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Geology topics

Richard L. Reynolds

Publications and source records attributed to Richard L. Reynolds.

At least 91 records · Page 5Linked to original sources

Effects of El Nino on streamflow, lake level, and landslide potential

One of the most important sources of year-to-year climate variation in the Southwest is the El Niño phenomenon of the tropical Pacific Ocean. El Niño is a natural but largely unpredictable condition that results from complex interplay among clouds and storms, regional winds, oceanic temperatures, and ocean currents along the equatorial Pacific. Under "normal" conditions, the tropical trade winds blow from east to west, Figure 1. Schematic diagram of normal and El Niño conditions in the Pacific Ocean. From NOAA El Niño website. ponding up warm water in the western Pacific. In the eastern Pacific, the trade winds pull up cold, deep, nutrient-rich waters along the equator from the Ecuadorian coast to the central Pacific. The warmth of the western Pacific results in a particularly vigorous hydrologic cycle there with towering cumulus clouds and tropical storms that "radiate" atmospheric waves and disturbances across vast regions of the globe. Heat and moisture lofted into the upper atmosphere by the clouds and storms are distributed by high-altitude winds across vast regions of the globe. During an El Niño, this situation is disrupted and the trade winds weaken, thus reducing the upwelling of cool waters in the eastern Pacific and allowing the pool of warm water in the west to drift eastward toward South America. As the central and eastern Pacific warms, atmospheric pressure gradients along the equator weaken, and the trade winds diminish even more. These changes in sea-level pressure of the atmosphere are characteristic of the strongest El Niño and were identified as the "Southern Oscillation" of the global atmosphere by Sir Gilbert Walker in the early decades of this century. A chicken-and-egg relation exists between the changes in ocean temperatures and changes in winds (and atmospheric pressure gradients); the two sets of changes reinforce and drive each other but neither is clearly or universally "the" initiator of El Niño. Ocean temperatures and surface winds interact to form the complex process, El Niño-Southern Oscillation (ENSO). The interactions can be set off by subtle changes in one or the other, by buffeting from other parts of the tropics, or from regions beyond the tropics. Such a complex interplay and its uncertain (and variable) origins are the primary limitations on our ability to predict El Niño. As the waters of the central and eastern Pacific warm, the powerful tropical Pacific storms begin to form farther east than usual (Fig. 1). As the distribution of storms spreads east along the equator, their influence on global weather systems also changes. Most notably, for our purposes, the jet stream over the North Pacific Ocean is invigorated and pulled farther south than normal, where it collects moisture and storms and carries them to the southwestern United States and northern Mexico. During an El Niño, the trade winds are too weak to cause upwelling of nutrient-rich waters off the coasts of Ecuador and Peru. Generations of South American fisherman thus have recognized these conditions by the disappearance of their standard catch, commonly during December and January, every three to seven years. Because of the near coincidence in timing between these conditions and Christmas, the fishing communities have called the phenomenon "El Niño", for the Christ child. The geologic record suggests that El Niño conditions have been a part of earth's climate for at least several thousand years. An El Niño event usually lasts for several seasons, and, along with its other effects, represents an interruption of the "normal" seasonal cycle of the tropical climate. After a few seasons, and usually during spring time (in the Northern Hemisphere), the seasonal cycle reasserts itself and the tropical ocean cools back to the normal east-to-west sea-surface temperature gradients. Sometimes the warm El Niño events give way to unusually cold sea-surface temperatures and unusually strong trade winds, a condition now called La Niña. On other occasions, La Niñas may begin on their own, without an immediately preceding El Niño. The effects of the El Niño and La Niña on global climate are, in part, mirror images of each other. For example, drought is a common occurrence in the southwestern United States during La Niña, in contrast to the wet years associated with El Niño.

Arizona, California, Nevada, New Mexico, Oregon, U↗

Sediment magnetic and geochemical data from Quaternary lacustine sediment in two cores from Tule Lake, Siskiyou County, California

Sediment magnetic and geochemical results have been obtained from the top 60 meters of lacustrine sediments recovered in two cores from Tule Lake in northern California. The sediment magnetic and geochemical data, presented here in tabular form, complement studies of diatoms and pollen in the cores that are the bases for published paleoclimatic interpretations. This report also documents the methods used to obtain the magnetic properties and geochemical data.

Open-File Report↗

Sediment magnetic, paleomagnetic, and geochemical data from Quaternary lacustrine sediment in a core from Grass Lake, Siskiyou County, California

Sediment magnetic and geochemical results have been obtained from the top 60 meters of lacustrine sediments recovered in two cores from Tule Lake in northern California. The sediment magnetic and geochemical data, presented here in tabular form, complement studies of diatoms and pollen in the cores that are the bases for published paleoclimatic interpretations. This report also documents the methods used to obtain the magnetic properties and geochemical data.

Open-File Report↗

Lake-level history of Lake Michigan for the past 12,000 years: the record from deep lacustrine sediments

Collection and analysis of an extensive set of seismic-reflection profiles and cores from southern Lake Michigan have provided new data that document the history of the lake basin for the past 12,000 years. Analyses of the seismic data, together with radiocarbon dating, magnetic, sedimentologic, isotopic, and paleontologic studies of core samples, have allowed us to reconstruct lake-level changes during this recent part of the lake's history. The post-glacial history of lake-level changes in the Lake Michigan basin begins about 11.2 ka with the fall from the high Calumet level, caused by the retreat of the Two Rivers glacier, which had blocked the northern outlet of the lake. This lake-level fall was temporarily reversed by a major influx of water from glacial Lake Agassiz (about 10.6 ka), during which deposition of the distinctive gray Wilmette Bed of the Lake Michigan Formation interrupted deposition of red glaciolacustrine sediment. Lake level then continued to fall, culminating in the opening of the North Bay outlet at about 10.3 ka. During the resulting Chippewa low phase, lake level was about 80 m lower than it is today in the southern basin of Lake Michigan. The rise of the early Holocene lake level, controlled primarily by isostatic rebound of the North Bay outlet, resulted in a prominent, planar, transgressive unconformity that eroded most of the shoreline features below present lake level. Superimposed on this overall rise in lake level, a second influx of water from Lake Agassiz temporarily raised lake levels an unknown amount about 9.1 ka. At about 7 ka, lake level may have fallen below the level of the outlet because of sharply drier climate. Sometime between 6 and 5 ka, the character of the lake changed dramatically, probably due mostly to climatic causes, becoming highly undersaturated with respect to calcium carbonate and returning primary control of lake level to the isostatically rising North Bay outlet. Post-Nipissing (about 5 ka) lake level has fallen about 6 m due to erosion of the Port Huron outlet, a trend around which occurred relatively small (± ∼2 m), short-term fluctuations controlled mainly by climatic changes. These cyclic fluctuations are reflected in the sed-imentological and sediment-magnetic properties of the sediments.

Indiana, Illinois, Michigan, Wisconsin↗

Lake Michigan's late Quaternary limnological and climate history from ostracode, oxygen isotope, and magnetic susceptibility

The limnology of Lake Michigan has changed dramatically since the late Pleistocene in response to the expansion and contraction of continental glaciers, to differential isostatic rebound, and to climate change. The lake sediment's stratigraphic trends, magnetic susceptibility, δ 18 O, and ostracode species abundance ratios provide criteria to identify the lake's response to glacial ice and to differential isostatic rebound. The latter phenomena dominate the lake's late Pleistocene and early Holocene history. The lake's hydrological budget provides the primary linkage between the lake and climate, particularly effective moisture. Dissolved salts were stored in the lake's water column when the lake's output shifted toward evaporation, but were flushed when output shifted toward outflow. The lake's salt storage history may be interpreted from some ostracode, δ 18 O, and magnetic susceptibility records found in sediment cores. Climate change influenced the entire lake's limnological history, but became the primary limnological driver from about the middle-Holocene to the present. The complex limnological history of Lake Michigan resulted in substantial changes in the ostracode species assemblages; from about 12,000 ka to about 5,500 ka, five ostracode intervals can be identified. These ostracode intervals provide a within-lake biostratigraphy and a stratigraphic reference for reconstruction of the paleoenvironmental dynamics of the lake.

Indiana, Illinois, Michigan, Wisconsin↗

Sulfidization and magnetization above hydrocarbon reservoirs

Post-depositional iron-sulfide (Fe-S) minerals that are related to hydrocarbon seepage have changed the original magnetizations at Cement oil field (Anadarko basin, Oklahoma), at Simpson oil field (North Slope basin, Alaska), and above deep Cretaceous oil and gas reservoirs, south Texas coastal plain. At Cement, ferrimagnetic pyrrhotite (Fe 7 S 8 ) formed with pyrite and marcasite in Permian red beds. The Fe-S minerals contain sulfur from two sources: (1) abiogenic sulfide, which has positive δ 34 S values, derived from thermochemical reduction of sulfate in deep reservoirs; and (2) biogenic sulfide, which has negative δ 34 S values, produced by reactions mediated by sulfate-reducing bacteria fed by leaking hydrocarbons. At Simpson, ferrimagnetic greigite (Fe 3 S 4 ) dominates magnetizations in nonmarine Upper Cretaceous clastic beds that contain epigenetic sulfide (δ 34 S > +20 per mil) and seeping biodegraded oil. In this setting, the authigenic magnetic sulfide mineral apparently incorporated sulfide produced by bacterial sulfate reduction under limited sulfate conditions. An inferred hydrocarbon food source for the sulfate-reducing bacteria links the hydrocarbon seepage to the greigite. The greigite is perhaps forming today. In middle Tertiary sandstones of southeast Texas, pyrite and marcasite formed when abiogenic H 2 S (enriched in 34 S) migrated upward from deep reservoirs, or when H 2 S (depleted in 34 S) was produced at shallow depths by bacteria that used organic material dissolved in migrating water from depth. The pyrite and marcasite replaced detrital magnetic iron-titanium oxide minerals. The degree of such replacement appears to increase toward faults that connect deep petroleum reservoirs to shallow sandstone. Our results show that abiologic and biologic mechanisms can generate different magnetic sulfide minerals in some sulfidic zones of hydrocarbon seepage. More commonly the magnetizations in such zones would be diminished as a result of the replacement of detrital magnetic minerals by the common nonmagnetic sulfide minerals, or would remain unchanged if such detrital minerals were originally absent.

Book chapter↗

Relations among hydrocarbon reservoirs, epigenetic sulfidization, and rock magnetization; Examples from the South Texas coastal plain

This paper focuses on the association between concentrations of iron disulfide (FeS 2 ) minerals in the shallow subsurface and underlying hydrocarbon accumulations. Such FeS 2 concentrations are the result of migration of either H 2 S or organic constituents from the underlying hydrocarbons. The H 2 S from reservoirs is produced inorganically from sulfate in the reservoir rocks at high temperature (>90 degrees C) and migrates to shallower beds to react inorganically with iron to form FeS 2 . Organic constituents from reservoirs, in contrast, provide nourishment for sulfate reducing bacteria in shallow relatively cool (<90 degrees C) beds. Sandstone in the Ray Point uranium district in Live Oak County, Texas contains abundant FeS 2 which formed both from deep-seated H 2 S and from H 2 S produced in the shallow subsurface by bacteria that utilized organic materials from depth. Deep petroleum reservoirs were physically connected to near-surface (<100 m) beds containing epigenetic FeS 2 by the Oakville fault. Epigenetic iron sulfide formation occurred in at least four episodes over at least five million years. Evidence from the Ray Point district and elsewhere in Texas illustrates that sulfidization reactions have destroyed magnetic iron-titanium oxide minerals in the vicinity of major growth faults, resulting in a systematic decrease in magnetic susceptibility and magnitude of remanent magnetization in the vicinity of such faults. Growth faults which tap hydrocarbon deposits may be detectable using aeromagnetic methods.

Texas↗

Iron sulfide minerals at Cement oil field, Oklahoma: Implications for magnetic detection of oil fields

Aeromagnetic anomalies at Cement oil field (Anadarko basin, Oklahoma) have been attributed to authigenic magnetite. The following characteristics of the magnetite, however, indicate that it is contamination introduced by drilling: (1) occurrence as sharp angular blades and as spheres, commonly with metallographic textures typical of industrial alloys and with associated steel and wustite (FeO); (2) presence only in well cuttings and absence from core and quarry samples; and (3) lack of association with detrital framework grains or with authigenic carbonate and sulfide minerals. Ferrimagnetic pyrrhotite occurs in well cuttings, cores, and quarry samples at Cement and is a possible natural source of the magnetic anomalies. Pyrrhotite, which is intergrown with more abundant FeS 2 minerals, formed as a result of hydrocarbon seepage. Pyrrhotite is confined to beds above oil and gas reservoirs. These beds, which lack detrital organic matter, contain higher mineral sulfide and lower mineral sulfate sulfur (1.7 and 0.1 wt %, respectively) than do correlative beds off the field (0.2 and 1.1 wt %, respectively). In the field, isotopic values of sulfide S show a systematic decrease upward through the Permian section from positive values (maximum, +12 per mil at ∼610-760 m depth) to negative values (-1 to -11 per mil between 32 and 230 m; -26 to -30 per mil at the surface). Geochemical results, together with time-temperature data derived from burial curves, limit the major sources of the sulfide in the Fe-S minerals to two possibilities. Isotopically heavy sulfide was generated either inorganically at temperatures >∼90 °C in beds beneath Permian beds, or by bacterial sulfate reduction at temperatures <∼60 °C in Permian strata. If the latter, microbial sulfate reduction occurred under sulfate-limited conditions. The isotopically light sulfide occurring in minerals near the present surface is attributed to bacterial reduction of sulfate. Sulfate-reducing bacteria derived metabolic energy from leaking hydrocarbons and associated organic compounds.

Oklahoma↗

Source of anomalous magnetization in an area of hydrocarbon potential: Petrologic evidence from the Jurassic Preuss Sandstone, Wyoming-Idaho thrust belt

The Jurassic Preuss Sandstone, which crops out in the central part of the Wyoming-Idaho thrust belt on trend with a hydrocarbon-producing region to the south, has been previously identified as the source of anomalous magnetization in the area. Elsewhere, anomalous magnetization in sedimentary rocks near hydrocarbon accumulations has been attributed to hydrocarbon-engendered magnetic minerals, but magnetization of the Preuss is controlled by detrital magnetite. Evidence of a detrital origin for magnetite includes (1) concentration of magnetite grains along laminations containing other heavy minerals, (2) the presence of exsolved ilmenite, hematite, and spinel in the magnetite grains, and (3) titanium contents typical of igneous-derived magnetite. That detrital magnetite is responsible for the anomalous magnetization in the Preuss is further indicated by the systematic eastward decrease in magnetite abundance corresponding to a similar eastward decrease in magnetic susceptibility and remanent magnetization of the unit. Petrologic and vitrinite reflectance studies indicate a complex low-temperature (<150°C or 302°F) diagenetic history for the Preuss. Nevertheless, preservation of detrital magnetite, the presence of diagenetically early ferric oxide minerals, and the absence of sulfide minerals all indicate that the Preuss has not experienced sulfidic-reducing conditions common in areas of hydrocarbon seepage. The marine carbon isotopic composition of calcite that cements most Preuss sandstones (^dgr13C values ranging from -2.47 to 1.48^pmil is evidence that carbonate diagenesis also was not influenced by hydrocarbons. The results of this multidisciplinary study of the Preuss underscore the importance of similar studies when evaluating the sources of aeromagnetic anomalies in areas of hydrocarbon potential.

Idaho, Utah, Wyoming↗

Sulfide mineralization and magnetization, Cement oil field, Oklahoma

Geochemical, petrographic, and rock-magnetic studies were undertaken to investigate possible sources for reported positive aeromagnetic anomalies over the Cement oil field, Oklahoma. Ferrimagnetic pyrrhotite (monoclinic, Fe 7 S 8 ), intergrown with more-abundant, nonmagnetic pyrite (FeS 2 ), is present in well-cutting, core, and quarry samples at Cement, and it is the only identified source of possible enhanced magnetization in rocks over the field. Magnetite, found only in well cuttings from Cement, is contamination from drilling. Magnetite was considered previously by others to be the source of magnetic anomalies at Cement.

Oklahoma↗

Origin of the Mariano Lake uranium deposit, McKinley County, New Mexico

The Mariano Lake uranium deposit, hosted by the Brushy Basin Member of the Jurassic Morrison Formation, occurs in the Smith Lake district of the Grants uranium region, New Mexico. The orebody, contains abundant amorphous organic material, which suggests that it represents a primary-type deposit; however, the orebody is close to a regional reduction-oxidation interface, which suggests that uranium was secondarily redistributed by oxidative processes. Uranium contents correlate positively with organic carbon contents. Petrographic evidence points to uranium residence in amorphous organic material that was post- depositionally introduced in the diagenetic history of the host sandstone. Uranium mineralization was preceded by precipitation of pyrite (δ 34 S values of — 11.0 to — 38.2 per mil), mixed-layer smectite-illite clays, and quartz and potassium feldspar overgrowths; and also partial dissolution of some detrital feldspars. Alterations associated with uranium mineralization include precipitation of the organic material, microcrys- talline quartz, and pyrite and marcasite (δ 34 S values of -29.4 to -41.6 per mil), and the destruction of detrital Fe-Ti oxide grains. Following mineralization, calcite, dolomite, barite, and kaolinite were precipitated, and some iron disulfides were replaced by ferric oxides. Geochemical data and petrographic observations both indicate that the Mariano Lake orebody is a primary-type deposit. Oxidative processes have not noticeably redistributed uranium in the immediate vicinity of the deposit, nor have they greatly modified geochemical characteristics in the ore. Impedance of ground-water flow by local folds and the lower porosity characteristics of ore zones may have helped to preserve the deposit.

New Mexico↗

Iron-titanium oxide minerals and magnetic susceptibility anomalies in the Mariano Lake-Lake Valley cores-Constraints on conditions of uranium mineralization in the Morrison Formation, San Juan Basin, New Mexico

Petrographic study of the Mariano Lake-Lake Valley cores reveals three distinct zones of postdepositional alteration of detrital Fe-Ti (iron-titanium) oxide minerals in the Westwater Canyon Member of the Upper Jurassic Morrison Formation. In the uranium-bearing and adjacent portions of the Westwater Canyon, these detrital Fe-Ti oxide minerals have been thoroughly altered by leaching of iron. Stratigraphically lower parts of the Westwater Canyon and the underlying Recapture Member are characterized by preservation of Fe-Ti oxide grains, primarily magnetite and ilmenite, and of hematite, and by an absence of uranium concentrations. Partly destroyed Fe-Ti oxide minerals occupy an interval between the zones of destruction and preservation. Alteration patterns of the Fe-Ti oxide minerals are reflected in bore-hole magnetic susceptibility logs. Magnetic susceptibility response in the upper parts of the Westwater Canyon Member is flat and uniformly < 500 /xSI units, but at greater depths it fluctuates sharply, from <1,000 to nearly 8,000 μSI units. The boundary between uniformly low and high magnetic susceptibility response corresponds closely to the interval that divides the zone of completely altered from the zone of preserved detrital Fe-Ti oxide minerals. The alteration pattern suggests that solutions responsible for destruction of the Fe-Ti oxide minerals originated in the overlying Brushy Basin Member of the Morrison Formation. Previous studies indicate that these solutions were rich in soluble organic matter and perhaps in uranium. Uranium precipitation may have been controlled by a vertically fluctuating interface between organic-rich solutions and geochemically different fluids in which the detrital Fe-Ti oxide minerals were preserved.

New Mexico↗

Paleomagnetic and petrologic evidence bearing on the age and origin of uranium deposits in the Permian Cutler Formation, Lisbon Valley, Utah

An approximate age for uranium deposits in red beds of the Permian Cutler Formation, Lisbon Valley salt anticline, Utah, was obtained using paleomagnetic techniques. Progressive thermal demagnetization of samples of mineralized sandstone isolates stable magnetization components having high (≳400 °C) unblocking temperatures that define a tilt-corrected mean direction of D = 358.1°, I = 65.5°, α 95 = 3.3°. This direction is close to expected Late Cretaceous to middle Tertiary mean directions at Lisbon Valley. In contrast, thermal cleaning of samples of unmineralized sandstone isolates tilt-corrected southeasterly, shallow mean directions (D = 140.5°, I = −9.5°, α 95 = 8.6°, and D = 155.9°, I = −4.4°, α 95 = 10.9°, for two localities in the Lisbon Valley area). These results are closely similar to results from the Cutler Formation elsewhere on the Colorado Plateau and from other Lower Permian strata in North America. In unmineralized sandstone, the stable remanent magnetization is carried predominantly by martite of postdepositional or detrital origin, whereas in mineralized sandstone, the stable magnetization is carried largely by authigenic specular hematite as uranium- and vanadium-bearing clusters in interstitial areas, and it thus reflects the time of mineralization. Partial dissolution of martite grains and grain-coating ferric oxide pigment prior to formation of abundant interstitial specular hematite has minimized or eliminated the influence of late Paleozoic magnetic components in mineralized sandstone. These results, combined with information on the structural development of the Lisbon Valley area and on nearby uranium deposits in the Triassic Chinle Formation, suggest that the growth of the Lisbon Valley anticline during Late Cretaceous to early or middle Tertiary time promoted oxidative destruction of Chinle orebodies and led to a redistribution of uranium and iron from the Chinle into the Cutler. Acidic solutions generated during destruction of sulfide minerals in Chinle orebodies may account for the simultaneous transport of significant quantities of iron and uranium and for the partial dissolution of martite in the Cutler host beds. Neutralization of these solutions by reaction with host-rock constituents (especially calcite) caused precipitation of amorphous ferric oxide, which incorporated uranium by adsorption and which aged to form specular hematite.

Utah↗

Suitability of nonwelded pyroclastic-flow deposits for studies of magnetic secular variation: A test based on deposits emplaced at Mount St. Helens, Washington, in 1980

Paleomagnetic directions obtained from nonwelded pyroclastic-flow deposits that were emplaced at Mount St. Helens, Washington, in 1980 have a precision and accuracy similar to data obtainable from lava flows. It is concluded that nonwelded pyroclastic-flow deposits, like lava flows, are suitable for studies of magnetic secular variation. Although clast rotations apparently caused an “inclination error” in the paleomagnetic directions, the error is a few degrees at most.

Washington↗

Geochemical characteristics of the Church Rock 1 and 1 East uranium deposits, Grants uranium region, New Mexico

In the Church Rock 1 and 1 East mines, Grants uranium region (GUR), New Mexico, uranium orebodies occur within three sandstone units in the upper part of the Westwater Canyon Member of the late Jurassic Morrison Formation. Geochemical analyses reveal that organic carbon contents in ore samples from all three sand units are uniformly low (most are less than 0.01 percent). Vanadium (ranging from 0.0002 to 0.19 percent) and sulfur (ranging from <0.01 to 0.74 percent) typically show positive correlations with uranium; however, vanadium contents rarely exceed those of uranium in ore samples. Although no systematic relationship of either selenium or molybdenum to uranium is evident, some ore samples contain anomalously high concentrations of either of these elements. Geochemically, the ore deposits of the Church Rock area contrast greatly with primary (tabular) uranium orebodies in the GUR which contain abundant organic carbon and greater amounts of vanadium and sulfur. These differences and radiometric age determinations strongly suggest that the Church Rock ores formed as a result of the redistribution of uranium from preexisting uranium deposits within the last 1 m.y. However, the Church Rock deposits differ geochemically from redistributed orebodies in the Westwater Canyon Member elsewhere in the GUR. Specifically, redistributed orebodies in the Ambrosia Lake district, which are comparable in contents of uranium and organic carbon with the Church Rock deposits, are characterized by vanadium contents typically higher than those of uranium. Similarly, sulfur contents in the redistributed deposits of the Ambrosia Lake district are greater than those found in the Church Rock ores. In addition, anomalously high concentrations of molybdenum have rarely been found in other redistributed orebodies of the GUR.

Open-File Report↗

Biogenic and nonbiogenic ore-forming processes in the south Texas uranium district; evidence from the Panna Maria deposit

Geochemical and petrographic studies of core samples from the Panna Maria uranium deposit, a roll-type orebody in the Eocene Jackson Group in Karnes County, Texas, yield important information on the origin of the deposit. Organic carbon content averages about 0.42 weight percent in reduced rock and correlates postively with sulfur content. Pyrite is the dominant iron disulfide (FeS 2 ) mineral in most of the ore zone and throughout a surrounding zone of reduced barren ground, and it is commonly associated with organic debris. Marcasite is sparse except in ore adjacent to the altered tongue in one core and locally in mineralized lignite. Sulfur isotopic compositions (delta 34 S) of FeS 2 minerals range broadly from -1 to -34 per mil; the lightest delta 34 S values (less than -20 per mil) were measured in samples from mineralized lignite and from the nose of the ore roll. Petrographic and geochemical characteristics of the Panna Maria deposit contrast greatly with those of three other south Texas roll-type uranium deposits (the Benavides, Felder, and Lamprecht deposits), which are devoid of organic carbon and which contain more sulfide than does the Panna Maria. These three deposits are characterized by abundant isotopically light ore-stage marcasite and by isotopically heavy preore (in the Benavides) or postore (in the Felder and Lamprecht) pyrite. We have concluded previously that sulfide-bearing fault-leaked solutions from underlying hydrocarbon accumulations were important in the formation of the Benavides, Felder, and Lamprecht deposits. Although the Panna Maria deposit shows an apparent alignment along a fault zone, and although underlying formations in the Karnes County area contain sour gas (delta 34 S [asymp] + 14 per mil) and produce oil, the deposit lacks characteristics indicating that its formation or preservation involved extrinsically derived reductants such as fault-leaked aqueous sulfide. Mineralization of the Panna Maria, rather, appears to have been controlled by intrinsically derived reductants related either directly or indirectly to the presence of organic matter.

Texas↗