Geology topics

Laurel G. Woodruff

Publications and source records attributed to Laurel G. Woodruff.

44 records · Page 3Linked to original sources

USGS2003

Arsenic in southeastern Michigan

Arsenic levels exceeding 10 μg/L are present in hundreds of private supply wells distributed over ten counties in eastern and southeastern Michigan. Most of these wells are completed in the Mississippian Marshall Sandstone, the principal bedrock aquifer in the region, or in Pleistocene glacial or Pennsylvanian bedrock aquifers. About 70% of ground water samples taken from more than 100 wells, have arsenic contents ≥10 μg/L with a maximum value of 220 μg/L . Water samples and continuous cores were taken from two test wells. Arsenic content of core samples ranges from <5 to more than 300 ppm, with the highest values found for pyritic black shales. Authigenic cements in the Marshall Sandstone include patchy authigenic pyrite that locally contains arsenic-rich (up to 8.5 wt. % As) domains. Bulk arsenic contents of pyrite-bearing intervals, sampled in well cuttings, are a high as 1020 ppm. Arsenic-rich pyrite is likely the ultimate source of arsenic in eastern and southeastern Michigan ground water, but evidence for pyrite oxidation at depth in bedrock aquifers is generally lacking. Pyrite oxidation may occur or have occurred in tills derived from the Marshall Sandstone and Coldwater Shale, which were found to contain arsenic-rich (up to at least 0.7 wt. % As) iron oxyhydroxides. Plausible mechanisms for widespread arsenic mobilization in eastern and southeastern Michigan ground water include weathering of pyrite in tills, reductive dissolution of iron oxyhydroxides in tills, and potentially, pyrite oxidation in bedrock aquifers, due to drawdown in wells or lowering of water-table levels in response to Pleistocene glaciation.

Michigan↗

USGS2003

The geochemical landscape of northwestern Wisconsin and adjacent parts of northern Michigan and Minnesota (geochemical data files)

This data set consists of nine files of geochemical information on various types of surficial deposits in northwestern Wisconsin and immediately adjacent parts of Michigan and Minnesota. The files are presented in two formats: as dbase files in dbaseIV form and Microsoft Excel form. The data present multi-element chemical analyses of soils, stream sediments, and lake sediments. Latitude and longitude values are provided in each file so that the dbf files can be readily imported to GIS applications. Metadata files are provided in outline form, question and answer form and text form. The metadata includes information on procedures for sample collection, sample preparation, and chemical analyses including sensitivity and precision.

Michigan, Minnesota, Wisconsin↗

USGS2003

Geochemistry of bedrock and glacial deposits in the vicinity of the Bend massive sulfide deposit, north central Wisconsin

In 1998 the U.S. Geological Survey (USGS) initiated a study to examine the natural regional environmental impact of sulfide mineralization exposed to episodic weathering and glaciation. The study focused on the Bend copper-gold massive sulfide deposit located in the Medford District of the Chequamegon National Forest in north central Wisconsin. The Bend massive sulfide deposit is a small, metal-rich sulfide body hosted by Paleoproterozoic metavolcanics. The mineralized horizon subcrops beneath 100-120 feet of glacial cover, and consists of massive pyrite and other sulfides. Bedrock and ore geochemistry are well characterized by analyses of diamond drill core provided to the USGS by Sharpe Energy and Resources. In July 1999, five rotasonic drillholes were completed through the unconsolidated Quaternary sediment, averaging about 100 feet thick, on a transect across the Bend deposit. Nearly continuous core was recovered from the surficial material along with several feet of the underlying bedrock. Samples representing the entire section were analyzed by the USGS to give a two-dimensional representation of element dispersal from the unmineralized bedrock. In addition, one hundred regional till samples were subsampled from the archives of the Quaternary Sediment Laboratory in the University of Wisconsin-Madison Department of Geology and Geophysics. These regional samples were collected mainly from Taylor County, where the Bend deposit is located, as well as contiguous parts of Clark and Marathon Counties. This open file report presents all of the geochemical data collected for this study. Additional publications describing the data in more detail are being completed.

Wisconsin↗

USGS2003

Bedrock, soil, and lichen geochemistry from Isle Royale National Park, Michigan

Isle Royale National Park, Michigan, is a large island in northeastern Lake Superior that became a national park in 1940 and was designated as a wilderness area in 1976. The relative isolation of Isle Royale (Figure 1), 25 kilometers out in Lake Superior from the Canadian mainland, its generally harsh climate, and its status as a wilderness national park have minimized human influence on the geochemical evolution of its landscape. USGS sampling on Isle Royale began in 1996 as part of a larger project on the geology of the Midcontinent rift in the Lake Superior region and continued through 2000. Sampling began with collecting bedrock samples to characterize the geochemistry of the volcanic rocks that make up the much of the island, as well as samples representative of the minor native copper mineralization found on the island. Preliminary results from the bedrock study indicated, among other findings, that basaltic bedrock on the island had no detectable mercury, but that there was an association between native copper mineralization and trace amounts of mercury (Cannon and Woodruff, 1999). This finding and the recognition by the National Park Service that 6 of 32 inland lakes on Isle Royale have mercury levels in game fish that exceed State of Michigan acceptable levels for human consumption (Kallemeyn, 2000) resulted in renewed sampling on the island focused more on environmental issues. To evaluate atmospheric inputs of mercury and other elements to soil geochemistry, regionally distributed samples of both soils and lichens were collected as paired samples across the entire island. At each soil sample site, three epiphytic (grows in trees) lichen species, Evernia mesomorpha , Hypogymnia plysodes , and Parmelia sucata , were always collected. At some sites Cladina rangiferina , a lichen that grows on bare bedrock and soil surfaces, was also collected. The occurrence of Cladina rangiferina on the island is somewhat limited, and so this lichen species was not collected at all sites. A high density of soil samples was collected within three individual watersheds (Sargent Lake, Lake Wagejo, and Lake Richie) for a localized study that evaluated the terrestrial distribution of mercury and other elements of environmental concern. These lakes were chosen using data from Kallemeyn (2000) that showed that Sargent Lake and Lake Wagejo have high mercury in fish, whereas Lake Richie, which is similar in size to Sargent Lake, does not. As part of this study on the terrestrial contribution of mercury to lakes, long cores of lake sediments were recovered from Sargent Lake and Lake Richie using a modified Livingston piston sampler. For an ancillary study that evolved from the study on the distribution of mercury in certain watersheds, some soil samples were collected to evaluate the impact of forest fire on soil geochemistry, deliberately sampling within and outside areas on the island that burned in severe forest fires in 1936. To complete bedrock sampling on the island, rock samples from the Copper Harbor Formation, a sedimentary unit that occurs on the southeastern part of the island were collected in 1999. This report presents all the geochemical data from samples collected by the USGS during this period (Figures 1 and 2). A number of reports presenting data interpretation are in preparation

Michigan↗

USGS2002

Bedrock and soil geochemistry from Voyageurs National Park, Minnesota

Bedrock, forest floor, and mineral soil sampling in Voyageurs National Park (VNP), Minnesota in 2000 and 2001 is part of a multidisciplinary project that includes the U. S. Geological Survey, National Park Service, University of Wisconsin – La Crosse, Minnesota Pollution Control Agency, and the Minnesota Department of Natural Resources. The joint project is examining the distribution of mercury in age-1 perch, lake water, bedrock and soils for eighteen watersheds in the interior of VNP. The purpose of the project was to establish the background and baseline geochemistry for bedrock and soil in the region, and to determine terrestrial mercury sources and sinks in VNP.

Minnesota↗

USGS1995

Evolution of tholeiitic diabase sheet systems in the eastern United States: examples from the Culpeper Basin, Virginia-Maryland, and the Gettysburg Basin, Pennsylvania

High-TiO2, quartz-normative (HTQ) tholeiite sheets of Early Jurassic age have intruded mainly Late Triassic sedimentary rocks in several early Mesozoic basins in the eastern US. Field observations, petrographic study, geochemical analyses and stable isotope data from three HTQ sheet systems were used to develop a general model of magmatic differentiation and magmatic-hydrothermal interaction for HTQ sheets. The three sheet systems have remarkably similar major-oxide and trace-element compositions. Cumulus and evolved diabase in comagmatic sheets separated by tens of kilometers are related by igneous differentiation. Differentiated diabase in all three sheets have petrographic and geochemical signatures and fluid inclusions indicating hydrothermal alteration beginning near magmatic temperatures and continuing to relatively low temperatures. Sulfur and oxygen isotope data are consistent with a magmatic origin for the hydrothermal fluid. -from Authors

Pennsylvania, Maryland, Virginia↗

USGS1995

Geologic, geochemical, and isotopic studies of a carbonate- and siliciclastic-hosted Pb-Zn deposit at Lion Hill, Vermont

Zn-, Pb-, Cu-, and Fe-bearing rocks of the Lion Hill area in western Vermont formed during the Early Cambrian by syngenetic sedimentary-exhalative and diagenetic replacement processes. Sphalerite, galena, chalcopyrite, pyrite, and, locally, magnetite form stratabound and broadly stratiform lenticular zones, -300 meters long and 25-50 meters thick, which are uneconomic at the present time. The lenses are structurally disrupted and metamorphosed to greenschist facies, probably due to the Taconic orogeny. Textural evidence suggests that mineralizing fluids permeated the sediments prior to lithification and that a dilatant fracture zone, possibly a feeder zone, contains some of the discordant veins at Lion Hill. The veins may have formed when the sediments were in a plastic, semiconsolidated state. The association of layered iron formation containing base-metal sulfide minerals provides possible lithologic evidence for syngenetic mineralization by submarine exhalative activity. Sand bars and tidal channels present in the sedimentary section could have acted as permeable pathways for movement of mineralizing fluids. The complex interlayering in the sedimentary sequence of carbonate and siliciclastic rock types having widely varying permeabilities created numerous fluid traps. Homogenization temperatures of primary and secondary inclusions in vein sphalerite range from 152°C to 196°C; salinities range from 11.5 to 14.0 equivalent weight percent NaCl. δ 34 S values of sulfides from Lion Hill vary from -25.9 to +10.0 per mil, and fall within the expected range for sulfide produced from bacteriogenic reduction of sulfate with δ 34 S values of 25 to 30 per mil. In addition, some pyrite probably formed from sulfate in trapped pore fluid that resulted in heavier isotopic values characteristic of more closed-system behavior. Three sphalerite samples that have heavier sulfur isotopic values may reflect a change in the source of sulfur during a later episode of mineralization, perhaps a change to a deep-seated source. Lead isotopic compositions of galenas from mineralized zones at Lion Hill range from 18.351 to 18.632 for 206 Pb/ 204 Pb, from 15.546 to 15.618 for 207 Pb/ 204 Pb, and from 38.126 to 38.496 for 208 Pb/ 204 Pb. The lead isotopic compositions of galena from Lion Hill and fluid inclusion and sulfur isotopic values for the Lion Hill sulfides are more like those of Pb-Zn-Ag deposits of Ireland than those of MVT or Appalachian-type Zn deposits. The prospect of an Irish-type sedimentary-exhalative origin for stratabound Pb-Zn deposits of the Paleozoic shelf of North America is of considerable importance to understanding the timing of mineralization relative to platform evolution and for evaluating the mineral resource potential of the region. Our study of the Lion Hill deposit indicates a potential for Irish-type Pb-Zn deposits in platform rocks of western Vermont; however, at Lion Hill they contain enrichments of Pb, Zn, and Cu rather than a Pb, Zn, and Ag association.

Vermont↗

USGS1992

Geology of Keweenawan Supergroup Rocks near the Porcupine Mountains, Ontonagon and Gogebic Counties, Michigan

This field trip examines the geology of rocks of the Keweenawan Supergroup (1 .1 Ga) and related intrusive rocks of the Midcontinent rift system (MRS) in the western part of the northern peninsula of Michigan. The combination of stops includes all formations of the Keweenawan Supergroup in this region. Examination of all described localities requires more than a single day and participants are encouraged to use this guidebook on their own to supplement the localities that will be visited on our one-day trip. Because of uncertainties of weather, road conditions, and remaining snow pack in early May in this region of very heavy snowfall, the stops that we will visitwill not be known until the date of the trip. Stops are numbered in stratigraphic order, from oldest to youngest, not in the order in which they will be visited.

Michigan↗