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Research about Massachusetts

Source-linked reports with geographic coverage including Massachusetts.

13 recordsLinked to original sources

A methods framework for evaluating measurement consistency across spectrometers for multispectral uncrewed aerial system vegetation mapping applications

The U.S. Geological Survey collects remote sensing data to support national scientific assessments of natural resources, hazards, and landscape change. Spectrometers and spectroradiometers are essential for gathering point-based spectral measurements used in applications such as uncrewed aerial systems (UAS) multispectral image calibration, validation, and analysis. Evaluating how different instruments perform in laboratory and field environments helps determine whether they provide consistent, interoperable measurements. Such verification can expand access to spectral ground data during UAS operations by allowing scientists to use alternative instruments when budgets, logistics, or field conditions limit options. We propose and test a methodological framework for evaluating spectrometers for measurement consistency during UAS multispectral vegetation mapping applications. There are three central evaluation components to the framework: laboratory, field, and relative to UAS multispectral imagery. By evaluating the instruments in both relatively controlled and uncontrolled environments, we thoroughly examine measurement consistency and when/why measurements may differ. We opportunistically selected two instruments for a case study in a coastal marsh setting: a compact laboratory spectrometer we modified for field use and a field-ready spectroradiometer. The instruments produced consistent measurements in both environments. We found differences between the field spectra and UAS spectra that likely reflect the perspectives of ground vs. aerial data and indicate that further radiometric calibration may be needed.

Massachusetts

PFAS mixture composition and internal exposure profiles shape biological responses under field-realistic exposure

Per- and polyfluoroalkyl substances (PFAS) occur as complex mixtures, yet mixture-dependent biological effects under environmentally realistic exposure conditions remain poorly understood. We conducted multiyear (2018, 2019, 2021) continuous-flow, field-based exposures of male fathead minnows ( Pimephales promelas ) using a low-PFAS reference well (REF; sum of measured PFAS (∑PFAS) 0.1–0.2 μg L –1 ) and PFAS-contaminated groundwater from a fire-training area (FTA) at Joint Base Cape Cod, Massachusetts. Dilution treatments enabled separation of concentration and mixture effects. Groundwater from well FTA1 was perfluorooctanesulfonate (PFOS) dominated (∑PFAS 10–31 μg L –1 ), whereas groundwater from well FTA2 had higher concentrations and was enriched in perfluorooctanoate (PFOA) and diverse precursors (∑PFAS ∼ 80 μg L –1 ). Despite comparable plasma ∑PFAS and PFOS in FTA1–100% and FTA2–50% on day-7, cumulative mortality reached approximately 35% in FTA2–50% and 17% in FTA2–100%, and secondary sex trait expression was reduced by approximately 65–80% relative to REF, whereas sperm motility effects were mixture- and time-dependent. Plasma PFAS profiles were dominated by perfluorohexanesulfonate (PFHxS), PFOS, and sulfonamide precursors. Liver transcriptomics from REF-acclimated fish revealed robust disruption of metabolic, mitochondrial, and endocrine pathways that link PFAS mixture chemistry and internal exposure profiles to organismal outcomes, and testis transcriptomics provided complementary insight into reproductive impairment. These results indicate that PFAS mixture composition and internal exposure profiles, including precursor-associated differences, are important determinants of ecotoxicological outcomes under field-realistic conditions.

Massachusetts

Tracking baseflow supply dynamics using SWOT data from small groundwater-dominated lakes

In situ surface-water monitoring strategies are biased towards larger perennial streams and lakes and are generally not designed to track mechanisms of baseflow supply contributed by the dynamic storage of aquifers. Additionally, small (< 1 km 2 ) groundwater-influenced lakes and wetlands globally have little in situ monitoring infrastructure. We explored the utility of remotely sensed Surface Water Ocean Topography Satellite (SWOT) data, collected from 2023 onward, to characterise the seasonal and multi-year water-level trends of groundwater flow-through kettle lakes distributed across the permeable sediments of eastern Massachusetts, USA. This analysis indicated that water levels for kettle lakes with areas down to approximately 0.05 km 2 are resolvable in the study area. Our examination of 17 kettle lakes found that SWOT water-surface elevation data closely tracked groundwater levels in adjacent monitoring wells where available, including the timing of seasonal patterns (highest levels generally in late spring), although there was some variation between years and there was a substantial lag in the timing of high water levels for a lake located downgradient from a 30-m-thick vadose zone. Furthermore, SWOT-observed water-level increases in kettle lakes tracked with baseflow increases in two adjacent groundwater-dominated streams, as would be expected from increased hydraulic gradients. Unlike spectral remote sensing, SWOT data are generally not affected by cloud cover, resulting in a potential for groundwater-dominated lakes to be sentinels of dynamic storage patterns, including identification of baseflow drought lags, which are currently ill-defined hydrological processes. SWOT monitoring of groundwater-influenced surface waters shows potential for augmenting existing monitoring wells and streamgages as continuous monitors of groundwater levels and baseflow supply in permeable terrain.

Massachusetts

The 3D Elevation Program—Supporting the economy of Massachusetts

Introduction Massachusetts extends from the mountains of the Appalachian system in the west of the State to the sandy beaches and rocky shorelines of the Atlantic coast in the east. Inland topographic data support a wide range of important activities, including geologic mapping, transportation planning, forest and wildlife management, quantifying ecological services, water supply protection, commonwealth-wide infrastructure planning, local site planning, and flood-plain management. Nearshore bathymetry can be used to support coastal portions of the Commonwealth by addressing the combined threats of ocean warming, strong storm surge, and rising sea levels. The maintenance and (or) expansion of Massachusetts ports (for instance, Boston, New Bedford) and Cape Cod sediment management depends upon the accurate mapping of bathymetry and the frequent influx of sediment and redeposition. Critical applications that address the broad range of requirements depend on light detection and ranging (lidar) data that provide a highly detailed three-dimensional (3D) model of the Earth’s surface and aboveground features. The 3D Elevation Program (3DEP) is managed by the U.S. Geological Survey (USGS) in partnership with Federal, State, Tribal, U.S. territorial, and local agencies to acquire consistent lidar coverage at quality level 2 or better to meet the many needs of the Nation and Massachusetts. The status of available and in-progress 3DEP baseline lidar data in Massachusetts is shown in figure 1. 3DEP baseline lidar data include quality level 2 or better, 1-meter or better digital elevation models, and lidar point clouds, and must meet the Lidar Base Specification version 1.2 ( https://www.usgs.gov/3dep/lidarspec ) or newer requirements. The National Enhanced Elevation Assessment identified user requirements and conservatively estimated that availability of lidar data would result in at least $1.23 million in new benefits annually to Massachusetts. The top 10 Massachusetts business uses for 3D elevation data, which are based on the estimated annual conservative benefits of 3DEP, are shown in table 2.

Massachusetts

Methods for estimating selected low-flow statistics at gaged and ungaged stream sites in Massachusetts

The U.S. Geological Survey, in cooperation with the Massachusetts Department of Conservation and Recreation, Office of Water Resources, computed selected at-site streamflow statistics at U.S. Geological Survey streamgages in and near Massachusetts and developed regional regression equations for estimating selected streamflows at ungaged stream sites in Massachusetts. Two sets of regional regression equations were developed: (1) the “mainland” equations, for mainland Massachusetts excluding the area covered by the second set, and (2) the “southeastern” equations, for the Plymouth-Carver-Kingston-Duxbury aquifer area in southeastern Massachusetts and for Cape Cod. The regression equations and at-site statistics may be used by Federal, State, and local water managers in addressing water-resources issues relevant in Massachusetts. Regional regression analyses for the mainland equations were developed to estimate the following 27 streamflow statistics: 99-, 98-, 95-, 90-, 85-, 80-, 75-, 70-, 60-, and 50-percent flow durations; monthly June, July, August, and September 90- and 50-percent flow durations; February, June, and August median of the monthly means; harmonic mean; and medians of the following annual low-flow frequency statistics: 7-day; 7-day, 2-year; 7-day, 10-year; 30-day, 2-year; and 30-day, 10-year. The analyses used 81 streamgages with minimal to no regulations in and near Massachusetts. The regression analyses determined that four basin characteristics—drainage area, combined hydrologic soils A and B, streamflow variability index, and annual mean temperature—were the only significant explanatory variables for the different mainland equations. Regional regression equations were developed for the Plymouth-Carver-Kingston-Duxbury aquifer area in southeastern Massachusetts and Cape Cod, because surface-water drainage areas and groundwater contributing areas do not always coincide in this area of the State. The regression analyses to estimate 10 flow durations from the 99th to 50th percentiles used 18 streamflow sites with some occasional minor regulations—because there are few unregulated streams in southeastern Massachusetts. The analyses determined that groundwater contributing area and storage (combined water bodies and wetlands) were the only significant explanatory variables in the southeastern equations.

Massachusetts

Simulated hydrologic responses to proposed wastewater-returnflow scenarios in Falmouth, Massachusetts

The Cape Cod aquifer is the sole source of drinking water for communities on Cape Cod, Massachusetts, including the Town of Falmouth, where the aquifer is currently threatened by contamination from septic-system-derived nitrogen. To address this problem, the Town is proposing to sewer areas of Falmouth, treat the wastewater at the Town’s Main Wastewater Treatment Facility (a nitrogen removing/tertiary treatment facility), and discharge the treated wastewater to an ocean outfall pipe in Nantucket Sound. The U.S. Geological Survey, in cooperation with the Town of Falmouth, updated a three-dimensional steady-state groundwater flow model to represent current (defined as 2019–23) average hydrologic conditions and to simulate the long-term average freshwater hydrologic response to two wastewater-return-flow scenarios. Scenario 1 involves the sewering of all properties south of Route 28 in Falmouth, which approximates the Town’s possible sewer expansion over the next 20–30 years. Scenario 2 involves sewering of all properties in Falmouth to demonstrate the maximum potential effect of sewering on the aquifer. Overall, the simulated hydrologic response of water-table altitudes and streamflow in both scenarios was relatively small compared to fluctuations from natural recharge. In scenario 1, the water-table altitude decreased by about 0.1 feet south of Route 28, where the conversion to municipal sewers removed wastewater-return flow from onsite septic systems. The water-table altitude decreased by about 0.1–0.2 feet over a larger area in Falmouth under town-wide sewering in scenario 2. The greatest decrease in water-table altitude in both scenarios occurred near the Main Wastewater Treatment Facility, with a decrease of about 1.1 feet in scenario 1 and about 1.3 feet in scenario 2. Simulated decreases in streamflow also were estimated for six selected streams in Falmouth and Mashpee. In both scenarios, the largest simulated decreases in streamflow were at the Coonamessett River, which is the closest stream to the Main Wastewater Treatment Facility. In scenario 1, the average annual decrease in flow at the Coonamessett River was 0.1 cubic feet per second, a 1.1 percent decrease from current (2019–23) conditions. In scenario 2, streamflow at the Coonamessett River decreased by 0.6 cubic feet per second, a 5.4 percent decrease from current (2019–23) conditions.

Massachusetts

The δ13C signature of dissolved organic and inorganic carbon reveals complex carbon transformations within a salt marsh

Coastal wetlands have high rates of atmospheric CO 2 uptake, which is subsequently respired back to the atmosphere, stored as organic matter within flooded, anoxic soils, or exported to the coastal ocean. Transformation of fixed carbon occurs through a variety of subsurface aerobic and anaerobic microbial processes, and results in a large inventory of dissolved carbon. Carbon source and the roles of aerobic respiration, sulfate reduction, and methane cycling were evaluated within salt marsh peat and the underlying sandy subterranean estuary. There is a large increase in dissolved inorganic carbon (DIC, 7,350 ± 3,900 μmol L −1 ), dissolved organic carbon (DOC, 1,040 ± 1,480 μmol L −1 ) and CH 4 (14.5 ± 33.3 μmol L −1 ) within the marsh porewaters compared to creek waters. Alkalinity production (5,730 ± 2,170 μeq L −1 ) and sulfate removal (1,810 ± 1,970 μmol L −1 ) indicate anaerobic respiration, however, relative contributions from the various decomposition pathways cannot be identified due to overlapping geochemical signatures. The δ 13 C of the DOC (−29.0 ± 3.7‰) and DIC (−11.2 ± 1.1‰) produced within the marsh differed from the bulk soil organic matter δ 13 C (−14.5 ± 0.2‰). We explore a variety of mechanisms that could result in co-occurring depleted δ 13 C-DOC and enriched δ 13 C-DIC compared to the bulk soil organic carbon pool and salt marsh vegetation, including selective mineralization, production of δ 13 C-depleted bacterial biomass, and methane-derived DOC. While important questions remain about carbon cycling pathways, we found evidence of a cryptic methane cycle. Alteration of the δ 13 C of carbon species complicates source attribution in solid and dissolved phases and careful consideration should be used when carbon is partitioned between in situ salt marsh production and external marine and terrestrial sources.

Massachusetts

Evidence of mineral alteration in a salt marsh subterranean estuary: Implications for carbon and trace element cycling

Subterranean estuaries (STE) in salt marshes are biogeochemically active zones where interactions between terrestrial groundwater and seawater drive complex cycling of carbon and trace elements, influenced by mineral dissolution. These systems, characterized by fine-grained organic-rich peat overlying permeable coastal aquifers, play a crucial role as a blue carbon sink, yet their geochemical dynamics remain poorly understood. We investigated dissolved trace elements, carbon, silica, and radium isotopes in a salt marsh STE (Sage Lot Pond, Waquoit Bay, MA) over seasonal and annual cycles. Our results reveal that groundwater and estuarine water circulation through marsh peat and aquifer sediments leads to enrichments of dissolved organic and inorganic carbon (DOC and DIC), Si, Ba, and Mn, with variable source/sink behavior of Fe and net removal of U. Submarine groundwater discharge dominated Ba fluxes, whereas pore water drainage from marsh peat acted as the main sink for U and source of Si. Fe cycling was variable, with terrestrial Fe largely removed as groundwater passed through the STE, consistent with Fe-sulfide and amorphous phase formation. Radium isotope ratios identified two distinct subsurface flow pathways, influenced by metal-oxide cycling and organic matter breakdown. Si production was decoupled from DIC, suggesting Si originates from mineral alteration, whereas DIC results from both mineral weathering and microbial respiration. Silicate mineral alteration, coupled with marsh pore water drainage, accounts for up to 16% of annual DIC exports (66 g C m −2 y −1 ), highlighting the importance of STEs in coastal carbon and trace element cycling, especially as marshes face environmental change.

Massachusetts

Groundwater flowpath characteristics drive variability in per- and polyfluoroalkyl substances (PFAS) loading across a stream-wetland system

Groundwater-dependent ecosystems in areas with industrial land use are at risk of exposure to a PFAS chemicals. We investigated one such system with several known PFAS source areas, where high and low permeability sediments (glacial) coupled with groundwater-lake and groundwater/surface-water interactions created complex ‘source to seep’ dynamics. Using heat-tracing and chemical methods, numerous preferential groundwater discharge zones were identified and sampled across the upper Quashnet River stream-wetland system in Mashpee, MA, USA, downgradient of Joint Base Cape Cod (JBCC). Surface-water and groundwater samples were analyzed for 40 PFAS compounds between March and October 2022. Samples were collected from groundwater seeps identified as preferential discharge points (PDPs), wells upgradient of the stream-wetland system, contributing flow-through kettle lakes, and along Quashnet River surface-waters. PFAS from sampled waters contained perfluorinated carboxylates (PFPea, PFHxA, PFNA), perfluorinated sulfonates (PFBS, PFPeS, PFHxS, PFOS), fluorotelomer sulfonates (6:2, 8:2 FtS), and perfluoroalkyl sulfonamides (PFOSA). Samples from PDPs and wells had measured PFAS concentrations ranging from non-detect to 4677 ng/L ng/L (mean = 418 ng/L, std. = 709 ng/L), and a range of deuterium excess values (3.2 to 15.9 per mil) indicative of varying degrees of groundwater-lake interaction prior to groundwater flowpath emergence at PDPs. Correlations ( p < 0.01) between deuterium excess, %PFAS precursors, and terminal PFAS compounds highlighted potential precursor transformations associated with lake-groundwater exchange along flowpaths sourcing PDPs. However, some seepages had higher total PFAS concentrations (>1000 ng/L) than upgradient kettle lakes despite showing lake (evaporative) isotopic signatures, indicating the potential for groundwater flowpath convergence at wetland discharge zones and the influence of lakebed PFAS precursor reactions. Results from these synoptic surveys address gaps in the existing PFAS literature by demonstrating the importance of subsurface fate and transport on PFAS compound concentrations and mass loading in preferential groundwater discharge zones.

Massachusetts

Linking stream-reach nitrogen loads and groundwater “reachsheds” to inform wastewater-nitrogen management actions, Cape Cod, Massachusetts

Study Region Cape Cod, Massachusetts, U.S.A. Study Focus Anthropogenic nitrogen (N) is a key factor in degrading groundwater and surface-water quality, particularly in coastal New England where onsite wastewater systems are prevalent. This study evaluated whether direct N-load measurements in streams on Cape Cod, Massachusetts, coupled with flow-path information from groundwater-flow models, can effectively identify potential land areas where nitrogen mitigation could substantially reduce loads to receiving waters. Nitrogen fluxes were measured along 63 stream reaches during winter and summer and paired with simulated groundwater recharge areas to identify and rank potential areas for reduction of nonpoint-source N inputs. New Hydrologic Insights for the Region Reach-scale nitrate-N loads ranged from −39.1–1182 kg-N/yr per 100 m of stream, indicating spatially variable groundwater inputs across seasons. “Reachsheds” — areas contributing groundwater recharge to specific stream reaches — were delineated using a regional groundwater-flow model. Strong correlations were found between observed N loads and land-use characteristics, especially the number of septic systems and total N inputs from the sum of considered sources. Observed N loads were moderately correlated with recharge area size and wastewater flow estimates. Correlating reach-specific groundwater N loads with land use and parcel-scale nitrogen-yield data identified reachsheds with the highest potential for N load reduction. This approach enables targeted implementation of restoration efforts to optimize nutrient management and support regional load reduction.

Massachusetts

Seabed maps showing topography, ruggedness, backscatter intensity, sediment mobility, and the distribution of geologic substrates in quadrangle 2 of the Stellwagen Bank National Marine Sanctuary region offshore of Boston, Massachusetts

The U.S. Geological Survey, in cooperation with the National Marine Sanctuary Program of the National Oceanic and Atmospheric Administration, has conducted seabed mapping and related research in the Stellwagen Bank National Marine Sanctuary (SBNMS) region since 1993. The area being mapped using geophysical and geological data includes the SBNMS and the surrounding region, which totals approximately 3,700 square kilometers (km 2 ) and is subdivided into 18 quadrangles. The seabed is a glaciated terrain that is topographically and texturally diverse. Quadrangle 2, the subject of this scientific investigations map, has a mapped area of 209 km 2 and has water depths that range from about 19 meters (m) on the Stellwagen Bank crest to about 68 m in the Stellwagen Basin. Seven map types, each at a scale of 1:25,000, depict seabed topography, ruggedness, backscatter intensity, distribution of geologic substrates, sediment mobility, distribution of fine- and coarse-grained sand, and substrate mud content. These maps show the distribution of geologic substrates across the southwestern part of Stellwagen Bank, in Stellwagen Basin to the west and southwest of the bank, and in Little Stellwagen Basin and the western part of Race Point Channel to the south of the bank. Interpretations of multibeam sonar bathymetric and seabed backscatter imagery, photographs, video imagery, and grain-size analyses were used to create the geology-based maps. Data from 733 stations were analyzed, including 656 sediment samples. The geologic substrate maps of quadrangle 2 show the distribution of 19 geologic substrates that represent a wide range of textures, such as rippled and immobile sand, immobile muddy sand and sandy mud, sand that partially veneers gravel, and a boulder ridge. Mapped substrates are characterized by sediment grain-size composition, surface morphology, substrate layering, the mobility or immobility of substrate surfaces, and water depth range. This scientific investigations map portrays the major geological elements (substrates, topographic features, and processes) of environments in quadrangle 2. It is intended to provide a foundation for research into present and past sediment transport processes in a complex terrain, provide insights into the ecological requirements of invertebrate and vertebrate species that utilize the various substrates, and support seabed management in the region.

Massachusetts

Evidence of nitrate attenuation in intertidal and subtidal groundwater in a subterranean estuary at a Cape Cod embayment, East Falmouth, Massachusetts, 2015–16

Nitrogen dynamics in intertidal and nearshore subtidal groundwater (subterranean estuary) adjacent to the Seacoast Shores peninsula, Falmouth, Massachusetts, were investigated during 2015–16 by the U.S. Geological Survey. The peninsula is a densely populated residential area with septic systems and cesspools that are substantial sources of nitrogen to groundwater. The study area is in the Eel River, an estuarine saltwater embayment connected to the ocean adjacent to the western shore of the peninsula, that was the subject of an earlier study by Colman and others (2018, https://doi.org/10.3133/sir20185095 ) on nitrogen transport and transformations in groundwater between onshore and offshore locations. The previous study documented the distribution of nitrate concentrations and nitrate attenuation reactions in fresh groundwater beneath the peninsula and the estuary. The current study extended those observations with more detailed sampling and analysis of shallow groundwater from wells near discharge sites beneath the estuary. The current field investigation included sampling of existing wells and installation and sampling of clusters of wells and temporary sampling points in the subterranean estuary, including (1) shallow transects 0.3 to 1.2 meters (m) deep extending from 1 to 13.5 m offshore and (2) deeper wells (from 1.83 to 4.88 m deep) extending from 4.3 to 14.3 m offshore. Measurements of hydraulic-head gradients 2–5 m below the sediment/water interface in the intertidal and nearshore subtidal zones indicated that groundwater flow generally was upwards (towards the estuary) under all tide conditions in October 2016. The magnitude of the gradient was greatest during low tide conditions, indicating that groundwater discharge likely decreased during high tides. Measurements of specific conductance in shallow groundwater in the subterranean estuary in three transects perpendicular to shore were consistent with the existence of saltwater flow cells (infiltration of overlying saline water, mixing with fresh groundwater, and discharge to the overlying saline water) in the intertidal and nearshore subtidal regions. The size of these flow cells was variable in space and time and dependent on the elevation of the tide (spring or neap). At this location in the Eel River subterranean estuary, and offshore to at least 13.5 m, offshore flow of fresh groundwater apparently prevented a deeper saltwater wedge from discharging to the surface. Nitrate concentrations in shallow groundwater (30 to 122 centimeters [cm] depth) were variable in space and time, ranging from not detectable to 600 micromoles per liter (μmol/L) (8.4 milligrams per liter as N), and were highest in June 2016 at depths from 61 to 122 cm below the sediment/water interface and from 4 to 9 m offshore. Nitrate generally was not detectable in saline shallow groundwater at 30-cm depth or at any depth from 30 to 122 cm from 10 to 13.5 m offshore. Dissolved oxygen concentrations were suboxic (less than 16 μmol/L) in 60 percent of the sampled subterranean groundwater beneath the intertidal and subtidal zones. In the remaining sites, the range of dissolved oxygen concentrations was from 18 to 272 μmol/L and the median concentration was 43 μmol/L. Evidence for microbial nitrate reduction (denitrification and possibly anammox) was provided by the distribution of the reaction product nitrogen gas (excess N 2 , or N 2MIC ), as determined from analysis of the dissolved nitrogen gas and argon gas (Ar) concentrations in groundwater samples. Excess nitrogen gas provided evidence for nitrate reduction in shallow groundwater below the subtidal and, to a lesser extent, intertidal zones adjacent to the Seacoast Shores peninsula. These zones, where evidence for nitrate reduction was detected, were in fresh and brackish groundwater near subtidal or intertidal saltwater cells where discharging fresh groundwater mixed with infiltrating saline water. Infiltrating seawater may have supplied organic carbon, one of several potential electron donors that are required for denitrification. Other potential electron donors, such as organic carbon, iron, manganese, hydrogen, methane, ammonium, elemental sulfur, or sulfide phases, may have been supplied by the estuarine sediments. Drainage from surface runoff near the shore also may have supplied organic carbon to fresh groundwater near the intertidal saltwater cell. The highest amounts of nitrate converted to excess nitrogen gas were estimated to be in the range of 230 to 430 μmol/L in nearly fresh groundwater near the subtidal saltwater cell at depths of 61 to 122 cm below the sediment/water interface and from 10 to 13.5 m offshore. Evidence of denitrification within 10 m of the shore was sparse (generally limited to less than 50 μmol/L of N 2 -N) despite the presence of high nitrate concentrations. The spatial distribution of estimated nitrate reduction in the intertidal and nearshore subtidal fresh and brackish groundwater may be related to local variability in the distribution of reactive electron donors in those zones. Variations in the amount of nitrate reduction to nitrogen gas were not clearly related to potential aqueous electron donors such as dissolved organic carbon, nor to potential reaction products such as alkalinity, but may have been controlled by combinations of aqueous and solid-phase reactants. The distribution of relatively shallow fresh groundwater containing nitrate could indicate potential nitrate discharge areas in the lower intertidal zone and uncertain locations farther offshore; however, the data did not extend all the way to the sediment/water interface or to the offshore freshwater limit. This study confirmed substantial loss of nitrate from some of the fresh and brackish groundwater in shallow subestuarine sediments prior to discharge but did not quantify how much nitrate eventually discharged to the estuary.

Massachusetts

Method for estimating water use and interbasin transfers of freshwater and wastewater in an urbanized basin

Techniques for management of drainage basins that use water budgets to balance available water resources with actual or anticipated water use require accurate and precise estimates of basin withdrawals, interbasin transfers of freshwater, unaccounted-for use, water use, consumptive use, inflow and infiltration, basin return flow, and interbasin transfers of wastewater. Frequently, interbasin transfers of freshwater and wastewater are not included in basin water budgets because they occur within public water-delivery and wastewater-collection systems. A new 10-step method was developed to improve estimates of inflow and infiltration and interbasin transfers using readily available statewide data. The accuracy and precision of water-use estimates determined by this method are improved through careful application of coefficients for small users and the use of metered values for large users. The method was developed and tested with data for the Ten Mile River Basin in southeastern Massachusetts. This report uses examples from the basin to illustrate each step of the method.

Massachusetts