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Leslie F. Ruppert

Publications and source records attributed to Leslie F. Ruppert.

At least 37 records · Page 2Linked to original sources

Leaching of trace elements from Pittsburgh coal mill rejects compared with coal combustion products from a coal-fired power plant in Ohio, USA

We investigated the leachability of elements from mill rejects from the high-sulfur, bituminous Upper Pennsylvanian Pittsburgh coal, using the synthetic groundwater leaching procedure (SGLP), long-term leaching (LTL), and the U.S. Environmental Protection Agency's (EPA's) toxicity characteristic leaching procedure (TCLP), and compared their leaching behavior with that of three coal combustion products (CCPs)—bottom ash, economizer fly ash , and fly ash—from the same coal. None of the environmentally hazardous Resource Conservation and Recovery Act of 1976 (RCRA) metals analyzed in the leachates from the mill rejects or the CCPs exceeded U.S. EPA toxicity characteristics (As, Ba, Cd, Cr, Hg, Pb, and Se). Most trace elements leached the least from mill rejects and bottom ash and leached the most from fly ash. The elements Ca, Co, Mg, Mn, and Sr, however, were more concentrated in mill reject leachates than CCP leachates. Most trace elements increased in concentration with increasing SGLP and LTL leaching duration, but As and V decreased in concentration with time in mill reject leachates, suggesting sorption or precipitation of these elements was occurring.

Ohio↗

Hydrogeochemistry and coal-associated bacterial populations from a methanogenic coal bed

Biogenic coalbed methane (CBM), a microbially-generated source of natural gas trapped within coal beds, is an important energy resource in many countries. Specific bacterial populations and enzymes involved in coal degradation, the potential rate-limiting step of CBM formation, are relatively unknown. The U.S. Geological Survey (USGS) has established a field site, (Birney test site), in an undeveloped area of the Powder River Basin (PRB), with four wells completed in the Flowers-Goodale coal bed, one in the overlying sandstone formation, and four in overlying and underlying coal beds (Knoblach, Nance, and Terret). The nine wells were positioned to characterize the hydraulic conductivity of the Flowers-Goodale coal bed and were selectively cored to investigate the hydrogeochemistry and microbiology associated with CBM production at the Birney test site. Aquifer-test results indicated the Flowers-Goodale coal bed, in a zone from about 112 to 120 m below land surface at the test site, had very low hydraulic conductivity (0.005 m/d) compared to other PRB coal beds examined. Consistent with microbial methanogenesis, groundwater in the coal bed and overlying sandstone contain dissolved methane (46 mg/L average) with low δ 13 C values (−67‰ average), high alkalinity values (22 meq/kg average), relatively positive δ 13 C-DIC values (4‰ average), and no detectable higher chain hydrocarbons, NO 3 − , or SO 4 2− . Bioassay methane production was greatest at the upper interface of the Flowers-Goodale coal bed near the overlying sandstone. Pyrotag analysis identified Aeribacillus as a dominant in situ bacterial community member in the coal near the sandstone and statistical analysis indicated Actinobacteria predominated coal core samples compared to claystone or sandstone cores. These bacteria, which previously have been correlated with hydrocarbon-containing environments such as oil reservoirs, have demonstrated the ability to produce biosurfactants to break down hydrocarbons. Identifying microorganisms involved in coal degradation and the hydrogeochemical conditions that promote their activity is crucial to understanding and improving in situ CBM production.

Montana, Wyoming↗

Notes on the origin of copromacrinite based on nitrogen functionalities and δ13C and δ15N determined on samples from the Peach Orchard coal bed, southern Magoffin County, Kentucky

This paper represents the first attempt to show, by means other than just petrographic ones, that one type of macrinite, herein designated copromacrinite, may result from macrofauna feces. For that purpose a combination of coal petrography, X-ray photoelectron spectroscopy, and elemental-analysis continuous-flow isotope ratio mass spectrometry methods were used to determine nitrogen functionalities and δ 13 C and δ 15 N compositions in 1) vitrinite-rich, 2) fusinite + semifusinite-rich, and 3) macrinite-rich (with a possible coprolitic origin) samples of the high volatile A bituminous Peach Orchard coal (Bolsovian; Middle Pennsylvanian) from Magoffin County, Kentucky. There were no significant differences between pyridinic-N and quaternary-N abundance in the three samples, however, pyrrolic-N was higher (~ 54%) in the macrinite-rich sample than in the other two samples (~ 38%). The data suggest that pyridinic-N and quaternary-N are independent of maceral group composition and that pyrrolic-N is dependent on maceral composition (fusinite + semifusinite versus macrinite). δ 13 C values obtained for bulk and demineralized coal of the vitrinite- and fusinite + semifusinite-rich samples are similar with δ 13 C values of − 24.80 ± 0.01‰ VPDB and − 24.61 ± 0.09‰ VPDB for bulk samples and − 24.81 ± 0.07‰ VPDB and − 24.52 ± 0.04‰ VPDB for demineralized samples. These values are within the expected range for vitrinite-rich samples and the slightly higher δ 13 C value of the fusinite + semifusinite-rich sample is expected as δ 13 C values for inertinite are higher than for vitrinite. However, there was a significant shift to a lower δ 13 C value (− 26.80 ± 0.01‰ VPDB for the bulk sample value) for the macrinite-rich sample. Because the samples are basically isorank, and δ 13 C (and δ 15 N) shifts do not occur during maturation until anthracite rank, the difference may be related to the presence or composition of the macrinite within the sample which lacks heat-effect indicators, such as devolatilization vacuoles and distorted pores. δ 15 N values are also similar for bulk and demineralized coal of the vitrinite- and fusinite + semifusinite-rich samples, and the bulk values were heavier in this samples (3.07 ± 0.03‰ Air and 2.92 ± 0.10‰ Air, respectively), and much lighter (− 2.83 ± 0.09‰ Air) for the macrinite-rich sample. The study of Peach Orchard coal samples using reflected-light microscopy, isotopic composition, and nitrogen-forms analyses revealed that the macrinite-rich sample contains macrinite with coprolitic features (e.g. oxidation rind, mix of undigested palynomorphs, frequent and randomly located funginite, agglutination pulp of semifusinite reflectance, internal lack of bedding fabric, and suggestion of structures resulting from intestines and stomach walls), more pyrrolic-N (~ 16%), and lower δ 13 C (~ 2‰ VPDB) and δ 15 N (~ 4‰ Air) values than the vitrinite and semifusinite + fusinite rich samples. These findings suggest that the maceral macrinite has multiple origins based on petrography and measurable chemical differences between the macrinite, vitrinite, and semifusinite + fusinite fractions within the coal. Assuming that copromacrinite observed is an excretion then the anomalies observed may result from the symbiotic relations between the macrofauna (e.g. cockroaches) and microbiota during the digestive processes, and the nitrogen balance mechanisms inside macrofauna body.

Kentucky↗

Carbon and oxygen isotopic composition of coal and carbon dioxide derived from laboratory coal combustion: A preliminary study

The concentration of carbon dioxide (CO 2 ) in the atmosphere has dramatically increased from the start of the industrial revolution in the mid-1700s to present levels exceeding 400 ppm. Carbon dioxide derived from fossil fuel combustion is a greenhouse gas and a major contributor to on-going climate change. Carbon and oxygen stable isotope geochemistry is a useful tool to help model and predict the contributions of anthropogenic sources of CO 2 in the global carbon cycle. Surprisingly few studies have addressed the carbon and oxygen isotopic composition of CO 2 derived from coal combustion. The goal of this study is to document the relationships between the carbon and oxygen isotope signatures of coal and signatures of the CO 2 produced from laboratory coal combustion in atmospheric conditions. Six coal samples were selected that represent various geologic ages (Carboniferous to Tertiary) and coal ranks (lignite to bituminous). Duplicate splits of the six coal samples were ignited and partially combusted in the laboratory at atmospheric conditions. The resulting coal-combustion gases were collected and the molecular composition of the collected gases and isotopic analyses of δ 13 C of CO 2 , δ 13 C of CH 4 , and δ 18 O of CO 2 were analysed by a commercial laboratory. Splits (~ 1 g) of the un-combusted dried ground coal samples were analyzed for δ 13 C and δ 18 O by the U.S. Geological Survey Reston Stable Isotope Laboratory. The major findings of this preliminary work indicate that the isotopic signatures of δ 13 C (relative to the Vienna Pee Dee Belemnite scale, VPDB) of CO 2 resulting from coal combustion are similar to the δ 13 C VPDB signature of the bulk coal (− 28.46 to − 23.86 ‰) and are not similar to atmospheric δ 13 C VPDB of CO 2 (~ − 8 ‰, see http://www.esrl.noaa.gov/gmd/outreach/isotopes/c13tellsus.html ). The δ 18 O values of bulk coal are strongly correlated to the coal dry ash yields and appear to have little or no influence on the δ 18 O values of CO 2 resulting from coal combustion in open atmospheric conditions. There is a wide range of δ 13 C values of coal reported in the literature and the δ 13 C values from this study generally follow reported ranges for higher plants over geologic time. The values of δ 18 O (relative to Vienna Standard Mean Ocean Water) of CO 2 derived from atmospheric combustion of coal and other high-carbon fuels (peat and coal) range from + 19.03 to + 27.03‰ and are similar to atmospheric oxygen δ 18 O VSMOW values which average + 23.8‰. Further work is needed on a broader set of samples to better define the relationships between coal composition and combustion-derived gases.

International Journal of Coal Geology↗

Radiometric dating of marine-influenced coal using Re–Os geochronology

Coal deposits are integral to understanding the structural evolution and thermal history of sedimentary basins and correlating contemporeous estuarine and fluvial delatic strata with marine sections. While marine shales may readily lend themselves to Re&ndash;Os dating due to the dominance of hydrogenous Re and Os, the lack of a chronometer for near-shore sedimentary environments hampers basinwide correlations in absolute time. Here, we employ the Re&ndash;Os geochronometer, along with total organic carbon (TOC) and Rock&ndash;Eval data, to determine the timing and conditions of a marine incursion at the top of the Matewan coal bed, Kanawha Formation, Pottsville Group, West Virginia, USA. The observed range for hydrogen index (HI: 267&ndash;290 mg hydrocarbon/gram total organic carbon) for these coal samples suggests dominance of aliphatic hydrocarbons with low carbon (<C 19 ) chain length. Average Re ( 107.6&plusmn;16.4 ng/g ) and Os ( 0.52&plusmn;0.09 ng/g ) concentrations of the marine-influenced Matewan coal are higher by few orders of magnitude than published data for terrestrial coal. A Re&ndash;Os isochron for the Matewan coal provides an age of 325&plusmn;14 Ma (Model 3; MSWD = 12; n=19 ; 2 &sigma; ). This is the first Re&ndash;Os age derived from coal samples; the age overlaps a new composite Re&ndash;Os age of 317&plusmn;2 Ma for the immediately overlying Betsie Shale Member. External precision for replicate Os analyses carried out for several Matewan coal samples shows a positive correlation with their HI. The HI, which is low in terrestrial organic matter, reflects the degree of marine influence. Thus, samples with the most profound marine influence also have the best analytical reproducibility. Equilibration of Os isotopes with seawater under marine conditions overwhelms variability inherited from terrestrial plant debris, decreasing scatter on the isochron. The 187 Re/ 188 Os ratios of the Matewan coal (&sim;3300&ndash;5135) are higher than most of those previously published for Phanerozoic black shale (mostly <2000). Mass balance calculations based on Re/TOC and Os/TOC ratios for the Matewan coal indicate that both Re and Os are primarily marine in origin, and their high 187 Re/ 188 Os ratios confirm efficient removal of both elements from a sulfidic water column into the coal. We show that Re&ndash;Os geochronology of marine-influenced coal can be a viable tool for constraining depositional ages.

West Virginia↗

Using ground and intact coal Samples to evaluate hydrocarbon fate during supercritical CO 2 injection into coal beds: effects of particle size and coal moisture

To investigate the potential for mobilizing organic compounds from coal beds during geologic carbon dioxide (CO 2 ) storage (sequestration), a series of solvent extractions using dichloromethane (DCM) and using supercritical CO 2 (40 &deg;C and 10 MPa) were conducted on a set of coal samples collected from Louisiana and Ohio. The coal samples studied range in rank from lignite A to high volatile A bituminous, and were characterized using proximate, ultimate, organic petrography, and sorption isotherm analyses. Sorption isotherm analyses of gaseous CO 2 and methane show a general increase in gas storage capacity with coal rank, consistent with findings from previous studies. In the solvent extractions, both dry, ground coal samples and moist, intact core plug samples were used to evaluate effects of variations in particle size and moisture content. Samples were spiked with perdeuterated surrogate compounds prior to extraction, and extracts were analyzed via gas chromatography&ndash;mass spectrometry. The DCM extracts generally contained the highest concentrations of organic compounds, indicating the existence of additional hydrocarbons within the coal matrix that were not mobilized during supercritical CO 2 extractions. Concentrations of aliphatic and aromatic compounds measured in supercritical CO 2 extracts of core plug samples generally are lower than concentrations in corresponding extracts of dry, ground coal samples, due to differences in particle size and moisture content. Changes in the amount of extracted compounds and in surrogate recovery measured during consecutive supercritical CO 2 extractions of core plug samples appear to reflect the transition from a water-wet to a CO 2 -wet system. Changes in coal core plug mass during supercritical CO 2 extraction range from 3.4% to 14%, indicating that a substantial portion of coal moisture is retained in the low-rank coal samples. Moisture retention within core plug samples, especially in low-rank coals, appears to inhibit accessibility of supercritical CO 2 to coal matrix porosity, limiting the extent to which hydrocarbons are mobilized. Conversely, the enhanced recovery of some surrogates from core plugs relative to dry, ground coal samples might indicate that, once mobilized, supercritical CO 2 is capable of transporting these constituents through coal beds. These results underscore the need for using intact coal samples, and for better characterization of forms of water in coal, to understand fate and transport of organic compounds during supercritical CO 2 injection into coal beds.

Energy & Fuels↗

Re–Os age for the Lower–Middle Pennsylvanian Boundary and comparison with associated palynoflora

The Betsie Shale Member is a relatively thick and continuous unit that serves as a marker bed across the central Appalachian basin, in part because it includes an organic-rich shale unit at its base that is observable in drill logs. Deposited during a marine transgression, the Betsie Shale Member has been correlated to units in both Wales and Germany and has been proposed to mark the boundary between the Lower and Middle Pennsylvanian Series within North America. This investigation assigns a new Re&ndash;Os date to the base of the Betsie and examines the palynoflora and maceral composition of the underlying Matewan coal bed in the context of that date. The Matewan coal bed contains abundant lycopsid tree spores along its base with assemblage diversity and inertinite content increasing upsection, as sulfur content and ash yield decrease. Taken together, these palynologic and organic petrographic results suggest a submerged paleomire that transitioned to an exposed peat surface. Notably, separating the lower and upper benches of the Matewan is a parting with very high sulfur content (28 wt.%), perhaps representing an early marine pulse prior to the full on transgression responsible for depositing the Betsie. Results from Re&ndash;Os geochronology date the base of the Betsie at 323 &plusmn; 7.8 Ma, consistent with previously determined age constraints as well as the palynoflora assemblage presented herein. The Betsie Shale Member is also highly enriched in Re (ranging from 319.7 to 1213 ng/g), with high 187 Re/ 188 Os values ranging from 3644 to 5737 likely resultant from varying redox conditions between the pore water and overlying water column during deposition and early condensing of the section.

West Virginia↗

Central Appalachian basin natural gas database: distribution, composition, and origin of natural gases

The U.S. Geological Survey (USGS) has compiled a database consisting of three worksheets of central Appalachian basin natural gas analyses and isotopic compositions from published and unpublished sources of 1,282 gas samples from Kentucky, Maryland, New York, Ohio, Pennsylvania, Tennessee, Virginia, and West Virginia. The database includes field and reservoir names, well and State identification number, selected geologic reservoir properties, and the composition of natural gases (methane; ethane; propane; butane, iso -butane [ i -butane]; normal butane [ n -butane]; iso -pentane [ i -pentane]; normal pentane [ n -pentane]; cyclohexane, and hexanes). In the first worksheet, location and American Petroleum Institute (API) numbers from public or published sources are provided for 1,231 of the 1,282 gas samples. A second worksheet of 186 gas samples was compiled from published sources and augmented with public location information and contains carbon, hydrogen, and nitrogen isotopic measurements of natural gas. The third worksheet is a key for all abbreviations in the database. The database can be used to better constrain the stratigraphic distribution, composition, and origin of natural gas in the central Appalachian basin.

Kentucky, Maryland, New York, Ohio, Pennsylvania, ↗

Executive summary

Fossil fuels from the Appalachian basin region have been major contributors to the Nation&rsquo;s energy needs over much of the last three centuries. Early records indicate that Appalachian coal was first mined in the middle 1700s (Virginia and Pennsylvania) and was used sparingly to fuel colonial settlements and, later, a fledgling industrial-based economy along the eastern seaboard of the United States (de Witt and Milici, 1989). In 2011, central Appalachian basin coal production accounted for approximately 77 percent of all U.S. metallurgical (or coking) coal and 29 percent of total U.S. production (U.S. Energy Information Administration, 2013). Following initial discoveries and commercial use in western New York (1821) and Ohio and West Virginia (mid-1830s), the Appalachian petroleum (oil and gas) industry began in earnest in 1859 with the discovery of oil at the Drake well in northwestern Pennsylvania. Between 1860 and 1989, the Appalachian basin produced more than 2.5 billion barrels of oil (BBO) and more than 30 trillion cubic feet of gas (TCFG) from more than 500,000 wells (de Witt and Milici, 1989). Although both oil and gas continue to be produced in the Appalachian basin, most new wells in the region are drilled in shale reservoirs to produce natural gas. Appalachian coal and petroleum resources are still available in sufficient quantities to contribute significantly to the Nation&rsquo;s energy needs. For example, the U.S. Energy Information Administration (2010) estimated that there are 6,484 million short tons of recoverable coal reserves in the Appalachian basin. Similarly, about 14.7 billion barrels of oil equivalent (BBOE) (1.2 BBO+81 TCFG [or 13.5 BBOE]) of recoverable Appalachian basin oil and gas remain available of an estimated ultimate endowment of approximately 25.5 billion BBOE (cumulative production + reserves + estimated recoverable undiscovered resources) (this volume, chap. C.1). U.S. Geological Survey (USGS) Professional Paper 1708 is a modern, indepth collection of reports, cross sections, and maps that describe the geology of the Appalachian basin and its fossil fuel resources. Several of the chapters have been published in outside journals or as other USGS publications. Although this volume is not a comprehensive regional treatment of all notable geologic and fossil fuel localities in the Appalachian basin, the selected study areas and topics presented in the chapters cover large segments of the basin and a wide range of stratigraphic intervals. As the title implies, this volume addresses topics that refer to the locations of coal and petroleum accumulations, the stratigraphic and structural framework, and the geochemical characteristics of the coal beds and petroleum in the basin, as well as the results and documentation of recent USGS assessments of coal, oil, and gas resources in the basin. Many of the maps and accompanying data supporting the reports in this volume are available as downloadable geographic information system (GIS) data files (such as selected coal beds, selected oil and gas fields, locations of oil and gas wells, coal production, coal chemistry, total petroleum system (TPS) boundaries, and bedrock geology). Log ASCII Standard (LAS) files for geophysical (gamma ray) wireline well logs also are included. This publication supplements and updates older USGS regional studies of Appalachian basin coal and petroleum resources such as those by Arndt and others (1968) and the numerous contributors to USGS Miscellaneous Map Series I&minus;917 (for example, Harris and others, 1978), respectively. USGS Professional Paper 1708 is intended primarily for geoscientists in academia, industry, and government who are interested in Appalachian basin geology and its coal and petroleum resources. Other users, however, may find the wide variety of topics, papers, and digital images of value for landuse and policy planning issues. Among the anticipated benefits of the report are improvements in (1) resource assessment estimates and methodology, (2) exploration strategies, (3) basin models, and (4) energy use policies.

Appalachian Basin↗

Coal and petroleum resources in the Appalachian basin: index maps of included studies

This chapter B.1 of U.S. Geological Survey (USGS) Professional Paper 1708 provides index maps for many of the studies described in other chapters of the report. Scientists of the USGS and State geological surveys studied coal and petroleum resources in the central and southern Appalachian structural basins. In the southern Appalachian basin, studies focused on the coal-bearing parts of the Black Warrior basin in Alabama. The scientists used new and existing geologic data sets to create a common spatial geologic framework for the fossil-fuel-bearing strata of the central Appalachian basin and the Black Warrior basin in Alabama. Digital data have been compiled into a geographic information system (GIS) that is included in chapter I.1 (Trippi and others, this volume). Shape files and related metadata for features shown in the index maps of this chapter can be downloaded from chapter I.1. The study area for the Appalachian basin resource framework study includes the fossil-fuel-bearing strata of the following States (listed alphabetically): Alabama, Kentucky, Maryland, New York, Ohio, Pennsylvania, Tennessee, Virginia, and West Virginia. The outline of the study area is shown in figure 1; it differs from the boundary of the Appalachian Basin Province (Province 67) defined for the 1995 National Oil and Gas Assessment (NOGA) by the U.S. Geological Survey (1996a). The difference is that the study area includes regions where the Pennsylvanian coal-bearing strata crop out but does not include all of the oil- and gas-bearing strata of the Black Warrior basin, Alabama. The reasons for providing the index maps in this chapter are to show the locations of different studies, to give an overview of topics covered, and to help the user choose which chapter to read. Figures 1 and 2 show the study area outline and county names. Figure 3 shows oil and gas production in 1995 and 2005. Figure 4 shows locations of Upper Devonian sandstone oil and gas fields. Figure 5 shows major coal regions and coal fields. Figure 6 shows coal production by county. Figure 7 shows the locations of 10 cross sections of regional extent through the subsurface of the Appalachian basin. Figure 8 shows conodont alteration index sample locations and interpreted isograds for Ordovician rocks. Figure 9 shows vitrinite-reflectance data for Pennsylvanian coal in the Appalachian basin. Figure 10 shows the locations of coalbed-methane (CBM) assessment units in the study area, and figure 12 shows counties producing CBM. Figure 12 shows sulfur content of coal delivered to powerplants from coal-producing counties in the Appalachian basin and Black Warrior basin. Figure 13 shows locations of wells in Ohio and Pennsylvania where oil and gas were sampled in Lower Silurian reservoirs. Figure 14 shows the Conasauga-Rome/Conasauga Total Petroleum System and selected wells in the Rome trough in Kentucky and West Virginia having oil and gas production and shows. Figure 15 shows the locations of samples from Silurian reservoirs in Kentucky, New York, Ohio, Pennsylvania, and West Virginia; the samples yielded total organic carbon data. Figure 16 shows the locations of the Ben Hur and Rose Hill oil fields, Virginia, and the Swan Creek oil field, Tennessee. The one index map that is not shown is the areal extent of the shale gas plays in the basin. The extents of the plays can be found in Coleman and others (this volume, chap. G.13).

Appalachian basin↗

Coal and coalbed-methane resources in the Appalachian and Black Warrior basins: maps showing the distribution of coal fields, coal beds, and coalbed-methane fields

The maps contained in this chapter show the locations of coal fields, coal beds assessed by the U.S. Geological Survey (USGS) in 2000, and coalbed-methane fields in the central and southern Appalachian basin study areas, which include the coal-producing parts of the Black Warrior basin. The maps were compiled and modified from a variety of sources such as Tully (1996), Northern and Central Appalachian Basin Coal Regions Assessment Team (2001), Hatch and others (2003), Milici (2004), and unpublished data from the State geological surveys of Pennsylvania, West Virginia, Virginia, and Alabama. The terms &ldquo;coalbed methane&rdquo; and &ldquo;coal-bed gas&rdquo; are used interchangeably in this report. All of the figures are located at the end of this report. The Appalachian basin historically has been subdivided into three coal regions on the basis of regional geologic structure and stratigraphy: the northern region in western Pennsylvania, eastern Ohio, western Maryland, and northern West Virginia; the central region in west-central and southwestern West Virginia, eastern Kentucky, northern Tennessee, and southwestern Virginia; and the southern region in southern Tennessee, northern Alabama, and northwestern Georgia. The Appalachian basin is one of the most important coal-producing regions in the Nation and the world, and coal has been mined there throughout the last three centuries. The coal is primarily used within the Eastern United States for electrical power generation, but some of it is suitable for metallurgical uses. In 2008, the Appalachian basin produced about 320 million short tons of coal from 1,278 underground and surface coal mines (Energy Information Agency, 2009a). Coalbed-methane production in the Appalachian basin coal regions is an increasingly important resource. In 2008, 247 billion cubic feet (bcf) of coalbed methane was produced in the basin from Alabama (107 bcf), Virginia (101 bcf), West Virginia (28 bcf), and Pennsylvania (11 bcf) (Energy Information Agency, 2009b). Coalbed-methane exploration is ongoing in all of the States in the Appalachian basin coal regions, and production is expected to increase. The study area for most reports in this volume is the Appalachian basin. The term &ldquo;Appalachian basin study area&rdquo; (shortened from &ldquo;Appalachian basin geologic framework study area&rdquo;) includes all of the Appalachian Basin Province (Province 67) and part of the neighboring Black Warrior Basin Province (Province 65) of Dolton and others (1995). The boundaries for these two provinces and the study area are shown on figure 1.

Appalachian basin↗

Correlation chart of Pennsylvanian rocks in Alabama, Tennessee, Kentucky, Virginia, West Virginia, Ohio, Maryland, and Pennsylvania showing approximate position of coal beds, coal zones, and key stratigraphic units

The Appalachian basin, one of the largest Pennsylvanian bituminous coal-producing regions in the world, currently contains nearly one-half of the top 15 coal-producing States in the United States (Energy Information Agency, 2006). Anthracite of Pennsylvanian age occurs in synclinal basins in eastern Pennsylvania, but production is minimal. A simplified correlation chart was compiled from published and unpublished sources as a means of visualizing currently accepted stratigraphic relations between the rock formations, coal beds, coal zones, and key stratigraphic units in Alabama, Tennessee, Kentucky, Virginia, West Virginia, Ohio, Maryland, and Pennsylvania. The thickness of each column is based on chronostratigraphic divisions (Lower, Middle, and Upper Pennsylvanian), not the thickness of strata. Researchers of Pennsylvanian strata in the Appalachian basin also use biostratigraphic markers and other relative and absolute geologic age associations between the rocks to better understand the spatial relations of the strata. Thus, the stratigraphic correlation data in this chart should be considered provisional and will be updated as coal-bearing rocks within the Appalachian coal regions continue to be evaluated. Most geologic formations are identified and defined by the distinctive lithologic features they contain. However, formations of Pennsylvanian age in the Appalachian basin and the Pennsylvania Anthracite region have traditionally been described and named to reflect the presence or absence of economic coal beds and coarse-grained sandstone units, most of which have since been proven to be locally or regionally discontinuous (Ruppert and Rice, 2001). Many of the stratigraphic names and boundaries used for the coals and other geologic units in the Pennsylvanian rocks differ between States or regions (fig. 1). Because local and regional stratigraphic complexities occur within some States, a multiplicity of State-specific names is introduced that may be confusing to those conducting regional geologic assessments in the basin. Nonetheless, many of these stratigraphic names and boundaries have some elements that allow for regional stratigraphic correlation. For instance, many coals in the northern Appalachian basin coal region are easier to trace over greater distances than coals in the central and southern Appalachian basin coal regions (fig. 2). The Upper Pennsylvanian Pittsburgh coal bed (fig. 1) of the northern Appalachian basin coal region, for example, occurs as a synchronogenic bed deposited on a laterally continuous surface of sediments (Cross, 1954; Tewalt and others, 2001). The base of the Pittsburgh coal bed is designated as the contact between the Conemaugh Group (Upper Pennsylvanian) and the overlying Monongahela Group in western Pennsylvania, western Maryland, Ohio, and West Virginia (fig. 1). Therefore, in areas where the Pittsburgh coal bed is present, there is little controversy over its position or the placement of the boundary between the Conemaugh and Monongahela Groups. In other regions of the basin, group and formation boundaries are more difficult to identify over extensive areas. One example is the placement of the contact between the New River Formation and the overlying Kanawha Formation&mdash;a boundary that is not easily defined beyond the area where these units were first defined in West Virginia. At the type section of the Kanawha Formation, the base of the Lower Douglas coal zone (fig. 1) defines the contact between the Kanawha Formation and the underlying New River Formation (Rice and others, 1994b). However, subsequent mapping has demonstrated that the Lower Douglas coal zone is regionally discontinuous and in many parts of West Virginia is absent (Blake and others, 2002). Where absent, the Nuttall Sandstone Member of the underlying New River Formation sometimes occurs in the stratigraphic position of the Lower Douglas coal zone. Yet, even the Nuttall Sandstone Member has been found to be regionally discontinuous and of varying thickness throughout its extent, features that hinder its use as a regional stratigraphic marker bed in the Appalachian basin. Because of the many names used to identify individual coal beds and coal zones in the historic Appalachian basin coal-mining districts, coal bed designations may differ even more than stratigraphic nomenclature. In eastern Kentucky, northwest of the Pine Mountain thrust fault on the Cumberland overthrust sheet, for example, coal beds or coal zones equivalent to the Lower Elkhorn coal zone (within the Pikeville Formation) are identified also as the Eagle coal zone, Pond Creek coal zone, and Blue Gem coal bed (fig. 1). Southeast of the Pine Mountain thrust fault, yet still in Kentucky, equivalent coals in this same interval are known as the Imboden and Rich Mountain. Moreover, this same interval of coal is identified as the Blue Gem coal in Tennessee, the Imboden coal bed or Campbell Creek or Pond Creek coal zones in Virginia, and the Eagle coal zone in West Virginia.

Appalachian basin↗

Coal assessments and coal research in the Appalachian basin

Coal is one of our most important domestic energy resources, producing 37 percent of the Nation&rsquo;s electricity in 2012. Coal mining within the Appalachian basin has been ongoing for three centuries and, cumulatively, the basin is the most productive coal region in the United States. In 2012, only the Powder River basin produced more coal than the Appalachian basin. Coal is the most important mined product within the basin, and research on the quality and quantity of the coal is one of the primary functions of the U.S. Geological Survey (USGS) and the State geological surveys of Alabama, Kentucky, Maryland, Ohio, Pennsylvania, Tennessee, Virginia, and West Virginia. The USGS and the State geological surveys historically have worked together on coal research and assessment projects to achieve mutually beneficial science goals. The 2000 USGS coal resource assessment of the Appalachian basin (Northern and Central Appalachian Basin Coal Regions Assessment Team, 2001, USGS Professional Paper 1625&ndash;C) was done in close collaboration with scientists of the State geological surveys of Kentucky, Maryland, Ohio, Pennsylvania, Virginia, and West Virginia. Five of the top-producing coal beds and coal zones within the basin were quantitatively assessed, and results show that ample coal resources remain. Coal quality, not coal quantity, is the principal driver for coal production and use within the basin and will be for the foreseeable future. Cumulative coalbed-methane (CBM) production within the Appalachian basin has been about 2.3 trillion cubic feet (TCF), and most of the production has come from Alabama and Virginia (Milici and Polyak, this volume, chap. G.2). Significant CBM resources occur throughout the coal-producing States in the Appalachian basin, and commercial production is possible in all. State geological surveys are concentrating on mapping and correlating coal beds and coal zones and studying CBM potential and production. Both State surveys and the USGS are researching the potential for carbon dioxide sequestration in unmined coal beds and other geologic reservoirs. In addition, the State geological surveys continue their long-term collaboration with the USGS and provide coal stratigraphic data to the National Coal Resources Data System (NCRDS).

Appalachian basin↗

Thermal maturity patterns in Pennsylvanian coal-bearing rocks in Alabama, Tennessee, Kentucky, Virginia, West Virginia, Ohio, Maryland, and Pennsylvania

Thermal maturation patterns of Pennsylvanian strata in the Appalachian basin and part of the Black Warrior basin were determined by compiling previously published and unpublished percent-vitrinite-reflectance (%R 0 ) measurements and preparing isograd maps on the basis of the measurements. The isograd values range from 0.6 %R 0 in Ohio and the western side of the Eastern Kentucky coal field to 5.5 %R 0 in the Southern field in the Pennsylvania Anthracite region, Schuylkill County, Pa. The vitrinite-reflectance values correspond to the American Society of Testing Materials (ASTM) coal-rank classes of high-volatile C bituminous to meta-anthracite, respectively. In general, the isograds show that thermal maturity patterns of Pennsylvanian coals within the Appalachian basin generally decrease from east to west. In the Black Warrior basin of Alabama, the isograds show a circular pattern with the highest values (greater than 1.6 %R 0 ) centered in Jefferson County, Ala. Most of the observed patterns can be explained by variations in the depth of burial, variations in geothermal gradient, or a combination of both; however, there are at least four areas of higher ranking coal in the Appalachian basin that are difficult to explain by these two processes alone: (1) a set of west- to northwest-trending salients centered in Somerset, Cambria, and Fayette Counties, Pa.; (2) an elliptically shaped, northeast-trending area centered in southern West Virginia and western Virginia; (3) the Pennsylvania Anthracite region in eastern Pennsylvania; and (4) the eastern part of the Black Warrior coal field in Alabama. The areas of high-ranking coal in southwestern Pennsylvania, the Black Warrior coal field, and the Pennsylvania Anthracite region are interpreted here to represent areas of higher paleo-heat flow related to syntectonic movement of hot fluids towards the foreland associated with Alleghanian deformation. In addition to the higher heat flow from these fluids, the Pennsylvania Anthracite region also was buried more deeply than other parts of the Appalachian basin. The area of high rank coal in southwestern Virginia probably was controlled primarily by overburden thickness, but may also have been influenced by higher geothermal gradients.

Appalacian basin↗

Results of coalbed-methane drilling, Mylan Park, Monongalia County, West Virginia

The Department of Energy National Energy Technology Laboratory funded drilling of a borehole (39.64378&deg;N., 80.04376&deg;W.) to evaluate the potential for coalbed-methane and carbon-dioxide sequestration at Mylan Park, a public park in Monongalia County, W. Va. The total depth of the borehole was 2,525 feet (ft) and contained 1,483.41 ft of Pennsylvanian coal-bearing strata, 739.67 ft of Mississippian strata, and 301.93 ft of Devonian strata. The drill site was located directly over abandoned mines in the Pittsburgh and Sewickley coal beds. Coal cores from remaining Pittsburgh and Sewickley coal-bed-mine pillars were cut and retrieved for desorption from both mines. In addition, coals were cored and desorbed from the Redstone, Pittsburgh roof coal interval, Little Pittsburgh, Elk Lick, Brush Creek, Upper Kittanning, Middle Kittanning, Clarion, Upper Mercer, Lower Mercer, and Quakertown coal beds and coal zones. All coals are Pennsylvanian in age and are high-volatile A bituminous in rank. A total of 34.75 ft of coal was desorbed over a maximum period of 662 days, although most of the coal was desorbed for about 275 days. Measured raw-total-gas contents ranged from 0.43 standard cubic feet per ton (SCF/ton, an industry abbreviation) for the mined Sewickley coal bed to 130.98 SCF/ton for the Upper Kittanning coal bed. Volumes of residual gas were not measured; therefore, the gas volumes reported here should be regarded as minimum volumes. The amount of oxygen in the gas samples collected from the desorption canisters ranged from 2.55 to 20.13 percent. Methane contents ranged from 0 percent for one single canister from the Pittsburgh (WV&ndash;02&ndash;B3&ndash;4) and Little Pittsburgh (WV&ndash;02&ndash;CB3&ndash;2) coal beds to almost 81 percent for two canisters from the Clarion coal zone (WV&ndash;02&ndash;B3&ndash;16 and WV&ndash;02&ndash;B3&ndash;17), which suggests that all of the gas samples were contaminated to some degree by air. Therefore, all gas compositions reported have been normalized to remove the air. With a single exception (the Quakertown coal zone), the coals from the Mylan Park study area are thermogenic in origin with the isotopic composition of carbon (carbon 13, 13 C) in methane (expressed as &delta; 13 C in units of parts per thousand (per mil) relative to the Vienna Peedee belemnite (VPDB) standard) ranging from -32.39 to -50.66 per mil and ratios of methane to hydrocarbons of higher molecular weight ranging from 10 to 53. The Quakertown coal zone has a C 1 /C 2+ ratio of 913, suggesting that it contains some microbial gas. High-pressure carbon-dioxide adsorption isotherms were measured on composite coal samples of the Upper Kittanning coal bed and the Middle Kittanning and Clarion coal zones. Assuming that the reservoir pressure in the Mylan Park coals is equivalent to the normal hydrostatic pressure, the estimated maximum carbon-dioxide adsorption pressures range from a low of about 300 pounds per square inch (lb/in 2 ) in coals from the Clarion coal zone to 500 lb/in 2 for coals from the Upper Kittanning coal bed. The estimated maximum methane adsorption isotherms show that the coals from the Upper Kittanning coal bed and the Middle Kittanning coal zone are undersaturated in methane, but coals from the Clarion coal zone are close to saturation.

West Virginia↗

Results of coalbed-methane drilling, Meadowfill Landfill, Harrison County, West Virginia

The U.S. Environmental Protection Agency funded drilling of a borehole (39.33889&deg;N., 80.26542&deg;W.) to evaluate the potential of enhanced coalbed-methane production from unminable Pennsylvanian coal beds at the Meadowfill Landfill near Bridgeport, Harrison County, W. Va. The drilling commenced on June 17, 2004, and was completed on July 1, 2004. The total depth of the borehole was 1,081 feet (ft) and contained 1,053.95 ft of Pennsylvanian coal-bearing strata, and 27.05 ft of Mississippian strata. A total of 37.02 ft of high-volatile A and B bituminous Pennsylvanian coal was cored and desorbed from the Harlem, Brush Creek, Upper Freeport, Upper Kittanning upper split, and Upper Kittanning coal beds and the Clarion coal zone. Intact coal intervals were desorbed for a maximum period of 92 days before they were crushed to approximately 10-mesh to determine residual gas amounts. Crushed coal was desorbed for a period of 36 days. Measured gas content, on a dry, ash-free basis, ranged from 79.69 standard cubic feet per ton (SCF/ton), or 2.49 cubic centimeters per gram (cc/g), for the Harlem coal bed to 223.21 SCF/ton, or 6.98 cc/g, for the Clarion coal zone. Methane contents of desorbed gas from coal samples in the Meadowfill Landfill study area ranged from 14.87 to 98.73 percent (corrected for air contamination) for the Harlem coal bed and Clarion coal zone, respectively. Proportions of methane to the sum of the higher molecular weight hydrocarbons ranged from about 40 to 340 as the desorbed gas contained only a small percentage of higher weight hydrocarbons. Coalbed methane from the Upper Kittanning upper split and the Upper Kittanning coal beds is thermogenic in origin with isotopic composition of carbon (carbon 13, 13 C) in methane (expressed as &delta; 13 C in units of parts per thousand (per mil) relative to the Vienna Peedee belemnite (VPDB) standard) ranging from -46.6 to -48.7 per mil. Coalbed methane from the Brush Creek and Upper Freeport coal beds and the Clarion coal zone contains some biogenic methane with &delta; 13 C values ranging from -51.05 to -51.56 per mil.

West Virginia↗

Appalachian basin bituminous coal: sulfur content and potential sulfur dioxide emissions of coal mined for electrical power generation

Data from 157 counties in the Appalachian basin of average sulfur content of coal mined for electrical power generation from 1983 through 2005 show a general decrease in the number of counties where coal mining has occurred and a decrease in the number of counties where higher sulfur coals (>2 percent sulfur) were mined. Calculated potential SO 2 emissions (assuming no post-combustion SO 2 removal) show a corresponding decrease over the same period of time.

Appalachian basin↗

Introduction to selected references on fossil fuels of the central and southern Appalachian basin

The Appalachian basin contains abundant coal and petroleum resources that have been studied and extracted for at least 150 years. In this volume, U.S. Geological Survey (USGS) scientists describe the geologic framework and geochemical character of the fossil-fuel resources of the central and southern Appalachian basin. Separate subchapters (some previously published) contain geologic cross sections; seismic profiles; burial history models; assessments of Carboniferous coalbed methane and Devonian shale gas; distribution information for oil, gas, and coal fields; data on the geochemistry of natural gas and oil; and the fossil-fuel production history of the basin. Although each chapter and subchapter includes references cited, many historical or other important references on Appalachian basin and global fossil-fuel science were omitted because they were not directly applicable to the chapters.

Appalachian basin↗