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USGS2018

Characteristics of tropical tree species in hyperspectral and multispectral data

Remote sensing has been hailed as a promising technology to provide spatially explicit information on tree species distribution. Such information is of high value for ecologists and forest managers, particularly in tropical environments in which it is acquired by costly field inventories performed at the plot level (∼1 ha). Over the last decade, hyperspectral sensors, usually on board airborne platforms, have been successfully employed for tropical tree species classification. Most of the studies focused on the improvement of the classification accuracy, without examining the sources of variability in canopy reflectance that contribute to discriminate among species. Trees of different species usually feature distinct crown structural and chemical characteristics defined by size, shape, leaf density, branching, pigment and nonpigment biochemical constituents, among others. Understanding the role of these characteristics on tree species discrimination is important to improve and optimize the use of hyperspectral data. Here, we show how spectral characteristics of tree species, from highly diverse tropical forests, are related to their chemical and structural properties. These spectral characteristics were retrieved by spectral mixture and feature analysis, using narrow-band data acquired in the optical domain (450–2400 nm). Finally, we assessed how the spectral resolution affects the classification accuracy and spectral separability.

Book chapter↗

USGS2000

Global ice-core research: Understanding and applying environmental records of the past

One way to study Earth’s past environmental conditions is to look at ice cores recovered from glaciers. Every year a layer of snow accumulates on glaciers, like a page in a history book, and eventually turns to ice. Like reading the pages of a history book, analyzing the layers in a glacial ice core for specific chemical and physical components is a way of “reading” the environmental changes of the past. Information from ice cores collected from Greenland and Antarctica already has provided important historical clues toward a better understanding of modern global environmental changes (Dansgaard and Oeschger, 1989; Lorius and others, 1989). Environmental changes are of major concern at low- or mid-latitude regions of our Earth simply because this is where 80 to 90 percent of the world’s human population live. Ice cores collected from isolated polar regions are, at best, proxy indicators of low- and mid-latitude environmental changes. Because polar icecore research is limiting in this sense, ice cores from low- and mid-latitude glaciers are being used to study past environmental changes in order to better understand and predict future environmental changes that may affect the populated regions of the world.

Idaho;Wyoming↗

USGS2020

Volcanological applications of unoccupied aircraft systems (UAS): Developments, strategies, and future challenges

Unoccupied aircraft systems (UAS) are developing into fundamental tools for tackling the grand challenges in volcanology; here, we review the systems used and their diverse applications. UAS can typically provide image and topographic data at two orders of magnitude better spatial resolution than space-based remote sensing, and close-range observations at temporal resolutions down to those of video frame rates. Responsive deployments facilitate dense time-series measurements, unique opportunities for geophysical surveys, sample collection from hostile environments such as volcanic plumes and crater lakes, and emergency deployment of ground-based sensors (and robots) into hazardous regions. UAS have already been used to support hazard management and decision-makers during eruptive crises. As technologies advance, increased system capabilities, autonomy and availability, supported by more diverse and lighter-weight sensors, will offer unparalleled potential for hazard monitoring. UAS are expected to provide opportunities for pivotal advances in our understanding of complex physical and chemical volcanic processes.

Volcanica↗

USGS2025

Hydrologic connectivity in floodplain systems: A multiscale review of concepts, metrics and management

Hydrologic connectivity (HC), particularly in floodplain systems, is pivotal in regulating ecosystem services by facilitating the movement of nutrients, sediments, chemicals, and biota. However, human interventions such as dam construction, levee installation, water management practices, and alterations in vegetation have significantly disrupted natural HC patterns globally. To provide a structured entry into the growing body of HC research, we conducted a systematic literature review of 1920 studies, analysing diverse definitions, influencing factors, quantification approaches, spatial and temporal scales, and management strategies. In addition to traditional review methods, our approach integrates keyword and cluster analysis to elucidate dominant research themes and trends across the literature. Our review reveals that the literature is heavily skewed towards research in North America and Europe (accounting for 72% of studies) and predominantly utilises field investigations, simulation modelling, and remote sensing integrated with geographic information systems. Although these methodologies have advanced our understanding, most studies focus on restricted spatial scales such as individual hillslopes, catchments, or stream networks and short temporal intervals, including single precipitation events or seasonal cycles. A narrow focus becomes a limitation when such studies do not contribute to broader efforts aimed at scaling insights across larger domains. These limitations highlight the potential benefits of innovative conceptual frameworks and quantification methods to better capture HC across broader environments and extended temporal scales. We conclude by discussing challenges in defining and quantifying floodplain HC and outlining potential future research directions to advance connectivity science and management, particularly in floodplain systems characterised by frequent hydrologic fluctuations, such as seasonal inundation and changing flow paths.

Hydrological Processes↗

USGS2005

Methods for synthesis of some jarosites

Experimental procedures in this report summarize attempts to synthesize potassium-, hydronium-, sodium-, and mixed-composition (hydronium-bearing) jarosites. After experimentation, some acceptable combinations of chemical and physical factors were found to routinely synthesize chemically different jarosites, which were used as part of a characterization study of some natural and synthetic jarosites. Jarosite is a sulfate mineral that is common in geologic settings where iron sulfide minerals such as pyrite or marcasite are subject to oxidative weathering. The presence of jarosite is a hallmark of acidic conditions. Jarosite forms as a secondary mineral in weathered sulfidic ores, coal mine wastes, on oxidizing mine wastes, and in streams affected by acid mine drainage. Jarosite also forms in acid-sulfate soils, as an alteration product of sulfidic shales, and in hydrothermal environments. Because of its important role in earth surface processes, the USGS is conducting mineralogical, geochemical, and remote sensing studies to characterize natural jarosites and to elucidate its stability range and conditions of formation. The presence of jarosite is not limited to the Earth. The recent identification of jarosite in the rocks at the Meridiani Planum on Mars has given planetary geologists reason to think that jarosite may be evidence of relict lacustrine (lake systems) or hydrothermal (water enriched magma emanations) systems on the Martian surface. USGS scientists are currently developing jarosite detection systems that can be placed on orbiting spectrometers. One day these systems may guide Mars landers to sites abundant in jarosite, sites most likely to have sheltered ancient Martian life.

Techniques and Methods↗

USGS2008

Methane hydrates

Gas hydrate is a solid, naturally occurring substance consisting predominantly of methane gas and water. Recent scientific drilling programs in Japan, Canada, the United States, Korea and India have demonstrated that gas hydrate occurs broadly and in a variety of forms in shallow sediments of the outer continental shelves and in Arctic regions. Field, laboratory and numerical modelling studies conducted to date indicate that gas can be extracted from gas hydrates with existing production technologies, particularly for those deposits in which the gas hydrate exists as pore-filling grains at high saturation in sand-rich reservoirs. A series of regional resource assessments indicate that substantial volumes of gas hydrate likely exist in sand-rich deposits. Recent field programs in Japan, Canada and in the United States have demonstrated the technical viability of methane extraction from gas-hydrate-bearing sand reservoirs and have investigated a range of potential production scenarios. At present, basic reservoir depressurisation shows the greatest promise and can be conducted using primarily standard industry equipment and procedures. Depressurisation is expected to be the foundation of future production systems; additional processes, such as thermal stimulation, mechanical stimulation and chemical injection, will likely also be integrated as dictated by local geological and other conditions. An innovative carbon dioxide and methane swapping technology is also being studied as a method to produce gas from select gas hydrate deposits. In addition, substantial additional volumes of gas hydrate have been found in dense arrays of grain-displacing veins and nodules in fine-grained, clay-dominated sediments; however, to date, no field tests, and very limited numerical modelling, have been conducted with regard to the production potential of such accumulations. Work remains to further refine: (1) the marine resource volumes within potential accumulations that can be produced through exploratory drilling programs; (2) the tools for gas hydrate detection and characterisation from remote sensing data; (3) the details of gas hydrate reservoir production behaviour through additional, well-monitored and longer duration field tests and (4) the understanding of the potential environmental impacts of gas hydrate resource development. The results of future production tests, in the context of varying market and energy supply conditions around the globe, will be the key to determine the ultimate timing and scale of the commercial production of natural gas from gas hydrates.

Book chapter↗

USGS2010

Visible and infrared remote imaging of hazardous waste: A review

One of the critical global environmental problems is human and ecological exposure to hazardous wastes from agricultural, industrial, military and mining activities. These wastes often include heavy metals, hydrocarbons and other organic chemicals. Traditional field and laboratory detection and monitoring of these wastes are generally expensive and time consuming. The synoptic perspective of overhead remote imaging can be very useful for the detection and remediation of hazardous wastes. Aerial photography has a long and effective record in waste site evaluations. Aerial photographic archives allow temporal evaluation and change detection by visual interpretation. Multispectral aircraft and satellite systems have been successfully employed in both spectral and morphological analysis of hazardous wastes on the landscape and emerging hyperspectral sensors have permitted determination of the specific contaminants by processing strategies using the tens or hundreds of acquired wavelengths in the solar reflected and/or thermal infrared parts of the electromagnetic spectrum. This paper reviews the literature of remote sensing and overhead imaging in the context of hazardous waste and discusses future monitoring needs and emerging scientific research areas.

Remote Sensing↗

USGS2006

Performance assessments of nuclear waste repositories: A dialogue on their value and limitations

Performance Assessment (PA) is the use of mathematical models to simulate the long-term behavior of engineered and geologic barriers in a nuclear waste repository; methods of uncertainty analysis are used to assess effects of parametric and conceptual uncertainties associated with the model system upon the uncertainty in outcomes of the simulation. PA is required by the U.S. Environmental Protection Agency as part of its certification process for geologic repositories for nuclear waste. This paper is a dialogue to explore the value and limitations of PA. Two “skeptics” acknowledge the utility of PA in organizing the scientific investigations that are necessary for confident siting and licensing of a repository; however, they maintain that the PA process, at least as it is currently implemented, is an essentially unscientific process with shortcomings that may provide results of limited use in evaluating actual effects on public health and safety. Conceptual uncertainties in a PA analysis can be so great that results can be confidently applied only over short time ranges, the antithesis of the purpose behind long-term, geologic disposal. Two “proponents” of PA agree that performance assessment is unscientific, but only in the sense that PA is an engineering analysis that uses existing scientific knowledge to support public policy decisions, rather than an investigation intended to increase fundamental knowledge of nature; PA has different goals and constraints than a typical scientific study. The “proponents” describe an ideal, sixstep process for conducting generalized PA, here called probabilistic systems analysis (PSA); they note that virtually all scientific content of a PA is introduced during the model-building steps of a PSA, they contend that a PA based on simple but scientifically acceptable mathematical models can provide useful and objective input to regulatory decision makers. The value of the results of any PA must lie between these two views and will depend on the level of knowledge of the site, the degree to which models capture actual physical and chemical processes, the time over which extrapolations are made, and the proper evaluation of health risks attending implementation of the repository. The challenge is in evaluating whether the quality of the PA matches the needs of decision makers charged with protecting the health and safety of the public.

Risk Analysis↗

USGS2018

Connectivity of streams and wetlands to downstream waters: An integrated systems framework

Interest in connectivity has increased in the aquatic sciences, partly because of its relevance to the Clean Water Act. This paper has two objectives: (1) provide a framework to understand hydrological, chemical, and biological connectivity, focusing on how headwater streams and wetlands connect to and contribute to rivers; and (2) briefly review methods to quantify hydrological and chemical connectivity. Streams and wetlands affect river structure and function by altering material and biological fluxes to the river; this depends on two factors: (1) functions within streams and wetlands that affect material fluxes; and (2) connectivity (or isolation) from streams and wetlands to rivers that allows (or prevents) material transport between systems. Connectivity can be described in terms of frequency, magnitude, duration, timing, and rate of change. It results from physical characteristics of a system, e.g., climate, soils, geology, topography, and the spatial distribution of aquatic components. Biological connectivity is also affected by traits and behavior of the biota. Connectivity can be altered by human impacts, often in complex ways. Because of variability in these factors, connectivity is not constant but varies over time and space. Connectivity can be quantified with field‐based methods, modeling, and remote sensing. Further studies using these methods are needed to classify and quantify connectivity of aquatic ecosystems and to understand how impacts affect connectivity.

Journal of the American Water Resources Associatio↗

USGS1987

Methods and applications in surface depression analysis

Gridded surface data sets are often incorporated into digital data bases, but extracting information from the data sets requires specialized raster processing techniques different from those historically used on remotely sensed and thematic data. Frequently, the information desired of a gridded surface is directly related to the topologic peaks and pits of the surface. A method for isolating these peaks and pits has been developed, and two examples of its application are presented. The perimeter of a pit feature is the highest-valued closed contour surrounding a minimum level. The method devised for finding all such contours is designed to operate on large raster surfaces. If the data are first inversely mapped, this algorithm will find surface peaks rather than pits. In one example the depressions, or pits, expressed in Digital Elevation Model data, are hydrologically significant potholes. Measurement of their storage capacity is the objective. The potholes are found and labelled as polygons; their watershed boundaries are found and attributes are computed. In the other example, geochemical surfaces, which were interpolated from chemical analyses of irregularly distributed stream sediment samples, were analyzed to determine the magnitude, morphology, and areal extent of peaks (geochemical anomalies).

Conference Paper↗

USGS2014

Dynamics of submarine groundwater discharge and associated fluxes of dissolved nutrients, carbon, and trace gases to the coastal zone (Okatee River estuary, South Carolina)

Multiple techniques, including thermal infrared aerial remote sensing, geophysical and geological data, geochemical characterization and radium isotopes, were used to evaluate the role of groundwater as a source of dissolved nutrients, carbon, and trace gases to the Okatee River estuary, South Carolina. Thermal infrared aerial remote sensing surveys illustrated the presence of multiple submarine groundwater discharge sites in Okatee headwaters. Significant relationships were observed between groundwater geochemical constituents and 226 Ra activity in groundwater with higher 226 Ra activity correlated to higher concentrations of organics, dissolved inorganic carbon, nutrients, and trace gases to the Okatee system. A system-level radium mass balance confirmed a substantial submarine groundwater discharge contribution of these constituents to the Okatee River. Diffusive benthic flux measurements and potential denitrification rate assays tracked the fate of constituents in creek bank sediments. Diffusive benthic fluxes were substantially lower than calculated radium-based submarine groundwater discharge inputs, showing that advection of groundwater-derived nutrients dominated fluxes in the system. While a considerable potential for denitrification in tidal creek bank sediments was noted, in situ denitrification rates were nitrate-limited, making intertidal sediments an inefficient nitrogen sink in this system. Groundwater geochemical data indicated significant differences in groundwater chemical composition and radium activity ratios between the eastern and western sides of the river; these likely arose from the distinct hydrological regimes observed in each area. Groundwater from the western side of the Okatee headwaters was characterized by higher concentrations of dissolved organic and inorganic carbon, dissolved organic nitrogen, inorganic nutrients and reduced metabolites and trace gases, i.e. methane and nitrous oxide, than groundwater from the eastern side. Differences in microbial sulfate reduction, organic matter supply, and/or groundwater residence time likely contributed to this pattern. The contrasting features of the east and west sub-marsh zones highlight the need for multiple techniques for characterization of submarine groundwater discharge sources and the impact of biogeochemical processes on the delivery of nutrients and carbon to coastal areas via submarine groundwater discharge.

South Carolina↗

USGS2013

Relating hyporheic fluxes, residence times, and redox-sensitive biogeochemical processes upstream of beaver dams

Abstract. Small dams enhance the development of patchy microenvironments along stream corridors by trapping sediment and creating complex streambed morphologies. This patchiness drives intricate hyporheic flux patterns that govern the exchange of O 2 and redox-sensitive solutes between the water column and the stream bed. We used multiple tracer techniques, naturally occurring and injected, to evaluate hyporheic flow dynamics and associated biogeochemical cycling and microbial reactivity around 2 beaver dams in Wyoming (USA). High-resolution fiber-optic distributed temperature sensing was used to collect temperature data over 9 vertical streambed profiles and to generate comprehensive vertical flux maps using 1-dimensional (1-D) heat-transport modeling. Coincident with these locations, vertical profiles of hyporheic water were collected every week and analyzed for dissolved O 2 , pH, dissolved organic C, and several conservative and redox-sensitive solutes. In addition, hyporheic and net stream aerobic microbial reactivity were analyzed with a constant-rate injection of the biologically sensitive resazurin (Raz) smart tracer. The combined results revealed a heterogeneous system with rates of downwelling hyporheic flow organized by morphologic unit and tightly coupled to the redox conditions of the subsurface. Principal component analysis was used to summarize the variability of all redox-sensitive species, and results indicated that hyporheic water varied from oxic-stream-like to anoxic-reduced in direct response to the hydrodynamic conditions and associated residence times. The anaerobic transition threshold predicted by the mean O 2 Damko ¨hler number seemed to overestimate the actual transition as indicated by multiple secondary electron acceptors, illustrating the gradient nature of anaerobic transition. Temporal flux variability in low-flux morphologies generated a much greater range in hyporheic redox conditions compared to high-flux zones, and chemical responses to changing flux rates were consistent with those predicted from the empirical relationship between redox condition and residence time. The Raz tracer revealed that hyporheic flow paths have strong net aerobic respiration, particularly at higher residence time, but this reactive exchange did not affect the net stream signal at the reach scale.

Freshwater Science↗

USGS2001

Evidence and characteristics of hydrolytic disproportionation of organic matter during metasomatic processes

Petroleum-geochemical analyses of carbonaceous regionally metamorphosed rocks, carbonaceous rocks from ore deposits, and alkalic plutonic rocks from diverse settings, demonstrated the presence of very low to moderately low concentrations of solvent-extractable organic matter, this observation in spite of the fact that some of these rocks were exposed to extremely high metamorphic temperatures. Biomarker and ??13C analyses established that the extractable organic matter originated as sedimentary-derived hydrocarbons. However, the chemistry of the extractable bitumen has been fundamentally transformed from that found in sediment bitumen and oils. Asphaltenes and resins, as defined in the normal petroleum-geochemical sense, are completely missing. The principal aromatic hydrocarbons present in oils and sediment bitumens (especially the methylated naphthalenes) are either in highly reduced concentrations or are missing altogether, Instead, aromatic hydrocarbons typical of sediment bitumens and oils are very minor, and a number of unidentified compounds and oxygen-bearing compounds are dominant. Relatively high concentrations of alkylated benzenes are typical. The polar "resin" fraction, eluted during column chromatography, is the principal compound group, by weight, being composed of six to eight dominant peaks present in all samples, despite the great geologic diversity of the samples. These, and other, observations suggest that a strong drive towards equilibrium exists in the "bitumen." Gas chromatograms of the saturated hydrocarbons commonly have a pronounced hump in both the n-paraffins and naphthenes, centered near the C19 to C26 carbon numbers, and a ubiquitos minimum in the n-paraffin distribution near n-C12 to n-C14. Multiple considerations dictate that the bitumen in the samples is indigenous and did not originate from either surficial field contamination or from laboratory procedures. Our observations are consistent with the hydrolytic disproportion of organic matter (HDOM), in which water and organic matter, including hydrocarbons, easily exchange hydrogen or oxygen with one another under certain conditions (Helgeson et al., 1993). The process appears to take place via well-known organic-chemical redox reaction pathways and is most evident in open-fluid systems. The conclusion that HDOM took place in the analyzed samples, thus producing the chemistry of the extractable bitumen, is supported by numerous previously published organic-geochemical studies of metamorphic, volcanic, plutonic, and ore-deposit-related rocks by other investigators. HDOM is suggested as an unrecognized geologic agent of fundamental importance. The process appears to control major chemical reactions in diverse geologic environments including, but not limited to, petroleum geology and geochemistry, regional metamorphism, and base- and precious-metal ore deposition. Copyright ?? 2001 Elsevier Science Ltd.

Geochimica et Cosmochimica Acta↗

USGS2001

Geologic studies in Alaska by the U.S. Geological Survey, 1999

The collection of nine papers that follow continue the series of U.S. Geological Survey (USGS) investigative reports in Alaska under the broad umbrella of the geologic sciences. The series presents new and sometimes preliminary findings that are of interest to earth scientists in academia, government, and industry; to land and resource managers; and to the general public. Reports presented in Geologic Studies in Alaska cover a broad spectrum of topics from various parts of the State (fig. 1), serving to emphasize the diversity of USGS efforts to meet the Nation's needs for earth-science information in Alaska. The papers in this volume are organized under the topics: Hazards, Geologic Framework, Environment and Climate, and Resources. This organization is intended to reflect the scope and objectives of USGS geologic programs currently active in Alaska. The two Hazards studies discuss volcano-related topics in the seismically active southcentral Alaska region. The first paper revisits the eruptive events of Redoubt Volcano that occurred more than a decade ago and the subsequent development of the Alaska Volcano Observatory (AVO). This treatise documents the historic impact of this eruption and briefly summarizes the state of our knowledge of the other Cook Inlet, Alaska Peninsula, and Aleutian Island volcanoes. Finally, it discusses the recent role that AVO has had in seismic station installation and hazard assessment at volcanically active sites throughout the world. The second paper discusses the eruptive history of Snowy Mountain in the upper Alaska Peninsula. Because subsets of its 25-30 lava flows erupted as packages in short episodes, calculation of the volcano's lifetime average volumetric eruption rate is problematic. A portion of the cone was hydrothermally weakened and collapsed in the late Holocene producing a 22-km2 debris avalanche. Geologic Framework studies provide background information that is the scientific basis for present and future earth science investigations. The first paper compares and contrasts the Insular-Intermontane suture zone (IISZ) of southeast Alaska with the Adria-Europe suture zone (AESZ) of Switzerland and Hungary. The study develops the hypothesis that the zones have distinct differences as well as similarities and neither is a simple lithotectonic terrane boundary. The second paper discusses the relation among volcanic, glacial, and tectonic activity in the Cold Bay and False Pass 1 :250,000-scale quadrangles on the Alaska Peninsula. During Pleistocene time, continental-shelf glaciations and two massive volcanic centers were the dominant controls over landscape development. The third paper gives detailed geologic information for Paleozoic rocks within the Taylor Mountains D-1 quadrangle portion of the Holitna Lowland of southwestern Alaska. Because of the excellent preservation of megafossils, these Silurian and Ordovician strata lend themselves to detailed statigraphic investigations. Further, low thermal alteration indices of this area have made them a potential target of petroleum exploration. The final report in this section discusses the development of a new spectral enhancement approach for interpreting Multispectral Scanner (MSS) and Thematic Mapper (TM) satellite images. This technique enhances the use of remote sensing data in identifying geologic units in areas that have been poorly investigated. This study used this technique to better define the distribution of a JMtu (mafic, ultramafic, and sedimentary) unit and a PzZrqs (pelitic and quartzitic schist) unit. Environment and climate studies are the emphasis of two papers. One presents the first radiocarbon-dated postglacial vegetation history of the Kenai Mountains of southcentral Alaska. This reconstruction is the result of the analysis of pollen assemblages and peat from sediments collected in Tern Lake and presents a minimum age for deglaciation of these interior valleys at 9,31 0±200 yr B .P. Current vegetation, however, developed within the past ca. 2,500 years. A second study discusses the cycling of arsenic and cadmium in sub-arctic boreal forest ecosystems typical of interior Alaska and defines the importance of various natural (geogenic) sources. The transport and uptake into vegetation of these elements from soils developed from loess as well as soils developed from the major rock units is presented. The bioaccumulation of cadmium in willow (Salix sp.) and its potential consequence to the health of browsing animals is discussed. Papers related to resource issues comprise the topic of the final report. This paper presents a brief statistical summary of the geochemistry of rock samples collected in the east-central portion of the Eagle 1 :250,000-scale quadrangle. This study helps define the rock unit source of both resource- and environmental-based chemical elements of interest in the Fortymile mining district. Two bibliographies at the end of the volume list reports covering Alaska earth science topics in USGS publications during 1999 and reports about Alaska by USGS authors in non-USGS publications during the same period.

Alaska↗

USGS1999

Overview of the Mars Pathfinder Mission: Launch through landing, surface operations, data sets, and science results

Mars Pathfinder successfully landed at Ares Vallis on July 4, 1997, deployed and navigated a small rover about 100 m clockwise around the lander, and collected data from three science instruments and ten technology experiments. The mission operated for three months and returned 2.3 Gbits of data, including over 16,500 lander and 550 rover images, 16 chemical analyses of rocks and soil, and 8.5 million individual temperature, pressure and wind measurements. Path‐finder is the best known location on Mars, having been clearly identified with respect to other features on the surface by correlating five prominent horizon features and two small craters in lander images with those in high‐resolution orbiter images and in inertial space from two‐way ranging and Doppler tracking. Tracking of the lander has fixed the spin pole of Mars, determined the precession rate since Viking 20 years ago, and indicates a polar moment of inertia, which constrains a central metallic core to be between 1300 and ∼2000 km in radius. Dark rocks appear to be high in silica and geochemically similar to anorogenic andesites; lighter rocks are richer in sulfur and lower in silica, consistent with being coated with various amounts of dust. Rover and lander images show rocks with a variety of morphologies, fabrics and textures, suggesting a variety of rock types are present. Rounded pebbles and cobbles on the surface as well as rounded bumps and pits on some rocks indicate these rocks may be conglomerates (although other explanations are also possible), which almost definitely require liquid water to form and a warmer and wetter past. Air‐borne dust is composed of composite silicate particles with a small fraction of a highly magnetic mineral, interpreted to be most likely maghemite; explanations suggest iron was dissolved from crustal materials during an active hydrologic cycle with maghemite freeze dried onto silicate dust grains. Remote sensing data at a scale of a kilometer or greater and an Earth analog correctly predicted a rocky plain safe for landing and roving with a variety of rocks deposited by catstrophic floods, which are relatively dust free. The surface appears to have changed little since it formed billions of years ago, with the exception that eolian activity may have deflated the surface by ∼3–7 cm, sculpted wind tails, collected sand into dunes, and eroded ventifacts (fluted and grooved rocks). Pathfinder found a dusty lower atmosphere, early morning water ice clouds, and morning near‐surface air temperatures that changed abruptly with time and height. Small scale vortices, interpreted to be dust devils, were observed repeatedly in the afternoon by the meteorology instruments and have been imaged.

Journal of Geophysical Research E: Planets↗

USGS2004

Improved 206Pb/238U microprobe geochronology by the monitoring of a trace-element-related matrix effect; SHRIMP, ID-TIMS, ELA-ICP-MS and oxygen isotope documentation for a series of zircon standards

Precise isotope dilution-thermal ionisation mass spectrometry (ID-TIMS) documentation is given for two new Palaeozoic zircon standards (TEMORA 2 and R33). These data, in combination with results for previously documented standards (AS3, SL13, QGNG and TEMORA 1), provide the basis for a detailed investigation of inconsistencies in 206Pb/238U ages measured by microprobe. Although these ages are normally consistent between any two standards, their relative age offsets are often different from those established by ID-TIMS. This is true for both sensitive high-resolution ion-microprobe (SHRIMP) and excimer laser ablation-inductively coupled plasma-mass spectrometry (ELA-ICP-MS) dating, although the age offsets are in the opposite sense for the two techniques. Various factors have been investigated for possible correlations with age bias, in an attempt to resolve why the accuracy of the method is worse than the indicated precision. Crystallographic orientation, position on the grain-mount and oxygen isotopic composition are unrelated to the bias. There are, however, striking correlations between the 206Pb/238U age offsets and P, Sm and, most particularly, Nd abundances in the zircons. Although these are not believed to be the primary cause of this apparent matrix effect, they indicate that ionisation of 206Pb/238U is influenced, at least in part, by a combination of trace elements. Nd is sufficiently representative of the controlling trace elements that it provides a quantitative means of correcting for the microprobe age bias. This approach has the potential to reduce age biases associated with different techniques, different instrumentation and different standards within and between laboratories. Crown Copyright ?? 2004 Published by Elsevier B.V. All rights reserved.

Chemical Geology↗

USGS1994

Remote sensing and airborne geophysics in the assessment of natural aggregate resources

Natural aggregate made from crushed stone and deposits of sand and gravel is a vital element of the construction industry in the United States. Although natural aggregate is a high volume/low value commodity that is relatively abundant, new sources of aggregate are becoming increasingly difficult to find and develop because of rigid industry specifications, political considerations, development and transporation costs, and environmental concerns, especially in urban growth centers where much of the aggregate is used. As the demand for natural aggregate increases in response to urban growth and the repair and expansion of the national infrastructure, new sources of natural aggregate will be required. The USGS has recognized the necessity of developing the capability to assess the potential for natural aggregate sources on Federal lands; at present, no methodology exists for systematically describing and evaluating potential sources of natural aggregate. Because remote sensing and airborne geophysics can detect surface and nearsurface phenomena, these tools may useful for detecting and mapping potential sources of natural aggregate; however, before a methodology for applying these tools can be developed, it is necessary to understand the type, distribution, physical properties, and characteristics of natural aggregate deposits, as well as the problems that will be encountered in assessing their potential value. There are two primary sources of natural aggregate: (1) exposed or near-surface igneous, metamorphic, and sedimentary bedrock that can be crushed, and (2) deposits of sand and gravel that may be used directly or crushed and sized to meet specifications. In any particular area, the availability of bedrock suitable for crushing is a function of the geologic history of the area - the processes that formed, deformed, eroded and exposed the bedrock. Deposits of sand and gravel are primarily surficial deposits formed by the erosion, transportation by water and ice, and deposition of bedrock fragments. Consequently, most sand and gravel deposits are Tertiary or Quaternary in age and are most common in glaciated areas, alluvial basins, and along rivers and streams. The distribution of potential sources of natural aggregate in the United States is closely tied to physiography and the type of bedrock that occurs in an area. Using these criteria, the United States can be divided into 12 regions: western mountain ranges, alluvial basins, Columbia Plateau, Colorado Plateau and Wyoming basin, High Plains, nonglaciated central region, glaciated central region, Piedmont Blue Ridge region, glaciated northeastern and Superior uplands, Atlantic and Gulf coastal plain, Hawaiian Islands, and Alaska. Each region has similar types of natural aggregate sources within its boundary, although there may be wide variations in specific physical and chemical characteristics of the aggregates within a region. Conventional exploration for natural aggregate deposits has been largely a ground-based operation (field mapping, sampling, trenching and augering, resistivity), although aerial photos and topographic maps have been extensively used to target possible deposits for sampling and testing. Today, the exploration process also considers other factors such as the availability of the land, space and water supply for processing purposes, political and environmental factors, and distance from the market; exploration and planning cannot be separated. There are many physical properties and characteristics by which aggregate material is judged to be acceptable or unacceptable for specific applications; most of these properties and characteristics pertain only to individual aggregate particles and not to the bulk deposit. For example, properties of crushed stone aggregate particles such as thermal volume change, solubility, oxidation and hydration reactivity, and particle strength, among many others, are important consi

Open-File Report↗

USGS2009

Can kittiwakes smell? Experimental evidence in a larid species

Birds have long been thought to have a poor sense of smell, although they have the proper anatomical and neurological structures for detecting olfactory cues ( Roper 1999 ). However, in the past decade several bird species have been shown to use smell in various contexts, such as foraging ( Nevitt et al. 1995 ), navigation ( Wallraff 2004 ), selection of nest materials ( Petit et al. 2002 , Gwinner & Berger 2008 ), nest location ( Bonadonna & Bretagnolle 2002 ), predator avoidance ( Amo et al. 2008 , Roth et al. 2008 ) and recognition of conspecifics ( Hagelin et al. 2003 ) or mates ( Bonadonna & Nevitt 2004 , for reviews see Roper 1999 , Hagelin & Jones 2007 , Nevitt 2008 ). The evidence, however, mainly concerns the Procellariiformes (petrels, shearwaters and albatrosses), a group that has long been suspected of using olfaction because of their strong body odour, highly developed olfactory bulb, nocturnal habits and burrow‐nesting ( Nevitt & Bonadonna 2005 , Nevitt 2008 ). Evidence of olfactory ability is scarce in other avian taxa. Exceptions include, for instance, Turkey Vulture Cathartes aura ( Smith & Paselk 1986 ), Brown Kiwi Apteryx australis ( Wenzel 1968 ), Homing Pigeon Columba livia ( Wallraff 2004 ), Blue Tit Cyanistes caeruleus ( Petit et al. 2002 , Amo et al. 2008 ), Domestic Fowl Gallus domesticus ( McKeegan et al. 2005 ), Kakapo Strigops habroptilus ( Hagelin 2004 ), Yellow‐backed Chattering Lory Lorius garrulus flavopalliatus ( Roper 2003 ), African Penguin Spheniscus demersus ( Cunningham et al. 2008 ) and Crested Auklets Aethia cristatella ( Hagelin et al. 2003 ). The Laridae, including Black‐legged Kittiwakes Rissa tridactyla , are diurnal, have relatively small olfactory bulbs ( Bang & Cobb 1968 ) and do not appear to use olfaction to locate food ( Frings et al. 1955 , Lequette et al. 1989 , Verheyden & Jouventin 1994 ). Kittiwakes use vocal cues in mate and parent/offspring recognition ( Wooller 1978 , Mulard & Danchin 2008 ), suggesting that olfaction may be at best secondary in those contexts. However, mates commonly allopreen, potentially exposing them to their mate’s chemical compounds. Moreover, the relative size of the olfactory bulb may be a poor predictor of olfactory abilities ( Hagelin 2004 , Mennerat et al. 2005 ). The aim of this experimental study was to assess whether Black‐legged Kittiwakes are able to detect odours added to the nest.

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