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At least 865 records · Page 48Linked to original sources

Delta-Flux: An eddy covariance network for a climate-smart Lower Mississippi Basin

Networks of remotely monitored research sites are increasingly the tool used to study regional agricultural impacts on carbon and water fluxes. However, key national networks such as the National Ecological Observatory Network and AmeriFlux lack contributions from the Lower Mississippi River Basin (LMRB), a highly productive agricultural area with opportunities for soil carbon sequestration through conservation practices. The authors describe the rationale to create the new Delta-Flux network, which will coordinate efforts to quantify carbon and water budgets at seventeen eddy covariance flux tower sites in the LMRB. The network structure will facilitate climate-smart management strategies based on production-scale and continuous measurements of carbon and water fluxes from the landscape to the atmosphere under different soil and water management conditions. The seventeen instrumented field sites are expected to monitor fluxes within the most characteristic landscapes of the target area: row-crop fields, pasture, grasslands, forests, and marshes. The network participants are committed to open collaboration and efficient regionalization of site-level findings to support sustainable agricultural and forestry management and conservation of natural resources.

Arkansas, Louisiana, Mississippi↗

A model for regional-scale oak savanna management: The roles of fire, canopy, and soils for understory plant diversity

Predicting the outcomes of land management on biodiversity is difficult without a mechanistic understanding of how management approaches, ecosystem structure, environmental conditions, and biodiversity interact. Management effects may be direct or indirect, context- or scale-dependent, or obscured by local environmental conditions. Resolving these relationships at the regional scale may be difficult, given heterogeneity in local environmental conditions, yet understanding broad-scale patterns can elucidate context dependencies and improve restoration outcomes. We confronted these challenges within globally rare oak savannas in the midwestern United States, which have been altered by fire exclusion and resulting woody encroachment. By modeling direct and indirect pathways by which management influences diversity, we test a general framework for savanna restoration. Across 100 oak savannas spanning five US states, management by prescribed fire and mechanical thinning of woody vegetation affected groundlayer plant species richness through changes to ecosystem structure (canopy openness and litter depth), and these effects were both context- and scale-dependent. Frequent prescribed fires and canopy thinning promoted greater canopy openness, which in turn increased richness at small (1 m 2 ), but not larger (1000 m 2 ) scales. Frequent fire additionally increased richness at small and larger scales through effects independent of ecosystem structure. While management effects were large relative to the influence of local edaphic conditions, soil productivity had two largely offsetting effects on small-scale richness, increasing richness directly but decreasing richness indirectly by promoting closed canopy structure. These results suggest using a combination of fire and canopy thinning to reverse the effects of decades of fire exclusion. However, management effects were also context-dependent, emphasizing that management outcomes vary regionally. Here, 1-m 2 plant species richness increased with both fire frequency and canopy thinning under low, but not high, productivity soil conditions. By demonstrating how specific management practices influence savanna structure and biodiversity by manipulating ecological processes across broad geographic and edaphic gradients, our findings provide a framework for understanding management outcomes at short and medium intervals (e.g., within and between decades, respectively), in the form of a model that can be refined by testing additional hypotheses to better predict savanna restoration outcomes.

Illinois, Indiana, Michigan, Ohio, Wisconsin↗

Environmental Setting of the Sugar Creek and Leary Weber Ditch Basins, Indiana, 2002-04

The Leary Weber Ditch Basin is nested within the Sugar Creek Basin in central Indiana. These basins make up one of the five study sites in the Nation selected for the Agricultural Chemicals: Sources, Transport, and Fate topical study, a part of the U.S. Geological Survey’s National Water-Quality Assessment Program. In this topical study, identifying the natural factors and human influences affecting water quality in the Leary Weber Ditch and Sugar Creek Basins are the focus of the assessment. A detailed comparison between the environmental settings of these basins is presented. Specifics of the topical study design as implemented in the Leary Weber Ditch and Sugar Creek Basins are described. The Leary Weber Ditch and Sugar Creek Basins have moderate temperatures with well-defined winter and summer seasons. The mean annual precipitation is 39.5 inches, with the majority of rainfall in spring and early summer and the lowest amount of precipitation in winter. Yearly, an average of 25 inches of moisture moves into the atmosphere as a result of evapotranspiration. Physiographically, both basins are contained completely within the New Castle Till Plains and Drainageways. The gradients of the valleys of Leary Weber Ditch and Sugar Creek differ substantially. Most of the Sugar Creek Basin and the entire Leary Weber Ditch Basin overlie a combination of Devonian limestone and dolomite bedrock. Unconsolidated materials (sand and gravel) overlie much of the bedrock in the basins. Soils are either loam or silt loam, generally deep, poorly drained, medium textured, and nearly level. The potential for surface erosion is negligible because runoff is slow. Available water capacity is high. Natural fertility and organic matter are moderate. Soils are naturally suited to row crops. Agriculture is the principal land use in the Leary Weber Ditch and Sugar Creek Basins. Respectively, 87 percent and 75 percent of the total land area in these basins are used for row crops. The cropped areas within the basins are divided nearly equally between corn and soybeans. Farming practices in the area employ a wide range of tools to promote growth and inhibit vegetative competition; these include the use of fertilizers, herbicides, and pesticides. Tile drains are used extensively to improve yields and make the soils farmable. Irrigation and manure application in the study area are minimal. Most of the study area is in Hancock County, Indiana. The county population is approximately 61,000. There are no large cities in either basin; most residents live in small communities or rural areas. Water use in Hancock County totalled 6.37 million gallons per day during 2002. Drinking water comes entirely from ground water. The U.S. Geological Survey operates streamflow-gaging stations at Sugar Creek at New Palestine and at Leary Weber Ditch at Mohawk within the study area. Mean daily streamflow for Sugar Creek is higher than streamflow at Leary Weber Ditch. Through most of its length, Sugar Creek is a gaining stream and base flow is supported by ground-water sources. At Leary Weber Ditch, there is little to no streamflow when tile drains are dry. Modifications to the natural hydrology of the study area include a large system of tile drains, the intersection of Sugar Creek by several major roads, and outflows from nearby wastewater-treatment plants. Leary Weber Ditch is affected only by tile drains.

Indiana↗

Supporting cost-effective watershed management strategies for Chesapeake Bay using a modeling and optimization framework

Extensive efforts to adaptively manage nutrient pollution rely on Chesapeake Bay Program's (Phase 6) Watershed Model, called Chesapeake Assessment Scenario Tool (CAST), which helps decision-makers plan and track implementation of Best Management Practices (BMPs). We describe mathematical characteristics of CAST and develop a constrained nonlinear BMP-subset model, software, and visualization framework. This represents the first publicly available optimization framework for exploring least-cost strategies of pollutant load control for the United States' largest estuary . The optimization identifies implementation options for a BMP subset modeled with load reduction effectiveness factors, and the web interface facilitates interactive exploration of >30,000 solutions organized by objective, nutrient control level, and for ~200 counties. We assess framework performance and demonstrate modeled cost improvements when comparing optimization-suggested proposals with proposals inspired by jurisdiction plans. Stakeholder feedback highlights the framework's current utility for investigating cost-effective tradeoffs and its usefulness as a foundation for future analysis of restoration strategies.

Chesapeake Bay watershed↗

Some relations between streamflow characteristics and the environment in the Delaware River region

Streamflow characteristics are determined by a large number of factors of the meteorological and terrestrial environments. Because of lack of quantitative data to describe some of the factors and complex interrelations among them, complete analysis of the relations between streamflow and the various environmental factors is impossible. However, certain simplifying assumptions and generalizations made possible a partial analysis for the Delaware River region. For relations involving average runoff or low-flow parameters, average annual precipitation was assumed to be the principal meteorological factor, and geology (a complex of many factors) was assumed to be the principal terrestrial influence, except for that of basin size which was largely eliminated by expression of discharge in terms of unit area. As a first approximation, physiographic units were used as a basis for classifying the geology. Relations between flow parameters and precipitation are fairly well defined for some physiographic units, but not for those in which the geology varies markedly or the areal variation in average precipitation is very small. These relations provide a basis for adjusting the flow parameters to reduce or eliminate the effects of areal variations in precipitation and increase their significance in studies of the effects of terrestrial characteristics. An investigation of the residual effect of basin size (the effect remaining when discharge is expressed in terms of unit area) on relations between flow parameters and average precipitation indicates that such effect is negligible, except for very large differences in area. Parameters that are derived from base-flow recession curves and are related to a common discharge per unit area have inherent advantages as indicators of effects of terrestrial characteristics of basins, because the.y are independent of areal variations in average annual precipitation. Winter base-flow parameters are also practically independent of the effects of evapotranspiration from ground water. However, in many parts of the region these advantages are reduced or nullified by the difficulties of defining base-flow recession curves, particularly winter curves, with sufficient accuracy. In the absence of suitable base-flow recession data and a suitable basis for adjusting parameters, the ratio of the discharge equaled or exceeded 90 percent of the time to the average discharge (Qtt/Qa), or a similar duration parameter, probably is the best indicator of the influence of terrestrial characteristics, although the ratio may vary somewhat with average precipitation. In a part of the region where geologic differences are large and areal variations in average precipitation are small, values of Qm/Qa for each major geologic unit were determined from streamflow records. From these values and the percentage of area represented by each unit, a ratio for each gaging station was computed. Comparison of these computed results with the observed results indicates that nearly all of the variation in the ratio is associated with variation in geology. The investigation indicates that the original assumptions are correct; average precipitation is the principal meteorological influence and geology is the principal terrestrial influence. Together these two factors account for a very large proportion of the variation in average runoff and low-flow characteristics.

Delaware, New Jersey, Pennsylvania↗

Policies and practices of beach monitoring in the Great Lakes, USA: a critical review

Beaches throughout the Great Lakes are monitored for fecal indicator bacteria (typically Escherichia coli) in order to protect the public from potential sewage contamination. Currently, there is no universal standard for sample collection and analysis or results interpretation. Monitoring policies are developed by individual beach management jurisdictions, and applications are highly variable across and within lakes, states, and provinces. Extensive research has demonstrated that sampling decisions for time, depth, number of replicates, frequency of sampling, and laboratory analysis all influence the results outcome, as well as calculations of the mean and interpretation of the results in policy decisions. Additional shortcomings to current monitoring approaches include appropriateness and reliability of currently used indicator bacteria and the overall goal of these monitoring programs. Current research is attempting to circumvent these complex issues by developing new tools and methods for beach monitoring. In this review, we highlight the variety of sampling routines used across the Great Lakes and the extensive body of research that challenges comparisons among beaches. We also assess the future of Great Lakes monitoring and the advantages and disadvantages of establishing standards that are evenly applied across all beaches.

Great Lakes↗

Improving the ability to include freshwater wetland plants in process-based models

Considerable effort and resources have been placed into conservation programs designed to reduce or alleviate negative environmental effects of crop production and into evaluation of the benefits of these programs. Wetlands are an important source of ecosystem services, but modeling wetland plants is an emerging science. To date, wetland plant growth has not been explicitly accounted for in ecosystem service models that quantify conservation program effects. As part of an effort to more accurately simulate wetland plants within process-based models, we expanded upon plant growth data collected in an earlier effort with additional sampling at two of four previously sampled areas, and included a fifth sampling site. We then used data from the five sites spanning five years as wetland plant parameters at both the species and functional group levels for the Agricultural Land Management Alternative with Numerical Assessment Criteria (ALMANAC) model. In addition to individual species, modelers are interested in functional groups representing a collection of species because it is unrealistic to model every species occurring in an ecosystem. ALMANAC simulations were completed at three sites for both individual wetland plant species and functional groups. At each site, simulated plant yields were within 1 Mg ha –1 (±7%) of measured values ( r 2 = 0.99). Multisite species simulated yields were within 37% of measured values ( r 2 = 0.95). Functional groups performed as well as individual species simulations. Functional group simulated yields were within 1 Mg ha –1 (±5%) of measured yields. Plant growth is a major component of these wetland ecosystems, and ALMANAC verified wetland plant parameters support more accurate assessments of conservation programs and practices on the influence of wetland ecosystems embedded within agricultural fields. The improved plant parameters we provide here will be transferred to other process-based models that focus on other ecosystem components such as soil and water effects, facilitating wetland evaluations across the United States and elsewhere.

California, Delaware, Maryland, North Dakota, Texa↗

Dissolved arsenic concentrations in surface waters within the upper portions of the Klamath River Basin, Oregon and California

Arsenic toxicity is an environmental health problem. Levels of arsenic in surface waters at some locations in the Klamath River Basin in southern Oregon and northern California can exceed the U.S. Environmental Protection Agency (EPA) standard for drinking water. There are both anthropogenic and natural sources of arsenic. The Klamath River Basin consists primarily of volcanic deposits and contains an underground geothermal system with hot springs and warm water wells, all known natural sources of arsenic. Anthropogenic sources of arsenic are related to the agricultural use of herbicides, fungicides, and insecticides. Surface water arsenic levels can also be affected by fertilizer amendments, evaporative concentration, oxygen-level depletion, and various geochemical transformations that can increase arsenic mobilization. In this study by the U.S. Geological Survey and the Bureau of Reclamation, dissolved concentrations of arsenic, copper, and lead were measured in surface waters at 39 unique sites within the upper portions of the Klamath River Basin between 2018 and 2022. In every year, except 2022, sites were sampled four times between April and November. Surface-water arsenic concentrations varied up to four-orders of magnitude among sites. Median arsenic concentration was lowest at Cherry Creek (0.03 micrograms per liter [μg/L]) and highest at Wood Kimball Spring (36.7 μg/L), two sites located north of Upper Klamath Lake. The highest arsenic concentrations (17.4±4.9 μg/L, n =3) were found in drain sites (defined here as a waterbody returning used irrigation water) while the lowest arsenic concentrations were found in an artesian well (0.8 μg/L, n =1). The elevated arsenic concentrations of the drain sites suggest that arsenic might be concentrated or mobilized by agricultural activities, water re-use practices, and (or) by geochemical processes occurring around water stored in drains (that is, in the water column and across sediment water boundaries). A source of arsenic in drain water in the Klamath Strait Drain area includes water used for irrigation originating from Ady Canal. Other potential sources include groundwater, geothermal water, and local soils and sediments. Seasonal differences in surface-water arsenic concentrations were detected at 13 sites, 10 of which had higher arsenic concentrations in summer than in either spring or fall. The sites sampled around Upper Klamath Lake, the impounded rivers, one of the two canal sites, and 5 of the 14 river sites had higher surface-water arsenic concentrations in the summer than in either spring or fall. Surface-water arsenic concentrations from groundwater sources (that is, springs and in the artesian well) did not vary significantly among seasons (p-values greater than 0.1). Median surface-water concentrations of copper and lead ranged from 0.03 to 3.7 μg/L, and from 0.013 to 0.175 μg/L ( n =2–18), respectively. Dissolved concentrations of both metals were below acute toxicity endpoints reported by the EPA for freshwater animals. Surface-water arsenic concentrations varied independently from corresponding changes in surface-water lead or copper concentrations. However, arsenic concentrations measured in bed-sediment samples collected from a subset of sites located north of Upper Klamath Lake correlated strongly and significantly with the corresponding sedimentary lead concentrations ( p =0.015). Aqueous arsenic speciation measured in a subset of sites in 2019 and 2022 showed that all the arsenic existed as arsenic (V), the most oxidized arsenic species, and presumably, the least toxic. The highest proportions of arsenite (As(III)), the presumably most toxic arsenic species, relative to total arsenic concentrations were found at drain sites. Our assessment of dissolved arsenic concentrations in various surface-water bodies in the Upper Klamath River Basin reveals geographical areas of consistently low (below 2.1 μg/L), moderate (below 10 μg/L) and high (above 10 μg/L) surface-water arsenic concentrations. South of Upper Klamath Lake, surface-water arsenic concentrations were consistently higher than 20 μg/L at two drain sites located in an area of predominant agricultural land use with extensive water re-use practices. North of Upper Klamath Lake, surface-water arsenic concentrations greater than 20 μg/L were consistently measured at sites with limited nearby agricultural activities, suggesting a geogenic source. The consistently high arsenic levels from the Wood River at Jackson F. Kimball State Park, Fort Creek, and Crooked Creek, which are sites located at or near headwater spring sources, suggest a natural background source of arsenic. Water flowing downstream from this area could be a potential source of arsenic to Upper Klamath Lake and the Upper Klamath River.

California, Oregon↗

Conceptual framework and approach for conducting a geoenvironmental assessment of undiscovered uranium resources

This report presents a novel conceptual framework and approach for conducting a geologically based environmental assessment, or geoenvironmental assessment, of undiscovered uranium resources within an area likely to contain uranium deposits. The framework is based on a source-to-receptor model that prioritizes the most likely contaminant sources, contaminant pathways, and affected environmental media for three common uranium extraction methods—open pit or underground mining with milling and in situ recovery (ISR). Data on regional geology, hydrology, and climate, as well as historical uranium mining and milling records are used to estimate the probable amounts of waste rock, tailings, wastewater, surface land disturbance, and subsurface aquifer disturbance for likely mining methods. Constituents of concern that might take the form of leachates, dust, radon, and sediments formed by chemical and physical weathering are also identified in the geoenvironmental assessment. Finally, areas where constituents of concern are likely to occur and persist in air, land, surface water, and groundwater are indicated by the potential for dispersion of dust by wind, accumulation of radon because of air stagnation, dispersion of sediments and wastewater by runoff, and infiltration of wastewater or leachates with consideration of the likely mobility of contaminants in surface water and groundwater. The geoenvironmental assessment output can be summarized in the following primary products: (1) a descriptive geoenvironmental model; (2) maps and statistics of variables that indicate the potential for constituents of concern to occur and persist in air, land, surface water, and groundwater within a tract that is geologically permissive for the occurrence of uranium; and (3) tables providing estimated or indicated quantities of waste rock, tailings, wastewater, dust, and radon emissions that could be associated with undiscovered uranium resources, if extracted, for each permissive tract. The uranium geoenvironmental assessment could help natural resource managers to prioritize and (or) identify (1) important potential contaminant pathways, (2) management practices required depending on the types of constituents that could be of concern, (3) areas for response in the event of accidental release, and (4) future directions for study. Furthermore, indicators of rock and water volumes potentially associated with an undiscovered uranium deposit may be evaluated to make quantitative comparisons of water required for uranium production or potential waste products generated during uranium extraction from areas permissive for uranium resource occurrence throughout the United States.

Scientific Investigations Report↗

Trends in environmental, anthropogenic, and water-quality characteristics in the upper White River Basin, Indiana

The U.S. Geological Survey (USGS), in cooperation with The Nature Conservancy, undertook a study to update and extend results from a previous study (Koltun, 2019, https://doi.org/10.3133/sir20195119 ), using data from 3 additional years and newer estimation methods. Koltun (2019) assessed trends in streamflow, precipitation, and estimated annual mean concentrations and flux of nitrate plus nitrite, total Kjeldahl nitrogen, total phosphorus, and total suspended solids (TSS) for USGS streamflow gages on the upper White River at Muncie, near Nora, and near Centerton, Indiana. Annual mean and maximum daily streamflows had statistically significant upward trends at all study gages between water years 1978 and 2020. An abrupt increase in streamflow occurred around water year 2001. Annual total precipitation at the Indianapolis International Airport increased between calendar years 1932 and 2020 at an average rate of 0.089 inches per year. The current study assessed the magnitude, direction, and likelihood of change in flow-normalized concentrations and flux of TSS, total phosphorus, nitrate plus nitrite, and total Kjeldahl nitrogen between water years 1997 and 2019. With two exceptions, concentration and flux changes that were statistically significant in Koltun (2019, https://doi.org/10.3133/sir20195119 ), which reported changes between water years 1997 and 2017, still have the same statistically significant change directions. The reliability of the current trend result for TSS is uncertain because of a large gap in the TSS record for the Centerton gage. For each constituent, spatial patterns were examined in the sampled distribution of nutrient and TSS concentration data from 20 mainstem, tributary, and distributary locations in the upper White River Basin. The largest median concentrations of TSS, total phosphorus, and total Kjeldahl nitrogen were associated with mainstem upper White River sites downstream from Indianapolis. The median total phosphorus and total Kjeldahl nitrogen concentrations were elevated relative to bracketing upstream/downstream mainstem sites at the upper White River site immediately downstream from Muncie. Data on several anthropogenic factors that could influence the concentrations and fluxes of nutrients and TSS were gathered and analyzed to better understand the factors’ spatial and temporal variations. Those anthropogenic factors included population, land cover, cropping and operational tillage practices, fertilizer application, and upgrades to wastewater treatment systems and delivery processes.

Indiana↗

Influence of redox gradients on nitrate transport from the landscape to groundwater and streams

Increases in nitrogen applications to the land surface since the 1950s have led to a cascade of negative environmental impacts, including degradation of drinking water supplies, nutrient enrichment of aquatic ecosystems and contributions to global climate change. In this study, groundwater, streambed porewater, and stream sampling were used to establish trends in nitrate concentrations and how redox gradients influence nitrate transport across diverse glacial terranes. Decadal sampling has found that elevated nitrate concentrations in shallow groundwater beneath cropland have been sustained for decades. Redox gradients established in the saturated zone using dissolved O 2 , iron, nitrate and excess N 2 from denitrification suggest that nitrate-bearing zones are thin in glacial terranes dominated by fine materials. These thin nitrate-bearing zones lead to suboxic, low nitrate streambed porewater and limit the contributions of nitrate to streams from slow-flow groundwater. In contrast, thick oxic zones in more coarse-grained glacial terranes allow nitrate to reach deeper groundwater, resulting in streambed porewater with elevated nitrate concentrations and causing a large portion of stream nitrate to be derived from slow-flow groundwater. Groundwater age tracer data indicate that denitrification occurs more quickly in the terrane dominated by fine material than in the more coarse-grained terrane. The quicker depletion of nitrate in the more fine-grained terrane suggests that the thinner oxic zone in this terrane is due, in part, to the greater availability and reactivity of electron donors in this terrane than in the more coarse-grained terrane. Groundwater age tracer data and hydrograph separation analysis suggest that saturated zone lag times between when changes in land use practices occur and when changes in stream water are fully observed may vary widely across hydrogeologic settings.

Illinois, Indiana, Iowa, Michigan, Minnesota, Wisc↗

Method description, quality assurance, environmental data, and other Information for analysis of pharmaceuticals in wastewater-treatment-plant effluents, streamwater, and reservoirs, 2004-2009

Abstract Wastewater-treatment-plant (WWTP) effluents are a demonstrated source of pharmaceuticals to the environment. During 2004-09, a study was conducted to identify pharmaceutical compounds in effluents from WWTPs (including two that receive substantial discharges from pharmaceutical formulation facilities), streamwater, and reservoirs. The methods used to determine and quantify concentrations of seven pharmaceuticals are described. In addition, the report includes information on pharmaceuticals formulated or potentially formulated at the two pharmaceutical formulation facilities that provide substantial discharge to two of the WWTPs, and potential limitations to these data are discussed. The analytical methods used to provide data on the seven pharmaceuticals (including opioids, muscle relaxants, and other pharmaceuticals) in filtered water samples also are described. Data are provided on method performance, including spike data, method detection limit results, and an estimation of precision. Quality-assurance data for sample collection and handling are included. Quantitative data are presented for the seven pharmaceuticals in water samples collected at WWTP discharge points, from streams, and at reservoirs. Occurrence data also are provided for 19 pharmaceuticals that were qualitatively identified. Flow data at selected WWTP and streams are presented. Between 2004-09, 35-38 effluent samples were collected from each of three WWTPs in New York and analyzed for seven pharmaceuticals. Two WWTPs (NY2 and NY3) receive substantial inflows (greater than 20 percent of plant flow) from pharmaceutical formulation facilities (PFF) and one (NY1) receives no PFF flow. Samples of effluents from 23 WWTPs across the United States were analyzed once for these pharmaceuticals as part of a national survey. Maximum pharmaceutical effluent concentrations for the national survey and NY1 effluent samples were generally less than 1 ug/L. Four pharmaceuticals (methadone, oxycodone, butalbital and metaxalone) in samples of NY3 effluent had median concentrations ranging from 3.4 to greater than 400 ug/L. Maximum concentrations of oxycodone (1,700 ug/L) and metaxalone (3,800 ug/L) in samples from NY3 effluent exceeded 1,000 ug/L. Three pharmaceuticals (butalbital, carisoprodol, and oxycodone) in samples of NY2 effluent had median concentrations ranging from 2 to 11 ug/L. These findings suggest that current 2 manufacturing practices at these PFFs can result in pharmaceutical concentrations from 10 to 1,000 times higher than those typically found in WWTP effluents.

Open-File Report↗

Estrogenic activity response to best management practice implementation in agricultural watersheds in the Chesapeake Bay watershed

Best management practices (BMPs) have been predominantly used throughout the Chesapeake Bay watershed (CBW) to reduce nutrients and sediments entering streams, rivers, and the bay. These practices have been successful in reducing loads entering the estuary and have shown the potential to reduce other contaminants (pesticides, hormonally active compounds, pathogens) in localized studies and modeled load estimates. However, further understanding of relationships between BMPs and non-nutrient contaminant reductions at regional scales using sampled data would be beneficial. Total estrogenic activity was measured in surface water samples collected over a decade (2008–2018) in 211 undeveloped NHDPlus V2.1 watersheds within the CBW. Bayesian hierarchical modeling between total estrogenic activity and landscape predictors including landcover, runoff, BMP intensity, and a BMP*agriculture intensity interaction term indicates a 96% posterior probability that BMP intensity on agricultural land is reducing total estrogenic activity. Additionally, watersheds with high agriculture and low BMPs had a 49% posterior probability of exceeding an effects-based threshold in aquatic organisms of 1 ng/L but only a 1% posterior probability of exceeding this threshold in high-agriculture, high-BMP watersheds.

Chesapeake Bay watershed↗

A review of selected inorganic surface water quality-monitoring practices: are we really measuring what we think, and if so, are we doing it right?

Successful environmental/water quality-monitoring programs usually require a balance between analytical capabilities, the collection and preservation of representative samples, and available financial/personnel resources. Due to current economic conditions, monitoring programs are under increasing pressure to do more with less. Hence, a review of current sampling and analytical methodologies, and some of the underlying assumptions that form the bases for these programs seems appropriate, to see if they are achieving their intended objectives within acceptable error limits and/or measurement uncertainty, in a cost-effective manner. That evaluation appears to indicate that several common sampling/processing/analytical procedures (e.g., dip (point) samples/measurements, nitrogen determinations, total recoverable analytical procedures) are generating biased or nonrepresentative data, and that some of the underlying assumptions relative to current programs, such as calendar-based sampling and stationarity are no longer defensible. The extensive use of statistical models as well as surrogates (e.g., turbidity) also needs to be re-examined because the hydrologic interrelationships that support their use tend to be dynamic rather than static. As a result, a number of monitoring programs may need redesigning, some sampling and analytical procedures may need to be updated, and model/surrogate interrelationships may require recalibration.

Environmental Science & Technology↗

Evaluating large wood additions as a scalable method of urban stream restoration

Urbanization is associated with increased erosion and habitat homogenization in stream ecosystems. This habitat degradation often has biological consequences, such as decreased species richness. Conventional stream restoration practices are costly, and projects are limited to small areas with easy access. A scalable, low-cost method of stream restoration is needed to address the widespread degradation occurring in urban streams. Large wood (LW) is an important element in stream ecosystems that is typically abundant in forested watersheds but scarce in urban streams. LW can reduce water velocities, generate pool habitat, decrease erosion, and provide cover for aquatic organisms. In this study, we performed experimental LW installations to assess the capacity of LW restoration to improve habitat and reduce sediment transport in an urban headwater stream in Cincinnati, Ohio. We tracked the geomorphic effects of these installations using a before-after-control-impact study design in four 60-m reaches, two treatment and two control, over a 1.5-year period to investigate the following questions: (1) Will unanchored LW additions remain stable in a flashy urban stream? (2) Will LW additions increase the availability of pool habitat? (3) Will wood additions increase bed stability and modify sediment size distributions? We found that LW installations rapidly increased pool habitat availability (size) around stable jams, but a majority of the LW jams were frequently mobilized and reconfigured by high-flow events. LW additions had no significant impact on the probability of stream bed mobilization, likely due to the instability of LW; however, the distance particles traveled once mobilized significantly decreased. While LW additions can increase the availability of pool habitat in urban headwater streams, further investigation is needed to understand the stability of such structures and the environmental context where these additions will be most beneficial.

Ohio↗

Estimation of regional flow-duration curves for Indiana and Illinois

Flow-duration curves (FDCs) of daily streamflow are useful for many applications in water resources planning and management but must be estimated at ungaged sites. One common technique for estimating FDCs at ungaged sites in a given region is to use equations obtained by linear regression of FDC quantiles against multiple basin characteristics that can be computed by means of a geographic information system (GIS) computer program. In this study, such regional regression equations for estimating FDC quantiles were computed at the 0.1, 0.2, 0.5, 1, 2, 5, 10, 20, 25, 30, 40, 50, 60, 70, 75, 80, 90, 95, 98, 99, 99.5, 99.8, and 99.9-percent exceedance probabilities for rural, unregulated streams in Indiana and Illinois with temporally stationary records, using data through September 30, 2007. The approach used accounts for censored values below 0.01 cubic feet per second, which are observed at exceedance probabilities as low as 70 percent (that is, occurring at least 30 percent of the time). The basin characteristics used are suitable for computation by the USGS Web-based application, StreamStats, and are available for all U.S. Environmental Protection Agency (EPA) Region V states and the larger Great Lakes area, with some specific local exceptions. Indiana and Illinois were each divided into three regions, and a different set of equations for estimating FDC quantiles was computed for each region. The error of estimation of the FDC quantiles, measured as the mean square residual in log space converted to a percentage of the quantile, varies somewhat among regions and varies strongly with exceedance probability, with a minimum error of 10 to 20 percent at an exceedance probability of 5 or 10 percent, but rises to 17 to 38 percent at the high-flow end of the FDCs (the 0.1-percent quantile) and 100 to 745 percent at the low-flow end. For comparison, errors of estimation also were computed for FDC quantiles estimated by linear regression on drainage area alone and by using the drainage-area ratio (DAR) method. Three criteria, the nearest basin centroid and two others termed “strict” and “broad”, were used to select index stations for the DAR method. The “strict” and “broad” criteria put conditions on the basin centroid distance and the range of their drainage-area ratios, and the errors were averaged for all index station pairs satisfying each criterion. The use of the simpler DAR method usually resulted in higher errors of estimation compared to the linear regression equations with multiple basin characteristics, except occasionally in the case of the DAR method with the strict index station selection criterion, a criterion that is rarely possible to satisfy in practice. An example application of the estimated equations to one gaged and a few ungaged locations in a watershed in the study area is included to illustrate the steps required. These steps are the computation of the basin characteristics and, using those characteristics together with the estimated equations, the computation of the FDC quantiles and their uncertainties.

Illinois, Indiana↗

Microbiomes from biorepositories? 16S rRNA bacterial amplicon sequencing of archived and contemporary intestinal samples of wild mammals (Eulipotyphla: Soricidae)

Interest in gut microbial community composition has exploded recently as a result of the increasing ability to characterize these organisms and a growing understanding of their role in host fitness. New technologies, such as next generation amplicon (16S rRNA) sequencing, have enabled identification of bacterial communities from samples of diverse origin (e.g., fecal, skin, genital, environmental, etc.). Relatively little work, however, has explored the feasibility of utilizing historical samples (e.g., museum archived samples) of varying age, quality, and preservation type. Because natural history collections span multiple decades, these biorepositories have the potential to provide fundamental historical baselines to measure and better understand biodiversity on a changing planet. Utilizing even a small proportion of museum specimens could provide a means of sampling past microbial communities, allowing for direct comparison to contemporary communities and more complete understanding of dynamic shifts through time. We examined the feasibility of obtaining 16S rRNA amplicon microbiome data from whole gastrointestinal tracts (GIs) of shrews of varying age and preservation method, including 5 freshly collected shrew GIs immediately fixed in liquid nitrogen (LN2), 10 ten-year old shrew GIs frozen at −20°C (whole animal), and 10 shrews of varying ages (4 from 1968, 1 from 1980, 1 from 2001, 1 from 2004, 1 from 2007, 1 from 2011 and 2 from 2013) fixed and stored whole in 70% ethanol. Not surprisingly, results of 16S rDNA amplicon sequencing reveal significantly different bacterial communities between different preservation techniques and age of samples. Ten-year old frozen samples had bacterial communities most similar to freshly collected (LN2) samples, while the bacterial communities of both were significantly different from the 70% ethanol preserved samples of various ages. Amongst those preserved in 70% ethanol, age of samples also influenced bacterial community composition. Additionally, we compare results of OTU based and ASV based analyses. Looking ahead, field collectors and museums should develop and adopt best practices related to frozen preservation to ensure adequate material for future microbiome investigations.

Frontiers in Ecology and Evolution↗

Variability in stream chemistry in relation to urban development and biological condition in seven metropolitan areas of the United States, 1999-2004

Beginning in 1999, the U.S. Geological Survey National Water Quality Assessment Program investigated the effects of urban development on stream ecosystems in nine metropolitan study areas across the United States. In seven of these study areas, stream-chemistry samples were collected every other month for 1 year at 6 to 10 sites. Within a study area, the sites collectively represented a gradient of urban development from minimally to highly developed watersheds, based on the percentage of urban land cover; depending on study area, the land cover before urban development was either forested or agricultural. The stream-chemistry factors measured in the samples were total nitrogen, total phosphorus, chloride, and pesticide toxicity. These data were used to characterize the stream-chemistry factors in four ways (hereafter referred to as characterizations)—seasonal high-flow value, seasonal low-flow value, the median value (representing a single integrated value of the factor over the year), and the standard deviation of values (representing the variation of the factor over the year). Aquatic macroinvertebrate communities were sampled at each site to infer the biological condition of the stream based on the relative sensitivity of the community to environmental stressors. A Spearman correlation analysis was used to evaluate relations between (1) urban development and each characterization of the stream-chemistry factors and (2) the biological condition of a stream and the different characterizations of chloride and pesticide toxicity. Overall, the study areas where the land cover before urban development was primarily forested had a greater number of moderate and strong relations compared with the study areas where the land cover before urban development was primarily agriculture; this was true when urban development was correlated with the stream-chemistry factors (except chloride) and when chloride and pesticide toxicity was correlated with the biological condition. Except for primarily phosphorus in two study areas, stream-chemistry factors generally increased with urban development, and among the different characterizations, the median value typically indicated the strongest relations. The variation in stream-chemistry factors throughout the year generally increased with urban development, indicating that water quality became less consistent as watersheds were developed. In study areas with high annual snow fall, the variation in chloride concentrations throughout the year was particularly strongly related to urban development, likely a result of road salt applications during the winter. The relations of the biological condition to chloride and pesticide toxicity were calculated irrespective of urban development, but the overall results indicated that the relations were still stronger in the study areas that had been forested before urban development. The weaker relations in the study areas that had been agricultural before urban development were likely the results of biological communities having been degraded from agricultural practices in the watersheds. Collectively, these results indicated that, compared with sampling a stream at a single point in time, sampling at regular intervals during a year may provide a more representative measure of water quality, especially in the areas of high urban development where water quality fluctuated more widely between samples. Furthermore, the use of "integrated" values of stream chemistry factors may be more appropriate when assessing relations to the biological condition of a stream because the taxa composition of a biological community typically reflects the water-quality conditions over time.

Scientific Investigations Report↗