Search USGS⌕ Search

SEARCH · Search USGS

Results for “Environment and Health”

Search indexed USGS publications on groundwater, aquifers, geologic maps, mineral resources and earthquakes. Explore source records by subject and place.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 91 records · Page 5Linked to original sources
USGS2010

Assessment of Energetic Compounds, Semi-volatile Organic Compounds, and Trace Elements in Streambed Sediment and Stream Water from Streams Draining Munitions Firing Points and Impact Areas, Fort Riley, Kansas, 2007-08

An assessment of energetic compounds (explosive and propellant residues) and associated semi-volatile organic compounds (SVOCs) and trace elements in streambed sediment and stream water from streams draining munitions firing points and impact areas at Fort Riley, northeast Kansas, was performed during 2007-08 by the U.S. Geological Survey (USGS) in cooperation with the U.S. Army. Streambed sediment from 16 sampling sites and stream-water samples from 5 sites were collected at or near Fort Riley and analyzed for as many as 17 energetic compounds, 65 SVOCs, and 27 trace elements. None of the energetic compounds or SVOCs were detected in streambed sediment collected from sites within the Fort Riley Military Reservation. This may indicate that these compounds either are not transported from dispersal areas or that analytical methods are not sensitive enough to detect the small concentrations that may be transported. Concentrations of munitions-associated trace elements did not exceed sediment-quality guidelines recommended by the U.S. Environmental Protection Agency (USEPA) and are not indicative of contamination of streambed sediment at selected streambed sampling sites, at least in regards to movement from dispersal areas. Analytical results of stream-water samples provided little evidence of contamination by energetic compounds, SVOCs, or associated trace elements. Perchlorate was detected in 19 of 20 stream-water samples at concentrations ranging from an estimated 0.057 to an estimated 0.236 ug/L (micrograms per liter) with a median concentration of an estimated 0.114 ug/L, substantially less than the USEPA Interim Health Advisory criterion (15 ug/L), and is in the range of documented background concentrations. Because of these small concentrations and possible natural sources (precipitation and groundwater), it is likely that the occurrence of perchlorate in stream water is naturally occurring, although a definitive identification of the source of perchlorate in stream water at Fort Riley is difficult. The only SVOCs detected in stream-water samples were bis(2-ethylhexyl) phthalate and di-n-butyl phthalate but at concentrations substantially less than the most stringent aquatic-life criteria established by the Kansas Department of Health and Environment. All trace element concentrations in stream-water samples were less than the most stringent aquatic-life criteria. The implication of these stream-water results is that contamination arising from firing-range activities, if it exists, is so small as to be nondetectable with current analytical methods or is not distinguishable from background concentrations for constituents that also are naturally occurring. Overall, the munitions-related constituents analyzed in streambed sediment and stream water, when detected, were at concentrations that were less than regulatory criteria

Scientific Investigations Report↗
USGS2010

Comparison of mercury in water, bottom sediment, and zooplankton in two Front Range reservoirs in Colorado, 2008-09

The U.S. Geological Survey, in cooperation with the Colorado Department of Public Health and Environment, conducted a study to investigate environmental factors that may contribute to the bioaccumulation of mercury in two Front Range reservoirs. One of the reservoirs, Brush Hollow Reservoir, currently (2009) has a fish-consumption advisory for mercury in walleye (Stizostedion vitreum), and the other, Pueblo Reservoir, which is nearby, does not. Water, bottom sediment, and zooplankton samples were collected during 2008 and 2009, and a sediment-incubation experiment was conducted in 2009. Total mercury concentrations were low in midlake water samples and were not substantially different between the two reservoirs. The only water samples with detectable methylmercury were collected in shallow areas of Brush Hollow Reservoir during spring. Mercury concentrations in reservoir bottom sediments were similar to those reported for stream sediments from unmined basins across the United States. Despite higher concentrations of fish-tissue mercury in Brush Hollow Reservoir, concentrations of methylmercury in sediment were as much as 3 times higher in Pueblo Reservoir. Mercury concentrations in zooplankton were at the low end of concentrations reported for temperate lakes in the Northeastern United States and were similar between sites, which may reflect the seasonal timing of sampling. Factors affecting bioaccumulation of mercury were assessed, including mercury sources, water quality, and reservoir characteristics. Atmospheric deposition was determined to be the dominant source of mercury; however, due to the proximity of the reservoirs, atmospheric inputs likely are similar in both study areas. Water-quality constituents commonly associated with elevated concentrations of mercury in fish (pH, alkalinity, sulfate, nutrients, and dissolved organic carbon) did not appear to explain differences in fish-tissue mercury concentrations between the reservoirs. Low methylmercury concentrations in hypolimnetic water indicate low potential for increased methylmercury production following the development of anoxic conditions in summer. Based on the limited dataset, water-level fluctuations and shoreline characteristics appear to best explain differences in fish-tissue mercury concentrations between the reservoirs. Due to the shallow depth and the large annual water-level fluctuations at Brush Hollow Reservoir, proportionally larger areas of shoreline at Brush Hollow Reservoir are subjected to annual reflooding compared to Pueblo Reservoir. Moreover, presence of macrophyte beds and regrowth of terrestrial vegetation likely increase the organic content of near-shore sediments in Brush Hollow Reservoir, which may stimulate methylmercury production in littoral areas subject to reflooding. Results of a laboratory incubation experiment were consistent with this hypothesis.

Colorado↗
USGS2011

Use of diverse geochemical data sets to determine sources and sinks of nitrate and methane in groundwater, Garfield County, Colorado, 2009

Previous water-quality assessments reported elevated concentrations of nitrate and methane in water from domestic wells screened in shallow zones of the Wasatch Formation, Garfield County, Colorado. In 2009, the U.S. Geological Survey, in cooperation with the Colorado Department of Public Health and Environment, analyzed samples collected from 26 domestic wells for a diverse set of geochemical tracers for the purpose of determining sources and sinks of nitrate and methane in groundwater from the Wasatch Formation. Nitrate concentrations ranged from less than 0.04 to 6.74 milligrams per liter as nitrogen (mg/L as N) and were significantly lower in water samples with dissolved-oxygen concentrations less than 0.5 mg/L than in samples with dissolved-oxygen concentrations greater than or equal to 0.5 mg/L. Chloride/bromide mass ratios and tracers of groundwater age (tritium, chlorofluorocarbons, and sulfur hexafluoride) indicate that septic-system effluent or animal waste was a source of nitrate in some young groundwater (less than 50 years), although other sources such as fertilizer also may have contributed nitrate to the groundwater. Nitrate and nitrogen gas (N2) concentrations indicate that denitrification was the primary sink for nitrate in anoxic groundwater, removing 99 percent of the original nitrate content in some samples that had nitrate concentrations greater than 10 mg/L as N at the time of recharge. Methane concentrations ranged from less than 0.0005 to 32.5 mg/L and were significantly higher in water samples with dissolved-oxygen concentrations less than 0.5 mg/L than in samples with dissolved-oxygen concentrations greater than or equal to 0.5 mg/L. High methane concentrations (greater than 1 mg/L) in some samples were biogenic in origin and appeared to be derived from a relatively deep source on the basis of helium concentrations and isotopic data. One such sample had water-isotopic and major-ion compositions similar to that of produced water from the underlying Mesaverde Group, which was the primary natural-gas producing interval in the study area. Methane in the Mesaverde Group was largely thermogenic in origin so biogenic methane in the sample probably was derived from deeper zones in the Wasatch Formation. The primary methane sink in the aquifer appeared to be methane oxidation on the basis of dissolved-oxygen and methane concentrations and methane isotopic data. The diverse data sets used in this study enhance previous water-quality assessments by providing new and more complete insights into the sources and sinks of nitrate and methane in groundwater. Field measurements of dissolved oxygen in groundwater were useful indicators of the Wasatch Formation's vulnerability to nitrate and methane contamination or enrichment. Results from this study also provide new evidence for the movement of water, ions, and gases into the shallow Wasatch Formation from sources such as the Mesaverde Group and deeper Wasatch Formation.

Scientific Investigations Report↗
USGS2011

Hydrogeologic setting and simulation of groundwater flow near the Canterbury and Leadville Mine Drainage Tunnels, Leadville, Colorado

The Leadville mining district is historically one of the most heavily mined regions in the world producing large quantities of gold, silver, lead, zinc, copper, and manganese since the 1860s. A multidisciplinary investigation was conducted by the U.S. Geological Survey, in cooperation with the Colorado Department of Public Health and Environment, to characterize large-scale groundwater flow in a 13 square-kilometer region encompassing the Canterbury Tunnel and the Leadville Mine Drainage Tunnel near Leadville, Colorado. The primary objective of the investigation was to evaluate whether a substantial hydraulic connection is present between the Canterbury Tunnel and Leadville Mine Drainage Tunnel for current (2008) hydrologic conditions. Altitude in the Leadville area ranges from about 3,018 m (9,900 ft) along the Arkansas River valley to about 4,270 m (14,000 ft) along the Continental Divide east of Leadville, and the high altitude of the area results in a moderate subpolar climate. Winter precipitation as snow was about three times greater than summer precipitation as rain, and in general, both winter and summer precipitation were greatest at higher altitudes. Winter and summer precipitation have increased since 2002 coinciding with the observed water-level rise near the Leadville Mine Drainage Tunnel that began in 2003. The weather patterns and hydrology exhibit strong seasonality with an annual cycle of cold winters with large snowfall, followed by spring snowmelt, runoff, and recharge (high-flow) conditions, and then base-flow (low-flow) conditions in the fall prior to the next winter. Groundwater occurs in the Paleozoic and Precambrian fractured-rock aquifers and in a Quaternary alluvial aquifer along the East Fork Arkansas River, and groundwater levels also exhibit seasonal, although delayed, patterns in response to the annual hydrologic cycle. A three-dimensional digital representation of the extensively faulted bedrock was developed and a geophysical direct-current resistivity field survey was performed to evaluate the geologic structure of the study area. The results show that the Canterbury Tunnel is located in a downthrown structural block that is not in direct physical connection with the Leadville Mine Drainage Tunnel. The presence of this structural discontinuity implies there is no direct groundwater pathway between the tunnels along a laterally continuous bedrock unit. Water-quality results for pH and major-ion concentrations near the Canterbury Tunnel showed that acid mine drainage has not affected groundwater quality. Stable-isotope ratios of hydrogen and oxygen in water indicate that snowmelt is the primary source of groundwater recharge. On the basis of chlorofluorocarbon and tritium concentrations and mixing ratios for groundwater samples, young groundwater (groundwater recharged after 1953) was indicated at well locations upgradient from and in a fault block separate from the Canterbury Tunnel. Samples from sites downgradient from the Canterbury Tunnel were mixtures of young and old (pre-1953) groundwater and likely represent snowmelt recharge mixed with older regional groundwater that discharges from the bedrock units to the Arkansas River valley. Discharge from the Canterbury Tunnel contained the greatest percentage of old (pre-1953) groundwater with a mixture of about 25 percent young water and about 75 percent old water. A calibrated three-dimensional groundwater model representing high-flow conditions was used to evaluate large-scale flow characteristics of the groundwater and to assess whether a substantial hydraulic connection was present between the Canterbury Tunnel and Leadville Mine Drainage Tunnel. As simulated, the faults restrict local flow in many areas, but the fracture-damage zones adjacent to the faults allow groundwater to move along faults. Water-budget results indicate that groundwater flow across the lateral edges of the model controlled the majority of flow in and out of the aquifer (79 percent and 63 percent of the total water budget, respectively). The largest contributions to the water budget were groundwater entering from the upper reaches of the watershed and the hydrologic interaction of the groundwater with the East Fork Arkansas River. Potentiometric surface maps of the simulated model results were generated for depths of 50, 100, and 250 m. The surfaces revealed a positive trend in hydraulic head with land-surface altitude and evidence of increased control on fluid movement by the fault network structure at progressively greater depths in the aquifer. Results of advective particle-tracking simulations indicate that the sets of simulated flow paths for the Canterbury Tunnel and the Leadville Mine Drainage Tunnel were mutually exclusive of one another, which also suggested that no major hydraulic connection was present between the tunnels. Particle-tracking simulations also revealed that although the fault network generally restricted groundwater movement locally, hydrologic conditions were such that groundwater did cross the fault network at many locations. This cross-fault movement indicates that the fault network controls regional groundwater flow to some degree but is not a complete barrier to flow. The cumulative distributions of adjusted age results for the watershed indicate that approximately 30 percent of the flow pathways transmit groundwater that was younger than 68 years old (post-1941) and that about 70 percent of the flow pathways transmit old groundwater. The particle-tracking results are consistent with the apparent ages and mixing ratios developed from the chlorofluorocarbon and tritium results. The model simulations also indicate that approximately 50 percent of the groundwater flowing through the study area was less than 200 years old and about 50 percent of the groundwater flowing through the study area is old water stored in low-permeability geologic units and fault blocks. As a final examination of model response, the conductance parameters of the Canterbury Tunnel and Leadville Mine Drainage Tunnel were manually adjusted from the calibrated values to determine if altering the flow discharge in one tunnel affects the hydraulic behavior in the other tunnel. The examination showed no substantial hydraulic connection. The multidisciplinary investigation yielded an improved understanding of groundwater characteristics near the Canterbury Tunnel and the Leadville Mine Drainage Tunnel. Movement of groundwater between the Canterbury Tunnel and Leadville Mine Drainage Tunnel that was central to this investigation could not be evaluated with strong certainty owing to the structural complexity of the region, study simplifications, and the absence of observation data within the upper sections of the Canterbury Tunnel and between the Canterbury Tunnel and the Leadville Mine Drainage Tunnel. There was, however, collaborative agreement between all of the analyses performed during this investigation that a substantial hydraulic connection did not exist between the Canterbury Tunnel and the Leadville Mine Drainage Tunnel under natural flow conditions near the time of this investigation.

Colorado↗
USGS2014

Water-quality variability and constituent transport and processes in streams of Johnson County, Kansas, using continuous monitoring and regression models, 2003-11

The population of Johnson County, Kansas increased by about 24 percent between 2000 and 2012, making it one of the most rapidly developing areas of Kansas. The U.S. Geological Survey, in cooperation with the Johnson County Stormwater Management Program, began a comprehensive study of Johnson County streams in 2002 to evaluate and monitor changes in stream quality. The purpose of this report is to describe water-quality variability and constituent transport for streams representing the five largest watersheds in Johnson County, Kansas during 2003 through 2011. The watersheds ranged in urban development from 98.3 percent urban (Indian Creek) to 16.7 percent urban (Kill Creek). Water-quality conditions are quantified among the watersheds of similar size (50.1 square miles to 65.7 square miles) using continuous, in-stream measurements, and using regression models developed from continuous and discrete data. These data are used to quantify variability in concentrations and loads during changing streamflow and seasonal conditions, describe differences among sites, and assess water quality relative to water-quality standards and stream management goals. Water quality varied relative to streamflow conditions, urbanization in the upstream watershed, and contributions from wastewater treatment facilities and storm runoff. Generally, as percent impervious surface (a measure of urbanization) increased, streamflow yield increased. Water temperature of Indian Creek, the most urban site which is also downstream from wastewater facility discharges, was higher than the other sites about 50 percent of the time, particularly during winter months. Dissolved oxygen concentrations were less than the Kansas Department of Health and Environment minimum criterion of 5 milligrams per liter about 15 percent of the time at the Indian Creek site. Dissolved oxygen concentrations were less than the criterion about 10 percent of the time at the rural Blue River and Kill Creek sites, and less than 5 percent of the time at the other sites. Low dissolved oxygen at all sites generally coincided with lowest streamflow and warmer water temperatures. Hourly dissolved oxygen concentrations less than 5 milligrams per liter were measured at all sites every year, indicating that even under normal climate conditions in non-urban watersheds such as Kill Creek, dissolved oxygen concentrations may not meet State aquatic-life criterion. Specific conductance was nearly always highest in Indian and Mill Creeks, which were the most urban streams with the largest upstream discharges from wastewater treatment facilities. The largest chloride concentrations and variability were recorded at urban sites and during winter. Each winter during the study period, chloride concentrations in the most urban site, Indian Creek, exceeded the U.S. Environmental Protection Agency-recommended criterion of 230 milligrams per liter for at least 10 consecutive days. The U.S. Environmental Protection Agency-recommended ecoregion criterion for turbidity was exceeded 30 (Indian Creek) to 50 (Blue River) percent of the time. The highest average annual streamflow-weighted suspendedsediment concentration during the study period was in Mill Creek, which has undergone rapid development that likely contributed to higher sediment concentrations. One of the largest suspended-sediment load events in Indian Creek was recorded in early May 2007 when about 25 percent of the total annual sediment load was transported during a period of about 2.25 days. A simultaneous load event was recorded in Kill Creek, when about 75 percent of the total annual sediment load was transported. Sediment yields generally increased as percent impervious surface increased. Computed hourly total nitrogen and total phosphorus concentrations and yields and streamflow-weighted concentrations generally were largest in Indian and Mill Creeks. Annual percent contribution of total nitrogen in the Blue River from wastewater treatment facility discharges ranged from 19 percent in 2010 to 60 percent in 2006. Annual percent contribution of total nitrogen in Indian Creek from wastewater treatment facility discharges ranged from 35 percent in 2010 to 93 percent in 2006. The largest percent nutrient contributions from wastewater discharges coincided with the smallest annual precipitation and streamflow volume, resulting in less contribution originating from runoff. Fecal indicator bacteria Escherichia coli density at the urban Indian Creek site was usually the largest of the five monitoring sites, with an annual median density that consistently exceeded the State primary contact criterion value but was less than the secondary contact criterion. Less than 1 percent of the total annual bacteria load in the Blue River and Indian Creek originated from wastewater discharges, except during 2006 when about 6 percent of the Indian Creek load originated from wastewater. Continuous water-quality monitoring provides a foundation for comprehensive evaluation and understanding of variability and loading characteristics in streams in Johnson County. Because several directly measured parameters are strongly correlated with particular constituents of interest, regression models provide a valuable tool for evaluating variability and loading on the basis of computed continuous data. Continuous data are particularly useful for characterizing nonpoint-source contributions from stormwater runoff. Transmission of continuous data in real-time makes it possible to rapidly detect and respond to potential environmental concerns. As monitoring technologies continue to improve, so does the ability to monitor additional constituents of interest, with smaller measurement error, and at lower operational cost. Continuous water-quality data including model information and computed concentrations and loads during the study period are available at http://nrtwq.usgs.gov/ks/ .

Kansas↗
USGS2016

Sediment oxygen demand in eastern Kansas streams, 2014 and 2015

Dissolved oxygen concentrations in streams are affected by physical, chemical, and biological factors in the water column and streambed, and are an important factor for the survival of aquatic organisms. Sediment oxygen demand (SOD) rates in Kansas streams are not well understood. During 2014 and 2015, the U.S. Geological Survey, in cooperation with the Kansas Department of Health and Environment, measured SOD at eight stream sites in eastern Kansas to quantify SOD rates and variability with respect to season, land use, and bottom-sediment characteristics. Sediment oxygen demand rates (SOD T ) ranged from 0.01 to 3.15 grams per square meter per day at the ambient temperature of the measurements. The summer mean SOD rate was 3.0-times larger than the late fall mean rate, likely because of increased biological activity at warm water temperatures. Given the substantial amount of variability in SOD rates possible within sites, heterogeneity of substrate type is an important consideration when designing SOD studies and interpreting the results. Sediment oxygen demand in eastern Kansas streams was correlated with land use and streambed-sediment characteristics, though the strength of relations varied seasonally. The small number of study sites precluded a more detailed analysis. The effect of basin land use and streambed sediment characteristics on SOD is currently (2016) not well understood, and there may be many contributing factors including basin influences on water quality that affect biogeochemical cycles and the biological communities supported by the stream.

Kansas↗
USGS2016

Spatiotemporal variability of inorganic nutrients during wastewater effluent dominated streamflow conditions in Indian Creek, Johnson County, Kansas, 2012–15

Nutrients, particularly nitrogen and phosphorus, are a leading cause of water-quality impairment in Kansas and the Nation. Indian Creek is one of the most urban drainage basins in Johnson County, Kansas, and environmental and biological conditions are affected by contaminants from point and other urban sources. The Johnson County Douglas L. Smith Middle Basin (hereinafter Middle Basin) wastewater treatment facility (WWTF) is the largest point-source discharge on Indian Creek. A second facility, the Tomahawk Creek WWTF, discharges into Indian Creek approximately 11.6 kilometers downstream from the Middle Basin WWTF. To better characterize the spatiotemporal variability of nutrients in Indian Creek, the U.S. Geological Survey, in cooperation with the Kansas Department of Health and Environment and Johnson County Wastewater, collected high-resolution spatial and temporal (a large number of samples collected over the entire reach or at single locations over a long period of time) inorganic nutrient (nitrate plus nitrite and orthophosphorus) data using a combination of discrete samples and sensor-measured data during 2012 through 2015. Nutrient patterns observed in Indian Creek along the upstream-downstream gradient during wastewater effluent dominated streamflow conditions were largely affected by the WWTFs and by travel time of the parcels of water. Nitrate plus nitrite concentrations in the Middle Basin WWTF effluent and at downstream sites varied by as much as 6 milligrams per liter over a 24-hour period. The cyclical variability in the Middle Basin WWTF effluent generated a nitrate plus nitrite pulse that could be tracked for approximately 11.5 kilometers downstream in Indian Creek, until the effect was masked by the Tomahawk Creek WWTF effluent discharge. All longitudinal surveys showed the same general patterns along the upstream-downstream gradient, though streamflows, wastewater effluent contributions to streamflow, and nutrient concentrations spanned a wide range. Differences in orthophosphorus and nitrate plus nitrite patterns were clear along the upstream-downstream gradient in Indian Creek, and orthophosphorus concentrations were not as variable as nitrate plus nitrite concentrations. In general, nitrate plus nitrite concentrations decreased downstream from the Middle Basin WWTF to minima near the confluence with Tomahawk Creek, increased downstream from the Tomahawk Creek WWTF, and then varied little within the study reach. Orthophosphorus concentrations generally decreased downstream from the Middle Basin WWTF. Despite the marked variability in nitrate plus nitrite concentrations caused by the Middle Basin WWTF effluent discharges, decreases in nitrate plus nitrite concentrations were discernable along the study reach between the two WWTFs. Decreases in nitrate plus nitrite concentrations along study reach were less variable than the cyclical variability typically measured, reiterating the effect of the Middle Basin WWTF effluent discharges on the spatiotemporal variability of nitrate plus nitrite in Indian Creek. Although decreases and rates of change in nitrate plus nitrite concentration were similar between the upper and lower reaches of Indian Creek, relations with initial nitrate plus nitrite concentrations and seasonal patterns were different between the upper (from College to the Marty study sites) and lower reaches (from Marty to the Mission Farms study sites) and did not reflect patterns observed for the overall reach. Quantifying the decreases in nitrate plus nitrite concentration caused by dilution and other in-stream processes were beyond the scope of this study, and were limited by available data. The data that are available suggest that dilution and other in-stream processes play a role in decreasing nitrate plus nitrite concentrations downstream from the Middle Basin WWTF in Indian Creek. Analysis of the spatiotemporal variability of nutrients focused on below-normal and normal streamflow conditions, when streamflow and nutrient conditions in Indian Creek were largely controlled by WWTF effluent flows and nutrient removal processes. Spatial and temporal data indicate there are decreases in nutrient concentrations along the upstream-downstream gradient in Indian Creek, but quantifying decreases is complicated by the variability in nutrient concentrations caused by the WWTFs. During below-normal and normal streamflow conditions, Indian Creek nutrient concentrations downstream from the Middle Basin WWTF primarily reflect effluent concentrations in the hours or days before depending on relative distance downstream.

Kansas↗
USGS2017

Preliminary assessment of a water-quality monitoring program for total maximum daily loads in Johnson County, Kansas, January 2015 through June 2016

Municipalities in Johnson County in northeastern Kansas are required to implement stormwater management programs to reduce pollutant discharges, protect water quality, and comply with applicable water-quality regulations in accordance with National Pollutant Discharge Elimination System permits for stormwater discharge. To this end, municipalities collect grab samples at streams entering and leaving their jurisdiction to determine levels of excessive nutrients, sediment, and fecal bacteria to characterize pollutants and understand the factors affecting them. In 2014, the U.S. Geological Survey and the Johnson County Stormwater Management Program, with input from the Kansas Department of Health and Environment, initiated a 5-year monitoring program to satisfy minimum sampling requirements for each municipality as described by new stormwater permits issued to Johnson County municipalities. The purpose of this report is to provide a preliminary assessment of the monitoring program. The monitoring program is described, a preliminary assessment of the monitoring program design is provided using water-quality data collected during the first 2 years of the program, and the ability of the current monitoring network and sampling plan to provide data sufficient to quantify improvements in water quality resulting from implemented and planned best management practices is evaluated. The information in this initial report may be used to evaluate changes in data collection methods while data collection is still ongoing that may lead to improved data utility. Discrete water-quality samples were collected at 27 sites and analyzed for nutrients, Escherichia coli ( E. coli ) bacteria, total suspended solids, and suspended-sediment concentration. In addition, continuous water-quality data (water temperature, pH, dissolved oxygen, specific conductance, turbidity, and nitrate plus nitrite) were collected at one site to characterize variability and provide a basis for comparison to discrete data. Base flow samples indicated that point sources are likely affecting nutrient concentrations and E. coli bacteria densities at several sites. Concentrations of all analytes in storm runoff samples were characterized by substantial variability among sites and samples. About one-half of the sites, representing different watersheds, had storm runoff samples with nitrogen concentrations greater than 10 milligrams per liter. About one-third of the sites, representing different watersheds, had storm runoff samples with total phosphorus concentrations greater than 3 milligrams per liter. Six sites had samples with E. coli densities greater than 100,000 colonies per 100 milliliters of water. Total suspended solids concentrations of about 12,000 milligrams per liter or greater occurred in samples from three sites. Data collected for this monitoring program may be useful for some general assessment purposes but may also be limited in potential to fully inform stormwater management activities. Valuable attributes of the monitoring program design included incorporating many sites across the county for comparisons among watersheds and municipalities, using fixed-stage samplers to collect multiple samples during single events, collection of base flow samples in addition to storm samples to isolate possible point sources from stormwater sources, and use of continuous monitors to characterize variability. Limiting attributes of the monitoring program design included location of monitoring sites along municipal boundaries to satisfy permit requirements rather than using watershed-based criteria such as locations of tributaries, potential pollutant sources, and implemented management practices. Additional limiting attributes include having a large number of widespread sampling locations, which presented logistical challenges for predicting localized rainfall and collecting and analyzing samples during short timeframes associated with storms, and collecting storm samples at fixed-stage elevations only during the rising limb of storms, which does not characterize conditions over the storm hydrograph. The small number of samples collected per site resulted in a sample size too small to be representative of site conditions, including seasonal and hydrologic variability, and insufficient for meaningful statistical analysis or site-specific modeling. Several measures could be taken to improve data utility and include redesigning the monitoring network according to watershed characteristics, incorporating a nested design in which data are collected at different scales (watershed, subwatershed, and best management practices), increasing sampling frequency, and combining different methods to allow for flexibility to focus on areas and conditions of particular interest. A monitoring design that would facilitate most of these improvements would be to focus efforts on a limited number of watersheds for several years, then cycle to the next set of watersheds for several years, eventually returning to previously monitored watersheds to document changes. Redesign of the water-quality monitoring program requires considerable effort and commitment from municipalities of Johnson County. However, the long-term benefit likely is a monitoring program that results in improved stream conditions and more effective management practices and efficient expenditure of resources.

Kansas↗
USGS2021

Assessment of streamflow and water quality in the Upper Yampa River Basin, Colorado, 1992–2018

The Upper Yampa River Basin drains approximately 2,100 square miles west of the Continental Divide in north-western Colorado. There is a growing need to understand potential changes in the quantity and quality of water resources as the basin is undergoing increasing land and water development to support growing municipal, industrial, and recreational needs. The U.S. Geological Survey, in cooperation with stakeholders in the Upper Yampa River Basin water community, began a study to characterize and identify changes in streamflow and selected water-quality constituents, including suspended sediment, Kjeldahl nitrogen, total nitrogen, total phosphorus, and orthophosphate, in the basin. This study used streamflow and water-quality data from selected U.S. Geological Survey sites to provide a better understanding of how major factors, including land use, climate change, and geological features, may influence streamflow and water quality. Analysis of long-term (1910–2018) and short-term (1992–2018) records of streamflow at main-stem Yampa River and tributary sites indicate downward trends in one or more streamflow statistics, including 1-day maximum, mean, and 7-day minimum. Long-term downward trends in daily mean streamflow in April (22 percent overall) at Yampa River at Steamboat Springs, Colorado, correspond to observed changes in streamflow documented across western North America and the Colorado River Basin that are predominately associated with changes in snowmelt runoff and temperatures. During the short-term period of analysis, decreases in streamflow at main-stem Yampa River and some tributary sites are likely related to changes in consumptive use and reservoir management or, at sites with no upstream flow impoundments, changes in irrigation diversions and climate. Concentrations of water-quality constituents were typically highest in spring (March, April, and May) during the early snowmelt runoff period as material that is washed off the land surface drains into streams. Highest concentrations occurred slightly later, in May, June, and July, at Yampa River above Stagecoach Reservoir, Colo., and slightly earlier, in February and March at Yampa River at Milner, Colo., indicating that these sites may have different or additional sources of phosphorus from upstream inputs. Yampa River at Milner, Colo., and Yampa River above Elkhead Creek, Colo., had the highest net yields of suspended sediment, Kjeldahl nitrogen, and total phosphorus, and are likely influenced by land use and erosion as the basins of both of these sites are underlain by highly erodible Cretaceous shales. Upward trends in estimated Kjeldahl nitrogen and total phosphorus concentrations and loads were found at Yampa River at Steamboat Springs, Colo. From 1999 to 2018, the Kjeldahl nitrogen concentration increased by 10 percent or 0.035 milligram per liter, and load increased by 22 percent or 26 tons. Total phosphorus concentration increased by 20 percent or 0.0081 milligram per liter, and loads increased by 41 percent or 6.2 tons. Decreases in streamflow and changes in land use may contribute to these trends. During multiple summer sampling events at Stagecoach Reservoir, the physical and chemical factors indicated conditions conducive to cyanobacterial blooms, including surface-water temperatures greater than 20 degrees Celsius and total phosphorus and total nitrogen concentrations in exceedance of Colorado Department of Public Health and Environment interim concentrations for water-quality standards. Local geological features (predominately sandstones and shales) and additional inputs from upstream land use likely contribute to the elevated nutrient conditions in Stagecoach Reservoir.

Colorado↗
USGS2021

Assessment of water-quality constituents monitored for total maximum daily loads in Johnson County, Kansas, January 2015 through December 2018

Stormwater discharges from municipalities are regulated by provisions in the Clean Water Act of 1972 to protect the Nation’s water resources from harmful pollutants. In 2014, the Kansas Department of Health and Environment issued new stormwater discharge permits for 17 municipalities in Johnson County, Kansas, in the northeastern part of the State. The county is largely suburban and has 20 municipalities within 22 watersheds. Municipalities in Johnson County are required to implement stormwater management programs that reduce discharges of pollutants, protect water quality, and satisfy applicable water-quality regulations. In 2015, the U.S. Geological Survey, in cooperation with the Johnson County Stormwater Management Program, began a 4-year monitoring program designed to meet new stormwater monitoring requirements for some municipalities in Johnson County. Additional data were collected to evaluate the usefulness of continuous water-quality monitoring and different sampling methods in assessing changes in water quality. Twelve of the 22 watersheds in the county were within the sampling network for this project. Discrete water-quality samples were collected at 25 stream sites and 2 lake sites using passive, grab, and equal-width increment sampling methods. Samples at all sites were analyzed for nutrients, Escherichia coli bacteria, total suspended solids, and suspended-sediment concentration. Ninety-nine percent of storm-event samples and 98 percent of low-flow samples were less than the Kansas Surface Water Quality Standard for nitrate plus nitrite. Eight percent of storm-event samples and 100 percent of low-flow samples were less than the total suspended solids screening value of 50 milligrams per liter. Passive samples generally had higher concentrations when compared to equal-width increment and grab samples, and grab samples and equal-width increment samples generally had similar concentrations. Continuous water-quality data were collected at one site. Ordinary least squares regression analysis was used to relate continuous (15-minute) water-quality sensor measurements to discretely sampled constituent concentrations at one site. Numerous factors affect water quality in urban runoff. Urban areas have many possible contaminant sources, including municipal and industrial wastewater discharges, stormwater runoff from impervious surfaces, and failing infrastructure. A better understanding of these factors can inform future monitoring efforts, leading to datasets that are representative of storm runoff and can be used to detect differences between sites and over time.

Kansas↗
USGS2021

Analysis of Escherichia coli, total recoverable iron, and dissolved selenium concentrations, loading, and identifying data gaps for selected 303(d) listed streams, Grand Valley, western Colorado, 1980–2018

Tributaries to the Colorado River in the Grand Valley in western Colorado (segment COLCLC13b) have been placed on the State of Colorado 303(d) list as impaired for Escherichia coli (E. coli) , total recoverable iron, and dissolved selenium. The Colorado Department of Public Health and Environment Water Quality Control Division is required to develop total maximum daily loads for these constituents in these tributaries. The U.S. Geological Survey, in cooperation with the Grand Valley Drainage District and Colorado Water Conservation Board, conducted a study to (1) characterize concentrations, loads, and load reductions for E. coli , total recoverable iron, and dissolved selenium using existing data and (2) identify water-quality data gaps to inform future monitoring strategies. This study analyzed water-quality and streamflow data for 3 main-stem sites (2 sites along the Colorado River and 1 site along the Gunnison River) and 29 selected sites on tributaries to the Colorado River. Sample data were available at five sites along Adobe Creek and at six sites along Leach Creek, the two tributaries in the study area that are impaired for E. coli . All geometric mean E. coli concentrations at sites along Adobe Creek and Leach Creek exceeded the State recreational use standard of 126 colony forming units per 100 milliliters (CFU/100 mL). In Adobe Creek, E. coli concentrations in samples ranged from 45.7 to more than 2,420 CFU/100 mL (method upper reporting limit for undiluted samples), and geometric mean concentrations at sites ranged from 301 to 1,180 CFU/100 mL. The E. coli concentrations generally increased in the downstream direction in Adobe Creek; however, increases were not seen between all sites. The largest downstream increase in E. coli concentration was measured between the two most upstream sites. In Leach Creek, concentrations of E. coli in samples ranged from 25.9 to more than 2,420 CFU/100 mL, and geometric mean concentrations at sites ranged from 160 to 259 CFU/100 mL. The E. coli concentrations showed no consistent downgradient increase in Leach Creek. In fact, some of the highest E. coli concentrations were measured at the most upstream site, Leach Creek at Summer Hill Drive. Total recoverable iron concentrations and loads were evaluated at 15 tributary sites for samples collected from August 1993 to February 2018. Median total recoverable iron concentrations ranged from 211 to 4,670 micrograms per liter (µg/L). The chronic aquatic-life water-quality standard (1,000 µg/L) was exceeded in most irrigation season (April through October) samples but was rarely exceeded in nonirrigation season (November through March) samples. Concentrations were often an order of magnitude higher in samples collected during irrigation season than in samples collected during nonirrigation season. None of the sites had enough concurrent total recoverable iron and streamflow data to compute annual loads. As with E. coli , the lack of concurrent total recoverable iron and streamflow information represents a data gap, which needs to be addressed to compute annual loads. Dissolved selenium concentrations and loads were evaluated at 20 tributary sites using discrete water-quality data collected 1991–2018. Dissolved selenium concentrations were higher during nonirrigation season than during irrigation season at tributary sites. However, irrigation season dissolved selenium loads were generally higher than nonirrigation selenium loads, because streamflows were higher during irrigation season. Regression analysis was used to estimate daily dissolved selenium concentrations and loads at three main-stem sites for water years (WYs) 1980–2018 (Gunnison River near Grand Junction and Colorado River near Colorado-Utah State Line) and WYs 2002–18 (Colorado River near Cameo). A trend analysis of dissolved selenium concentrations and loads was completed for these sites from the same respective starting dates but ending in 2017. A continuing downward trend in dissolved selenium concentration was observed at all sites and across all seasonal designations of the analysis. The dissolved selenium concentration decreased by 0.12 µg/L from WY 2002 to 2017 at Colorado River near Cameo, representing an 18-percent decrease during the time period. The dissolved selenium concentration at Gunnison River near Grand Junction decreased by 4.2 µg/L from WY 1980 to 2017, representing a 56-percent decrease overall. During the same time period, dissolved selenium concentration at Colorado River near Colorado-Utah State Line decreased by 3.8 µg/L, representing a 56-percent decrease overall. A downward trend in dissolved selenium load was also observed at all sites and across all seasonal designations of the analysis. The relative contribution of dissolved selenium from the Grand Valley near Grand Junction was estimated by comparing loads at main-stem sites bracketing the study area. The two upstream sites, Colorado River near Cameo and Gunnison River near Grand Junction, contributed 60,300 cumulative pounds and 251,000 cumulative pounds, respectively, during WYs 2002–18. At the furthest downstream site, Colorado River near Colorado-Utah State Line, 490,000 cumulative pounds were estimated during the same time period, indicating that the region between Whitewater and State line contributed approximately 179,000 cumulative pounds or a mean annual load of 10,500 lb/yr. Grand Valley dissolved selenium contributions appear to be stable during WYs 2002–18.

Colorado↗
USGS2022

Linear regression model documentation for computing water-quality constituent concentrations using continuous real-time water-quality data for the Republican River, Clay Center, Kansas, July 2018 through March 2021

The Republican River is the primary inflow to Milford Lake and drains areas of Kansas, Nebraska, and Colorado. Milford Lake has been listed as impaired and designated hypereutrophic by the Kansas Department of Health and Environment because of excessive nutrient loading. Milford Lake had confirmed harmful algal blooms every summer from 2011 through 2017 and in 2020 and 2021. In the lower Republican River drainage basin, the Regional Conservation Partnership Program, administered by the Natural Resources Conservation Service, provides reimbursement to agricultural producers that implement best management practices intended to decrease sediment and nutrient runoff and loading into Milford Lake. Sediment and nutrient loads could potentially be driving factors in the development of harmful algal blooms in the reservoir. Since July 2018, the U.S. Geological Survey, in cooperation with the Kansas Water Office, has collected continuous and discrete water-quality data at the Republican River at Clay Center, Kansas, streamgage (U.S. Geological Survey station 06856600), which is about 15 river miles upstream from Milford Lake. This report documents site-specific regression models for the computation of continuous concentrations of suspended sediment, total nitrogen, total phosphorus, and total carbon developed using continuous and discrete data collected from July 24, 2018, the date of continuous water-quality monitor installation, through March 31, 2021. The objective of this study is to characterize sediment and nutrient transport in the Milford Lake drainage basin before, during, and after best management practice implementation using the models described in this report. The explanatory variable turbidity explained a high amount (72–96 percent) of the variance in suspended-sediment, total nitrogen, total phosphorus, and total carbon concentrations. Statistical plots for the four selected models showed the desired normality and homoscedasticity in residuals, and model standard error ratios indicated that recomputing each selected model after removing a randomly selected 10 percent of the data did not substantially change model coefficients.

Kansas↗
USGS2022

Characterization of and relations among precipitation, streamflow, suspended-sediment, and water-quality data at the U.S. Army Garrison Fort Carson and Piñon Canyon Maneuver Site, Colorado, water years 2016–18

Frequent and prolonged military training maneuvers are an intensive type of land use that may disturb land cover, compact soils, and have lasting effects on adjacent stream hydrology and ecosystems. To better understand the potential effect of military training on hydrologic and environmental processes, the U.S. Geological Survey in cooperation with the U.S. Army established hydrologic and water-quality data-collection networks at the U.S. Army Garrison Fort Carson (AGFC) in 1978 and at the Piñon Canyon Maneuver Site (PCMS) in 1982. The purpose of this report is to present precipitation, streamflow, suspended-sediment, and water-quality data collected by the U.S. Geological Survey at the AGFC and PCMS for water years (WYs) 2016–18 and to evaluate those data in relation to long-term data from the AGFC and PCMS. In WYs 2016–18, the U.S. Geological Survey monitored 26 sites on the AGFC and 17 sites on the PCMS for precipitation amount, streamflow, suspended sediment, and (or) water quality. On the AGFC, total annual precipitation in WYs 2016–18 was larger than the long-term mean for all 3 years at Rod and Gun Meteorologic Station at Fort Carson, CO (Rod and Gun). There were statistically significant upward trends in annual precipitation at Rod and Gun and Young Hollow Meteorologic Station at Fort Carson, CO (Young Hollow) with slopes of 1.25 and 0.66 inches per year (in/yr), respectively. The precipitation totals for WY 2017 were either the largest on record or in the top three for both sites and at Sullivan Park Meteorologic Station at Fort Carson, CO. On the PCMS, total annual precipitation was larger than the long-term mean in WYs 2016–18 at Brown Sheep Camp Meteorologic Station near Tyrone, CO; CIG Pipeline South Meteorologic Station near Simpson, CO; Bear Springs Hills Meteorologic Station near Houghton, CO (Bear Springs); and Upper Red Rock Canyon Meteorologic Station near Houghton, CO (Upper Red Rock). There were statistically significant upward trends in precipitation at Bear Springs and Upper Red Rock with slopes of 0.16 and 0.19 in/yr, respectively. The precipitation totals for WY 2017 were the largest on record for all sites except for Upper Bent Canyon Meteorological Station near Delhi, CO. Streamflow was calculated at 18 sites on the AGFC and 7 sites on the PCMS in at least 1 of WYs 2016–18. At AGFC, mean annual (or seasonal) streamflow in WYs 2016–18 was less than the long-term mean at 7 sites and greater than the long-term mean at 3 sites. There were statistically significant downward trends in mean annual or seasonal streamflow at Womack Ditch from Little Fountain Creek near Fort Carson, CO, and Ripley Ditch from Little Fountain Creek at Fort Carson, CO, with slopes of −0.036 and −0.028 cubic feet per second per year (ft 3 /s/y), respectively; and a significant upward trend in streamflow at Turkey Creek West Seepage below Teller Reservoir near Stone City, CO, with a slope of less than 0.001 ft 3 /s/y. Unlike for precipitation, the mean annual or seasonal streamflow for WY 2017 was not in the top 3 for any of the 12 sites with measured flow. At the PCMS, mean annual (or seasonal) streamflow was less than the long-term mean streamflow in WYs 2016–18 at the Taylor Arroyo below Rock Crossing near Thatcher, CO, and Bent Canyon Creek at Mouth near Timpas, CO, sites; and in WYs 2016 and 2018 at the Purgatoire River near Thatcher, CO (Purgatoire Thatcher), and Purgatoire River at Rock Crossing near Timpas, CO (Purgatoire Rock Crossing). There were no statistically significant trends in mean annual (or seasonal) streamflow at sites on the PCMS, and unlike for precipitation, the mean streamflow for WY 2017 was not in the top three for any sites except Purgatoire Rock Crossing. In WYs 2016–18, streamflow from sites on the AGFC and PCMS represented only a small fraction of streamflow in Fountain Creek or the Purgatoire River, and changes in streamflow that resulted from military maneuvers on the AGFC and PCMS were not likely to be detected in the downstream receiving waters. Suspended-sediment concentrations, loads, and yields for WYs 2016–18, were analyzed at two sites on the AGFC and five sites on the PCMS. On the AGFC, mean seasonal suspended-sediment concentrations ranged from 3.10 to 155 milligrams per liter (mg/L), mean seasonal suspended-sediment loads ranged from 0.04 to 27.1 tons per day (t/d), and seasonal suspended-sediment yields ranged from 0.28 to 216 tons per season per square mile (t/s/mi 2 ). Suspended-sediment yields at the two AGFC sites in WYs 2016–18 were all less than the long-term means. On the PCMS, mean seasonal suspended-sediment concentrations (at sites with some streamflow during a WY) ranged from 1.12 to 41.8 mg/L, mean suspended-sediment loads ranged from 0.01 to 13.1 t/d, and seasonal suspended-sediment yields ranged from 0.06 to 57.4 t/s/mi 2 . Suspended-sediment yields at the five PCMS sites in WYs 2016–18 were all less than the long-term means. In WYs 2016–18, mean daily suspended-sediment loads at Little Fountain were 1.3, 2.5, and 7.6 percent, respectively, of the mean daily suspended-sediment load at Fountain Creek at Security, Colorado. Likewise, the total of mean daily suspended-sediment loads from the five tributary sites to the Purgatoire River in WYs 2016–18 were about 0.25, 0.17, and 3.2 percent, respectively, of the historical mean daily suspended-sediment load at Purgatoire Thatcher. Spearman’s rank correlation coefficient was used to evaluate the strength and form of the relations between daily total precipitation and daily mean streamflow and between daily mean streamflow and suspended-sediment concentration and load for WYs 2016–18. For the sites on the AGFC and PCMS, there were weak or statistically insignificant positive correlations between precipitation and streamflow at nearby streamgauges, but strong statistically significant positive correlations between streamflow and suspended-sediment concentration and load. The ephemeral nature of the streams, quantity and timing of precipitation, air temperature, seasonal soil-moisture deficits, and effective runoff detention in erosion-control ponds could all contribute to inconsistent conversion of precipitation to streamflow. Water-quality data were analyzed for as many as 43 parameters from 9 samples collected from 3 sites on the AGFC and from 37 samples collected from 4 sites on PCMS during WYs 2016–18. The concentrations of selected water-quality parameters were compared to regulatory standards for aquatic life from the Colorado Department of Public Health and Environment (CDPHE) or aquatic-life criteria from the U.S. Environmental Protection Agency (EPA). There is at least 1 CDPHE standard or EPA criterion for 30 of the 43 water-quality parameters. For all samples from both the AGFC and the PCMS in WYs 2016–18, the concentrations of most water-quality parameters were compliant with the associated standards or criteria. However, there were some exceedances of standards or criteria: 11 samples exceeded the CDPHE recreational class standard for Escherichia coli concentration, 9 samples exceeded the CDPHE chronic unfiltered phosphorus aquatic-life standard, 36 samples exceeded the CDPHE chronic sulfate aquatic-life standard, 5 samples exceeded the EPA criterion for selenium, 7 samples exceeded the EPA criterion for aluminum, 2 samples exceeded the CDPHE chronic standard for iron, and 15 samples exceeded the CDPHE chronic standard for manganese. Identifying potential effects of military training on water quality in adjacent streams on the AGFC and PCMS is difficult due to the ephemeral nature of streamflow, limited number of sampling locations and samples, and limited access to the study areas. At the PCMS, pairs of water-quality samples were collected in March and May 2017 before and after an April–May 2017 military training event. At the Purgatoire Rock Crossing site, streamflow at the time of the May sample was approximately 35 times larger than streamflow for the March sample. The absolute percent differences of concentrations for 27 parameters ranged from −71.7 to 183 percent, and 7 parameters had increases in concentration whereas 22 parameters had no change or decreases in concentrations. The absolute percent differences of loads for 24 parameters ranged from 141 to 198 percent. The generally lower concentrations and higher loads were expected given the higher streamflows at the time of collection of the May compared to the March samples.

Colorado↗
USGS2023

Linear regression model documentation for computing water-quality constituent concentrations or densities using continuous real-time water-quality data for the Kansas River above Topeka Weir at Topeka, Kansas, November 2018 through June 2021

The Kansas River and its associated alluvial aquifer provide drinking water to more than 950,000 people in northeastern Kansas. Water suppliers that rely on the Kansas River as a water-supply source use physical and chemical processes to treat and remove contaminants before public distribution. An early-notification system of changing water-quality conditions allows water suppliers to proactively make decisions that affect water treatment. The U.S. Geological Survey (USGS), in cooperation with the Kansas Water Office (funded in part through the Kansas Water Plan), the Kansas Department of Health and Environment, The Nature Conservancy, the City of Lawrence, the City of Manhattan, the City of Olathe, the City of Topeka, WaterOne, and Evergy, began collecting water-quality data at the Kansas River above Topeka Weir at Topeka, Kansas (USGS site 06888990, hereafter referred to as the “Topeka site”), during November 2018 to develop linear regression models that relate continuous in situ water-quality sensor measurements to discretely sampled water-quality constituent concentrations or densities. The addition of the Topeka site expanded an existing water-quality monitoring network, which included the upstream Kansas River at Wamego, Kans., and downstream Kansas River at De Soto, Kans., sites. Linear regression analysis was used to develop models that compute real-time concentrations or densities for total dissolved solids, major ions, hardness as calcium carbonate, nutrients (nitrogen and phosphorus species), chlorophyll a , total suspended solids, suspended sediment, and Escherichia coli at the Topeka site using data collected during November 2018 through June 2021. Water-quality constituent concentrations or densities computed from the models documented in this report are available at the USGS National Real-Time Water-Quality website (https://nrtwq.usgs.gov), are useful to the public for cultural and recreational purposes, and can be used to guide water-treatment processes, compare conditions with Federal and State water-quality criteria, and characterize changes in Kansas River water-quality conditions through time.

Kansas↗
USGS2023

Investigation of potential factors controlling benthic algae in the upper White River Basin, Colorado, 2018–21

Nuisance levels of benthic filamentous green algae are becoming increasingly common in surface waters of Colorado and the western United States. In 2018 the U.S. Geological Survey began a study in cooperation with the White River and Douglas Creek Conservation Districts, Colorado River Basin Salinity Control Forum, and the Colorado River Water Conservation District to collect and analyze physical, chemical, and biological information for the upper White River Basin in Colorado and investigate causes of benthic algal blooms in the basin. This report (1) presents site-specific data including water temperature, riparian canopy cover, streambed particle size, and algal biomass and community composition; (2) describes the potential for streambed movement during spring runoff using physical channel characteristics and peak streamflow velocities; and (3) explains the results of a linear mixed-effects model used to test hypotheses about the influence of physical and chemical factors in explaining the occurrence of algal blooms across the basin. Benthic algal biomass ranged from 0.7 to 309 milligrams per square meter during the summer (July–August) from 2018 through 2021 and exceeded the Colorado Department of Public Health and Environment criteria of 150 milligrams per square meter on four occasions, in 2018. Four genera of filamentous green algae were identified in the upper White River Basin, including Cladophora , Stigeoclonium , Ulothrix , and Spirogyra . Many genera of cyanobacteria were present, including some capable of producing toxins and taste and odor compounds. The nuisance diatom Didymosphenia geminata , commonly referred to as didymo, was found at two sites on the South Fork White River and along the main stem White River. Hypotheses pertaining to the influence of measured variables on algal biomass were tested with a linear mixed-effects model. Median rock size and mean August water temperature had significant positive effects, meaning that greater bed stability and higher mean August water temperatures result in greater algal biomass. Total nitrogen to total phosphorus ratios had a significant negative effect on algal biomass, meaning that more nitrogen-limiting conditions, or greater phosphorus availability, corresponded to greater algal biomass. Streamflow and water temperature data at White River above Coal Creek near Meeker, Colo., were used to assess possible causes of bloom conditions across years, including when algal blooms were first studied in the basin during 2016 and 2017. Early or low-magnitude peak streamflow conditions were not prerequisites for algal bloom occurrence. Conversely, relatively large, late, and long-lasting peak streamflows, such as those measured in 2019, may limit algal blooms during the same year and into subsequent years, as evidenced by extremely low algal biomass in 2019 and 2020. The broad spatial extent of bloom conditions indicates that the factors contributing to the occurrence of algal blooms are likely basinwide. Findings from this multiyear study indicate that the effects caused by larger peak streamflow, including movement of the streambed, may be the dominant control on the occurrence of an algal bloom. The findings also indicate that in the absence of disturbance other resources, including substrate size, water temperature, and nutrient availability, moderate algal biomass.

Colorado↗
USGS2024

Water-quality trends in the Kansas River, Kansas, since enactment of the Clean Water Act, 1972–2020

The Clean Water Act was passed by Congress in 1972 to regulate pollution within the waters of the United States. The U.S. Geological Survey (USGS), in cooperation with the Kansas Department of Health and Environment (KDHE), the Kansas Water Office, the Nature Conservancy, the City of Lawrence, the City of Manhattan, the City of Olathe, the City of Topeka, WaterOne, and Evergy, compiled and analyzed historical streamflow and water-quality data collected by USGS and KDHE to characterize trends in water-quality constituents of interest because of their relation to water supply, drinking-water treatment, and sediment and nutrient transport, among others (total dissolved solids, chloride, ammonia, dissolved inorganic nitrogen [ammonia and nitrate plus nitrite], total nitrogen, orthophosphate, total phosphorus, total suspended solids, and fecal coliform bacteria) during mean- and low-flow conditions in the Kansas River since the passage of the Clean Water Act in 1972 through 2020. Trends in water-quality concentrations, or densities, and loads were analyzed using the Exploration and Graphics for RivER Trends R package and Weighted Regressions on Time, Discharge, and Season (WRTDS) model at upstream (Kansas River at Wamego, Kansas; USGS station 06887500) and downstream (Kansas River at De Soto, Kansas; USGS station 06892350) locations along the Kansas River using streamflow and water-quality data collected by the USGS and KDHE during 1972 through 2020. The Exploration and Graphics for RivER Trends Confidence Intervals R package and WRTDS bootstrap test estimated direction, uncertainty, and likelihood of trends in concentration and loads for each water-quality constituent of interest. Downward trends in concentration and load were observed for 5 of the 9 water-quality constituents at both sites during mean-flow conditions during the study period. During low-flow conditions, 7 of the 9 constituents exhibited downward trends, possibly reflecting reductions in point-source contributions to the Kansas River. Downward trends in ammonia, dissolved inorganic nitrogen, and total nitrogen during mean- and low-flow conditions were observed at both Kansas River sites, which were similar to patterns observed nationally. Upward trends were generally observed for orthophosphate and total phosphorus, which were similar to patterns observed at sites in the Mississippi River Basin. Downward trends, or no trend, were observed for chloride. Upward and downward trends were observed for total dissolved solids. Downward trends in total suspended solids and fecal coliform bacteria were observed at both sites, which were also similar to patterns observed nationally. The long-term trend analyses in this report are an essential step to understanding how water-quality conditions have changed in the Kansas River since the passage of the Clean Water Act.

Kansas↗
USGS2024

Water-quality constituent concentrations and loads computed using real-time water-quality data for the Republican River, Clay Center, Kansas, August 2018 through July 2023

Milford Lake, the largest reservoir by surface area in Kansas, has had confirmed harmful algal blooms every summer since reporting began in 2011, except 2018–19. Milford Lake has been listed as impaired and designated hypereutrophic under section 303(d) of the 1972 Clean Water Act. In 2014, the Kansas Department of Health and Environment established a total maximum daily load for eutrophication and dissolved oxygen impairments. In 2018, the Natural Resources Conservation Service funded the Regional Conservation Partnership Program for the Milford Lake Watershed to focus on best management practices in the Lower Republican River Basin. The U.S. Geological Survey, in cooperation with the Kansas Water Office, completed this study to assess and quantify water-quality constituent concentrations and loads for total nitrogen (TN), total phosphorus (TP), and suspended sediment (SS) using previously published models for the Republican River near Clay Center, Kansas (U.S. Geological Survey station 06856600), about 15 miles upstream from Milford Lake, during August 1, 2018, through July 31, 2023. TN, TP, and SS concentrations and loads were monitored because of their relation to water supply and water-quality issues in Milford Lake, including nutrient and sediment transport, taste-and-odor events, potentially toxic cyano-harmful algal bloom events, and subsequent downstream transport of contaminants. Data from this report can be used to evaluate changing conditions, provide science-based information for decision making, and help meet regulatory requirements. The study mean annual loads for TN and TP were greater than the reported mean annual total maximum daily load and exceeded the watershed reduction goals as well as Kansas nonpoint source reduction goals defined by the Watershed Restoration and Protection Strategy for the Lower Republican watershed. TN and TP annual loads during 2019–20 were greater than the defined mean annual total maximum daily load. During 2022, TN and TP annual loads were less than the Kansas nonpoint source reduction goal and during 2023 were less than the watershed reduction goal. SS loads were less than the mean annual sedimentation rate computed from the total maximum daily load for the entirety of the study period, and the study mean annual load was 72 percent less than the designed annual reservoir sedimentation rate for Milford Lake. Data collected during the study period represented a wide range of streamflow and water-quality conditions at the Clay Center site, ranging from low-flow with less frequent runoff during 2023 to high-flow with frequent runoff during 2018. Nutrient reduction goals were only met in the final 2 years of the study period when annual mean flow conditions were lower than normal, indicating that goals may be unattainable during average or high-flow conditions. In all years except 2019, the annual mean SS load was less than the 20-year sediment load reduction target. Although annual SS loads at the Clay Center site generally decreased over time, corresponding reductions in annual streamflow indicated that these reductions may primarily be related to less frequent runoff from the upstream basin. Continued water-quality monitoring and tracking of best management practices are necessary to understand the success of Regional Conservation Partnership Program efforts to reduce nutrient transport in the Milford Lake Watershed.

Kansas↗
USGS2000

Regression analysis and real-time water-quality monitoring to estimate constituent concentrations, loads, and yields in the Little Arkansas River, south-central Kansas, 1995-99

Water from the Little Arkansas River is used as source water for artificial recharge to the Equus Beds aquifer, which provides water for the city of Wichita in south-central Kansas. To assess the quality of the source water, continuous in-stream water-quality monitors were installed at two U.S. Geological Survey stream-gaging stations to provide real-time measurement of specific conductance, pH, water temperature, dissolved oxygen, and turbidity in the Little Arkansas River. In addition, periodic water samples were collected manually and analyzed for selected constituents, including alkalinity, dissolved solids, total suspended solids, chloride, sulfate, atrazine, and fecal coliform bacteria. However, these periodic samples do not provide real-time data on which to base aquifer-recharge operational decisions to prevent degradation of the Equus Beds aquifer. Continuous and periodic monitoring enabled identification of seasonal trends in selected physical properties and chemical constituents and estimation of chemical mass transported in the Little Arkansas River. Identification of seasonal trends was especially important because high streamflows have a substantial effect on chemical loads and because concentration data from manually collected samples often were not available. Therefore, real-time water-quality monitoring of surrogates for the estimation of selected chemical constituents in streamflow can increase the accuracy of load and yield estimates and can decrease some manual data-collection activities. Regression equations, which were based on physical properties and analysis of water samples collected from 1995 through 1998 throughout 95 percent of the stream's flow duration, were developed to estimate alkalinity, dissolved solids, total suspended solids, chloride, sulfate, atrazine, and fecal coliform bacteria concentrations. Error was evaluated for the first year of data collection and each subsequent year, and a decrease in error was observed as the number of samples increased. Generally, 2 years of data (35 to 55 samples) collected throughout 90 to 95 percent of the stream's flow duration were sufficient to define the relation between a constituent and its surrogate(s). Relations and resulting equations were site specific. To test the regression equations developed from the first 3 years of data collection (1995-98), the equations were applied to the fourth year of data collection (1999) to calculate estimated constituent loads and the errors associated with these loads. Median relative percentage differences between measured constituent loads determined using the analysis of periodic, manual water samples and estimated constituent loads were less than 25 percent for alkalinity, dissolved solids, chloride, and sulfate. The percentage differences for total suspended solids, atrazine, and bacteria loads were more than 25 percent. Even for those constituents with large relative percentage differences between the measured and estimated loads, the estimation of constituent concentrations with regression analysis and real-time water-quality monitoring has numerous advantages over periodic manual sampling. The timely availability of bacteria and other constituent data may be important when considering recreation and the whole-body contact criteria established by the Kansas Department of Health and Environment for a specific water body. In addition, water suppliers would have timely information to use in adjusting water-treatment strategies; environmental changes could be assessed in time to prevent negative effects on fish or other aquatic life; and officials for the Equus Beds Ground-Water Recharge Demonstration project could use this information to prevent the possible degradation of the Equus Beds aquifer by choosing not to recharge when constituent concentrations in the source water are large. Constituent loads calculated from the regression equations may be useful for calculating total maximum daily loads (TMDL's), wh

Water-Resources Investigations Report↗