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Groundwater source water assessment area delineation of public supply wells in the Treasure Valley, western Idaho

The Idaho Department of Environmental Quality (IDEQ) is responsible for assessing the source water for public water supply systems including the delineation of source water assessment areas for wells, which are defined as the subsurface areas contributing water to a well during a period of time. Part of the IDEQ assessment plan is to update source water assessments over time. The U.S. Geological Survey (USGS) developed a new groundwater-flow model for part of the western Snake River Plain aquifer in southwestern Idaho. This groundwater- flow model provided a new opportunity for IDEQ to update source water assessment for public water supply wells within the model boundary. The USGS, in cooperation with IDEQ, used the USGS Treasure Valley Groundwater Flow Model along with a MODPATH particle tracking post-processing program to reassess public-water supply source water assessment areas. The USGS created an automated script that requests a well location, depth, and pumpage rate, and then incorporates that information into the Treasure Valley Groundwater Flow Model combined with the MODPATH model to create 3-, 6-, and 10-year time of travel zones that are output to a geographic information system shapefile. The TVSWA_Delineator script provides a fast, transparent tool for IDEQ to reassess or create new public-water supply source water assessment area delineations based on new and updated information and is available as a Python script and a Windows executable with the compiled script and all necessary components. TVSWA_Delineator utilizes a quadtree approach to rediscretize the Treasure Valley Groundwater Flow Model grid around the pumping well location from 1-mile cell lengths telescoped down to 1/16 mile. This rediscretization increases the source water assessment area delineation resolution near the pumping well and minimizes the effect of weak sinks in the MODPATH model. The stress inputs for each month of the final 10 years (2006 to 2015) of the Treasure Valley Groundwater Flow model historical simulation were averaged for the particle tracking analysis. The MODPATH model used backwards tracking of particles released at each stress period to create the source water assessment area delineations. This report documents the creation of the TVSWA_Delineator Python script, including adaptations made to the Treasure Valley Groundwater Flow Model, creation of a companion MODPATH model, and post-processing results to provide source water assessment areas.

Idaho

Multi-scale geophysical mapping of the brine and bedrock surfaces along the Dolores River, Paradox Valley, Colorado, December 2023

Total dissolved solids derived from salt dome–sourced brine in the underlying alluvial aquifer substantially increase with distance in the reach of the Dolores River that passes through Paradox Valley in southwestern Colorado. The area has been the site of salinity control operations since the 1990s to reduce salt loading to the downstream Colorado River. Previous airborne and ground/water-based electromagnetic (EM) geophysical data have successfully mapped the top of the brine surface, albeit with relatively coarse near-surface resolution and limited spatial coverage. This present December 2023 study used ground-based high-resolution EM and passive seismic (horizontal-to-vertical spectral ratio, HVSR) tools to map in detail the depth and thickness of the brine zone in the alluvial aquifer (top of the brine down to bedrock contact) in areas immediately surrounding the Dolores River where previous airborne EM (AEM) results indicated brine within 10 m of land surface. Results indicate the deepest bedrock is generally associated with the shallowest brine and local depressions in the collapse breccia (caprock to the Paradox Formation salt) may facilitate vertical migration of brine into the alluvial aquifer. Additionally, the ground-based EM mapping corroborated general patterns in depth to brine that were observed in previous AEM results while also revealing additional detail, including suspected focused brine discharge zones to the Dolores River. A river-based survey wherein EM data, channel depth and river water–specific conductance information were collected augmented these findings and indicated specific areas on both the western and eastern sides of the river where focused brine discharge may occur. This study comprises a large-scale, ground- and water-based geophysical mapping effort, including hundreds of HVSR soundings and 100s of kilometres of EM data, which were successfully translated into digital brine and bedrock surfaces that could be incorporated into groundwater modelling efforts, future well siting or other decision-making.

Colorado

Methods for estimating selected low-flow statistics at gaged and ungaged stream sites in Massachusetts

The U.S. Geological Survey, in cooperation with the Massachusetts Department of Conservation and Recreation, Office of Water Resources, computed selected at-site streamflow statistics at U.S. Geological Survey streamgages in and near Massachusetts and developed regional regression equations for estimating selected streamflows at ungaged stream sites in Massachusetts. Two sets of regional regression equations were developed: (1) the “mainland” equations, for mainland Massachusetts excluding the area covered by the second set, and (2) the “southeastern” equations, for the Plymouth-Carver-Kingston-Duxbury aquifer area in southeastern Massachusetts and for Cape Cod. The regression equations and at-site statistics may be used by Federal, State, and local water managers in addressing water-resources issues relevant in Massachusetts. Regional regression analyses for the mainland equations were developed to estimate the following 27 streamflow statistics: 99-, 98-, 95-, 90-, 85-, 80-, 75-, 70-, 60-, and 50-percent flow durations; monthly June, July, August, and September 90- and 50-percent flow durations; February, June, and August median of the monthly means; harmonic mean; and medians of the following annual low-flow frequency statistics: 7-day; 7-day, 2-year; 7-day, 10-year; 30-day, 2-year; and 30-day, 10-year. The analyses used 81 streamgages with minimal to no regulations in and near Massachusetts. The regression analyses determined that four basin characteristics—drainage area, combined hydrologic soils A and B, streamflow variability index, and annual mean temperature—were the only significant explanatory variables for the different mainland equations. Regional regression equations were developed for the Plymouth-Carver-Kingston-Duxbury aquifer area in southeastern Massachusetts and Cape Cod, because surface-water drainage areas and groundwater contributing areas do not always coincide in this area of the State. The regression analyses to estimate 10 flow durations from the 99th to 50th percentiles used 18 streamflow sites with some occasional minor regulations—because there are few unregulated streams in southeastern Massachusetts. The analyses determined that groundwater contributing area and storage (combined water bodies and wetlands) were the only significant explanatory variables in the southeastern equations.

Massachusetts

Hydraulic properties of the Madison aquifer system in the western Rapid City area, South Dakota

Available information on hydrogeology, data from borehole geophysical logs, and aquifer tests were used to determine the hydraulic properties of the Madison aquifer. From aquifer-test analysis, transmissivity and storage coefficient were determined for the Minnelusa and Madison aquifers, and vertical hydraulic conductivity (K v ') along with specific storage (Ss') for the Minnelusa confining bed. Borehole geophysical well logs were used to determine the thickness and location of the Minnelusa aquifer, the lower Minnelusa confining bed, and the Madison aquifer within the Madison Limestone. Porosity values determined from quantitative analysis of borehole geophysical well logs were used in analyzing the aquifer-test data. The average porosity at the two aquifer-test sites is about 10 percent in the Minnelusa aquifer, 5 percent in the lower Minnelusa confining bed, and 35 percent in the Madison aquifer. The first aquifer test, which was conducted at Rapid City production well #6, produced measured drawdown in the Minnelusa and Madison aquifers. Neuman and Witherspoon's method of determining the hydraulic properties of leaky two-aquifer systems was used to evaluate the aquifer-test data by assuming the fracture and solution-opening network is equivalent to a porous media. Analysis of the aquifer test for the Minnelusa aquifer yielded a transmissivity value of 12,000 feet squared per day and a storage coefficient of 3 x 10 -3 . The specific storage of the Minnelusa confining bed was 2 x 10 -7 per foot, and its vertical hydraulic conductivity was 0.3 foot per day. The transmissivity of the Madison aquifer at this site was 17,000 feet squared per day, and the storage coefficient was 2 x 10 -3 . The second aquifer test, which was conducted at Rapid City production well #5 (RC-5) produced measured drawdown only in the Madison aquifer. Hantush and Jacob's method of determining the hydraulic properties of leaky confined aquifers with no storage in the confining bed was used to evaluate the aquifer-test data by assuming the fracture and solution-opening network is equivalent to a porous media. The analysis of data from the RC-5 aquifer test showed that transmissivity was not equal in all directions. Hantush's method was used to determine the direction of radial anisotropy and magnitude of the major and minor axes of transmissivity. The major axis of transmissivity is at an angle of 42° east of north, and the transmissivity along this axis is about 56,000 feet squared per day. The minor axis of transmissivity is at an angle of 48° west of north, and the transmissivity along this axis is about 1,300 feet squared per day. The major axis of transmissivity intersects Cleghorn Springs, a large resurgent spring on the west edge of Rapid City. The shape of the potentiometric contours of the Madison aquifer near RC-5 agree with the orientation of the transmissivity ellipse. The average value of the storage coefficient from the isotropic analysis of the aquifer-test data was 3.5 x 10 -4 , and the average vertical hydraulic conductivity of the lower Minnelusa confining bed was 9.6 x 10 -3 foot per day.

South Dakota

Completion summary for monitor wells NRF-17 and NRF-18 at the Naval Reactors Facility, Idaho National Laboratory, Idaho

The U.S. Geological Survey (USGS)—in cooperation with the U.S. Department of Energy (DOE) for the Naval Reactors Laboratory Field Office that supports operations for the Naval Reactors Facility (NRF) located at the Idaho National Laboratory (INL)—drilled and constructed well NRF-17 (formerly borehole USGS 151) and well NRF-18 (formerly borehole USGS 152) for stratigraphic framework analyses and water-quality monitoring at the Idaho National Laboratory (INL) near the NRF, in southeastern Idaho. Borehole USGS 151 was continuously cored from about 48 to 1,070 feet (ft) below land surface (BLS); rotary drilled from approximately 1,070 to 1,720 ft BLS; and re-drilled to complete construction as a monitor well NRF-17, completed to 461 ft BLS. Borehole USGS 152 was continuously cored from approximately 19 to 1,259 ft BLS; rotary drilled from approximately 1,259 to 1,630 ft BLS; and re-drilled to complete construction as a monitor well NRF-18, completed to 450 ft BLS. Geophysical data were examined with photographed core material to record lithologic descriptions and to suggest zones where groundwater flow was anticipated. Basalt flows varied from highly fractured to dense, with high-to-low vesiculation. Well NRF-17 generally was constructed in mostly dense basalt (greater than 75 percent), and well NRF-18 was constructed in primarily fractured and (or) vesicular basalt. In well NRF-17, the well capacity is directly affected by the limited amount of fractured basalt, which serves as the primary pathway for groundwater. This effect was observed during the pumping test conducted after the well's final construction. Single-well aquifer tests were done at wells NRF-17 and NRF-18 to provide estimates of transmissivity and hydraulic conductivity after final well construction and initial well development. Estimated values of transmissivity and hydraulic conductivity for well NRF-17 were 8.81 feet squared per day (ft 2 /d) and 1.04×10 -2 feet per day (ft/d), respectively. Estimated values of transmissivity and hydraulic conductivity for well NRF-18 were 4.77×10 3 ft 2 /d and 5.61 ft/d, respectively. The NRF-17 pump test resulted in 19.41 ft of measured drawdown at a sustained average pumping rate of 3.3 gallons per minute (gal/min). The NRF-18 pump test resulted in 0.55 ft of measured drawdown at a sustained average pumping rate of 31.0 gal/min. Water-quality samples collected from the two wells were analyzed for cations, anions, metals, nutrients, volatile organic compounds, stable isotopes, and radionuclides. Water samples for select inorganic constituents showed concentrations consistent with signatures from tributary valley groundwater with influences from ephemeral surface-water recharge from the Big Lost River. Water-quality samples analyzed for stable isotopes of oxygen and hydrogen are consistent with signatures from tributary valley groundwater and surface-water recharge inputs to the aquifer. No measured water-quality results were greater than their respective maximum contaminant levels for public drinking-water supplies. Inorganic and nutrient water-quality results for well NRF-17 and well NRF-18 suggest the groundwater in this area is potentially affected by industrial wastewater disposal.

Idaho

Geologic framework and hydrostratigraphy of the Edwards and Trinity aquifers within parts of Bandera and Kendall Counties, Texas

The karstic Edwards and Trinity aquifers are classified as major sources of water in south-central Texas by the Texas Water Development Board. During 2019–23 the U.S. Geological Survey, in cooperation with the Edwards Aquifer Authority, mapped and described the geology and hydrostratigraphy of the rocks composing the Edwards and Trinity aquifers within parts of Bandera and Kendall Counties from field observations of the surficial expressions of the rocks. The thicknesses of the mapped lithostratigraphic and hydrostratigraphic units were also estimated from field observations in the study area. The Cretaceous rocks in the study area are part of the Trinity Group and Edwards Group. The groups, formations, and members are composed primarily of layers of marls, shales, and limestones. The limestones are composed of mudstone through grainstone, framestone and boundstone, dolomite, and argillaceous and evaporitic rocks. The principal structural feature in the study area is the Balcones fault zone. The Balcones fault zone is the result of late Oligocene and early Miocene extensional faulting and fracturing that was a result of the eastern Edwards Plateau uplift. In the Balcones fault zone, most of the faults in the study area are high-angle to vertical, en echelon, normal faults that are predominantly downthrown to the southeast. Hydrostratigraphically, the rocks exposed in the study area are those that contain the Edwards aquifer, the upper zone of the Trinity aquifer, and the middle zone of the Trinity aquifer. Descriptions of the hydrostratigraphic units, thicknesses, hydrologic function, porosity types, and field identification and observations are provided, including those for the informal Bandera and Love Creek hydrostratigraphic units of the Edwards aquifer, which were identified through the mapping for this study.

Texas

Water quality of the Quaternary and Ada-Vamoosa aquifers on the Osage Reservation, Osage County, Oklahoma, 1997

The project was to provide information on the quality of ground water from rural-domestic-water wells within the Osage Reservation and compare the water-quality to proximity to oil wells. About 38,500 oil wells have been drilled in the Reservation since drilling began in 1896. About 1,480 square miles or 64 percent of the Reservation is within a quarter mile of an oil well. The unconfined Quaternary sand aquifer covers about 315 square miles or about 14 percent of the Reservation and the confined Ada-Vamoosa sandstone aquifer covers about 800 square miles or about 35 percent of the Reservation. Fifty-eight percent of the Quaternary aquifer and 69 percent of the outcrop area of the Ada-Vamoosa aquifer are within a quarter mile of an oil well. One hundred twenty domestic ground-water wells were sampled from the Quaternary and Ada-Vamoosa aquifers. Forty-nine percent of the Reservation is underlain by the aquifers. Ground-water quality is good on most of the Reservation, but the use of domestic-water-supply wells tend to minimize water-quality problems. Existing water-supply wells commonly are located in areas that produce usable volumes of potable water. Several constituents in samples from the Ada-Vamoosa aquifer within a quarter mile of an oil well were significantly greater than from the aquifer not near oil wells. The constituents include specific conductance, dissolved solids, sodium, sulfate, chloride, bromide, and silica. These ions are probably derived from brine water. In the Ada-Vamoosa aquifer subgroups, 57 percent of the samples near oil wells and 24 percent of the samples not near oil wells had dissolved-solids concentrations greater than 500 milligrams per liter. The water quality in the Quaternary and Ada-Vamoosa aquifers is similar in areas where no oil wells have been drilled but is significantly different for several constituents. Median concentrations of major constituents from the Ada-Vamoosa aquifer not near oil wells were less than or equal to values from the Quaternary aquifer. Sixty-four percent of the water-quality samples from the Quaternary and 51 percent from the Ada-Vamoosa aquifers have dissolved-solids concentrations less than the secondary drinking water regulations of 500 milligrams per liter. Fifty-nine percent of the aquifer samples in the Quaternary aquifer subgroups not near oil wells and 70 percent of the samples near oil wells had dissolved solids less than 500 milligrams per liter. Areas in the Ada-Vamoosa aquifer near Hominy, Pershing, and Hula Lake have dissolved-solids concentrations greater than the secondary drinking water regulations. Water-quality samples from the Quaternary aquifer in these areas also have dissolved-solids concentrations greater than 500 milligrams per liter.

Oklahoma

Geologic framework and hydrostratigraphy of the Edwards and Trinity aquifers within Hays County, Texas

During 2023–24, the U.S. Geological Survey, in cooperation with the Edwards Aquifer Authority, revised a previous publication of the geologic framework and hydrostratigraphy of the Edwards and Trinity aquifers that was completed during 2018 within Hays County, Texas. The purpose of this report is to present the updated geologic framework and hydrostratigraphy of the rocks containing the Edwards and Trinity aquifers in Hays County from field observations of the surficial expressions of the rocks. The report includes a detailed 1:24,000-scale hydrostratigraphic map with names and descriptions of the geologic framework and hydrostratigraphic units (HSUs) in the study area. The study includes updates to the interpretation of the Kainer Formation of the Edwards Group with the addition of a burrowed unit between the basal nodular and dolomitic members. Hydrostratigraphy was also updated with the addition of the Seco Pass HSU for the burrowed member of the Kainer Formation. The study also includes updates to the interpretation of the hydrostratigraphy of the Trinity aquifer with the addition of the cavernous HSU at the top of the upper zone of the Trinity aquifer and the Herff Falls HSU between the Bulverde and Rust HSUs of the middle zone of the Trinity aquifer. This updated report provides additional information about a complex aquifer system. The complexity in the aquifer system results from a combination of the original depositional history, bioturbation, development of primary and secondary porosity, postdepositional diagenesis, fracturing, and faulting.

Texas

James Buttle review: The characteristics of baseflow resilience across diverse ecohydrological terrains

The dynamic storage of aquifers is the portion of groundwater that can potentially drain to any given point along a stream to create baseflow. Baseflow typically occurs year-round in perennial streams, though the characteristics and stability of dynamic storage are often most important to instream processes during extended dry periods (without precipitation and snowmelt) when runoff and quickflows are minimised. The term ‘baseflow resilience’ is defined for this review as the tendency of baseflow in streams to maintain a consistent volume and water quality year to year while under stress from climate variability and extremes, along with anthropogenic stressors such as water withdrawals, land use change, and water quality degradation. ‘Baseflow resilience’ has, in part, a user-defined meaning spanning water supply and water quality variables of primary interest. Watershed characteristics that directly impact resilience can often produce non-intuitive feedbacks that enhance some attributes of baseflow while simultaneously impairing others. For example, permeable stream corridor geology creates strong stream-groundwater hydrologic connectivity, yet fast groundwater drainage via preferential high-permeability flowpaths can lead to streamflow not being sustained during extended dry periods. Also, shallow groundwater sources are generally more immediately vulnerable to extreme events, warming, salinization, transpiration, and precipitation drought, compared to deeper groundwater. Yet baseflow drought in streams influenced by deeper groundwater can lag precipitation drought by years, and contaminant legacies may propagate through deep groundwater flowpaths to receiving waters for decades to centuries. Finally, irrigation withdrawals can intercept groundwater that would have drained to streams, and the application of irrigation may leach contaminants from the soil zone by unnaturally raising water tables, yet irrigation return flows can sustain baseflow and groundwater-dependent habitats in semiarid areas. This review covers the concept of hydrologic resilience in the context of stream baseflow processes and summarises the common hydrogeological controls on, and multiscale stressors of, dynamic groundwater storage. Further, we present several quantitative metrics to assess a range of water supply to water quality baseflow characteristics using both broadly available and boutique data types, a subset of which are demonstrated using data from the Delaware River Basin, USA.

Delaware River Basin

Recharge rates and aquifer hydraulic characteristics for selected drainage basins in middle and east Tennessee

Quantitative information concerning aquifer hydrologic and hydraulic characteristics is needed to manage the development of ground-water resources. These characteristics are poorly defined for the bedrock aquifers in Middle and East Tennessee where demand for water is increasing. This report presents estimates of recharge rate, storage coefficient, diffusivity, and transmissivity for representative drainage basins in Middle and East Tennessee, as determined from analyses of stream-aquifer interactions. The drainage basins have been grouped according to the underlying major aquifer, then statistical descriptions applied to each group, in order to define area1 distribution of these characteristics. Aquifer recharge rates are estimated for representative low, average, and high flow years for 63 drainage basins using hydrograph analysis techniques. Net annual recharge during average flow years for all basins ranges from 4.1 to 16.8 in/yr (inches per year), with a mean value of 7.3 in. In general, recharge rates are highest for basins underlain by the Blue Ridge aquifer (mean value11.7 in/yr) and lowest for basins underlain by the Central Basin aquifer (mean value 5.6 in/yr). Mean recharge values for the Cumberland Plateau, Highland Rim, and Valley and Ridge aquifers are 6.5, 7.4, and 6.6 in/yr, respectively. Gravity drainage characterizes ground-water flow in most surficial bedrock aquifer in Tennessee. Accordingly, a gravity yield analysis, which compares concurrent water-level and streamflow hydrographs, was used to estimate aquifer storage coefficient for nine study basins. The basin estimates range from 0.002 to 0.140; however, most estimates are within a narrow range of values, from 0.01 to 0.025. Accordingly, storage coefficient is estimated to be 0.01 for all aquifers in Middle and East Tennessee, with the exception of the aquifer in the inner part of the Central Basin, for which storage coefficient is estimated to be 0.002. Estimates of aquifer hydraulic diffusivity are derived from estimates of the streamflow recession index and drainage density for 75 drainage basins; values range from 3,300 to 130,000 ft^2/d (feet squared per day). Basin-specific and site-specific estimates of transmissivity are computed from estimates of hydraulic diffusivity and specific-capacity test data, respectively. Basin-specific, or areal, estimates of transmissivity range from 22 to 1,300 ft^2/d, with a mean of 240 ft^2/d In general, areal transmissivity is highest for basins underlain by the Cumberland Plateau aquifer (mean value 480 ft^2/d) and lowest for basins underlain by the Central Basin aquifer (mean value 79 ft^2/d). Mean transmissivity values for the Highland Rim, Valley and Ridge, and Blue Ridge aquifer are 320,140, and 120 ft^2/d respectively. Site-specific estimates of transmissivity, computed from specific-capacity data from 118 test wells in Middle and East Tennessee range from 2 to 93,000 ft^2/d with a mean of 2,600 ft^2/d Mean transmissivity values for the Cumberland Plateau, Highland Rim, Central Basin, Valley and Ridge, and Blue Ridge aquifers are 2,800,1,200, 7,800, 390, and 65Oft Id, respectively.

Tennessee

Assessing flood water infiltration and storage in a restored floodplain

In urban areas, floodplain restoration is gaining prominence as a strategy for restoring the natural functions of floodplain ecosystems and reducing flood risk. This has spurred research into potential interactions between floodwaters, the hyporheic zone, and the floodplain aquifer. An urban restored stream in Wisconsin, USA, was used as a case study to examine four methods to estimate floodplain infiltration and storage during overbank floods. We characterised flood-related infiltration over a 4-year period from 2018 through 2021 by simultaneously and continuously measuring groundwater levels and vertical temperature profiles with stream water levels linked to high-resolution flood inundation maps. High-resolution topographic data helped to quantify surface floodplain storage and the unsaturated soil volume relative to flood stage. Infiltration estimates from the simple methods align well with those from the more complex methods; however, the complex methods provide additional insights about the factors influencing infiltration. Results from all methods indicate that the volume of water that vertically infiltrates during floods is likely small relative to the total volume of the flood, with 0.08%–0.52% of flood water infiltrating into the floodplain, on average. Spatially variable vertical hydraulic gradients, driven by flood depth, groundwater level, and permeability, imply heterogeneous patterns of infiltration across the floodplain. Gradients favourable for infiltration typically occurred during the onset of flooding but, over the study period, were mostly (98% of the time) favourable for groundwater discharge to the channel (non-flood periods). These findings highlight the importance of considering surface-groundwater dynamics, floodplain soils, and unsaturated floodplain volume in defining the benefits of floodplain infiltration for flood attenuation.

Wisconsin

An evaluation of the effects of different deicing salt application rates on three watersheds in Essex County, New York

The U.S. Geological Survey, in cooperation with the New York State Department of Transportation, evaluated the effects of different deicing salt application rates on surface water, groundwater, and highway runoff quality near State highways in northern New York. Three reaches of State highways were tested with different deicing treatments between October 2019 and November 2022: a salt-sand mixture (Treatment A), a salt mixture applied at a lower rate (Treatment B), and a control mixture consistent with typical deicing salt amounts and application rates. Data on pavement conditions and the quality of surface water, highway runoff, and groundwater were collected. Surface electromagnetic data were also collected. Surface-water and groundwater quality downgradient from the State highways were compared with water quality at upgradient locations. The percentage of snow or ice coverage was used to evaluate the effectiveness of the salt applications. This report provides an overview of the transport of deicing salt. The Treatment B watershed had deicing mixture applied more frequently than other highway reaches, which caused it to have the highest annual total chloride application. Despite differences in chloride application, flow-weighted mean chloride concentrations in highway runoff were comparable across treatments. Chloride concentrations were elevated in surface water and groundwater downgradient from highways relative to chloride concentrations upgradient from highways. A chloride mass balance, calculated for one treatment watershed, indicated that groundwater affected by legacy deicing practices may be contributing additional chloride to surface water. Spatial patterns from electromagnetic surveys show a shallow saline plume alongside the highway in that area. Differences in winter severity and pavement-surface conditions drove deicing salt applications in the treatment areas. This study found that several factors affect chloride loads in the watersheds, including variable winter conditions, adaptive snow and ice management, legacy management practices, and area-specific aquifer and groundwater conditions.

New York

Geologic framework and hydrostratigraphy of the Edwards and Trinity aquifers within northern Medina County, Texas

During 2023–24, the U.S. Geological Survey, in cooperation with the Edwards Aquifer Authority, revised a previous publication of the geologic framework and hydrostratigraphy of the Edwards and Trinity aquifers that was completed during 2018–20 within northern Medina County, Texas. The purpose of this report is to present the updated geologic framework and hydrostratigraphy of the rocks containing the Edwards and Trinity aquifers in northern Medina County from field observations of the surficial expressions of the rocks. The report includes a detailed 1:24,000-scale hydrostratigraphic map with names and descriptions of the geologic and hydrostratigraphic units (HSUs) in the study area. This study includes updates to the geology of the Kainer Formation (or its stratigraphic equivalent, the Fort Terrett Formation) with the addition of a burrowed unit between the basal nodular and dolomitic members. The hydrostratigraphy was also updated with the addition of HSU IIA for the upper part of the Devils River Limestone and the Seco Pass HSU for the burrowed member of the Kainer (or Fort Terrett) Formation. The Cretaceous age rocks (listed in ascending order) in the study area are part of the Trinity Group, Edwards Group and stratigraphically equivalent Devils River Limestone, Washita Group, Eagle Ford Group, Austin Group, and Taylor Group, with isolated areas where Late Cretaceous age igneous rocks have intruded. The groups and formations are composed primarily of relatively thick layers of clays, shales, and limestone. The igneous rocks are coarse-grained ultramafic in composition. Hydrostratigraphically, the rocks exposed in the study area (listed in descending order from land surface) are igneous, the upper confining unit to the Edwards aquifer, the Edwards aquifer, the upper zone of the Trinity aquifer, and the upper part of the middle zone of the Trinity aquifer. The karstic carbonate Edwards and Trinity aquifers developed because of their original depositional history, primary and secondary porosity, diagenesis, fracturing, and faulting. These factors have resulted in development of modified porosity, permeability, and transmissivity within and between the aquifers.

Texas

Hydrogeologic framework of the Mountain Home area, southern Idaho

In the arid western Snake River Plain around the City of Mountain Home, Idaho, declining groundwater levels concern agricultural, municipal, and other water users who rely on groundwater for sustenance because surface-water resources are limited. The U.S. Geological Survey developed this hydrogeologic framework to provide an updated characterization of groundwater resources in the western Snake River Plain around the City of Mountain Home. The hydrogeologic framework comprises: (1) a conceptual description of hydrogeologic units, (2) a three-dimensional hydrogeologic model and borehole database, (3) a map of groundwater levels and change, and (4) a discussion of groundwater occurrence and movement within the study area. Hydrogeologic units were defined based on existing literature and the borehole database compiled for this study; the five hydrogeologic units are granite, rhyolite, basalt, fine-grained sediments, and coarse-grained sediments. Each unit can bear water, but the main regional aquifer in the study area occurs in the basalt and fine-grained sediment units with depth to water ranging from 150 to 765 feet. A perched groundwater zone near the City of Mountain Home is primarily hosted in basalt and used domestically with most depths to water ranging from 30 to 100 feet. Interflow zones, scoria, and vertical fractures create heterogeneity within the basalt hydrogeologic unit that exerts strong control on groundwater movement, creating horizontal perching conditions and zones of enhanced vertical conductivity that facilitate downward groundwater percolation. In the fine- and coarse-grained sediments and rhyolite units, inferred faults both impede and enhance groundwater movement. The borehole database was constructed by digitizing 540 well-driller reports and was used to build a three-dimensional hydrogeologic framework model which reasonably represents the spatial distribution of hydrogeologic units in the study area. Generally, fine-grained sediments underlie much of the study area, with basalt concentrated in the central and western study area and rhyolite and granite in the uplands to the north. Groundwater levels were measured in 180 wells in March and November 2023; these data were used to develop water-table contour maps and describe groundwater-level change over an irrigation season. Groundwater generally flows south-southwest to the Snake River and groundwater levels declined across most of the study area (from 0.03 to 22.01 feet) between spring and autumn 2023, which is consistent with long-term declines in the Cinder Cone Butte Critical Groundwater Area and Mountain Home Groundwater Management Area. Groundwater levels rose (0.6 to 15.44 feet) over the irrigation season in most wells in the perched groundwater zone near the City of Mountain Home and near the Snake River, indicating the importance of surface-water recharge to groundwater in areas where surface water irrigation occurs. In aggregate, this hydrogeologic framework provides an updated characterization of and new insights into groundwater resources in the study area to help inform water resources management.

Idaho

Hydrogeologic investigation and simulation of ground-water flow in the Upper Floridan Aquifer of north-central Florida and southwestern Georgia and delineation of contributing areas for selected city of Tallahassee, Florida, water-supply wells

A 4-year investigation of the Upper Floridan aquifer and ground-water flow system in Leon County, Florida, and surrounding counties of north-central Florida and southwestern Georgia began in 1990. The purpose of the investigation was to describe the ground-water flow system and to delineate the contributing areas to selected City of Tallahassee, Florida, water-supply wells. The investigation was prompted by the detection of low levels of tetrachloroethylene in ground-water samples collected from several of the city's water-supply wells. Hydrologic data and previous studies indicate that; ground-water flow within the Upper Floridan aquifer can be considered steady-state; the Upper Floridan aquifer is a single water-bearing unit; recharge is from precipitation; and that discharge occurs as spring flow, leakage to rivers, leakage to the Gulf of Mexico, and pumpage. Measured transmissivities of the aquifer ranged from 1,300 ft 2 /d (feet squared per day) to 1,300,000 ft2/d. Steady-state ground-water flow in the Upper Floridan aquifer was simulated using a three-dimensional ground- water flow model. Transmissivities ranging from less than 5,000 ft2/d to greater than 11,000,000 ft 2 /d were required to calibrate to observed conditions. Recharge rates used in the model ranged from 18.0 inches per year in areas where the aquifer was unconfined to less than 2 inches per year in broad areas where the aquifer was confined. Contributing areas to five Tallahassee water-supply wells were simulated by particle- tracking techniques. Particles were seeded in model cells containing pumping wells then tracked backwards in time toward recharge areas. The contributing area for each well was simulated twice, once assuming a porosity of 25 percent and once assuming a porosity of 5 percent. A porosity of 25 percent is considered a reasonable average value for the Upper Floridan aquifer; the 5 percent porosity simulated the movement of ground-water through only solution-enhanced bedding plains and fractures. The contributing areas were generally elliptical in shape, reflecting the influence of the sloping potentiometric surface. The contributing areas delineated for a 5 percent porosity were always much larger than those determined using a 25 percent porosity. The lowest average ground-water velocity computed within a contributing area, using a 25 percent porosity, was 1.0 ft/d (foot per day) and the highest velocity was 1.6 ft/d. The lowest average ground-water velocity, determined using a 5 percent porosity, was 2.4 ft/d and the highest was 7.4 ft/d. The contributing areas for each of the five wells was also determined analytically and compared to the model-derived areas. The upgradient width of the simulated contributing areas were larger than the upgradient width of the analytically determined contributing areas for four of the five wells. The model could more accurately delineate contributing areas because of the ability to simulate wells as partially penetrating and by incorporating complex, three-dimensional aquifer characteristics, which the analytical method could not.

Florida, Georgia

Ground-water flow in the surficial aquifer system and potential movement of contaminants from selected waste-disposal sites at Cecil Field Naval Air Station, Jacksonville, Florida

As part of the Installation Restoration Program, Cecil Field Naval Air Station, Jacksonville, Florida, is considering remedialaction alternatives to control the possible movement of contaminants from sites that may discharge to the surface. This requires a quantifiable understanding of ground-water flow through the surficial aquifer system and how the system will respond to any future stresses. The geologic units of interest in the study area consist of sediments of Holocene to Miocene age that extend from land surface to the base of the Hawthorn Group. The hydrogeology within the study area was determined from gamma-ray and geologists' logs. Ground-water flow through the surficial aquifer system was simulated with a seven-layer, finite-difference model that extended vertically from the water table to the top of the Upper Floridan aquifer. Results from the calibrated model were based on a long-term recharge rate of 6 inches per year, which fell in the range of 4 to 10 inches per year, estimated using stream hydrograph separation methods. More than 80 percent of ground-water flow circulates within the surficial-sand aquifer, which indicates that most contaminant movement also can be expected to move through the surficial-sand aquifer alone. The surficial-sand aquifer is the uppermost unit of the surficial aquifer system. Particle-tracking results showed that the distances of most flow paths were 1,500 feet or less from a given site to its discharge point. For an assumed effective porosity of 20 percent, typical traveltimes are 40 years or less. At all of the sites investigated, particles released 10 feet below the water table had shorter traveltimes than those released 40 feet below the water table. Traveltimes from contaminated sites to their point of discharge ranged from 2 to 300 years. The contributing areas of the domestic supply wells are not very extensive. The shortest traveltimes for particles to reach the domestic supply wells from their respective contributing areas ranged from 70 to 200 years.

Florida

Design, revisions, and considerations for continued use of a ground-water-flow model of the coastal plain aquifer system in Virginia

A digital numerical model of the ground-water-flow system in the Virginia Coastal Plain was constructed as part of the Regional Aquifer System Analysis program of the U.S. Geological Survey and subsequently revised based on reinterpretations of the hydrogeologic framework. The revised model has been incorporated by the Virginia Department of Environmental Quality as a means to evaluate the effects of existing and proposed ground-water withdrawals. The revised model, which is documented here, includes many design features of the original model. Principal modifications are (1) reassignment of some model layers to represent different aquifers, (2) replacement of applied recharge and the uppermost surface-water layer by constant-head cells to represent the unconfined aquifer, and (3) revision of the lateral extents and transmissivity and vertical leakance values assigned to model layers. Ground-water levels simulated by the revised model under steady-state conditions, using withdrawal rates representing the period 1978-80, generally are similar to the water levels simulated by the original model under transient conditions using the same withdrawal rates. Differences probably result largely from changes in transmissivity and vertical leakance values. T he revised model enables the continued evaluation of development of the large and complex aquifer system. Improved information on parts of some aquifers has been incorporated. Only large, regional-scale trends in ground-water water levels, flow directions, and flow rates are simulated, however, and not local trends and (or) short-term changes in water level and flow. Changing hydraulic stresses, knowledge of hydrogeologic conditions, and resource-management needs require periodic revision of the model to maintain its usefulness for the management of ground-water resources in the Virginia Coastal Plain.

Virginia

Biodegradation of chlorinated ethenes at a karst site in middle Tennessee

This report presents results of field and laboratory investigations examining the biodegradation of chlorinated ethenes in a karst aquifer contaminated with trichloroethylene (TCE). The study site, located in Middle Tennessee, was selected because of the presence of TCE degradation byproducts in the karst aquifer and available site hydrologic and chlorinated-ethene information. Additional chemical, biological, and hydrologic data were gathered to evaluate whether the occurrence of TCE degradation byproducts in the karst aquifer was the result of biodegradation within the aquifer or simply transport into the aquifer. Geochemical analysis established that sulfate-reducing conditions, essential for reductive dechlorination of chlorinated solvents, existed in parts of the contaminated karst aquifer. Other areas of the aquifer fluctuated between anaerobic and aerobic conditions and contained compounds associated with cometabolism, such as ethane, methane, ammonia, and dissolved oxygen. A large, diverse bacteria population inhabits the contaminated aquifer. Bacteria known to biodegrade TCE and other chlorinated solvents, such as sulfate-reducers, methanotrophs, and ammonia-oxidizers, were identified from karst-aquifer water using the RNA-hybridization technique. Results from microcosms using raw karst-aquifer water found that aerobic cometabolism and anaerobic reductive-dechlorination degradation processes were possible when appropriate conditions were established in the microcosms. These chemical and biological results provide circumstantial evidence that several biodegradation processes are active in the aquifer. Additional site hydrologic information was developed to determine if appropriate conditions persist long enough in the karst aquifer for these biodegradation processes to be significant. Continuous monitoring devices placed in four wells during the spring of 1998 indicated that pH, specific conductance, dissolved oxygen, and oxidation-reduction potentials changed very little in areas isolated from active ground-water flow paths. These stable areas in the karst aquifer had geochemical conditions and bacteria conducive to reductive dechlorination of chlorinated ethenes. Other areas of the karst aquifer were associated with active ground-water flow paths and fluctuated between anaerobic and aerobic conditions in response to rain events. Associated with this dynamic environment were bacteria and geochemical conditions conducive to cometabolism. In summary, multiple lines of evidence developed from chemical, biological, and hydrologic data demonstrate that a variety of biodegradation processes are active in this karst aquifer.

Tennessee