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Simulation and particle-tracking analysis of ground-water flow near the Savannah River site, Georgia and South Carolina, 2002, and for selected ground-water management scenarios, 2002 and 2020

Ground-water flow under 2002 hydrologic conditions was evaluated in an eight-county area in Georgia and South Carolina near the Savannah River Site (SRS), by updating boundary conditions and pumping rates in an existing U.S. Geological Survey (USGS) ground-water model. The original ground-water model, developed to simulate hydrologic conditions during 1987-92, used the quasi-three-dimensional approach by dividing the Floridan, Dublin, and Midville aquifer systems into seven aquifers. The hydrogeologic system was modeled using six active layers (A2-A7) that were separated by confining units with an overlying source-sink layer to simulate the unconfined Upper Three Runs aquifer (layer A1). Potentiometric- surface maps depicting September 2002 for major aquifers were used to update, evaluate, and modify boundary conditions used by the earlier ground-water flow model. The model was updated using the USGS finite-difference code MODFLOW-2000 for mean-annual conditions during 1987-92 and 2002. The specified heads in the source-sink layer A1 were lowered to reflect observed water-level declines during the 1998-2002 drought. These declines resulted in a decrease of 12.1 million gallons per day (Mgal/d) in simulated recharge or vertical inflow to the uppermost confined aquifer (Gordon, layer A2). Although ground-water pumpage in the study area has increased by 32 Mgal/d since 1995, most of this increase (17.5 Mgal/d) was from the unconfined Upper Three Runs aquifer (source-sink layer A1) with the remaining 14.5 Mgal/d assigned to the active layers within the model (A2-A7). The simulated water budget for 2002 shows a decrease from the 1987-92 model from 1,040 Mgal/d to 1,035 Mgal/d. The decreased ground-water inflows and increased ground-water withdrawal rates reduced the simulated ground-water outflow to river cells in the active layers of the model by 43 Mgal/d. The calibration statistics for all layers of the 2002 simulation resulted in a decrease in the root mean square (RMS) of the residuals from 10.6 to 8.0 feet (ft). The residuals indicate 83.3 percent of the values for the 2002 simulation met the calibration error criteria established in the original model, whereas 88.8 percent was within the specified range for the 1987-92 simulation. Simulated ground-water outflow to the Savannah River and its tributaries during water year 2002 was 560 cubic feet per second (ft3/s), or 86 percent of the observed gain in mean-annual streamflow between streamflow gaging stations at the Millhaven, Ga., and Augusta, Ga. At Upper Three Runs Creek, simulated ground-water discharge during 2002 was 110 ft3/s, or 83 percent of the observed streamflow at two streamflow gaging stations near the SRS. These results indicate that the constructed model calibrated to 1987-92 conditions and modified for 2002 dry conditions is still representative of the hydrologic system. The USGS particle-tracking code MODPATH was used to generate advective water-particle pathlines and their associated time-of-travel based on MODFLOW simulations for 1987-92, 2002, and each of four hypothetical ground-water management scenarios. The four hypothetical ground-water management scenarios represent hydrologic conditions for (1) reported pumping for 2002 and boundary conditions for an average year; (2) reported pumping for 2002 with SRS pumping discontinued and boundary conditions for an average year; (3) projected 2020 pumping and boundary conditions for an average year; and (4) projected 2020 pumping and boundary conditions for a dry year. The MODPATH code was used in forward-tracking mode to evaluate flowpaths from areas on the SRS and in backtracking mode to evaluate further areas of previously documented trans-river flow on the Georgia side of the Savannah River. Trans-river flow is a condition in which the local head gradients might allow migration of contaminants from the SRS into the underlying aquifers and beneath the Savannah River into Georgia. More...

Georgia, South Carolina

Quality of ground water around Vadnais Lake and in Lambert Creek watershed, and interaction of ground water with Vadnais Lake, Ramsey County, Minnesota

Vadnais Lake is located in northern Ramsey County, Minnesota. The lake is managed by the St. Paul Water Utility for storage of municipal water supplies that are provided to residents of St. Paul and surrounding communities. In recent years, algal blooms in Vadnais Lake have caused taste and odor problems in St. Paul's municipal water supply. This problem has potentially been exacerbated by phosphorus enrichment of the lake from surface-water transport and from nutrient recycling between the lake and bottom sediments. Phosphorus loading in Vadnais Lake has been linked to increased algal growth. Surface-water drainage from supply lakes and, during wet years, from wetlands in Lambert Creek watershed, which extends over about 20 square miles east of the lake, is known to be a significant source of phosphorus. The role of ground water in the phosphorus budget of the lake was unknown. The results of this study indicate that ground-water transport of phosphorus into Vadnais Lake is a small part of the phosphorus budget of the lake. Seepage into and out of Vadnais Lake was estimated by the following methods: (1) interpretation of the hydraulic conductivities of glacial deposits around the lake and of the hydraulic gradients between ground water in these deposits and the lake; and (2) interpretation of the hydraulic conductivities of lakebed materials and of the hydraulic gradients between ground water in the lakebed and the lake. The estimated net annual seepage out of the lake determined by the second method of 9.56 x 10 7 feet 3 per year was greater by an order of magnitude than the value determined by the first method, which was 7.63 x 10 6 feet 3 per year. The net seepage out of Vadnais Lake was a small part of the lake water budget. Inflow to the lake is mostly streamflow from Sucker Creek, which is water from the Mississippi River routed through a series of lakes. Outflow from the lake is mostly withdrawals by the St Paul Water Utility. The net seepage out of the lake between spring and winter was from less than 1 to about 4 percent of the total loss attributed to withdrawals and evaporation. The quality of the ground water in the study area was similar to the quality measured in shallow glacial-drift aquifers throughout Minnesota. Calcium magnesium bicarbonate water was the dominant type. Concentrations of volatile organic compounds in ground-water samples were below detection limits. The concentration of total phosphorus in ground-water samples generally was below 0.15 milligrams per liter. The results of the seepage analysis and ground-water quality evaluation indicate that the effect of the quality of the surrounding ground water on the quality of Vadnais Lake probably was small. Ground water that discharged to the lake generally had lower concentrations of calcium, magnesium, bicarbonate, and total dissolved solids than the lake. The mixing of ground water with the lake slightly diluted the lake with respect to these constituents.

Minnesota

Simulation of projected water demand and ground-water levels in the Coffee Sand and Eutaw-McShan aquifers in Union County, Mississippi, 2010 through 2050

Ground water from the Eutaw-McShan and the Coffee Sand aquifers is the major source of supply for residential, commercial, and industrial purposes in Union County, Mississippi. Unbiased, scientifically sound data and assessments are needed to assist agencies in better understanding and managing available water resources as continuing development and growth places more stress on available resources. The U.S. Geological Survey, in cooperation with the Tennessee Valley Authority, conducted an investigation using water-demand and ground-water models to evaluate the effect of future water demand on groundwater levels. Data collected for the 12 public-supply facilities and the self-supplied commercial and industrial facilities in Union County were used to construct water-demand models. The estimates of water demand to year 2050 were then input to a ground-water model based on the U.S. Geological Survey finite-difference computer code, MODFLOW. Total ground-water withdrawals for Union County in 1998 were estimated as 2.85 million gallons per day (Mgal/d). Of that amount, municipal withdrawals were 2.55 Mgal/d with about 1.50 Mgal/d (59 percent) delivered to residential users. Nonmunicipal withdrawals were 0.296 Mgal/d. About 80 percent (2.27 Mgal/d) of the total ground-water withdrawal is produced from the Eutaw-McShan aquifer and about 13 percent (0.371 Mgal/d) from the Coffee Sand aquifer. Between normal- and high-growth conditions, total water demand could increase from 72 to 131 percent (2.9 Mgal/d in 1998 to 6.7 Mgal/d in year 2050) with municipal demand increasing from 77 to 146 percent (2.6 to 6.4 Mgal/d). Increased pumping to meet the demand for water was simulated to determine the effect on water levels in the Coffee Sand and Eutaw- McShan aquifers. Under baseline-growth conditions, increased water use by year 2050 could result in an additional 65 feet of drawdown in the New Albany area below year 2000 water levels in the Coffee Sand aquifer and about 120 feet of maximum drawdown in the Eutaw-McShan aquifer. Under normal-growth conditions, increased water use could result in an additional 65 feet of drawdown in the New Albany area below year 2000 water levels in the Coffee Sand aquifer and about 135 feet of maximum drawdown in the Eutaw-McShan aquifer. Under high-growth conditions, increased water use could result in 75 feet of drawdown in the New Albany area below year 2000 water levels in the Coffee Sand aquifer and about 190 feet of maximum drawdown in the Eutaw-McShan aquifer. The resulting highgrowth projected water level for the year 2050 at the center of the drawdown cone in the New Albany area is between 450 and 500 feet above the top of the Eutaw-McShan aquifer.

Mississippi

Effects of simulated ground-water pumping and recharge on ground-water flow in Cape Cod, Martha's Vineyard, and Nantucket Island basins, Massachusetts

Three-dimensional transient ground-water-flow models that simulate both freshwater and saltwater flow were developed for the flow cells of the Cape Cod Basin to determine the effects of long-term pumping and recharge, seasonal fluctuations in pumping and recharge, and prolonged reductions of natural recharge, on the position of the freshwater-saltwater interface, water-table and pond altitudes, and streamflow and discharge to coastal marshes and embayments. Two-dimensional, finite-difference change models were developed for Martha's Vineyard and Nantucket Island basins to determine anticipated drawdowns in response to projected summer season pumping rates for 180 days of no recharge.

Water Supply Paper

Aquifer-test results, direction of ground-water flow, and 1984-90 annual ground-water pumpage for irrigation, lower Big Lost River Valley, Idaho

The study area (see index map of Idaho), part of the Big Lost River drainage basin, is at the northern side of the eastern Snake River Plain. The lower Big Lost River Valley extends from the confluence of Antelope Creek and the Big Lost River to about 4 mi south of Arco and encompasses about 145 mi 2 (see map showing water-level contours). The study area is about 18 mi long and, at its narrowest, 4 mi wide. Arco, Butte City, and Moore, with populations of 1,016, 59, and 190, respectively, in 1990, are the only incorporated towns. The entire study area, except the extreme northwestern part, is in Butte City. The study area boundary is where alluvium and colluvium pinch out and abut against the White Knob Mountains (chiefly undifferentiated sedimentary rock with lesser amounts of volcanic rock) on the west and the Lost River Range (chiefly sedimentary rock) on the east. Gravel and sand in the valley fill compose the main aquifer. The southern boundary is approximately where Big Lost River valley fill intercalates with or abuts against basalt of the Snake River Group. Spring ground-water levels and flow in the Big Lost River depend primarily on temperature and the amount and timing of precipitation within the entire drainage basin. Periods of abundant water supply and water shortages are, therefore, related to the amount of annual precipitation. Surface reservoir capacity in the valley (Mackay Reservoir, about 20 mi northwest of Moore) is only 20 percent of the average annual flow of the Big Lost River (Crosthwaite and others, 1970, p. 3). Stored surface water is generally unavailable for carryover from years of abundant water supply to help relieve drought conditions in subsequent years. Many farmers have drilled irrigation wells to supplement surface-water supplies and to increase irrigated acreage. Average annual flow of the Big Lost River below Mackay Reservoir near Mackay (gaging station 13127000, not shown) in water years 1905, 1913-14, and 1920-90 was about 224,600 acre-ft; average annual flow of the Big Lost River near Arco (gaging station 13132500; see map showing water-level contours) in water years 1947-61, 1967-80, and 1983-90 was about 79,000 acre-ft (Harenberg and others, 1991, p. 254-255). Moore Canal and East Side Ditch divert water from the Big Lost River at the Moore Diversion, 3 mi north of Moore (see map showing water-level contours) and supply water for irrigation near the margins of the valley. When water supply is average or greater, water in the Big Lost River flows through the study area and onto the Snake River Plain, where it evaporates or infiltrates into the Snake River Plain aquifer. When water supply is below average, water in the Big Lost River commonly does not reach Arco; rather, it is diverted for irrigation in the interior of the valley, evaporates, or infiltrates to the valley-fill aquifer. This report describes the results of a study by the U.S. Geological Survey, in cooperation with the Idaho Department of Water Resources, to collect hydrologic data needed to help address water-supply problems in the Big Lost River Valley. Work involved (1) field inventory of 81 wells, including 46 irrigation wells; (2) measurement of water levels in 154 wells in March 1991; (3) estimation of annual ground-water pumpage for irrigation from 1984 through 1990; and (4) analysis of results of an aquifer test conducted southwest of Moore. All data obtained during this study may be inspected at the U.S. Geological Survey, Idaho District office, Boise.

Idaho

A simple device for measuring differences in hydraulic head between surface water and shallow ground water

This fact sheet describes a simple device for measuring the vertical hydraulic gradient (VHG) of shallow ground water beneath a stream bed. The VHG can be used to determine whether a stream is receiving or losing water at the point of measurement. Used as part of a spatial or temporal survey, such measurements can yield valuable information about the local hydrology of a stream/ground-water system. This device also can be used to withdraw shallow subsurface water for chemical analyses. The device is inexpensive and lightweight, but lacks the precision and range of measurement of other probes, such as those described by Winter and others (1988) and Duff and others (1998).

Fact Sheet

National water summary 1986: Hydrologic events and ground-water quality

Ground water is one of the most important natural resources of the United States and degradation of its quality could have a major effect on the welfare of the Nation. Currently (1985), ground water is the source of drinking water for 53 percent of the Nation's population and for more than 97 percent of its rural population. It is the source of about 40 percent of the Nation's public water supply, 33 percent of water for irrigation, and 17 percent of freshwater for selfsupplied industries. Ground water also is the source of about 40 percent of the average annual streamflow in the United States, although during long periods of little or no precipitation, ground-water discharges provide nearly all of the base streamflow. This hydraulic connection between aquifers and streams implies that if a persistent pollutant gets into an aquifer, it eventually could discharge into a stream. Information presented in the 1986 National Water Summary clearly shows that the United States has very large amounts of potable ground water available for use. Although naturally occurring constituents, such as nitrate, and human-induced substances, such as synthetic organic chemicals, frequently are detected in ground water, their concentrations usually do not exceed existing Federal or State standards or guidelines for maximum concentrations in drinking water. Troublesome contamination of ground water falls into two basic categories related to the source or sources of the contamination. Locally, high concentrations of a variety of toxic metals, organic chemicals, and petroleum products have been detected in ground water associated with point sources such as wastedisposal sites, storage-tank leaks, and hazardous chemical spills. These types of local problems commonly occur in densely populated urban areas and industrialized areas. Larger, multicounty areas also have been identified where contamination frequently is found in shallow wells. These areas generally are associated with broad-scale, or nonpoint, sources of contamination such as agricultural activities or highdensity domestic waste disposal (septic systems) in urban centers. At present, only a very small percentage of the total volume of potable ground water in the United States is contaminated from both point and nonpoint sources; however, available data, especially data about the occurrence of synthetic organic and toxic substances, generally are inadequate to determine the full extent of ground-water contamination in the Nation's aquifers or to define trends in groundwater quality. Most information about the occurrence of these substances has come from the study of individual sites or areas where contamination had already been detected or suspected. Management and protection of ground water present a major challenge to the Nation. Current and projected costs of detection and cleanup of existing ground-water contamination are staggering and, even so, complete removal of pollutants from ground water in the vicinity of some waste sites might not be technically feasible. At all levels of government, the task of protecting the resource for its most beneficial uses is difficult and controversial. Despite increasing awareness that some of the Nation's ground water is contaminated with a variety of toxic metals, synthetic organic chemicals, radionuclides, pesticides, and other contaminants that might present a long-term risk to human health, public policy towards ground-water protection is still in the formative stages. Despite increasing efforts devoted to ground-water protection by State and Federal regulatory and resource-management agencies, the extent of ground-water contamination is likely to appear to increase over the next few years because more agencies will be searching for evidence of contamination, and they will be using increasingly sensitive analytical procedures. Increased technology and expanded monitoring activities probably will detect the effects of past contamination and land uses on water quality. The significant time lag between a waterquality change in one part of an aquifer system and the effects of that change at a downgradient site, such as a well, results from the generally slow movement of ground water. This lag between cause and observed effect needs to be considered in evaluating the effectiveness of current and future ground-water policies and remedial measures. Conclusive answers to questions about the location, extent, and severity of ground-water contamination, and about trends in ground-water quality, must await further collection and analysis of data from the Nation's aquifers. Generalizations, however, can be made, and the 1986 National Water Summary, which describes the natural quality of ground-water resources in each State and the major contamination problems that have been identified as of 1986, provides a national perspective of the ground-water-quality situation. The 1986 National Water Summary follows the format of previous volumes. It contains three parts, and the contents of each of these parts are highlighted below.

Water Supply Paper

Surface-Water, Water-Quality, and Ground-Water Assessment of the Municipio of Mayaguez, Puerto Rico, 1999-2002

The surface-water assessment portion of this study focused on analysis of low-flow characteristics in local streams and rivers, because the supply of safe drinking water was a critical issue during recent dry periods. Low-flow characteristics were evaluated at one continuous-record gaging station based on graphical curve-fitting techniques and log-Pearson Type III frequency curves. Estimates of low-flow characteristics for 20 partial-record stations were generated using graphical-correlation techniques. Flow-duration characteristics for the continuous- and partial-record stations were estimated using the relation curves developed for the low-flow study. Stream low-flow statistics document the general hydrology under current land use, water-use, and climatic conditions. A survey of streams and rivers utilized 37 sampling stations to evaluate the sanitary quality of about 165 miles of stream channels. River and stream samples for fecal coliform and fecal streptococcus analyses were collected on two occasions at base-flow conditions. Bacteriological analyses indicate that a significant portion of the stream reaches within the municipio of Mayaguez may have fecal coliform bacteria concentrations above the water-quality goal (standard) established by the Puerto Rico Environmental Quality Board (Junta de Calidad Ambiental de Puerto Rico) for inland surface waters. Sources of fecal contamination may include: illegal discharge of sewage to storm-water drains, malfunctioning sanitary sewer ejectors, clogged and leaking sewage pipes, septic tank leakage, unfenced livestock, and runoff from livestock pens. Long-term fecal coliform data from five sampling stations located within or in the vicinity of the municipio of Mayaguez have been in compliance with the water-quality goal for fecal coliform concentration established in July 1990. Geologic, topographic, soil, hydrogeologic, and streamflow data were compiled into a database and used to divide the municipio of Mayaguez into five hydrogeologic terranes. This integrated database then was used to evaluate the ground-water potential of each hydrogeologic terrane. Lineament-trace analysis was used to help assess the ground-water development potential in the hydrogeologic terranes containing igneous rocks. Analyses suggest that areas with slopes greater than 15 degrees have relatively low ground-water development potential. The presence of fractures, independent of the topographic slope, may locally enhance the water-bearing properties in the hydrogeologic terranes containing igneous rocks. The results of this study indicate that induced streamflow generally is needed to sustain low to moderate ground-water withdrawal rates in the five hydrogeologic terranes. The ground-water flow systems in the hydrogeologic terranes are only able to sustain small withdrawal rates that rarely exceed 50 gallons per minute. Areas with a high density of fractures, as could be the case at the intersection of lineament traces in the upper parts of the Rio Ca?as and Rio Yaguez watersheds, are worthy of exploratory drilling for ground-water development.

Water-Resources Investigations Report

Questa baseline and pre-mining ground-water quality investigation. 25. Summary of results and baseline and pre-mining ground-water geochemistry, Red River Valley, Taos County, New Mexico, 2001-2005

Active and inactive mine sites are challenging to remediate because of their complexity and scale. Regulations meant to achieve environmental restoration at mine sites are equally challenging to apply for the same reasons. The goal of environmental restoration should be to restore contaminated mine sites, as closely as possible, to pre-mining conditions. Metalliferous mine sites in the Western United States are commonly located in hydrothermally altered and mineralized terrain in which pre-mining concentrations of metals were already anomalously high. Typically, those pre-mining concentrations were not measured, but sometimes they can be reconstructed using scientific inference. Molycorp?s Questa molybdenum mine in the Red River Valley, northern New Mexico, is located near the margin of the Questa caldera in a highly mineralized region. The State of New Mexico requires that ground-water quality standards be met on closure unless it can be shown that potential contaminant concentrations were higher than the standards before mining. No ground water at the mine site had been chemically analyzed before mining. The aim of this investigation, in cooperation with the New Mexico Environment Department (NMED), is to infer the pre-mining ground-water quality by an examination of the geologic, hydrologic, and geochemical controls on ground-water quality in a nearby, or proximal, analog site in the Straight Creek drainage basin. Twenty-seven reports contain details of investigations on the geological, hydrological, and geochemical characteristics of the Red River Valley that are summarized in this report. These studies include mapping of surface mineralogy by Airborne Visible-Infrared Imaging Spectrometry (AVIRIS); compilations of historical surface- and ground- water quality data; synoptic/tracer studies with mass loading and temporal water-quality trends of the Red River; reaction-transport modeling of the Red River; environmental geology of the Red River Valley; lake-sediment chemistry; geomorphology and its effect on ground-water flow; geophysical studies on depth to ground-water table and depth to bedrock; bedrock fractures and their potential influence on ground-water flow; leaching studies of scars and waste-rock piles; mineralogy and mineral chemistry and their effect on ground-water quality; debris-flow hazards; hydrology and water balance for the Red River Valley; ground-water geochemistry of selected wells undisturbed by mining in the Red River Valley; and quality assurance and quality control of water analyses. Studies aimed specifically at the Straight Creek natural-analog site include electrical surveys; high-resolution seismic survey; age-dating with tritium/helium; water budget; ground-water hydrology and geochemistry; and comparison of mineralogy and lithology to that of the mine site. The highly mineralized and hydrothermally altered volcanic rocks of the Red River Valley contain several percent pyrite in the quartz-sericite-pyrite (QSP) alteration zone, which weather naturally to acid-sulfate surface and ground waters that discharge to the Red River. Weathering of waste-rock piles containing pyrite also contributes acid water that eventually discharges into the Red River. These acid discharges are neutralized by circumneutral-pH, carbonate-buffered surface and ground waters of the Red River. The buffering capacity of the Red River, however, decreases from the town of Red River to the U.S. Geological Survey (USGS) gaging station near Questa. During short, but intense, storm events, the buffering capacity is exceeded and the river becomes acid from the rapid flushing of acidic materials from natural scar areas. The lithology, mineralogy, elevation, and hydrology of the Straight Creek proximal analog site were found to closely approximate those of the mine site with the exception of the mine site?s Sulphur Gulch catchment. Sulphur Gulch contains three subcatchments?upper Sulphur Gulch, Blind Gulch, and Spring Gulc

New Mexico

Ground-water recharge in humid areas of the United States: A summary of Ground-Water Resources Program studies, 2003-2006

Increased demands on water resources by a growing population and recent droughts have raised awareness about the adequacy of ground-water resources in humid areas of the United States. The spatial and temporal variability of ground-water recharge are key factors that need to be quantified to determine the sustainability of ground-water resources. Ground-water recharge is defined herein as the entry into the saturated zone of water made available at the water-table surface, together with the associated flow away from the water table within the saturated zone (Freeze and Cherry, 1979). In response to the need for better estimates of ground-water recharge, the Ground-Water Resources Program (GWRP) of the U.S. Geological Survey (USGS) began an initiative in 2003 to estimate ground-water recharge rates in the relatively humid areas of the United States.

Fact Sheet

MODFLOW-2000, The U.S. Geological Survey modular ground-water model: User guide to modularization concepts and the ground-water flow process

MODFLOW is a computer program that numerically solves the three-dimensional ground-water flow equation for a porous medium by using a finite-difference method. Although MODFLOW was designed to be easily enhanced, the design was oriented toward additions to the ground-water flow equation. Frequently there is a need to solve additional equations; for example, transport equations and equations for estimating parameter values that produce the closest match between model-calculated heads and flows and measured values. This report documents a new version of MODFLOW, called MODFLOW-2000, which is designed to accommodate the solution of equations in addition to the ground-water flow equation. This report is a user's manual. It contains an overview of the old and added design concepts, documents one new package, and contains input instructions for using the model to solve the ground-water flow equation.

Open-File Report

Ground-water resources in Kaloko-Honokohau National Historical Park, Island of Hawaii, and numerical simulation of the effects of ground-water withdrawals

Within the Kaloko-Honokohau National Historical Park, which was established in 1978, the ground-water flow system is composed of brackish water overlying saltwater. Ground-water levels measured in the Park range from about 1 to 2 feet above mean sea level, and fluctuate daily by about 0.5 to 1.5 feet in response to ocean tides. The brackish water is formed by mixing of seaward flowing fresh ground water with underlying saltwater from the ocean. The major source of fresh ground water is from subsurface flow originating from inland areas to the east of the Park. Ground-water recharge from the direct infiltration of precipitation within the Park area, which has land-surface altitudes less than 100 feet, is small because of low rainfall and high rates of evaporation. Brackish water flowing through the Park ultimately discharges to the fishponds in the Park or to the ocean. The ground water, fishponds, and anchialine ponds in the Park are hydrologically connected; thus, the water levels in the ponds mark the local position of the water table. Within the Park, ground water near the water table is brackish; measured chloride concentrations of water samples from three exploratory wells in the Park range from 2,610 to 5,910 milligrams per liter. Chromium and copper were detected in water samples from the three wells in the Park and one well upgradient of the Park at concentrations of 1 to 5 micrograms per liter. One semi-volatile organic compound, phenol, was detected in water samples from the three wells in the Park at concentrations between 4 and 10 micrograms per liter. A regional, two-dimensional (areal), freshwater-saltwater, sharp-interface ground-water flow model was used to simulate the effects of regional withdrawals on ground-water flow within the Park. For average 1978 withdrawal rates, the estimated rate of fresh ground-water discharge to the ocean within the Park is about 6.48 million gallons per day, or about 3 million gallons per day per mile of coastline. Although the coastal discharge within the Park is actually brackish water, the model assumes that freshwater and saltwater do not mix and therefore the model-calculated coastal discharge within the Park is in the form of freshwater discharge. Model results indicate that ground-water withdrawals in excess of average 1978 withdrawal rates will reduce the rate of freshwater coastal discharge within the Park. Withdrawals from wells directly upgradient of the Park had the greatest effect on the model-calculated freshwater coastal discharge within the Park, whereas withdrawals from wells south of Papa Bay had little effect on the freshwater discharge within the Park. For an increased ground-water withdrawal rate of 56.8 million gallons per day, relative to average 1978 withdrawal rates in the Kona area, model-calculated freshwater coastal discharge within the Park was reduced by about 47 percent.

Hawaii

Ground-water quality data in the north San Francisco Bay hydrologic provinces, California, 2004: Results from the California Ground-water Ambient Monitoring and Assessment (GAMA) program

Ground-water quality in the ~1,000 square-mile (mi2) North San Francisco Bay study unit was investigated from August to November, 2004, as part of the California Groundwater Ambient Monitoring and Assessment (GAMA) program. Samples were collected from 89 public-supply wells, 7 hydrothermal wells, and 1 hydrothermal spring in Napa, Sonoma and Marin Counties. Eighty-four of the public-supply wells sampled were selected to provide a spatially distributed, randomized monitoring network for statistical calculations and constituent detection frequency. The study was designed to provide a spatially-unbiased assessment of raw ground-water quality within the study unit, as well as a statistically-consistent basis for comparing the water quality of different study units. Ground-water samples were analyzed for major and minor ions, trace elements, nutrients, volatile organic compounds, pesticides and pesticide degradates, waste-water indicators, dissolved methane, nitrogen, carbon dioxide and noble gases (in collaboration with Lawrence Livermore National Laboratory). Naturally occurring isotopes (tritium, carbon-14, oxygen-18, deuterium and helium-4) also were measured in the samples to help identify the source and age of the ground water. Results show that no anthropogenic constituents were detected at concentrations higher than those levels set for regulatory purposes, and relatively few naturally-occurring constituents were detected at concentrations greater than regulatory levels. In this study, 21 of the 88 volatile organic compounds (VOCs) and gasoline additives and (or) oxygenates investigated were detected in ground-water samples, however, detected concentrations were one-half to one-forty-thousandth the maximum contaminant levels (MCL). Thirty-two percent of the randomized wells sampled had at least a single detection of a VOC or gasoline additive and (or) oxygenate. The most frequently detected compounds were chloroform, found in 12 of the 84 randomized wells; carbon disulfide, found in 8 of the 84 randomized wells; and toluene, found in 4 of the 84 randomized wells. Trihalomethanes were the most frequently detected class of VOCs. Nine of the 122 pesticides and (or) pesticide degradates investigated were detected in ground-water samples, however, concentrations were one-seventieth to one-eight-hundredth the MCLs. Seventeen percent of the randomized wells sampled had at least a single detection of pesticide and pesticide degradate. Herbicides were the most frequently detected class of pesticides. The most frequently detected compound was simazine, found in 8 of the 84 of the randomized wells. Chlordiamino-s-triazine and deisopropyl atrazine were both found in 2 of the 84 randomized wells sampled. Thirteen out of 63 compounds that may be indicative of the prescence of waste-water were detected in ground-water samples. Twenty-six percent of the randomized wells sampled for waste-water indicators had at least one detection. Isophorone was the most frequently detected in 6 of the 84 randomized wells. Bisphenol-A, caffeine, and indole each were detected in 3 of the 84 randomized wells. Major and minor ions and dissolved solids (DS) samples were collected at 33 public-supply wells; 3 samples had DS concentrations above the secondary maximum contaminant level (SMCL) of 500 mg/L. Ground-water samples from 32 public-supply wells were analyzed for trace elements. Arsenic concentrations above the MCL of 10 μg/L were measured at 4 public-supply wells, boron concentrations above the detection level for the purpose of reporting (DLR) of 100 μg/L were measured at 19 wells. Iron concentrations above the SMCL of 300 μg/L were measured at 7 wells, a lead concentration above the California notification level (NL) of 15 μg/L at one well, and manganese concentrations above the SMCL of 50 μg/L were measured at 17 wells. Vanadium concentrations above the DLR of 3 μg/L were measured at 9 public-supply wells; and chromium(VI) concentrations above the DLR of 1 μg/L were measured at 48 public-supply wells. Major and minor ions and dissolved solids (DS) samples were collected at 33 public-supply wells; 3 samples had DS concentrations above the secondary maximum contaminant level (SMCL) of 500 mg/L. Ground-water samples from 32 public-supply wells were analyzed for trace elements. Arsenic concentrations above the MCL of 10 μg/L were measured at 4 public-supply wells, boron concentrations above the detection level for the purpose of reporting (DLR) of 100 μg/L were measured at 19 wells. Iron concentrations above the SMCL of 300 μg/L were measured at 7 wells, a lead concentration above the California notification level (NL) of 15 μg/L at one well, and manganese concentrations above the SMCL of 50 μg/L were measured at 17 wells. Vanadium concentrations above the DLR of 3 μg/L were measured at 9 public-supply wells; and chromium(VI) concentrations above the DLR of 1 μg/L were measured at 48 public-supply wells. Microbial constituents were analyzed in 22 ground-water samples. Total coliform was detected in three wells. Counts ranged from 2 colonies per 100 mL to 20 colonies per 100 mL. MCLs for microbial constituents are based on reoccurring detection, and will be monitored during future sampling.

California

Chemical composition of ground water, hydrologic properties of basin-fill material, and ground-water movement in Salt Lake Valley, Utah

The chemical composition and movement of ground water and hydrologic properties of the basin‑fill material were studied to better under‑ stand the flow system in Salt Lake Valley, Utah. Recharge sources and water‑rock interactions influence the water chemistry in the principal and shallow unconfined aquifers. Chloride concentration in water from some wells has increased from the 1950’s and 1960’s to 1992, possibly because of the infiltration of water that contains dissolved road salt and the movement of ground water with relatively high chloride concentrations from volcanic rocks in the vicinity of these wells. Hydraulic‑conductivity values determined from slug tests done on wells finished in the shallow unconfined aquifer and confining layers ranged from 0.003 to 33.4 feet per day. Transmissivity values determined for the principal aquifer from four multiple‑well aquifer tests ranged from 6,400 to 43,600 feet squared per day. Vertical hydraulic‑conductivity values estimated from these tests are from 0.01 to 1 foot per day. Water from 81 sites was analyzed for the stable‑isotope ratios of oxygen and hydrogen to determine sources of recharge and mixing of water from these sources. Water sampled from the principal aquifer in the southeastern part of the valley is isotopically similar to water in Big and Little Cottonwood Creeks. Ground water sampled from the shallow unconfined aquifer is generally enriched in oxygen‑18 and deuterium relative to other water in the valley, except for water from the Jordan River and its diversions, which are probable recharge sources. Tritium concentrations ranging from about 33 to 59 tritium units in water from the principal aquifer in the southeastern part of the valley are representative of concentrations in water that was recharged in the 1960’s.

Utah

Water-quality assessments of ground water and surface water in the Warwick aquifer area, Fort Totten Indian Reservation, North Dakota

A data summary was prepared to assess the quality of ground water and surface water in the Warwick aquifer area. During 1967-93, a total of 205 samples were collected from 61 wells and 18 surface-water locations, and the samples were analyzed for various water-quality constituents. Overall, the quality of ground water in the Warwick aquifer is within the selected drinking water guidelines for North Dakota, and the quality of water from wells less than or equal to 25 feet deep and wells greater than 25 feet deep is similar. Only a few water-quality constituents had concentrations that exceeded the selected drinking water guidelines for North Dakota. Arsenic concentrations neared or exceeded North Dakota drinking water standards in samples collected from two wells greater than 133 feet deep located within the production well field area. Thus, arsenic may be a concern in deeper portions of the aquifer. The quality of the surface water in the Warwick aquifer area was similar to the quality of the ground water in the aquifer. However, specific conductance, pH values, and concentrations of common agricultural pesticides generally are greater in the surface water than in the ground water.

Open-File Report

Movement and fate of creosote waste in ground water, Pensacola, Florida; U.S. Geological Survey toxic waste--ground-water contamination program

In 1983, the U.S. Geological Survey, Office of Hazardous Waste Hydrology, selected the former American Creosote Works site near Pensacola, Florida as a national research demonstration area. Seventy-nine years (1902-81) of seepage from unlined discharge impoundments had released creosote, diesel fuel, and pentachlorophenol (since 1950) wastes into the ground-water system. A cluster of from 2 to 5 wells constructed at different depths at 9 sites yielded water which revealed contamination 600 feet downgradient and to a depth of 100 feet below land surface near the site. The best cross-sectional representation of the contaminant plume was obtained from samples collected and analyzed for oxidation-reduction sensitive inorganic chemical constituents. Energy dispersive x-ray fluorescence detected recently formed iron carbonate in soil samples from highly reducing ground-water zones. Approximately eighty specific organic contaminants were isolated from ground-water samples by gas-chromotography/mass spectrometry. Column studies indicate the dimethyl phenols are not sorbed or degraded by the sand-and-gravel aquifer materials. Five of nineteen individual phenolic and related compounds are biodegradable based on anaerobic digestor experiments with ACW site bacterial populations. The potential impacts in the nearby Pensacola Bay biotic community are being evaluated. (USGS)

Open-File Report

Effects of alternative instream-flow criteria and water-supply demands on ground-water development options in the Big River Area, Rhode Island

Transient numerical ground-water-flow simulation and optimization techniques were used to evaluate potential effects of instream-flow criteria and water-supply demands on ground-water development options and resultant streamflow depletions in the Big River Area, Rhode Island. The 35.7 square-mile (mi2) study area includes three river basins, the Big River Basin (30.9 mi2), the Carr River Basin (which drains to the Big River Basin and is 7.33 mi2 in area), the Mishnock River Basin (3.32 mi2), and a small area that drains directly to the Flat River Reservoir. The overall objective of the simulations was to determine the amount of ground water that could be withdrawn from the three basins when constrained by streamflow requirements at four locations in the study area and by maximum rates of withdrawal at 13 existing and hypothetical well sites. The instream-flow requirement for the outlet of each basin and the outfall of Lake Mishnock were the primary variables that limited the amount of ground water that could be withdrawn. A requirement to meet seasonal ground-water-demand patterns also limits the amount of ground water that could be withdrawn by up to about 50 percent of the total withdrawals without the demand-pattern constraint. Minimum water-supply demands from a public water supplier in the Mishnock River Basin, however, did not have a substantial effect on withdrawals in the Big River Basin. Hypothetical dry-period instream-flow requirements and the effects of artificial recharge also affected the amount of ground water that could be withdrawn. Results of simulations indicate that annual average ground-water withdrawal rates that range up to 16 million gallons per day (Mgal/d) can be withdrawn from the study area under simulated average hydrologic conditions depending on instream-flow criteria and water-supply demand patterns. Annual average withdrawals of 10 to 12 Mgal/d are possible for proposed demands of 3.4 Mgal/d in the Mishnock Basin, and for a constant annual instream-flow criterion of 0.5 cubic foot per second per square mile (ft3/s/mi2) at the four streamflow-constraint locations. An average withdrawal rate of 10 Mgal/d can meet estimates of future (2020) water-supply needs of surrounding communities in Rhode Island. This withdrawal rate represents about 13 percent of the average 2002 daily withdrawal from the Scituate Reservoir (76 Mgal/d), the State?s largest water supply. Average annual withdrawal rates of 6 to 7 Mgal/d are possible for more stringent instream-flow criteria that might be used during dry-period hydrologic conditions. Two example scenarios of dry-period instream-flow constraints were evaluated: first, a minimum instream flow of 0.1 cubic foot per second at any of the four constraint locations; and second, a minimum instream flow of 10 percent of the minimum monthly streamflow estimate for each streamflow-constraint location during the period 1961?2000. The State of Rhode Island is currently (2004) considering methods for establishing instream-flow criteria for streams within the State. Twelve alternative annual, seasonal, or monthly instream-flow criteria that have been or are being considered for application in southeastern New England were used as hypothetical constraints on maximum ground-water-withdrawal rates in management-model calculations. Maximum ground-water-withdrawal rates ranged from 5 to 16 Mgal/d under five alternative annual instream-flow criteria. Maximum ground-water-withdrawal rates ranged from 0 to 13.6 Mgal/d under seven alternative seasonal or monthly instream-flow criteria. The effect of ground-water withdrawals on seasonal variations in monthly average streamflows under each criterion also were compared. Evaluation of management-model results indicates that a single annual instream-flowcriterion may be sufficient to preserve seasonal variations in monthly average streamflows and meet water-supply demands in the Big River Area, because withdrawals from wells in the Big

Scientific Investigations Report

Simulation of the Ground-Water Flow System in 1992, and Simulated Effects of Projected Ground-Water Withdrawals in 2020 in the New Jersey Coastal Plain

In 1992, ground-water withdrawals from the unconfined and confined aquifers in the New Jersey Coastal Plain totaled about 300 million gallons per day, and about 70 percent (200 million galllons per day) of this water was pumped from confined aquifers. The withdrawals have created large cones of depression in several Coastal Plain aquifers near populated areas, particularly in Camden and Ocean Counties. The continued decline of water levels in confined aquifers could cause saltwater intrusion, reduction of stream discharge near the outcrop areas of these aquifers, and depletion of the ground-water supply. Because of this, withdrawals from wells located within these critical areas have been reduced in the Potomac-Raritan-Magothy aquifer system, the Englishtown aquifer system, and the Wenonah-Mount Laurel aquifer. A computer-based model that simulates freshwater and saltwater flow was used to simulate transient ground-water flow conditions and the location of the freshwater-saltwater interface during 1989-92 in the New Jersey Coastal Plain. This simulation was used as the baseline for comparison of water levels and flow budgets. Four hypothetical withdrawal scenarios were simulated in which ground-water withdrawals were either increased or decreased. In scenario 1, withdrawals from wells located within critical area 2 in the Potomac-Raritan-Magothy aquifer system were reduced by amounts ranging from 0 to 35 percent of withdrawals prior to 1992. Critical area 2 is mainly located in Camden County, and most of Burlington and Gloucester Counties. With the reductions, water levels recovered about 30 feet in the regional cone of depression centered in Camden County in the Upper Potomac-Raritan-Magothy aquifer and by 20 ft in the Lower and Middle Potomac-Raritan-Magothy aquifers. In scenarios 2 to 4, withdrawals projected for 2020 were input to the model. In scenario 2, withdrawal restrictions within the critical areas were imposed in the Potomac-Raritan-Magothy aquifer system, the Englishtown aquifer system, and the Wenonah-Mount Laurel aquifer, but withdrawals were increased outside the critical areas to the projected 2020 demand. With withdrawals restrictions in critical areas, water levels recovered about 20 feet at the center of the regional cone of depression in the Upper Potomac-Raritan Magothy aquifer. Water levels recovered by about 20 feet at the center of a regional cone of depression in the Englishtown aquifer system in Ocean County, and by about 20 feet in the Wenonah-Mount Laurel aquifer in the same area. In scenario 3, withdrawals were increased to the projected 2020 demand inside and outside the critical areas. As a result, water levels declined as much as 20 feet at the center of a regional cone of depression in the Englishtown aquifer system in Ocean County, and as much as 10 feet in the Wenonah-Mounty Laurel aquifer near this area. The Englishtown aquifer system and the Wenonah-Mount Laurel aquifer are particularly sensitive to increases and decreases in withdrawals because in certain areas the transmissivities of these aquifers are lower than the transmissivities of other confined aquifers of the New Jersey Coastal Plain, and because these aquifers are hydraulically connected. Simulated water levels declined by as much as 10 ft at the center of the regional cone of depression in Atlantic County. In scenario 4, withdrawal amounts were equal to that in scenario 2, except an additional 13.2 million gallons per day was withdrawn from hypothetical wells located outside the critical areas in the Upper Potomac-Raritan-Magothy aquifer, Englishtown aquifer system, and the Wenonah-Mount Laurel aquifer. The additional withdrawals resulted in increased leakage from overlying aquifers to the Wenonah-Mount Laurel aquifer and subsequently to the Englishtown aquifer system.

Water-Resources Investigations Report