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Effects of fire temperature on the physical and chemical characteristics of the ash from two plots of Cork oak (Quercus Suber)

Cork oak, (Quercus suber) is widely distributed in the Mediterranean region, an area subject to frequent fires. The ash produced by burning can have impacts on the soil status and water resources that can differ according to the temperature reached during fire and the characteristics of the litter, defined as the dead organic matter accumulated on the soil surface prior to the fire. The aim of this work is to determine the physical and chemical characteristics of ash produced in laboratory experiments to approximate conditions typical of fires in this region. The litter of Quercus suber collected from two different plots on the Iberian Peninsula, Mas Bassets (Catalonia) and Albufeira (Portugal), was combusted at different temperatures for 2h. We measured Mass Loss (ML per cent), ash colour and CaCO 3 content, pH, Electrical Conductivity (EC) and the major cations (Ca 2+ , Mg 2+ , K + and Na + ) released from ash slurries created by mixing ash with deionized water. The results showed that ML per cent is higher at all temperatures in Albufeira samples compared to Mas Bassets samples, except at 550??C, and the rate of loss increases faster with temperature than the Mas Bassets samples. At 150??C the ash colour is yellowish, becoming reddish at 200- 250??C and black at 300??C. Above 400??C the ash is grey/white. This thermal degradation is mostly observed in Albufeira litter. The formation of CaCO 3 was identified at a lower temperature in Albufeira litter. At temperatures <300??C, pH and EC values are lower, rising at higher temperatures, especially in Albufeira slurries. The concentration of cations at lower temperatures does not differ substantially from the unburned sample except for Mg 2+ . The cation concentration increases at medium temperatures and decrease at higher temperatures, especially the concentration of divalent cations. The monovalent cations showed a larger concentration at moderate temperatures, mainly in Albufeira ash slurries. The analysis of the Ca:Mg ratio also showed that for the same temperature, a higher severity results for Albufeira litter. Potential negative effects on soil properties are observed at medium and higher temperatures. These negative effects include a higher percentage of mass loss, meaning more soil may be exposed to erosion, higher pH values and greater cation release from ash, especially monovalalent cations (K + ,Na + ) in higher proportions than the divalent ions (Ca 2+ , Mg 2+ ), that can lead to impacts on soil physical properties like aggregate stability. Furthermore, the ions in ash may alter soil chemistry which may be detrimental to some plants thus altering the recovery of these ecosystems after fire. Low intensity prescribed fire can be a useful tool to land management in these sites, due to the reduced effects of fire temperatures on the physical and chemical properties of surface litter, and can reduce the risk of high temperature wildland fires by reducing fuel loadings. From the perspective of water resources, lower fire temperatures produce fewer impacts on the chemistry of overland flow and there is less probability that the soil surface will be eroded. Copyright ?? 2009 John Wiley & Sons, Ltd.

Land Degradation and Development

Physical and chemical properties of water and sediments, Grand Portage and Wauswaugoning Bays, Lake Superior, Grand Portage Indian Reservation, northeastern Minnesota, 1993-96

This report is a compilation of data on the physical and chemical properties of water and sediments in Grand Portage and Wauswaugoning Bays of Lake Superior along the shoreline of the Grand Portage Indian Reservation. The data were collected during 1993-96 by the U.S. Geological Survey in cooperation with the Grand Portage Indian Reservation. The data include: (1) temperature, pH, and specific conductance measurements and dissolved oxygen concentrations; (2) Secchi disk transparency, alkalinity, and turbidity measurements; (3) fecal Coliform and fecal Streptococcal bacteria colony counts (per 100 milliliters of sample water); (4) major and minor ion, nutrient, and trace-metal concentrations; (5) dissolved and suspended residue concentrations; (6) pesticide, phenol, and asbestos concentrations; (7) suspended sediment trace-metal concentrations; and (8) bottom sediment trace-metal concentrations. Water samples were collected from nine sites; suspended and bottom sediment samples were collected from five sites. The data in this report can be used to evaluate present water-quality conditions and as a reference to monitor potential long-term changes in these conditions.

Minnesota

Chemical and physical data for the Flaming Gorge Reservation area, Utah and Wyoming, 1973-75

This report presents the basic data that were collected by the U.S. Geological Survey during a study of the chemical quality of water in Flaming Gorge Reservoir. An interpretive report will follow. The basic data were collected from the reservoir during the period August 1973 to October 1975. The reservoir was sampled for chemical and physical data at 25 sites. The sites are shown in figure 1 and the data are listed in tables 1-3. In addition to the data collected from the reservoir, streamflow and water-quality data are collected on a continuing basis at sites on the major streams flowing into and out of the reservoir. The inflow sites are Green River near Green River, Wyo., Blacks Fork near Little America, Wyo., and Henrys Fork near Manila, Utah (fig. 1). The out- flow site is Green River near Greendale, Utah. These data are published in an annual series, and for the period of this project the data are in U.S. Geological Survey (197l-75a, b, c, d).

Utah, Wyoming

Effects of urban development on stream ecosystems alongthe Front Range of the Rocky Mountains, Colorado and Wyoming

The U.S. Geological Survey (USGS) conducted a study from 2002 through 2003 through its National Water-Quality Assessment (NAWQA) Program to determine the effects of urbanization on the physical, chemical, and biological characteristics of stream ecosystems along the Front Range of the Rocky Mountains. The objectives of the study were to (1) examine physical, chemical, and biological responses at sites ranging from minimally to highly developed; (2) determine the major physical, chemical, and landscape variables affecting aquatic communities at these sites; and (3) evaluate the relevance of the results to the management of water resources in the South Platte River Basin.

Fact Sheet

Selected water-quality data from Fallen Leaf Lake, El Dorado County, California, June through October 1974

In 1974 the U.S. Geological Survey entered into a cooperative agreement with the California Department of Water Resources to study the limnology of Fallen Leaf Lake and adjacent streams. The lake is in California, near the crest of the Sierra Nevada about 23 miles southwest of Reno, Nevada (fig. 1). The study was undertaken to help develop a better understanding of selected characteristics of a high-altitude dilute-solution lake-stream system and the effect of man on the system. Fallen Leaf Lake and the adjacent streams were chosen for the study because the lake represents an alpine system in a basin that has had limited development for a number of years. Recently, local and state groups have become extremely interested in the effects of man's activities on the condition of the lake. The study was designed to: 1. Provide data on selected physical, chemical, and biological characteristics of Fallen Leaf Lake and adjacent streams, 2. Determine whether the magnitude and changes in magnitude of a number of physical, chemical, and biological variables are affected by natural or cultural processes, 3. Characterize a high-altitude, dilute-solution aquatic ecosystem, 4. Compare and contrast the physical, chemical, and biological characteristics of Fallen Leaf Lake and adjacent streams with other lakes in the area.

California

Effects of physical and chemical heterogeneity on water-quality samples obtained from wells

Factors that affect the mass of chemical constituents entering a well include the distributions of flow rate and chemical concentrations along and near the screened or open section of the well. Assuming a layered porous medium (with each layer being characterized by a uniform hydraulic conductivity and chemical concentration), a knowledge of the flow from each layer along the screened zone and of the chemical concentrations in each layer enables the total mass entering the well to be determined. Analyses of hypothetical systems and a site at Galloway, NJ, provide insight into the temporal variation of water-quality data observed when withdrawing water from screened wells in heterogeneous ground-water systems. The analyses of hypothetical systems quantitatively indicate the cause-and-effect relations that cause temporal variability in water samples obtained from wells. Chemical constituents that have relatively uniform concentrations with depth may not show variations in concentrations in the water discharged from a well after the well is purged (evacuation of standing water in the well casing). However, chemical constituents that do not have uniform concentrations near the screened interval of the well may show variations in concentrations in the well discharge water after purging because of the physics of ground-water flow in the vicinity of the screen. Water-quality samples were obtained through time over a 30 minute period from a site at Galloway, NJ. The water samples were analyzed for aromatic hydrocarbons, and the data for benzene, toluene, and meta+para xylene were evaluated for temporal variations. Samples were taken from seven discrete zones, and the flow-weighted concentrations of benzene, toluene, and meta+para xylene all indicate an increase in concentration over time during pumping. These observed trends in time were reproduced numerically based on the estimated concentration distribution in the aquifer and the flow rates from each zone. The results of the hypothetical numerical experiments and the analysis of the field data both corroborate the impact of physical and chemical heterogeneity in the aquifer on water-quality samples obtained from wells. If temporal variations in concentrations of chemical constituents are observed, they may indicate variability in the ground-water system being sampled, which may give insight into the chemical distributions within the aquifer and provide guidance in the positioning of new sampling devices or wells.

Groundwater

Physical and chemical characteristics of water in coal-mine ponds of eastern Oklahoma.

Coal-mine ponds cover 4000 acres and have a storage capacity of about 100 000 acre-feet. They are important wild-life habitats and contribute locally to agricultural and municipal water supply. The physical and chemical properties of the water are very variable. By and large, the pond waters showed a lack of mixing and thermal stratification with bottom to surface temperatures differing by up to 30oC over 20 ft depth in July. The medium pH was 7.7, except for ponds associated with the Secor coal bed (pH 3.3). Sulphate was the principal ion in the mine pond water. Other chemicals varied with the associated coal-bed. Chloride concentrations were 11 mg/L or less, except for ponds associated with the Dowson coal (140 mg/L). Dissolved concentration was low 40 mu g/L, except in ponds associated with the Secor (3000 mu g/L and Dowson (2100) coals. Dissolved manganese was less than 1500 micrograms/L except for Secor (35 000), Dowson (4300) and Weir-Pittsburg (3700 micrograms/L). -M.J.Haigh

Oklahoma Geology Notes

Occurrence and distribution of fecal indicator bacteria, and physical and chemical indicators of water quality in streams receiving discharge from Dallas/Fort Worth International Airport and vicinity, North-Central Texas, 2008

This report, done by the U.S. Geological Survey in cooperation with Dallas/Fort Worth International (DFW) Airport in 2008, describes the occurrence and distribution of fecal indicator bacteria (fecal coliform and Escherichia [E.] coli), and the physical and chemical indicators of water quality (relative to Texas Surface Water Quality Standards), in streams receiving discharge from DFW Airport and vicinity. At sampling sites in the lower West Fork Trinity River watershed during low-flow conditions, geometric mean E. coli counts for five of the eight West Fork Trinity River watershed sampling sites exceeded the Texas Commission on Environmental Quality E. coli criterion, thus not fully supporting contact recreation. Two of the five sites with geometric means that exceeded the contact recreation criterion are airport discharge sites, which here means that the major fraction of discharge at those sites is from DFW Airport. At sampling sites in the Elm Fork Trinity River watershed during low-flow conditions, geometric mean E. coli counts exceeded the geometric mean contact recreation criterion for seven (four airport, three non-airport) of 13 sampling sites. Under low-flow conditions in the lower West Fork Trinity River watershed, E. coli counts for airport discharge sites were significantly different from (lower than) E. coli counts for non-airport sites. Under low-flow conditions in the Elm Fork Trinity River watershed, there was no significant difference between E. coli counts for airport sites and non-airport sites. During stormflow conditions, fecal indicator bacteria counts at the most downstream (integrator) sites in each watershed were considerably higher than counts at those two sites during low-flow conditions. When stormflow sample counts are included with low-flow sample counts to compute a geometric mean for each site, classification changes from fully supporting to not fully supporting contact recreation on the basis of the geometric mean contact recreation criterion. All water temperature measurements at sampling sites in the lower West Fork Trinity River watershed were less than the maximum criterion for water temperature for the lower West Fork Trinity segment. Of the measurements at sampling sites in the Elm Fork Trinity River watershed, 95 percent were less than the maximum criterion for water temperature for the Elm Fork Trinity River segment. All dissolved oxygen concentrations were greater than the minimum criterion for stream segments classified as exceptional aquatic life use. Nearly all pH measurements were within the pH criterion range for the classified segments in both watersheds, except for those at one airport site. For sampling sites in the lower West Fork Trinity River watershed, all annual average dissolved solids concentrations were less than the maximum criterion for the lower West Fork Trinity segment. For sampling sites in the Elm Fork Trinity River, nine of the 13 sites (six airport, three non-airport) had annual averages that exceeded the maximum criterion for that segment. For ammonia, 23 samples from 12 different sites had concentrations that exceeded the screening level for ammonia. Of these 12 sites, only one non-airport site had more than the required number of exceedances to indicate a screening level concern. Stormflow total suspended solids concentrations were significantly higher than low-flow concentrations at the two integrator sites. For sampling sites in the lower West Fork Trinity River watershed, all annual average chloride concentrations were less than the maximum annual average chloride concentration criterion for that segment. For the 13 sampling sites in the Elm Fork Trinity River watershed, one non-airport site had an annual average concentration that exceeded the maximum annual average chloride concentration criterion for that segment.

Scientific Investigations Report

Characterization of the biological, physical, and chemical properties of a toxic thin layer in a temperate marine system

The distribution of plankton in the ocean is patchy across a wide range of spatial and temporal scales. One type of oceanographic feature that exemplifies this patchiness is a ‘thin layer’. Thin layers are subsurface aggregations of plankton that range in vertical thickness from centimeters to a few meters, which may extend horizontally for kilometers and persist for days. We undertook a field campaign to characterize the biological, physical, and chemical properties of thin layers in Monterey Bay, California (USA), an area where these features can be persistent. The particle aggregates (marine snow) sampled in the study had several quantifiable properties indicating how the layer was formed and how its structure was maintained. Particles were more elongated above the layer, and then changed orientation angle and increased in size within the layer, suggesting passive accumulation of particles along a physical gradient. The shift in particle aggregate orientation angle near the pycnocline suggests that shear may also have played a role in generating the thin layer. Pseudo-nitzschia spp. were the most abundant phytoplankton within the thin layer. Further, both dissolved and particulate domoic acid were highest within the thin layer. We suggest that phosphate stress is responsible for the formation of Pseudo-nitzschia spp. aggregates. This stress together with increased nitrogen in the layer may lead to increased bloom toxicity in the subsurface blooms of Pseudo-nitzschia spp. Several zooplankton groups were observed to aggregate above and below the layer. With the knowledge that harmful algal bloom events can occur in subsurface thin layers, modified sampling methods to monitor for these hidden incubators could greatly improve the efficacy of early-warning systems designed to detect harmful algal blooms in coastal waters.

Marine Ecology Progress Series (MEPS)

Physical and chemical stressors on algal, invertebrate, and fish communities in 14 Milwaukee area streams, 2004–2013

In 2004, the U.S. Geological Survey (USGS) began sampling 14 wadable streams in urban or urbanizing watersheds near Milwaukee, Wisconsin. The overall goal of the study is to assess the health of the aquatic communities in the Milwaukee Metropolitan Sewerage District planning area to inform current and future watershed management. In addition to collection of biological data on aquatic communities, physical and chemical data were also collected to evaluate effects of potential environmental stressors on the aquatic communities. This fact sheet summarizes the primary results of the study from 2004 to 2013. Detailed information is described in Scudder Eikenberry and others (2020a), and all data are available in Scudder Eikenberry and others (2020b; https://doi.org/10.5066/P9FWMODL ).

Wisconsin

Physical and chemical characteristics of Terrace Reservoir, Conejos County, Colorado, May 1994 through May 1995

Terrace Reservoir receives drainage of low-pH, metal-enriched water from mineralized areas, including the Summitville Mine, within the Alamosa River Basin. Drainage from the Summitville Mine has contributed a substantial part of the metal load to Terrace Reservoir. From May 1994 through May 1995, a study was done by the U.S. Geological Survey, in cooperation with the U.S. Environmental Protection Agency, to evaluate the physical and chemical characteristics of Terrace Reservoir. Terrace Reservoir was thermally stratified from about mid-May through August 1994. Thermal stratification was absent from September\x111994through March 1995. During periods of stratification, underflow of the Alamosa River was predominant, and residence times of the underflow were shortened by 40 to 75\x11percent of the theoretical residence times for a well-mixed reservoir. Transport and deposition of suspended solids in Terrace Reservoir varied spatially and temporally. Most of the suspended solids were deposited in Terrace Reservoir. The concentration of dissolved oxygen in the reservoir varied little spatially or temporally and generally was within a few tenths of the dissolved-oxygen concentration of the inflow. The pH of water in the reservoir generally ranged from about 4.0 to about 7.0, depending on date, depth, and location. The largest pH values were measured during May. A markeddecrease of about 1.5\x11pH units occurred at site T5 in the reservoir about mid-June. The pH of the reservoir remained at or below 5.5 from mid-June through November. Dissolved-metal concentrations varied spatially and temporally in response to several factors, which included inflow characteristics, reservoir stratification and mixing, inflow-routing and flow-through patterns, residence times, sedimentation, dissolved oxygen, and pH.Inflow chemistry is the dominant controlling factor of metal chemistry within Terrace Reservoir.During periods of stratification, large vertical variations in metal concentrations occurred. The highest metal concentrations in the reservoir generally were measured in the hypolimnion between June and August. During June, epilimnetic water of the reservoir had pH values greater than 6.0, and metal concentrations were lower than hypolimnetic concentrations. In the hypolimnion, pH values were less than 5.5. The difference between the chemistry of the epilimnion and the hypolimnion was due to differences in flow routing and residence times of water in those respective layers. The dissolved-metal concentrations were larger during July and August than during June.During September, small vertical variations in metalconcentrations occurred, and the dissolved-metal concentrations were nearly equivalent to the average August metal concentrations, indicatingthat the metal concentrations measured during September resulted largely from reservoir mixing.During March, the largest metal concentrationsoccurred in the epilimnion, where pH was about 5.5; in the hypolimnion, where the pH was about 6.0, dissolved-metal concentrations were substantially lower and reflected inflow concentrations.

Colorado

Physical and chemical characteristics of Terrace Reservoir, Conejos County, Colorado, May 1994 through May 1995; interim report

Terrace Reservoir receives drainage of low-pH, metal-enriched water from mineralized areas, including the Summitville Mine, within the Alamosa River Basin. Drainage from the Summitville Mine has contributed a substantial part of the metal load to Terrace Reservoir. From May 1994 through May 1995, a study was done by the U.S. Geological Survey, in cooperation with the U.S. Environmental Protection Agency, to evaluate the physical and chemical characteristics of Terrace Reservoir. Terrace Reservoir was thermally stratified from about mid-May through August 1994. Thermal stratification was absent from September\x111994through March 1995. During periods of stratification, underflow of the Alamosa River was predominant, and residence times of the underflow were shortened by 40 to 75\x11percent of the theoretical residence times for a well-mixed reservoir. Transport and deposition of suspended solids in Terrace Reservoir varied spatially and temporally. Most of the suspended solids were deposited in Terrace Reservoir. The concentration of dissolved oxygen in the reservoir varied little spatially or temporally and generally was within a few tenths of the dissolved-oxygen concentration of the inflow. The pH of water in the reservoir generally ranged from about 4.0 to about 7.0, depending on date, depth, and location. The largest pH values were measured during May. A markeddecrease of about 1.5\x11pH units occurred at site T5 in the reservoir about mid-June. The pH of the reservoir remained at or below 5.5 from mid-June through November. Dissolved-metal concentrations varied spatially and temporally in response to several factors, which included inflow characteristics, reservoir stratification and mixing, inflow-routing and flow-through patterns, residence times, sedimentation, dissolved oxygen, and pH. Inflow chemistry is the dominant controlling factor of metal chemistry within Terrace Reservoir. During periods of stratification, large vertical variations in metal concentrations occurred. The highest metal concentrations in the reservoir generally were measured in the hypolimnion between June and August. During June, epilimnetic water of the reservoir had pH values greater than 6.0, and metal concentrations were lower than hypolimnetic concentrations. In the hypolimnion, pH values were less than 5.5. The difference between the chemistry of the epilimnion and the hypolimnion was due to differences in flow routing and residence times of water in those respective layers. The dissolved-metal concentrations were larger during July and August than during June. During September, small vertical variations in metal concentrations occurred, and the dissolved-metal concentrations were nearly equivalent to the average August metal concentrations, indicatingthat the metal concentrations measured during September resulted largely from reservoir mixing.During March, the largest metal concentrationsoccurred in the epilimnion, where pH was about 5.5; in the hypolimnion, where the pH was about 6.0, dissolved-metal concentrations were substantially lower and reflected inflow concentrations.

Colorado

Great Salt Lake, Utah: Chemical and physical variations of the brine, 1963-1966

Great Salt Lake is a shallow, closed-basin lake in northern Utah. Its surface area and concentration of dissolved solids vary in response to both annual and long-term climatic changes. The lake gains water mainly as streamflow from mountains to the east and loses water through evaporation. In 1965, at a lake-surface altitude of 4,194 feet, the surface area was about 1,000 square miles, and the maximum measured depth was 27 feet. Studies to define the variations in chemical and physical characteristics of the brine began in 1963, and detailed sampling of the lake at 29 sites was made in October 1965 and May 1966. Data resulting from concurrent sampling of the 29 sites indicated that four types of brine coexist in the lake.

Utah

Efficiency of a stormwater detention pond in reducing loads of chemical and physical constituents in urban streamflow, Pinellas County, Florida

A multipurpose wet stormwater detention pond in Pinellas Park, Florida was studied to determine its effectiveness in reducing the load of selected water-quality constituents commonly found in urban streamflow. Water-quality samples, and data on streamflow and precipitation were collected at the outflow and principal inflow of detention area 3 on Saint Joe Creek. To compare the constituent loads entering and leaving the detention pond, flows and water quality were monitored simultaneously at the inflow and outflow sites for six storms, and were monitored intermittently during periods of base flow. Lodas od 19 selected chemical and physical constituents were determined. Because all the stormwater entering the detention pond was not measured at the inflow site, computed stormwater inflow loads were adjusted to account for loads from the unmonitored areas. The ratio of storm- water volume measured at the outflow site to stormwater volume measured at the inflow site was used to adjust inflow loads for individual storms. Pond efficiencies for selected water- quality constituents for each of the storms were estimated by dividing the difference in outflow and adjusted inflow loads by the adjusted inflow load. Stormwater loads of the major ions (chloride, calcium and bicarbonate) and dissolved solids at the outflow site exceeded loads at the inflow site, partly as a result of mixing with base flow stored within the pond. However, the detention pond was effective in reducing the stormwater load of such urban-runoff contaminants as metals, nutrients, suspended solids, and biochemical and chemical oxygen demand. Estimated median pond efficiencies for reducing constituent loads ranged from 25 to more than 60 percent for metals, 2 to 52 percent for nutrients, 2 to 52 percent for nutrients, 7 to 11 percent for two measurements of suspended solids, and 16 to 49 percent for the oxygen- consuming substances. The reductions of constituent loads in stormwater are probably a result of dilution with pond water (particularly for smaller storms), adsorption, chemical precipitation, settling, biologic uptake, and oxidation. The establishment of aquatic vegetation midway through the study appears to have increased the efficiency of the pond in reducing loads of urban-runoff contaminants in stormwater. The efficiency of the detention pond in reducing base-flow loads was estimated by comparing base-flow loads at the out- flow site prior to and after construction of the pond. Loads of major ions and dissolved solids in base flow were reduced at median efficiencies ranging from 17 to 35 percent. Urban-runoff con- taminants in base flow were generally reduced at higher efficiencies. Median efficiencies ranged from 38 to 82 percent for metals, 19 to 83 percent for nutrients, 34 to 45 percent for suspended solids, and 43 to 65 for the oxygen-consuming substances. The reductions in loads in base flow are probably a result of adsorption, chemical precipitation, biologic uptake, and settling within the pond. These processes were more effective in reducing base-flow loads after the establishment of aquatic vegetation in the pond.

Water-Resources Investigations Report

Physical and Chemical Water-Quality Data from Automatic Profiling Systems, Boulder Basin, Lake Mead, Arizona and Nevada, Water Years 2001-04

Water-quality profile data were collected in Las Vegas Bay and near Sentinel Island in Lake Mead, Arizona and Nevada, from October 2000 to September 2004. The majority of the profiles were completed with automatic variable-buoyancy systems equipped with multiparameter water-quality sondes. Profile data near Sentinel Island were collected in August 2004 with an automatic variable-depth-winch system also equipped with a multiparameter water-quality sonde. Physical and chemical water properties collected and recorded by the profiling systems, including depth, water temperature, specific conductance, pH, dissolved-oxygen concentration, and turbidity are listed in tables and selected water-quality profile data are shown in graphs.

Open-File Report

Fish communities and their relation to physical and chemical characteristics of streams from selected environmental settings in the Lower Susquehanna River basin, 1993-95

Studies of fish-community composition were conducted annually in selected reaches (from 100 to 303 meters in length) on seven streams from June 1993 to June 1995 within the Lower Susquehanna River Basin. In 1994, additional reaches were selected on three of the streams, resulting in a total of 28 samples. The study reaches were selected on the basis of type of bedrock and land use/land cover; the major emphasis was on agricultural land use or areas in transition from agricultural to commercial, industrial, and residential land uses. At each reach, environmental characteristics consisting of instream and riparian habitat conditions, hydrology, and water quality were determined. The relation of fish communities at these reaches to physical and chemical characteristics of streams was analyzed to determine if the fish communities differed temporally or spatially. Data were analyzed by parametric and multivariate techniques. During the course of the study, a total of 33,143 fish were collected, consisting of 39 species representing 8 families. Cyprinidae (minnows) were dominant with 17 species, followed by Centrarchidae (sunfishes) with 7 species and Percidae (perches and darters) with 4 species. Three species?blacknose dace ( Rhinichthys atratulus ), white sucker ( Catostomus commersoni ), and the sculpins ( Cottus spp)?accounted for 49 percent of the total fish collected. The environmental variables most closely related to the fish communities present at the reaches were mean channel width, mean water temperature, mean canopy angle, and suspended-sediment concentrations. These variables accounted for about 79 percent of the variation in the environmental-species relation. Channel width and mean water temperature are correlated with stream size variables. The stream size gradient is the most influential variable to the fish communities studied in the Lower Susquehanna River Basin.

Water-Resources Investigations Report

Physical and chemical characteristics of water in coal-mine ponds, eastern Oklahoma, June to November 1977-81

Water at 102 sites in 59 coal-mine ponds in eastern Oklahoma was sampled at lease twice during June to November 1977-81 to determine temperature, specific conductance, dissolved oxygen, pH, and dissolved sulfate, chloride, iron, and manganese--as part of a study of the hydrology of the Oklahoma coalfield. These determinations show that during June to October water in ponds deeper than ~10 ft was stratified; ponds which had little or not change of temperature with depth generally were shallow or were sampled in early November. Temperature, dissolved oxygen, and pH usually decreased with depth, whereas specific conductance usually increased with depth. Concentrations of dissolved sulfate, chloride, iron, and manganese varied from site to site. Specific conductance, which is a measure of dissolved solids in the water, ranged from 93 to 4,800 mmho/cm at 25oC. Some physical and chemical characteristics of the mine-pond water are related to the coal bed adjacent to the pond. Mean specific-conductance values and dissolved-sulfate concentrations were greatest in ponds associated with mining of Dawson, Weir-Pittsburg, and Secor coals. Mean dissolved-iron concentrations were greatest in ponds associated with mining of the Dawson, Secor, and Hartshorne coals. Mean dissolved-manganese concentrations were greatest in ponds associated with mining of the Dawson, Weir-Pittsburg, and Secor coals, but greatly exceeded secondary drinking-water limits regardless of coal bed mined.

Oklahoma

Use of a single-bowl continuous-flow centrifuge for dewatering suspended sediments: effect on sediment physical and chemical characteristics

The use of a single-bowl continuous-flow centrifuge (CFC, Sharples-Pennwalt Model AS-12) for dewatering suspended sediment from large volumes of river water is evaluated. Sediment-recovery efficiency of 86-91 per cent is comparable to that of other types of CFC units. The recovery efficiency is limited by the particle-size distribution of the feed water and by the limiting particle diameter that is retained in the centrifuge bowl. The limiting particle diameter, using the parameters for this study (bowl radius = 10.5cm; bowl length = 71.1 cm; rotational velocity = 16000 r min −1 ; flow rate = 2 L min −1 , and an assumed hydrated particle density = 1.7 gm cm −3 ), is 370 nm. There seems to be no particle-size fractionation within the centrifuge bowl—the median particle size was the same at the top as at the bottom. Particle electrophoretic mobility plays some role in fractionation of particles within the centrifuge. The mobility ranged from −1.19 to −2.01 × 10 −8 m 2 V −1 s −1 , which is typical of clays coated with organic matter, the charge of which is partially neutralized by divalent cations and iron. Contamination by trace metals and organics is minimized by coating all surfaces that come in contact with the sample with either FEP or PFA Teflon and using a removable FEP Teflon liner in the centrifuge bowl. Because of the physical and chemical factors affecting particle fractionation within the centrifuge, care must be exercised in interpreting the environmental consequences of particles collected by continuous-flow centrifugation.

Hydrological Processes