Search USGS⌕ Search

Geology topics

Research about Vermont

Source-linked reports with geographic coverage including Vermont.

At least 19 recordsLinked to original sources

Multiple lines of evidence reveal rapid, seasonal watershed responses to enhanced weathering

Enhanced weathering accelerates carbon dioxide removal from the atmosphere through the rapid dissolution of land amendments of crushed, cation-rich rocks. The export of enhanced weathering dissolution products to drainage networks has important implications for carbon dioxide removal durability and measurement yet has received little attention. Here we observe rapid and pronounced streamwater chemistry responses within weeks of a crushed basalt application to a temperate headwater catchment: alkalinity exceeded counterfactual estimates by as much as 557 μeq l −1 , accompanied by changes in silica, lithium and major-ion chemistry consistent with basalt weathering. Difference-in-differences analysis identified repeated treatment effects with enhanced weathering accounting for 7–17% of streamwater alkalinity in successive summers and autumns, but less in winter and spring. This seasonal response reflects a combination of temperature controls on basalt dissolution kinetics and hydrologic controls on weathering-product export. Over 2 years, 9.5–11% of theoretical carbon dioxide removal potential was exported as alkalinity (34.7 t CO 2 km −2 yr −1 ).

Vermont↗

Sex-specific reproductive investment and survival of adult Atlantic salmon kelts across multiple dams

In adult Atlantic salmon, individual variation in migration and movement within rivers during spawning (i.e., reproductive movement, RM) is an important component of overall reproductive investment that may influence subsequent survival and repeat spawning. We test the cost-of-reproduction hypothesis—which states that increased reproductive investment decreases survival—by first quantifying individual RM of landlocked Atlantic salmon and then evaluating how RM, sex, and dams influence outmigration survival. Consistent with sexual selection for male mobility, male RM was ~4 times greater than that of females: they moved further, were more exploratory, visited a tributary more, went further upstream, and spent longer in the river. Results provide mixed support for a cost of RM on outmigration survival: individuals (inclusive of both sexes) that abandoned spawning and migrated downstream (i.e., “fallbacks”) survived 3.5-fold better than those that spawned (supporting an overall cost-of reproduction). However, males (with higher RM) had 2.8 times higher survival than females, and among males there was no effect of RM on survival (not-supporting a cost-of-RM). The most influential factor on survival was dam interactions, which reduced per-kilometer survival 18-fold relative to migration within free-flowing reaches. Documenting male-biased survival was unexpected given the (1) high RM of males and (2) that most prior studies find higher outmigration survival of female Atlantic salmon. We highlight how dams exacerbate the already high costs of reproduction in Atlantic salmon, which has important implications for contemporary evolution of behavioral tradeoffs.

Vermont↗

3D Elevation Program—Vermont

Using 3D Elevation Program data, a modern illustration of each State's landscape showcases its elevation differences in vivid detail. Each State has been consistently adjusted and colorized according to its highest and lowest elevations, accentuating differences even in States with low relief. To further emphasize landforms, shaded relief has been added on top of the elevation colors.

Vermont↗

Estimating flood discharges at selected annual exceedance probabilities for unregulated, rural streams in Vermont, 2023

This report provides estimates of flood discharge at selected annual exceedance probabilities (AEPs) for streamgages in and adjacent to Vermont and equations for estimating flood discharges at AEPs of 50-, 20-, 10-, 4-, 2-, 1-, 0.5-, and 0.2-percent (recurrence intervals of 2-, 5-, 10-, 25-, 50-, 100-, and 500-years, respectively) for ungaged, unregulated, rural streams in Vermont with drainage areas between 0.47 and 851 square miles. The equations were developed using generalized least-squares regression and flood-frequency and drainage-basin characteristics from 156 streamgages. Flood-frequency analyses were completed using data through the 2023 water year. The drainage-basin characteristics used as explanatory variables in the regression equations are drainage area, percentage of wetland area, and basin-wide mean of the average annual precipitation. The average standard errors of prediction used to estimate flood discharges at the 50-, 20-, 10-, 4-, 2-, 1-, 0.5-, and 0.2-percent AEP with these equations are 34.9, 37.1, 38.2, 41.6, 43.8, 46.0, 49.1, and 53.2 percent, respectively. Flood discharges at selected AEPs for streamgages were computed using the Expected Moments Algorithm. Techniques used to adjust an AEP discharge computed from a streamgage record with results from the regression equations and to estimate flood discharge at a selected AEP for an ungaged site upstream or downstream from a streamgage using a drainage-area adjustment are both described. The final regression equations and the flood-discharge frequency data used in this study will be available in StreamStats. StreamStats is an internet-based application that provides automated regression-equation solutions for user-selected sites on streams.

Vermont↗

Observations of tear-drinking by lepidopterans on moose ( Alces alces americana ) in northeastern North America

Lepidoptera have long been known to feed on the tears of vertebrates as a presumed source of minerals or nutrients. While this unusual behavior has been observed in a variety of species, only a single previous record has been documented outside of the tropics. Here, we present the first documentation of moths visiting the eyes of a bull moose ( Alces americanus americanus ), captured via trail camera in Green Mountain National Forest, Vermont, United States. We discuss the biogeography of this behavior, how it may differ between tropical and temperate climates, and its potential impact on moose health.

Vermont↗

The 3D Elevation Program—Supporting Vermont's economy

Introduction The geographic information system (GIS) community in Vermont has a long history of interdisciplinary and cooperative projects that have facilitated the leveraging of geospatial technology on myriad data acquisitions across the State. High-resolution elevation data are proving to be a resource of great economic value in dealing with many important issues in Vermont. Vermont attained statewide coverage of quality level 2 coverage of topographic light detection and ranging (lidar) data in 2019. Having access to elevation data that are exponentially more accurate than what was previously available is enabling GIS professionals to better support and empower decision makers in economically important efforts such as environmental protection, public safety, watershed management and water quality, geology, transportation planning, forest and wildlife management, local planning, and flood plain management. In addition, developing a consistent and seamless statewide topographic framework supplants the traditionally time consuming and costly approach of extensive field data collection by requiring less time and money, therefore adding economic benefits. Critical applications that meet the State’s management needs depend on lidar data that provide a highly detailed three-dimensional (3D) model of the Earth’s surface and aboveground features. The 3D Elevation Program (3DEP) is managed by the U.S. Geological Survey (USGS) in partnership with Federal, State, Tribal, U.S. territorial, and local agencies to acquire consistent lidar coverage at quality level 2 or better to meet the many needs of the Nation and Vermont. The status of available and in-progress 3DEP baseline lidar data in Vermont is shown in figure 1. 3DEP baseline lidar data include quality level 2 or better, 1-meter or better digital elevation models, and lidar point clouds, and must meet the Lidar Base Specification version 1.2 ( https://www.usgs.gov/3dep/lidarspec ) or newer requirements. The National Enhanced Elevation Assessment identified user requirements and conservatively estimated that availability of lidar data would result in at least $1.64 million in new benefits annually to the State. The top eight Vermont business uses for 3D elevation data, which are based on the estimated annual conservative benefits of 3DEP, are shown in table 2.

Vermont↗

Long‑term monitoring of mercury in Vermont’s forest soils: Trends over 20 years in near–surface horizons

Mercury is a soil pollutant of widespread concern, usually derived from airborne deposition. A long–term forest soil monitoring program began in 2002 at five sites (elevation 590–1140 m) in Vermont, USA. Total mercury (THg) and soil organic carbon (SOC) were assessed in the uppermost humified soil layer, either an Oa or A horizon. Sampling occurred every 5 years from ten subplots at each site. Tree species ranged from deciduous, mixed deciduous/conifer, to all conifer. After five samplings, the site means for THg ranged from 167 to 447 µg kg –1 and increased linearly with elevation ( R 2 = 0.78). One site had a significant temporal increase in THg of 3.9 µg kg –1 yr –1 ( p = 0.02). Overall SOC site means ranged from 133 to 434 g kg –1 . One site showed a significant temporal increase in SOC ( p = 0.01). The mean ratio of THg:SOC was similar at four of the sites (1318–1518 µg kg –1 ) but much lower (648 µg kg –1 ) at the site with the highest SOC and the temporal increase in THg. Within individual subplots, THg increased up to a maximum SOC concentration of ~ 320 g kg –1 and usually decreased above that threshold. Although both wet and dry mercury deposition in the northeast USA have declined, no evidence of declining soil THg concentration was found, likely due to strong retention by SOC. Continued monitoring is essential considering ongoing changes in deposition and future changes in the source–sink balance of mercury.

Vermont↗

Flood of July 2023 in Vermont

A major storm caused catastrophic flooding in many parts of Vermont on July 9–12, 2023, resulting in millions of dollars in damages. The high amount of rainfall caused several rivers to peak at record levels, in some cases exceeding records set during Tropical Storm Irene in 2011. The U.S. Geological Survey, in cooperation with the Federal Emergency Management Agency, collected and analyzed data that characterized the flood in Vermont. The data collected included peak water-surface elevations, taken from high-water marks at bridges, dams, and roads, and peak streamflow and annual exceedance probabilities (AEPs) at streamgages, lake gages, and selected ungaged locations. At 11 of the 80 streamgages with 12 to 94 years of record, the July 2023 peak streamflow was the peak of record. Ten streamgages recorded a peak streamflow with an AEP of less than or equal to 1 percent (greater than or equal to a 100-year recurrence interval). The July 2023 flood affected many of the same communities as the historical flood caused by Tropical Storm Irene in 2011. Twenty of the 45 continuous-recording streamgages running during both events recorded greater peak streamflows during the July 2023 flood than during Tropical Storm Irene in 2011. Four of the 11 U.S. Geological Survey streamgages with period-of-record maximum peak streamflows observed during the July 2023 flood had previously recorded their maximum period-of-record peak streamflows during Tropical Storm Irene. There were 17 rivers in Vermont that were surveyed for high-water marks during both Tropical Storm Irene and the July 2023 flood. On those 17 rivers, a total of 103 sites contained surveyed high-water marks for both events. Thirty-two of these sites had higher surveyed elevations for the July 2023 flood than Tropical Storm Irene, including Black River in Newport, Black River in Springfield, Jewell Brook, Middlebury River, Missisquoi River, Ottauquechee River, Otter Creek, Wells River, Whetstone Brook, and Winooski River. Peak water-surface elevations were not collected on the Lamoille River in 2011. Federal Emergency Management Agency flood insurance studies were evaluated in the context of the July 2023 flood. Peak streamflows at streamgages and nearby locations were assessed to determine the influence of the July 2023 flood on the AEPs used in past studies. Overall, 21 of 26 streamflow-computation locations in the flood insurance studies had more than a 10 percent difference in the 1-percent AEP streamflow. A hydraulic evaluation of surveyed water-surface elevations following the July 2023 flood was compared with the AEP profiles from past studies. Four of the 10 streamgages analyzed had poor alignment between the AEPs of the observed streamflows and the AEPs of the observed peak water-surface elevations as computed from flood insurance studies.

Vermont↗

Spatial variation in landlocked Atlantic Salmon smolt survival associated with dam passage, avian predation, and stocking location

Objective We evaluated survival differences between upstream and downstream stocking for landlocked Atlantic Salmon Salmo salar smolts in a tributary to Lake Champlain. Methods We radio-tagged smolts and stocked them concurrently with 22,000 smolts at two release sites in 2 years. The downstream location (DS, river kilometer 16, no dam passage) was a historically used site in a dam tailrace, whereas the upstream site (US, river kilometer 27, two dams to pass) was in a side channel and stocked for the first time. We estimated survival, counted birds during stocking, and searched nesting colonies for transmitters. Results Within stocking reaches, survival per kilometer for the DS release group was markedly lower than that for the US group (US 2021 and 2022 = 0.98, 0.98, respectively; DS 2021 and 2022 = 0.82, 0.69, respectively). At the DS site, we documented a tenfold increase in avian predators following stocking, whereas no increase was detected at the US site. Passage was >96% at both dams, but postpassage survival (per kilometer) was much lower at the second dam (2021 = 0.78, 2022 = 0.82) compared to the first dam (2021 = 0.96, 2022 = 0.97). Surprisingly, cumulative survival to Lake Champlain was higher for fish that were released upstream in 2022 (US = 43%; DS = 32%) despite dam passage and additional migratory distance. At least 20% (2021) and 7% (2022) of successful migrants were later consumed by birds in the river delta or in Lake Champlain. Conclusions Upstream stocking did not consistently result in lower cumulative survival, likely due to predators habituated to annually reoccurring stocking in a dam tailrace that increased stocking-related mortality at the DS release site. We highlight the importance of evaluating historically used stocking sites, as substantial loss of smolts could be avoided by simple changes to stocking practices. Avian predation was a major source of mortality, necessitating further studies to understand and address survival issues within Lake Champlain.

Vermont↗

Two-stage models improve machine learning classifiers in wildlife research: A case study in identifying false positive detections of Ruffed Grouse

Autonomous recording units are increasingly being used to monitor wildlife on large geographic and temporal scales, paired with machine learning (ML) to automate detection of wildlife. However, false positive detections from ML classifiers can result in erroneous ecological models that can lead to misguided management and conservation actions. We used a two-stage general approach to understand and reduce false positive detections, a technique in which outputs of the primary classification model are passed to a secondary classification model to yield the probability that a detection from the primary model is a true positive detection. This approach is demonstrated on two open-source models that detect Ruffed Grouse ( Bonasa umbellus ). We analyzed over 9500 h of acoustic data collected in 2022–2023 from the Green Mountain National Forest in Vermont, USA, and found the two models detected different types of acoustic signals associated with differing life history traits. The first model yielded 4106 detections (71.5 % true positives) while the second model yielded 524 detections (17.0 % true positives). Secondary logistic regression models separated true positives and false positives with high accuracy (84.5 % and 89.8 % respectively). Our findings go beyond improving Ruffed Grouse monitoring and conservation efforts to, more broadly, illustrate how two-stage ML approaches can improve the use of model-derived detections in wildlife research.

Vermont↗

Long-term trends of streamwater chemistry in an agricultural watershed: Effects of anthropogenic and climatic factors

The chemistry of headwater streams is a key indicator of the health of riparian zones and surrounding terrestrial ecosystems. This chemistry is shaped by biogeochemical processes, including chemical weathering, and anthropogenic activities that interact with one another and are sensitive to climate. Elucidating trends in streamwater chemistry and the drivers that underpin them is essential for informing land-management decisions and anticipating water-quality issues that may affect downstream waters. In this work, we investigated the effects of anthropogenic and climatic factors on long-term variations in the chemistry of a first-order stream draining an agricultural catchment nested within the Sleepers River Research Watershed in Vermont, USA. We observed statistically significant increases in alkalinity and the concentrations of calcium and magnesium over a 31-year period for which 17 years of measurements were available. Through the application of generalized linear models, we found that the upward trends in alkalinity and calcium were associated with rising air temperatures, while a response to historical acid deposition played a minor role. We hypothesize that increased production of biogenic carbon dioxide and organic acids in soil and groundwater may lead to increases in chemical weathering rates under warmer climate conditions. This study emphasizes the important role of rising temperatures in the long-term increase in streamwater alkaline solutes, potentially overshadowing other influences like acidification recovery and agricultural practices. It also highlights the importance of comprehensive, long-term research to understand climate impacts on chemical weathering and inland water chemistry, which is critical for managing water quality and understanding regional and global carbon cycles.

Vermont↗

Estimated reductions in phosphorus loads from removal of leaf litter in the Lake Champlain drainage area, Vermont

Excess nutrient loading and other factors are driving eutrophication and other negative effects on water-quality conditions in Lake Champlain and other receiving waters in Vermont. Two common best management practices were evaluated to determine how these practices can be optimized by targeting maintenance and operation to align better with seasonally driven needs, specifically to help municipalities remove a greater proportion of seasonal leaves and organic debris, reduce nutrient loading, and achieve water-quality goals. To characterize solid materials typically removed by the municipal BMPs of catch-basin (CB) cleaning and street cleaning (SC), subsamples of CB and SC materials were collected each month from nine participating municipalities in central and northwestern Vermont between September 2017 and November 2018. Monthly and seasonal composites of CB and SC samples were created from the subsamples of available materials from all municipalities. Samples were analyzed for concentrations of total organic carbon, total Kjeldahl nitrogen, and total phosphorus (P), and separated into three particle-size fractions. Distribution of particle-size fractions was similar between CB and SC as both practices generally collect the coarser fraction of solid materials (greater than 125 micrometers in diameter). In the fall, however, the range of the coarser fraction of materials increased. This is attributed to the ability of SC to collect leaves and other light organic materials that commonly pass through a CB system designed to trap heavier materials. Total organic carbon, total Kjeldahl nitrogen, and total P concentrations were highest in the catch-basin samples in the fall of 2017, and concentrations in the SC samples were highest in the fall of 2018. The collection of fewer samples in 2017 may account for some of the variability between fall 2017 and fall 2018 results. A subset of SC samples collected from piles representing specific street-cleaning routes in September and November 2018 were also analyzed. Materials collected in November were dominated by leaves, and the concentrations of the analyzed species of carbon, nitrogen, and phosphorus in some samples were more than double those in samples collected on the same street-cleaning routes in September. The Vermont Department of Environmental Conservation and the University of Vermont developed estimates of load-reduction credits for CB and SC practices based on a policy developed by the Wisconsin Department of Natural Resources that determined the potential for credits associated with leaf-removal activities. This process also considered BMPs that were initiated during the U.S. Environmental Protection Agency’s Lake Champlain Basin Total Maximum Daily Load monitoring period (2000 to 2009) and adapted the Wisconsin Department of Natural Resources policies to apply to existing SC routes in the cooperating Vermont municipalities that possessed at least 17 percent tree cover. This exercise demonstrated that applying the Wisconsin Department of Natural Resources policy to existing street-cleaning routes possessing 17 percent or more tree cover would result in reductions in total P loads up to 65 percent of mandated target reductions, and about a 25 percent reduction on average. Continuous simulations of stormwater runoff volume, and of loads of suspended sediments and total P, also were created for Englesby Brook Basin, an urbanized basin in Burlington and South Burlington that drains to Lake Champlain. Although the basin is more developed than the average of the nine cooperating municipalities, streamflow and P loading data collected by the U.S. Geological Survey were available to evaluate model performance. Simulations based on a year of average climatic conditions projected potential small reductions in total P of 0.08 to 0.10 percent as a result of CB cleaning and SC practices. Simulated weekly SC practices, however, reduced street-solid loads by as much as 7 percent. When the proportion of total P seen in fall SC materials collected in Vermont was applied to these simulated street-solid loads, estimated reductions of total P were about 29 percent. The combination of analytical results, estimated load-reduction credits, and simulated reductions indicate that targeted increases of SC activities to reduce leaf loading in the fall have the potential to reduce loading to receiving waters and could help regulated communities meet their water-quality goals.

Vermont↗

Illuminating the “invisible”: Substantial deep respiration and lateral export of dissolved carbon from beneath soil

Dissolved organic and inorganic carbon (DOC and DIC) influence water quality, ecosystem health, and carbon cycling. Dissolved carbon species are produced by biogeochemical reactions and laterally exported to streams via distinct shallow and deep subsurface flow paths. These processes are arduous to measure and challenge the quantification of global carbon cycles. Here we ask: when, where, and how much is dissolved carbon produced in and laterally exported from the subsurface to streams? We used a catchment-scale reactive transport model, BioRT-HBV, with hydrometeorology and stream carbon data to illuminate the “invisible” subsurface processes at Sleepers River, a carbonate-based catchment in Vermont, United States. Results depict a conceptual model where DOC is produced mostly in shallow soils (3.7 ± 0.6 g/m 2 /yr) and in summer at peak root and microbial respiration. DOC is flushed from soils to the stream (1.0 ± 0.2 g/m 2 /yr) especially during snowmelt and storms. A large fraction of DOC (2.5 ± 0.2 g/m 2 /yr) percolates to the deeper subsurface, fueling deep respiration to generate DIC. DIC is exported predominantly from the deeper subsurface (7.1 ± 0.4 g/m 2 /yr, compared to 1.3 ± 0.3 g/m 2 /yr from shallow soils). Deep respiration reduces DOC and increases DIC concentrations at depth, leading to commonly observed DOC flushing (increasing concentrations with discharge) and DIC dilution patterns (decreasing concentrations with discharge). Surprisingly, respiration processes generate more DIC than weathering in this carbonate-based catchment. These findings underscore the importance of vertical connectivity between the shallow and deep subsurface, highlighting the overlooked role of deep carbon processing and export.

Vermont↗

Disentangling the responses of dissolved organic carbon and nitrogen concentrations to overlapping drivers in a northeastern United States forested watershed

The concurrent reduction in acid deposition and increase in precipitation impact stream solute dynamics in complex ways that make predictions of future water quality difficult. To understand how changes in acid deposition and precipitation have influenced dissolved organic carbon (DOC) and nitrogen (N) loading to streams, we investigated trends from 1991 to 2018 in stream concentrations (DOC, ~3,800 measurements), dissolved organic nitrogen (DON, ~1,160 measurements), and dissolved inorganic N (DIN, ~2,130 measurements) in a forested watershed in Vermont, USA. Our analysis included concentration-discharge (C-Q) relationships and Seasonal Mann-Kendall tests on long-term, flow-adjusted concentrations. To understand whether hydrologic flushing and changes in acid deposition influenced long-term patterns by liberating DOC and dissolved N from watershed soils, we measured their concentrations in the leachate of 108 topsoil cores of 5 cm diameter that we flushed with solutions simulating high and low acid deposition during four different seasons. Our results indicate that DOC and DON often co-varied in both the long-term stream dataset and the soil core experiment. Additionally, leachate from winter soil cores produced especially high concentrations of all three solutes. This seasonal signal was consistent with C-Q relation showing that organic materials (e.g., DOC and DON), which accumulate during winter, are flushed into streams during spring snowmelt. Acid deposition had opposite effects on DOC and DON compared to DIN in the soil core experiment. Low acid deposition solutions, which mimic present day precipitation, produced the highest DOC and DON leachate concentrations. Conversely, high acid deposition solutions generally produced the highest DIN leachate concentrations. These results are consistent with the increasing trend in stream DOC concentrations and generally decreasing trend in stream DIN we observed in the long-term data. These results suggest that the impact of acid deposition on the liberation of soil carbon (C) and N differed for DOC and DON vs. DIN, and these impacts were reflected in long-term stream chemistry patterns. As watersheds continue to recover from acid deposition, stream C:N ratios will likely continue to increase, with important consequences for stream metabolism and biogeochemical processes.

Vermont↗

Birth rates and neonate survival in a parasite rich moose population in Vermont, USA

Moose ( Alces alces ) populations are declining across much of their southern geographic range in North America. In Vermont and other northeastern states, measurable declines are attributed to low calf survival and reduced productivity associated with persistent winter tick ( Dermacentor albipictus ) parasitism. In 2017–2020, we studied 75 radio-collared female moose (38 calves and 37 adults) in Vermont to examine physiological, spatial, and temporal parameters relative to calf survival and adult productivity. Physiological measures included concentration of fecal glucocorticoid metabolites (fGCM) which reflects stress, and urea nitrogen:creatinine ratios in urine (UN:C) which proxy nutritional state. The pregnancy rate at capture across years was 0.67 (95% CI = 0.50 – 0.80), and was negatively related to presence of lungworm ( Dictyocaulus spp.). The birth rate calculated as the average number of offspring delivered per adult female was <1.0 overall (2017–2020, LCI = 0.22, UCI = 0.86), similar across years, but increased with age. Logistic exposure models indicated that daily calf survival to 60 d increased as Julian birth date and days since birth increased (log odds = 0.0819, SE = 0.0215). The per capita independence rate, or rate that adult females add independent calves to the population, was negatively related to UN:C ratios and positively with fGCM. Further, this rate was related to autumnal habitat use of adult females; it was greater in home ranges characterized by large amounts of mature (canopy) evergreen forests and wetland habitats, and small amounts of mixed forests and elevation than in ranges with abundant levels of mixed forest at high elevation. We conclude that winter ticks can negatively affect moose fecundity, and efforts to reduce host (moose) density through harvest or parasite (host) abundance through habitat manipulation may improve productivity and recruitment in local moose populations.

Vermont↗

Optical properties of dissolved organic matter in throughfall and stemflow vary across tree species and season in a temperate headwater forest

Tree-derived dissolved organic matter (DOM) comprises a significant carbon flux within forested watersheds. Few studies have assessed the optical properties of tree-derived DOM. To increase understanding of the factors controlling tree-derived DOM quality, we measured DOM optical properties, dissolved organic carbon (DOC) and calcium concentrations in throughfall and stemflow for 17 individual rain events during summer and fall in a temperate deciduous forest in Vermont, United States. DOC and calcium fluxes in throughfall and stemflow were enriched on average 4 to 70 times incident fluxes in rain. A multiway model was developed using absorbance and fluorescence spectroscopy to further characterize DOM optical properties. Throughfall contained a higher percentage of protein-like DOM fluorescence than stemflow while stemflow was characterized by a higher percentage of humic-like DOM fluorescence. DOM absorbance spectral slopes in yellow birch ( Betula alleghaniensis ) stemflow were significantly higher than in sugar maple ( Acer saccharum ) stemflow. DOM optical metrics were not influenced by rainfall volume, but percent protein-like fluorescence increased in throughfall during autumn when leaves senesced. Given the potential influence of tree-derived DOM fluxes on receiving soils and downstream ecosystems, future modeling of DOM transport and soil biogeochemistry should represent the influence of differing DOM quality in throughfall and stemflow across tree species and seasons.

Vermont↗

Seasonal movements and spatial overlap of juvenile and adult lake sturgeon in Lake Champlain

The lake sturgeon Acipenser fulvescens is a large, long-lived, potamodromous species that is widely distributed throughout freshwater systems in the central part of North America. In this study, we used acoustic telemetry to examine seasonal distribution and movement patterns of endangered Lake Sturgeon in Lake Champlain, Vermont. Acoustic tags were implanted in 29 juvenile Lake Sturgeon (453–874 mm TL) and 19 adults (1,215–1,615 mm TL) from the Winooski River and nearby areas of Lake Champlain between 2015 and 2019; tags were detected with 23 passive acoustic receivers deployed in the river and delta area and an additional 34 receivers deployed throughout Lake Champlain. Home range analysis using a lattice-based density estimator indicated that juvenile home range sizes were the same as adult home range sizes in spring and summer but were statistically larger than adult home ranges in winter. Cumulative home range analysis showed that juvenile and adult home ranges overlapped in shallow (<10-m) water in the summer and fall. In winter and spring, cumulative home ranges from juveniles included deepwater sites (>25 m), while adults remained in shallow water near the mouth of their spawning river. Seven juveniles made long-range movements (18–34 km) during the winter and spring months, and 13 juveniles moved back into the lower section of their natal river after overwintering in Lake Champlain. This study is the first to directly compare adult and juvenile Lake Sturgeon distribution, home range size, movements, and habitat use in a large lake system and provides a baseline for further research on the movement ecology of Lake Sturgeon in Lake Champlain.

Vermont↗

Using dissolved organic matter fluorescence to predict total mercury and methylmercury in forested headwater streams, Sleepers River, Vermont USA

Aqueous transport of mercury (Hg) across the landscape is closely linked to dissolved organic matter (DOM). Both quantity and quality of DOM affect Hg mobility, as well as the formation and transport of toxic methylmercury (MeHg), but only a limited number of field studies have investigated Hg and MeHg with respect to specific DOM components. We investigated these interactions at the 41-ha forested W-9 catchment at Sleepers River, Vermont, which has a long history of mercury and other biogeochemical research. We examined spatial and temporal patterns of filtered Hg fractions and dissolved organic carbon (DOC) concentration, DOM quality, and major solutes at 12 stream sites within W-9 and the downstream W-3 gage (837 ha) over five sampling campaigns including a large (79 mm) fall storm, spring snowmelt, and three seasonally contrasting base flow periods. Filtered total Hg (THg), MeHg, and DOC concentrations increased in order base flow < snowmelt < fall storm, except that MeHg remained at baseflow levels during snowmelt. Ranges of median concentrations across sites for the five campaigns were THg, <0.2–4.1 ng L −1 ; MeHg, <0.03–0.45 ng L −1 ; and DOC, 0.8–14.0 mg L −1 . Humic-like DOM fluorescence components, as determined by parallel factor analysis (PARAFAC), dominated the fluorescence across sites and sampling campaigns. THg correlated strongly ( r > 0.94) with these humic components, but even more strongly with bulk DOC and absorbance at 254 nm (UV 254 ; r > 0.96), and less strongly with protein-like DOM (0.7 < r < 0.9). MeHg correlated in the same order but less strongly with humic- (0.8 < r < 0.9) and protein-like (0.6 < r < 0.8) DOM. MeHg increased in summer, potentially in response to enhanced microbial production in warmer periods. MeHg formation may have been linked to protein-like DOM, but its transport was linked to humic-like DOM.

Vermont↗