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Modeling subsurface performance of a geothermal reservoir using machine learning

Geothermal power plants typically show decreasing heat and power production rates over time. Mitigation strategies include optimizing the management of existing wells—increasing or decreasing the fluid flow rates across the wells—and drilling new wells at appropriate locations. The latter is expensive, time-consuming, and subject to many engineering constraints, but the former is a viable mechanism for periodic adjustment of the available fluid allocations. In this study, we describe a new approach combining reservoir modeling and machine learning to produce models that enable such a strategy. Our computational approach allows us, first, to translate sets of potential flow rates for the active wells into reservoir-wide estimates of produced energy, and second, to find optimal flow allocations among the studied sets. In our computational experiments, we utilize collections of simulations for a specific reservoir (which capture subsurface characterization and realize history matching) along with machine learning models that predict temperature and pressure timeseries for production wells. We evaluate this approach using an “open-source” reservoir we have constructed that captures many of the characteristics of Brady Hot Springs, a commercially operational geothermal field in Nevada, USA. Selected results from a reservoir model of Brady Hot Springs itself are presented to show successful application to an existing system. In both cases, energy predictions prove to be highly accurate: all observed prediction errors do not exceed 3.68% for temperatures and 4.75% for pressures. In a cumulative energy estimation, we observe prediction errors that are less than 4.04%. A typical reservoir simulation for Brady Hot Springs completes in approximately 4 h, whereas our machine learning models yield accurate 20-year predictions for temperatures, pressures, and produced energy in 0.9 s. This paper aims to demonstrate how the models and techniques from our study can be applied to achieve rapid exploration of controlled parameters and optimization of other geothermal reservoirs.

Energies

High‐frequency rupture processes of the 2014 Mw 8.2 Iquique and 2015 Mw 8.3 Illapel, Chile, earthquakes determined from strong‐motion recordings

Strong‐motion recordings of the 2014 M w "> M w Mw 8.2 Iquique and 2015 M w "> M w Mw 8.3 Illapel, Chile, earthquakes were analyzed to determine rupture propagation and the location, timing, and strength of subevents that produce most of the high‐frequency (≥1 Hz) ground motions. A moving window,cross‐correlation analysis of recordings from a local dense array, band‐pass filtered at 1 Hz, directly shows that the Iquique earthquake ruptured to the southeast over a distance of about 60 km. Array analysis of lower frequency energy (0.03–0.1 Hz) indicates that it occurred updip of the high‐frequency rupture. A methodology was developed for inverting the envelopes of acceleration records (1–5 Hz) to map high‐frequency source factors on the rupture zone and was applied to the two earthquakes. Waveforms of M w "> M w Mw 6 earthquakes were used as empirical Green’s functions in the inversions. High‐frequency subevents within the two M w "> M w Mw 8 earthquakes were located at depths ranging from 25 to 55 km and mostly occurred downdip of the peak slip of these earthquakes. Fourier spectral ratios of the Iquique mainshock with respect to M w "> M w Mw 5–6 aftershocks were fit to determine their stress drops. The stress drops were roughly constant from M w "> M w Mw 5 to 8 at 10–20 MPa. A compound rupture model is described in which subevents occur in areas of spatially heterogeneous strength and stress on the rupture, and produce the high‐frequency radiated energy of the overall earthquake, but are not located in the areas of peak slip. The stress drop of the overall earthquake is shown to equal the root mean square stress drop of subevents averaged over the rupture area.

Iquique, Illapel

Problems encountered in the use of neutron methods for elemental analysis on planetary surfaces

From experimental studies of gamma rays from fast and thermal neutron reactions in hydrogeneous and non-hydrogeneous, semi-infinite samples and from Monte Carlo calculations on soil of a composition which might typically be encountered on planetary surfaces, it is found that gamma rays from fast or inelastic scattering reactions would dominate the observed spectra. With the exception of gamma rays formed by inelastically scattered neutrons on oxygen, useful spectra would be limited to energies below 3 MeV. Other experiments were performed which show that if a gamma-ray detector were placed within 6 m of an isotopic neutron source in a spacecraft, it would be rendered useless for gamma-ray spectrometry below 3 MeV because of internal activation produced by neutron exposure during space travel. Adequate shielding is not practicable because of the size and weight constraints for planetary missions. Thus, it is required that the source be turned off or removed to a safe distance during non-measurement periods. In view of these results an accelerator or an off-on isotopic source would be desirable for practical gamma-ray spectral analysis on planetary surfaces containing but minor amounts of hydrogen.

Nuclear Instruments and Methods

Mercury speciation and stable isotopes in emperor penguins: First evidence for biochemical demethylation of methylmercury to mercury-dithiolate and mercury-tetraselenolate complexes

Apex marine predators, such as toothed whales and large petrels and albatrosses, ingest mercury (Hg) primarily in the form of methylmercury (MeHg) via prey consumption, which they detoxify as tiemannite (HgSe). One of the most intriguing current questions in Hg research is how more abundant lower trophic level predators detoxify MeHg, particularly in marine environments where tissue Hg burdens can be elevated. To address this need, we used high energy-resolution X-ray absorption near edge structure spectroscopy paired with nitrogen (N) and Hg stable isotopes to identify the chemical forms of Hg, Hg source, and species-specific δ 202 Hg isotopic values in emperor penguin, a mesopredator feeding primarily on Antarctic silverfish. The penguin liver contains variable proportions of MeHg and two inorganic Hg species (IHg), Hg-dithiolate (Hg(SR) 2 ) and Hg-tetraselenolate (Hg(Sec) 4 ) complexes, each characterized by a specific isotopic value (δ 202 MeHg = 0.3 ± 0.2‰, δ 202 Hg(SR) 2 = −1.6 ± 0.2‰, δ 202 Hg(Sec) 4 = −2.0 ± 0.1‰). Using δ 15 N as tracer of food source, we show that Hg(SR) 2 is not dietary but a biochemical demethylation product of MeHg metabolism. Penguin females transfer Hg to the egg as MeHg in the egg albumen, 89% MeHg and 11% IHg in the membrane, and 32% MeHg and 68% Hg(Sec) 4 in the yolk, on average (n = 15). Despite IHg species in eggs, MeHg is the main species quantitatively transferred by the mother to the chick because of the disproportionate mass of the MeHg-rich albumen compared to the yolk (n = 18). Further research is needed to elucidate the MeHg to Hg(SR) 2 demethylation pathway firmly documented here for the first time in multicellular organisms, and to understand why the thiolate ligands are not exchanged for Se ligands to form Hg(Sec) 4 , as the liver does not suffer from Se deficiency.

Adelie Land

Geologic cross section A–A′ through the Appalachian basin from the southern margin of the Ontario Lowlands province, Genesee County, western New York, to the Valley and Ridge province, Lycoming County, north-central Pennsylvania

Introduction Geologic cross section A–A′ is the fifth in a series of cross sections constructed by the U.S. Geological Survey (USGS) to document and improve understand­ing of the geologic framework and petroleum systems of the Appalachian basin. Cross section A–A′ provides a regional view of the structural and stratigraphic frame­work of the Appalachian basin from the southern mar­gin of the Ontario Lowlands province in western New York, across the Allegheny Plateau province of central New York and north-central Pennsylvania, to the Valley and Ridge province in north-central Pennsylvania, a dis­tance of approximately 176 miles. This cross section is a companion to cross sections E–E′, D–D′, C–C′ , and I–I′ that are located approximately 100 to 500 miles to the southwest. Cross section A–A′ complements earlier geologic or strati­graphic cross sections through the central New York and north-central Pennsylvania part of the Appalachian basin. Although some of these other cross sections show more structural and stratigraphic detail, they are of more limited extent geographically and stratigraphically. Cross section A–A′ contains much information that is useful for evaluating energy resources in the Appalachian basin. Although the Appalachian basin petroleum systems are not shown on the cross section, many of their key elements (such as source rocks, reservoir rocks, seals, and traps) can be inferred from lithologic units, unconformities, and geologic structures shown on the cross section. Important oil- and gas-bearing formations like the Oriskany Sandstone, Medina Group sandstones, Tuscarora Sandstone, and the Marcellus and Utica Shales are present on cross-section A–A′ .

New York, Pennsylvania

Cross section N–N' through the Valley and Ridge province of the southern Appalachian basin, from Greene County, west-central Alabama, to Bibb County, central Alabama

Introduction Geologic cross section N–N′ is the sixth in a series of geologic cross sections constructed by the U.S. Geological Survey to document and improve understanding of the geologic framework and petroleum systems of the Appalachian basin. Cross section N–N′ provides a regional view of the structural and stratigraphic framework of the Appalachian basin in the Valley and Ridge province in western and central Alabama; it spans approximately 69 miles (mi) (111 kilometers [km]). This geologic cross section is a companion to geologic cross sections E–E′ , D–D′ , C–C′ , I–I′ , and A–A′ that are located approximately 350 to 550 mi (563 to 885 km) to the northeast. Cross section N–N' complements earlier geologic cross sections through the Alabama part of the Appalachian basin. Although some of the other cross sections show more structural and stratigraphic detail, they are of more limited extent geographically and stratigraphically. Cross section N–N′ contains information that is useful for evaluating energy resources in the Appalachian basin. Although the Appalachian basin petroleum systems are not shown on the cross section, many of their key elements (such as source rocks, reservoir rocks, seals, and traps) can be inferred from lithologic units, unconformities, and geologic structures shown on the cross section. Other aspects of petroleum systems (such as the timing of petroleum generation and petroleum migration pathways) may be evaluated by burial history, thermal history, and fluid flow models based on what is shown on the cross section. In addition, cross section N–N′ may be used as a reconnaissance tool to identify plausible geologic structures and strata for the subsurface storage of liquid waste or for the sequestration of carbon dioxide.

Alabama

Predicting attenuation of salinized surface- and groundwater-resources from legacy energy development in the Prairie Pothole Region

Oil and gas (energy) development in the Williston Basin, which partly underlies the Prairie Pothole Region in central North America, has helped meet U.S. energy demand for decades. Historical handling and disposal practices of saline wastewater co-produced during energy development resulted in salinization of surface and groundwater at numerous legacy energy sites. Thirty years of monitoring (1988–2018) at Goose Lake, which has been producing since the 1960s, documents long-term spatial and temporal changes in water quality from legacy energy development. Surface water quality was highly variable and decoupled from changes in groundwater quality, likely due to annual and regional climatic fluctuations. Therefore, changes in surface water-quality were not considered a reliable indicator of subsurface chloride migration. However, chloride concentrations in monitoring wells near wastewater sources exhibited systematic temporal reductions allowing for estimates of the time required for natural attenuation of groundwater to U.S. Environmental Protection Agency acute and chronic chloride toxicity benchmarks and a local background level. Point attenuation rates differed based on sediment type (outwash vs till) and yielded a range of predicted years when water-quality targets will be reached: acute – 2045 to 2113; chronic – 2069 to 2160; background – 2126 to 2275. Bulk attenuation rates from four separate years of data were used to calculate the distances chloride could migrate downgradient from the largest wastewater source. Potential distances of downgradient migration before dilution to water-quality targets decreased from 1989 to 2018: acute – 949 to 673 m; chronic – 1220 to 922 m; background – 1878 to 1525 m. Several downgradient wetlands are within these distances and will continue to receive saline contaminated groundwater for years. While these results demonstrate chloride attenuation at a legacy energy site, they also highlight the persistence of saline wastewater contamination and the need to mitigate future spills to prevent long-term salinization from energy development.

Montana

Mineral exploration and soil analysis using in situ neutron activation

A feasibility study has been made to operate by remote control an unshielded portable positive-ion accelerator type neutron source to induce activities in the ground or rock by “in situ” neutron irradiation. Selective activation techniques make it possible to detect some thirty or more elements by irradiating the ground for periods of a few minutes with either 3-MeV or 14-MeV neutrons. The depth of penetration of neutrons, the effect of water content of the soil on neutron moderation, gamma ray attenuation in the soil and other problems are considered. The analysis shows that, when exploring for most elements of economic interest, the reaction 2 H(d,n) 3 He yielding ∼ 3-MeV neutrons is most practical to produce a relatively uniform flux of neutrons of less than 1 keV to a depth of 19″–20″. Irradiation with high energy neutrons (∼ 14 MeV) can also be used and may be better suited for certain problems. However, due to higher background and lower sensitivity for the heavy minerals, it is not a recommended neutron source for general exploration use. Preliminary experiments have been made which indicate that neutron activation in situ is feasible for a mineral exploration or qualititative soil analysis.

Nuclear Instruments and Methods

Geophysical characterization of the Northwest Geysers geothermal field, California

The Clear Lake Volcanic Field in northern California is the youngest and northern-most part of a long-lived volcanic system that has produced recent (~10 ka) eruptions. Adjacent to the Clear Lake Volcanic Field is the worlds largest energy producing geothermal field, The Geysers. The hottest part of The Geysers geothermal field is in the northwest where temperatures reach ~400 C at 3 km depth. Low permeability, high thermal gradients, and low steam saturation prescribed development of an enhanced geothermal system (EGS) in the Northwest Geysers to increase energy producing capacity. Though the Northwest Geysers is known to be the hottest part of the field, geophysical methods have failed to adequately image any inferred heat source. This project aims to image the heat source of the Northwest Geysers using newly collected gravity and magnetotelluric (MT) measurements. Gravity data were jointly modeled with existing magnetic data along a two-dimensional profile aligned with an existing geologic cross-section. The key feature of the potential field model is a low-density, low-susceptibility body at 5 km depth (bmsl) under the EGS. MT data were modeled in three-dimensions to characterize subsurface resistivity structure, where the upper 3 km of the resistivity model agrees well with existing data. Lithologic and steam saturation are estimated from modeled resistivity values using existing geophysical data. Below 3 km depth (bmsl), the resistivity model images a possible young intrusion under the EGS. A possible zone of partial melt (<5%) below 7 km depth (bmsl) in the northwestern part of the field is also imaged which extends northeast towards the main part of the Clear Lake Volcanic Field.

California

Materials flow of indium in the United States in 2008 and 2009

Indium is a material that has many applications. It is used by anyone who watches television or views a computer screen. It is found in solar energy arrays and in soldering applications that are required to be lead free. In 2009, about 550 metric tons (t) of indium metal was produced from primary sources world-wide; it was estimated that the United States consumed about 110 t of indium metal (20 percent of world primary production). However, when imports of consumer products that contain indium are considered, the United States consumed about 200 t of indium (36 percent of world primary production). When one considers the recovery from the low-efficiency sputtering process that coats indium-tin oxide onto glass and other surfaces, the recycling rate (within the manufacturing process that uses indium-tin oxide in flat panel displays approaches 36 percent. However, indium recovery from old scrap generated from end-of-life consumer products is not sufficiently economic to add significantly to secondary production. Between 1988 and 2010, indium prices averaged $381 per kilogram (in constant 2000 dollars). However, prices have been quite volatile (deviating from the average of $381 per kilogram by &plusmn;$199 per kilogram, a 52 percent difference from the average), reflecting short-term disequilibrium of supply and demand but also responsiveness of supply to demand. The dynamics of zinc smelting govern the primary supply of indium because indium is a byproduct of zinc smelting. Secondary indium supply, which accounts for about one-half of total indium supply, is governed by indium prices and technological advances in recovery. Indium demand is expected to grow because the number and volume of cutting edge technology applications that depend on indium are expected to grow.

Circular

Digital recordings of aftershocks of the 17 October 1989 Loma Prieta, California, earthquake

After the 17 October 1989 Loma Prieta, central California, earthquake (291 00:04:15.25 UTC, M s =7.1), the U. S. Geological Survey recorded aftershocks at sites of seismologic and engineering interest. This report describes a seismic-waveform dataset collected from 17 October 1989 (291 UTC) to 14 March 1990 (073 UTC) with GEOS digital seismographs deployed from USGS offices in Menlo Park, California. It is a summary of field and data-playback information that is intended to facilitate use of the waveform data in seismologic and engineering studies. It includes station locations, instrumentation histories (trigger parameters, sensor parameters, clock corrections, etc.), listings of waveform records, preliminary seismicity listings, and information about data availability. Our principal research goal is to understand the influence of seismic-source and wave-propagation phenomena on damaging ground motions, and to use this knowledge to predict hazards from future earthquakes. Source processes encompass the spatial and temporal variations in the excitation of seismic waves at the fault. Wave-propagation processes include amplification and deamplification as seismic energy radiates away from the fault through rocks and soils of variable seismic properties. Since shallow geology at a site (upper tens to hundreds of meters) can exert a relatively great influence on damaging ground motions, it is useful to separate wave-propagation phenomena into whole-path and site parts. In studying these phenomena, aftershock waveform recordings can play an important role. Compared to main shocks, aftershocks are simple earthquakes and aftershock records tend to be relatively dominated by wave-propagation effects. Geometrically, since aftershocks are distributed over the fault zone, aftershock records should resemble part of the main-shock ground motion contributed by localized rupture. This observation forms the basis of the empirical-Green's-function method wherein main-shock ground motion is modeled by summing aftershock records. The Loma Prieta earthquake provided a rare opportunity that motivated the intensive aftershock-recording effort described in this report. In a seismically noisy urban environment like the San Francisco Bay area, such a large set of high quality seismic data would otherwise be unobtainable.

California

Airborne radioactivity survey of the Miller Hill area, Carbon county, Wyoming

The accompanying map shows the results of an airborne radioactivity survey covering 65 square miles northwest of Miller Hill, Carbon county, Wyoming. The survey was made by the U.S. Geological Survey as part of a cooperative program with the U.S. Atomic Energy Commission. At 500 feet above the ground, the width of the zone from which anomalous radioactivity is measured varies with the intensity of radiation of the source and, for strong sources, the width would be as much as 1,400 feet. Quarter-mile spacing of the flight paths of the aircraft should be adequate to detect anomalies from strong sources of radioactivity. However, small areas of considerable radioactivity midway between flight paths may not be noted. The approximate location of each radioactivity anomaly is shown on the accompanying map. The plotted position of an anomaly may be in error by as much as a quarter of a mile owing to errors in the available base maps up to several square miles in which it is impossible to find and plot recognizable landmarks. The radioactivity anomalies shown on the accompanying map cannot be interpreted in terms of either the radioactive content or the extent of the source materials. The present technique of airborne radioactivity measurement does not permit distinguishing between activity due to thorium and that due to uranium. An anomaly, therefore, may represent radioactivity due entirely to uranium, or to thorium, or to a combination of uranium and thorium. The radioactivity that is recorded by airborne measurements at 500 feet above the ground can be caused by: 1. A moderately large area in which the rocks and soils are slightly more radioactive than the rocks and soils of the surrounding area. 2. A smaller area in which the rocks and soils are considerably more radioactive than rocks and soils in the surrounding area. 3. A very small area in which to rocks and soils are much more radioactive than the rocks and soils of the surrounding area. Any particular anomaly, therefore, may represent either slightly greater-than-average radioactivity over an area of a few thousand square feet, or high radioactivity over an area of a few hundred square feet. The radioactivity anomalies shown on the accompanying map indicate localities of more-than-average radioactivity, and therefore, suggest areas in which uranium or thorium deposits are more likely to occur.

Wyoming

Groundwater availability of the Williston Basin, United States and Canada

Executive Summary The Williston Basin of the Northern Great Plains is a sedimentary basin—a geologic bowl-like structure filled with layered sedimentary rocks dating as far back as the Paleozoic age. The basin, which is nationally important for the production of energy resources, spans Montana, North Dakota, and South Dakota in the United States, and Manitoba and Saskatchewan in Canada. The three uppermost principal aquifer systems are the glacial, lower Tertiary, and Upper Cretaceous aquifer systems. As deep as 3,000 feet (ft) at the center of the basin, these are the most accessible aquifer systems in the basin and are the primary sources of potable groundwater in much of this area. The glacial aquifer system consists of Quaternary-age unconsolidated till, silt, clay, outwash sand and gravel, and occasional cobbles and boulders. The lower Tertiary and Upper Cretaceous aquifer systems consist primarily of sandstone, siltstone, mudstone, shale, and coal. As energy demands have increased in the basin, horizontal drilling and hydraulic-fracturing have been used (especially since 2005) to develop previously inaccessible formations—namely, the Bakken and Three Forks Formations. The basin has yielded a large supply of domestic oil and natural gas since the 1950s, but the technologies required to extract those materials use large amounts of freshwater. The increasing freshwater demands of energy production in the Williston Basin, in addition to population growth, have led to a need for new tools to assess groundwater resources.

Williston Basin

Understanding the resource potential of natural hydrogen on Earth: Scientific gaps, uncertainties and recommendations

A comprehensive scientific research roadmap is essential to bridge knowledge gaps and deepen the understanding of key geological, geochemical, and geophysical aspects of natural hydrogen (H 2 ) as a potential new energy resource. This paper reviews major scientific uncertainties on natural H 2 , suggesting research priorities, as a guide for defining exploration strategies, techniques, and data interpretation. The uncertainties concern all phases of the natural H 2 cycle, from generation (source rocks) through migration (advection and diffusion) and accumulation (reservoir and cap rocks) to the application and interpretation of subsurface and surface geochemical and geophysical exploration techniques. Understanding H 2 sources and generation rates (the amount of H 2 generated by a given volume of rock over time) is crucial for determining whether a geological H 2 system operates as a short-term dynamic system with rapid H 2 production and release, or as a conventional gas system with long-term accumulations, analogous to petroleum reservoirs. Preliminary estimates for serpentinisation, radiolysis, and organic matter degradation suggest that H 2 generation is not inherently fast, especially for non-hydrothermal continental systems (crystalline basement of shields, ophiolites, peridotite massifs, sedimentary basins), and long-term accumulations, like those of fossil natural gas systems, represent the most likely scenario. The mechanisms of H 2 migration through geological formations require application of fundamental principles of fluid-flow physics, distinguishing advection and diffusion, as well as their forms (from gas-phase, bubble flows to aqueous solutions). Additional studies of H 2 accumulation and retention in subsurface reservoirs could improve understanding of mechanisms of H 2 migration by focusing on the rock fluid-bearing properties and the factors affecting H 2 preservation, such as the presence of cap rocks impermeable to H 2 , pressure conditions, residence times, and microbial or abiotic consumption. Advanced techniques, including reservoir modelling, flow simulations, 3D imaging (micro-CT) of H 2 -bearing rocks, and extraction and analysis of gas occluded in rocks, can provide insights into the stability and potential recoverability of H 2 accumulations. The interpretation of surface exploration techniques, including gas geochemistry, geophysics, and remote sensing, long employed in mineral and energy resource exploration, is now being adapted for natural H 2 studies, but challenges remain in the data interpretation. Distinguishing H 2 seepage due to geological degassing from H 2 produced near the surface by modern microbial processes or artificial sources, such as hammering or drilling for soil-gas sampling, drilling into aquifers, and corrosion in boreholes, is an essential step in exploration. The simple detection of H 2 in soils, even in morphological structures like sub-circular depressions or “fairy circles”, cannot be cursorily interpreted as a signal of natural H 2 seepage from a deep source. A holistic geochemical approach, including isotopic analyses of gases associated with H 2 , is recommended to distinguish among the variety of possible H 2 origins. Observations of H 2 in wells should be interrogated to rule out possible artifacts such as corrosion and drill bit metamorphism. The integration of multiple geophysical methods, including seismic, gravimetric, magnetic, and electro-magnetic surveys, is recommended to mitigate interpretation ambiguities regarding the structure of a subsurface H 2 system (source and reservoir rocks, including fluid and gas storage), due to the non-uniqueness of rock-specific physical properties.

Earth-Science Reviews

Linear solvation energy relationships for toxicity of selected organic chemicals to Daphnia pulex and Daphnia magna

In the Laurentian Great Lakes, more than 300 contaminants have been identified in fish, other biota, water, and sediment. Current hazard assessment of these chemicals by the National Fisheries Research Center-Great Lakes is based on their toxicity, occurrence in the environment, and source. Although scientists at the Center have tested over 70 chemicals with the crustacean Daphnia pulex , the number of experimental data needed to screen the huge array of chemicals in the Great Lakes exceeds the practical capabilities of conducting bioassays. This limitation can be partly circumvented, however, by using mathematical models based on quantitative structure-activity relationships (QSAR) to provide rapid, inexpensive estimates of toxicity. Many properties of chemicals, including toxicity, bioaccumulation and water solubility are well correlated and can be predicted by equations of the generalized linear solvation energy relationships (LSER). The equation we used to model solute toxicity is Toxicity = constant + m VI/100 + s (π* + dδ) + b βm + a αm where VI = intrinsic (Van der Waals) molar volume; π* = molecular dipolarity/polarizability; δ = polarizability 'correction term'; βm = solute hydrogen bond acceptor basicity; and αm = solute hydrogen bond donor acidity. The subscript m designates solute monomer values for α and β. We applied the LSER model to 48-h acute toxicity data (measured as immobilization) for six classes of chemicals detected in Great Lakes fish. The following regression was obtained for Daphnia pulex (concentration = μM): log EC50 = 4.86 - 4.35 VI/100; N = 38, r2 = 0.867, sd = 0.403 We also used the LSER modeling approach to analyze to a large published data set of 24-h acute toxicity for Daphnia magna ; the following regression resulted, for eight classes of compounds (concentration = mM): log EC50 = 3.88 - 4.52 VI/100 - 1.62 π* + 1.66 βm - 0.916 αm; N = 62, r2 = 0.859, sd = 0.375 In addition we developed computer software that identifies chemical structures, estimates the LSER parameters, and predicts toxicity. The LSER models promise to be effective in differentiating between reactive and nonreactive toxicity behavior where other models have failed. Contaminants with reactive behavior are generally the most toxic and rank highest in hazard assessment of environmental chemicals.

Proceedings of the QSAR

The Loma Prieta, California, Earthquake of October 17, 1989: Main shock characteristics

The October 17, 1989, Loma Prieta, Calif., earthquake (0004:15.2 G.m.t. October 18; lat 37.036º N., long 121.883º W.; 19-km depth) had a local magnitude (M L ) of about 6.7, a surface-wave magnitude (M S ) of 7.1, a seismic moment of 2.2x10 19 N-m to 3.5x10 19 N-m, a source duration of 6 to 15 s, and an average stress drop of at least 50 bars. Slip occurred on a dipping fault surface about 35 km long and was largely confined to a depth of about 7 to 20 km. The slip vector had a large vertical component, and slip was distributed in two main regions situated northwest and southeast of the hypocenter. This slip distribution caused about half of the earthquake's energy to be focused toward the urbanized San Francisco Bay region, while the other half was focused toward the southeast. Had the rupture initiated at the southeast end of the aftershock zone, shaking in the bay region would have been both longer and stronger. These source parameters suggest that the earthquake was not a typical shallow San Andreas-type event but a deeper event on a different fault with a recurrence interval of many hundreds of years. Therefore, the potential for a damaging shallow event on the San Andreas fault in the Santa Cruz Mountains may still exist.

California

Constraints on eruption processes and event masses for the 2016–2017 eruption of Bogoslof volcano, Alaska, through evaluation of IASI satellite SO2 masses and complementary datasets

Bogoslof volcano, Alaska, experienced at least 70 explosive eruptions between 12 December 2016 and 31 August 2017. Due to its remote location and limited local monitoring network, this eruption was monitored and characterized primarily using remote geophysical and satellite techniques. SO 2 emissions from Bogoslof were persistently detected by the Infrared Atmospheric Sounding Interferometer (IASI) satellite sensors. Of Bogoslof’s 70 explosive events, 50% produced measurable SO 2 masses ranging from 0.1 to 21.5 kt, with a median and standard deviation of 0.7 ± 4.0 kt SO 2 , respectively. Here, we compare IASI-derived SO 2 masses from Bogoslof events to complementary geophysical datasets to provide insights into eruption source processes, namely the degree of seawater scrubbing of water-soluble SO 2 and variations in magma flux. Correlations with the number of lightning strokes and infrasound energy are expected to indicate magma-flux as a controlling process, while correlations with infrasound frequency index are expected to indicate variations in vent-water content as a controlling factor. These comparisons suggest that the measured SO 2 masses are primarily a function of eruption magnitude (degassed magma mass) and that scrubbing of SO 2 emissions by vent seawater may have exerted a minor effect on the observed SO 2 masses. SO 2 masses were combined with petrologic constraints on melt inclusion and matrix glass S concentrations to calculate degassed magma masses and volumes. The cumulative SO 2 -derived degassed magma mass and estimated volume (dense-rock equivalent) for the full Bogoslof eruption were found to be 2.8 × 10 10 kg and 9.3 × 10 6 m 3 , respectively. When individual event masses are compared against event masses calculated using an empirical plume-height method, a strong correlation is found ( R 2 = 0.83), with better than order-of-magnitude agreement in most cases. These estimates of eruption masses provide useful information on the magnitude, behavior, and associated hazards of the 2016–2017 eruption, and potentially future unrest at Bogoslof volcano.

Alaska

New activities at the U.S. Geological Survey

As the Nation's principal source of information about the configuration of the land surface, the composition and structure of the rocks at and beneath the surface, the distribution and character of its energy, mineral, and water resources, and the nature of natural geologic processes, the U. S. Geological Survey focuses its work on some of the Nation's most critical problems. As the Survey tackles new problems with new techniques, it is fully aware of the resource needs and environmental pressures of an expanding economy and growing population.

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