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USGS1989

Calorimetry of heterogeneous systems: H+ binding to TiO2 in NaCl

A simultaneous calorimetric and potentiometric technique has been developed for measuring the thermodynamics of proton binding to mineral oxides in the presence of a supporting electrolyte. Modifications made to a commercial titration calorimeter to add a combination pH electrode and maintain an inert atmosphere in the calorimeter reaction vessel are described. A procedure to calibrate potentiometric measurements in heterogeneous systems to correct for the suspension effect on pH is given. The enthalpy change for proton dissociation from TiO 2 in aqueous suspension as a function of pH is reported for 0.01, 0.1, and 0.5 M NaCl. The enthalpy change for proton dissociation is endothermic, ranging from 10.5 ± 3.8 to 45.0 ± 3.8 kJ mol −1 over the pH range from 4 to 10.

Thermochimica Acta↗

USGS2005

Environmental Isotope Characteristics of Landfill Leachates and Gases

The isotopic characteristics of municipal landfill leachate and gases (carbon dioxide and methane) are unique relative to the aqueous and gaseous media in most other natural geologic environments. The δ 13 C of the CO 2 in landfills is significantly enriched in 13 C, with values as high as +20 ‰ reported. The δ 13 C and δD values of the methane fall within a range of values representative of microbial methane produced primarily by the acetate-fermentation process. The δD of landfill leachate is strongly enriched in deuterium, by approximately 30 ‰ to nearly 60 ‰ relative to local average precipitation values. This deuterium enrichment is undoubtedly due to the extensive production of microbial methane within the limited reservoir of a landfill. The concentration of the radiogenic isotopes, 14 C and 3 H, are significantly elevated in both landfill leachate and methane. The 14 C values range between approximately 120 and 170 pMC and can be explained by the input of organic material that was affected by the increased 14 C content of atmospheric CO2 caused by atmospheric testing of nuclear devices. The tritium measured in leachate, however, is often too high to be explained by previous atmospheric levels and must come from material buried within the landfill. The unique isotopic characteristics observed in landfill leachates and gases provide a very useful technique for confirming whether contamination is from a municipal landfill or some other local source.

Groundwater↗

USGS2022

Quality assurance report for Loch Vale Watershed, 2010–19

The Loch Vale Watershed Research and Monitoring Program collects long-term datasets of ecological and biogeochemical parameters in Rocky Mountain National Park to support both (1) management of this protected area and (2) research into watershed-scale ecosystem processes as those processes respond to atmospheric deposition and climate variability. The program collects data on precipitation depth and atmospheric deposition chemistry—as well as surface water biogeochemistry—within the watershed and in other areas of the park. These data are used by resource managers, scientists, policy makers, and students, so it is important that all collected data meet high quality standards. This report presents an evaluation of data quality for precipitation, atmospheric ammonia, and surface water quality samples collected from 2010 to 2019. This report also presents changes made to the monitoring and laboratory equipment used during the study period and describes new data streams added to the project, including atmospheric ammonia, surface water chlorophyll-a, and dissolved oxygen in two lakes: The Loch and Sky Pond. Quality-assurance procedures looked at the accuracy and precision of measurements made over the study period and found that precipitation and surface water chemistry data were 99 percent accurate and precise. Records that failed to meet quality standards were removed from published databases. From 2010 to 2014, a colocated precipitation gauge and deposition collector were installed on site as quality checks. From 2014 to 2018, power loss at the site resulted in significant loss of precipitation data records during the snow seasons. Those problems were addressed by installing new solar-power equipment in 2019. Measurements of deposition chemistry, atmospheric ammonia deposition, and surface water biogeochemistry were all sufficiently complete and consistent to support project data needs.

Colorado↗

USGS2016

Variation of energy and carbon fluxes from a restored temperate freshwater wetland and implications for carbon market verification protocols

Temperate freshwater wetlands are among the most productive terrestrial ecosystems, stimulating interest in using restored wetlands as biological carbon sequestration projects for greenhouse gas reduction programs. In this study, we used the eddy covariance technique to measure surface energy carbon fluxes from a constructed, impounded freshwater wetland during two annual periods that were 8 years apart: 2002–2003 and 2010–2011. During 2010–2011, we measured methane (CH 4 ) fluxes to quantify the annual atmospheric carbon mass balance and its concomitant influence on global warming potential (GWP). Peak growing season fluxes of latent heat and carbon dioxide (CO 2 ) were greater in 2002–2003 compared to 2010–2011. In 2002, the daily net ecosystem exchange reached as low as −10.6 g C m −2  d −1 , which was greater than 3 times the magnitude observed in 2010 (−2.9 g C m −2  d −1 ). CH 4 fluxes during 2010–2011 were positive throughout the year and followed a strong seasonal pattern, ranging from 38.1 mg C m −2  d −1 in the winter to 375.9 mg C m −2  d −1 during the summer. The results of this study suggest that the wetland had reduced gross ecosystem productivity in 2010–2011, likely due to the increase in dead plant biomass (standing litter) that inhibited the generation of new vegetation growth. In 2010–2011, there was a net positive GWP (675.3 g C m −2  yr −1 ), and when these values are evaluated as a sustained flux, the wetland will not reach radiative balance even after 500 years.

California↗

USGS2001

Simple Techniques For Assessing Impacts Of Oil And Gas Operations On Public Lands: A Field Evaluation Of A Photoionization Detector (PID) At A Condensate Release Site, Padre Island National Seashore, Texas

Simple, cost-effective techniques are needed for land managers to assess the environmental impacts of oil and gas production activities on public lands, so that sites may be prioritized for remediation or for further, more formal assessment. Field-portable instruments provide real-time data and allow the field investigator to extend an assessment beyond simply locating and mapping obvious disturbances. Field investigators can examine sites for the presence of hydrocarbons in the subsurface using a soil auger and a photoionization detector (PID). The PID measures volatile organic compounds (VOC) in soil gases. This allows detection of hydrocarbons in the shallow subsurface near areas of obvious oil-stained soils, oil in pits, or dead vegetation. Remnants of a condensate release occur in sandy soils at a production site on the Padre Island National Seashore in south Texas. Dead vegetation had been observed by National Park Service personnel in the release area several years prior to our visit. The site is located several miles south of the Malaquite Beach Campground. In early 2001, we sampled soil gases for VOCs in the area believed to have received the condensate. Our purpose in this investigation was: 1) to establish what sampling techniques might be effective in sandy soils with a shallow water and contrast them with techniques used in an earlier study; and 2) delineate the probable area of condensate release. Our field results show that sealing the auger hole with a clear, rigid plastic tube capped at the top end and sampling the soil gas through a small hole in the cap increases the soil VOC gas signature, compared to sampling soil gases in the bottom of an open hole. This sealed-tube sampling method increases the contrast between the VOC levels within a contaminated area and adjacent background areas. The tube allows the PID air pump to draw soil gas from the volume of soil surrounding the open hole below the tube in a zone less influenced by atmospheric air. In an open hole, the VOC readings seem to be strongly dependent on the degree of diffusion and advection of soil gas VOCs into the open hole from the surrounding soil, a process that may vary with soil and wind conditions. Making measurements with the sealed hole does take some additional time (4-7 minutes after the hole is augered) compared to the open-hole technique (1-2 minutes). We used the rigid-plastic tube technique to survey for soil gas VOCs across the entire site, less than ? acre. Condensate has impacted at least 0.28 acres. The impacted area may extend northwest of the surveyed area.

Open-File Report↗

USGS2018

Groundwater flux estimation in streams: A thermal equilibrium approach

Stream and groundwater interactions play an essential role in regulating flow, temperature, and water quality for stream ecosystems. Temperature gradients have been used to quantify vertical water movement in the streambed since the 1960s, but advancements in thermal methods are still possible. Seepage runs are a method commonly used to quantify exchange rates through a series of streamflow measurements but can be labor and time intensive. The objective of this study was to develop and evaluate a thermal equilibrium method as a technique for quantifying groundwater flux using monitored stream water temperature at a single point and readily available hydrological and atmospheric data. Our primary assumption was that stream water temperature at the monitored point was at thermal equilibrium with the combination of all heat transfer processes, including mixing with groundwater. By expanding the monitored stream point into a hypothetical, horizontal one-dimensional thermal modeling domain, we were able to simulate the thermal equilibrium achieved with known atmospheric variables at the point and quantify unknown groundwater flux by calibrating the model to the resulting temperature signature. Stream water temperatures were monitored at single points at nine streams in the Ozark Highland ecoregion and five reaches of the Kiamichi River to estimate groundwater fluxes using the thermal equilibrium method. When validated by comparison with seepage runs performed at the same time and reach, estimates from the two methods agreed with each other with an R 2 of 0.94, a root mean squared error (RMSE) of 0.08 (m/d) and a Nash–Sutcliffe efficiency (NSE) of 0.93. In conclusion, the thermal equilibrium method was a suitable technique for quantifying groundwater flux with minimal cost and simple field installation given that suitable atmospheric and hydrological data were readily available.

Oklahoma↗

USGS2009

Dual nitrate isotopes in dry deposition: Utility for partitioning NOx source contributions to landscape nitrogen deposition

Dry deposition is a major component of total atmospheric nitrogen deposition and thus an important source of bioavailable nitrogen to ecosystems. However, relative to wet deposition, less is known regarding the sources and spatial variability of dry deposition. This is in part due to difficulty in measuring dry deposition and associated deposition velocities. Passive sampling techniques offer potential for improving our understanding of the spatial distribution and sources of gaseous and aerosol N species, referred to here as dry deposition. We report dual nitrate isotopic composition ( δ 15 N and δ 18 O) in actively collected dry and wet deposition across the high‐deposition region of Ohio, New York, and Pennsylvania. We also present results from initial tests to examine the efficacy of using passive nitric acid collectors as a collection medium for isotopic analysis at a site in New York. Isotopic values in actively collected dry deposition, including particulate nitrate and gaseous nitric acid, are compared with those in wet nitrate deposition and surrounding NO x emission sources. δ 15 N values in dry and wet fractions are highest at the westernmost sites and lowest at the easternmost sites, and stationary source NO x emissions (e.g., power plants and incinerators) appear to be the primary control on δ 15 N spatial variability. In contrast, δ 18 O values show a less consistent spatial pattern in dry deposition. Both δ 15 N and δ 18 O show strong seasonality, with higher values in winter than summer. Seasonal variations in stationary source NO x emissions appear to be the most likely explanation for seasonal variations in δ 15 N, whereas seasonal variations in air temperature and solar radiation indicate variable chemical oxidation pathways control δ 18 O patterns. Additionally, we demonstrate the utility of passive samplers for collecting the nitric acid (HNO 3 ) component of dry deposition suitable for isotopic analysis. We observe slight differences in δ 15 N‐HNO 3 values between simultaneous samples collected actively and passively (0.6‰). However, we observe a larger offset in δ 18 O values between actively and passively collected samples; the causes for this offset warrant further investigation. Nonetheless, passive sample collection represents a significant cost savings over active sampling techniques and could allow a more extensive understanding of patterns of dry deposition and associated insights to nitrogen sources across landscapes.

Journal of Geophysical Research: Biogeosciences↗

USGS2026

The surface elevation table and marker horizon technique: A protocol for measuring wetland elevation dynamics, narrative (Version 2.0)

The National Park Service (NPS), in response to the growing evidence and awareness of the effects of climate change on federal lands, determined that monitoring wetland elevation change is a top priority in North Atlantic Coastal parks (Stevens et al. 2010). As a result, the NPS Northeast Coastal and Barrier Network (NCBN) in collaboration with colleagues from the U.S. Geological Survey (USGS) and the National Oceanic and Atmospheric Administration (NOAA) have developed a protocol for monitoring wetland elevation change and other processes important for determining the viability of wetland communities. Although focused on North Atlantic Coastal parks, this document is applicable to all coastal and inland wetland regions. Wetlands exist within a narrow range of elevation that is influenced by local hydrologic conditions. For tidally influenced coastal wetlands, local hydrologic conditions may be changing as sea levels continue to rise. As sea level rises, coastal wetland systems may either a) build elevation to maintain favorable hydrologic conditions for their survival or b) become increasingly inundated beyond their physiological tolerance resulting in an eventual conversion to open water. A better understanding of these processes will help to determine the present and future viability of coastal wetlands managed by the NPS and can help address measures to ensure these communities exist into the future. This protocol provides the reader with instructions and guidelines on designing a monitoring plan or study to: Quantify elevation change in wetlands with the Surface Elevation Table (SET); understand the processes that influence elevation change, including vertical accretion (SET and Marker Horizon methods); survey the wetland surface and SET mark to a common reference datum to allow for comparing sample stations to each other and to local tidal datums; survey the SET mark to monitor its relative stability; and establish water level equipment to characterize the hydrology and tidal datums for a particular wetland site or sites. The protocol is divided into two documents: The narrative (this document) presents an overview of all aspects of monitoring wetland elevation dynamics, and a document of Standard Operating Procedures (SOPs) with detailed instructions on the design, installation, data collection, and data management in support of monitoring changes in wetland elevation.

Science Report↗

USGS1995

Aerodynamic measurements of methyl bromide volatilization from tarped and nontarped fields

Methyl bromide (MeBr) is used extensively in agriculture as a soil fumigant and there is growing concern over the role it may play in the depletion of stratospheric ozone. Methyl bromide is applied using various techniques and very little is known about how much of the applied fumigant volatilizes into the atmosphere after the application. This field study was designed to estimate the post-application methyl bromide volatilization loss rates from two different application practices. The fields were approximately 6 km apart in Monterey County, California, and were treated in conformity with local practices as of 1992. The MeBr was injected at a depth of 25 to 30 cm. One field was covered simultaneously with a high-barrier plastic film tarp during the application, and the other was left uncovered, but the furrows made by the injection shanks were bedded over. Volatilization fluxes were estimated using an aerodynamic-gradient technique immediately following the completion of the application process and continued for 9 d for the tarped field and 6 d for the nontarped field. The cumulative volatilization losses from the tarped field were 22% of the nominal application within the first 5 d of the experiment and about 32% of the nominal application within 9 d including the one day after the tarp was removed on Day 8 after application. In contrast, the nontarped field lost 89% of the nominal application by volatilization in 5 d. The volatilization rate from the tarped field was shown to be significantly lower than the nontarped field at a 95% confidence level.

Journal of Environmental Quality↗

USGS2016

High spatio-temporal resolution observations of crater-lake temperatures at Kawah Ijen volcano, East Java, Indonesia

The crater lake of Kawah Ijen volcano, East Java, Indonesia, has displayed large and rapid changes in temperature at point locations during periods of unrest, but measurement techniques employed to-date have not resolved how the lake’s thermal regime has evolved over both space and time. We applied a novel approach for mapping and monitoring variations in crater-lake apparent surface (“skin”) temperatures at high spatial (~32 cm) and temporal (every two minutes) resolution at Kawah Ijen on 18 September 2014. We used a ground-based FLIR T650sc camera with digital and thermal infrared (TIR) sensors from the crater rim to collect (1) a set of visible imagery around the crater during the daytime and (2) a time series of co-located visible and TIR imagery at one location from pre-dawn to daytime. We processed daytime visible imagery with the Structure-from-Motion photogrammetric method to create a digital elevation model onto which the time series of TIR imagery was orthorectified and georeferenced. Lake apparent skin temperatures typically ranged from ~21 to 33oC. At two locations, apparent skin temperatures were ~ 4 and 7 oC less than in-situ lake temperature measurements at 1.5 and 5 m depth, respectively. These differences, as well as the large spatio-temporal variations observed in skin temperatures, were likely largely associated with atmospheric effects such as evaporative cooling of the lake surface and infrared absorption by water vapor and SO2. Calculations based on orthorectified TIR imagery thus yielded underestimates of volcanic heat fluxes into the lake, whereas volcanic heat fluxes estimated based on in-situ temperature measurements (68 to 111 MW) were likely more representative of Kawah Ijen in a quiescent state. The ground-based imaging technique should provide a valuable tool to continuously monitor crater-lake temperatures and contribute insight into the spatio-temporal evolution of these temperatures associated with volcanic activity.

Kawah Ijen volcano↗

USGS2002

Water budget for and nitrogen loads to Northeast Creek, Bar Harbor, Maine

The potential for nutrient enrichment to coastal estuaries on Mt. Desert Island, Maine, may affect the health of these important ecosystems at Acadia National Park. Inputs of water and nitrogen entering one of these coastal estuaries, Northeast Creek, and adjacent wetlands on Mt. Desert Island were quantified in a recent study conducted by the U.S. Geological Survey, in cooperation with the National Park Service. Streamflow and concentra-tions of nitrogen species in the four perennial streams entering the wetland/estuary system were measured monthly for 18 months to estimate loads and develop a water budget. Old Mill Brook was instrumented with a continuous-recording stream-flow gage; the MOVE.1 record-extension technique was used with this and several other nearby continuous gages to estimate daily surface-water inflow to the wetland. Inflow from ungaged basins was estimated from the unit-area yield calculated from data obtained from the gaged basins. Precipitation data collected at the National Atmospheric Deposition Program (NADP) site at Acadia National Park Headquarters and the Acadia National Park weather station were used to calculate atmospheric inputs. Evapotranspiration from the wetland was calculated using Fennessey and Vogel?s regionalized multivariate regression model of Penman-Montieth evapotranspiration. Geologic data collected in the field and taken from published geologic maps indicate that ground water probably does not contribute significantly to the water budget of this wetland system. Surface-water outflow from the wetland was not calculated because of the tidal nature of the outlet of the wetland and the difficulties associated with measuring flow in a tidal stream.

Maine↗

USGS2017

Comparison of conventional K-Ar and 40Ar/39Ar dating of young mafic volcanic rocks

K-Ar and 40Ar/39Ar ages have been measured on nine mafic volcanic rocks younger than 1 myr from the Snake River Plain (Idaho), Mount Adams (Washington), and Crater Lake (Oregon). The K-Ar ages were calculated from Ar measurements made by isotope dilution and K2O measurements by flame photometry. The 40Ar/39Ar ages are incremental-heating experiments using a low-blank resistance-heated furnace. The results indicate that high-quality ages can be measured on young, mafic volcanic rocks using either the K-Ar or the 40Ar/39Ar technique. The precision of an 40Ar/39Ar plateau age generally is better than the precision of a K-Ar age because the plateau age is calculated by pooling the ages of several gas increments. The precision of a plateau age generally is better than the precision of an isotope correlation (isochron) age for the same sample. For one sample the intercept of the isochron yielded an 40Ar/36Ar value significantly different from the atmospheric value of 295.5. Recalculation of increment ages using the isochron intercept for the composition of nonradiogenic Ar in the sample resulted in much better agreement of ages for this sample. The results of this study also indicate that, given suitable material and modern equipment, precise K-Ar and 40Ar/39Ar ages can be measured on volcanic rocks as young as the latest Pleistocene, and perhaps even the Holocene.

Quaternary Research↗

USGS2018

Rapid, remote assessment of Hurricane Matthew impacts using four-dimensional structure-from-motion photogrammetry

Timely assessment of coastal landforms and structures after storms is important for evaluating storm impacts, aiding emergency response and restoration, and initializing and assessing morphological models. Four-dimensional multiview photogrammetry, also known as structure from motion (4D SfM), provides a method for generating three-dimensional reconstructions of landscapes at two times (before and after events) using only photos and existing information for ground control points. Here, these techniques were applied using National Oceanic and Atmospheric Administration (NOAA)-obtained oblique aerial photos taken before (2015) and immediately after Hurricane Matthew (2016) to assess coastal changes near Matanzas, Florida. This work demonstrated that 3D digital elevation models can be constructed within 48 hours of postevent photo collection without on-site ground control measurements. One advantage of timely SfM elevation-change assessments is that they avoid confusion of storm impacts with changes that occur after the event but before LIDAR surveys can be performed. The accuracy and precision of the 4D SfM maps were assessed a posteriori using the first-available LIDAR data, which were collected more than a month after the hurricane, and 11 independent ground-truth survey points measured a week after the hurricane. Horizontal coordinates of the 4D SfM reconstruction were biased by an average of 0.79 m (0.83 m root-mean-square difference; RMSD) compared with the ground-truth points, but vertical elevations were more accurate. They were biased from the LIDAR by −0.09 to −0.25 m, with ∼0.20 m RMSD from both the LIDAR data and five ground-truth points with good vertical positioning and 0.25 m RMSD from LIDAR data along a 60-m stretch of pavement. This level of precision was sufficient to quantify geomorphological change that was often in excess of 1 m. The methodology is conducive for rapid assessment of changes along short stretches (tens of kilometers) of coast with modest resources and could be scaled up for larger regions.

Florida↗

USGS2024

High resolution identification and quantification of diffuse deep groundwater discharge in mountain rivers using continuous boat-mounted helium measurements

Discharge of deeply sourced groundwater to streams is difficult to locate and quantify, particularly where both discrete and diffuse discharge points exist, but diffuse discharge is one of the primary controls on solute budgets in mountainous watersheds. The noble gas helium is a unique identifier of deep groundwater discharge because groundwater with long residence times is commonly enriched in helium. In this study, a portable mass spectrometer was used to measure longitudinal variation in dissolved helium concentrations in two mountainous rivers at high spatial resolution not feasible with traditional sampling techniques. Helium profiles were then simulated using a mass-balance model to quantify longitudinal variation in groundwater discharge to the receiving rivers. Results indicate helium concentrations were enriched by multiple orders of magnitude above atmospheric equilibrium in both rivers and that this persisted for up to 18 km below observed pulse inputs in the Colorado River. Helium mass-balance models match observed longitudinal patterns with the exception of sharp initial increases in helium observed in the rivers. Increased longitudinal groundwater discharge rates correspond to mapped geologic structures in both watersheds that likely transport deep geothermal water. Models show variable sensitivity to spatial assignment of input variables representing the groundwater source, illustrating the importance of collecting data from discrete groundwater discharges where possible. The methodology shows promise for field experiments designed to assess air–water exchange rates and to quantify total groundwater discharge from a combination of discrete and diffuse sources.

Colorado, Utah↗

USGS2013

Direct estimation of diffuse gaseous emissions from coal fires: current methods and future directions

Coal fires occur in nature spontaneously, contribute to increases in greenhouse gases, and emit atmospheric toxicants. Increasing interest in quantifying coal fire emissions has resulted in the adaptation and development of specialized approaches and adoption of numerical modeling techniques. Overview of these methods for direct estimation of diffuse gas emissions from coal fires is presented in this paper. Here we take advantage of stochastic Gaussian simulation to interpolate CO 2 fluxes measured using a dynamic closed chamber at the Ruth Mullins coal fire in Perry County, Kentucky. This approach allows for preparing a map of diffuse gas emissions, one of the two primary ways that gases emanate from coal fires, and establishing the reliability of the study both locally and for the entire fire. Future research directions include continuous and automated sampling to improve quantification of gaseous coal fire emissions.

International Journal of Coal Geology↗

USGS2009

Measurement of soil carbon oxidation state and oxidative ratio by 13 C nuclear magnetic resonance

The oxidative ratio (OR) of the net ecosystem carbon balance is the ratio of net O 2 and CO 2 fluxes resulting from photosynthesis, respiration, decomposition, and other lateral and vertical carbon flows. The OR of the terrestrial biosphere must be well characterized to accurately estimate the terrestrial CO 2 sink using atmospheric measurements of changing O 2 and CO 2 levels. To estimate the OR of the terrestrial biosphere, measurements are needed of changes in the OR of aboveground and belowground carbon pools associated with decadal timescale disturbances (e.g., land use change and fire). The OR of aboveground pools can be measured using conventional approaches including elemental analysis. However, measuring the OR of soil carbon pools is technically challenging, and few soil OR data are available. In this paper we test three solid-state nuclear magnetic resonance (NMR) techniques for measuring soil OR, all based on measurements of the closely related parameter, organic carbon oxidation state (C ox ). Two of the three techniques make use of a molecular mixing model which converts NMR spectra into concentrations of a standard suite of biological molecules of known C ox . The third technique assigns C ox values to each peak in the NMR spectrum. We assess error associated with each technique using pure chemical compounds and plant biomass standards whose C ox and OR values can be directly measured by elemental analyses. The most accurate technique, direct polarization solid-state 13 C NMR with the molecular mixing model, agrees with elemental analyses to ??0.036 C ox units (??0.009 OR units). Using this technique, we show a large natural variability in soil C ox and OR values. Soil C ox values have a mean of -0.26 and a range from -0.45 to 0.30, corresponding to OR values of 1.08 ?? 0.06 and a range from 0.96 to 1.22. We also estimate the OR of the carbon flux from a boreal forest fire. Analysis of soils from nearby intact soil profiles imply that soil carbon losses associated with the fire had an OR of 1.09 1 (??0.00 3 ). Fire appears to be a major factor driving the soil C pool to higher oxidation states and lower OR values. Episodic fluxes caused by disturbances like fire may have substantially different ORs from ecosystem respiration fluxes and therefore should be better quantified to reduce uncertainties associated with our understanding of the global atmospheric carbon budget. Copyright 2009 by the American Geophysical Union.

Journal of Geophysical Research G: Biogeosciences↗

USGS2017

Part I, the development of the method

A freshly exposed surface of obsidian will take up water from the atmosphere to form a hydrated surface layer. This layer has a different density and refractive index than does the remainder of the obsidian. Using special techniques, a thin section of the obsidian cut at right angles to the surface can be prepared. When examined under the microscope the hydrated layer is visible and its thickness can be measured. Photomicrographs of such thin sections are shown. Factors that determine the rate of hydration were considered. Using artifacts from archaeological sites of known age, the influence of temperature, relative humidity, chemical composition of the obsidian, burning and erosion of the obsidian on the rates of hydration was determined. Temperature and chemical composition are the main factors controlling the rate of hydration. Obsidian hydrates more rapidly at a higher temperature, and thus progresses at a faster rate in tropical than in arctic climates. Rhyolitic obsidian hydrates more slowly than does trachytic obsidian. Using archaeological data from various parts of the world, several tentative hydration rates were determined for tropical, temperate, and arctic climates. The method in its present state of development is especially suited to determine relative chronologies in layered sequences of artifacts from a single site, or region. It is also useful for detecting fake artifacts. Future work to refine the method is suggested.

American Antiquity↗

USGS2000

Seasonal estimates of riparian evapotranspiration using remote and in situ measurements

In many semi-arid basins during extended periods when surface snowmelt or storm runoff is absent, groundwater constitutes the primary water source for human habitation, agriculture and riparian ecosystems. Utilizing regional groundwater models in the management of these water resources requires accurate estimates of basin boundary conditions. A critical groundwater boundary condition that is closely coupled to atmospheric processes and is typically known with little certainty is seasonal riparian evapotranspiration ET). This quantity can often be a significant factor in the basin water balance in semi-arid regions yet is very difficult to estimate over a large area. Better understanding and quantification of seasonal, large-area riparian ET is a primary objective of the Semi-Arid Land-Surface-Atmosphere (SALSA) Program. To address this objective, a series of interdisciplinary experimental Campaigns were conducted in 1997 in the San Pedro Basin in southeastern Arizona. The riparian system in this basin is primarily made up of three vegetation communities: mesquite (Prosopis velutina), sacaton grasses (Sporobolus wrightii), and a cottonwood (Populus fremontii)/willow (Salix goodingii) forest gallery. Micrometeorological measurement techniques were used to estimate ET from the mesquite and grasses. These techniques could not be utilized to estimate fluxes from the cottonwood/willow (C/W) forest gallery due to the height (20-30 m) and non-uniform linear nature of the forest gallery. Short-term (2-4 days) sap flux measurements were made to estimate canopy transpiration over several periods of the riparian growing season. Simultaneous remote sensing measurements were used to spatially extrapolate tree and stand measurements. Scaled C/W stand level sap flux estimates were utilized to calibrate a Penman-Monteith model to enable temporal extrapolation between Synoptic measurement periods. With this model and set of measurements, seasonal riparian vegetation water use estimates for the riparian corridor were obtained. To validate these models, a 90-day pre-monsoon water balance over a 10 km section of the river was carried out. All components of the water balance, including riparian ET, were independently estimated. The closure of the water balance was roughly 5% of total inflows. The ET models were then used to provide riparian ET estimates over the entire corridor for the growing season. These estimates were approximately 14% less than those obtained from the most recent groundwater model of the basin for a comparable river reach.

Conference Paper↗