Geology topics
Ryan J. McAleer
Publications and source records attributed to Ryan J. McAleer.
Geology & mineralogy of the Old Mine Park area Trumbull Connecticut
Old Mine Park, in the northern Trumbull area (also known as Long Hill) of southwestern Connecticut, is a recreation area encompassing the mineral-rich hill of “Saganawamps” and owned by the Town of Trumbull. Most of its 72 acres are wooded, rocky and undeveloped but it is surrounded by dense infrastructure and transportation, residential, retail, and commercial development (Figure 1). It preserves the first tungsten mine operated east of the Mississippi and the first topaz locality identified in the USA (Hitchcock and Silliman, 1825), as well as the type locality for the mineral tungstite (WO 3 ·H 2 O). Hiking and biking trails cross the property and continue beyond the park along the former New Haven railroad line that parallels the Pequonnock River, which flows through the southern part of the park. Access is from the south via Old Mine Road, or from the north via Corporate Drive. During the mining era and for many decades after its creation the park was a famous source of mineral specimens. In 2016 the Trumbull Parks and Recreation Commission suspended collecting of any kind.
Unmixing multiple metamorphic muscovite age populations with powder X-ray diffraction and 40Ar/39Ar analysis
A combination of modal estimates from powder X-ray diffraction (XRD) experiments and argon isotopic data shows that muscovite 40 Ar/ 39 Ar total gas age correlates with muscovite composition near the retrograde Bald Mountain shear zone (BMSZ) in Claremont, New Hampshire, and that the shear zone was active at ∼245 Ma. Petrologic study demonstrates that chemical disequilibrium is preserved in muscovite grains in these samples. The recognition of this preservation is critical to the interpretation of the 40 Ar/ 39 Ar step-heating experiments, which never produce age plateaus and yield spectra with steps that range in age by ∼20 Ma. Petrographic, compositional, and crystallographic data all indicate that the age spectra reflect dissolution of metastable Na-rich muscovite and precipitation of stable Na-poor muscovite associated with deformation in the BMSZ.Comparison of whole rock and muscovite concentrate XRD patterns from individual samples demonstrates that the mineral separation process can fractionate these muscovite populations. Therefore, four muscovite concentrates of varying magnetic susceptibility were prepared from a single hand sample, analyzed by XRD, and dated. These four splits define a mixing line that resolves end-member ages of 244.5 ± 4.2 Ma and 302.5 ± 12.5 Ma (1σ). Although the ages are imprecise, the petrologically supported conclusion that these schists preserve two discrete ages is distinct from an interpretation that the spectra reflect cooling through closure at ∼270 Ma, as might be concluded in the absence of petrologic characterization. The XRD results also demonstrate that, even well above anchizone conditions, petrologic information relevant to 40 Ar/ 39 Ar dating is observable in subtle variations in the crystallography of muscovite grains.
Diagenetic barite-pyrite-wurtzite formation and redox signatures in Triassic mudstone, Brooks Range, northern Alaska
Mineralogical and geochemical studies of interbedded black and gray mudstones in the Triassic part of the Triassic-Jurassic Otuk Formation (northern Alaska) document locally abundant barite and pyrite plus diverse redox signatures. These strata, deposited in an outer shelf setting at paleolatitudes of ~45 to 60°N, show widespread sedimentological evidence for bioturbation. Barite occurs preferentially in black mudstones (TOC = 0.93–6.46 wt%), forming displacive euhedral crystals with pyrite inclusions and rims, and late albite inclusions or intergrowths. Pyrite also occurs as small (3–20 μm) framboids, discontinuous laminae, euhedral and anhedral crystals, and replacements of barite and fossils (mainly radiolarians). Paragenetically early wurtzite is present as clusters of very small (1–3 μm) aggregates of radiating crystals 0.5 to 1.0 μm long with cores of organic matter that overgrow framboidal pyrite; later wurtzite forms 10- to 30-μm bladed crystals. Equant grains (3–30 μm) and small (20 μm) angular clusters of zinc sulfide that include <1-μm-long, comb-like structures are sphalerite or wurtzite, or both. Minor siderite forms euhedral crystals intergrown with albite that enclose wurtzite and barite. Illite shows intergrowths with sphalerite; rare K-feldspar is intergrown with barite. Formation of these minerals and assemblages is attributed to early diagenetic processes. Whole-rock geochemical data for 15 samples show large ranges in redox proxies including Post Archean Average Shale (PAAS)-normalized enrichment factors (EFs) for V, U, Mo, and Re, and Al-normalized ratios for V, U, and Mo. Results for most black mudstones, with or without abundant barite and/or pyrite, suggest deposition within an oxygen minimum zone. Cerium anomalies, PAAS-normalized and calculated on a detrital-free basis, range widely from 0.49 to 0.96 and may reflect diagenetic overprinting by Ce-depleted fluids. Considering data for both black and gray mudstones, the overall geochemical pattern together with evidence from pyrite framboid sizes suggest that redox conditions fluctuated greatly from euxinic to oxic, like the redox profiles reported for modern shelf sediments offshore Peru and Namibia. The euxinic redox signatures in some Otuk black mudstones may correlate with widespread Early to Middle Triassic ocean anoxic events proposed for other regions. Calculations of median EFs for trace elements in Otuk black mudstones reveal both enrichments and depletions. Normalizations to the median composition of the three least-mineralized black mudstones show that barite- and/or pyrite-rich samples display large (>50%) positive changes for Li (+80.4%), V (+75.6%), Sr (+75.9%), Ba (+790%), Cu (+92.1%), Ni (+169%), Ag (+156%), Au (+3091%), As (+109%), Sb (+476%), and Se (+205%); Zn shows a moderate positive change of +42.1%. Moderate negative changes are evident only for Ge (−47.2%) and W (−30.6%). The local enrichments may reflect one or more factors including redox variations in bottom waters and pore fluids, element mobility during diagenesis, and selective fractionation into minerals such as barite, pyrite, and wurtzite. Anomalously low U/Al and UEF values, compared to those for other modern and ancient organic-rich sediments and sedimentary rocks, are attributed to increased solubility and loss of U during bioturbation-related oxygenation in the subsurface. Physicochemical constraints on barite, pyrite, and wurtzite formation are informed by use of a pH-fO2 plot constructed at 10 °C. Based on paragenetic evidence for multistage deposition of these three minerals, together with the presence of illite intergrown with ZnS and K-feldspar with barite, proposed diagenetic trends involve an increase in pH and fO2 related to the ingress of sulfate-rich pore fluids during bioturbation, followed by a return to lower then higher pH and fO2 conditions linked to carbon, sulfur, barium, and iron cycling during diagenesis. Labile Ba of marine pelagic origin was mobilized from organic-rich sediment upward to the sulfate-methane transition zone where barite precipitated during the interaction of reduced Ba- and CH4-rich fluids with sulfate-bearing pore fluids. The formation of paragenetically early wurtzite (ZnS) crystals, as well as locally high EF values for Cu, Ni, Ag, and Au, is attributed to metal enrichment of pore fluids, with sources being derived in part from water-column deposition from hydrothermal plumes related to coeval Triassic seafloor vent systems including a volcanogenic massive sulfide deposit in British Columbia and the Wrangellia Large Igneous Province in Alaska.
A review of spatially resolved techniques and applications of organic petrography in shale petroleum systems
This review examines new techniques and applications of organic petrography in source-rock reservoir petroleum systems that have occurred along with development of the global ‘shale revolution’ in energy resources. The review is limited to techniques and instrumentation that provide spatially resolved information, typically at or below microscales, for dispersed organic matter occurring in situ in samples of shale and mudrock. A brief summary of ion beam sample preparation is followed by discussion of the most common analytical techniques and applications. Advantages and limitations of each technique, including requisite sample preparation, types of information generated [e.g., molecular or elemental (isotopic) abundance], sensitivity, and resolution are discussed. In a few cases, techniques not yet applied to organic petrology of shale or mudrock are described (e.g., X-ray photoelectron spectroscopy imaging), in anticipation of near-term future application. The most common in situ techniques applied for characterization of organic matter in shale and mudrock include optical (including fluorescence) and electron microscopies, Raman, fluorescence, and infrared spectroscopies, and surficial measurements via force microscopy. Techniques that show growing application to organic petrography of shale include tip-enhanced photothermal infrared spectroscopy, mass spectrometry imaging, and synchrotron-based spectroscopies, among others. It is anticipated that the future of dispersed organic matter petrography will hold continued development of integrated instrument techniques (e.g., simultaneous or sequential correlative microscopies and/or spectroscopies of the same location), increased instrumental resolution, increased use of multiscale and multimodal organic petrography investigations, and three-dimensional imaging and chemical speciation mapping applications via multiple analytical approaches.
New interpretations of the ages and origins of the Hawkeye Granite Gneiss and Lyon Mountain Granite Gneiss, Adirondack Mountains, NY: Implications for the nature and timing of Mesoproterozoic plutonism, metamorphism, and deformation
The Hawkeye Granite Gneiss and Lyon Mountain Granite Gneiss are widespread Mesoproterozoic plutonic rocks that occur in the amphibolite- to granulite-facies Adirondack Highlands of northern New York, USA. The strongly deformed Hawkeye Granite Gneiss, previously dated by zircon multi-grain thermal ionization mass spectrometry (TIMS) U-Pb analyses at about 1100 Ma, was intruded by the weakly deformed Lyon Mountain Granite Gneiss. Previous sensitive high resolution ion microprobe (SHRIMP) analyses of Lyon Mountain Granite Gneiss zircon rims were considered to record the time of igneous emplacement at about 1.05 Ga, whereas the ages of zircon cores (~1.15 Ga) were interpreted as being inherited from nearby metaigneous country rocks. This interpretation has formed the basis of numerous models for the Mesoproterozoic structural and tectonic evolution of the Adirondacks Highlands. New U-Pb spot analyses (~15-20 µm diameter) by SHRIMP from four samples of Hawkeye Granite Gneiss and eight samples of Lyon Mountain Granite Gneiss challenge the historically accepted ages of the rocks. Using a combination of high-resolution CL imagery of oscillatory zoned cores and weakly zoned to unzoned rims, SHRIMP U-Pb geochronology, SHRIMP trace element geochemistry, and SEM petrography, we conclude that: (1) the Hawkeye Granite Gneiss was emplaced at about 1160 to 1155 Ma; (2) the vast majority of Lyon Mountain Granite Gneiss zircon cores yield ages of 1150 to 1145 Ma and are mainly primary, not inherited; and (3) the Hawkeye Granite Gneiss and Lyon Mountain Granite Gneiss zircon rims (~1080 to 1000 Ma) are metamorphic in origin, not igneous. Thus, both the Hawkeye Granite Gneiss and Lyon Mountain Granite Gneiss are considered herein to be late members of the mangerite-charnockite-granite (MCG) plutonic suite, emplaced during the waning stages of the Shawinigan orogeny. Zircon cores from two small plutons of largely undeformed fayalite granite of the Lyon Mountain Granite Gneiss are about 1142 Ma, providing a minimum age constraint for the termination of the Shawinigan. Zircon rim ages can be deconvoluted into multiple metamorphic events of the Ottawan and Rigolet tectonothermal events. These new interpretations have profound implications for structural, tectonic, and ore deposit models of the Adirondacks Highlands.
Formation of miarolitic-class, segregation-type pegmatites in the Taishanmiao batholith, China: The role of pressure fluctuations and volatile exsolution during pegmatite formation in a closed, isochoric system
The Taishanmiao granitic batholith, located in the Eastern Qinling Orogen in Henan Province, China, contains numerous small (mostly tens of centimeters in maximum dimension) bodies exhibiting textures and mineralogy characteristics of simple quartz and alkali feldspar pegmatites. Analysis of melt inclusions (MI) and fluid inclusions (FI) in pegmatitic quartz, combined with Rhyolite-MELTS modeling of the crystallization of the granite, have been applied to develop a conceptual model of the physical and geochemical processes associated with the formation of the pegmatites. These results allow us to consider the formation of the Taishanmiao pegmatites within the context of varios models that have been proposed for pegmatite formation. Field observations and geochemical data indicate that the pegmatites represent the latest stage in the crystallization of the Taishanmiao granite and occupy ≤4 vol% of the syenogranite phase of the batholith. Results of Rhyolite-MELTS modeling suggest that the pegmatite-forming melts can be produced through continuous fractional crystallization of the Taishanmiao granitic magma, consistent with the designation of the pegmatites as a miarolitic class, segregation-type pegmatites rather than the more common intrusive-type of pegmatite. The mineral assemblage predicted by Rhyolite-MELTS after ~96% of the original granite-forming melt had crystallized consists of ~51 vol% alkali feldspar, 34 vol% quartz, 14 vol% plagioclase, 0.1 vol% biotite, and 1 vol% magnetite, similar to the alkali feldspar + quartz dominated mineralogy of the pegmatites. Moreover, the modeled residual melt composition following crystallization of ~96% of the original melt is similar to the composition of homogenized MI in quartz within the pegmatite. Rhyolite-MELTS predicts that the granite-forming melt remained volatile-undersaturated during crystallization of the batholith and contained ~6.3 wt% H 2 O and ~500 ppm CO 2 after ~96% crystallization when the pegmatites began to develop. The Rhyolite-MELTS prediction that the melt was volatile-undersaturated at the time the pegmatites began to form, but became volatile-saturated during the early stages of pegmatite formation, is consistent with the presence of some inclusion assemblages consisting of only MI, while others contain co-existing MI and FI. The relationship between halogen (F and Cl) and Na abundances in MI is also consistent with the interpretation that the very earliest stages of pegmatite formation occurred in the presence of a volatile-undersaturated melt and that the melt became volatile saturated as crystallization progressed. We propose a closed system, isochoric model for the formation of the pegmatites. Accordingly, the Taishanmiao granite crystallized isobarically at ~3.3 kbar, and the pegmatites began to form at ~734 °C and ~ 3.3 kbar, after ~96% of the original granitic melt had crystallized. During the final stages of crystallization of the granite, small pockets of the remaining residual melt became isolated within the enclosing granite and evolved as constant mass (closed), constant volume (isochoric) systems, similar to the manner in which volatile-rich melt inclusions in igneous phenocrysts evolve during post-entrapment crystallization under isochoric conditions. As a result of the negative volume change associated with crystallization, pressure in the pegmatite initially decreases as crystals form, and this leads to volatile exsolution from the melt phase. The changing PTX conditions produce a pressure-induced “liquidus deficit” that is analogous to liquidus undercooling and results in crystal growth as required to return the system to equilibrium PTX conditions. Owing to the complex closed system, isochoric PVTX evolution of the melt-crystal-volatile system, the pressure does not decrease rapidly or monotonically during pegmatite formation but, rather, gradually fluctuates such that at some stages in the evolution of the pegmatite the pressure is decreasing while at other times the pressure increases as the system cools to maintain mass and volume balance. This behavior, in turn, leads to alternating episodes of precipitation and dissolution that serve to coarsen (ripen) the crystals to produce the pegmatitic texture. The evolution of the pegmatitic melt described here is analogous to that which has been well-documented to occur in volatile-rich MI that undergo closed system, isochoric, post-entrapment crystallization.
Two-event genesis of Butte lode veins: Geologic and geochronologic evidence from ore veins, dikes, and host plutons
The long-standing ore-genesis model for world-class deposits of the Butte mining district, Montana, is of deep pre-Main Stage porphyry Cu-Mo and overlying Main Stage Ag-Zn-Cu-zoned lode veinsformed from discrete hydrothermal systems related to rhyolite dikes. The lode-specific model describes metals zones that formed in the lode veins as hydrothermal processes diminished in intensity (changing temperature and chemical characteristics) outward from the district center. New geologic and multi-method geochronologic studies pro- vide new timing constraints on the lode veins and reevaluation of geologic relations (Lund and others, 2018), leading to a new model for formation of the lode veins and their relations to stockwork Cu-Mo deposits and igneous events.
Stop 3 – The Petersburg “Granite” redefined: Recognition and implications of Silurian to Devonian rocks in central-eastern Virginia
Introduction Although the Petersburg Granite had long been in practical use as a building stone since the 1830s (Watson, 1906; 1907; 1910; Darton, 1911; Steidtmann, 1945), it was first formally defined as a geologic unit by Anna Jonas on the 1928 geologic map of Virginia. Anna Jonas defined this unit as a Precambrian coarse-grained porphyritic biotite granite that was intruded by finer grained granite and cut by pegmatite (Nelson, 1928). This belt of mostly granitic rocks extends from near Ashland, Virginia north of Richmond, to near Stony Creek, south of Petersburg, Virginia (e.g., Virginia Division of Mineral Resources, 1993) and is bounded by the Hylas fault zone to the northwest, the Mesozoic Richmond basin to the west, and the newly recognized Nottoway River fault zone to the southwest (e.g., Carter and others, 2020; 2021). The eastern boundary of this belt is covered by Coastal Plain sediments, but geophysical and deep borehole data suggest an orogen-scale suture separates it from the Neoproterozoic Chesapeake block to the east (Figure 1; Carter and others, 2021).
Photoluminescence imaging of whole zircon grains on a petrographic microscope—An underused aide for geochronologic studies
The refractory nature of zircon to temperature and pressure allows even a single zircon grain to preserve a rich history of magmatic, metamorphic, and hydrothermal processes. Isotopic dating of micro-domains exposed in cross-sections of zircon grains allows us to interrogate this history. Unfortunately, our ability to select the zircon grains in a heavy mineral concentrate that records the most geochronologic information is limited by our inability to predict internal zonation from observations of whole grains. Here we document the use of a petrographic microscope to observe and image the photoluminescence (PL) response of whole zircon grains excited under ultraviolet (UV) light, and the utility of this PL response in selecting grains for geochronology. While zircon fluorescence has long been known, there is limited documentation of its utility for and application to geochronologic studies. Our observations of zircon from an un-metamorphosed igneous rock, two meta-igneous rocks, and a placer deposit show that variations in the PL color are readily observable in real-time, both among grains in a population of zircons and within single grains. Analyses of cross-sections of the same grains demonstrate that the changes in PL correlate with zoning in backscattered electron (BSE) and cathodoluminescence (CL) images as well as with changes in U + Th concentration and spectroscopic proxies for radiation damage. In other words, the whole grain PL provides a low-resolution preview of the U + Th zoning expected in a cross-sectioned grain. We demonstrate the usefulness of this “preview” in identifying and selecting the subset of zircon grains in a heavy mineral separate that has metamorphic rims of sufficient width to date by secondary ionization mass spectrometry (SIMS). The data are also used to place preliminary constraints on the age and U + Th concentrations at which a yellow PL response is observed in natural samples. The PL response of zircon is well-known among spectroscopists, and these simple applications demonstrate several ways in which the response might be more effectively used by geochronologists.
Exhumation of the Coyote Mountains metamorphic core complex (Arizona): Implications for orogenic collapse of the southern North American Cordillera.
A microstructural and thermochronometric analysis of the Coyote Mountains detachment shear zone provides new insight into the collapse of the southern North American Cordillera. The Coyote Mountains is a metamorphic core complex that makes up the northern end of the Baboquivari Mountains in southern Arizona. The Baboquivari Mountains records several episodes of crustal shortening and thickening and regional metamorphism, including the Late Cretaceous‐early Paleogene Laramide orogeny which is locally expressed by the Baboquivari thrust fault. Thrusting and shortening were accompanied by magmatic activity recorded by intrusion of Paleocene muscovite‐biotite‐garnet peraluminous granites such as the ~58 Ma Pan Tak Granite, interpreted as anatectic melts representing the culmination of the Laramide orogeny. Following Laramide crustal shortening, the northern end of the Baboquivari Mountains was exhumed along a top‐to‐the‐north detachment shear zone, which resulted in the formation of the Coyote Mountains metamorphic core complex. Structural and microstructural analysis show that the detachment shear zone evolved under a strong component of noncoaxial (simple shear) deformation, at deformation conditions of ~450 ± 50°C, under a differential stress of ~60 MPa, and a strain rate of 1.5 × 10 −11 to 5.0 × 10 −13 s −1 at depth of ~11–14 km. Detailed 40 Ar/ 39 Ar geochronology of biotite and muscovite, in the context of the deformation conditions determined by quartz microstructures, suggests that the mylonitization associated with the formation of the Coyote Mountains metamorphic core complex started at ~29 Ma (early Oligocene). Apatite fission track ages indicate that the footwall of the Coyote Mountains metamorphic core complex experienced rapid exhumation to the upper crust by ~24 Ma. The fact that mylonitization and rapid extensional exhumation postdates Laramide thickening by ~30 Myr indicates that crustal thickness alone was insufficient to initiate extensional tectonic and required an additional driving force. The timing of mylonitization and rapid exhumation documented here and in other MCCs are consistent with the hypothesis that slab rollback and the effect of a slab window trailing the Mendocino Triple Junction have been critical in driving the development of the MCCs of the southwest.
Geochronologic age constraints on tectonostratigraphic units of the central Virginia Piedmont, USA
New geologic mapping coupled with uranium-lead (U-Pb) zircon geochronology (sensitive high-resolution ion microprobe-reverse geometry [SHRIMP-RG] and laser ablation-inductively coupled plasma-mass spectrometry [LA-ICP-MS]) analyses of 10 samples, provides new constraints on the tectonostratigraphic framework of the central Virginia Piedmont. Detrital zircon analysis confirms that the Silurian-Devonian Quantico Formation is a postorogenic successor basin, with zircons derived primarily from Ordovician Chopawamsic Formation volcanic rocks. Detrital zircons from strata of the Long Island syncline, previously mapped as a separate successor basin, have a peri-Gondwanan component distinct from Laurentian-sourced rocks of the Potomac terrane to the west. Volcanism of the Chopawamsic Formation spanned at least 14 million years during the Ordovician. The Chopawamsic Formation contains sheet-like Late Ordovician-Silurian granodioritic and tonalitic intrusions that were once mapped as Carboniferous. Biotite-muscovite migmatitic paragneiss, which borders the Chopawamsic Formation on its southeast side and also occurs east of the Lakeside fault, preserves evidence of Silurian deformation and metamorphism, with a Carboniferous (Alleghanian) overprint. Limited SHRIMP-RG analysis of detrital zircons from this paragneiss yields a Laurentian (Mesoproterozoic) signature, which suggests that the structurally concordant contact between volcanic rocks of the Chopawamsic Formation and paragneiss is either a pre-Alleghanian fault or an unconformity.
40Ar/39Ar and U-Pb SIMS zircon ages of Ediacaran dikes from the Arabian-Nubian Shield of south Jordan
A spectacular feature of the Arabian-Nubian Shield (ANS) is the abundance of well-exposed and extensive Neoproterozoic dike swarms of multiple generations. These dikes are generally categorized into metamorphosed and unmetamorphosed post-orogenic dike swarms. The unmetamorphosed dikes in the northern ANS can be grouped into an old and young generations. We dated three dikes from the old generation of the unmetamorphosed dikes: a composite dike with latite margins and rhyolite core (607 ± 6 Ma, U-Pb), a biotite rhyolite dike (600 ± 4 Ma, 40Ar/39Ar age of biotite) and an andesite dike (594 ± 3, 40Ar/39Ar age of amphibole). We propose that these dikes representing the old generation were emplaced at different episodes extending approximately between 607 and 590 Ma. Time and composition equivalent plutonic rocks are common in Jordan and the northern ANS. These dikes crosscut the late to post-collisional granitoids and display a subduction-related character as evidenced from the Nb-Ta anomaly, suggesting a transitional magmatic activity from the orogenic to extensional environment. This generation of dikes is absent in the alkali feldspar A-type granite dated at 586 ± 5 Ma in Jordan and equivalent rocks in the northern ANS, which are crosscut only by the dolerite dikes which has an approximate crystallization age of ~579 Ma (40Ar/39Ar whole rock total gas age). Their within-plate character is supported by the absence of the Nb-Ta anomaly and the high field strength elements tectonic discrimination plots. We propose that these dolerite dikes represent the last Neoproterozoic igneous activity in the northern ANS, i.e. the magmatic activity was terminated ~50 m.y. before the estimated age of the Ram Unconformity at ~530 Ma. This age is in agreement with a previously suggested model of mantle lithosphere delamination from below the northern ANS after a significant crust-mantle thickening caused by the East African Orogeny. The thickening triggered exceptionally rapid uplift, followed by erosional unroofing of the ANS rocks, some lateral extension, and post-orogenic magmatic activity. This was followed by thermal relaxation and subsidence and the gradual denudation, erosion, and peneplanation that gradually developed until the approximate age of the unconformity at ~530 Ma.
Geochronology of the Oliverian Plutonic Suite and the Ammonoosuc Volcanics in the Bronson Hill arc: Western New Hampshire, USA
U-Pb zircon geochronology by sensitive high-resolution ion microprobe–reverse geometry (SHRIMP-RG) on 11 plutonic rocks and two volcanic rocks from the Bronson Hill arc in western New Hampshire yielded Early to Late Ordovician ages ranging from 475 to 445 Ma. Ages from Oliverian Plutonic Suite rocks that intrude a largely mafic lower section of the Ammonoosuc Volcanics ranged from 474.8 ± 5.2 to 460.2 ± 3.4 Ma. Metamorphosed felsic volcanic rocks from within the Ammonoosuc Volcanics yielded ages of 460.1 ± 2.4 and 455.0 ± 11 Ma. Younger Oliverian Plutonic Suite rocks that either intrude both the upper and lower Ammonoosuc Volcanics or Partridge Formation ranged in age from 456.1 ± 6.7 Ma to 445.2 ± 6.7 Ma. These new data and previously published results document extended magmatism for >30 m.y. The ages, along with the lack of mappable structural discontinuities between the plutons and their volcanic cover, suggest that the Bronson Hill arc was part of a relatively long-lived composite arc. The Early to Late Ordovician ages presented here overlap with previously determined igneous U-Pb zircon ages in the Shelburne Falls arc to the west, suggesting that the Bronson Hill arc and the Shelburne Falls arc could be part of one, long-lived composite arc system, in agreement with the interpretation that the Iapetus suture (Red Indian Line) lies to the west of the Shelburne Falls–Bronson Hill arc system.
Sampling the volatile-rich transition zone beneath Bermuda
Intraplate magmatic provinces found away from active plate boundaries, provide direct sampling of the Earth’s mantle composition and heterogeneity. Observed chemical heterogeneities in the mantle are commonly attributed to recycling during subduction1-3, which allows for the addition of volatiles and incompatible elements into the mantle. Although many intraplate volcanoes sample deep mantle reservoirs, possibly at the core-mantle boundary4,5, not all intraplate volcanoes are deep rooted6 and reservoirs in other shallower boundary layers likely participate in magma generation. Here we present new evidence that suggests that Bermuda sampled a previously unknown mantle domain, characterized by silica under-saturated melts that have significant enrichments in incompatible elements and volatiles, and a unique, extreme isotopic signature. Bermuda records the most radiogenic 206Pb/204Pb isotopes ever documented in an ocean basin (19.9-21.7), coupled with low 207Pb/204Pb (15.5-15.6) and relatively invariant Sr, Nd, and Hf isotopes, suggesting that this source must be <650 Ma. We interpret the Bermuda source as a new, transient mantle reservoir that resulted from recycling and storage of incompatible elements and volatiles7-10 in the transition zone, aided by the fractionation of Pb by minerals that are only stable in this boundary layer such as K-Hollandite11-12. Recent recycling and storage of material into the transition zone suggests that this reservoir can only be found in the Atlantic Ocean. Our geodynamic models suggest that this layer was sampled by disturbances related to mantle flow. Seismic studies have shown that recycled materials can be stored in the transition zone13. For the first time we show geochemical evidence that this storage is key in the generation of extreme isotopic domains previously thought to be related only to deep recycling.
Syn-collisional exhumation of hot middle crust in the Adirondack Mountains (New York, USA): Implications for extensional orogenesis in the southern Grenville province
Extensional deformation in the lower to middle continental crust is increasingly recognized and shown to have significant impact on crustal architecture, magma emplacement, fluid flow, and ore deposits. Application of the concept of extensional strain to ancient orogenic systems, like the Grenville province of eastern North America, has helped decipher the structural evolution of these regions. The Marcy massif is a ~3000 km2 Mesoproterozoic anorthosite batholith in the Adirondack Mountains (New York, USA) of the southern Grenville province. Bedrock geology mapping at 1:24,000 scale paired with characterization of bedrock exposed by recent landslides provides a glimpse into the structural architecture of the massif and its margin. New data demonstrate granulite- to amphibolite-facies deformational fabrics parallel the margin of the batholith, and that the Marcy massif is draped by a southeast-directed detachment zone. Within the massif, strain is localized into mutually offsetting conjugate shear zones with antithetic kinematic indicators. These relationships indicate that strain was coaxial within the Marcy massif, and that subsimple shear components of strain were partitioned along its margin. In situ U–Th–total Pb monazite analysis shows that deformation around and over the Marcy massif occurred from 1070 to 1060 Ma during granulite-facies metamorphism, and monazite from all samples record evidence for fluid-mediated dissolution reprecipitation from 1050 to 980 Ma. We interpret that rocks cooled isobarically after accretionary orogenesis and emplacement of the anorthosite- mangerite- charnockitegranite plutonic suite at ca. 1160–1140 Ma. Gravitational collapse during the Ottawan phase of the Grenville orogeny initiated along a southeast-directed detachment zone (Marcy massif detachment zone), which accommodated intrusion of the Lyon Mountain Granite Gneiss, and facilitated substantial fluid flow that catalyzed the formation of major ore deposits in the Adirondack Highlands.
Geology of the Mineral and Lake Anna West Quadrangles, Virginia
This map product is a cooperator series publication and, as such, does not have a specific abstract. Geologic mapping for this map product was completed between 2014 and 2017, with most of the field work occurring between January 2016 and May 2017. Numerous foot traverses were completed along creeks and roads throughout the field area; the shore of Lake Anna was accessed by kayak to provide additional data. Distributions of soil units were considered when assigning bedrock type in areas where outcrop was lacking and helped to distinguish fluvial terrace deposits. Hill-shade raster images created from LiDAR datasets and geophysical data sets proved useful in the field to trace bedrock and surficial units. GPS location control and field data were collected and recorded in digital databases using a variety of geologic mapping applications for an iPad 3rd Gen Model A1403 and Motion C5v tablet using Fieldmove 2013.1. Structural measurements were also plotted on field maps. Data collected included lithology and the orientation of foliations, folds, lineations, joints, and faults. Representative rock samples of significant formations were thin-sectioned for petrographic analysis; a few samples from these and surrounding quadrangles were analyzed for zircon U-Pb geochronology and geochemistry.