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Groundwater flowpath characteristics drive variability in per- and polyfluoroalkyl substances (PFAS) loading across a stream-wetland system

Groundwater-dependent ecosystems in areas with industrial land use are at risk of exposure to a PFAS chemicals. We investigated one such system with several known PFAS source areas, where high and low permeability sediments (glacial) coupled with groundwater-lake and groundwater/surface-water interactions created complex ‘source to seep’ dynamics. Using heat-tracing and chemical methods, numerous preferential groundwater discharge zones were identified and sampled across the upper Quashnet River stream-wetland system in Mashpee, MA, USA, downgradient of Joint Base Cape Cod (JBCC). Surface-water and groundwater samples were analyzed for 40 PFAS compounds between March and October 2022. Samples were collected from groundwater seeps identified as preferential discharge points (PDPs), wells upgradient of the stream-wetland system, contributing flow-through kettle lakes, and along Quashnet River surface-waters. PFAS from sampled waters contained perfluorinated carboxylates (PFPea, PFHxA, PFNA), perfluorinated sulfonates (PFBS, PFPeS, PFHxS, PFOS), fluorotelomer sulfonates (6:2, 8:2 FtS), and perfluoroalkyl sulfonamides (PFOSA). Samples from PDPs and wells had measured PFAS concentrations ranging from non-detect to 4677 ng/L ng/L (mean = 418 ng/L, std. = 709 ng/L), and a range of deuterium excess values (3.2 to 15.9 per mil) indicative of varying degrees of groundwater-lake interaction prior to groundwater flowpath emergence at PDPs. Correlations ( p < 0.01) between deuterium excess, %PFAS precursors, and terminal PFAS compounds highlighted potential precursor transformations associated with lake-groundwater exchange along flowpaths sourcing PDPs. However, some seepages had higher total PFAS concentrations (>1000 ng/L) than upgradient kettle lakes despite showing lake (evaporative) isotopic signatures, indicating the potential for groundwater flowpath convergence at wetland discharge zones and the influence of lakebed PFAS precursor reactions. Results from these synoptic surveys address gaps in the existing PFAS literature by demonstrating the importance of subsurface fate and transport on PFAS compound concentrations and mass loading in preferential groundwater discharge zones.

Massachusetts

How do hydrological variability and human activities control the spatiotemporal changes of riverine nitrogen export in the Upper Mississippi River Basin?

Excessive nitrogen export from agricultural watersheds remains a critical water quality challenge, with the Upper Mississippi River Basin (UMRB) significantly contributing to downstream eutrophication and hypoxia in the Gulf. This study investigates the spatiotemporal dynamics of riverine nitrate plus nitrite (NO 3 – + NO 2 – -N) export across the UMRB at high spatial resolution (12-digit Hydrologic Unit Codes or HUC12 subwatershed scale) during 2001–2020 and quantifies the effects of anthropogenic activities and hydrological variability on riverine NO 3 – + NO 2 – -N export changes in the region between 2001–2005 and 2016–2020. Our results revealed hotspots of substantial increases in NO 3 – + NO 2 – -N yields across the UMRB, with distinct regional patterns in driving factors. Over the entire UMRB, NO 3 – + NO 2 – -N yields increased by 9.7 kg/ha/yr on average from 2001–2005 to 2016–2020, with anthropogenic activities contributing 4.8 kg/ha/yr and hydrological variability contributing 4.9 kg/ha/yr. The northern and western UMRB had combined influences from both anthropogenic activities and hydrological variability, while the east-central regions had predominantly hydrologically driven changes. Agricultural sources, including fertilizer, manure, and biological nitrogen fixation, collectively contributed over 80% of NO 3 – + NO 2 – -N loading throughout the basin. This framework for disentangling human and hydrological impacts provides critical insights for developing effective and targeted watershed management strategies to reduce nutrient losses and improve water quality.

Upper Mississippi River Basin

Woods Hole Coastal and Marine Science Center—2023 annual report

The 2023 annual report of the U.S. Geological Survey Woods Hole Coastal and Marine Science Center highlights accomplishments of 2023, includes a list of 2023 publications, and summarizes the work of the center, as well as the work of each of its science groups. This product allows readers to gain a general understanding of the focus areas of the center’s scientific research and learn more about specific projects and progress made throughout 2023, all while enjoying photographs taken in various environments and laboratories, and applicable maps and figures.

Circular

Woods Hole Coastal and Marine Science Center—2024 annual report

The 2024 annual report of the U.S. Geological Survey Woods Hole Coastal and Marine Science Center highlights accomplishments of 2024, includes a list of 2024 publications, and summarizes the work of the center, as well as the work of each of its science groups. This product allows readers to gain a general understanding of the focus areas of the center’s scientific research and learn more about specific projects and progress made throughout 2024, all while enjoying photographs taken in various environments and laboratories, and applicable maps and figures.

Circular

Anaerobic biodegradation of perfluorooctane sulfonate (PFOS) and microbial community composition in soil amended with a dechlorinating culture and chlorinated solvents

Perfluorooctane sulfonate (PFOS), one of the most frequently detected per - and polyfluoroalkyl substances (PFAS) occurring in soil, surface water, and groundwater near sites contaminated with aqueous film-forming foam (AFFF), has proven to be recalcitrant to many destructive remedies, including chemical oxidation. We investigated the potential to utilize microbially mediated reduction (bioreduction) to degrade PFOS and other PFAS through addition of a known dehalogenating culture, WBC-2, to soil obtained from an AFFF-contaminated site. A substantial decrease in total mass of PFOS (soil and water) was observed in microcosms amended with WBC-2 and chlorinated volatile organic compound (cVOC) co-contaminants — 46.4 ± 11.0 % removal of PFOS over the 45-day experiment. In contrast, perfluorooctanoate (PFOA) and 6:2 fluorotelomer sulfonate (6:2 FTS) concentrations did not decrease in the same microcosms. The low or non-detectable concentrations of potential metabolites in full PFAS analyses, including after application of the total oxidizable precursor assay, indicated that defluorination occurred to non-fluorinated compounds or ultrashort-chain PFAS. Nevertheless, additional research on the metabolites and degradation pathways is needed. Population abundances of known dehalorespirers did not change with PFOS removal during the experiment, making their association with PFOS removal unclear. An increased abundance of sulfate reducers in the genus Desulfosporosinus (Firmicutes) and Sulfurospirillum (Campilobacterota) was observed with PFOS removal, most likely linked to initiation of biodegradation by desulfonation. These results have important implications for development of in situ bioremediation methods for PFAS and advancing knowledge of natural attenuation processes.

Science of the Total Environment

Evaluating groundwater quality influences from oil field operations and other anthropogenic activities in an urban setting, Santa Fe Springs, California

Groundwater quality is often affected by anthropogenic activities in urban settings. This study examines groundwater quality in and around the Santa Fe Springs Oil Field in Los Angeles County, California, where oil and gas production commonly intersects with high density industrial, commercial and residential land uses. Utilizing a combination of new and historical data, we evaluated potential pathways that would allow for oil field formation fluids to migrate into groundwater and whether mixing may have occurred based on the distribution of groundwater and oil field formation fluid tracers in samples. Samples were analyzed for a wide array of constituents including volatile organic compounds, light hydrocarbons, major ions, and various isotopic compositions. Despite evidence of oil field infrastructure providing potential pathways of migration via uncemented annular spaces, casing breaches and historical disposal of oil field formation water in surface ponds, the distribution and occurrence of stable isotopes of water, chloride, boron, and total dissolved solids do not indicate mixing of oil field formation water and groundwater. However, methane isotopic signatures and the presence of heavier alkanes suggest gas from oil-bearing formations have migrated from depth via oil field well infrastructure. Volatile organic compound detections were mainly from manufactured compounds unrelated to oil and gas production, with a relatively limited number of petroleum hydrocarbons also detected. Volatile organic compounds were generally found in wells tapping shallow, modern aged groundwater, indicating anthropogenic activities occurring at or near land surface as the source. Study results suggest that while oil field infrastructure provides migration pathways for oil field formation fluids to be introduced into groundwater, urban land uses not related to oil and gas production are the primary drivers of groundwater quality degradation.

California

The 2023 US 50-State National Seismic Hazard Model: Overview and implications

The US National Seismic Hazard Model (NSHM) was updated in 2023 for all 50 states using new science on seismicity, fault ruptures, ground motions, and probabilistic techniques to produce a standard of practice for public policy and other engineering applications (defined for return periods greater than ∼475 or less than ∼10,000 years). Changes in 2023 time-independent seismic hazard (both increases and decreases compared to previous NSHMs) are substantial because the new model considers more data and updated earthquake rupture forecasts and ground-motion components. In developing the 2023 model, we tried to apply best available or applicable science based on advice of co-authors, more than 50 reviewers, and hundreds of hazard scientists and end-users, who attended public workshops and provided technical inputs. The hazard assessment incorporates new catalogs, declustering algorithms, gridded seismicity models, magnitude-scaling equations, fault-based structural and deformation models, multi-fault earthquake rupture forecast models, semi-empirical and simulation-based ground-motion models, and site amplification models conditioned on shear-wave velocities of the upper 30 m of soil and deeper sedimentary basin structures. Seismic hazard calculations yield hazard curves at hundreds of thousands of sites, ground-motion maps, uniform-hazard response spectra, and disaggregations developed for pseudo-spectral accelerations at 21 oscillator periods and two peak parameters, Modified Mercalli Intensity, and 8 site classes required by building codes and other public policy applications. Tests show the new model is consistent with past ShakeMap intensity observations. Sensitivity and uncertainty assessments ensure resulting ground motions are compatible with known hazard information and highlight the range and causes of variability in ground motions. We produce several impact products including building seismic design criteria, intensity maps, planning scenarios, and engineering risk assessments showing the potential physical and social impacts. These applications provide a basis for assessing, planning, and mitigating the effects of future earthquakes.

Earthquake Spectra

Land-based nutrient flux to a fringing reef: Insights from Ofu Island, American Samoa

Submarine groundwater discharge (SGD) is a critical driver of nutrient transport in coral reef ecosystems, shaping water quality, primary productivity, and overall reef health. This study quantifies SGD fluxes and associated nutrient dynamics in two reef flat pools within the Ofu Unit of the National Park of American Samoa: Papaloloa and Fatuana. A multi-method approach integrating unoccupied aerial system-based thermal infrared (UAS-TIR) surveys, radon-based SGD measurements, multichannel electrical resistivity tomography (ERT), and discrete water sampling was used to assess SGD rates and nutrient contributions. UAS-TIR imagery revealed cooler sea surface temperatures in both pools, indicative of SGD, with the higher fluxes observed in Papaloloa. Radon measurements revealed a strong inverse correlation between SGD rates and tidal stage, with a more immediate SGD response at Papaloloa due to its highly permeable calcareous sand and gravel substrate. In contrast, a 2–3-hour lag in SGD response at Fatuana suggests discharge from a more inland aquifer that has lower diffusivity. Nutrient concentrations correlated with temperature and salinity, confirming SGD as the dominant nutrient transport mechanism, whereas isotopic analyses indicated inputs from both groundwater and potential anthropogenic sources. Despite lower SGD flux at Fatuana, higher algal cover suggests additional factors influencing algal proliferation, including substrate availability and hydrodynamic conditions. Excess nutrient inputs from SGD may contribute to algal overgrowth, which threatens Ofu’s thermally tolerant corals by increasing competition for space and light. These findings underscore the complexity of SGD-mediated nutrient dynamics in reef environments and emphasize the need for integrated hydrological and ecological assessments to support effective reef conservation and management strategies.

American Samoa, Ofu Island, Olosega Island

Bayesian mapping of regionally grouped, sparse, univariate earth science data

Some earth science data are naturally grouped by region, and it is often desirable to map these data by region. However, if there are only a few samples within each region, then the map should be smoothed in an appropriate way to mitigate the problems that arise from having only a few samples. A smoothing algorithm based on a Bayesian hierarchical model is developed and presented in this report. This algorithm has several features that make it especially suitable for mapping earth science data: it can account for measurements that are censored, it can process multiple datasets with different measurement errors and different censoring thresholds, and it can calculate the uncertainty in any statistic that is mapped. The algorithm is demonstrated by mapping gold concentrations that are measured in streambed sediments in the Taylor Mountains quadrangle in southwestern Alaska.

Alaska

On-demand global Landsat evapotranspiration product: Development, evaluation, and dissemination

Global actual evapotranspiration (ET) is one of the essential climate variables needed to understand and manage the relationships among food, energy, and water resources. The U.S. Geological Survey Earth Resources Observation and Science (EROS) Center launched a provisional ET product in 2020, offering on-demand, field-scale global coverage derived from Landsat data through the EROS Science Processing Architecture (ESPA) platform. The ESPA interface provides ET data for cloud-free Landsat overpasses starting in 1982 with Landsat 4 through the current Landsat 9. The ET data are delivered as a Provisional Level-3 Science product created using the Operational Simplified Surface Energy Balance (SSEBop) model. Landsat surface temperature and reference ET are the main model drivers along with vegetation index and net radiation for model parameterization. A large volume of Landsat-based ET orders (e.g., over 1,200,000 images from June 2020 through December 2025) around the world indicate increasing awareness and application of the ET data. The ESPA platform enables land and water resource managers and researchers to access a first-order ET product without requiring advanced knowledge of remote sensing technology or evapotranspiration modeling. We present the methodology and workflow of the on-demand Landsat ET product and its performance evaluations over diverse hydro-climatic settings. The product can help estimate field-scale consumptive water use and thus quickly and consistently assess historical water use, allocation, and budget to inform water management under changing environments. Future ET data aggregated to monthly and seasonal time scales are expected to enhance integration with decision-making tools and procedures.

Remote Sensing of Environment

Exploring the science and data foundation for Federal public lands decisions

Public lands provide diverse resources, values, and services worldwide. Laws and policies typically require consideration of science in public lands decisions, and resource managers are committed to science-informed decision-making. However, it can be challenging for managers to use, and document the use of, science and data in their decisions. To better understand science and data use in Federal public lands decisions in the United States, we assessed the number, type, and age of documents cited in 70 Environmental Assessments (EAs) completed by the Bureau of Land Management (BLM) in Colorado from 2015–2019. We focused on the BLM, as they manage the largest area of public lands in the United States. We selected Colorado as our study area, as actions proposed on BLM lands in Colorado are representative of those across the nation. Fifty percent of citations were categorized as science and 23% as data. EAs contained an average of 17 citations (range 0–111), with documents analyzing effects of oil and gas development and recreation actions including the highest and lowest mean number of citations (41 and 6, respectively). Of individual resource analysis sections within EAs, 24% contained ≥1 science citation and 21% contained ≥1 data citation. Journal articles were the most cited type of document (26% of citations) followed by non-BLM inventories (13%). Forty-seven percent of citations were relatively recent (2010 or later); the oldest citation was from 1927. Commonly analyzed resources with the highest mean number of citations were socioeconomics, mineral resources, and noise. Fourteen of 33 commonly analyzed resources included <1 citation on average. Actions and resources with no or few citations represent opportunities for strengthening the transparent use of science and data in public lands decision-making.

Colorado

Engineering and risk research—A strategic vision for extending USGS earthquake science to risk assessment and mitigation

As a part of the U.S. Geological Survey (USGS) Natural Hazards Mission Area, the Engineering and Risk Project (ERP) of the Geologic Hazards Science Center conducts civil engineering research to extend natural hazards science to risk assessments. The ERP includes predominantly, but not exclusively, staff funded by the USGS Earthquake Hazards Program. A major focus of the ERP is to deliver actionable information to decisionmakers that helps promote the safety, security, and economic well-being of the Nation. The report discusses briefly the ERP’s evolution and scope, its organization structure, describes key products and deliverables, their efforts to engage with external partners, and its strategy and vision in conducting range of engineering and risk research. The research topics outlined in this report, as developed by the ERP, may be used to facilitate project planning activities during the next 10 years and serve as a longer-term planning resource for the USGS Earthquake Hazards Program and Geologic Hazards Science Center.

Circular

Predictions of anthropogenic background PFAS concentrations in soil and relation to bedrock lithology and groundwater quality

Detectable concentrations of per- and polyfluoroalkyl substances (PFAS) have been observed in soils in remote areas and presumably originate from atmospheric deposition. These anthropogenic background concentrations may enable some PFAS to leach to groundwater at levels that exceed regulatory criteria for drinking water. However, anthropogenic background soil concentrations and their connection to groundwater are not well characterized. We developed a boosted regression tree model to predict perfluorooctanesulfonic acid (PFOS) and perfluorooctanoic acid (PFOA) concentrations in shallow soils across northern New England. Low soil pH was the most important predictor of elevated anthropogenic PFOS and PFOA concentrations in background soils, rather than potential PFAS sources, land use, or population density. Total organic carbon (TOC) was also an important predictor for PFOS soil concentrations. Model predictions indicate that 73% of the shallow soils within Maine, Vermont, and New Hampshire exceed New Hampshire’s Soil Remediation Standard for PFOS (0.5 ng/g) and 41% exceed the PFOA standard (0.4 ng/g). Analysis of soil model results and groundwater data suggests that areas with high soil pH are associated with higher groundwater detection frequencies, illustrating how areas with less retention in soil are, conversely, also areas with potentially greater groundwater vulnerability. Further analysis indicates that groundwater may be more vulnerable in calcareous lithologies.

Maine, New Hampshire, Vermont

Transit time modeling framework for predicting freshwater salinization in urban catchments

The salinity of inland freshwaters is rising globally, particularly in urban watersheds where winter road deicers are widely applied. Attributing stream salinity dynamics to specific sources and transport pathways remains challenging due to episodic salt inputs, engineered drainage, and strong coupling between hydrology and subsurface storage. We present a modeling framework that couples climate-driven deicer build-up and wash-off with transient transit time distribution theory to simulate salt transport through drainage, interflow, and groundwater pathways. Applied to an urban watershed in Northern Virginia (USA), the model reproduces ten years of high-frequency stream salinity measurements across daily-to-decadal timescales. The calibrated model implies an average deicer application of 206 tonnes Cl −1 yr −1 , or roughly one 20 kg bag of rock salt person −1 yr −1 when normalized by the 20,000 people living in the watershed. In winter months, higher infiltration routes a large fraction of snowmelt and deicers into shallow subsurface pathways, enhancing vadose-zone and interflow contributions to stream salinity. Limited subsurface storage capacity and seasonal hydrologic turnover flush excess chloride from the vadose zone and groundwater during subsequent summer storms. By linking climate-driven deicer inputs, hydrologic connectivity, and stream water age, the framework provides a transferable basis for diagnosing and managing freshwater salinization in urban watersheds.

Virginia

Low-frequency earthquakes track the motion of a captured slab fragment

Accurate tectonic models are essential for assessing seismic hazard and fault interactions. However, the plate configuration at the complex Mendocino triple junction, where the San Andreas Fault and the Cascadia subduction zone meet, remains uncertain. We analyzed fault slip associated with a recently identified zone of tectonic tremor and low-frequency earthquakes (LFEs) near the southern edge of the subducting Gorda slab. Based on tidal sensitivity and P-wave first motions, we show that the LFEs are generated by dipping, strike-slip motion. This suggests that a former Farallon slab fragment, now captured by the Pacific plate, is translating northward beneath westernmost North America. This geometry effectively extends the slab interface fault, challenging prevailing interpretations of slab window formation and creating a potential unaccounted earthquake hazard in this region.

Science

Potential for continental scientific drilling to inform fault mechanics and earthquake science

Our understanding of fault mechanics and earthquake processes remains limited, largely due to minimal direct observations near active faults at seismogenic depths. This lack of data restricts our ability to accurately assess and mitigate both natural and human-induced seismic hazards. However, recent advancements in drilling capabilities and downhole sensing technologies offer an opportunity: the ability to observe the physical conditions within a volume near active fault zones. In this contribution, we highlight how scientific drilling can provide access to the near-fault environment, enabling measurements of the stress, temperature, fluid pressure, and rock properties at depths where ruptures initiate, propagate, and arrest. These observations are essential to refine models of earthquake nucleation and dynamic rupture, bridging gaps between laboratory experiments, numerical simulations, and surface observations. These insights can advance fundamental understanding in earthquake science but also support the development of more effective seismic hazard assessments and risk mitigation strategies.

Seismica

Groundwater budget for the Mountain Home area, southern Idaho, 2022–23

The U.S. Geological Survey, with funding from the Idaho Department of Water Resources, developed a groundwater budget for the Mountain Home area in southern Idaho for irrigation year 2023 (November 1, 2022–October 31, 2023). This study focused on the water balance across the Cinder Cone Butte Critical Groundwater Area (CGWA), Mountain Home Groundwater Management Area (GWMA), and the rest of the study area (RoSA), compiling data from various sources, including precipitation records, groundwater level measurements, metered groundwater pumpage data, surface water diversions and evapotranspiration (ET) estimates derived from remote sensing satellite imagery, and ground-based reference data. Key inflow components included recharge from applied surface water irrigation (which incorporates incidental recharge from irrigation practices and conveyance losses), estimated tributary streamflow, and estimated mountain block recharge. The key outflow components were groundwater pumpage for irrigation, municipal, industrial, and domestic uses, and ET. Recharge from applied irrigation and mountain block recharge were the largest inflows, and groundwater pumpage for irrigation was the largest outflow. The CGWA had a positive groundwater budget residual of 2,170 acre-feet (acre-ft), which contrasts with observed long-term groundwater level declines and historical trends of storage depletion. This positive residual is likely associated with unquantified outflows, including lateral groundwater flow out of the subregion, or other complexities, such as overestimated tributary contributions relative to the actual recharge for the 2023 water budget. The GWMA exhibited a positive residual of 56,563 acre-ft, primarily owing to recharge from applied surface water irrigation and areal recharge during a wetter-than-average year, which allowed irrigation entities to deliver more water from in-basin and out-of-basin reservoirs. The RoSA showed a large positive residual of 124,933 acre-ft. The interpretation of these positive residuals must account for significant uncertainties, including estimations of areal recharge, tributary streamflow (particularly losses and diversions), ET, the volume of surface water loss to the Snake River, lateral groundwater flows between subregions and across study area boundaries, and the unquantified groundwater discharge to the Snake River. These uncertainties, in combination with the complex hydrogeologic controls on water movement and limitations of remotely sensed data, directly affect the accuracy of water availability assessments. Future data collection efforts would help reduce these uncertainties and support water resource management decisions in the Mountain Home area. Key efforts could include installing additional streamflow gaging stations (particularly to quantify tributary losses and gains and surface water losses to the Snake River), improving groundwater pumpage metering, and validating remotely sensed ET data with ground-based measurements. Furthermore, to better quantify unrepresented or highly uncertain fluxes, focused investigations on groundwater discharge to the Snake River, lateral groundwater flows between subregions and across study area boundaries, and a more robust determination of the actual influence and volume of mountain block recharge would help refine future water availability assessments for the Mountain Home area.

Idaho

Inference of pattern-based geological CO2 sequestration and oil recovery potential in a commingled main pay and residual oil zone CO2-EOR flood

Several detailed studies have shown that residual oil zones (ROZs) can present significant resources for additional hydrocarbon recovery as well as subsurface carbon dioxide (CO 2 ) sequestration via enhanced oil recovery by injecting CO 2 (CO 2 -EOR). Field development strategies included new wells drilled dedicated to main pay zones (MPZ) and ROZs, or existing wells in MPZs deepened to ROZs for commingled injection-production using different well patterns. The latter presented a challenge when discerning the injection and production from each of the zones, and for subsequent quantification of CO 2 sequestration and EOR potential from different patterns and from the field. In this paper, an innovative method for analyzing commingled injections and productions from MPZs and ROZs, with application to pattern-based data from four staggered line drive patterns in Wasson Field's Denver Unit, Texas, USA, was developed. Decline curve and ratio-trend methods were used as means of history-matching and forecasting. Cumulative production-time and cumulative production-rate data for oil, gas, and water, as well as water-oil ratio (WOR) and gas-oil ratio (GOR), were analyzed along with injection data for time intervals covering major injection events in MPZ, or MPZ and ROZ combined. A combined analysis enabled inference of allocation of fluids into different zones during WAG (water alternating gas) injection and thereby estimation of CO 2 storage, utilization, and retention in different zones as a function of total injection. Results show that ROZs generally present higher CO 2 sequestration potential compared to MPZs, and a comparable incremental oil recovery factor of ∼20%, on average. Results based on ratio analysis further show that while the WOR trend of the pattern production is mostly dominated and controlled by ROZ, GOR is controlled by both intervals. Although the method relying on decline curves and the approach used in zonal fluid allocations are subject to their limitations, this study presents a practical and innovative well-pattern-based method to infer and forecast CO 2 sequestration and oil recovery quantities and fluid ratios from MPZs and ROZs in commingled operations and highlight the added potential offered by ROZs.

Texas