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286 records · Page 16Linked to original sources
USGS1958

Geology and ore deposits of the Monument Valley area, Apache and Navajo counties, Arizona: Part II

In 1951 and 1952, the U.S. Geological Survey conducted a program of uranium investigations and geologic mapping in the Monument Valley area, Apache and Navajo Counties, Ariz. About 700 square miles were mapped on the Navajo Indian Reservation. A resource appraisal of the area was an inherent part of the program, and is detailed in this report. Production of vanadium and uranium is from two areas, the Monument No. 1 mine area in Navajo County, and the Monument No. 2 mine area in Apache County. In the period 1942-53 about 200,300 tons of ore was produced from these two areas. This ore yielded about 1,700,000 pounds of U 3 O 8 and about 6,500,000 pounds of V 2 O 5 . The grade ranged from 0.15 percent U 3 O 8 to 0.60 percent U 3 O 8 , and from 0.38 percent V 2 O 5 to 3.02 percent V 2 O 5 . The vanadium-uranium ratio is about 4:1. The ore deposits are composed principally of the hydrous calcium-uranium vanadate tyuyamunite in basal channel sediments of the Shinarump member off the Chinle formation. Four types of ore bodies are present: (1) rods, (2) tabular ore bodies, (3) corvusite-type ore bodies, and (4) rolls. The reserves of uranium- and vanadium-bearing material are classed as measured, indicated, inferred, and potential. The reserves are further divided into three grade classes for material 1 foot or more thick: (1) 0.10 percent U 3 O 8 and 1.00 percent V 2 O 5 and above; (2) 0.05 percent U 3 O 8 and 0.50 percent V 2 O 5 and less than 0.10 percent U 3 O 8 and 1.00 percent V 2 O 5 ; and (3) 0.01 percent U 3 O 8 and 0.10 percent V 2 O 5 and less than 0.05 percent U 3 O 8 and 0.05 percent V 2 O 5 . Measured reserves as of June 1953, in the Monument Valley area, Arizona, (all in the Monument No. 2 mine) total about 36,000 tons. Indicated reserves in the first grade class amount to about 62,000 tons. In this same grade class inferred reserves total about 3,000,000 tons. In the second grade class indicated and inferred reserves amount to about 2,000,000 tons. Inferred reserves in the third grade class total about 345,000 tons of mineralized material. Potential reserves in all grade classes for the Monument Valley area amount to about 13,000,000 tons. It is recommended that an extensive exploration program be carried out in the Monument Valley area, Arizona. This program would consist of two phases. The first phase would involve a geophysical survey of selected channels and would have at its principal objective the delineation of the trend, length, width, and depth of scour of the channels. The second phase would consist of a diamond-drilling program that would make use of the data secured by the geophysical survey. This drilling program would have as one of its principal objectives the determination of which channels are most likely to contain ore bodies. Once the favorable channels are discovered, the drilling program could be carried on most suitably by private operators.

Arizona↗
USGS2012

Magmatic ore deposits in layered intrusions - Descriptive model for reef-type PGE and contact-type Cu-Ni-PGE deposits

Layered, ultramafic to mafic intrusions are uncommon in the geologic record, but host magmatic ore deposits containing most of the world's economic concentrations of platinum-group elements (PGE) (figs. 1 and 2). These deposits are mined primarily for their platinum, palladium, and rhodium contents (table 1). Magmatic ore deposits are derived from accumulations of crystals of metallic oxides, or immiscible sulfide, or oxide liquids that formed during the cooling and crystallization of magma, typically with mafic to ultramafic compositions. "PGE reefs" are stratabound PGE-enriched lode mineralization in mafic to ultramafic layered intrusions. The term "reef" is derived from Australian and South African literature for this style of mineralization and used to refer to (1) the rock layer that is mineralized and has distinctive texture or mineralogy (Naldrett, 2004), or (2) the PGE-enriched sulfide mineralization that occurs within the rock layer. For example, Viljoen (1999) broadly defined the Merensky Reef as "a mineralized zone within or closely associated with an unconformity surface in the ultramafic cumulate at the base of the Merensky Cyclic Unit." In this report, we will use the term PGE reef to refer to the PGE-enriched mineralization, not the host rock layer. Within a layered igneous intrusion, reef-type mineralization is laterally persistent along strike, extending for the length of the intrusion, typically tens to hundreds of kilometers. However, the mineralized interval is thin, generally centimeters to meters thick, relative to the stratigraphic thickness of layers in an intrusion that vary from hundreds to thousands of meters. PGE-enriched sulfide mineralization is also found near the contacts or margins of layered mafic to ultramafic intrusions (Iljina and Lee, 2005). This contact-type mineralization consists of disseminated to massive concentrations of iron-copper-nickel-PGE-enriched sulfide mineral concentrations in zones that can be tens to hundreds of meters thick. The modes and textures of the igneous rocks hosting the mineralization vary irregularly on the scale of centimeters to meters; autoliths and xenoliths are common. Mineralization occurs in the igneous intrusion and in the surrounding country rocks. Mineralization can be preferentially localized along contact with country rocks that are enriched in sulfur-, iron-, or CO2-bearing lithologies. Reef-type and contact-type deposits, in particular those in the Bushveld Complex, South Africa, are the world's primary source of platinum and rhodium (tables 2 and 3; fig. 2). Reef-type PGE deposits are mined only in the Bushveld Complex (Merensky Reef and UG2), the Stillwater Complex (J-M Reef), and the Great Dyke (Main Sulphide Layer). PGE-enriched contact-type deposits are only mined in the Bushveld Complex. The other deposits in tables 2 and 3 are undeveloped; some are still under exploration.

Open-File Report↗
USGS1982

Assessment of the petroleum, coal, and geothermal resources of the Economic Community of West African States (ECOWAS) region

Approximately 85 percent of the land area of the ECOWAS (Economic Community of West African States) region is covered by basement rocks (igneous and highly metamorphosed rocks) or relatively thin layers of Paleozoic, Upper Precambrian, and 'Continental Intercalaire? sedimentary rocks. These areas have little or no petroleum potential. Areas of the ECOWAS region that have potential for petroleum production or potential for increased petroleum production include the narrow belt of sedimentary rocks that stretches along the continental margin from Mauritania to Nigeria and the Niger Delta and the Benue depression. The Senegal Basin, located on the continental margin of Mauritania, Senegal, Gambia, Guinea Bissau, and Guinea, has been intensely explored by the oil industry and most of the larger structures onshore and on the shelf probably have been tested by drilling with little or no resulting commercial production. Unless basic ideas pertaining to the petroleum geology of the Senegal Basin are revised, future discoveries are expected to be limited to small fields overlooked by industry at a time when petroleum prices were low. On the continental shelf of Sierra Leone and the continental shelf of northeast and central Liberia, the sedimentary rocks are relatively thin, and industry has shown little interest in the area. On the continental rise of these countries, however, the sedimentary section, deposited in a complex fault-block system, increases in thickness. A renewal of industry interest in this deep-water area will probably follow further development of deep-water production technology. A recent oil discovery on the continental slope off the Ivory Coast is expected to spur further exploration offshore of southeastern Liberia, Ivory Coast, Ghana, Togo, and Benin. This relatively unexplored area in the Gulf of Guinea has good possibilities .for the discovery of giant oil fields. Nigeria's oil development from the Niger Delta may have peaked, as 13 of 14 giant oil fields were discovered prior to 1969 and the greatest number of fields were discovered in the period 1965 through 1967. Like delta regions in other parts of the world, individual oil fields of the Niger Delta are small to medium by world standards and future discoveries, therefore, are likely to reflect this reality. The natural gas resources of the Niger Delta, unlike its oil resources, are comparatively underdeveloped. Parts of the Benue depression in Nigeria and Niger could contain significant deposits of petroleum. The lower Benue depression, immediately north of the Niger Delta, has been extensively explored by drilling. Except for noncommercial discoveries of oil and gas and traces of oil and gas on the ground surface, the results of exploration in the lower Benue depression were negative. However, in the Lake Chad area of Chad and in southern Chad near the Central African Republic boundary, oil and gas discoveries were made just prior to the cessation of all drilling and exploration activity in early 1979. It is rumored that these discoveries may be large although little information is available. The relation between the two areas in Chad and their overall relation to the Benue depression is poorly understood; however, the possibility of thick sedimentary sections containing Cretaceous marine source rock and Tertiary reservoir beds-all contained within grabens in a highly faulted failed-arm system subjected to high heat flow--is attractive. Of the ECOWAS countries, only Nigeria and Niger produce coal commercially. Nigeria produces subbituminous coal from Paleocene-Maestrichtian and Maestrichtian (Late Cretaceous) age rocks of the Niger Delta region; reserves are estimated, on the basis of extensive drilling, to be 350 million tons (standard coal equivalent). In addition, lignite deposits of the Niger Delta appear to be large but have not been developed. Niger produces small amounts of coal used locally by uranium mine and mill operations from C

Open-File Report↗
USGS2013

Porphyry copper assessment of Europe, exclusive of the Fennoscandian Shield: Chapter K in Global mineral resource assessment

The U.S. Geological Survey (USGS) collaborated with European geologists to assess resources in porphyry copper deposits in Europe, exclusive of Scandinavia (Sweden, Denmark, Norway, and Finland) and Russia. Porphyry copper deposits in Europe are Paleozoic and Late Cretaceous to Miocene in age. A number of the 31 known Phanerozoic deposits contain more than 1 million metric tons of contained copper, including the Majdanpek deposit, Serbia; Assarel, Bulgaria; Skouries, Greece; and Rosia Poeni, Romania. Five geographic areas were delineated as permissive tracts for post-Paleozoic porphyry copper deposits. Two additional tracts were delineated to show the extent of permissive igneous rocks associated with porphyry copper mineralization related to the Paleozoic Caledonian and Variscan orogenies. The tracts are based on mapped and inferred subsurface distributions of igneous rocks of specific age ranges that define areas where the occurrence of porphyry copper deposits within 1 kilometer of the Earth’s surface is possible. These tracts range in area from about 4,000 to 93,000 square kilometers. Although maps at a variety of different scales were used in the assessment, the final tract boundaries are intended for use at a scale of 1:1,000,000. The post-Paleozoic deposits in Europe all formed in conjunction with the tectonic evolution of southern Europe as the former Tethyan Ocean closed by convergence of the African and Arabian Plates with Europe, accompanied by accretion of microcontinents to the southern Eurasian Plate and development and demise of magmatic arcs and ocean basins. Many of the deposits formed in extensional or post-collisional settings; these tectonic environments are increasingly being recognized as environments where porphyry copper deposits occur. Probabilistic estimates of undiscovered porphyry copper deposits were made for four Phanerozoic permissive tracts; the other tracts are discussed qualitatively. Assessment participants estimated numbers of undiscovered deposits at different levels of confidence for the four tracts. These estimates were then combined with grade and tonnage models using Monte Carlo simulation to generate probabilistic estimates of amounts of in-place undiscovered resources. Additional resources that may be present in extensions of known deposits were not evaluated. Assessment results are reported in tables and graphs as expected amounts of metal and rock in undiscovered deposits at different quantile levels, as well as the arithmetic mean for each commodity for each tract. This assessment estimated a mean of 14 undiscovered porphyry copper deposits within the four permissive tracts for which estimates were made. On the basis of global grade and tonnage models, mean (arithmetic) estimated resources that could be associated with undiscovered deposits are about 46 million metric tons of copper and about 2,600 metric tons of gold, as well as byproduct molybdenum and silver. Reliable reported identified resources for the 27 deposits in the assessed areas total about 44 million metric tons of copper and about 2,300 metric tons of gold. Exploration for gold-rich porphyry systems is ongoing in some parts of historical copper mining districts in central Europe and in northwesternmost (European) Turkey. Political and social conflicts, environmental concerns associated with historical mining, and the global economic situation have had negative effects on exploration, development, and mining in Europe for many years. The assessment includes an overview with summary tables. Detailed descriptions of each tract, including the rationales for delineation and assessment, are given in appendixes A–G. Appendix H describes a geographic information system (GIS) that includes tract boundaries and point locations of known porphyry copper deposits and significant prospects.

Scientific Investigations Report↗
USGS2007

Geology and Mineral Resources of the East Mojave National Scenic Area, San Bernardino County, California

From our evaluations that largely used model-based criteria, we conclude that much of the East Mojave National Scenic Area (EMNSA) contains significant indications of epigenetic mineralization of various types. Economically significant concentrations of many metals may possibly remain to be discovered in many parts of the EMNSA (see also Wetzel and others, 1992). We have discussed specific types of metallic deposits that are known to be present in the EMNSA. Some mountain ranges that have widespread occurrences are the Providence Mountains, Clark Mountain Range, Ivanpah Mountains, and New York Mountains; the area of Hackberry Mountain is included in a tract that is judged to be favorable for the discovery of epithermal, volcanic-hosted gold deposits (pl. 2). These ranges make up a broad, roughly north-south-trending region in the central part of the EMNSA. Much less endowed with known occurrences of all of the various types of deposits considered above are the Granite Mountains, the central parts of the Piute Range, the Fenner Valley area, the general area of Cima Dome, the Cima volcanic field, and areas west to Soda Lake. We have attempted to make some judgments concerning the gravel-covered areas in the EMNSA (pl. 3), including the areal extent of bedrock apparently covered only by thin veneers of gravel. But few data are available to us for the overwhelming bulk of the covered areas. The presence of any mineralization, the type of mineralization, and the extent and intensity of mineralization in the covered areas is essentially unknown. The likelihood is high, however, that those areas in the EMNSA covered only by a thin cap of gravels could host mineralization similar to that known in the adjoining mountain ranges. Most buried epigenetic-mineral deposits do not respond to standard geophysical methods, particularly at the coarse spacing of the data-collection points available for our evaluation. Restricting judgments concerning the presence of undiscovered metal resources in the EMNSA only to currently known types of deposits and to regionally representative tonnages for such deposits would undoubtedly yield small estimates for volumes of many metals that might be exploited. Metals from most newly discovered, base- and ferrous-metal deposits of the types presently known in the EMNSA probably would be insignificant from the standpoint of national needs. For example, copper from a newly discovered skarn deposit in the EMNSA would have roughly a 25 percent chance of being in excess of approximately 10,000 tonnes contained Cu, if the grade-and-tonnage distribution curves of Jones and Menzie (1986b) for copper skarns are applicable to copper skarn in the EMNSA. Most copper in the United States is produced in the Southwest from much larger open-pit operations than those associated with the typical copper skarn; the former operations exploit large-tonnage porphyry-type systems. Historically, the EMNSA has been the site of minor production of many metals from a large number of sites. Since 1985, however, a small number of sites in the EMNSA whose gold production and reserves are much greater than that of the preceding discoveries have been developed (see U.S. Bureau of Mines, 1990a). Nonetheless, widespread distribution of numerous types of deposits (including copper skarn, lead-zinc skarn, tin-tungsten skarn, polymetallic vein, gold-silver quartz-pyrite vein, low-fluorine porphyry molybdenum, gold breccia pipe, and volcanic-hosted gold) that are petrogenetically associated with igneous rock in many parts of the EMNSA is indicative of a metallogenic environment that may be the site of future discoveries of mineral-deposit types that are not now recognized by the exploration community. The science, art, and, yes, even luck of exploration procedures continually evolve, and this evolution is one of the most important aspects of currently employed methods of exploration (Bailly, 1981; Hutchinson and Grauch, 1991).

Miscellaneous Field Studies Map↗
USGS1959

Geology of the Lake Mary quadrangle, Iron County, Michigan

The Lake Mary quadrangle is in eastern Iron County, in the west part of the Upper Peninsula of Michigan. The quadrangle is underlain by Lower and Middle Precambrian rocks, formerly designated Archean and Algonkian rocks, and is extensively covered by Pleistocene glacial deposits. A few Upper Precambrian (Keweenawan) diabase dikes and two remnants of sandstone and dolomite of early Paleozoic age are also found in the area. The major structural feature is the Holmes Lake anticline, the axis of which strikes northwest through the northeast part of the quadrangle. Most of the quadrangle, therefore, is underlain by rock of the west limb of the anticline. To the northwest along the fold axis, the Holmes Lake anticline is separated from the Amasa oval by a saddle of transverse folds in the vicinity of Michigamme Mountain in the Kiernan quadrangle. The Lower Precambrian rocks are represented by the Dickinson group and by porphyritic red granite whose relation to the Dickinson group is uncertain, but which may be older. The rocks of the Dickinson group are chiefly green to black metavolcanic schist and red felsite, some of the latter metarhyolite. The dark schist is commonly magnetic. The Dickinson group underlies the core area of the Holmes Lake anticline, which is flanked by steeply dipping Middle Precambrian formations of the Animikie series. A major unconformity separates the Lower Precambrian rocks from the overlying Middle Precambrian rocks. In ascending order the formations of the Middle Precambrian are the Randville dolomite, the Hemlock formation, which includes the Mansfield iron-bearing slate member, and the Michigamme slate. An unconformity occurs between the Hemlock formation and Michigamme slate. The post-Hemlock unconformity is thought to be represented in the Lake Mary quadrangle by the absence of iron-formation of the Amasa formation, which is known to lie between the Hemlock and the Michigamme to the northwest of the Lake Mary quadrangle in the Crystal Falls quadrangle. Post-Hemlock erosion may account also for the absence of iron-formation of the Fence River formation on the east limb of the Holmes Lake anticline within the Lake Mary quadrangle. The Randville dolomite is not exposed and is known only from diamond drilling in the northeast part of the area where it occurs in the east and west limbs of the Holmes Lake anticline. The formation has a maximum thickness of about 2,100 feet; this includes a lower arkosic phase, some of which is quartz pebble conglomerate, a medial dolomitic phase, and an upper slate phase. The triad is gradational. Included within the formation are a few beds of chloritic schist thought to be of volcanic origin. An unconformity between the Randville and the succeeding Hemlock is not indicated in the quadrangle, but is probably present. The Hemlock formation is best exposed in the northwest and south-central parts of the area. The apparent thickness of the formation is 10,000- 17,000 feet. It is composed mainly of mafic metavolcanic rocks and intercalated slate and iron-formation. In the north part of the quadrangle the volcanic rocks are greenstone, which includes altered basaltic flow rocks, volcanic breccia, tuff, and slate. Pillow structures are common in the metabasalt. It is not certain if any Hemlock rocks are present in the east limb of the Holmes Lake anticline. In the south part of the quadrangle, the rocks of the Hemlock are chiefly chlorite and hornblende schist and hornfels. Pyroxene hornfels is sparingly present. At least two sedimentary slate belts are included in the Hemlock formation. One of these, the Mansfield iron-bearing slate member, includes in its upper part an altered chert-siderite iron-formation 30 to over 150 feet thick from which iron ore has been mined at the Mansfield location. The position of the iron-bearing rocks has been determined magnetically, and past explorations for iron ore are discussed. Though probably; unconformable, the contact between the Hemlock and the Michigamme formations appears conformable. The Michigamme slate consists of at least 4,000 feet of interbedded mica schist and granulite, the altered equivalents of the slate and graywacke characteristic of the Michigamme in adjacent areas. The Michigamme rocks are best exposed in the south part of the quadrangle in the vicinity of Peavy Pond. Two periods of regional metamorphism have resulted in the alteration of almost all of the rocks of the quadrangle. The Lower Precambrian rocks underwent at least one period of metamorphism, uplift, and erosion before the deposition of the Randville dolomite. After the deposition of the Michigamme slate, a post-Middle Precambrian period of regional metamorphism occurred with attending deformation and igneous intrusion. The grade of metamorphism rises toward the south in the area. The rocks in the northern two-thirds of the quadrangle are representative of greenschist facies of regional metamorphism, whereas the rocks in the southern onethird of the quadrangle are representative of the albite-epidote-amphibolite, the amphibolite, and the pyroxene hornfels facies, the metamorphic node centering about the intrusive Peavy Pond complex in the Peavy Pond area. The Precambrian sedimentary and volcanic rocks are cut by intrusive igneous rocks of different types and several different ages. Gabbroic sills and dikes invaded the Hemlock rocks at some time after the Hemlock was deposited and before the post-Middle Precambrian orogeny and metamorphism. Some contact metamorphism attended the intrusion of the major sills. One of the sills, the West Kiernan sill, is well differentiated. A syntectonic igneous body, composed of gabbro and minor ultramafic parts and fringed with intermediate and felsic differentiates and hybrids, the Peavy; Pond complex, was intruded into the Hemlock and Michigamme formations during the post-Middle Precambrian orogeny. The complex is situated in the Peavy Pond area at the crest of the regional metamorphic node. Contact-altered sedimentary and volcanic rocks margin the complex. The effects of regional metamorphism have been superposed on the contact metamorphic rocks peripheral to the complex and on the igneous rocks of the complex as well. The mafic augite-bearing rocks of the complex emplaced early in the orogeny were deformed by granulation at the peak of the deformation and subsequently metamorphosed to hornblende rocks. Some of the intermediate and felsic rocks of the complex were foliated by the deformation, while the more fluid, felsic parts of the complex were intruded under orogenic stress and crystallized after the peak of deformation. The deformation culminated in major faulting during which the formations were dislocated, and some of the granite of the complex was extremely brecciated. A few diabase dikes, probably of Keweenawan age, have intruded the deformed and altered Animikie rocks. The only known metallic resource is iron ore. The Mansfield mine produced 1¥2 million tons of high-grade iron ore between the years 1890 and 1913. Sporadic exploration since 1913 has failed to reveal other ore deposits of economic importance.

Michigan↗
USGS2017

Fluorine

Fluorine compounds are essential in numerous chemical and manufacturing processes. Fluorspar is the commercial name for fluorite (isometric CaF 2 ), which is the only fluorine mineral that is mined on a large scale. Fluorspar is used directly as a fluxing material and as an additive in different manufacturing processes. It is the source of fluorine in the production of hydrogen fluoride or hydrofluoric acid, which is used as the feedstock for numerous organic and inorganic chemical compounds. The United States was the world’s leading producer of fluorspar until the mid-1950s. In the mid-1970s, the U.S. fluorspar mining industry began to decline because of foreign competition. By 1982, there was essentially only a single U.S. producer left, and that company ceased mining in 1996. Consumption of fluorspar in the United States peaked in the early 1970s, which was also the peak period of U.S. steel production. Since then, U.S. fluorspar consumption has decreased substantially; the United States has nonetheless increased its imports of downstream fluorine compounds, such as, in order of tonnage imported, hydrofluoric acid, aluminum fluoride, and cryolite. This combination of no U.S. production (until recently) and high levels of consumption has made the United States the world’s leading fluorspar-importing country, in all its various forms. The number of fluorspar-exporting countries has decreased substantially in recent decades, and, as a result, the United States has become dependent on just a few countries to supply its needs. In 2013, the United States imported the majority of its fluorspar from three countries, which were, in descending order of the amount imported, Mexico, China, and South Africa. Geologically, in igneous systems, fluorine is one of a number of elements that are “incompatible.” These incompatible elements become concentrated in the residual magma while the common silicates crystallize upon magma ascent and cooling, leading to relatively high fluorine concentrations in the more evolved or differentiated igneous rocks and in hydrothermal deposits associated with those evolved igneous rocks. In sedimentary rocks, fluorine’s highest concentrations are found in phosphorites because fluorine substitutes for hydroxyl ions in apatite, which leads to fluorine concentrations of, typically, from 2 to 4 weight percent in phosphorites. Because of the presence of fluorine, phosphate fertilizer manufacturers can produce a fluorosilicic acid byproduct. Most deposits mined for fluorine are hydrothermal, however, and consist of fluorine minerals that precipitated from hot water. Magmatic brines and brines from deep within sedimentary basins that have high concentrations of dissolved fluoride are the mineralizing fluids for various types of hydrothermal fluorspar deposits. Relatively dilute hydrothermal fluids that formed in some volcanic rocks can also transport sufficient fluoride to form a high-grade fluorspar deposit. Fluorite has low solubility in a common range of hydrothermal temperatures, particularly from about 160 degrees Celsius (°C) down to 60 °C. The increasing fluorite solubility below 60 °C partly explains why some water with exceptionally high levels of dissolved fluorine are found even at ambient temperatures in evaporitic lake basins in some East African Rift valleys in Kenya and Tanzania. The geologic conditions that led to the high concentrations there are known to exist in a number of other places in the world as well, including, perhaps, places in the Basin and Range province of the United States. Eight minerals or mineral groups have sufficient fluorine in their structures to be considered as possible ores of the element; they are bastnaesite (also spelled bastnäsite; and other fluorocarbonates), cryolite, sellaite, villiaumite, fluorite, fluorapatite (in phosphorites), various phyllosilicates, and topaz. Fluorite is currently the only mineral that is mined for fluorine, and nomineral except fluorite is likely to become a source of commercially produced fluorine as a primary product as long as supplies from relatively thick and high-grade fluorite deposits continue to be available. At least seven classes (which include one subclass) of hydrothermal fluorite deposits are recognized; they are classified according to their tectonic and (or) magmatic settings, as follows: (1) carbonatite-related fluorspar deposits; (2) alkaline-intrusion-related fluorspar deposits; (3) alkaline-volcanic-related epithermal fluorspar deposits; (4) Mississippi Valley-type fluorspar deposits (and a subclass of salt-related carbonate-hosted fluorspar deposits); (5) fluorspar deposits related to strongly differentiated granites; (6) subalkaline-volcanic-related epithermal fluospar deposits; and (7) fluorspar deposits that appear to be conformable within tuffaceous limy lacustrine sediments. An eighth class (not hydrothermal) is that of fluorspar deposits concentrated in soils and weathered zones; that is, residual fluorspar deposits. Generally, fluorspar deposits related to strongly differentiated granites have larger tonnages and lower grades than carbonatite-related fluorspar deposits, which, in turn, have larger tonnages and lower grades than fluorspar vein deposits from various other classes. The United States has a few identified resources of fluorspar, most notably the Klondike II property in the Illinois- Kentucky fluorspar district located about 8 kilometers southwest of Salem, Kentucky, which has a large vein that contains at least 1.6 million metric tons at a grade of 60 percent CaF 2 (Feytis, 2009). Additional fluorspar resources of lower grade but larger tonnage have been identified at Hicks Dome in the Illinois-Kentucky fluorspar district and at Lost River near the western tip of the Seward Peninsula in Alaska, along with a couple of dozen smaller, higher grade resources. Internationally, new mines that either opened before the beginning of 2013 or were scheduled to open soon after that time include the Nui Phao tungsten-fluorspar-bismuth-copper-gold deposit in northern Vietnam; the St. Lawrence project in Newfoundland, Canada, which is located in a well-known fluorspar district; the Bamianshan deposit, which is related to a strongly differentiated granite in northwestern Zhejiang Province, China, near some of that Province’s large, subalkaline-volcanic-related epithermal veins; and the Nokeng project in South Africa, which is also related to a strongly differentiated granite. Other deposits in northwestern Australia, Nevada (United States), Norway, South Africa, and Sweden have been identified and could be put into production within just a few years. Among undiscovered resources, an interesting possibility might be to produce a fluorine product from evaporitic, high-fluorine, high-pH sodium-carbonate brines like Lake Magadi (Kenya) and Lake Natron (Tanzania) in Africa’s Eastern Rift Valley. In addition, apparently conformable fluorspar deposits in tuffaceous limy lacustrine sediments, such as those in Italy, are likely to occur in similar young alkalic volcanic settings elsewhere in the world. Modern geophysical and geochemical exploration techniques have typically not been brought to bear in exploration for new fluorspar deposits, although such techniques are likely to be used in future exploration. The tendency for fluorine to dissolve in significant concentrations in water at low temperature allows both surface water and groundwater to be used as sampling media in geochemical exploration. Evolved granite-related fluorspar deposits may be particularly susceptible to geophysical exploration methods because crystalline rocks that form a basement to sedimentary sections can be approximately defined with gravity and magnetic methods, and magnetite-bearing skarns can be directly detected with magnetic surveys. Environmental considerations of fluorine mining focus especially on drinking water, where high fluorine concentrations can lead to tooth decay; dental and skeletal fluorosis; and bone and cartilage conditions, including genu valgum, which is the crippling bone deformity more commonly known as knock knee. Trace amounts of other elements in fluorspar ores are a concern at some deposits; for example, high beryllium concentrations in alkaline-volcanic-related epithermal deposits or high cadmium concentrations associated with Mississippi Valley-type and salt-related carbonate-hosted fluorspar deposits. Future research might include testing whether fluorine can be extracted economically from high-pH, sodium-carbonate brines and exploring for new occurrences of apparently conformable fluorspar deposits in tuffaceous limy lacustrine sediments outside of the Latium Region of Italy. Other promising new areas of research could be studies of fluorspar deposit fluid inclusion compositions by quadrupole mass spectrometry, by noble gas mass spectrometry on irradiated fluid inclusions, or by chlorine isotopes, while also measuring the chemistry of the same fluid inclusions either by bulk crush-and-leach methods or by laser ablation-inductively coupled plasma mass spectrometry. Advanced studies of fluid inclusion chemistry could be applied beneficially to some of the enigmatic large epithermal fluorspar veins at various places in the world, where they might determine those deposits’ possible relationships to igneous intrusions, or to dissolved salt, or to heated meteoric water in volcanic sections, or perhaps to all three. This knowledge could help focus new exploration.

Professional Paper↗
USGS2005

Geologic map of the Pinedale quadrangle, McKinley County, New Mexico

The 1:24,000-scale geologic map of the Pinedale 7.5' quadrangle lies in the western part of the Grants uranium mineral belt, which was mapped and studied under a cooperative agreement between the USGS and the U.S. Department of Energy. A spectacular panoramic view of the southern half of the Pinedale quadrangle is obtained looking northward from Interstate Highway 40, particularly from the New Mexico State travelers' rest stop near the Shell Oil Company's Ciniza Refinery, 28.5 kilometers (17.8 miles) east of Gallup. A west-trending escarpment, 200 meters high, of massive red sandstone, rises above a broad valley, its continuity broken only by a few deep and picturesque canyons in the western half of the quadrangle. The escarpment is formed by the eolian Entrada Sandstone of Late Jurassic age. The Entrada unconformably overlies the Chinle Formation of Late Triassic age, which occupies the valley below. The Chinle Formation consists of cherty mottled limestone and mudstone of the Owl Rock Member and underlying, poorly consolidated, red to purple fluvial siltstone, mudstone, and sandstone beds of the Petrified Forest Member. The pinyon- and juniper-covered bench that tops the escarpment is underlain by the Todilto Limestone. A quarry operation, located just north of the Indian community of Iyanbito in the southwestern part of the quadrangle, produces crushed limestone aggregate for highway construction and railroad ballast. Beyond the escarpment to the north and rising prominently above it, is the northwest-trending Fallen Timber Ridge. Near the west side of the quadrangle lie the peaks of Midget Mesa, and Mesa Butte, the latter of which has the highest altitude in the area at 2,635 meters (8,030 feet) above sea level. The prominences are capped by buff-colored resistant beds of the Dakota Sandstone of Late Cretaceous age, containing some interbedded coal. These beds unconformably overlie the uranium-bearing Morrison Formation, which consists of red, green, and gray shale, orange feldspathic sandstone, and green tuffaceous mudstone, deposited in ancient lakes, alluvial fans, and rivers during the Upper Jurassic Period. Thick, crossbedded, white beds of the Cow Springs Sandstone, derived from ancient windblown desert sands, underlie the Morrison. In the northern part of the quadrangle, the Dakota Sandstone is overlain by gray Mancos Shale and yellowish-gray Two Wells and Gallup Sandstones that were deposited in Late Cretaceous seas. Unconsolidated deposits of Quaternary age are found throughout the quadrangle in talus, slope wash, fans, valley alluviums, pediments, and as windblown sands in dunes and blanket deposits. The strata conform to the regional dip of about three degrees to north, except where they are down-folded some 200 meters along the Pinedale monocline, whose limbs follow a sinuous west-northwest trend across the northern half of the quadrangle. The monocline is beautifully exposed at Pinedale, where it shows as much as 20 degrees dip on the pine-studded bare rock slope of the Two Wells Sandstone. A north-plunging broad anticline and accompanying syncline is developed in the east-central part of the quadrangle but dies out against the monocline. A minor fault, with barely 3 meters of vertical displacement, extends several kilometers westward across the Todilto Limestone bench. A large landslide mass, 1.5 kilometers long by 0.7 kilometers wide occurs in the Mancos Shale west of Pinedale. Exploration drilling for uranium in the Morrison Formation has been extensive in the quadrangle, particularly north of the monocline, which adjoins the Old Church Rock mine area, west northwest of the quadrangle.

Miscellaneous Field Studies Map↗
USGS2014

Executive summary

Fossil fuels from the Appalachian basin region have been major contributors to the Nation’s energy needs over much of the last three centuries. Early records indicate that Appalachian coal was first mined in the middle 1700s (Virginia and Pennsylvania) and was used sparingly to fuel colonial settlements and, later, a fledgling industrial-based economy along the eastern seaboard of the United States (de Witt and Milici, 1989). In 2011, central Appalachian basin coal production accounted for approximately 77 percent of all U.S. metallurgical (or coking) coal and 29 percent of total U.S. production (U.S. Energy Information Administration, 2013). Following initial discoveries and commercial use in western New York (1821) and Ohio and West Virginia (mid-1830s), the Appalachian petroleum (oil and gas) industry began in earnest in 1859 with the discovery of oil at the Drake well in northwestern Pennsylvania. Between 1860 and 1989, the Appalachian basin produced more than 2.5 billion barrels of oil (BBO) and more than 30 trillion cubic feet of gas (TCFG) from more than 500,000 wells (de Witt and Milici, 1989). Although both oil and gas continue to be produced in the Appalachian basin, most new wells in the region are drilled in shale reservoirs to produce natural gas. Appalachian coal and petroleum resources are still available in sufficient quantities to contribute significantly to the Nation’s energy needs. For example, the U.S. Energy Information Administration (2010) estimated that there are 6,484 million short tons of recoverable coal reserves in the Appalachian basin. Similarly, about 14.7 billion barrels of oil equivalent (BBOE) (1.2 BBO+81 TCFG [or 13.5 BBOE]) of recoverable Appalachian basin oil and gas remain available of an estimated ultimate endowment of approximately 25.5 billion BBOE (cumulative production + reserves + estimated recoverable undiscovered resources) (this volume, chap. C.1). U.S. Geological Survey (USGS) Professional Paper 1708 is a modern, indepth collection of reports, cross sections, and maps that describe the geology of the Appalachian basin and its fossil fuel resources. Several of the chapters have been published in outside journals or as other USGS publications. Although this volume is not a comprehensive regional treatment of all notable geologic and fossil fuel localities in the Appalachian basin, the selected study areas and topics presented in the chapters cover large segments of the basin and a wide range of stratigraphic intervals. As the title implies, this volume addresses topics that refer to the locations of coal and petroleum accumulations, the stratigraphic and structural framework, and the geochemical characteristics of the coal beds and petroleum in the basin, as well as the results and documentation of recent USGS assessments of coal, oil, and gas resources in the basin. Many of the maps and accompanying data supporting the reports in this volume are available as downloadable geographic information system (GIS) data files (such as selected coal beds, selected oil and gas fields, locations of oil and gas wells, coal production, coal chemistry, total petroleum system (TPS) boundaries, and bedrock geology). Log ASCII Standard (LAS) files for geophysical (gamma ray) wireline well logs also are included. This publication supplements and updates older USGS regional studies of Appalachian basin coal and petroleum resources such as those by Arndt and others (1968) and the numerous contributors to USGS Miscellaneous Map Series I−917 (for example, Harris and others, 1978), respectively. USGS Professional Paper 1708 is intended primarily for geoscientists in academia, industry, and government who are interested in Appalachian basin geology and its coal and petroleum resources. Other users, however, may find the wide variety of topics, papers, and digital images of value for landuse and policy planning issues. Among the anticipated benefits of the report are improvements in (1) resource assessment estimates and methodology, (2) exploration strategies, (3) basin models, and (4) energy use policies.

Appalachian Basin↗
USGS2013

Porphyry copper assessment of Southeast Asia and Melanesia: Chapter D in Global mineral resource assessment

The U.S. Geological Survey collaborated with member countries of the Coordinating Committee for Geoscience Programmes in East and Southeast Asia (CCOP) on an assessment of the porphyry copper resources of Southeast Asia and Melanesia as part of a global mineral resource assessment. The region hosts world-class porphyry copper deposits and underexplored areas that are likely to contain undiscovered deposits. Examples of known porphyry copper deposits include Batu Hijau and Grasberg in Indonesia; Panguna, Frieda River, and Ok Tedi in Papua New Guinea; and Namosi in Fiji. This assessment covers the countries of Cambodia, Indonesia, Lao People&rsquo;s Democratic Republic, Malaysia, Myanmar, Papua New Guinea, Singapore, Thailand, and parts of southeastern China, India, the Solomon Islands, Vanuatu, and Fiji. Twenty-two geographic areas were delineated as tracts that are permissive for porphyry copper deposits in Southeast Asia. Permissive tracts are grouped into four broadly defined geographic/geologic areas, as follows: (1) the Indochina Peninsula area, (2) Indonesian and Malaysian Islands, (3) New Guinea Island and Papuan New Guinea islands, and (4) Melanesia. Individual tracts range from less than 1,000 to more than 350,000 square kilometers in area. Permissive tracts are based on mapped and inferred subsurface (<1 kilometer depth) distributions of igneous rocks of specific age ranges that define magmatic arcs and magmatic belts that are likely to contain porphyry copper deposits. Most of these magmatic arcs are subduction-related, although some have porphyry-style deposits occurring in postcollisional and (or) poorly understood tectonic settings. Although maps at a variety of different scales were used in the compilation, the final tract boundaries are intended for use at a scale of 1:1,000,000. Global grade and tonnage models for porphyry copper deposits were evaluated. Most of the known deposits are best described as fitting the copper-gold (Cu-Au) subtype of porphyry copper deposit. For some permissive tracts, a general porphyry copper-gold-molybdenum (Cu-Au-Mo) model was used. Assessment participants estimated numbers of undiscovered deposits at different levels of confidence for most of the permissive tracts. These estimates were combined with grade and tonnage models using a Monte Carlo simulation to estimate undiscovered resources. Additional resources in extensions of deposits with identified resources were not evaluated. Assessment results, presented in tables and graphs, show mean amounts of metal and mineralized rock in undiscovered deposits at different quantile levels, as well as the arithmetic mean for each tract. This assessment estimated a mean of 89 undiscovered porphyry copper deposits for the assessed permissive tracts in Southeast Asia and Melanesia. About 288 million metric tons (Mt) of copper and 18,000 metric tons (t) of gold, as well as byproduct molybdenum and silver, could be associated with undiscovered deposits. This represents about four times the number of deposits with identified resources (23) already discovered in Southeast Asia; reliable reported identified resources for those 23 deposits total 84 Mt of copper and 6,000 t of gold. Eleven permissive tracts have no known porphyry copper deposits with reported resources. Three of those 11 tracts lacked sufficient information for a probabilistic assessment and are discussed in qualitative terms. On a regional basis, both the Indochina Peninsula area and the Indonesian-Malaysian Islands area are estimated to contain about 10 times as much in place copper in undiscovered porphyry copper deposits as has been identified to date. For the New Guinea Island areas, the ratio of undiscovered to identified copper resources is about 2. Some parts of the region have a long history of porphyry exploration cycles and mine development, interrupted at times by political and social unrest, environmental concerns, and natural disasters. Changes in mining laws within the region and the recent high price of gold on the world market have prompted renewed interest in porphyry copper deposits in Southeast Asia and Melanesia. However, predicted undiscovered deposits may not be found, and if found, may not be developed. This assessment includes an overview of the assessment results with summary tables. Detailed descriptions of each tract are included in appendixes, with estimates of numbers of undiscovered deposits, and probabilistic estimates of amounts of copper, molybdenum, gold, and silver that could be contained in undiscovered deposits for each permissive tract. A geographic information system (GIS) that accompanies the report includes tract boundaries and a database of known porphyry copper deposits and significant prospects.

Scientific Investigations Report↗
USGS1992

Bedrock geology and mineral resources of the Knoxville 1° x 2° quadrangle, Tennessee, North Carolina, and South Carolina

The Knoxville 1° x 2° quadrangle spans the Southern Blue Ridge physiographic province at its widest point from eastern Tennessee across western North Carolina to the northwest corner of South Carolina. The quadrangle also contains small parts of the Valley and Ridge province in Tennessee and the Piedmont province in North and South Carolina. Bedrock in the Valley and Ridge consists of unmetamorphosed, folded and thrust-faulted Paleozoic miogeoclinal sedimentary rocks ranging in age from Cambrian to Mississippian. The Blue Ridge is a complex of stacked thrust sheets divided into three parts: (1) a west flank underlain by rocks of the Late Proterozoic and Early Cambrian Chilhowee Group and slightly metamorphosed Late Proterozoic Ocoee Supergroup west of the Greenbrier fault; (2) a central part containing crystalline basement of Middle Proterozoic age (Grenville), Ocoee Supergroup rocks east of the Greenbrier fault, and rocks of the Murphy belt; and (3) an east flank containing the Helen, Tallulah Falls, and Richard Russell thrust sheets and the amphibolitic basement complex. All of the east flank thrust sheets contain polydeformed and metamorphosed sedimentary and igneous rocks of mostly Proterozoic age. The Blue Ridge is separated by the Brevard fault zone from a large area of rocks of the Inner Piedmont to the east, which contains the Six Mile thrust sheet and the ChaugaWalhalla thrust complex. All of these rocks are also polydeformed and metamorphosed sedimentary and igneous rocks. The Inner Piedmont rocks in this area occupy both the Piedmont and part of the Blue Ridge physiographic provinces. The intensity of deformation and metamorphism increases from west to east in the Blue Ridge. The west flank is mostly chlorite grade or relatively unmetamorphosed, and the central part of the Blue Ridge is mostly staurolite, garnet, or biotite grade, although sillimanite grade rocks occur along the eastern part of the central Blue Ridge in the vicinity of the leading edge of the Hayesville fault. The east flank of the Blue Ridge and much of the Inner Piedmont are at kyanite or sillimanite grade of regional metamorphism except for a zone of retrograde rocks in the Brevard fault zone and a small area of biotite-grade rocks in the extreme southwest part of the Grandfather Mountain window in the northeast corner of the quadrangle. The major mineral resources in the Knoxville 1° x 2° quadrangle are construction materials and a variety of industrial minerals mostly related to either granite and pegmatite or ultramafic rocks. Past production in the quadrangle of metals, which are of secondary importance relative to construction materials and industrial minerals, include copper in massive sulfides of the Besshi type, gold-bearing quartz veins, and residual iron and manganese deposits. Resources are discussed in relation to the Valley and Ridge, Blue Ridge, and Piedmont provinces. The following resources are the most important: A. Construction materials: Dimension stone of the Tennessee marble district in the Valley and Ridge. Limestone and dolomite of the Valley and Ridge. Sand and gravel and crushed stone, widespread throughout the quadrangle. B. Industrial minerals: Feldspar, flake mica, and quartz produced by flotation methods from the Spruce Pine Alaskite (muscovite granodiorite) in the east flank of the Blue Ridge. The district produces about half of the U.S. feldspar and significant amounts of the U.S. flake mica. Olivine produced from alpine-type dunite bodies in the east flank of the Blue Ridge. Talc and marble from the Murphy belt in the central part of the Blue Ridge. Vermiculite produced from a large deposit near Tigerville, S.C., in the Inner Piedmont. Deposit worked out and mine backfilled. Smaller deposits associated with ultramafic rocks in the east flank of the Blue Ridge are now uneconomic and have not been worked in the past 20 years. C. Metals: Copper in three deposits, the Fontana and Hazel Creek mines in the Great Smoky Mountains National Park in the Central Blue Ridge, and the Cullowhee mine in the east flank of the Blue Ridge. D. Organic fuels: The rocks of the quadrangle contain no coal and probably lie outside the maximum range in thermal maturity permitting the survival of oil. The rocks in the Valley and Ridge and for a short distance eastward below the west flank of the Blue Ridge probably lie within a zone of thermal maturity permitting the survival of natural gas. Consequently the western part of the quadrangle is an area of high risk for hydrocarbon exploration. No exploration drilling has been done in this belt.

North Carolina, South Carolina, Tennessee↗
USGS2004

Bedrock geology and mineral resources of the Knoxville 1° x 2° quadrangle, Tennessee, North Carolina, and South Carolina

The Knoxville 1&deg;x 2&deg; quadrangle spans the Southern Blue Ridge physiographic province at its widest point from eastern Tennessee across western North Carolina to the northwest corner of South Carolina. The quadrangle also contains small parts of the Valley and Ridge province in Tennessee and the Piedmont province in North and South Carolina. Bedrock in the Valley and Ridge consists of unmetamorphosed, folded and thrust-faulted Paleozoic miogeoclinal sedimentary rocks ranging in age from Cambrian to Mississippian. The Blue Ridge is a complex of stacked thrust sheets divided into three parts: (1) a west flank underlain by rocks of the Late Proterozoic and Early Cambrian Chilhowee Group and slightly metamorphosed Late Proterozoic Ocoee Supergroup west of the Greenbrier fault; (2) a central part containing crystalline basement of Middle Proterozoic age (Grenville), Ocoee Supergroup rocks east of the Greenbrier fault, and rocks of the Murphy belt; and (3) an east flank containing the Helen, Tallulah Falls, and Richard Russell thrust sheets and the amphibolitic basement complex. All of the east flank thrust sheets contain polydeformed and metamorphosed sedimentary and igneous rocks of mostly Proterozoic age. The Blue Ridge is separated by the Brevard fault zone from a large area of rocks of the Inner Piedmont to the east, which contains the Six Mile thrust sheet and the ChaugaWalhalla thrust complex. All of these rocks are also polydeformed and metamorphosed sedimentary and igneous rocks. The Inner Piedmont rocks in this area occupy both the Piedmont and part of the Blue Ridge physiographic provinces. The intensity of deformation and metamorphism increases from west to east in the Blue Ridge. The west flank is mostly chlorite grade or relatively unmetamorphosed, and the central part of the Blue Ridge is mostly staurolite, garnet, or biotite grade, although sillimanite grade rocks occur along the eastern part of the central Blue Ridge in the vicinity of the leading edge of the Hayesvil Ie fault. The east flank of the Blue Ridge and much of the Inner Piedmont are at kyanite or silli manite grade of Manuscript approved for publication February 22, 1991. regional metamorphism except for a zone of retrograde rocks in the Brevard fault zone and a small area of biotite-grade rocks in the extreme southwest part of the Grandfather Mountain window in the northeast corner of the quadrangle. The major mineral resources in the Knoxville 1&deg;x2&deg; quadrangle are construction materials and a variety of industrial minerals mostly related to either granite and pegmatite or ultramafic rocks. Past production in the quadrangle of metals, which are of secondary importance relative to construction materials and industrial minerals, include copper in massive sulfides of the Besshi type, gold-bearing quartz veins, and residual iron and manganese deposits. Resources are discussed in relation to the Valley and Ridge, Blue Ridge, and Piedmont provinces. The following resources are the most important: A. Construction materials: Dimension stone of the Tennessee marble district in the Valley and Ridge. Limestone and dolomite of the Valley and Ridge. Sand and gravel and crushed stone, widespread throughout the quadrangle. B. Industrial minerals: Feldspar, flake mica, and quartz produced by flotation methods from the Spruce Pine Alaskite (muscovite granodiorite) in the east flank of the Blue Ridge. The district produces about half of the U.S. feldspar and significant amounts of the U.S. flake mica. Olivine produced from alpine-type dunite bodies in the east flank of the Blue Ridge. Talc and marble from the Murphy belt in the central part of the Blue Ridge, Vermiculite produced from a large deposit near Tigerville, S.C-, in the Inner Piedmont. Deposit worked out and mine backfilled. Smaller deposits associated with ultramafic rocks in the east flank of the Blue Ridge are now uneconomic and have not been worked in the past 20 years. C. Metals: Copper in three deposits, the Fontana and Hazel Creek mines in the Great Smoky Mountains Abstract Figure 1. Location of the Knoxville 1&ordm;x2&ordm; quadrangle, with state and county boundaries National Park in the Central Blue Ridge, and the Cullowhee mine in the east flank of the Blue Ridge. D. Organic fuels: The rocks of the quadrangle contain no coal and probably lie outside the maximum range in thermal maturity permitting the survival of oil. The rocks in the Valley and Ridge and for a short distance eastward below the west flank of the Blue Ridge probably lie within a zone of thermal maturity permitting the survival of natural gas. Consequently the western part of the quadrangle is an area of high risk for hydrocarbon exploration. No exploration drilling has been done in this belt.

North Carolina, South Carolina, Tennessee↗
USGS2014

Concealed basalt-matrix diatremes with Cu-Au-Ag-(Mo)-mineralized xenoliths, Santa Cruz Porphyry Cu-(Mo) System, Pinal County, Arizona

The Santa Cruz porphyry Cu-(Mo) system near Casa Grande, Arizona, includes the Sacaton mine deposits and at least five other concealed, mineralized fault blocks with an estimated minimum resource of 1.5 Gt @ 0.6% Cu. The Late Cretaceous-Paleocene system has been dismembered and rotated by Tertiary extension, partially eroded, and covered by Tertiary-Quaternary basin-fill deposits. The mine and mineralized fault blocks, which form an 11 km (~7 miles) by 1.6 km (~1 mile) NE-SW–trending alignment, represent either pieces of one large deposit, several deposits, or pieces of several deposits. The southwestern part of the known system is penetrated by three or more diatremes that consist of heterolithic breccia pipes with basalt and clastic matrices, and subannular tuff ring and maar-fill sedimentary deposits associated with vents. The tephra and maar-fill deposits, which are covered by ~485 to 910 m (~1,600–3,000 ft) of basin fill, lie on a mid-Tertiary erosion surface of Middle Proterozoic granite and Late Cretaceous porphyry, which compose most xenoliths in pipes and are the host rocks of the system. Some igneous xenoliths in the pipes contain bornite-chalcopyrite-covellite assemblages with hypogene grades >1 wt % Cu, 0.01 ounces per ton (oz/t) Au, 0.5 oz/t Ag, and small amounts of Mo (<0.01 wt %). These xenoliths were derived from mineralized rocks that have not been encountered in drill holes, and attest to additional, possibly higher-grade deposits within or subjacent to the known system. The geometry, stratigraphy, and temporal relationships of pipes and tephras, interpreted from drill hole spacing and intercepts, multigenerational breccias and matrices, reequilibrated and partially decomposed sulfide-oxide mineral assemblages, melted xenoliths, and breccia matrix compositions show that the diatremes formed in repeated stages. Initial pulses of basalt magma fractured granite, porphyry, and other crustal rocks during intrusion, transported multi-sized fragments of these rocks upward, and partially melted small fragments. Rapid decompression of magma induced catastrophic devolatilization that ruptured overlying rocks to the surface, and generated fragment-volatile suspensions that abraded conduits into near-vertical cylindrical structures. Fragments entrained in suspensions were milled and sorted, and ejected as basal surge, pyroclastic deposits, and airfall tephra that built tuff rings around vents and filled vent depressions. Comminuted m- to mm-sized fragments of wall rocks in magma and suspensions that remained in conduits solidified as heterolithic breccias. Subsequent pulses of basalt magma ascended through the same conduits, brecciated older heterolithic breccias, devolatilized, and quenched, leaving two or more generations of nested and mingled heterolithic breccias and internal zones of fluidized fragments. Tephra and maar-fill deposits from later eruptions are composed of more hydrous and oxidized minerals than earlier tephras, reflecting a higher proportion of water in transport fluid which, based on fluid inclusion populations in mineralized xenoliths, was saline water and CO 2 . The large vertical extent (~600 m; ~2,000 ft) of basalt matrix in pipes, near-paleosurface matrix vesiculation, and plastically deformed basalt lapilli indicates that diatreme eruptions were predominantly phreatic. Diatreme xenoliths represent crustal stratigraphy and, as in the Santa Cruz system, provide evidence of concealed mineral resources that can guide exploration drilling through cover. Vectors to the source of bornite-dominant xenoliths containing >1% Cu and significant Au and Ag could be determined by refinement of breccia pipe geometries, by reassembly of mineralized fault blocks using modal, chemical, and temporal characteristics of hydrothermal mineral assemblages and fluid inclusions, and by paleodrainage analysis.

Arizona↗
USGS2012

Local-area-enhanced, 2.5-meter resolution natural-color and color-infrared satellite-image mosaics of the Zarkashan mineral district in Afghanistan: Chapter G in Local-area-enhanced, high-resolution natural-color and color-infrared satellite-image mosaics of mineral districts in Afghanistan

The U.S. Geological Survey (USGS), in cooperation with the U.S. Department of Defense Task Force for Business and Stability Operations, prepared databases for mineral-resource target areas in Afghanistan. The purpose of the databases is to (1) provide useful data to ground-survey crews for use in performing detailed assessments of the areas and (2) provide useful information to private investors who are considering investment in a particular area for development of its natural resources. The set of satellite-image mosaics provided in this Data Series (DS) is one such database. Although airborne digital color-infrared imagery was acquired for parts of Afghanistan in 2006, the image data have radiometric variations that preclude their use in creating a consistent image mosaic for geologic analysis. Consequently, image mosaics were created using ALOS (Advanced Land Observation Satellite; renamed Daichi) satellite images, whose radiometry has been well determined (Saunier, 2007a,b). This part of the DS consists of the locally enhanced ALOS image mosaics for the Zarkashan mineral district, which has copper and gold deposits. ALOS was launched on January 24, 2006, and provides multispectral images from the AVNIR (Advanced Visible and Near-Infrared Radiometer) sensor in blue (420–500 nanometer, nm), green (520–600 nm), red (610–690 nm), and near-infrared (760–890 nm) wavelength bands with an 8-bit dynamic range and a 10-meter (m) ground resolution. The satellite also provides a panchromatic band image from the PRISM (Panchromatic Remote-sensing Instrument for Stereo Mapping) sensor (520–770 nm) with the same dynamic range but a 2.5-m ground resolution. The image products in this DS incorporate copyrighted data provided by the Japan Aerospace Exploration Agency (©JAXA,2006,2007, 2008), but the image processing has altered the original pixel structure and all image values of the JAXA ALOS data, such that original image values cannot be recreated from this DS. As such, the DS products match JAXA criteria for value added products, which are not copyrighted, according to the ALOS end-user license agreement. The selection criteria for the satellite imagery used in our mosaics were images having (1) the highest solar-elevation angles (near summer solstice) and (2) the least cloud, cloud-shadow, and snow cover. The multispectral and panchromatic data were orthorectified with ALOS satellite ephemeris data, a process which is not as accurate as orthorectification using digital elevation models (DEMs); however, the ALOS processing center did not have a precise DEM. As a result, the multispectral and panchromatic image pairs were generally not well registered to the surface and not coregistered well enough to perform resolution enhancement on the multispectral data. Therefore, it was necessary to (1) register the 10-m AVNIR multispectral imagery to a well-controlled Landsat image base, (2) mosaic the individual multispectral images into a single image of the entire area of interest, (3) register each panchromatic image to the registered multispectral image base, and (4) mosaic the individual panchromatic images into a single image of the entire area of interest. The two image-registration steps were facilitated using an automated control-point algorithm developed by the USGS that allows image coregistration to within one picture element. Before rectification, the multispectral and panchromatic images were converted to radiance values and then to relative-reflectance values using the methods described in Davis (2006). Mosaicking the multispectral or panchromatic images started with the image with the highest sun-elevation angle and the least atmospheric scattering, which was treated as the standard image. The band-reflectance values of all other multispectral or panchromatic images within the area were sequentially adjusted to that of the standard image by determining band-reflectance correspondence between overlapping images using linear least-squares analysis. The resolution of the multispectral image mosaic was then increased to that of the panchromatic image mosaic using the SPARKLE logic, which is described in Davis (2006). Each of the four-band images within the resolution-enhanced image mosaic was individually subjected to a local-area histogram stretch algorithm (described in Davis, 2007), which stretches each band’s picture element based on the digital values of all picture elements within a 315-m radius. The final databases, which are provided in this DS, are three-band, color-composite images of the local-area-enhanced, natural-color data (the blue, green, and red wavelength bands) and color-infrared data (the green, red, and near-infrared wavelength bands). All image data were initially projected and maintained in Universal Transverse Mercator (UTM) map projection using the target area’s local zone (42 for Zarkashan) and the WGS84 datum. The final image mosaics were subdivided into two overlapping tiles or quadrants because of the large size of the target area. The two image tiles (or quadrants) for the Zarkashan area are provided as embedded geotiff images, which can be read and used by most geographic information system (GIS) and image-processing software. The tiff world files (tfw) are provided, even though they are generally not needed for most software to read an embedded geotiff image. Within the Zarkashan study area, three subareas were designated for detailed field investigations (that is, the Mine Area, Bolo Gold Prospect, and Luman-Tamaki Gold Prospect subareas); these subareas were extracted from the area’s image mosaic and are provided as separate embedded geotiff images.

Zarkashan Mineral District↗
USGS2025

Timing of hydrothermal alteration and Au-Sb-W mineralization, Stibnite-Yellow Pine district, Idaho

The Stibnite-Yellow Pine district of central Idaho was mined from the early 1900s until the 1990s, extracting gold, antimony, tungsten, and mercury from veins and disseminated and replacement ores in mountainous terrain along the headwaters of the Salmon River. Mining during the two World Wars supplied critical antimony and tungsten to the war efforts. Recent exploration has delineated mineral resources of over 187 metric tons Au, 274 metric tons Ag, and 93,000 metric tons Sb. Mineralization is hosted in Cretaceous Idaho batholith granitic rocks and a sequence of Neoproterozoic to Paleozoic metasedimentary strata of carbonate and siliciclastic compositions. Historical studies outlined some of the complex paragenesis but debated the absolute age of mineralization. New petrographic and geochronologic work documents a sequence of five hydrothermal events in the Stibnite-Yellow Pine district. Event 1 is related to Cretaceous magmatic and hydrothermal activity and includes events ranging in age from 86 to 75 Ma, including sparse quartz-molybdenite veins dated at 86 Ma. Disseminated gold mineralization of event 2 is associated with sericitic alteration and sulfidation of igneous biotite and replacement of plagioclase by potassium feldspar, largely in granodiorite. Gold is present in zoned arsenian pyrite in both disseminated ores and in crosscutting carbonate-quartz veins containing pyrite and arsenopyrite. The large Yellow Pine deposit, localized at a dilatant bend in the Meadow Creek fault, hosts such disseminated and vein gold. Event 2 is interpreted as the major gold-forming event; 40 Ar/ 39 Ar ages of sericite and potassium feldspar alteration range, respectively, from 70 to 59 and 66 to 56 Ma. The long span is interpreted to reflect the age of gold mineralization and local overprinting by event 3. A narrower range from 66 to 61 Ma is interpreted to date the peak of gold mineralization and alteration. Event 3, tungsten mineralization with scheelite, is texturally later than event 2 gold and localized along the Meadow Creek structure. Event 3 scheelite has been dated by isotope dilution-thermal ionization mass spectrometry (ID-TIMS) and laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) U-Pb methods at 57 Ma. Event 4, best developed in the West End area, includes gold-silver–bearing quartz-carbonate-pyrite veins and breccias with epithermal textures and potassium feldspar alteration envelopes. Adularia from event 4 yields 40 Ar/ 39 Ar plateau ages of 52 to 51 Ma. Event 5 antimony and mercury mineralization consists of stibnite veins and breccia cements at the Yellow Pine and Hangar Flat deposits as well as cinnabar veins and replacements at the peripheral Fern and Hermes deposits; it is constrained by an LA-ICP-MS U-Pb date on scheelite (ca. 47 Ma) intergrown with stibnite. Minor propylitic and argillic alteration is evident in 47 Ma igneous dikes, which do not contain economic mineralization. The Au-Sb-W ores in the Stibnite-Yellow Pine mining district formed over an extended time period from about 70 to 45 Ma in multiple pulses that were localized along the Meadow Creek fault zone. Each event corresponds to episodes of magmatism and/or hydrothermal activity in the region. Insignificant event 1 skarn and molybdenum mineralization is similar in age to the Thompson Creek porphyry molybdenum deposit in central Idaho. Event 2 gold mineralization occurred during a magmatic gap in central Idaho but was synchronous with magmatism in the Bitterroot lobe further north; event 2 is similar in age to orogenic gold-arsenic mineralization at the Beartrack mine in eastern Idaho. Event 3 scheelite mineralization coincides with tungsten mineralization at the Quartz Creek deposit, late magmatism in the Bitterroot lobe, and rapid exhumation of the Atlanta lobe of the Idaho batholith. Event 4 gold mineralization is coincident with the onset of regional Challis magmatism and extension. Event 5 antimony and mercury mineralization is time-equivalent to epithermal gold mineralization in the nearby Thunder Mountain volcanic field and the peak of Challis magmatism.

Idaho↗
USGS2017

Suitability of river delta sediment as proppant, Missouri and Niobrara Rivers, Nebraska and South Dakota, 2015

Sediment management is a challenge faced by reservoir managers who have several potential options, including dredging, for mitigation of storage capacity lost to sedimentation. As sediment is removed from reservoir storage, potential use of the sediment for socioeconomic or ecological benefit could potentially defray some costs of its removal. Rivers that transport a sandy sediment load will deposit the sand load along a reservoir-headwaters reach where the current of the river slackens progressively as its bed approaches and then descends below the reservoir water level. Given a rare combination of factors, a reservoir deposit of alluvial sand has potential to be suitable for use as proppant for hydraulic fracturing in unconventional oil and gas development. In 2015, the U.S. Geological Survey began a program of researching potential sources of proppant sand from reservoirs, with an initial focus on the Missouri River subbasins that receive sand loads from the Nebraska Sand Hills. This report documents the methods and results of assessments of the suitability of river delta sediment as proppant for a pilot study area in the delta headwaters of Lewis and Clark Lake, Nebraska and South Dakota. Results from surface-geophysical surveys of electrical resistivity guided borings to collect 3.7-meter long cores at 25 sites on delta sandbars using the direct-push method to recover duplicate, 3.8-centimeter-diameter cores in April 2015. In addition, the U.S. Geological Survey collected samples of upstream sand sources in the lower Niobrara River valley. At the laboratory, samples were dried, weighed, washed, dried, and weighed again. Exploratory analysis of natural sand for determining its suitability as a proppant involved application of a modified subset of the standard protocols known as American Petroleum Institute (API) Recommended Practice (RP) 19C. The RP19C methods were not intended for exploration-stage evaluation of raw materials. Results for the washed samples are not directly applicable to evaluations of suitability for use as fracture sand because, except for particle-size distribution, the API-recommended practices for assessing proppant properties (sphericity, roundness, bulk density, and crush resistance) require testing of specific proppant size classes. An optical imaging particle-size analyzer was used to make measurements of particle-size distribution and particle shape. Measured samples were sieved to separate the dominant-size fraction, and the separated subsample was further tested for roundness, sphericity, bulk density, and crush resistance. For the bulk washed samples collected from the Missouri River delta, the geometric mean size averaged 0.27 millimeters (mm), 80 percent of the samples were predominantly sand in the API 40/70 size class, and 17 percent were predominantly sand in the API 70/140 size class. Distributions of geometric mean size among the four sandbar complexes were similar, but samples collected from sandbar complex B were slightly coarser sand than those from the other three complexes. The average geometric mean sizes among the four sandbar complexes ranged only from 0.26 to 0.30 mm. For 22 main-stem sampling locations along the lower Niobrara River, geometric mean size averaged 0.26 mm, an average of 61 percent was sand in the API 40/70 size class, and 28 percent was sand in the API 70/140 size class. Average composition for lower Niobrara River samples was 48 percent medium sand, 37 percent fine sand, and about 7 percent each very fine sand and coarse sand fractions. On average, samples were moderately well sorted. Particle shape and strength were assessed for the dominant-size class of each sample. For proppant strength, crush resistance was tested at a predetermined level of stress (34.5 megapascals [MPa], or 5,000 pounds-force per square inch). To meet the API minimum requirement for proppant, after the crush test not more than 10 percent of the tested sample should be finer than the precrush dominant-size class. For particle shape, all samples surpassed the recommended minimum criteria for sphericity and roundness, with most samples being well-rounded. For proppant strength, of 57 crush-resistance tested Missouri River delta samples of 40/70-sized sand, 23 (40 percent) were interpreted as meeting the minimum criterion at 34.5 MPa, or 5,000 pounds-force per square inch. Of 12 tested samples of 70/140-sized sand, 9 (75 percent) of the Missouri River delta samples had less than 10 percent fines by volume following crush testing, achieving the minimum criterion at 34.5 MPa. Crush resistance for delta samples was strongest at sandbar complex A, where 67 percent of tested samples met the 10-percent fines criterion at the 34.5-MPa threshold. This frequency was higher than was indicated by samples from sandbar complexes B, C, and D that had rates of 50, 46, and 42 percent, respectively. The group of sandbar complex A samples also contained the largest percentages of samples dominated by the API 70/140 size class, which overall had a higher percentage of samples meeting the minimum criterion compared to samples dominated by coarser size classes; however, samples from sandbar complex A that had the API 40/70 size class tested also had a higher rate for meeting the minimum criterion (57 percent) than did samples from sandbar complexes B, C, and D (50, 43, and 40 percent, respectively). For samples collected along the lower Niobrara River, of the 25 tested samples of 40/70-sized sand, 9 samples passed the API minimum criterion at 34.5 MPa, but only 3 samples passed the more-stringent criterion of 8 percent postcrush fines. All four tested samples of 70/140 sand passed the minimum criterion at 34.5 MPa, with postcrush fines percentage of at most 4.1 percent. For two reaches of the lower Niobrara River, where hydraulic sorting was energized artificially by the hydraulic head drop at and immediately downstream from Spencer Dam, suitability of channel deposits for potential use as fracture sand was confirmed by test results. All reach A washed samples were well-rounded and had sphericity scores above 0.65, and samples for 80 percent of sampled locations met the crush-resistance criterion at the 34.5-MPa stress level. A conservative lower-bound estimate of sand volume in the reach A deposits was about 86,000 cubic meters. All reach B samples were well-rounded but sphericity averaged 0.63, a little less than the average for upstream reaches A and SP. All four samples tested passed the crush-resistance test at 34.5 MPa. Of three reach B sandbars, two had no more than 3 percent fines after the crush test, surpassing more stringent criteria for crush resistance that accept a maximum of 6 percent fines following the crush test for the API 70/140 size class. Relative to the crush-resistance test results for the API 40/70 size fraction of two samples of mine output from Loup River settling-basin dredge spoils near Genoa, Nebr., four of five reach A sample locations compared favorably. The four samples had increases in fines composition of 1.6–5.9 percentage points, whereas fines in the two mine-output samples increased by an average 6.8 percentage points.

Nebraska, South Dakota↗