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USGS1976

Availability and chemical characteristics of ground water in central La Plata County, Colorado

The central part of La Plata County, Colo., has undergone rapid population growth in recent years. This growth has resulted in an increased demand for information for additional domestic, industrial, and municipal water supplies. A knowledge of the occurrence of ground water will permit a more efficient allocation of the resource. Aquifers in central La Plata County include: alluvium, Animas Formation of Quaternary and Tertiary age, Fruitland Formation, Pictured Cliffs Sandstone, three formations of the Mesa Verde Group, the Mancos Shale, Dakota Sandstone, Morrison Formation of Cretaceous and Jurassic age, and undifferentiated formations. Well yields generally are low, usually less than 25 gallons per minute. However, higher yields, 25 to 50 gallons per minute may be found locally in aquifers in the alluvium and the Animas Formation. The quality of water from the aquifers is dependent on rock type. Most of the water is a calcium bicarbonate type. However, aquifers that are predominantly fine-grained or contain interbeds of shale may contain sodium bicarbonate type water. The dissolution of minerals in the coal beds, which are present in the Mesa Verde Group and the Dakota Sandstone, can contribute high concentrations of iron, sulfate, and chloride to ground water. (Woodard-USGS)

Water-Resources Investigations Report↗

USGS2014

Composition of dust deposited to snow cover in the Wasatch Range (Utah, USA): Controls on radiative properties of snow cover and comparison to some dust-source sediments

Dust layers deposited to snow cover of the Wasatch Range (northern Utah) in 2009 and 2010 provide rare samples to determine the relations between their compositions and radiative properties. These studies are required to comprehend and model how such dust-on-snow (DOS) layers affect rates of snow melt through changes in the albedo of snow surfaces. We evaluated several constituents as potential contributors to the absorption of solar radiation indicated by values of absolute reflectance determined from bi-conical reflectance spectroscopy. Ferric oxide minerals and carbonaceous matter appear to be the primary influences on lowering snow-cover albedo. Techniques of reflectance and Mössbauer spectroscopy as well as rock magnetism provide information about the types, amounts, and grain sizes of ferric oxide minerals. Relatively high amounts of ferric oxide, indicated by hard isothermal remanent magnetization (HIRM), are associated with relatively low average reflectance (<0.25) across the visible wavelengths of the electromagnetic spectrum. Mössbauer spectroscopy indicates roughly equal amounts of hematite and goethite, representing about 35% of the total Fe-bearing phases. Nevertheless, goethite (α-FeOOH) is the dominant ferric oxide found by reflectance spectroscopy and thus appears to be the main iron oxide control on absorption of solar radiation. At least some goethite occurs as nano-phase grain coatings less than about 50 nm thick. Relatively high amounts of organic carbon, indicating as much as about 10% organic matter, are also associated with lower reflectance values. The organic matter, although not fully characterized by type, correlates strongly with metals (e.g., Cu, Pb, As, Cd, Mo, Zn) derived from distal urban and industrial settings, probably including mining and smelting sites. This relation suggests anthropogenic sources for at least some of the carbonaceous matter, such as emissions from transportation and industrial activities. The composition of the DOS samples can be compared with sediments in a likely dust-source setting at the Milford Flat Fire (MFF) area about 225 km southwest of Salt Lake City. The MFF area represents geologically and physiographically similar and widespread dust sources west-southwest of the Wasatch Range and heavily populated Wasatch Front. The DOS layers and MFF sediments are similar in some textural, chemical, and magnetic properties, as well as in the common presence of goethite, hematite, magnetite-bearing basalt fragments, quartz, plagioclase, illite, and kaolinite. Textural and some chemical differences among these deposits can be explained by atmospheric sorting as well as by inputs from other settings, such as salt-crusted playas and contaminant sources.

Utah↗

USGS1981

Water resources inventory of Connecticut Part 7: upper Connecticut River basin

The 508 square miles of the upper Connecticut River basin in north-central Connecticut include the basins of four major tributaries: the Scantic, Park, and Hockanum Rivers, and the Farmington River downstream from Tariffville. Precipitation over this area averaged 44 inches per year during 1931-60. In this period, an additional 3,800 billion gallons of water per year entered the basin in the main stem of the Connecticut River at the Massachusetts state line, about 230 billion gallons per year in the Farmington River at Tariffville, and about 10 billion gallons per year in the Seantic River at the Massachusetts state line. Some water was also imported from outside the basin by water-supply systems. About half the precipitation, 22.2 inches, was lost from the basin by evapotranspiration; the remainder flowed out of the study area in the Connecticut River at Portland. Variations in streamflow at 41 long-term continuous-record gaging stations are summarized in standardized graphs and tables that can be used to estimate streamflow characteristics at other sites. For example, mean-flow and two low-flow characteristics: (1) the 7-day annual minimum flow for 2-year and (2) 10-year recurrence intervals, have been determined for many partial-record stations throughout the basin. Of the 30 principal lakes, ponds, and reservoirs, two have usable storage capacities of more than 1 billion gallons. The maximum safe draft rate (regulated flow) of the largest of these, Shenipsit Lake at Rockville, is 6.5 million gallons per day for the 2-year and 30-year recurrence intervals (median and lowest annual flow). Floods have occurred within each month of the year but in different years. The greatest known flood on the Connecticut River was in March 1936; it had a peak flow of 130,000 cubic feet per second at Hartford. Since then, major floods have been reduced by flood-control measures. The major aquifers underlying the basin are composed of unconsolidated materials (stratified drift and till) and bedrock. Stratified drift overlies till and bedrock in valleys and lowlands in the eastern and western parts and in most of the broad central valley. The stratified drift generally ranges in thickness from 10 feet in small valleys to more than 200 feet in the Connecticut River Valley. Bedrock underlies the entire basin and is composed of (1) interbedded sedimentary and igneous rocks and (2) crystalline rocks. Ground-water sources yield from several million gallons per day from large well fields to 1 gallon per minute from single wells. Yields of 100 gal/min or more are most commonly obtained from screened wells tapping stratified-drift aquifers; amounts can be calculated by use of a series of graphs in conjunction with estimates of aquifer transmissivity and thickness. Eighteen areas underlain by good aquifers are selected as the most favorable locations for large-scale development of ground water. Selection of these areas is based on estimates of aquifer characteristics and the amount of water potentially available from induced infiltration of streamflow at low-flow conditions. Small to moderate water supplies can generally be obtained from any of the aquifers. Wells in bedrock yield at least a few gallons per minute at most sites. The probability of obtaining an adequate yield for domestic supply is greater in sedimentary than in crystalline bedrock and is also greater in stratified-drift overburden than in till. Where unaffected by man's activities, the water is of the calcium magnesium bicarbonate type, is generally low to moderate in dissolved-solids concentration, and ranges from soft to hard. In general, streamflow is less mineralized than ground water, particularly when it consists largely of direct runoff. However, streams become more highly mineralized during low-flow conditions, when most flow consists of more highly mineralized water discharged from aquifers. The median dissolved-solids concentration in water from 25 stream sites was 113 mg/L (milligrams per liter) during high flow, and 148 mg/L during low flow within the study period. Iron and manganese occur naturally in objectionable concentrations in some streams draining swamps and in some waters draining from sedimentary bedrock which contains iron- and manganese-bearing minerals. Man's activities have affected the water quality of streams in much of the area, particularly in the Hockanum and Park River basins. The degradation in quality in these streams is shown by wide and erratic changes in dissolved-solids concentration, excessive amounts of trace elements, a low dissolved-oxygen content, and abnormally high temperatures. Ground water within this area is degraded principally by induced infiltration of surface water that contains chemical wastes, by leachate from wastes stored or disposed of on the ground, and by effluents discharged from septic tanks. The quantity and quality of water are satisfactory for a wide variety of uses, and, with suitable treatment, the water may be used for most purposes. The total amount of water used in 1968 was more than 100 billion gallons. About 80 percent of this was used for industrial purposes, and 90 percent of the industrial water was obtained from surface-water sources. About 85 percent of the population was supplied with water for domestic use by 15 major public and municipal systems and 25 private associations. Analyses of water from the 13 largest systems show generally good quality.

Connecticut↗

USGS2016

Pb-Sr isotopic and geochemical constraints on sources and processes of lead contamination in well waters and soil from former fruit orchards, Pennsylvania, USA: A legacy of anthropogenic activities

Isotopic discrimination can be an effective tool in establishing a direct link between sources of Pb contamination and the presence of anomalously high concentrations of Pb in waters, soils, and organisms. Residential wells supplying water containing up to 1600 ppb Pb to houses built on the former Mohr orchards commercial site, near Allentown, PA, were evaluated to discern anthropogenic from geogenic sources. Pb (n = 144) and Sr (n = 40) isotopic data and REE (n = 29) data were determined for waters from residential wells, test wells (drilled for this study), and surface waters from pond and creeks. Local soils, sediments, bedrock, Zn-Pb mineralization and coal were also analyzed (n = 94), together with locally used Pb-As pesticide (n = 5). Waters from residential and test wells show overlapping values of 206 Pb/ 207 Pb, 208 Pb/ 207 Pb and 87 Sr/ 86 Sr. Larger negative Ce anomalies (Ce/Ce*) distinguish residential wells from test wells. Results show that residential and test well waters, sediments from residential water filters in water tanks, and surface waters display broad linear trends in Pb isotope plots. Pb isotope data for soils, bedrock, and pesticides have contrasting ranges and overlapping trends. Contributions of Pb from soils to residential well waters are limited and implicated primarily in wells having shallow water-bearing zones and carrying high sediment contents. Pb isotope data for residential wells, test wells, and surface waters show substantial overlap with Pb data reflecting anthropogenic actions (e.g., burning fossil fuels, industrial and urban processing activities). Limited contributions of Pb from bedrock, soils, and pesticides are evident. High Pb concentrations in the residential waters are likely related to sediment build up in residential water tanks. Redox reactions, triggered by influx of groundwater via wells into the residential water systems and leading to subtle changes in pH, are implicated in precipitation of Fe oxyhydroxides, oxidative scavenging of Ce(IV), and desorption and release of Pb into the residential water systems. The Pb isotope features in the residences and the region are best interpreted as reflecting a legacy of industrial Pb present in underlying aquifers that currently supply the drinking water wells.

Pennsylvania↗

USGS1986

Water resources inventory of Connecticut Part 9: Farmington River basin

The Farmington River basin covers 435 square miles in north-central Connecticut upstream from Tariffville and downstream of the Massachusetts state line. Most water in the basin is derived from precipitation, which averages 48 inches (366 billion gallons) per year. An additional 67 billion gallons of water per year enters the basin from Massachusetts in the West Branch of the Farmington River, Hubbard River, Valley Brook and some smaller streams. Of the total 433 billion gallons, 174 billion gallons returns to the atmosphere through evaporation and transpiration. 239 billion gallons flows out of the study area in the Farmington River at Tariffville, and 20 billion gallons is diverted for Hartford water supply. Variations in streamflow at 23 continuous-record gaging stations are summarized in standardized graphs and tables that can be used to estimate streamflow characteristics at other sites. For example, mean flow and low-flow characteristics such as the 7-day annual minimum flow for 2-year and 10-year recurrence intervals, have been determined for many partial-record stations from the data for the 23 continuous-record stations. Of the 31 principal lakes, ponds, and reservoirs in the basin, eight have usable storage capacities of more than 1 billion gallons. Two of the largest, Colebrook River Lake and Barkhamsted Reservoir, have more than 30 billion gallons usable storage. Floods have occurred in the area in every month of the year. The greatest known flood on the Farmington River was in August 1955, which had a peak flow of 140,000 cubic feet per second at Collinsville. Since then, three major floodcontrol reservoirs have been constructed to reduce the hazards of high streamflow. The major aquifers underlying the basin are composed of unconsolidated materials (stratified drift and till) and bedrock (sedimentary, igneous, and metamorphic). Stratified drift overlies till and bedrock in valleys and lowlands; it averages about 90 feet in thickness, and is capable of large sustained yields of water to individual wells. Based on hydrologic characteristics and available recharge, sixteen stratified-drift areas are selected as the most favorable for large-scale development. Potential yields can be estimated by several methods. Small water supplies can be obtained from all aquifers. Wells in bedrock yield at least one to two gallons per minute at most sites. The probability of adequate yields for domestic supply is greater from sedimentary than from crystalline bedrock and is also greater from stratified-drift overburden than from till. The quality of water from all sources in the basin is good except where adversely affected by swamp drainage, aquifer composition or human activities. The water is generally low in dissolved-solids concentration and is soft to moderately hard. Surface water is less mineralized than ground water, especially during high-flow conditions when it is primarily direct runoff. Samples of water collected from 20 streams during high flow had 34 mg/L median dissolved-solids concentration and 16 mg/L median hardness. Samples collected from the same sites at low flow had 52 mg/L median dissolved solids and 28 mg/L median hardness. In contrast, water from wells had 112 mg/L median dissolved-solids concentration and 60 mg/L median hardness. Iron and manganese occur in objectionable concentrations ~n a few parts of the basin where streams drain swamps and aquifers are rich in iron- and manganese-bearing minerals. Five percent of streams at high flow, 21 percent at low flow, and 7 percent of ground-water samples contained iron in sufficient concentration to cause stains on plumbing fixtures and laundry. Human activities have modified the quality of water in parts of the basin. The high bacterial content of the Pequabuck River. and the high nitrate and chloride concentrations in some ground-water samples, are evidence of man’s influence. The quantity and quality of water in the basin’s streams and aquifers are satisfactory for a wide variety of uses. and, with suitable treatment, may be used for most purposes. The total amount of water used by 21 principal public supplies within the basin was 29 billion gallons in 1970. About 70 percent of this was used for domestic and commercial purposes, and nearly 30 percent was used by industry. Analyses of water from these systems show good quality.

Connecticut↗

USGS1974

Stratigraphy and nahcolite resources of the saline facies of the Green River Formation, Rio Blanco County, Colorado

Based on a study of 10 drill cores, a sequence of oil shale and associated nahcolite, nearly 2,000 feet thick, in the lacustrine Green River Formation (Eocene) in the Piceance Creek basin, Rio Blanco County, Colo., was divided in ascending order into zones 1 to 13, B-groove, Mahogany zone (with lower, middle, and upper parts), and A-groove at the top. The odd-numbered zones and the Mahogany zone are mappable subsurface units of relatively thick oil shale and are distinguished from the even-numbered zones and A- and B-grooves which are thinner units of oil shale of lower grade. Large amounts of nahcolite found in zones 5 to 12 occur in (1) coarse-grained crystalline aggregates scattered through oil shale, (2) laterally continuous units of fine-grained crystals disseminated in oil shale, (3) brown microcrystalline beds, and (4) white coarse-grained beds that grade laterally into halitic rocks toward basin center. The original .upper limit of the nahcolite and halitic rocks is not yet completely known, but the present top is marked by a dissolution surface. Above this surface the rocks, extending from zones 11 or 12 upward into the Mahogany zone, form a water-saturated 'leached zone,' a geohydrologic unit in which large amounts of water-soluble minerals probably mostly nahcolite, and halite, were removed by ground-water dissolution. Rocks in the leached zone, mostly oil shale, are commonly broken and fractured and contain crystal cavities and solution breccias. Several solution breccias can be traced laterally into unleached beds of nahcolite and halite. Although evidence of salines is found in rocks above A-groove, the original saline facies that includes most of the bedded deposits extends from zone 5 upward into A-groove. Potentially ruinable beds of white nahcolite as much as 12 feet thick are found at depths of 1,560 or more feet below the surface. Some thicker beds of high-grade nahcolite are believed to be too close to the dissolution surface for safe room-and-pillar mining. Probably the most economical method of mining nahcolite would be as a coproduct of a shale-oil industry. Removal of nahcolite prior to retorting increases significantly the grade of oil shale by as much as 1.6 times, Several zones are more than 300 feet thick and average 30 or more weight percent nahcolite. Resources of nahcolite per square mile range as high as 489 million short tons. The total nahcolite resource in the basin is conservatively estimated at 32 billion short tons, which makes it the secondlargest deposit of sodium carbonate known .in the world.

Open-File Report↗

USGS1964

Geology and ground-water resources of Richardson County, Nebraska

Richardson County is in the extreme southeast corner of Nebraska. It has an area of 545 square miles, and in 1960 it had a population of 13,903. The county is in the physiographic region referred to as the Dissected Loess-covered Till Prairies. Major drainage consists of the Big Nemaha River, including its North and South Forks, and Muddy Creek. These streams flow southeastward and empty into the Missouri River, which forms the eastern boundary of the county. The climate of Richardson County is subhumid; the normal annual precipitation is about 35 inches. Agriculture is the chief industry, and corn is the principal crop. Pleistocene glacial drift, loess, and alluvial deposits mantle the bedrock except in the southern and southwestern parts of the county where the bedrock is at the surface. Ground water is obtained from glacial till, fluvioglacial material, terrace deposits, and coarse alluvial deposits, all of Pleistocene age--and some is obtained from bedrock aquifers of Pennsylvanian and Permian age. Adequate supplies of ground water are in many places difficult to locate because the water-bearing sands and gravels of Pleistocene age vary in composition and lack lateral persistence. Perched water tables are common in the upland areas and provide limited amounts of water to many of the shallow wells, Very few wells in bedrock yield adequate supplies, as the permeability of the rock is low and water that is more than a few tens of feet below the bedrock surface is highly mineralized. Recharge is primarily from local precipitation, and water levels in many wells respond rapidly to increased or decreased precipitation. The quality of the ground water is generally satisfactory for most uses, although all the water is hard, and iron and manganese concentrations, in some areas, are relatively high. Ground water is used mainly for domestic and stock purposes.

Water Supply Paper↗

USGS2007

The geology of asbestos in the United States and its practical applications

Recently, naturally occurring asbestos (NOA) has drawn the attention of numerous health and regulatory agencies and citizen groups. NOA can be released airborne by (1) the disturbance of asbestos-bearing bedrocks through human activities or natural weathering, and (2) the mining and milling of some mineral deposits in which asbestos occurs as an accessory mineral(s). Because asbestos forms in specific rock types and geologic conditions, this information can be used to focus on areas with the potential to contain asbestos, rather than devoting effort to areas with minimal NOA potential. All asbestos minerals contain magnesium, silica, and water as essential constituents, and some also contain major iron and/or calcium. Predictably, the geologic environments that host asbestos are enriched in these components. Most asbestos deposits form by metasomatic replacement of magnesium-rich rocks. Asbestos-forming environments typically display shear or evidence for a significant influx of silica-rich hydrothermal fluids. Asbestos-forming processes can be driven by regional metamorphism, contact metamorphism, or magmatic hydrothermal systems. Thus, asbestos deposits of all sizes and styles are typically hosted by magnesium-rich rocks (often also iron-rich) that were altered by a metamorphic or magmatic process. Rock types known to host asbestos include serpentinites, altered ultramafic and some mafic rocks, dolomitic marbles and metamorphosed dolostones, metamorphosed iron formations, and alkalic intrusions and carbonatites. Other rock types appear unlikely to contain asbestos. These geologic insights can be used by the mining industry, regulators, land managers, and others to focus attention on the critical locales most likely to contain asbestos.

Environmental & Engineering Geoscience↗

USGS2017

Gallium

Gallium is a soft, silvery metallic element with an atomic number of 31 and the chemical symbol Ga. Gallium is used in a wide variety of products that have microelectronic components containing either gallium arsenide (GaAs) or gallium nitride (GaN). GaAs is able to change electricity directly into laser light and is used in the manufacture of optoelectronic devices (laser diodes, light-emitting diodes [LEDs], photo detectors, and solar cells), which are important for aerospace and telecommunications applications and industrial and medical equipment. GaAs is also used in the production of highly specialized integrated circuits, semiconductors, and transistors; these are necessary for defense applications and high-performance computers. For example, cell phones with advanced personal computer-like functionality (smartphones) use GaAs-rich semiconductor components. GaN is used principally in the manufacture of LEDs and laser diodes, power electronics, and radio-frequency electronics. Because GaN power transistors operate at higher voltages and with a higher power density than GaAs devices, the uses for advanced GaN-based products are expected to increase in the future. Gallium technologies also have large power-handling capabilities and are used for cable television transmission, commercial wireless infrastructure, power electronics, and satellites. Gallium is also used for such familiar applications as screen backlighting for computer notebooks, flat-screen televisions, and desktop computer monitors. Gallium is dispersed in small amounts in many minerals and rocks where it substitutes for elements of similar size and charge, such as aluminum and zinc. For example, gallium is found in small amounts (about 50 parts per million) in such aluminum-bearing minerals as diaspore-boehmite and gibbsite, which form bauxite deposits, and in the zinc-sulfide mineral sphalerite, which is found in many mineral deposits. At the present time, gallium metal is derived mainly as a byproduct of the processing of bauxite ore for aluminum; lesser amounts of gallium metal are produced from the processing of sphalerite ore from three types of deposits (sediment-hosted, Mississippi Valley-type, and volcanogenic massive sulfide) for zinc. The United States is expected to meet its current and expected future needs for gallium through imports of primary, recycled, and refined gallium, as well as through domestic production of recycled and refined gallium. The U.S. Geological Survey estimates that world resources of gallium in bauxite exceed 1 billion kilograms, and a considerable quantity of gallium could be present in world zinc reserves.

Professional Paper↗

USGS2017

Platinum-group elements

The platinum-group elements (PGEs)—platinum, palladium, rhodium, ruthenium, iridium, and osmium—are metals that have similar physical and chemical properties and tend to occur together in nature. PGEs are indispensable to many industrial applications but are mined in only a few places. The availability and accessibility of PGEs could be disrupted by economic, environmental, political, and social events. The United States net import reliance as a percentage of apparent consumption is about 90 percent. PGEs have many industrial applications. They are used in catalytic converters to reduce carbon monoxide, hydrocarbon, and nitrous oxide emissions in automobile exhaust. The chemical industry requires platinum or platinum-rhodium alloys to manufacture nitric oxide, which is the raw material used to manufacture explosives, fertilizers, and nitric acid. In the petrochemical industry, platinum-supported catalysts are needed to refine crude oil and to produce aromatic compounds and high-octane gasoline. Alloys of PGEs are exceptionally hard and durable, making them the best known coating for industrial crucibles used in the manufacture of chemicals and synthetic materials. PGEs are used by the glass manufacturing industry in the production of fiberglass and flat-panel and liquid crystal displays. In the electronics industry, PGEs are used in computer hard disks, hybridized integrated circuits, and multilayer ceramic capacitors. Aside from their industrial applications, PGEs are used in such other fields as health, consumer goods, and finance. Platinum, for example, is used in medical implants, such as pacemakers, and PGEs are used in cancer-fighting drugs. Platinum alloys are an ideal choice for jewelry because of their white color, strength, and resistance to tarnish. Platinum, palladium, and rhodium in the form of coins and bars are also used as investment commodities, and various financial instruments based on the value of these PGEs are traded on major exchanges. PGEs are among the rarest metals; Earth’s upper crust contains only about 0.0005 part per million (ppm) platinum. Today, the average grade of PGEs in ores that are mined primarily for their PGE concentrations varies from 5 to 15 ppm, although the concentration of PGEs in hand-picked ore specimens may range from tens to hundreds of parts per million. More than 100 different minerals have one of the PGEs as an essential component. PGE minerals occur as native metals. They also occur as compounds with other transition metals (copper, iron, mercury, nickel, and silver), post-transition metals (bismuth, lead, and tin), metalloids (antimony, arsenic, and tellurium), and nonmetals (selenium and sulfur). From 1900 to 2011, approximately 14,200 metric tons of PGEs was produced, and roughly 95 percent of that production (13,500 metric tons) took place between 1960 and 2011. The breakdown of production by country shows that, since 1900, about 90 percent of the production came from South Africa and Russia. The secondary supply of platinum, palladium, and rhodium is obtained through the recycling of catalytic converters from end-of-life vehicles, jewelry, and electronic equipment. Recycled platinum, palladium, and rhodium provide a significant proportion of the world’s total supply; these secondary sources are sufficient to close the gap between world mine production and consumption. Exploration and mining companies report resources of about 104,000 metric tons of PGEs (including minor amounts of gold) in mineral deposits around the world that could be developed. For PGEs, almost all the reported production and identified resources are associated with deposits in three geologic features—the Bushveld Complex, which is a layered mafic-to-ultramafic intrusion in South Africa; the Great Dyke, which is a layered mafic-to-ultramafic intrusion in Zimbabwe; and sill-like intrusions associated with flood basalts in the Noril’sk-Talnakh area of Russia. The metallic forms of PGEs are generally considered to be inert. PGEs pose a risk to human health only in cases where individuals are occupationally exposed to synthetic PGE compounds, especially workers in precious-metal refineries. In the natural environment, background PGE concentrations are low in water, sediment, soil, and plants. Anthropogenic sources of PGEs in the environment include catalytic converters used in modern automobiles, platinum-based chemotherapy drugs, and smelter emissions. The abundance of sulfide minerals defines the environmental and geologic characteristics of PGE-enriched magmatic sulfide deposits; those deposits with the highest amount of sulfide minerals could have the highest environmental impact. Acid rock drainage from reef-type and contact-type deposits is unlikely because the ores and their host rocks contain low proportions of sulfide minerals. For some conduit-type orebodies with massive ores, mineral-processing techniques separate and produce concentrates of copper-, iron-, and nickel-bearing sulfide minerals; those with copper and nickel are processed to extract metal, but the iron-sulfide minerals, mainly pyrrhotite, are discarded as waste. This results in waste material with a high acid-generating potential. The most significant primary source of PGEs in the United States is a deposit in the Stillwater Complex, which is a layered igneous intrusion in Montana. Approximately 305 metric tons of platinum and palladium have been mined from the Stillwater Complex deposit since 1986. Exploration and development drilling indicate that another 2,200 metric tons are present. Mining has progressed to depths of 1,800 meters below the surface, but the bottom of the ore deposit has not been reached; geologic estimates suggest that another 1,000 to 6,200 metric tons of PGEs could be present at depth. In the future, PGEs may be mined from deposits found near the base of the Duluth Complex, which is a group of igneous intrusions in Minnesota.

Professional Paper↗

USGS1979

Lithologic log, lithium content, and mineralogy of sediments penetrated in test boring drilled in Eureka Valley, Inyo County, California

A test boring was drilled in a playa in Eureka Valley, Calif., by the U.S. Geological Survey in the spring of 1978. Work was done under the terms of a cooperative agreement between the U.S. Geological Survey and the U.S. Bureau of Land Management to evaluate the leasable mineral potential of various playas in the California Desert Planning area, as described in the environmental analysis (prepared by the U.S. Geological Survey, 1978). The purpose of this report is to describe the occurrence and distribution of lithium in the basin sediments as part of a program to identify additional domestic resources of nonpegmatite lithium (Vine, 1978). Interest in this playa stems from the fact that Eureka Valley is located in a region where other lithium resources have been identified. Lithium is recovered from subsurface brines at Clayton Valley, Nev., to the north and at Searles Lake, Calif., to the south. Eureka Valley is a closed topographic basin that has an arid climate, it thus provides suitable conditions for the entrapment of a brine and subsequent concentration of lithium by evaporation. Development of new energy related uses for lithium in batteries for electric vehicle propulsion and for off-peak power storage by the utility industry (Chilenskas and others, 1977) may he aided by identification of a large domestic resource of lithium.

California↗

USGS1958

Ground-water resources in the tri-state region adjacent to the Lower Delaware River

The purpose of this report is to appraise and evaluate the groundwater resources of a tri-state region adjacent to the lower Delaware River that is centered around Philadelphia, Pa., and Camden, N. J., and includes Wilmington, Del., and Trenton, N.J. Specifically, the region includes New Castle County, Del.; Burlington, Camden, Gloucester, Mercer, and Salem Counties in New Jersey; and Bucks, Chester, Delaware, Montgomery, and Philadelphia Counties in Pennsylvania. The peculiar advantages of ground water, such as its availability in many places without the necessity for expensive pipelines and its relatively uniform temperature and quality, make it an especially valuable resource in an industrial area. Large, readily available supplies of good, fresh water have contributed substantially to the recent rapid industrial growth of the lower Delaware River basin and will be vital to its continued prosperity. The major part of these supplies is drawn from the streams passing through the region, but very large quantities of ground water also are used. The region is divided almost equally by the Fall Line, which extends in a southwesterly direction along the general course of the Delaware River from Trenton, N.J., to Wilmington, Del., and beyond. Northwest of the Fall Line is a region of consolidated rocks in which ground water occurs mainly in cracks, crevices, and openings created or enlarged by weathering. The capacity of the various geologic formations to yield water depends largely upon the degree to which they have been fractured and weathered. The yield of individual wells in this part of the region is generally small to moderate and not readily predictable. Ground water in this part of the region is generally low in dissolved minerals and suitable for many uses without treatment. Southeast of the Fall Line lie the unconsolidated rocks of the Coastal Plain. Ground water occurs in these rocks largely in the pore spaces between the individual mineral grains. The major formations and the principal aquifers are rather uniform in their water-bearing characteristics over large areas. The yield of individual wells is moderate to very large and may be predicted with a reasonable degree of assurance. Sufficient quantities of ground water are available in most places for all ordinary purposes. The chemical quality of the ground water from the Coastal Plain aquifers is generally acceptable for most uses, but objectionable quantities of iron or other minerals are found in some places, and some waters have a low pH and are corrosive. More than 40 distinct geologic formations occur in the region. They range in age from Precambrian to Recent. Nearly all will yield some water to wells. However, only about a dozen yield water freely enough to be considered major aquifers. Of these, the sands of the Raritan and Magothy formations have been developed most intensively, and the Cohansey sand appears to have the greatest capacity for additional development. The present withdrawal of ground water in the region is estimated to average more than 200 mgd, of which more than half is drawn from the aquifers in the Raritan and Magothy formations. It is estimated that additional supplies of ground water, aggregating more than 1 billion gallons a day, can be developed within the region. Furthermore, substantial additional quantities can be developed outside the region for use within it if the need should ever arise. Induced recharge from the Delaware River supplies a substantial portion of the total water drawn from the Raritan and Magothy formations. In some areas, the quality of the water from these aquifers is approaching that of the river. Increased withdrawals of water from wells along the river will tend to increase induced recharge. Thus, the maintenance of a good quality of water in the river, which is desirable for many other reasons, is imperative if the quality of the ground-water supply is to be maintained. The proposed deepening of the Delaware River channel from Philadelphia to Trenton will greatly increase the opportunity for the interchange of water between the river and the adjacent aquifers. Whether this will be beneficial or detrimental to the ground-water supplies will depend upon the quality of the water in that reach of the river. If an acceptable quality of river water is maintained, the groundwater resources of the region will be augmented. If salt water from the ocean or excessive contamination from other sources should render the river water undesirable as a source of recharge, actual and potential ground-water supplies aggregating about 250 mgd would be endangered. The danger of salt-water encroachment into the aquifers normally yielding fresh water may limit the optimum yield of some of the most important aquifers in the region. Encroachment may come either from salt water in the surface-water bodies of the region or from parts of the aquifers, normally containing salt water. The protection of ground-water supplies against salt-water encroachment can be maintained only by constant vigilance, careful distribution of the pumping from the aquifers, regular sampling of outpost wells in exposed localities, and adjustment of rates of pumping in the light of changing conditions. The maximum beneficial utilization of the ground-water resources cannot be accomplished in haphazard fashion. It must be planned and controlled on the basis of sound, current information about the hydrology of the various aquifers. Continued and, in some areas, intensified investigations of the ground-water resources of the region should form the basis for such planning and control.

New Jersey, Pennsylvania, Delaware↗

USGS1951

Diamond-drill exploration of the Rousseau talc prospect, Cambridge, Vermont, and the Barnes Hill prospect, Waterbury, Vermont

The Geological Survey carried out a program of diamond-drilling at two localities in Vermont during the period July-September 1950. The deposits chosen for drilling were two of the more promising talc deposits associated with ultramafic rocks of several that had been mapped earlier by the Geological Survey, but could not be evaluated accurately because critical data were lacking that could be obtained only by sub-surface exploration. The Rousseau talc prospect is in Cambridge township, Lamoille County, Vermont. Surface rights are owned by L. and N. N. Porter; mineral rights are owned by Eastern Magnesia Talc Co. Three drill holes encountered no talc; the other five penetrated from 2 to 110 feet of talc ore. The deposit lies on the west limb of the Green Mountain anticlinorium. The country rock consists of quartz-chlorite-sericite schist and chlorite-albite schist. The schistosity strikes slightly west of north and dips 20° - 40° to the west. The talc deposit is roughly lenticular, and although generally concordant in detail with the schistosity of the country rock, is slightly cross-cutting in overall relationship. The entire deposit is composed of Tit (talc-carbonate rock) and steatite, out is presumably derived from ultramafic igneous rooks which were first serpentinized. The dimensions of the lens are about 700 feet by 500 feet by 130 feet. The talc is of good quality and is suitable, either as a mine run product or as a flotation concentrate, for most industrial uses other than industrial steatite. No pencil stock was encountered. The Barnes hill talc prospect is in Waterbury township, Washington County, Vermont. Surface rights are divided among Donald P. and Glenola Brown, John Barnes, and Eastern Magnesia Talc Co. One drill hole at Barnes hill was barren. The other six penetrated about 20 to 140 feet of talc ore. The deposit lies on the east limb of the Green Mountain anticlinorium. The country rock outside of the ultramafic rock body consists of quartz-chlorite-sericite schist, chlorite-albite schist; and chlorite amphibolite, which strike generally about N, 20° E. and dip steeply to the east. The ultramafic body is elliptical in plan, about 1,600 feet long and 360 feet wide. The vertical dimension is unknown. The original ultramafic rock has been almost completely serpentinized and is extensively altered to grit and steatite. The talc ore is somewhat irregularly distributed throughout the ultramafic body, but it is possible to delineate with considerable confidence portions of the body that consist predominantly of ore. The largest ore bodies are in the eastern and northern parts of the ultramafic body. The ore contains more or less admixed serpentine, and so is only of intermediate to fairly good color (whiteness). It is suitable for many industrial uses in which purity and high whiteness are not necessary. No pencil stock was seen.

Vermont↗

USGS2014

Geologic map of the Weka Dur gold deposit, Badakhshan Province, Afghanistan, modified from the 1967 original map compilation of M.P. Guguev and others

This geologic map of the Weka Dur gold deposit located in Badakhshan Province, Afghanistan, is a redrafted and modified version of the Geological map of the Weka Dur area, scale 1:10,000 and Geological map of the Weka Dur deposit, scale 1:2,000 from Guguev and others (1967) (Soviet report no. R1584). That unpublished Soviet report contains the original maps and cross sections, which were prepared in cooperation with the Ministry of Mines and Industries of the Republic of Afghanistan in 1967 under contract no. 1378 (Technoexport, USSR). This USGS publication not only reproduces the geology of the original Soviet maps and cross sections, but also illustrates a mapped adit with reported gold concentrations from sampling within the adit, and shows the location of Soviet trenches along the Weka Dur gold deposit. The Weka Dur gold deposit lies in a cluster of other gold deposits in Badakhshan Province (Ragh district), such as the Kadar, Nesheb Dur, and Rishaw gold occurrences. These gold occurrences lie within a zone of late Hercynian folding and are most likely related to fluids that originated from orogenic processes. The Weka Dur deposit is the largest recorded gold occurrence in Afghanistan and is hosted in Proterozoic mica schist and amphibolite that is intruded by diabase dikes and other intrusive rocks. The tabular orebody is 350 meters (m) long and 2 m wide and can be traced downdip for 110 m. Mineralization consists of ochreous, brecciated schists containing high gold concentrations along gently and steeply dipping fissures. The brecciated rocks grade to 46.7 grams per ton (g/t) silver and contain arsenopyrite, galena, chalcopyrite, and scheelite. Trenches and adits were constructed, mapped, and sampled during the 1960s. Calculated resources are 958.3 kilograms of gold, averaging 4.1 g/t gold.

Badakhshan Province↗

USGS2010

Temperature data from wells in Long Valley Caldera, California

The 30-by-20-km Long Valley Caldera (LVC) in eastern California (fig.1) formed at 0.76 Ma in a cataclysmic eruption that resulted in the deposition of 600 km? of Bishop Tuff outside the caldera rim (Bailey, 1989). By approximately 0.6 Ma, uplift of the central part of the caldera floor and eruption of rhyolitic lava formed the resurgent dome. The most recent eruptive activity in the area occurred approximately 600 yr ago along the Mono-Inyo craters volcanic chain (Bailey, 2004; Hildreth, 2004). LVC hosts an active hydrothermal system that includes hot springs, fumaroles, mineral deposits, and an active geothermal well field and power plant at Casa Diablo along the southwestern boundary of the resurgent dome (Sorey and Lewis, 1976; Sorey and others, 1978; Sorey and others, 1991). Electric power generation began in 1985 with about 10 Mwe net capacity and was expanded to about 40 Mwe (net) in 1991 (Campbell, 2000; Suemnicht and others, 2007). Plans for further expansion are focused mainly on targets in the caldera?s western moat (Sass and Priest, 2002) where the most recent volcanic activity has occurred (Hildreth, 2004). LVC has been the site of extensive research on geothermal resources and volcanic hazards (Bailey and others, 1976; Muffler and Williams, 1976; Miller and others, 1982; Hill and others 2002). The first geothermal exploratory drilling was done in the shallow (< 200 m deep) hydrothermal system at Casa Diablo in the 1960?s (McNitt, 1963). Many more boreholes were drilled throughout the caldera in the 1970?s and 1980?s by private industry for geothermal exploration and by the U.S. Geological Survey (USGS) and Sandia National Laboratory for volcanic and geothermal research and exploration. Temperature logs were obtained in some of these wells during or immediately following drilling, before thermal equilibration was complete. Most of the temperature logs, however, were obtained weeks, months, or years after well completion and are representative of dynamic thermal equilibrium. The maximum reservoir temperature for LVC is estimated to be about 220?C on the basis of chemical geothermometers (Fournier and Truesdell, 1973) using analytical results from water samples collected from a large number of wells and springs across the caldera and around its periphery (Lewis, 1974; Mariner and Wiley, 1976; Farrar and others, 1985, 1987, 1989, White and Peterson, 1991). The deepest well in LVC (~3 km) is the Long Valley Exploratory Well (LVEW) drilled in the 1990?s with funding from the U.S. Department of Energy to investigate the potential for near-magmatic-temperature energy extraction and the occurrence of magma under the central part of the resurgent dome (Finger and Eichelberger, 1990; Finger and Jacobsen, 1999; Sackett and others, 1999). However, temperatures beneath the resurgent dome have proved disappointingly low and in LVEW reach a maximum of only 102 degrees C in a long isothermal section (2,100 to 3,000 m) in Mesozoic basement rocks (Farrar and others, 2003). Temperature data from well logs and geothermometry reveal that the highest temperatures in LVC are beneath the western moat. The hottest temperatures measured in LVC exceed 200 degrees C in two wells (44-16 and RDO-8) located in the western moat. Well 44-16 was drilled through the entire thickness of post-caldera volcanic fill and bottomed in Mesozoic basement. Well RDO-8 was drilled through post-caldera volcanic rocks and 305 m into the Bishop Tuff (Wollenberg and others, 1986). Temperatures in the hydrothermal system decrease toward the east by processes of conduction and dilution from cold groundwater recharge that occurs mostly around the caldera margin and beneath the resurgent dome. Reservoir temperatures at Casa Diablo (fig.1) are about 170?C (for example, MBP-3 and Mammoth-1), decreasing to about 100 degrees C in wells near Hot Creek Gorge (for example, MW-4 and CH-10B), and are generally less than 50?C in thermal springs near Lake

Data Series↗

USGS2017

Graphite

Graphite is a form of pure carbon that normally occurs as black crystal flakes and masses. It has important properties, such as chemical inertness, thermal stability, high electrical conductivity, and lubricity (slipperiness) that make it suitable for many industrial applications, including electronics, lubricants, metallurgy, and steelmaking. For some of these uses, no suitable substitutes are available. Steelmaking and refractory applications in metallurgy use the largest amount of produced graphite; however, emerging technology uses in large-scale fuel cell, battery, and lightweight high-strength composite applications could substantially increase world demand for graphite. Graphite ores are classified as “amorphous” (microcrystalline), and “crystalline” (“flake” or “lump or chip”) based on the ore’s crystallinity, grain-size, and morphology. All graphite deposits mined today formed from metamorphism of carbonaceous sedimentary rocks, and the ore type is determined by the geologic setting. Thermally metamorphosed coal is the usual source of amorphous graphite. Disseminated crystalline flake graphite is mined from carbonaceous metamorphic rocks, and lump or chip graphite is mined from veins in high-grade metamorphic regions. Because graphite is chemically inert and nontoxic, the main environmental concerns associated with graphite mining are inhalation of fine-grained dusts, including silicate and sulfide mineral particles, and hydrocarbon vapors produced during the mining and processing of ore. Synthetic graphite is manufactured from hydrocarbon sources using high-temperature heat treatment, and it is more expensive to produce than natural graphite. Production of natural graphite is dominated by China, India, and Brazil, which export graphite worldwide. China provides approximately 67 percent of worldwide output of natural graphite, and, as the dominant exporter, has the ability to set world prices. China has significant graphite reserves, and China’s graphite production is expected to increase, although rising labor costs and some mine production problems are developing. China is expected to continue to be the dominant exporter for the near future. Mexico and Canada export graphite mainly to the United States, which has not had domestic production of natural graphite since the 1950s. Most graphite deposits in the United States are too small, low-grade, or remote to be of commercial value in the near future, and the likelihood of discovering larger, higher-grade, or favorably located domestic deposits is unlikely. The United States is a major producer of synthetic graphite.

Professional Paper↗

USGS1997

Hydrogeology and water quality of the West Valley Creek Basin, Chester County, Pennsylvania

The West Valley Creek Basin drains 20.9 square miles in the Piedmont Physiographic Province of southeastern Pennsylvania and is partly underlain by carbonate rocks that are highly productive aquifers. The basin is undergoing rapid urbanization that includes changes in land use and increases in demand for public water supply and wastewater disposal. Ground water is the sole source of supply in the basin. West Valley Creek flows southwest in a 1.5-mile-wide valley that is underlain by folded and faulted carbonate rocks and trends east-northeast, parallel to regional geologic structures. The valley is flanked by hills underlain by quartzite and gneiss to the north and by phyllite and schist to the south. Surface water and ground water flow from the hills toward the center of the valley. Ground water in the valley flows west-southwest parallel to the course of the stream. Seepage investigations identified losing reaches in the headwaters area where streams are underlain by carbonate rocks and gaining reaches downstream. Tributaries contribute about 75 percent of streamflow. The ground-water and surface-water divides do not coincide in the carbonate valley. The ground-water divide is about 0.5 miles west of the surface-water divide at the eastern edge of the carbonate valley. Underflow to the east is about 1.1 inches per year. Quarry dewatering operations at the western edge of the valley may act partly as an artificial basin boundary, preventing underflow to the west. Water budgets for 1990, a year of normal precipitation (45.8 inches), and 1991, a year of sub-normal precipitation (41.5 inches), were calculated. Streamflow was 14.61 inches in 1990 and 12.08 inches in 1991. Evapotranspiration was estimated to range from 50 to 60 percent of precipitation. Base flow was about 62 percent of streamflow in both years. Exportation by sewer systems was about 3 inches from the basin and, at times, equaled base flow during the dry autumn of 1991. Recharge was estimated to be 18.5 inches in 1990 and 13.7 inches in 1991. Ground-water quality in the basin reflects differences in lithology and has been affected by human activities. Ground water in the carbonate rocks is naturally hard, has a near neutral pH, and contains more dissolved solids and less dissolved iron, manganese, and radon-222 than ground water in the noncarbonate rocks, which is soft, with moderately acidic to acidic pH. Regional contamination by chloride and nitrate and local contamination by organic compounds and metals was detected. Natural background concentrations are estimated to be about 1 milligram per liter for nitrate as nitrogen and less than 3 milligrams per liter for chloride. Ground water in unsewered areas and agricultural areas of the basin has median concentrations of nitrate that are greater than those in ground water from other areas; septic system effluent and fertilizer are probable sources of elevated nitrate. Water samples from wells in urbanized areas contain greater concentrations of chloride than samples from wells in residential areas; road salt is the probable source of elevated chloride. Organic solvents, especially trichloroethylene, were detected in 30 percent of the wells sampled in the urbanized carbonate valley. Most of the organic solvents and some of the metals in ground water were detected near old industrial sites. Base-flow stream quality of West Valley Creek was determined at 15 sites from monthly sampling for 1 year. Differences in stream quality reflect differences in lithology, land use, and point sources in tributary subbasins and mainstem reaches. The chemical composition of base flow in the mainstem is dominated by ground-water discharge from carbonate rocks. Elevated concentrations of nitrate (greater than 3 milligrams per liter as nitrogen) in base flow were measured in a tributary draining agricultural land and in a tributary draining an unsewered residential area. Elevated concentrations of phosphate (greater than 0.5 milligrams per liter as phosphorus) were measured in a stream that receives treated sewage effluent. Discharge of water containing elevated sulfate (about 250 milligrams per liter) from quarry dewatering operations contributes to die increase in sulfate concentration (of 10 to 40 milligrams per liter) in base flow downstream from the quarry. The chloride load at all stream sites is greater than the load contributed by precipitation and mineral weathering to the basin, indicating anthropogenic sources of chloride throughout the basin. The diversity index of the benthic invertebrate community has increased since 1973 at the longterm biological monitoring site on West Valley Creek, indicating an improvement in stream quality. The improvement probably is related to controls on discharges and banning of pesticides, such as DOT, in the 1970's. Concentrations of dissolved constituents, except for chloride, determined for base flow in the autumn do not appear to have changed since 1971. Application of the seasonal Kendall test for trend indicates that concentrations of chloride in base flow have increased since 1971; this increase may be related to the increase in urbanization in the basin. The benthic community structure at the West Valley Creek site in 1991 indicates slight nutrient enrichment. Lithium was detected in ground water and surface water downgradient from two lithiumprocessing facilities. Until 1991, lithium was discharged into a losing reach of West Valley Creek, thus introducing lithium into the ground-water system. The potential for cross-contamination between the ground-water and surface-water systems is great, as demonstrated by the detection of lithium in ground water and surface water downstream and downgradient from the two lithium-processing facilities. The lithium that was discharged into the creek acts as a conservative tracer in gaining reaches of West Valley Creek, maintaining a mass balance and characteristic isotopic signature. Lithium-7/lithium-6 ratios were greater in streams that are affected by sewage and by lithium-processing discharges and in ground water downgradient from the lithium-processing facilities than natural background lithium isotopic ratios.

Pennsylvania↗

USGS1993

International strategic minerals inventory summary report; rare-earth oxides

Bastnaesite, monazite, and xenotime are currently the most important rare-earth minerals. Bastnaesite occurs as a primary mineral in carbonatites. Monazite and xenotime also can be found in primary deposits but are recovered principally from heavy-mineral placers that are mined for titanium or tin. Each of these minerals has a different composition of the 15 rare-earth elements. World resources of economically exploitable rare-earth oxides (REO) are estimated at 93.4 million metric tons in place, composed of 93 percent in primary deposits and 7 percent in placers. The average mineral composition is 83 percent bastnaesite, 13 percent monazite, and 4 percent of 10 other minerals. Annual global production is about 67,000 metric tons of which 41 percent is from placers and 59 percent is from primary deposits; mining methods consist of open pits (94 percent) and dredging (6 percent). This output could be doubled if the operations that do not currently recover rare earths would do so. Resources are more than sufficient to meet the demand for the predictable future. About 52 percent of the world's REO resources are located in China. Ranking of other countries is as follows: Namibia (22 percent), the United States (15 percent), Australia (6 percent), and India (3 percent); the remainder is in several other countries. Conversely, 38 percent of the production is in China, 33 percent in the United States, 12 percent in Australia, and 5 percent each in Malaysia and India. Several other countries, including Brazil, Canada, South Africa, Sri Lanka, and Thailand, make up the remainder. Markets for rare earths are mainly in the metallurgical, magnet, ceramic, electronic, chemical, and optical industries. Rare earths improve the physical and rolling properties of iron and steel and add corrosion resistance and strength to structural members at high temperatures. Samarium and neodymium are used in lightweight, powerful magnets for electric motors. Cerium and yttrium increase the density and heat resistance of sintered ceramics. Yttrium and gadolinium contribute to the efficiency of electronic switches and sensors. Cerium improves the effectiveness of catalysts in the petroleum and automotive industries. Cerium oxides speed glass melting and are used to polish glass by chemical, rather than mechanical, means. Cerium, europium, terbium, and yttrium, as phosphoric compounds, promote the vivid colors of television screens. Consumption of rare earths is expected to grow by about 2.6 percent per year.

Circular↗