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USGS2014

Evaluation of a mass-balance approach to determine consumptive water use in northeastern Illinois

A principal component of evaluating and managing water use is consumptive use. This is the portion of water withdrawn for a particular use, such as residential, which is evaporated, transpired, incorporated into products or crops, consumed by humans or livestock, or otherwise removed from the immediate water environment. The amount of consumptive use may be estimated by a water (mass)-balance approach; however, because of the difficulty of obtaining necessary data, its application typically is restricted to the facility scale. The general governing mass-balance equation is: Consumptive use = Water supplied - Return flows . This study explored a mass-balance field-based computation of consumptive use in a residential setting at the scale of a sanitary sewer service area (sewershed). In addition, the feasibility (cost and difficulty) and relative uncertainties (accuracies) associated with applying the approach at this scale were evaluated. The study was conducted during 2011–13 within a 3.5-square mile (mi 2 ) sewershed confined to a predominantly residential area of Elk Grove Village, Illinois. Following background evaluation of the geohydrologic setting, sewershed infrastructure, and possible components of supplied and returned water, the identified primary components were 1. public water deliveries by the Elk Grove Village Department of Public Works, 2. self-served groundwater withdrawals in an included unincorporated neighborhood with public sanitary sewer service, 3. return flows to the sanitary sewer system, and 4. direct return of water discharged from swimming pools to Salt Creek. Water volumes principally were reported for deliveries, measured for sanitary sewer returns by using an acoustic Doppler current-velocity meter, and estimated for domestic withdrawals and swimming pool discharges to storm sewers. All water volumes required some degree of estimation. Observation wells were installed adjacent to sewer pipelines (lines) to determine the depth of the water table relative to that of the sewer lines and to collect water samples for detection of optical brighteners, as they are routinely discharged as clotheswashing waste to sanitary sewers. These data provided qualitative information on gains (inflow and infiltration) and losses (exfiltration) of sewer flow by pipe leakage, which might otherwise not be considered in the sewer flow return measurements. Hydrographs of sewer flow also were evaluated to identify and estimate storm-associated inputs to sewer flow. The volume of sanitary sewer return flow (778 million gallons per year [Mgal/yr]) was determined to substantially exceed the volume of supplied water (566 Mgal/yr), thus, for this study setting, voiding the utility of the applied mass-balance approach for estimating consumptive water use. Mass-balance components, including sanitary sewer flow and supplied-water use, were estimated within reasonable limits of uncertainty. Evidence of a water table that is typically shallower than the area’s sewer lines, yet is sometimes depressed near more deeply buried sewer lines, suggests groundwater infiltration into the sewers contributes to the excess volume of return flow. Technical obstacles and project resources precluded accurate quantification of infiltration volumes and other gains and losses to sanitary sewer flow. As estimated from various simplified methods, a minimum of 26 percent of return flow measured in the sanitary sewer represented groundwater infiltration and stormwater inflow; separately, about 2 percent of return flow was estimated as inflow. On the basis of the alternative winter base-rate method, consumptive use in the sewershed was estimated as 13 percent, which compares favorably with that used by the State of Illinois for Lake Michigan allocation accounting (10 percent) and other States and Canadian Provinces in the Great Lakes region (generally 10-15 percent). The study also provided other findings considered useful to studies of water use and to performance evaluation of sanitary sewer infrastructure. In urban residential settings, the comparatively small volumes of nonpublic sources of water (self-supplied) and direct (nonsanitary) return flow potentially can be ignored in the estimation of consumptive use. An acoustic Doppler current-velocity meter can be used in sanitary sewers to accurately measure discharge and reasonably estimate storm-associated inflows. Hourly to daily patterns of water use can be readily identified and quantified in the return flow record for the sanitary sewers. Relative volumes of infiltration gains (and exfiltration losses) can be substantial, even in sewer systems of communities making significant investments in system upgrades to limit sewer line leakage. Monitoring of optical brighteners in groundwater (and potentially in sanitary sewer flow) can provide a useful means of identifying probable leakage from (and to) sewer lines. Accurate quantification of gains and losses to sanitary sewer flow at the sewershed scale will require additional research effort and technical advances. Under ideal conditions, accurate quantification of consumptive use at the sewershed scale by the described mass-balance approach might be possible. Under most prevailing conditions, quantification likely would be more costly and time consuming than that of the present study, given the freely contributed technical support of the host community and relatively appropriate conditions of the study area. Essentials to quantification of consumptive use are a fully cooperative community, storm and sanitary sewers that are separate, and newer sewer infrastructure and (or) a robust program for limiting infiltration, exfiltration, and inflow.

Illinois↗
USGS2013

Methods, quality assurance, and data for assessing atmospheric deposition of pesticides in the Central Valley of California

The U.S. Geological Survey monitored atmospheric deposition of pesticides in the Central Valley of California during two studies in 2001 and 2002–04. The 2001 study sampled wet deposition (rain) and storm-drain runoff in the Modesto, California, area during the orchard dormant-spray season to examine the contribution of pesticide concentrations to storm runoff from rainfall. In the 2002–04 study, the number and extent of collection sites in the Central Valley were increased to determine the areal distribution of organophosphate insecticides and other pesticides, and also five more sample types were collected. These were dry deposition, bulk deposition, and three sample types collected from a soil box: aqueous phase in runoff, suspended sediment in runoff, and surficial-soil samples. This report provides concentration data and describes methods and quality assurance of sample collection and laboratory analysis for pesticide compounds in all samples collected from 16 sites. Each sample was analyzed for 41 currently used pesticides and 23 pesticide degradates, including oxygen analogs (oxons) of 9 organophosphate insecticides. Analytical results are presented by sample type and study period. The median concentrations of both chloryprifos and diazinon sampled at four urban (0.067 micrograms per liter [μg/L] and 0.515 μg/L, respectively) and four agricultural sites (0.079 μg/L and 0.583 μg/L, respectively) during a January 2001 storm event in and around Modesto, Calif., were nearly identical, indicating that the overall atmospheric burden in the region appeared to be fairly similar during the sampling event. Comparisons of median concentrations in the rainfall to those in the McHenry storm-drain runoff showed that, for some compounds, rainfall contributed a substantial percentage of the concentration in the runoff; for other compounds, the concentrations in rainfall were much greater than in the runoff. For example, diazinon concentrations in rainfall were about 70 percent of the diazinon concentration in the runoff, whereas the chlorpyrifos concentration in the rain was 1.8 times greater than in the runoff. The more water-soluble pesticides—carbaryl, metolachlor, napropamide, and simazine—followed the same pattern as diazinon and had lower concentrations in rain compared to runoff. Similar to chlorpyrifos,compounds with low water solubilities and higher soil-organic carbon partition coefficients, including dacthal, pendimethalin, and trifluralin, were found to have higher concentrations in rain than in runoff water and were presumed to partition to the suspended sediments and organic matter on the ground. During the 2002–04 study period, the herbicide dacthal had the highest detection frequencies for all sample types collected from the Central Valley sites (67–100 percent). The most frequently detected compounds in the wet-deposition samples were dacthal, diazinon, chlorpyrifos, and simazine (greater than 90 percent). The median wet-deposition amounts for these compounds were 0.044 micrograms per square meter per day (μg/m 2 /day), 0.209 μg/m 2 /day, 0.079 μg/m 2 /day, and 0.172 μg/m 2 /day, respectively. For the dry-deposition samples, detection frequencies were greater than 73 percent for the compounds dacthal, metolachor, and chlorpyrifos, and median deposition amounts were an order of magnitude less than for wet deposition. The differences between wet deposition and dry deposition appeared to be closely related to the Henry’s Law (H) constant of each compound, although the mass deposited by dry deposition takes place over a much longer time frame. Pesticides detected in rainfall usually were detected in the aqueous phase of the soil-box runoff water, and the runoff concentrations were generally similar to those in the rainfall. For compounds detected in the aqueous phase and suspended-sediment samples of soil-box runoff, concentrations of pesticides in the aqueous phase generally were detected in low concentrations and had few corresponding detections in the suspended- sediment samples. Dacthal, diazinon, chlorpyrifos, and simazine were the most frequently detected pesticides (greater than 83 percent) in the aqueous-phase samples, with median concentrations of 0.010 μg/L, 0.045 μg/L, 0.016 μg/L, and 0.077 μg/L, respectively. Simazine was the most frequently detected compound in the suspended-sediment samples (69 percent), with a median concentration of 0.232 μg/L. Results for compounds detected in the surficial-soil samples collected throughout the study period showed that there was an increase in concentration for some compounds, indicating atmospheric deposition of these compounds onto the soil-box surface. In the San Joaquin Valley, the compounds chlorpyrifos, dacthal, and iprodione were detected at higher concentrations (between 1.4 and 2 times greater) than were found in the background samples collected from the San Joaquin Valley soil-box sites. In the Sacramento Valley, the compounds chlorpyrifos, dacthal, iprodione, parathionmethyl, and its oxygen analog, paraoxon-methyl, were detected in samples collected during the study period in low concentrations, but were not detected in the background concentration of the Sacramento Valley soil mix.

California↗
USGS1998

Water-quality assessment of the Central Arizona Basins, Arizona and northern Mexico – Environmental setting and overview of water quality

The Central Arizona Basins study area in central and southern Arizona and northern Mexico is one of 60 study units that are part of the U.S. Geological Survey's National Water-Quality Assessment program. The purpose of this report is to describe the physical, chemical, and environmental characteristics that may affect water quality in the Central Arizona Basins study area and present an overview of water quality. Covering 34,700 square miles, the study area is characterized by generally north to northwestward-trending mountain ranges separated by broad, gently sloping alluvial valleys. Most of the perennial rivers and streams are in the northern part of the study area. Rivers and streams in the south are predominantly intermittent or ephemeral and flow in response to precipitation such as summer thunderstorms. Effluent-dependent streams do provide perennial flow in some reaches. The major aquifers in the study area are in the basin-fill deposits that may be as much as 12,000 feet thick. The 1990 population in the study area was about 3.45 million, and about 61 percent of the total was in Maricopa County (Phoenix and surrounding cities). Extensive population growth over the past decade has resulted in a twofold increase in urban land areas and increased municipal water use; however, agriculture remains the major water use. Seventy-three percent of all water with drawn in the study area during 1990 was used for agricultural purposes. The largest rivers in the study area-the Gila, Salt, and Verde-are perennial near their headwaters but become intermittent downstream because of impoundments and artificial diversions. As a result, the Central Arizona Basins study area is unique compared to less arid basins because the mean surface-water outflow is only 528 cubic feet per second from a total drainage area of 49,650 square miles. Peak flows in the northern part of the study area are the result of snowmelt runoff; whereas, summer thunderstorms account for the peak flows in the southern part. Ground water is the primary water supply in most of Arizona and the only source of drinking water used by communities in the southern half of the study area. Years of overpumping have caused water tables in basin fill to drop below once-perennial streams leaving streambeds dry, water too deep to pump economically, pumping of poorer quality water with depth, and earth fissures resulting from subsidence after dewatering of sediments. Natural processes-such as leaching of trace elements and major ions from geologic formations-and human activities-such as mining, agriculture, and urban development-have major effects on the quality of surface-water and ground-water resources in the Central Arizona Basins study area. Surface-water quality standards in Arizona are based on the designated use of the water such as full or partial body contact, fish consumption, aquatic and wildlife uses, and agriculture. Maintaining the biological integrity (health) of surface waters in Arizona is an important part of ensuring that these waters are suitable for designated uses. Important water-quality issues for surface water that are somewhat unique to Arizona include: (1) streamflows and riparian environments sustained by effluent from municipal wastewater-treatment plants that contains high concentrations of nutrients, potentially toxic trace elements and organic compounds, and fecal bacteria; (2) industrial, mining, agricultural, and municipal sources of contamination from Mexico; and (3) unpredictable high flows from major summer thunder storms causing stream-channel changes; high suspended-sediment concentrations and loads; sewage overflows; and breaching, erosion, and washout of landfills and mining operations. The quality of water in aquifers that are protected for drinking- water use is subject to standards that are in most cases equal to or more stringent than the primary drinking-water regulations of the U.S. Environmental Protection Agency. The general che

Arizona↗
USGS2012

Magnitude of flood flows for selected annual exceedance probabilities in Rhode Island through 2010

Heavy persistent rains from late February through March 2010 caused severe widespread flooding in Rhode Island that set or nearly set record flows and water levels at many long-term streamgages in the State. In response, the U.S. Geological Survey, in partnership with the Federal Emergency Management Agency, conducted a study to update estimates of flood magnitudes at streamgages and regional equations for estimating flood flows at ungaged locations. This report provides information needed for flood plain management, transportation infrastructure design, flood insurance studies, and other purposes that can help minimize future flood damages and risks. The magnitudes of floods were determined from the annual peak flows at 43 streamgages in Rhode Island (20 sites), Connecticut (14 sites), and Massachusetts (9 sites) using the standard Bulletin 17B log-Pearson type III method and a modification of this method called the expected moments algorithm (EMA) for 20-, 10-, 4-, 2-, 1-, 0.5-, and 0.2-percent annual exceedance probability (AEP) floods. Annual-peak flows were analyzed for the period of record through the 2010 water year; however, records were extended at 23 streamgages using the maintenance of variance extension (MOVE) procedure to best represent the longest period possible for determining the generalized skew and flood magnitudes. Generalized least square regression equations were developed from the flood quantiles computed at 41 streamgages (2 streamgages in Rhode Island with reported flood quantiles were not used in the regional regression because of regulation or redundancy) and their respective basin characteristics to estimate magnitude of floods at ungaged sites. Of 55 basin characteristics evaluated as potential explanatory variables, 3 were statistically significant—drainage area, stream density, and basin storage. The pseudo-coefficient of determination (pseudo- R2 ) indicates these three explanatory variables explain 95 to 96 percent of the variance in the flood magnitudes from 20- to 0.2-percent AEPs. Estimates of uncertainty of the at-site and regression flood magnitudes are provided and were combined with their respective estimated flood quantiles to improve estimates of flood flows at streamgages. This region has a long history of urban development, which is considered to have an important effect on flood flows. This study includes basins that have an impervious area ranging from 0.5 to 37 percent. Although imperviousness provided some explanatory power in the regression, it was not statistically significant at the 95-percent confidence level for any of the AEPs examined. Influence of urbanization on flood flows indicates a complex interaction with other characteristics that confounds a statistical explanation of its effects. Standard methods for calculating magnitude of floods for given AEP are based on the assumption of stationarity, that is, the annual peak flows exhibit no significant trend over time. A subset of 16 streamgages with 70 or more years of unregulated systematic record indicates all but 4 streamgages have a statistically significant positive trend at the 95-percent confidence level; three of these are statistically significant at about the 90-percent confidence level or above. If the trend continues linearly in time, the estimated magnitude of floods for any AEP, on average, will increase by 6, 13, and 21 percent in 10, 20, and 30 years' time, respectively. In 2010, new peaks of record were set at 18 of the 21 active streamgages in Rhode Island. The updated flood frequency analysis indicates the peaks at these streamgages ranged from 2- to 0.2-percent AEP. Many streamgages in the State peaked at a 0.5- and 0.2-percent AEP, except for streamgages in the Blackstone River Basin, which peaked from a 4- to 2-percent AEP.

Rhode Island↗
USGS2013

The quality of our Nation's waters: factors affecting public-supply-well vulnerability to contamination: understanding observed water quality and anticipating future water quality

As part of the U.S. Geological Survey National Water-Quality Assessment (NAWQA) Program, a study was conducted from 2001 to 2011 to shed light on factors that affect the vulnerability of water from public-supply wells to contamination (referred to hereafter as “public-supply-well vulnerability”). The study was designed as a follow-up to earlier NAWQA studies that found mixtures of contaminants at low concentrations in groundwater near the water table in urban areas across the Nation and, less frequently, in deeper groundwater typically used for public supply. Beside the factors affecting public-supply-well vulnerability to contamination, this circular describes measures that can be used to determine which factor (or factors) plays a dominant role at an individual public-supply well. Case-study examples are used throughout to show how such information can be used to improve water quality. In general, the vulnerability of the water from public-supply wells to contamination is a function of contaminant input within the area that contributes water to a well, the mobility and persistence of a contaminant once released to the groundwater, and the ease of groundwater and contaminant movement from the point of recharge to the open interval of a well. The following measures described in this circular are particularly useful for indicating which contaminants in an aquifer might reach an individual public-supply well and when, how, and at what concentration they might arrive: * Sources of recharge—Information on the sources of recharge for a well provides insight into contaminants that might enter the aquifer with the recharge water and potentially reach the well. * Geochemical conditions—Information on the geochemical conditions encountered by groundwater traveling to a well provides insight into contaminants that might persist in the water all the way to the well. * Groundwater-age mixtures—Information on the ages of the different waters that mix in a well provides insight into the time lag between contaminant input at the water table and contaminant arrival at the well. It also provides insight into the potential for in-well dilution of contaminated water by unaffected groundwater of a different age that simultaneously enters the well. Preferential flow pathways—pathways that provide little resistance to flow—can influence how all other factors affect public-supply-well vulnerability to contamination. For example, preferential flow pathways can influence whether a contaminant source is physically linked to a well, whether contaminant concentrations are substantially altered before contaminated groundwater reaches a well, and whether contaminated groundwater can arrive at a well within a timeframe of concern to the well owner. Methods for recognizing the influence of preferential flow pathways on the quality of water from a public-supply well are presented in this circular and can provide opportunities to prevent or mitigate the deterioration of a water supply. Knowing what water-quality variables to measure, what spatial and temporal scales on which to measure them, and how to interpret the resulting data makes it possible for samples from public-supply wells to provide a broad window into a well’s past and present water quality—and possibly future water quality. Such insight can enable resource managers to prioritize actions for sustaining a high-quality groundwater source of drinking water.

Circular↗
USGS2009

Hydrology, Water Quality, and Aquatic Communities of Selected Springs in the St. Johns River Water Management District, Florida

Hydrologic, physicochemical, and aquatic community data were collected and compiled by the U.S. Geological Survey for selected springs within the St. Johns River Water Management District from January 2004 to October 2007. Nine springs were included in this study: Alexander, Apopka, Bugg, De Leon, Gemini, Green, Rock, Silver Glen, and Wekiwa. Urban lands increased in Alexander, Apopka, De Leon, Gemini, Green, and Wekiwa springsheds between 1973 and 2004, accompanied by a loss of forested and/or agricultural lands in most springsheds. Forested cover increased and open surface waters and wetlands decreased in the Bugg and Rock springsheds. Although rainfall did not change significantly over time in each springshed, spring discharge decreased significantly in De Leon, Fern Hammock, Rock, Silver, and Wekiwa Springs. Nitrate concentrations increased significantly with time in Apopka, Fern Hammock, Gemini Springs run, and Juniper Springs, and decreased significantly in Alexander Spring, Bugg Spring run, Rock Springs, and Wekiwa Springs. Phosphorus increased significantly with time in Juniper Springs and decreased significantly in Apopka, De Leon, Rock, Silver Glen, and Wekiwa Springs. Benthic macroinvertebrate communities ranged from relatively low diversity assemblages (Green Spring) to assemblages with high taxonomic richness, diversity, and dominance (Rock and De Leon Springs). Shannon-Wiener diversity index averages among samples pooled by spring were lowest for Apopka Spring and greatest for Rock, Bugg, and Silver Glen Springs. Mean Stream Condition Index for pooled samples per spring was lowest for De Leon and Gemini Springs and highest for Rock and Wekiwa Springs. Mean percentages of very tolerant taxa were lowest for Alexander Spring and highest for Bugg and Green Springs. Fish community richness was lowest for Green Spring, and greatest for Alexander Spring run and Silver Glen Springs. Forty five fish species representing 35 genera and 23 families were collected or observed from all springs in this study. Samples were dominated by centrarchids, cyprinids, fundulids, atherinopsids, and poeciliids.

Scientific Investigations Report↗
USGS2013

Water quality in the Anacostia River, Maryland and Rock Creek, Washington, D.C.: Continuous and discrete monitoring with simulations to estimate concentrations and yields of nutrients, suspended sediment, and bacteria

Concentrations and loading estimates for nutrients, suspended sediment, and E. coli bacteria were summarized for three water-quality monitoring stations on the Anacostia River in Maryland and one station on Rock Creek in Washington, D.C. Both streams are tributaries to the Potomac River in the Washington, D.C. metropolitan area and contribute to the Chesapeake Bay estuary. Two stations on the Anacostia River, Northeast Branch at Riverdale, Maryland and Northwest Branch near Hyattsville, Maryland, have been monitored for water quality during the study period from 2003 to 2011 and are located near the shift from nontidal to tidal conditions near Bladensburg, Maryland. A station on Paint Branch is nested above the station on the Northeast Branch Anacostia River, and has slightly less developed land cover than the Northeast and Northwest Branch stations. The Rock Creek station is located in Rock Creek Park, but the land cover in the watershed surrounding the park is urbanized. Stepwise log-linear regression models were developed to estimate the concentrations of suspended sediment, total nitrogen, total phosphorus, and E. coli bacteria from continuous field monitors. Turbidity was the strongest predictor variable for all water-quality parameters. For bacteria, water temperature improved the models enough to be included as a second predictor variable due to the strong dependence of stream metabolism on temperature. Coefficients of determination (R 2 ) for the models were highest for log concentrations of suspended sediment (0.9) and total phosphorus (0.8 to 0.9), followed by E. coli bacteria (0.75 to 0.8), and total nitrogen (0.6). Water-quality data provided baselines for conditions prior to accelerated implementation of multiple stormwater controls in the watersheds. Counties are currently in the process of enhancing stormwater controls in both watersheds. Annual yields were estimated for suspended sediment, total nitrogen, total phosphorus, and E. coli bacteria using the U.S. Geological Survey model LOADEST with hourly time steps of turbidity, flow, and time. Yields of all four parameters were within ranges found in other urbanized watersheds in Chesapeake Bay. Annual yields for all four watersheds over the period of study were estimated for suspended sediment (65,500 – 166,000 kilograms per year per square kilometer; kg/yr/km 2 ), total nitrogen (465 - 911 kg/yr/km 2 ), total phosphorus (36 - 113 kg/yr/km 2 ), and E. coli bacteria (6.0 – 38 x 10 12 colony forming units/yr/km 2 ). The length of record was not sufficient to determine trends for any of the water-quality parameters; within confidence intervals of the models, results were similar to loads determined by previous studies for the Northeast and Northwest Branch stations of the Anacostia River.

Maryl↗
USGS2020

Temporal and spatial variability of water quality in the San Antonio segment of the Edwards aquifer recharge zone, Texas, with an emphasis on periods of groundwater recharge, September 2017–July 2019

Ongoing urbanization on the Edwards aquifer recharge zone in the greater San Antonio area raises concern about the potential adverse effects on the public water supply from development. To address this concern, the U.S. Geological Survey, in cooperation with the City of San Antonio, studied patterns of temporal and spatial changes in water quality at selected surface-water and groundwater sites in the Edwards aquifer recharge zone, with an emphasis on changes during periods of groundwater recharge. Water-quality characteristics were continuously monitored and discrete water samples were collected at two sets of paired surface-water (stream) and groundwater (well) sites during a 2-year period (2017–19) that included relatively dry conditions and a large recharge event in September 2018 when as much as 16 inches of rain fell in parts of the study area. Continuous monitoring of water-level altitude, specific conductance, and concentrations of nitrate in two wells completed in the Edwards aquifer provided high-resolution data showing detailed changes in water quality across a broad range of hydrologic conditions. Water levels in the wells responded rapidly (within hours to days) to recharge from both small and large rainfall and runoff events; changes in groundwater quality as a consequence of the influx of surface-derived recharge were indicated by changes in values of the monitored characteristics. A broad range in measured values of the stable isotopes of water expressed as delta deuterium and delta oxygen-18 in the water samples collected from two streams (Salado and West Elm Creeks), in comparison to the tight clustering of the values of these isotopes in groundwater samples, indicates that source waters (surface waters) of widely varying chemical characteristics become homogenized within the aquifer system. Concentrations of major ions, trace ions, and nutrient concentrations in stormwater runoff indicate a combination of land-derived and rainfall-derived constituents. The distribution of concentrations of nitrogen species (nitrite, nitrate, and nitrogen in ammonia) among sampling sites transitions from a more variable distribution in stormwater runoff to a more uniform distribution in groundwater in which the dominant form is nitrate. Differences in nitrate isotopic composition and concentration in groundwater across the study area are likely controlled by the relative contributions of natural and anthropogenic nitrogen (with the anthropogenic nitrogen component including a wastewater source) and by the process of nitrification. Among all measured constituents, pesticides detected in discrete stormwater-runoff samples provided the clearest indication that urbanization was adversely affecting water quality; specifically, the more urbanized surface-water site had a greater number of detections and greater variety of detected pesticides. Though temporal variability in the numbers and types of pesticides was evident, the overall proportion of pesticides was dominated by triazine herbicides including atrazine, atrazine degradates, and simazine. The observed hydrologic responses to rainfall and corresponding changes in water quality in wells are thought to result from the direct hydrologic connectivity of surface water and unconfined groundwater; however, patterns of groundwater-quality change indicate mixing from multiple sources such as ambient groundwater, recent surface-derived recharge, and possibly inflow from other aquifers. Therefore, understanding the connection between urbanization and groundwater quality cannot be inferred from the input of stormwater runoff alone as changes related to local and regional hydrologic conditions also need to be considered. It should be noted that a single study comparing the results from two site pairs is not able to support definitive conclusions about the full effect of urbanization on surface water/groundwater quality; however, this study does provide useful insights about the spatial and temporal variability of both stormwater runoff and unconfined groundwater that are consistent with expectations based on the current conceptual model that depicts the Edwards aquifer surface-water/groundwater system as a single water resource.

Texas↗
USGS2008

Simulations of ground-water flow and particle pathline analysis in the zone of contribution of a public-supply well in Modesto, eastern San Joaquin Valley, California

Shallow ground water in the eastern San Joaquin Valley is affected by high nitrate and uranium concentrations and frequent detections of pesticides and volatile organic compounds (VOC), as a result of ground-water development and intensive agricultural and urban land use. A single public-supply well was selected for intensive study to evaluate the dominant processes affecting the vulnerability of public-supply wells in the Modesto area. A network of 23 monitoring wells was installed, and water and sediment samples were collected within the approximate zone of contribution of the public-supply well, to support a detailed analysis of physical and chemical conditions and processes affecting the water chemistry in the well. A three-dimensional, steady-state local ground-water-flow and transport model was developed to evaluate the age of ground water reaching the well and to evaluate the vulnerability of the well to nonpoint source input of nitrate and uranium. Particle tracking was used to compute pathlines and advective travel times in the ground-water flow model. The simulated ages of particles reaching the public-supply well ranged from 9 to 30,000 years, with a median of 54 years. The age of the ground water contributed to the public-supply well increased with depth below the water table. Measured nitrate concentrations, derived primarily from agricultural fertilizer, were highest (17 milligrams per liter) in shallow ground water and decreased with depth to background concentrations of less than 2 milligrams per liter in the deepest wells. Because the movement of water is predominantly downward as a result of ground-water development, and because geochemical conditions are generally oxic, high nitrate concentrations in shallow ground water are expected to continue moving downward without significant attenuation. Simulated long-term nitrate concentrations indicate that concentrations have peaked and will decrease in the public-supply well during the next 100 years because of the low nitrate concentrations in recharge beneath the urban area and the increasing proportion of urban-derived ground water reaching the well. The apparent lag time between peak input concentrations and peak concentrations in the well is about 20 to 30 years. Measured uranium concentrations were also highest (45 micrograms per liter) in shallow ground water, and decreased with depth to background concentrations of about 0.5 microgram per liter. Naturally-occurring uranium adsorbed to aquifer sediments is mobilized by oxygen-rich, high-alkalinity water. Alkalinity increased in shallow ground water in response to agricultural development. As ground-water pumping increased in the 1940s and 1950s, this alkaline water moved downward through the ground-water flow system, mobilizing the uranium adsorbed to aquifer sediments. Ground water with high alkalinity and high uranium concentrations is expected to continue to move deeper in the system, resulting in increased uranium concentrations with depth in ground water. Because alkalinity (and correspondingly uranium) concentrations were high in shallow ground water beneath both the urban and the agricultural land, long-term uranium concentrations in the public-supply well are expected to increase as the proportion of uranium-affected water contributed to the well increases. Assuming that the alkalinity near the water table remains the same, the simulation of long-term alkalinity in the public-supply well indicates that uranium concentrations in the public-supply well will likely approach the maximum contaminant level; however, the time to reach this level is more than 100 years because of the significant proportion of old, unaffected water at depth that is contributed to the public-supply well.

California↗
USGS2015

Organic waste compounds as contaminants in Milwaukee-area streams

Organic waste compounds (OWCs) are ingredients and by-products of common agricultural, industrial, and household substances that can contaminate our streams through sources like urban runoff, sewage overflows, and leaking septic systems. To better understand how OWCs are affecting Milwaukee-area streams, the U.S. Geological Survey, in cooperation with the Milwaukee Metropolitan Sewerage District, conducted a three-year study to investigate the presence and potential toxicity of 69 OWCs in base flow, stormflow, pore water, and sediment at 14 stream sites and 3 Milwaukee harbor locations. This fact sheet summarizes the major findings of this study, including detection frequencies and concentrations, potential toxicity, the prevalence of polycyclic aromatic hydrocarbons (PAHs), and the influence of urbanization.

Wisconsin↗
USGS2024

Mapping development preferences on the perceived value of ecosystem services and land use conflict and compatibility in Greater Kuala Lumpur

Rapid and unplanned development can diminish the social values for ecosystem services associated with urban landscapes. Tropical Global South cities, such as Greater Kuala Lumpur (GKL), Malaysia, that are highly biodiverse, are particularly vulnerable to the fragmentation and loss of natural ecosystems. This study investigates the social values for ecosystem services in GKL, a rapidly urbanising metropolitan area in Southeast Asia and presents the novel application of the SolVES ( Social Values for Ecosystem Services ) tool to an urban area. A public participatory GIS (PPGIS) survey was conducted to assess residents’ development preferences and perceived distribution of social values. The study revealed two groups of respondents, using cluster analysis, each with unique development preferences - a group favouring both green and grey developments and another favouring green development but strongly opposing grey development. The two groups differed statistically in their sociodemographic characteristics, and also how they mapped different social values. Our spatial analysis of their preferences towards future urban expansion in GKL highlighted locations where there is potential for land-use conflict. For example, the favour-balanced-development group tended to value built areas over green spaces. These findings support the need to consider residents’ preferences and socioecological traits through greater public engagement in urban landscape management.

Greater Kuala Lumpur↗
USGS2008

Reverse Evolution of Armor Plates in the Threespine Stickleback

Faced with sudden environmental changes, animals must either adapt to novel environments or go extinct. Thus, study of the mechanisms underlying rapid adaptation is crucial not??only for the understanding of natural evolutionary processes but also for the understanding of human-induced evolutionary change, which is an increasingly important problem [1-8]. In the present study, we demonstrate that the frequency of completely plated threespine stickleback fish (Gasterosteus aculeatus) has increased in an urban freshwater lake (Lake Washington, Seattle, Washington) within the last 40 years. This is a dramatic example of "reverse evolution," [9] because the general evolutionary trajectory is toward armor-plate reduction in freshwater sticklebacks [10]. On the basis of our genetic studies and simulations, we propose that the most likely cause of reverse evolution is increased selection for the completely plated morph, which we suggest could result from higher levels of trout predation after a sudden increase in water transparency during the early 1970s. Rapid evolution was facilitated by the existence of standing allelic variation in Ectodysplasin (Eda), the gene that underlies the major plate-morph locus [11]. The Lake Washington stickleback thus provides a novel example of reverse evolution, which is probably caused by a change in allele frequency at the major plate locus in response to a changing predation regime. ?? 2008 Elsevier Ltd. All rights reserved.

Current Biology↗
USGS1997

Surface-water-quality assessment of the upper Illinois River Basin in Illinois, Indiana, and Wisconsin– Results of investigations through April 1992

A water-quality assessment of the upper Illinois River Basin (10,949 square miles) was conducted during water years 1987-91. This assessment involved interpretation of available data; 4 years of intensive data collection, including monthly sample collection at eight fixed-monitoring stations in the basin; and synoptic studies of selected water-quality constituents at many sites. The number of exceedances of water-quality criteria for chromium, copper, lead, mercury, silver, and zinc in water was essentially the same at similar stations between 1978-86 and 1987-90. For water and sediment, a large signature for many trace inorganic constituents was observed from the Chicago metropolitan area, mainly from the Des Plaines River Basin and continuing down the Illinois River. Loads of trace inorganic constituents in water were 2-13 times greater from the Chicago metropolitan area than from rural areas in the upper Illinois River Basin. Concentrations of cadmium, mercury, nickel, selenium, and zinc appeared to be relatively enriched in biota in the upper Illinois River Basin compared to other river basins. Biota from some urban sites were enriched with respect to several elements. For example, relatively large concentrations of cadmium, chromium, copper, lead, and nickel were observed in biota from sites in the Chicago River in the metropolitan area and the Calumet River. Results of pesticide sampling in 1988 and 1989 identified the pesticides bromacil, diazinon, malathion, prometon, and simazine as urban related and alachlor, atrazine, cyanazine, metolachlor, and metribuzin as agricultural related. Phenol concentrations never exceeded general-use and secondary-contact water-quality standards of 100 and 300 micrograms per liter, respectively. Pentachlorophenol concentrations observed at the Illinois River at Marseilles, Ill., between 1981 and 1992 decreased beginning in 1987. A breakdown product of the organochlorine pesticide dichloro-diphenyl-trichloroethane (DDT), p,p'-DDE was the most commonly detected organic compound in biota in both 1989 and 1990. In the nine fish-fillet samples collected in 1989, exceedances of U.S. Environmental Protection Agency (USEPA) fish tissue concentrations were noted for p,p'-DDE in all nine fillets and for dieldrin in five of the nine fillets. Nutrient concentrations in water in the study area generally were larger than concentrations typically found in natural waters. The Des Plaines River Basin contributed approximately 41 percent of the total nitrogen load to the upper Illinois River Basin, whereas the Kankakee River and Iroquois River Basins contributed about 34 and 14 percent of the total load, respectively. Dissolved-oxygen concentrations measured during a 1988 synoptic sampling exceeded State water-quality standards at 76 percent of the sampled sites. Bacteria densities greater than water-quality standards were observed at all of the fixed-monitoring stations, but densities greater than water-quality criteria and standards were observed more often at stations in the Des Plaines River Basin. Results from the analysis of changes in water quality following changes in wastewater-treatment practices indicated that current monitoring programs, although sufficient for their intended purposes, are not suitable for this type of retrospective assessment in large-scale water-quality assessments. Changes were not indicated in fish-community structure and population following changes in wastewater-treatment practices. A strong relation between the quality of the fish community and overall water-quality conditions was observed, although USEPA acute criteria for the protection of freshwater aquatic life were rarely exceeded. Analyses of fish-community data clearly showed that water quality in the urbanized parts of the study area were degraded relative to those in agricultural areas. Total chromium in streambed sediments and total recoverable sodium in water were highly correlated

Illinois, Indiana, Wisconsin↗
USGS2015

The Pacific northwest stream quality assessment

In 2015, the U.S. Geological Survey (USGS) National Water-Quality Assessment (NAWQA) program is assessing stream quality in the Pacific Northwest. The goals of the Pacific Northwest Stream Quality Assessment (Pacific Northwest study) are to assess the quality of streams in the region by characterizing multiple water-quality factors that are stressors to aquatic life and to evaluate the relation between these stressors and biological communities. The effects of urbanization and agriculture on stream quality for the Puget Lowlands and Willamette Valley are the focus of this regional study. Findings will provide the public and policymakers with information regarding which human and environmental factors are the most critical in affecting stream quality and, thus, provide insights about possible approaches to protect or improve the health of streams in the region. The Pacific Northwest study will be the third regional study by the NAWQA program, and it will be of similar design and scope as the first two—the Midwest in 2013 and the Southeast in 2014 (Van Metre and others, 2012, 2014).

Oregon, Washington↗
USGS1983

Magnitude and frequency of flooding on small urban watersheds in the Tampa Bay area, west-central Florida

Hydrologic data collected on nine small urban watersheds in the Tampa Bay area of west-central Florida and a method for estimating peak discharges in the study area are described. The watersheds have mixed land use and range in size from 0.34 to 3.45 square miles. Watershed soils, land use, and storm-drainage system data are described. Urban development ranged from a sparsely populated area with open-ditch storm sewers and 19% impervious area to a completely sewered watershed with 61% impervious cover. The U.S. Geological Survey natural-basin and urban-watershed models were calibrated for the nine watersheds using 5-minute interval rainfall data from the Tampa, Florida, National Weather Service rain gage to simulate annual peak discharge for the period 1906-52. A log-Pearson Type III frequency analysis of the simulated annual maximum discharge was used to determine the 2-, 5-, 10-, 25-, 50-, and 100-year flood discharges for each watershed. Flood discharges were related in a multiple-linear regression to drainage area, channel slope, detention storage area, and an urban-development factor determined by the extent of curb and gutter street drainage and storm-sewer system. The average standard error for the regional relations ranged from + or - 32 to + or - 42%. (USGS)

Florida↗
USGS1987

Magnitude and frequency of floods in rural and urban basins of North Carolina

The applicability of the nationwide urban flood relations in the Piedmont and Coastal Plain provinces is evaluated. Data for 254 gaging stations on rural streams with 10 or more years of record were used in multiple linear regression analyses with basin and climatic variables, to derive regional relations for estimating flood discharges having recurrence intervals of 2- to 100-years. Rural relations are presented for three hydrologic areas: (1) Blue Ridge-Piedmont, (2) Coastal Plain, and (3) Sand Hills. Drainage area is the only basin characteristic in the relations. The average standard error of estimate of the relations for the Blue Ridge-Piedmont, Coastal Plain, and Sand Hills hydrologic areas is 44, 39, and 24%, respectively. Flood discharges for the 2-, 5-, 10-, 25-, 50-, and 100-year recurrence intervals for the 254 streamflow stations used in the regionalization study are also presented. Flood frequency distributions of simulated annual maximum discharges for four urban basins in the Coastal Plain indicate that the nationwide relations are applicable in the province. The root mean squared error for the 10- and 100-year flood discharges, using the nationwide relations, is 44% and 49%, respectively. Simulated data for six sites in the Piedmont were used to analyze the applicability of the nationwide urban relations in the province. The root mean squared error is 64% for the 10-year flood and 42% for the 100-year flood. No recommendation is made concerning use of the nationwide relations in the Piedmont.

North Carolina↗
USGS2012

Recent and historic sediment dynamics along Difficult Run, a suburban Virginia Piedmont stream

Suspended sediment is one of the major concerns regarding the quality of water entering the Chesapeake Bay. Some of the highest suspended-sediment concentrations occur on Piedmont streams, including Difficult Run, a tributary of the Potomac River draining urban and suburban parts of northern Virginia. Accurate information on catchment level sediment budgets is rare and difficult to determine. Further, the sediment trapping portion of sediment budget represents an important ecosystem service that profoundly affects downstream water quality. Our objectives, with special reference to human alterations to the landscape, include the documentation and estimation of floodplain sediment trapping (present and historic) and bank erosion along an urbanized Piedmont stream, the construction of a preliminary sediment balance, and the estimation of legacy sediment and recent development impacts. We used white feldspar markers to measure floodplain sedimentation rates and steel pins to measure erosion rates on floodplains and banks, respectively. Additional data were collected for/from legacy sediment thickness and characteristics, mill pond impacts, stream gaging station records, topographic surveying, and sediment density, texture, and organic content. Data were analyzed using GIS and various statistical programs. Results are interpreted relative to stream equilibrium affected by both post-colonial bottomland sedimentation (legacy) and modern watershed hardening associated with urbanization. Six floodplain/channel sites, from high to low in the watershed, were selected for intensive study. Bank erosion ranges from 0 to 470 kg/m/y and floodplain sedimentation ranges from 18 to 1369 kg/m/y (m refers to meters of stream reach). Upstream reaches are net erosional, while downstream reaches have a distinctly net depositional flux providing a watershed sediment balance of 2184 kg/m/y trapped within the system. The amounts of both deposition and erosion are large and suggest nonequilibrium channel conditions. Both peak discharge and number of peaks above base have substantially increased since the mid-1960s when urbanization of the watershed began. Deposition patterns are most closely correlated with channel gradient, sinuosity, and channel width/floodplain width for recent and historic periods. The substantial amounts of fine grained sediment deposited on the floodplain over the past two centuries or so do not appear to be closely related to historic mill pond presence or location. The floodplain continues to provide the critical ecosystem service of sediment trapping in the face of multiple human alterations. Trends in sediment deposition/erosion may react rapidly to land use practices within the watershed and offer a valuable barometer of the effects of management actions.

Geomorphology↗
USGS2022

Discovery and potential ramifications of reduced iron-bearing nanoparticles — Magnetite, wüstite, and zero-valent iron — In wildland–urban interface fire ashes

The increase in fires at the wildland–urban interface has raised concerns about the potential environmental impact of ash remaining after burning. Here, we examined the concentrations and speciation of iron-bearing nanoparticles in wildland–urban interface ash. Total iron concentrations in ash varied between 4 and 66 mg g −1 . Synchrotron X-ray absorption near-edge structure (XANES) spectroscopy of bulk ash samples was used to quantify the relative abundance of major Fe phases, which were corroborated by transmission electron microscopy measurements. Maghemite (γ-(Fe 3+ ) 2 O 3 ) and magnetite (γ-Fe 2+ (Fe 3+ ) 2 O 4 ) were detected in most ashes and accounted for 0–90 and 0–81% of the spectral weight, respectively. Ferrihydrite (amorphous Fe( III )–hydroxide, (Fe 3+ ) 5 HO 8 ·4H 2 O), goethite (α-Fe 3+ OOH), and hematite (α-Fe 3+ 2 O 3 ) were identified less frequently in ashes than maghemite and magnetite and accounted for 0–65, 0–54, and 0–50% of spectral weight, respectively. Other iron phases identified in ashes include wüstite (Fe 2+ O), zerovalent iron, FeS, FeCl 2 , FeCl 3 , FeSO 4 , Fe 2 (SO 4 ) 3 , and Fe(NO 3 ) 3 . Our findings demonstrate the impact of fires at the wildland–urban interface on iron speciation; that is, fires can convert iron oxides ( e.g. , maghemite, hematite, and goethite) to reduced iron phases such as magnetite, wüstite, and zerovalent iron. Magnetite concentrations ( e.g. , up to 25 mg g −1 ) decreased from black to gray to white ashes. Based on transmission electron microscopy (TEM) analyses, most of the magnetite nanoparticles were less than 500 nm in size, although larger particles were identified. Magnetite nanoparticles have been linked to neurodegenerative diseases as well as climate change. This study provides important information for understanding the potential environmental impacts of fires at the wildland–urban interface, which are currently poorly understood.

Environmental Science Nano↗