Estimates of the water-quality of ground-water discharge also provide an indication of the effects of road salt, manure, and human wastewater from villages on the water quality of streams that feed the Pepacton Reservoir. The most common contaminant in ground-water discharge was chloride from road salt; concentrations were less than 15 mg/L. Investigation of ground-water quality within a large watershed by measurement of stream base-flow quantity and quality followed by mass-balance calculations has benefits and drawbacks in comparison to direct ground-water sampling from wells. First, sampling streams is far less expensive than siting, installing, and sampling a watershed-wide network of wells. Second, base-flow samples represent composite samples of ground-water discharge from the most active part of the ground-water flow system across a drainage area, whereas a well network would only be representative of discrete points within local ground-water flow systems. Drawbacks to this method include limited reach selection because of unfavorable or unrepresentative hydrologic conditions, potential errors associated with a large number of streamflow and water-quality measurements, and limited ability to estimate concentrations of nonconservative constituents such as nutrients. The total gain in streamflow from the upper end to the lower end of each valley reach was positively correlated with the annual-runoff volume calculated for the drainage area of the reach. This correlation was not greatly affected by the proportions of ground-water and tributary contributions, except at two reaches that lost much of their tributary flow after the July survey. In these reaches, the gain in total streamflow showed a negative departure from this correlation. Calculated ground-water discharge exceeded the total tributary inflow in each valley reach in both surveys. Groundwater discharge, as a percentage of streamflow gain, was greatest among reaches in wide valleys (about 1,000-ft wide valley floors) that contain permeable valley fill because tributary flows were seasonally diminished or absent as a result of streambed infiltration. Tributary inflows, as a percentage of streamflow gain, were highest in reaches of narrow valleys (200-500-ft wide valley floors) with little valley fill and high annual runoff. Stream-water and ground-water quality were characterized by major-ion type as either (1) naturally occurring water types, relatively unaffected by road salt, or (2) road-salt-affected water types having elevated concentrations of chloride and sodium. The naturally occurring waters were typically the calcium-bicarbonate type, but some contained magnesium and (or) sulfate as secondary ions. Magnesium concentration in base flow is probably related to the amount of till and its carbonate content, or to the amount of lime used on cultivated fields within a drainage area. Sulfate was a defining ion only in dilute waters (with short or unreactive flow paths) with low concentrations of bicarbonate. Nearly all tributary waters were classified as naturally occurring water types. Ground-water discharge from nearly all valley reaches that contain State or county highways had elevated concentrations of chloride and sodsodium. The mean chloride concentrations of ground-water discharge--from 8 to 13 milligrams per liter--did not exceed Federal or State standards, but were about 5 times higher than naturally occurring levels. Application of road salt along a valley bottom probably affects only the shallow ground water in the area between a road and a stream. The elevated concentrations of chloride and sodium in the base-flow samples from such reaches indicate that the concentrations in the affected ground water were high enough to offset the low concentrations in all unaffected ground water entering the reach. Nutrient (nitrate and orthophosphate) concentrations in base-flow samples collected throughout the valleyreach network could not generally be used to estimate their concentrations in ground-water discharge because these constituents can be transformed or removed from water through biological uptake, transformation, or by adsorption on sediments. Base-flow samples from streams with upgradient manure sources or villages served by septic systems consistently had the highest concentrations of these nutrients.

Scientific Investigations Report↗
USGS2007

Hydrogeologic investigation, water chemistry analysis, and model delineation of contributing areas for City of Tallahassee public-supply wells, Tallahassee, Florida

Ground water from the Upper Floridan aquifer is the sole source of water supply for Tallahassee, Florida, and the surrounding area. The City of Tallahassee (the City) currently operates 28 water-supply wells; 26 wells are distributed throughout the City and 2 are located in Woodville, Florida. Most of these wells yield an ample supply of potable water; however, water from several wells has low levels of tetrachloroethylene (PCE). The City removes the PCE from the water by passing it through granular-activated carbon units before distribution. To ensure that water-supply wells presently free of contamination remain clean, it is necessary to understand the ground-water flow system in sufficient detail to protect the contributing areas. Ground-water samples collected from four public-supply wells were analyzed for tritium ( 3 H), chlorofluorocarbons (CFCs), and sulfur hexafluoride (SF 6 ). Using data for the CFC compounds, apparent ground-water ages ranged from 7 to 31 years. For SF 6 , the apparent ages tended to be about 5 to 10 years younger than those from CFCs. Apparent ages based on the tritium/tritiogenic helium-3 ( 3 H/ 3 He trit ) method ranged from 26 to 33 years. The three dating methods indicate that the apparent age of ground water generally decreases from northern to southern Leon County. This southward trend of decreasing ages is consistent with increasing amounts of recharge that occur as ground water moves from north to south. The ground-water age data derived by geochemical and tracer analyses were used in combination with the flow model and particle tracking to determine an effective porosity for the Hawthorn clays and Upper Floridan aquifer. The effective porosities for the Upper Floridan aquifer that resulted in best model matches were averaged to produce an effective porosity of 7 percent, and the effective porosities for the Hawthorn clays that resulted in a match were averaged to produce an effective porosity of 22 percent. Probabilistic contributing areas were determined for 26 City wells using MODFLOW and MODPATH. For each probabilistic contributing area delineated, the model was run 100 times and the results were analyzed statistically. For each of the 100 runs, a different hydraulic conductivity for each of the zones was assigned to the Upper Floridan aquifer. The hydraulic conductivities were generated randomly assuming a lognormal probability distribution; the mean of the distribution was equal to the hydraulic conductivity from the calibrated model. The 5-year time-dependent capture zones (TDCZs), assuming effective porosities of 0.1, 1, and 7 percent for four representative wells, were delineated. The higher probabilities of capture (greater than 40, 60, and 80 percent) were similar for all effective porosities, and the TDCZ delineated using a 7-percent porosity was slightly smaller; the lower probabilities of capture (greater than 10 and 20 percent) showed a large range of variability.

Florida↗
USGS2007

Evaluation of the Contributing Area for Recovery Wells at the Naval Industrial Reserve Ordnance Plant, Fridley, Minnesota

The Naval Industrial Reserve Ordnance Plant is located on the southernmost tip of Anoka County, Minnesota, within the City of Fridley, and about one-quarter mile east of the Mississippi River. Industrial production at the plant began in 1941 and has continued since that time. Contamination spills and poor disposal practices in the past have led to significant ground-water contamination beneath the facility. A ground-water recovery (and containment) system began operation in 1992 to prevent contaminated ground-water from migrating off site. In an effort to determine the effectiveness of the recovery system, pressure transducers were installed in 23 monitoring wells, multiple hand water-level measurements were taken in an additional 56 wells, and two extensive rounds of water-level measurements were taken in all wells (one during pumping and one during non-pumping conditions). The cones of depression of the shallow flow zone wells AT-8 (17 gallons per minute (gal/min) and AT-9 (142 gal/min) overlap to form one broad cone, while the cone of depression of well AT-7 (42 gal/min) was more isolated. Shallow flow zone well AT-5A (156 gal/min) had a large, broad cone of depression which was the result of the relatively high pumping rate and the relatively high permeability of 200 feet per day (ft/d). Intermediate flow zone well AT-3A (182 gal/min) had a broad cone of depression that extended to the intermediate clays; well AT-10 (23 gal/min) had a relatively steep cone because it was screened in a relatively low-permeability zone. Deep flow zone well AT-5B (86 gal/min) had a broad cone of depression. Intermediate well AT-3A appears to be drawing water up vertically out of the deep flow zone. The combined contributing areas of recovery wells AT-7, AT-8, and AT-9 capture the high levels of trichloroethene (TCE) contamination (greater than 100 parts per billion (ppb) along their combined axis. Well AT-5A has a broad contributing area that reaches approximately halfway to the Mississippi River and captures the eastern flank of the highest levels of contamination in the shallow zone; but it does not capture the highest levels that will still discharge to the Mississippi River. The combined contributing areas of wells AT-3A and AT-10 should capture the TCE contamination in the intermediate zone that is moving off site. Well AT-5B captures about a third of the TCE contamination in the deep flow zone where the concentration exceeds 100 ppb.

Scientific Investigations Report↗
USGS2009

Aquifer chemistry and transport processes in the zone of contribution to a public-supply well in Woodbury, Connecticut, 2002-06

A glacial aquifer system in Woodbury, Connecticut, was studied to identify factors that affect the groundwater quality in the zone of contribution to a community public-supply well. Water samples were collected during 2002-06 from the public-supply well and from 35 monitoring wells in glacial stratified deposits, glacial till, and fractured bedrock. The glacial aquifer is vulnerable to contamination from a variety of sources due to the short groundwater residence times and the urban land use in the contributing recharge area to the public-supply well. The distribution and concentrations of pH, major and trace elements, stable isotope ratios, recharge temperatures, dissolved organic carbon (DOC), and volatile organic compounds (VOCs), and the oxidation-reduction (redox) conditions, were used to identify recharge source areas, aquifer source material, anthropogenic sources, chemical processes, and groundwater-flow paths from recharge areas to the public-supply well, PSW-1. The major chemical sources to groundwater and the tracers or conditions used to identify them and their processes throughout the aquifer system include (1) bedrock and glacial stratified deposits and till, characterized by high pH and concentrations of sulfate (SO42-), bicarbonate, uranium (U), radon-222, and arsenic (As) relative to those of other wells, reducing redox conditions, enriched delta sulfur-34 (d34S) and delta carbon-13 (d13C) values, depleted delta oxygen-18 (d18O) and delta deuterium (dD) values, calcite near saturation, low recharge temperatures, and groundwater ages of more than about 9 years; (2) natural organic matter, either in sediments or in an upgradient riparian zone, characterized by high concentrations of DOC or manganese (Mn), low concentrations of dissolved oxygen (DO) and nitrate (NO3-), enriched d34S values, and depleted d18O and dD values; (3) road salt (halite), characterized by high concentrations of sodium (Na), chloride (Cl-), and calcium (Ca), and indicative chloride/bromide (Cl:Br) mass concentration ratios; (4) septic-system leachate, characterized by high concentrations of NO3-, DOC, Na, Cl-, Ca, and boron (B), delta nitrogen-15 (d15N) and d18O values, and indicative Cl:Br ratios; (5) organic solvent spills, characterized by detections of perchloroethene (PCE), trichloroethene (TCE), and 1,1-dichloroethene (1,1-DCE); (6) gasoline station spills, characterized by detections of fuel oxygenates and occasionally benzene; and (7) surface-water leakage, characterized by enriched d18O and dD values and sometimes high DOC and Mn-reducing conditions. Evaluation of Cl- concentrations and Cl:Br ratios indicates that most samples were composed of mixtures of groundwater and some component of road salt or septic-system leachate. Leachate from septic-tank drainfields can cause locally anoxic conditions with NO3- concentrations of as much as 19 milligrams per liter (mg/L as N) and may provide up to 15 percent of the nitrogen in water from well PSW-1, based on mixing calculations with d15N of NO3-. Most of the water that contributes to PSW-1 is young (less than 7 years) and derived from the glacial stratified deposits. Typically, groundwater is oxic, but localized reducing zones that result from abundances of organic matter can affect the mobilization of trace elements and the degradation of VOCs. Groundwater from fractured bedrock beneath the valley bottom, which is old (more than 50 years), and reflects a Mn-reducing to methanic redox environment, constitutes as much as 6 percent of water samples collected from monitoring wells screened at the bottom of the glacial aquifer. Dissolved As and U concentrations generally are near the minimum reporting level (MRL) (0.2 micrograms per liter or ?g/L and 0.04 ?g/L, respectively), but water from a few wells screened in glacial deposits, likely derived from underlying organic-rich Mesozoic rocks, contain As concentrations up to 7 ?g/L. At one location, concentrations of As and U were high

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