Aerial observations of suspended sediment plumes in San Francisco Bay and the adjacent Pacific Ocean
No abstract avaiable
Journal of Research of the U.S. Geological Survey↗
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Technique for concentrating nannoplankton from the Tertiary rocks of the California Coast and Peninsular Ranges
No abstract available.
Journal of Research of the U.S. Geological Survey↗
Seismic anomalies expand Alaska’s Umiat Anticline potential
Recent seismic advancements, including AVO analysis, have redefined Alaska's Umiat field potential, revealing deeper reservoirs and increasing estimated oil in place.
Alaska↗
Relating systematic molecular and textural properties of graptolite pyrolyzed via gold tube hydrous pyrolysis: Implications for thermal proxies in lower Paleozoic marine shales
A series of gold tube pyrolysis experiments (72 h, 300–550 °C, 50 MPa) conducted on a graptolite-rich lower Paleozoic marine shale generated pyrolysis residues for a comprehensive evaluation of the molecular and structural variability of three types of graptolite periderm. Organic petrology, Raman spectroscopy, and field emission scanning electron microscopy (FE-SEM) with energy dispersive spectroscopy (EDS) were combined to evaluate the thermal evolution process. The three types of graptolite periderm, namely granular, non-granular, and nodular graptolite, were analyzed by Raman spectroscopy wherein point measurements were obtained after the maceral was identified and the location verified by organic petrology. Distinct thermal evolution pathways among non-granular, granular, and nodular graptolite periderms were recorded. The evolution patterns of the Raman parameters, particularly D1 and G bands, highlight the differences in geochemical composition of the graptolite periderm types and the alteration of molecular structure with increasing thermal maturity. Raman parameters D1 (position of the D1 peak), G-FWHM (full width at half maximum of the G peak), and ratios D1-FWHM/G-FWHM (full width at half maximum of the D1 peak ratioed to G-FWHM) and A D1 /A G (ratio of D1 and G peak intensities) showed effectiveness in assessing thermal maturity. Bireflectance with increasing gold tube pyrolysis temperature followed a hierarchy: non-granular > granular > nodular, reflecting different molecular alignment intensities. Qualitative FE-SEM evaluation showed that fine-grained mineral inclusions (primarily Fe-sulfide as determined via EDS) were associated with the graptolite populations, with granular graptolite containing greater amounts of coarser-grained (e.g., ∼300–1400 nm) mineral inclusions relative to non-granular and nodular graptolite, which contain finer-grained (e.g., ∼100–200 nm) inclusions difficult to resolve with optical microscopy. These findings are investigated to highlight the mechanisms that drive organic matter evolution within graptolite during thermal maturation, as well as to explore some of the limitations of using spectroscopic parameters as thermal maturity proxies.
International Journal of Coal Geology↗
Sedimentological and geochemical characterization of lacustrine deposits of the Babouri-Figuil basin, northern Cameroon: Implications for source rocks distribution and petroleum exploration
The West and Central African Rift System (WCARS) refers to the series of Cretaceous rift basins where commercial hydrocarbon accumulations have been discovered. Some of the WCARS frontier basins are currently being investigated to increase our understanding of these basins in light of new commercial discoveries. The present study was performed in the Babouri-Figuil Basin (BFB), which is genetically related to the WCARS and constitutes an area of interest in terms of petroleum prospecting, where the distribution of petroleum source rocks and potential targets for petroleum exploration across the entire basin is poorly understood. For the current study, an integrated facies analysis along with organic and inorganic geochemical techniques were applied to the basin's Cretaceous deposits with the aim of reconstructing the paleodepositional environment, assessing factors that triggered the input of organic matter, and providing a spatial overview of the organic matter accumulation in the basin based on outcrop samples. An alluvial fan-lacustrine-braided river system is inferred from the facies analysis of the stratigraphic sequence consisting of conglomerate, sandstone, siltstone, limestone, marlstone, and claystone. Bulk analysis of organic matter reveals that black shale and massive claystone are the main prospective petroleum source rocks in the basin. Inorganic geochemical analyses reveal the influence of anoxic conditions, moderate to high primary productivity, and low terrigenous inputs in organic matter enrichment. The formations rich in organic matter are predominantly concentrated in the western and eastern parts of the basin which may represent areas with depressions, characterized by high accommodation space. In terms of the regional context of the WCARS rift basins, typical hydrocarbon exploration in the BFB may target basal-conglomerate, sandstone beds situated directly above or/and interbedded with the Lower Cretaceous source rocks, and the Upper Cretaceous sandstone beds. Basement rocks (granite, granodiorite, and gneisses) and oil shale deposits may represent potential unconventional hydrocarbon exploration. The current integrated study provides an insight that should guide future hydrocarbon exploration campaigns in the basin.
Babouri-Figuil basin↗
Indications of preferential groundwater seepage feeding northern peatland pools
Groundwater seepage from underlying permeable glacial sedimentary structures, such as eskers, has been hypothesized to directly feed pools in northern peat bogs. These hypotheses directly contradict classical peat bog models for ombrogenous systems, wherein meteoric water is the sole water input to these systems. Variations in the underlying mineral sediment in contact with the peat imply that unrecognized hydrogeologic connectivity may exist with pools in northern peat bogs, particularly where high permeability materials are in contact with the peat. Seepage dynamics originating from these structural variations were investigated using a suite of thermal and hydrogeophysical methods deployed around pools in a peat bog of northeastern Maine, USA. Thermal characterization methods mapped anomalies that were confirmed as matrix seepage or preferential flow pathways (PFPs). Geochemical methods were employed at identified thermal anomalies to confirm upwelling of solute-rich groundwater. Conduits around pools were associated with surficial terminations of suspected peat pipes, based on the inference of pathways extending down into the peat, that focus flow through PFPs in the peat matrix. Discharge also occurred through the peat matrix adjacent to suspected pipe structures and matrix seepage rates were quantified using analysis of diurnal temperature signals recorded at multiple depths. Seepage rates, with a maximum of nearly 0.4 m/d, were measured at localized points around pools. Periods of synchronized temperatures paired with highly muted diurnal temperature signals, recorded in diurnal temperature with depth data, were interpreted qualitatively as activation of strong upward discharge rates through suspected peat pipes. These time periods correlated strongly with local precipitation events around the peatland. Ground-penetrating radar surveys revealed discontinuities in the low permeability glacio-marine clay at the mineral sediment-peat interface, interpreted to be regional glacial esker deposits, which were located beneath and around pools. Heat tracing, specific conductance contrasts, seepage rates, and trace metal concentrations all imply groundwater seepage originating from underlying permeable glacial esker deposits and directly sourcing pools. Preferential groundwater inputs into northern peat bogs may play a key role in developing and maintaining pool systems, with enhanced solute transport impacting peatland ecology, water resources, and carbon cycling.
Maine↗
Magmatic source of the opening phase of Kīlauea’s 2018 Lower East Rift Zone eruption
The 2018 eruption of Kīlauea volcano in its Lower East Rift Zone began with the discharge of evolved high-Ti basalt as weak lava fountains and short, slow-moving lava flows. The lavas were quickly geochemically recognized as being derived from magmas stored within the rift zone and remobilized by a new intrusion, a sequence that is common at Kīlauea. This initial phase of the 2018 eruption, referred to as phase 1a, lasted for 6 days and was followed by extrusion of mixed magma after a 3-day pause. Even though remobilization of older rift zone magmas is common within Kīlauea’s rift zones, it is difficult to determine which past intrusion(s) may have initially emplaced those stored magmas. This difficulty stems from the tendency for Kīlauea magmas to follow very similar differentiation paths without significant variations in major, minor, or even trace element chemistry. We investigate possible magma sources for the lavas erupted during phase 1a of the 2018 eruption using whole-rock, mineral, and glass major and trace element compositions from historical East Rift Zone eruptions with adjacent fissures. We consider two primary hypotheses for the phase 1a source: magmas associated with the 1955 Lower East Rift Zone eruption or the nine eruptions in the Middle and Upper East Rift Zone during the 1960s. Our results suggest that magma associated with the earliest phases of Kīlauea’s 1955 eruption was the most likely source of the 2018 phase 1a remobilized magma. We determine volatile saturation pressures from melt inclusion chemistry and find similar storage depths for the 2018 phase 1a and early 1955 magmas. The phase 1a and early 1955 lavas are nearly indistinguishable in all of the compositional criteria considered, implying that the leftover 1955 magma body barely cooled and differentiated in the 63 years between eruptions (cooling rates of ~0.1 °C/year). This study sheds light on the potential for protracted storage of eruptible magmas in rift zones at Kīlauea, and highlights some of the challenges and solutions to identifying genetic relationships between magmas at Kīlauea.
Hawaii↗
Validating antler- and movement-based estimates of caribou reproduction using video camera collars
Wildlife agencies invest substantial resources in monitoring ungulate reproductive rates given ongoing concerns about population trends and their implications for management. For barren-ground caribou ( Rangifer tarandus ) in the North American Arctic, data on parturition and neonate survival have traditionally been collected using visual observations of antler retention and calf presence from small, fixed-wing aircraft. However, these surveys are weather-dependent, expensive, and dangerous, motivating the development of movement-based approaches that infer reproductive events from global positioning system (GPS) location data. We had the unique opportunity to use video camera collars to validate both antler- and movement-based methods for estimating reproduction in barren-ground caribou, using data from the Porcupine (2018–2023) and Western Arctic (2021, 2023) herds in Alaska, USA, and Yukon, Canada. For the movement-based approaches, we assessed individual-based and population-based methods, which both inferred parturition following a sharp decline in movement and inferred calf loss following a sharp increase in movement. We investigated these approaches using rarified 1-, 2-, 4-, and 8-hour fix intervals. Based on video collar observations, we found that antler retention at the onset of the calving period was highly accurate for predicting parturition (96% accuracy) but became unreliable as calving progressed, as approximately 80% of parturient females shed their antlers during the calving period. In contrast, both movement methods performed marginally for estimating caribou parturition (~70% accuracy), with estimates from the individual-based method exhibiting greater bias than those from the population-based method. The individual-based method also poorly predicted neonate survival (≤49% accuracy for detecting parturition and calf fate for the Porcupine Herd). Video data revealed that inaccuracies with the movement methods often occurred when caribou bedded during storms, rested after traversing mountainous terrain, lost a calf shortly after birth, or increased movement to evade insects. These results have important implications for management agencies using antler- and movement-based methods to estimate caribou reproduction, particularly when informing assessments of population decline or recovery. Our results demonstrate the utility of video collar data for validating reproductive monitoring approaches and provide insights into how these approaches can be improved.
Alaska, Yukon↗
Lunar analog study using portable gamma-ray neutron detector: Radiochemical mapping of silicic-to-basaltic volcanic terrains in the San Francisco Volcanic Field, Arizona
Studying lunar silicic volcanism provides key insights into the Moon’s crustal evolution, magmatic processes, and volcanic history. The Lunar-VISE (Lunar Vulkan Imaging and Spectroscopy Explorer) mission will investigate the Gruithuisen domes, a unique lunar region hypothesized to have formed through silicic volcanism. Using instruments on a Firefly Aerospace lander and a Honeybee Robotics rover, Lunar-VISE will analyze mineralogy, geochemistry, and surface properties to determine the origin and evolution of the domes, with a gamma-ray and neutron spectrometer (LV-GRNS) among its payload instruments. In preparation for this mission, we conducted preliminary fieldwork using a handheld gamma-ray neutron detector with NaI(Tl) and Cs LiYCl :Ce (CLYC) scintillators. This study focuses on various rhyolitic and basaltic volcanic centers in the San Francisco Volcanic Field (SFVF) near Flagstaff, Arizona—specifically Sugarloaf Peak, Bonito Lava Flow, and Robinson Mountain, a region containing several well-characterized lunar analog sites. The SFVF was selected for this study due to its broad compositional diversity spanning basaltic to rhyolitic compositions, its well-preserved volcanic morphologies, and its extensive use in previous NASA field campaigns and astronaut training exercises, making it an ideal terrestrial laboratory for testing planetary exploration techniques. We measured natural radioactivity, specifically from potassium (K), thorium (Th), and uranium (U) and other elements in their decay chains, which serve as diagnostic tracers of magmatic differentiation and crustal evolution processes, to assess geochemical variability across compositionally diverse terrains. The detector’s sensitivity was assessed across varying concentration levels. Regionally averaged concentrations of radioisotopes were determined by gamma-ray spectroscopy at selected sites. Our measurements reveal significant compositional variations between sites, with Sugarloaf Peak (rhyolitic, silicic dome) exhibiting the highest average radioisotope concentrations (K: 3.29 ± 0.24 wt%, U: 14.35 ± 1.81 ppm, Th: 27.14 ± 2.43 ppm), while Bonito Lava Flow (K: 1.13 ± 0.08 wt%, U: 3.86 ± 0.52 ppm, Th: 7.52 ± 1.02 ppm), and Robinson Mountain (K: 1.46 ± 0.16 wt%, U: 5.59 ± 1.06 ppm, Th: 11.75 ± 1.98 ppm) show lower concentrations aligned with basaltic compositions. Gamma-ray fluxes were elevated by a factor of approximately three to four at Sugarloaf Peak relative to nearby basaltic terrains, consistent with expected geochemical differentiation patterns. Furthermore, at meter scales, proximity to geological features significantly affects measurements. Th concentrations adjacent to a cliff face at Sugarloaf’s base were 28% higher than values measured 3-5 meters away from the same feature, demonstrating localized compositional heterogeneity. Analysis of station-by-station measurements reveals that K, U, and Th concentrations show an elevation trend at Robinson Mountain and generally higher concentrations near Sugarloaf Peak’s summit, suggesting progressive magmatic differentiation and/or the presence of more evolved lithologies at higher elevations. By mapping these elements on Earth using GRNS, we aim to optimize measurement techniques for Lunar-VISE and similar rover-borne missions by demonstrating the applicability of portable GRNS instruments for planetary surface exploration in an analog environment.
Arizona↗
Rare earth element-mineralized carbonatite in the Bear Lodge Alkaline Complex, USA—Ore genesis implications from fluid inclusion characterization
Rare earth element (REE) resources of the Bear Lodge Alkaline Complex, Wyoming, are hosted in variably leached carbonatite spatially related to diatreme breccia pipes. We investigated the genesis of REE and lesser-known gold resources through fluid inclusion analysis of carbonatite, fluorite breccia, and smoky quartz vein samples. Physicochemical characteristics of inclusion-trapped fluids were evaluated using petrography, microthermometry, Raman spectroscopy, decrepitate mound analysis, energy-dispersive spectroscopy, laser ablation inductively coupled plasma mass spectrometry, and noble gas isotope analysis. Microthermometry results reveal three fluid types that affected carbonatite dikes within deeper zones that escaped near-surface, ore-grade REE enrichment: (1) high-temperature (330–432°C) magmatic fluid captured in fine-grained calcite; (2) REE-enriched alkali bicarbonate-sulfate brine; and (3) low-temperature (117–182°C) diluted magmatic or meteoric water. Multiphase brine-like inclusions contain burbankite, nahcolite, strontianite, celestine and alkali sulfate daughter crystals, linking them to early burbankite mineralization. Peripheral smoky quartz and fluorite occurrences at Smith Ridge, 1.5 km from the central carbonatite dike swarm, contain primary inclusions that are Cl-poor and rich in Na-HCO 3 -SO 4 , similar to secondary and pseudosecondary inclusions in carbonatites. Helium isotopes reveal a MORB-like source for carbonatite samples and an older crust signature at Smith Ridge, consistent with the proximal ridge-top exposures of Archean granite. Results from this fluid inclusion study coupled with previous studies of carbonatite mineral paragenesis, show that light REEs (LREEs) were not mobilized great distances. Instead, burbankite crystallized within carbonatite from alkali bicarbonate fluids. With sodium retained in early burbankite, outward-emanating fluids enriched in potassium relative to sodium (higher K:Na) resulted in potassium–ferric iron metasomatism of silicate host rocks. This alkali fractionation was accompanied by fractionation of LREEs and heavy REEs (HREEs), with LREEs dominating the central carbonatite resources. In contrast, areas of peripheral REE mineralization at Bear Lodge are commonly characterized by higher HREE:LREE ratios. The K:Na ratio of associated fenites or alteration assemblages could be indicative of early crystallized burbankite in carbonatites and REE fractionation processes potentially leading to areas of concentrated HREEs with greater supply vulnerabilities.
South Dakota, Wyoming↗
The addition of 144Nd atomic mass to routine ICP-MS analysis as a Quick Screening Tool for Approximating Rare Earth Elements (Q-STAR) in natural waters
Rare earth elements (REEs) are a class of critical minerals, all of which can have supply chain vulnerability that impacts economic security. These elements are widely measured in environmental matrices via inductively coupled plasma mass spectrometry (ICP-MS); however, successful quantification can require time-consuming, sample-specific optimization. While a sample-by-sample approach is appropriate for targeted quantification studies, this approach is not suitable for mineral exploration efforts where rapidly screening thousands of samples for the presence of REEs is desired. Here, we demonstrated the use of a Quick Screening Tool for Approximating REEs (Q-STAR) to detect REEs in surface water and groundwater matrices, collected as part of existing environmental studies. A mass-to-charge ratio of 144 ( m / z = 144) was added to an ICP-MS method to screen for REEs in filtered water samples submitted for metals analyses to the U.S. Geological Survey (USGS) National Water Quality Laboratory. We detected the presence of REEs above a reference threshold of 1200 counts per second in 18 % of pre-selected 6626 samples. Using this screened dataset, we mapped estimated dissolved REE concentrations across the United States in relation to ecoregions and underlying geology. Data are constrained to where sample collection took place but nevertheless show estimated aqueous dissolved REE concentrations on a geographic scale that has not yet been studied. To validate Q-STAR, REEs were measured in a USGS standard reference sample, a subset of 88 archived filtered water samples, and in fresh filtered surface water samples. Our targeted analyses demonstrated a strong linear relationship between Q-STAR predicted and measured values in all archived samples for Nd (r 2 = 0.94), and light REEs (LREEs) such as lanthanum (La) (r 2 = 0.93), praseodymium (Pr) (r 2 = 0.94) and samarium (Sm) (r 2 = 0.94). Using Q-STAR screen values, nine field sites were identified and surface water samples recollected to confirm the continued presence of Nd and LREEs. Q-STAR can be used to screen an unlimited number of water samples for the presence of REEs prior to time-intensive and costly quantitative analyses and to generate large REE datasets for further investigation.
Journal of Geochemical Exploration↗
Confocal laser-scanning microscopy (CLSM)-based thermal maturity of Tasmanites and progress in standardization of fluorescence microspectrometry
Evaluation of thermal maturity in vitrinite-free or vitrinite-deficient sediments via fluorescence microspectrometry can provide relevant information related to petroleum exploration and thermal history assessment. However, variation in spectral fluorescence properties of alginite macerals with increasing thermal maturity is largely underexplored. Here, authors of this study have applied confocal laser-scanning microscopy (CLSM) in conjunction with fluorescence microspectrometry to a maturity series of marine Upper Devonian Tasmanites algae from the Ohio Shale (Huron Member) and a single sample from the Marcellus Formation of the Appalachian Basin. Spectral fluorescence properties of Tasmanites were evaluated in relation to orientation, measurement location, and the number of measurements per sample, and were compared to published literature. Emission spectra of Tasmanites from continuous wave laser excitation (405 nm) were acquired from sections perpendicular and parallel to bedding and at different positions within individual Tasmanites bodies. The results showed a progressive red-shift in emission maxima (λ max ) in a large sample sized maturity series ( N = 19), e.g., 493 to 578 nm for the perpendicular section at middle position. Further, blue-shifted apex and mineral-adjacent positions within sections perpendicular to bedding were observed, with the latter being reported here for the first time. While blue-shift at apex positions can be attributed to mechanical deformation-induced reorientation of photoselected fluorophores, the blue-shifted mineral-adjacent positions could result from strain loading and development of a plastic deformation region at the mineral contact zone with Tasmanites . A decrease in standard deviation with increasing number of measured emission maxima is well-observed, and 15 to 20 individual measurements per sample appears sufficient for low standard deviation and coefficient of variance. CLSM-derived thermal maturity parameters indicated that a moderate positive correlation of red/green quotient (Q 650/500 ; R 2 = 0.67) with solid bitumen reflectance (BR o in %) exists. For reproducible results, the determination of λ max and Q 650/500 should be conducted exclusively in the middle position at perpendicular and parallel sections of the polished whole-rock pellets, where the lowest standard deviation in measurement was observed. These results strengthen the suitability and relevance of the CLSM technique in thermal maturity studies of dispersed organic matter (DOM) and contribute to the standardization of fluorescence microspectrometry methods in organic petrology investigation.
Kentucky, Ohio, Virginia, West Virginia↗
Identifying precursors and tracking pulses of magma ascent in multidisciplinary data during the 2018–2023 phreatomagmatic eruption at Semisopochnoi Island, Alaska
The 2018–2023 phreatomagmatic eruptions at Semisopochnoi Island, Alaska produced abundant long-period (LP) seismicity, harmonic and broadband tremor, and explosion signals over several well-monitored periods of eruption and quiescence. The corresponding dataset provides an excellent opportunity to investigate precursory and syn -eruptive geophysical signals of long-lived phreatomagmatic eruptions using multiparameter observations. We generated explosion and LP event catalogs through novel implementations of the REDPy ( Hotovec-Ellis, 2024 ) repeating event detector in mid-2021 following a network upgrade and the onset of a new phase of the eruption. The hundreds of detected explosions show a high degree of infrasound waveform similarity over more than a year, indicating a repeating source mechanism likely associated with explosive magma-water interaction. The seismic LP catalog shows that events began over a month prior to renewed explosive activity at the beginning of August 2021, and that lower frequency index (FI) LPs were generated in the week prior to the onset of explosions. We applied a recently developed machine learning tool (VOISS-Net, Tan et al., 2024 ) to catalog abundant broadband and harmonic seismic tremor recorded before and during the renewed explosive activity, along with LPs and explosions. The tremor catalogs complement the LP and explosion catalogs by filling out the seismic sequence with the dominant signal types. Together, these catalogs reveal a seismic sequence of renewed unrest that started with several weeks of LP events, followed by LPs with lower FI values and harmonic tremor in the days prior to explosive activity, and finally the onset of discrete explosions and broadband eruption tremor. We interpret this sequence as the ascent of a new pulse of magma that first interacted with the hydrothermal/groundwater system to produce LPs, followed by harmonic tremor, and that ultimately drove explosive magma-water interactions and periods of continuous ash emissions. The 2021 seismic sequence, in combination with long-term records of satellite SO 2 emissions, deformation from interferometric synthetic aperture radar (InSAR) analysis, ash sample analysis, infrasound, and volcano tectonic seismicity, allows us to interpret the entire 9-year period of unrest and eruption that began with an intrusion and earthquake swarm in 2014.
Alaska↗
Reaction kinetics and accelerant effects of sulfides in early mature hydrocarbon generation using hydrous pyrolysis
Hydrocarbon generation in organic-rich sediments is influenced by the molecular organic composition and relative abundance of associated minerals. Certain mineral-derived elements act as catalysts and reaction intermediaries, facilitating early-stage hydrocarbon formation in potential source rocks. This study investigated the role of sulfur contributed from pyrite as an accelerant in thermal reaction, focusing on its effects on early maturation and consequent hydrocarbon generation from gilsonite (low-sulfur solid petroleum). Hydrous pyrolysis (HP) experiments were conducted on mixtures of gilsonite and pyrite in varying ratios (1:0.1, 1:0.5, 1:1, 1:2, and 1:10 w/w gilsonite:pyrite) at 320, 350, and 370 °C for 72 h. Untreated and thermally altered residues were analyzed using solid bitumen reflectance (BR o , %), total organic carbon (TOC) content, programmed temperature pyrolysis, scanning electron microscopy with energy-dispersive spectroscopy (SEM-EDS), and X-ray diffraction (XRD) to evaluate the potential accelerant role of pyritic sulfur in hydrocarbon formation. The results show HP residues at 320 and 350 °C with greater pyrite concentrations had higher BR o , while reflectance values were similar in the 370 °C residues, regardless of pyrite concentration, suggesting enhanced reaction at lower thermal conditions. Increasing pyrite content systematically decreased hydrogen index (HI) values while increasing the transformation ratio (TR) and production index (PI), indicating enhanced conversion of organic matter to hydrocarbons with increasing pyrite concentrations. Gas yields increased with pyrite addition, particularly at 350 °C, confirming secondary cracking effects. However, gas production stabilized or declined at higher pyrite loadings (1:10), suggesting alternative reaction pathways such as coke formation. Our data indicate the presence of pyrite lowers the activation energy for thermal cracking, shifting peak experimental hydrocarbon generation temperatures downward by 20–30 °C, with the most pronounced accelerant effects observed at moderate pyrite concentrations (1:0.5 and 1:1). The thermodynamic framework reveals that pyrite stability is influenced by experimental conditions, with pyrrhotite formation favored in the presence of gilsonite due to reduced oxygen fugacity. Pyrite transformation to pyrrhotite, as observed through XRD, SEM-EDS, and predicted by thermodynamic data, further supports the accelerant role of S, as pyrrhotite exhibits a higher hydrogen transfer potential, promoting early oil generation. These findings highlight the importance of pyrite in modulating hydrocarbon generation pathways in organic-rich systems.
Journal of Analytical and Applied Pyrolysis↗
Simulated ground motion dataset in the Azores Plateau, Portugal, on rock and soil sites
Building on a previously developed bedrock dataset, this study extends the Azores Plateau ground motion simulations to include soil-amplified records and introduces a comprehensive validation framework. Soil amplification is modeled using one-dimensional soil profiles. A stochastic source-based approach is employed to generate the dataset, incorporating randomization of input-model parameters to account for the aleatory uncertainty in seismic activity. The accuracy of the dataset is verified through a comprehensive validation framework, showing that the randomization effectively captures variance and inter-period correlation observed in records. This work provides a robust dataset for advancing seismic hazard and risk assessment in the Azores Plateau.
central and eastern Azores islands↗
Small-volume tephra deposits of the May 1924 explosions from Halemaʻumaʻu, Kīlauea volcano, and their origin
More than 50 explosive eruptions occurred from Halemaʻumaʻu at Kīlauea volcano over 17 days from May 11 to 27, 1924. Ballistics weighing as much as 14,000 kg were ejected and most landed within 2 km of the vent. Fine ash made up a major component of the tephra and was dispersed tens of kilometers downwind. Draining of the Halemaʻumaʻu lava lake occurred in late February 1924, with the crater floor eventually subsiding by a further ∼70 m (to ∼180 m below the crater rim) by the time the first explosions took place during the night of May 10–11. The largest explosions occurred on May 17–18 and smaller explosions continued until May 27, at which point Halemaʻumaʻu had more than doubled in width and depth. The explosions generated plumes reaching up to ∼10 km high with ballistics ejected up to 2 km from the crater. Almost 100 years later, we investigate and characterize the preserved tephra deposits within ∼3 km of the 1924 crater rim. Grain size and shape analyses were performed on 202 samples collected from 34 tephra profiles using dynamic image analysis, with a subset of layers from nine tephra profiles used for componentry (200 grains per layer in the 0.5–1 mm size fraction). Additionally, we characterize the average diameters (using the five largest clasts) at 216 locations and measure the average diameters of 2291 ballistics (largest per ∼100 m 2 area). Physical descriptions from fieldwork and grain size distributions were used to subdivide the tephra layers into five lithofacies: coarse homogeneous, fine homogenous, red ash, accretionary lapilli-bearing, and finely laminated. Grain size versus shape data show a range of values that demonstrate most grains are dense, smooth, and equant, in alignment with lithic clasts dominating the tephra componentry. The fine grained and accretionary lapilli-bearing nature of some of these lithofacies confirms that water influenced the style of the explosions. However, we also note juvenile clasts within many of the tephra layers, indicating that many of the layers were formed during phreatomagmatic explosions (sensu stricto), despite the eruptive mechanism being dominantly phreatic. Juvenile clasts are more abundant higher in the tephra profiles, suggesting that juvenile magma was more involved later in the explosive sequence. Thermal and hydrologic modeling indicate that groundwater inflow into a short-lived, small-diameter volcanic conduit (10-m to 120-m-diameter used for modeling) during the 78–85 days preceding the first explosion provides a physically plausible mechanism for this eruptive sequence.
Hawaii↗
Multi-scale predictors of Northern Long-eared Bat (Myotis septentrionalis) occupancy in the United States
Historically, Myotis septentrionalis (Northern Long eared Bat) was among the most common forest-interior species in North America. Largely due to high mortality from white-nose syndrome, this species has experienced severe population declines across its range. To create an updated species distribution map representing summer occupancy probabilities from 2017 to 2022, we integrated stationary acoustic data with live-capture data from the database of the North American Bat Monitoring Program into a multi-scale, multi-method occupancy modeling framework. Our results provide data-driven predictions with quantified uncertainty for summer occupancy probabilities for Northern Long-eared Bats at 2 spatial scales across the range of the species, while also accounting for inherent observation biases (e.g., imperfect detection).
Journal of North American Bat Research↗
Imaging of seismic discontinuities using an adjoint method
For imaging of seismic discontinuities at depth, reverse time migration (RTM) is a powerful method to apply to recordings of seismic events. It is especially powerful when an extensive receiver array, numerous seismic sources, or both, permit adequate reconstruction of incident and scattered wavefields at depth. Reconstructing either the incident or scattered wavefield at depth becomes less accurate when relatively few recordings of seismic events are available. Here we explore an inverse scattering approach to imaging discontinuities based on an adjoint method, employing sensitivity kernels (Frechet derivatives) that represent jumps in material properties across seismic-discontinuity surfaces. When combined with ray-based requirements on scattering geometry, it constitutes a powerful approach to determining the locations and amplitudes of the discontinuities, recovering only those properties that can be resolved by a spatially limited source and/or receiver distribution. This is illustrated by synthetic examples with local sources followed by a field example in a subduction zone setting
Washington↗