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Research about Idaho

Source-linked reports with geographic coverage including Idaho.

At least 469 records · Page 26Linked to original sources

SHRIMP U-Pb geochronology of Neoproterozoic Windermere Supergroup, central Idaho: Implications for rifting of western Laurentia and synchroneity of Sturtian glacial deposits

In central Idaho roof pendants, a northwest-trending belt of metamorphosed strata, correlative with the Windermere Supergroup, links northern and southern segments of the western Laurentia Neoproterozoic rift belt. Nine newly named formations within the Gospel Peaks sequence-A through Gospel Peaks sequence-D record Cryogenian preglacial, rift-glacial, and postglacial events as well as Neoproterozoic III glacial and rift events. The Edwardsburg Formation of Gospel Peaks sequence B includes interfingered bimodal rift-related volcanic and glaciogenic diamictite strata. Zircons from a rhyodacite flow in the lower Edwardsburg Formation and from a rhyolite flow at its top, dated by using the sensitive high-resolution ion microprobe (SHRIMP), yielded a weighted average of 685 ± 7 Ma and 684 ± 4 Ma. Reevaluation of geochronology and correlations indicates that Cryogenian rifting may have been (1) protracted between 780 and 685 Ma, (2) diachronous along the Cordillera, and/or (3) stepwise with a Cordilleran-wide event at ca. 685 Ma that initiated the formation of the Cordilleran miogeocline and set its geometry. Reevaluation of the Cryogenian glacial record indicates that (1) two associated ca. 685 Ma glacial intervals in the Edwardsburg Formation correlate with the Rapitan glaciation, (2) the Sturtian snowball Earth event must be reevaluated on the basis of revision of Rapitan glaciation from 750–700 Ma to ca. 685 Ma, and (3) there were older Cryogenian glaciations or Cryogenian glaciations were not globally synchronous. New dates and correlations significantly impact the number and synchroneity of possible snowball Earth events and the paleolatitudes of Cryogenian glaciations. Western Laurentian events at ca. 685 Ma particularily affect Neoproterozoic paleocontinental reconstructions by indicating diachronous and multi step breakup of supercontinent Rodinia.

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Paleomagnetism of basaltic lava flows in coreholes ICPP-213, ICPP-214, ICPP-215, and USGS 128 near the Vadose Zone Research Park, Idaho Nuclear Technology and Engineering Center, Idaho National Engineering and Environmental Laboratory, Idaho

A paleomagnetic study was conducted on basalt from 41 lava flows represented in about 2,300 ft of core from coreholes ICPP-213, ICPP-214, ICPP-215, and USGS 128. These wells are in the area of the Idaho Nuclear Technology and Engineering Center (INTEC) Vadose Zone Research Park within the Idaho National Engineering and Environmental Laboratory (INEEL). Paleomagnetic measurements were made on 508 samples from the four coreholes, which are compared to each other, and to surface outcrop paleomagnetic data. In general, subhorizontal lines of correlation exist between sediment layers and between basalt layers in the area of the new percolation ponds. Some of the basalt flows and flow sequences are strongly correlative at different depth intervals and represent important stratigraphic unifying elements. Some units pinch out, or thicken or thin even over short separation distances of about 1,500 ft. A more distant correlation of more than 1 mile to corehole USGS 128 is possible for several of the basalt flows, but at greater depth. This is probably due to the broad subsidence of the eastern Snake River Plain centered along its topographic axis located to the south of INEEL. This study shows this most clearly in the oldest portions of the cored sections that have differentially subsided the greatest amount.

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Estimating the magnitude of the 100-year peak flow in the Big Lost River at the Idaho National Engineering and Environmental Laboratory, Idaho

Accurate estimates of peak flows in the Big Lost River at the Idaho National Engineering and Environmental Laboratory (INEEL) are needed to assist planners and managers with evaluating possible effects of flooding on facilities at the INEEL. A large difference of 4,350 cubic feet per second (ft 3 /s) between two previous estimates of the magnitude of the 100-year peak flow in the Big Lost River near the western boundary of the INEEL prompted the present study. Regression models that compared annual peak flows and attenuation of annual peak flows between successive gaging stations for the same flow event were used to estimate the magnitude of the 100-year peak flow in the Big Lost River. The 100-year peak flow of 4,790 ft 3 /s at the Howell Ranch gaging station was used as the starting point for this analysis. This estimate was determined by using a three-parameter log-Pearson Type III distribution as outlined in “Guidelines for Determining Flood Flow Frequency” (Bulletin 17B by the Interagency Advisory Committee on Water Data). The regression models indicated that, in the reach of the Big Lost River between Howell Ranch and Mackay Reservoir, downstream peak flows are lower than upstream peak flows. Peak-flow attenuation values for this reach of the river decreased nonlinearly as the magnitude of the peak flow increased. Extrapolation of the trend resulted in an attenuation estimate of 13 percent for this reach relative to the 100-year peak flow at the Howell Ranch gaging station. In the lower reach of the Big Lost River between Mackay Reservoir and Arco, downstream peak flows are also lower than upstream peak flows. However, in contrast to the upper reach, peak-flow attenuation values decreased linearly as the magnitude of the peak flow increased. Extrapolation of the data indicated that peak-flow attenuations in this reach of the river approach zero for flows approaching the 100-year peak-flow estimate immediately upstream and downstream from Mackay Reservoir. A regression model of annual maximum daily mean flows between Arco and the INEEL diversion dam indicated that the attenuation values in this reach of the river are nearly the same for all flows of record. Extrapolation of the linear regression of these values resulted in an attenuation estimate of 10 percent. Seepage measurements made during 1951–53 also resulted in a loss estimate of approximately 10 percent. This attenuation value, combined with the values from analyses of the upstream reaches, resulted in an estimate of the 100-year peak flow for the Big Lost River immediately upstream from the INEEL diversion dam of 3,750 ft 3 /s; upper and lower 95-percent confidence limits were 6,250 ft 3 /s and 1,300 ft 3 /s, respectively. Localized rainfall, even of high intensity, is not likely to produce large peak flows at the INEEL because of high loss rates (infiltration, bank storage, and channel storage) along much of the stream channel. The relatively short flow durations resulting from rainstorms historically have not provided sufficient volumes of water to satisfy local storage demands (bank and channel storage). Only after these storage demands are met do the loss rates decrease enough for significant peak flows to reach the INEEL site. An uncertain component of the present analysis is the effect of seismic activity on the 100-year peak-flow estimate. Analysis of the effect of the magnitude 7.3 Borah Peak earthquake in 1983 on normal flow conditions in the Big Lost River suggests that the joint occurrence of a large earthquake and a 100-year peak flow could significantly increase the magnitude of the peak flow at the INEEL.

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Two-station comparison of peak flows to improve flood-frequency estimates for seven streamflow-gaging stations in the Salmon and Clearwater River Basins, Central Idaho

Improved flood-frequency estimates for short-term (10 or fewer years of record) streamflow-gaging stations were needed to support instream flow studies by the U.S. Forest Service, which are focused on quantifying water rights necessary to maintain or restore productive fish habitat. Because peak-flow data for short-term gaging stations can be biased by having been collected during an unusually wet, dry, or otherwise unrepresentative period of record, the data may not represent the full range of potential floods at a site. To test whether peak-flow estimates for short-term gaging stations could be improved, the two-station comparison method was used to adjust the logarithmic mean and logarithmic standard deviation of peak flows for seven short-term gaging stations in the Salmon and Clearwater River Basins, central Idaho. Correlation coefficients determined from regression of peak flows for paired short-term and long-term (more than 10 years of record) gaging stations over a concurrent period of record indicated that the mean and standard deviation of peak flows for all short-term gaging stations would be improved. Flood-frequency estimates for seven short-term gaging stations were determined using the adjusted mean and standard deviation. The original (unadjusted) flood-frequency estimates for three of the seven short-term gaging stations differed from the adjusted estimates by less than 10 percent, probably because the data were collected during periods representing the full range of peak flows. Unadjusted flood-frequency estimates for four short-term gaging stations differed from the adjusted estimates by more than 10 percent; unadjusted estimates for Little Slate Creek and Salmon River near Obsidian differed from adjusted estimates by nearly 30 percent. These large differences probably are attributable to unrepresentative periods of peak-flow data collection.

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Stage-discharge relations for selected culverts and bridges in the Big Lost River flood plain at the Idaho National Engineering and Environmental Laboratory, Idaho

Information is needed by the U.S. Department of Energy at the Idaho National Engineering and Environmental Laboratory to determine the extent and severity of potential flooding at facilities along the Big Lost River. Two computer programs—the Culvert Analysis Program (CAP) and the HECRAS model—were used to define stage-discharge relations for 31 culverts and 2 bridge sites in a 10- mile reach of the river. These relations can be used to improve surface-water-flow models to evaluate potential flooding. Relations between headwater, tailwater, and discharge through each structure were unique. Discharge through the culverts as computed by the CAP ranged from about 0 cubic feet per second to as much discharge as could be conveyed, and tailwater elevations ranged from about 0 to 30 feet above the outlet elevation. Discharge through the bridges, as computed by the HEC-RAS model, ranged from nearly 0 to 7,000 cubic feet per second, and tailwater elevations ranged from nearly 0 to 30 feet above the streambed on the downstream cross section of each bridge. Stage-discharge relations provided in lookup tables in this report can be incorporated into numerical surface-water-flow models to simulate the effects of hydraulic structures on flood flows. One limitation of the CAP and HEC-RAS models is that changes in flow conditions, such as obstruction by sediment and debris, are not simulated. If flow through a hydraulic structure is obstructed by sediment or debris, then model-simulated discharges through the structure might be greater than would be experienced under actual conditions.

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Aquatic assemblages and their relation to temperature variables of least-disturbed streams in the Salmon River basin, central Idaho, 2001

In the late 1990s, Idaho’s established stream temperature criteria for the protection of coldwater biota and salmonid spawning were considered inadequate because the criteria did not agree with observed biological conditions in many instances and did not allow for variability in environmental condition or species diversity across a broad area such as the entire State of Idaho. In 2001, benthic invertebrate and fish assemblages in 34 least-disturbed streams in the Salmon River Basin, central Idaho, were evaluated in relation to stream temperature and other environmental variables. The Salmon River Basin retains watersheds that are minimally affected by human activities. These “natural” stream conditions provide a basis for deriving attainable stream temperatures that can be used to set new, and revise existing, water-quality criteria for stream habitats affected by human activities. During July through September 2001, data were collected to document the thermal regime of least-disturbed streams, characterize the distribution of aquatic biota at streams representing a gradient of temperature, and describe the relations between environmental variables and benthic invertebrate and fish assemblages. Nine stream temperature metrics were compared with the U.S. Environmental Protection Agency’s criterion of 10 ° C (degrees Celsius) for bull trout spawning and juvenile rearing. The maximum weekly-maximum temperature at all 33 sites where temperature data were available exceeded this criterion. The maximum daily-maximum temperature (MDMT) at 30 of the sites exceeded the Idaho Department of Environmental Quality (IDEQ) criterion of 13.0 ° C for the protection of salmonid spawning; and the maximum daily-average temperature at all 33 sites exceeded the 9.0 ° C criterion for the protection of salmonid spawning. The thermal regime at most sites did not exceed the IDEQ criteria for the protection of coldwater biota. Nine environmental variables—water-surface gradient, discharge, wetted channel width, width:depth ratio, aspect, total seasonal thermal input, open canopy, riparian canopy density, and elevation were selected for correlation with the nine stream temperature metrics. Elevation showed the strongest inverse correlation with the stream temperature metrics. Two hundred and one benthic invertebrate taxa from the 34 sampling sites were identified. The most abundant taxa were Baetis tricaudatus , Oligochaeta, Tvetenia bavarica gr., Acari, Rhithrogena , Cinygmula , Heterlimnius , Micropsectra , Eukiefferiella devonica gr., Drunella doddsi , and Cricotopus . Of the 201 benthic invertebrate taxa collected during this study, 57 taxa (present at a minimum of 5 sampling sites) were significantly correlated with one or more of the stream temperature metrics. Among the invertebrate taxa collected, 32 were identified as coldwater taxa. Of the coldwater taxa collected, Zapada oregonensis gr. showed the strongest inverse correlation with the stream temperature metrics and was collected at sites where maximum weekly-maximum temperature (based on date of sample and 6 days prior) ranged from 11.3 ° to 18.5 °C. Ten species of fish in the families Salmonidae, Cottidae, and Cyprinidae were collected. Two species (bull trout and chinook salmon) listed as threatened under the U.S. Fish and Wildlife Service Endangered Species Act were collected. Among all species, bull trout showed the strongest inverse correlation between relative fish abundance and stream temperature. Bull trout and juvenile bull trout densities were inversely correlated with stream temperature. The probability of occurrence of juvenile bull trout was significantly correlated with MDMT on the basis of results from a logistic regression model developed during this study. However, this model differed from a similar model developed by the U.S. Forest Service on the basis of regional data collected in the Pacific Northwest. The regression model based on data collected during this study showed higher probabilities of occurrence of bull trout at colder stream temperatures (10 ° to 15 ° C) and lower probabilities of occurrence at warmer stream temperatures (16 ° to 21 ° C) than did the model based on regional data. The model comparisons suggest that regional or local differences need to be considered when deriving stream temperature criteria.

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Reevaluation of background iodine-129 concentrations in water from the Snake River Plain aquifer, Idaho, 2003

Background concentrations of iodine-129 (129I, half-life = 15.7 million years) resulting from natural production in the earth?s atmosphere, in situ production in the earth by spontaneous fission of uranium-238(238U), and fallout from nuclear weapons tests conducted in the 1950s and 1960s were reevaluated on the basis of 52 analyses of ground- and surface-water samples collected from the eastern Snake River Plain in southeastern Idaho. The background concentration estimated using the results of a subset of 30 ground-water samples analyzed in this reevaluation is 5.4 attocuries per liter (aCi/L; 1 aCi = 10-18 curies) and the 95-percent nonparametric confidence interval is 5.2 to 10.0 aCi/L. In a previous study, a background 129I concentration was estimated on the basis of analyses of water samples from 16 sites on or tributary to the eastern Snake River Plain. At the 99-percent confidence level, background concentrations of 129I in that study were less than or equal to 8.2 aCi/L. During 1993?94, 34 water samples from 32 additional sites were analyzed for 129I to better establish the background concentrations in surface and ground water from the eastern Snake River Plain that is presumed to be unaffected by wastedisposal practices at the Idaho National Engineering and Environmental Laboratory (INEEL). Surface water contained larger 129I concentrations than water from springs and wells contained. Because surface water is more likely to be affected by anthropogenic fallout and evapotranspiration, background 129I concentrations were estimated in the current research using the laboratory results of ground-water samples that were assumed to be unaffected by INEEL disposal practices.

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Spatial variability of sedimentary interbed properties near the Idaho Nuclear Technology and Engineering Center at the Idaho National Engineering and Environmental Laboratory, Idaho

The subsurface at the Idaho National Engineering and Environmental Laboratory (INEEL) is complex, comprised primarily of thick, fractured basalt flows interbedded with thinner sedimentary intervals. The unsaturated zone can be as thick as 200 m in the southwestern part of the INEEL. The Vadose Zone Research Park (VZRP), located approximately 10 km southwest of the Idaho Nuclear Technology and Engineering Center (INTEC), was established in 2001 to study the subsurface of a relatively undisturbed part of the INEEL. Waste percolation ponds for the INTEC were relocated to the VZRP due to concerns that perched water within the vadose zone under the original infiltration ponds (located immediately south of the INTEC) could contribute to migration of contaminants to the Snake River Plain aquifer. Knowledge of the spatial distribution of texture and hydraulic properties is important for developing a better understanding of subsurface flow processes within the interbeds, for example, by identifying low permeability layers that could lead to the formation of perched ground-water zones. Because particle-size distributions are easier to measure than hydraulic properties, particle size serves as an analog for determining how the unsaturated hydraulic properties vary both vertically within particular interbeds and laterally within the VZRP. As part of the characterization program for the subsurface at the VZRP, unsaturated and saturated hydraulic properties were measured on 10 core samples from six boreholes. Bulk properties, including particle size, bulk density, particle density, and specific surface area, were determined on material from the same depth intervals as the core samples, with an additional 66 particle- size distributions measured on bulk samples from the same boreholes. From lithologic logs of the 32 boreholes at the VZRP, three relatively thick interbeds (in places up to 10 m thick) were identified at depths of 35, 45, and 55 m below land surface. The 35-m interbed extends laterally over a distance of at least 900 m from the Big Lost River to the new percolation pond area of the VZRP. Most wells within the VZRP were drilled to depths less than 50 m, making it difficult to infer the lateral extent of the 45-m and 55-m interbeds. The 35-m interbed is uniform in texture both vertically and laterally; the 45-m interbed coarsens upward; and the 55-m interbed contains alternating coarse and fine layers. Seventy-one out of 90 samples were silt loams and 9 out of 90 samples were classified as either sandy loams, loamy sands, or sands. The coarsest samples were located within the 45-m and 55-m interbeds of borehole ICPP-SCI-V-215, located near the southeast corner of the new percolation pond area. At the tops of some interbeds, baked-zone intervals were identified by their oxidized color (yellowish red to red) compared to the color of the underlying non-baked material (pale yellow to brown). The average geometric mean particle diameter of baked-zone intervals was only slightly coarser, in some cases, than the underlying non-baked sediment. This is likely due to both depositional differences between the top and bottom of the interbeds and the presence of small basalt clasts in the sediment. Core sample hydraulic properties from baked zones within the different interbeds did not show effects from alteration caused during basalt deposition, but differed mainly by texture. Saturated hydraulic conductivities (Ksat) for the 10 core samples ranged from 10-7 to 10-4 cm/s. Low permeability layers, with Ksat values less than 10-7 cm/s, within the 35-m and 45-m interbeds may cause perched ground-water zones to form beneath the new percolation pond area, leading to the possible lateral movement of water away from the VZRP.

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Probability of detecting elevated concentrations of nitrate in ground water in a six-county area of south-central Idaho

A probability map constructed for this study identified several areas in a six-county region of south-central Idaho with high probabilities of detecting elevated concentrations (greater than 2 milligrams per liter) of nitrate. An increasing proportion of Idaho’s ground water being used for drinking water and large increases in the inputs of nitrogen to ground water in Cassia, Gooding, Jerome, Lincoln, Minidoka, and Twin Falls Counties have prompted concerns about the quality of the resource. The probability map was constructed to assist regulatory and resource agencies in managing land use and protecting water resources. To construct the probability map, hydrogeologic and anthropogenic data were integrated with ground-water quality data in a geographic information system. The resulting data set contained land use, geology, precipitation, soil characteristics, depth to ground water, nitrogen input, and ground-water velocity information for each of the 1,365 samples collected from 1991 to 2001. Logistic regression analysis was used to determine the most statistically significant variables related to the detection of elevated nitrate concentrations. The resulting multivariate probability model showed that ground-water velocity, nitrogen input, precipitation, soil drainage, land use, and depth to ground water were significantly correlated with elevated nitrate concentrations. A subset of the water-quality data set was used to verify these results. Linear regression of the percentage of predicted probabilities of elevated nitrate concentrations and the actual percentage of elevated nitrate concentrations with the model data set and the verification data set both showed good correlations: r-squared values were 0.96 and 0.97, respectively. Statistical comparisons of both data sets showed that ground-water samples containing elevated nitrate concentrations had significantly higher probabilities of detection (p < 0.001) than samples without elevated nitrate concentrations. On the basis of these results, a map identifying the probability of detecting elevated nitrate concentrations was constructed. High-probability areas on the map coincided with regions of agricultural land use and high nitrogen input, except in southern Gooding County and western Jerome County. In these areas, high ground-water velocities representing a predominance of regional ground water resulted in a low probability of detecting elevated nitrate concentrations. Areas of poor prediction tended to be congregated along the transition zone between high and low ground-water velocities in Jerome and Gooding Counties, indicating a mix of regional and recently recharged ground water.

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Quantification of metal loads and assessment of metal sources in upper Beaver Creek watershed, Shoshone County, Idaho, May and June 2002

Abandoned mine lands contribute to significant water-quality degradation in the Beaver Creek watershed in northern Idaho. Streams in this watershed drain the northern flank of the Coeur d’Alene mining district, one of the world’s largest producers of silver and one of the country’s major historical producers of lead and zinc for more than 100 years. Effective cleanup of these streams will depend on accurate characterization of metal concentrations in streams and various sources of these metals. Cadmium, lead, and zinc loads entering Beaver Creek and its major tributary, Carbon Creek, were quantified, and source areas for these metals were assessed during May and June 2002. Metal loads were calculated for main-stem and surface-inflow sites by combining measured streamflow with dissolved cadmium, lead, and zinc concentrations analyzed in waterquality samples collected during three synoptic sampling events. To assess the effects of surface and shallow subsurface inflows on the gain or loss of streamflow and metal loads, Beaver and Carbon Creeks were divided into subreaches. Four subreaches were defined on Beaver Creek using five main-stem sampling sites (UBC3, UBC5, UBC8, BC10, and BC14); two subreaches were defined on Carbon Creek using three main-stem sampling sites (CC2, CC6, and CC9). During each of the synoptic sampling events, concentrations of cadmium and zinc were highest in samples collected at the Carlisle Mine adit between sites CC2 and CC6. During two of the three synoptic sampling events, the concentration of lead was highest in samples collected from a left-bank seep downgradient from the Idora Mill between sites UBC3 and UBC5. The largest identified cadmium and zinc source to Beaver Creek is the surface inflow from Carbon Creek (between sites UBC8 and BC10), which accounted for 45 to 72 percent of the main-stem cadmium load and 49 to 89 percent of the main-stem zinc load in Beaver Creek. Another large source of cadmium and zinc to Beaver Creek is subsurface flow through the tiered flotation tailings pile near Carbon Center (between sites BC10 and BC14) into Beaver Creek. Amounts of lead contributed by source areas to Beaver Creek vary with streamflow conditions. During high streamflow, the largest source of lead to Beaver Creek is the remobilization of fine-grained (less than 0.45-micrometer), lead-enriched particulates from the streambed throughout the study area. During low streamflow, bank seepage of subsurface water into Beaver Creek in the subreach downgradient from the Idora Mill (between sites UBC3 and UBC5) is the major source of lead to Beaver Creek. During each synoptic sampling event, Carbon Creek is a major source of lead to Beaver Creek. The Carlisle Mine adit (between CC2 and CC6) is the largest source of cadmium and zinc to Carbon Creek and, ultimately, to Beaver Creek, and accounted for 57 to 88 percent of the total main-stem cadmium load and 56 to 88 percent of the total main-stem zinc load in Carbon Creek during each of the synoptic sampling events. Another source of cadmium and zinc to Carbon Creek is resurfacing cadmium- and zincenriched hyporheic flow (possibly originating from the Carlisle adit or the Carlisle Mill) between sites CC6 and CC9. As in Beaver Creek, amounts of lead contributed to Carbon Creek by source areas vary with streamflow conditions. During high streamflows, increased discharge from the Carlisle Mine adit appears to be the largest source of lead to Carbon Creek; during low streamflows, resurfacing lead-enriched hyporheic flow appears to be the major source of lead to Carbon Creek.

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Geochemistry of the Birch Creek Drainage Basin, Idaho

The U.S. Survey and Idaho State University, in cooperation with the U.S. Department of Energy, are conducting studies to describe the chemical character of ground water that moves as underflow from drainage basins into the eastern Snake River Plain aquifer (ESRPA) system at and near the Idaho National Engineering and Environmental Laboratory (INEEL) and the effects of these recharge waters on the geochemistry of the ESRPA system. Each of these recharge waters has a hydrochemical character related to geochemical processes, especially water-rock interactions, that occur during migration to the ESRPA. Results of these studies will benefit ongoing and planned geochemical modeling of the ESRPA at the INEEL by providing model input on the hydrochemical character of water from each drainage basin. During 2000, water samples were collected from five wells and one surface-water site in the Birch Creek drainage basin and analyzed for selected inorganic constituents, nutrients, dissolved organic carbon, tritium, measurements of gross alpha and beta radioactivity, and stable isotopes. Four duplicate samples also were collected for quality assurance. Results, which include analyses of samples previously collected from four other sites, in the basin, show that most water from the Birch Creek drainage basin has a calcium-magnesium bicarbonate character. The Birch Creek Valley can be divided roughly into three hydrologic areas. In the northern part, ground water is forced to the surface by a basalt barrier and the sampling sites were either surface water or shallow wells. Water chemistry in this area was characterized by simple evaporation models, simple calcite-carbon dioxide models, or complex models involving carbonate and silicate minerals. The central part of the valley is filled by sedimentary material and the sampling sites were wells that are deeper than those in the northern part. Water chemistry in this area was characterized by simple calcite-dolomite-carbon dioxide models. In the southern part, ground water enters the ESRPA. In this area, the sampling sites were wells with depths and water levels much deeper than those in the northern and central parts of the valley. The calcium and carbon water chemistry in this area was characterized by a simple calcite-carbon dioxide model, but complex calcite-silicate models more accurately accounted for mass transfer in these areas. Throughout the geochemical system, calcite precipitated if it was an active phase in the models. Carbon dioxide either precipitated (outgassed) or dissolved depending on the partial pressure of carbon dioxide in water from the modeled sites. Dolomite was an active phase only in models from the central part of the system. Generally the entire geochemical system could be modeled with either evaporative models, carbonate models, or carbonate-silicate models. In both of the latter types of models, a significant amount of calcite precipitated relative to the mass transfer to and from the other active phases. The amount of calcite precipitated in the more complex models was consistent with the amount of calcite precipitated in the simpler models. This consistency suggests that, although the simpler models can predict calcium and carbon concentrations in Birch Creek Valley ground and surface water, silicate-mineral-based models are required to account for the other constituents. The amount of mass transfer to and from the silicate mineral phases was generally small compared with that in the carbonate phases. It appears that the water chemistry of well USGS 126B represents the chemistry of water recharging the ESRPA by means of underflow from the Birch Creek Valley.

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Measurement of sedimentary interbed hydraulic properties and their hydrologic influence near the Idaho Nuclear Technology and Engineering Center at the Idaho National Engineering and Environmental Laboratory

Disposal of wastewater to unlined infiltration ponds near the Idaho Nuclear Technology and Engineering Center (INTEC), formerly known as the Idaho Chemical Processing Plant, at the Idaho National Engineering and Environmental Laboratory (INEEL) has resulted in the formation of perched water bodies in the unsaturated zone (Cecil and others, 1991). The unsaturated zone at INEEL comprises numerous basalt flows interbedded with thinner layers of coarse- to fine-grained sediments and perched ground-water zones exist at various depths associated with massive basalts, basalt-flow contacts, sedimentary interbeds, and sediment-basalt contacts. Perched ground water is believed to result from large infiltration events such as seasonal flow in the Big Lost River and wastewater discharge to infiltration ponds. Evidence from a large-scale tracer experiment conducted in 1999 near the Radioactive Waste Management Complex (RWMC), approximately 13 km from the INTEC, indicates that rapid lateral flow of perched water in the unsaturated zone may be an important factor in contaminant transport at the INEEL (Nimmo and others, 2002b). Because sedimentary interbeds, and possibly baked-zone alterations at sediment-basalt contacts (Cecil and other, 1991) play an important role in the generation of perched water it is important to assess the hydraulic properties of these units.

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Notes. Characterization of plutonium in ground water near the idaho chemical processing plant

Plutonium is present in very low concentrations in ground water near the disposal well at the Idaho Chemical Processing Plant but was not detected in waters at greater distances. Because of the absence of strong complexing agents, the plutonium is present as an uncomplexed (perhaps hydrolyzed) tetravalent species, which is readily precipitated or sorbed by basalt or sediments along the ground-water flow path.

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Mercury deposition in snow near an industrial emission source in the western U.S. and comparison to ISC3 model predictions

Mercury (total and methyl) was evaluated in snow samples collected near a major mercury emission source on the Idaho National Engineering and Environmental Laboratory (INEEL) insoutheastern Idaho and 160 km downwind in Teton Range in westernWyoming. The sampling was done to assess near-field (<12 km)deposition rates around the source, compare them to those measured in a relatively remote, pristine downwind location, andto use the measurements to develop improved, site-specific modelinput parameters for precipitation scavenging coefficient and thefraction of Hg emissions deposited locally. Measured snow waterconcentrations (ng L -1 ) were converted to deposition (ugm -2 ) using the sample location snow water equivalent. Thedeposition was then compared to that predicted using the ISC3 airdispersion/deposition model which was run with a range ofparticle and vapor scavenging coefficient input values. Acceptedmodel statistical performance measures (fractional bias andnormalized mean square error) were calculated for the differentmodeling runs, and the best model performance was selected. Measured concentrations close to the source (average = 5.3 ngL -1 ) were about twice those measured in the Teton Range(average = 2.7 ng L -1 ) which were within the expected rangeof values for remote background areas. For most of the samplinglocations, the ISC3 model predicted within a factor of two of theobserved deposition. The best modeling performance was obtainedusing a scavenging coefficient value for 0.25 μm diameterparticulate and the assumption that all of the mercury isreactive Hg(II) and subject to local deposition. A 0.1 μm particle assumption provided conservative overprediction of thedata, while a vapor assumption resulted in highly variable predictions. Partitioning a fraction of the Hg emissions to elemental Hg(0) (a U.S. EPA default assumption for combustion facility risk assessments) would have underpredicted the observed fallout.

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