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Geology topics

Kendra J. Lynn

Publications and source records attributed to Kendra J. Lynn.

At least 19 recordsLinked to original sources
USGS2026

Storage timescales and the crystal growth history recorded in the layered reservoir of the Unit 3 Kulanaokuaiki Tephra Member of the Uēkahuna Ash from Kīlauea volcano

The Kulanaokuaiki Tephra Unit 3 (900 C.E.) was a subplinian basaltic scoria eruption, the largest known to have occurred at Kīlauea’s summit. The initiation mechanism and cause(s) of this highly hazardous eruption remain poorly understood, particularly as this style of activity has not been observed in the modern period. We use olivine diffusion timescales from Fe-Mg and lithium zoning to assess magma storage timescales and evaluate evidence for mixing prior to eruption. Of the 200 crystals assessed, 55% are normally zoned for forsterite and 45% are non-zoned. Zoned crystals (> 1 mm) ( n = 96) have average compositions of Fo 89 cores and Fo 81 rims, while small crystals 0.5–1 mm ( n = 14) have Fo 85 cores and Fo 82 rims. Modeled Fo diffusion timescales range from < 1 to 12.6 years (median of 3.0 years). Lithium maps in 32 of the forsterite-zoned crystals reveal a variety of lithium zoning types, most of which we attribute to crystal growth. Many lithium profiles are coupled to phosphorus within the outer ~ 100 μm of the crystal ( n = 17), reflecting growth processes and precluding their use for diffusion studies. Overall, our Unit 3 olivine dataset displays no evidence of magmatic priming shortly prior to eruption, unlike prior observations for the basaltic subplinian eruption of the Keanakāko‘i Tephra Unit E (1650 C.E.). Thus, explosive eruption magmas may be stored for considerably longer than previously thought, and magmatic priming is not a necessary precursor for Kīlauea’s explosive eruptions. We hypothesize that gas-driven filter pressing from crystallization of microlites and macrocrysts in the reservoir slurry contributed to the explosivity of the Unit 3 eruption.

Hawaii↗
USGS2026

Timescales of cumulate mobilization and mixing for the 1868 A.D. eruption of Mauna Loa, Island of Hawai‘i

The deadly 1868 A.D. eruption of Mauna Loa’s lower Southwest Rift Zone (Island of Hawai‘i) included a M7.9 earthquake and associated tsunami and landslides, demonstrating the severe hazards posed by Earth’s largest active subaerial volcano. To better understand the relationship between intense seismic activity, dike emplacement, magma storage, transport histories, and mobilization of olivine cumulates at Mauna Loa, we examine compositional zoning of olivine in the 1868 lava flows. Samples range from basalt (< 10% olivine) to picrite (30–40% olivine). The olivine cargo is heterogeneous (Fo 78.2–89.2 ; forsterite = [Mg/(Mg + Fe) × 100]) but dominated by ~ Fo 89 cores that lie above the Fe-Mg equilibrium field of host glasses. Crystal rims < Fo 80 are due to post-eruptive modification in slow cooling lava flows. Minor element compositions fall within the range of other Mauna Loa olivine erupted in the past 200 years. Olivine crystals exhibit both normal and complex Fo zoning patterns that yield timescales of diffusive re-equilibration that range from 3 to 258 days, with 72% of crystals recording 71 days or less. These timescales correspond to magmatic priming of the summit reservoir system ~ 2 months prior to the eruption and the M7.9 earthquake likely facilitated the transport of the crystal-rich summit-derived magmas downrift shortly prior to eruption. If the recently proposed faster Fe-Mg diffusion coefficient is used, timescales instead range from < 1 day to 25 days, with most recording 1 week or less. In this scenario, most of the olivine zoning would have to have been generated after the M7.9 earthquake perturbed the system.

Hawaii↗
USGS2026

Geochemistry of the 2022 Mauna Loa eruption: A comparison with earlier historical summit reservoir eruptions, with implications for magma supply and recharge

On November 28th, 2022, following a record historical repose period of 38 years, Mauna Loa erupted about 145 × 10 6 m 3 of lava and tephra over a 15-day period. The eruption was confined to the summit caldera region and the upper Northeast Rift Zone and is remarkably homogeneous in composition in both time and space. In these respects, it is typical of prior shallow summit reservoir magma bodies, recently estimated to be at a depth of around 1–2 km beneath the caldera. In contrast with these earlier magma bodies, which typically contain 6.7–7.1% MgO and are perched at the low-MgO end of olivine-control trends, the 2022 lava and tephra are more evolved with 6.24 + / − 0.03% MgO. This implies a temperature difference of around 11 °C with the prior 1984 magma. The simplest explanation is that over 38 years, cooling and crystallization of the remaining 1984 magma body has significantly exceeded magma recharge, giving rise to the evolved 2022 magma. The problem with this model is that we know from a variety of geophysical observations that in those 38 years, Mauna Loa has been erratically inflating, with heightened periods since around 2000 attributed to magma recharge. To reconcile these differences, we suggest instead that the 1984 magma cooled and crystallized much more extensively, from 1166 °C to around 1106 °C, co-crystallizing plagioclase, clinopyroxene, pigeonite and subsequently enstatite instead of pigeonite. At this point, the residual 1984 magma would have an MgO content around 4.2% and been about 50% solidified. Subsequent recharge and mixing by dominantly reservoir magmas, derived from a deeper 3–4-km intermediate magma reservoir, eventually produced the 2022 magma.

Hawaii↗
USGS2026

Osmium isotope constraints on Mauna Loa–Kilauea magmatic connectivity, Island of Hawai‘i

The Hawaiian volcanic chain exhibits a long-recognized double track of volcanism defined by the Loa and Kea trends, which erupt chemically and isotopically distinct lavas. Mauna Loa and Kīlauea, the two most frequently active volcanoes of the Loa and Kea trends, produce distinct endmember compositions. However, historical periods of compositional convergence have prompted debate regarding a potential magmatic connection between the two adjacent volcanoes. Proposed links include a shallow edifice-level plumbing system, a common magma source at ∼40 km depth, or a deeper asthenospheric source. In the latter scenario, based on correlated Sr–Nd–Pb isotopes and trace-element systematics, a “shared” mantle source supplies melt alternately to both volcanoes on multi-decadal timescales. Here, we use Os isotopes to evaluate the proposed connections. We measured Os isotopes in eight historical Mauna Loa tholeiites along with three Kīlauea tholeiites (1832 summit eruption; Uēkahuna Bluff; 2000 Pu‘u‘ō‘ō eruption) previously identified as isotopically intermediate between Mauna Loa and Kīlauea endmembers. We found that the acidic bromide leachates of all samples yield more radiogenic 187 Os/ 188 Os than corresponding bulk residues, with the labile Os-bearing phase comprising ∼0.4–27% of bulk Os. Mauna Loa tholeiites display nearly constant 187 Os/ 188 Os over the past ∼200 years (0.134–0.136; mean = 0.1357 ± 0.0013, n = 8, 2SD), despite large variations in total [Os] ranging from ∼30 pg/g (2022 tholeiite) to ∼966 pg/g (1868 picrite). The Kīlauea 1832 sample has 187 Os/ 188 Os = 0.1302 ± 0.0008, slightly higher than the Kīlauea endmember (0.1285 ± 0.0008), whereas the Uēkahuna Bluff and Pu‘u‘ō‘ō samples exhibit more elevated ratios (0.1314 ± 0.0008 and 0.1327 ± 0.0008, respectively). We conclude that the “shared” mantle source exerts negligible control on Mauna Loa Os isotope systematics. In contrast, the Kīlauea mantle source is more heterogeneous, with contributions from small-scale recycled domains with variable time-integrated Re/Os ratios.

Hawaii↗
USGS2026

Lava flow emplacement dynamics during the Mauna Loa 2022 eruption

On November 27, 2022, Mauna Loa erupted for the first time in 38 years, threatening a major highway on the Island of Hawaiʻi. The opening phases of the eruption were focused at the volcano’s summit, before magma propagated into the upper Northeast Rift Zone to erupt at four fissure segments that localized at fissure 3 by December 2. This fissure produced a braided ʻaʻā flow that traversed the steep north flank at >1 km/hr, before slowing as slopes shallowed. Effusion rates peaked in the early hours of the eruption and then steadied at around 100 m3/s at fissure 3. Lava effusion became variable and dropped abruptly on December 7. The eruption ended on December 10 with a final flow length of 18 km. We tracked lava effusion rates, flow advance, channel dynamics, and 3-D flow field development with field and remote sensing observations throughout this eruption to inform lava flow forecasts and investigate ʻaʻā flow dynamics. Flows were mapped using optical and infrared imagery, uncrewed aircraft systems, and airborne single-pass InSAR. Video- and time-lapse cameras were deployed to record lava fountaining and channelized flow at frequent intervals, supplemented by field measurements. Analyses of these data built a detailed record of effusion rates and associated flow dynamics. We combine these high frequency observations of the proximal flow field with broader thermal and 3-D mapping of the evolution in the medial and distal flow field to examine ʻaʻā flow dynamics from source to toe. Within the steep, medial section of the flow field, channel blockages caused back-ups and overflows as the eruption progressed. Disrupted lava supply to the distal flow field and low slopes resulted in stalling, widening, and thickening at the toe. Overall, 142 million m3 of lava covered 36 km2 over 13 days. Our results inform the controls on development and evolution of lava flow fields, with implications for forecasting primary flow advance and secondary flow field growth.

Hawaii↗
USGS2026

Spatial and temporal geochemical variations of lava flows and tephra deposits from the December 2020 to September 2024 eruptions of Kīlauea volcano

Kīlauea volcano underwent dramatic morphological changes in 2018. That year recorded the end of the 35-year-long eruption of Puʻuʻōʻō (1983–2018) and 10-year-long (2008–2018) Halemaʻumaʻu lava lake and emplacement of the ~4-month-long lower East Rift Zone lava flows that coincided with ~500 m of summit caldera collapse. Starting on December 20, 2020, eruptions resumed at Kīlauea’s summit. There were five summit eruptions between December 2020 and September 2023, which ranged in duration from more than a year to as short as a week. Following these summit eruptions, seismicity and deformation increased in the upper Southwest Rift Zone in 2024, culminating in a ~8.5-h-long eruption in this region on June 3, 2024. Increased seismicity and deformation then shifted to the upper and middle East Rift Zone and after several months culminated in an eruption just west of, and within, Nāpau Crater in the middle East Rift Zone from September 15 to 20, 2024. Despite vast morphological changes at Kīlauea’s summit, the geochemical compositions (i.e., whole rock and glass) that erupted from December 2020 to September 2023 are all remarkably similar to each other. Whole-rock compositions appear distinct from the preceding 2008–2018 Halemaʻumaʻu lava lake and phase 3 (i.e., summit or uprift-derived mafic lavas) of the 2018 lower East Rift Zone lava flows, although glass compositions appear to have more overlap with 2018 lower East Rift Zone glasses. The June 3, 2024, upper Southwest Rift Zone spatter and lava flows exhibit a dramatic enrichment in whole-rock MgO that is not recorded in glass, which reflects accumulation of olivine (e.g., antecrysts or xenocrysts) during dike emplacement, and is consistent with the abundance of olivine in the lava flows (5–10%). June 2024 Southwest Rift Zone whole-rock and glass compositions overlap with those erupted at the summit from December 2020 to September 2023, whereas some whole-rock trace (i.e., Sc, Sr, and Zr) and major elements (i.e., CaO) are suggestive of mixing with a magmatic component that had fractionated plagioclase and pyroxene and/or a new parental magma influencing the summit reservoir system. The September 15–20, 2024, eruption at Nāpau Crater in the middle East Rift Zone involved the most differentiated magma since eruptive activity resumed in December 2020, with its magma fractionating olivine + plagioclase + pyroxene. The September 15–20, 2024, composition resembles Puʻuʻōʻō lava flows that erupted in, or near, Nāpau Crater in 1983 (episode 1), 1997 (episode 54), and 2011 (episode 59), with episode 59 having a compositional cluster that is most similar to that of the September 2024 lava flows. The data presented and provided herein open new research perspectives for long-term analyses of geochemical variations following caldera collapse at Kīlauea volcano and facilitate comparisons with other basaltic caldera systems worldwide.

Hawaii↗
USGS2026

Small-volume tephra deposits of the May 1924 explosions from Halemaʻumaʻu, Kīlauea volcano, and their origin

More than 50 explosive eruptions occurred from Halemaʻumaʻu at Kīlauea volcano over 17 days from May 11 to 27, 1924. Ballistics weighing as much as 14,000 kg were ejected and most landed within 2 km of the vent. Fine ash made up a major component of the tephra and was dispersed tens of kilometers downwind. Draining of the Halemaʻumaʻu lava lake occurred in late February 1924, with the crater floor eventually subsiding by a further ∼70 m (to ∼180 m below the crater rim) by the time the first explosions took place during the night of May 10–11. The largest explosions occurred on May 17–18 and smaller explosions continued until May 27, at which point Halemaʻumaʻu had more than doubled in width and depth. The explosions generated plumes reaching up to ∼10 km high with ballistics ejected up to 2 km from the crater. Almost 100 years later, we investigate and characterize the preserved tephra deposits within ∼3 km of the 1924 crater rim. Grain size and shape analyses were performed on 202 samples collected from 34 tephra profiles using dynamic image analysis, with a subset of layers from nine tephra profiles used for componentry (200 grains per layer in the 0.5–1 mm size fraction). Additionally, we characterize the average diameters (using the five largest clasts) at 216 locations and measure the average diameters of 2291 ballistics (largest per ∼100 m 2 area). Physical descriptions from fieldwork and grain size distributions were used to subdivide the tephra layers into five lithofacies: coarse homogeneous, fine homogenous, red ash, accretionary lapilli-bearing, and finely laminated. Grain size versus shape data show a range of values that demonstrate most grains are dense, smooth, and equant, in alignment with lithic clasts dominating the tephra componentry. The fine grained and accretionary lapilli-bearing nature of some of these lithofacies confirms that water influenced the style of the explosions. However, we also note juvenile clasts within many of the tephra layers, indicating that many of the layers were formed during phreatomagmatic explosions (sensu stricto), despite the eruptive mechanism being dominantly phreatic. Juvenile clasts are more abundant higher in the tephra profiles, suggesting that juvenile magma was more involved later in the explosive sequence. Thermal and hydrologic modeling indicate that groundwater inflow into a short-lived, small-diameter volcanic conduit (10-m to 120-m-diameter used for modeling) during the 78–85 days preceding the first explosion provides a physically plausible mechanism for this eruptive sequence.

Hawaii↗
USGS2026

Comprehensive characterization of Mauna Loa basalt rheology based on the 2022 eruption

Rheological data are crucial for the understanding of storage, transport, eruption, and emplacement of magma and lava. While viscosity estimates for lavas from Mauna Loa, the largest active volcano on Earth, exist, no direct rheological measurements have been done to date. This is especially surprising given the role Mauna Loa lavas and resulting landforms play in the interpretation of volcanic processes across our solar system and beyond. We present the first complete rheological characterization of Mauna Loa lava, based on the 2022 eruption. We constrain the melt viscosity and map the lava's rheology during crystallization at isothermal subliquidus conditions and at cooling at rates between 0.25 and 3.00 °C/minute. These experiments were performed at oxygen fugacities relevant to storage and eruption conditions at Mauna Loa (log fO 2 = -8.7). We integrate textural and thermal characteristics obtained from the experiments with those from water quenched natural samples (i.e. sampled from actively flowing lava and quenched within seconds to preserve the textural state of the lava while flowing) to reconstruct the evolution of lava rheology during emplacement. This integration suggests that the Mauna Loa lavas were emplaced at viscosities between 10 1.5 to 10 4.5 Pa s over the temperature range of 1150 – 1090 °C before entering a region of rapid viscosity increase and effective solidification caused by groundmass crystallization. We provide a detailed comparison of our data to rheological reconstructions of the 1984 eruption. The resulting rheological map can help guide physical property-based magma ascent and lava emplacement models, as well as the interpretation of flow morphologies and the conditions of formation of basaltic landforms on other planets.

Hawaii↗
USGS2026

Petrologic and geochemical characterization of the first year of the 2024–ongoing episodic Halemaumau eruption of Kilauea (Episodes 1–39)

Kīlauea has been erupting episodically since December 23, 2024 (and is ongoing at the time of this writing in 2026) with two consistently active vents in Halema‘uma‘u producing lava fountains ranging in height from 40 to 540 m. In the first year of the eruption (through December 24, 2025, episode 39), the U.S. Geological Survey's Hawaiian Volcano Observatory collected 178 samples for eruption monitoring purposes and used a subset of 80 for near-real-time geochemical analyses. Tephra, lava, and recycled lava lake ooze-out samples have been studied on inter-episode timescales using diverse microanalytical techniques, where research-scale investigations have proven to be advantageous pseudo-near-real-time techniques. Here we present a geochemical and petrologic overview of episodes 1–39 to better understand eruption dynamics and identify changes at Kīlauea following the 2018 summit caldera collapse. There are no significant intra-episode geochemical changes that might be related to variable fountain heights or episode durations, suggesting that eruption dynamics are instead primarily controlled by viscosity and conduit geometry changes throughout a single episode and between episodes. There is variable but clear influence of the still-molten lava lake interior on compositions of this eruption, including in tephra samples from lava fountains, indicating that the vent conduits are connected in some way at depth with the still molten passive lava lake core. Tephra glasses (7.0–7.8 wt.% MgO) show cyclic changes in MgO that were decoupled from lava fountain heights and behavior in episodes 1–28 but positively correlated after episode 29. Additionally, whole-rock and glass compositions are enriched in minor elements such as K 2 O and TiO 2 compared to 2008–2023 summit eruptions, tracking the arrival of a new magma composition that may be related to the prolonged episodic eruptive behavior. Olivine-hosted melt inclusions from five episodes have ~0.35–0.43 wt.% H2O, < 300 ppm CO 2 and < 1500 ppm S, with no significant variations between episodes. Melt and fluid inclusion barometry show that magmas driving these episodes are stored and sourced from the shallow 1–2 km Halemaʻumaʻu reservoir, as were olivine from the 2023 summit eruption. The ongoing episodic eruption also has higher bulk-rock MgO compared to the five previous summit eruptions (2020−2023) and the forsterite (Fo) content of olivine has varied systematically from 2015 to 2025 with the equilibrium olivine composition of the Halema‘uma‘u reservoir increasing from Fo 80.7 in 2015 to Fo 82.7 by 2025. We argue that the Halemaʻumaʻu reservoir is heating up because the rate of magma supply is outpacing effusion and cooling following caldera collapse in 2018.

Hawaii↗
USGS2026

Insights from more than a year of ongoing episodic lava fountaining at Kilauea

Episodic lava fountaining is rare globally, with only three occurrences from Kīlauea (Hawaii) since 1823. Beginning in December 2024, an eruption within the summit crater, Halemaʻumaʻu, has produced 52 fountaining episodes to date, each lasting typically for hours and separated by days to weeks. Although multiple mechanisms have been proposed, fundamental questions remain about how magma reservoir pressure, conduit permeability, and volatile exsolution control fountaining onset. We present a multi-parameter record of episodic fountaining at Kīlauea using modern geochemical, geophysical, and geologic monitoring. These observations revealed systematic correlations between fountaining and summit inflation, enabling unprecedented quantitative forecasts. This eruption will provide new constraints on the timing, evolution, and processes driving episodic fountaining globally, and highlights Kīlauea’s role as a natural laboratory for studying volcanic processes.

Hawaii↗
USGS2025

Utilizing crystal records to determine the underlying architecture and timescales of magmatic processes during the 2022 Mauna Loa eruption

Details of Mauna Loa’s plumbing system and magma storage dynamics are relatively poorly constrained, relative to nearby Kīlauea volcano. Recent studies have begun to address this gap in knowledge using geophysical imaging or olivine-focused petrology. Here, we use the crystal cargo from the 2022 summit and Northeast Rift Zone eruption to advance our understanding of Mauna Loa’s storage regions and pre˗eruptive processes. We identify textural and geochemical populations of olivine, orthopyroxene, clinopyroxene, and plagioclase macrocrysts as well as evolved glomerocrysts consisting of orthopyroxene, clinopyroxene, and plagioclase. Summit versus rift zone trends can be distinguished between specific crystal populations and are used to infer magma transfer pathways. Melt inclusion barometry from three orthopyroxene populations indicate crystallization depths of ~2–3 km which coincide with previous olivine˗hosted fluid inclusion barometry across Mauna Loa’s recent 200˗yr eruptive history. We combine orthopyroxene˗hosted melt inclusion barometry with diffusion chronometry on the same crystals using Fe˗Mg interdiffusion to estimate timescales of mixing and recharge prior to the eruption. Summit orthopyroxene yield timescales of weeks to months, aligning with geophysically recognized pre˗eruptive intrusion events and previously determined olivine timescales. Northeast Rift Zone orthopyroxene crystals have resorbed cores and yield short pre˗eruptive mixing timescales on the order of hours to days. Chemistry and timescales from the orthopyroxene populations suggest some of the 2022 magmas may have bypassed the shallowest portions of the summit reservoir system and were transferred directly into the rift zone syn˗eruptively.

Hawaii↗
USGS2025

Near-real-time geochemical monitoring of Hawaiian volcanoes using energy dispersive X-ray fluorescence (EDXRF)

Syn-eruption geochemical monitoring during volcanic activity is an important component of integrated volcanic monitoring. Volcanoes on the Island of Hawai‘i are primarily monitored by the U.S. Geological Survey’s Hawaiian Volcano Observatory using instrumental networks, field surveys, satellite observations, and petrologic monitoring. In collaboration with the University of Hawaiʻi at Hilo, an important component of this monitoring is near-real-time (generally within 24 h of sample collection) bulk-rock geochemistry using benchtop energy-dispersive X-ray fluorescence (EDXRF). Bulk-rock geochemistry, coupled with additional petrologic and geophysical analyses, are used to track eruption dynamics to help facilitate identification and understanding of changes that signal the onset of potentially hazardous activity. In this paper, we present EDXRF methodology for bulk-rock analysis used to evaluate the 2018 Kīlauea and 2022 Mauna Loa eruptions and compare this technique to other geochemical methods. Syn-eruption geochemical monitoring using EDXRF provides reliable quantitative data that is important for understanding eruption dynamics. Critical to this process are calibrating the instrument for analysis over the same range of compositions expected during volcanic activity, compiling a relevant database from past eruptions on the same instrument for comparison, and having the physical infrastructure and trained personnel to complete the analyses in a timely fashion. In addition to the scientific goals of petrologic monitoring, near-real-time geochemical analysis in Hawaii provides important information about the nature of on-going eruptions and informs decision-makers and the public about associated evolving hazards.

Hawaii↗
USGS2025

Fluid inclusion constraints on the geometry of the magmatic plumbing system beneath Mauna Loa – Part I: Lavas and tephras

There are few petrological constraints on magma storage depths at Mauna Loa, Hawai‘i. Yet understanding the geometry of the magmatic plumbing system is critical for interpreting geophysical signals of unrest at this very high-threat volcano. We address this gap by examining CO₂-rich fluid inclusions (FI) in lava and tephra from seven eruptions (8870 ± 56 14C yr BP, 1852, 1855, 1868, 1949, 1950, and 1984), supplemented with published data from 2022. Raman spectroscopy was used to determine FI densities, from which entrapment pressures were calculated using a CO₂-H₂O equation of state. Most FI record pressures of ~ 0.25–1.25 kbar (~ 2–5 km depth below the summit), consistent with geophysical estimates from the past 40 years. In summit eruptions, FI hosted in more evolved olivine and orthopyroxene clots (Fo and Mg# < 84) record slightly shallower pressures than those in more primitive olivines (Fo > 84) from rift zone eruptions, suggesting a crystal-poor evolved cap near the top of the reservoir (~ 2 km). The similarity in storage depths across all eight eruptions indicates that Mauna Loa’s magmas have tapped a quasi-stable reservoir over the past two centuries, and possibly over 10 kyr. Electron backscatter diffraction reveals deformations to the crystal lattice in Fo82-83 olivines, likely due to deformation during storage in mush piles. The intensity of deformation is comparable to that seen at Kīlauea, implying that mush pile stress may be decoupled from edifice size or longevity. Finally, SO₂ contents in FI increase from ~ 2 mol% at 2 kbar to ~ 15 mol% at 0.5 kbar, suggesting sulphur degassing begins far deeper than the 0.2–0.3 kbar commonly assumed for Hawaiian systems. This validates the newest generation of S degassing models (e.g., Sulfur_X), and explains precursory SO2 emissions in the ~3 hours prior to the onset of the 2022 eruption (Esse et al. 2025).

Hawaii↗
USGS2025

Fluid inclusion constraints on the geometry of the magmatic plumbing system beneath Mauna Loa – Part 2: Xenoliths

Mauna Loa volcano erupts crystal-poor material at its summit and more crystal-rich material on its rift zones. Some of the more olivine-rich lava flows contain xenoliths with diverse mineralogy, including cumulate harzburgites with high-Mg# orthopyroxenes and high-Fo olivines (both > 84). Previous experimental work and thermodynamic modelling has proposed that high-Mg# orthopyroxenes only crystallize from Mauna Loa melts at high pressures (> 6 kbar, > 20 km), leading to suggestions that there is a region of sub-Moho magma storage at Mauna Loa in addition to the geophysically imaged magma reservoir at 2–5 km depth below the summit. We use melt and fluid inclusion barometry combined with thermodynamic models to further investigate this suggestion. Fluid inclusion data from harzburgites and dunitic xenoliths yield storage depths remarkably similar to those found in non-xenolithic crystals from lavas and tephras, with a clear peak at ~ 2–3 km (below the summit). Depths from melt inclusions in these xenoliths overlap with fluid inclusion pressures, ruling out the possibility of fluid inclusion re-equilibration during a period of stalling in a shallower reservoir. We examine five different thermodynamic models and find that the minimum pressure of olivine-orthopyroxene co-saturation varies by ~ 4 kbar (~ 12 km). These models also fail to predict that orthopyroxene is stable in ~ 15–80% of compositionally relevant experimental charges which grew orthopyroxene. Overall, this shows that phase stability modelling is an unreliable method of determining magma storage depth at Mauna Loa. We suggest that model discrepancies reflect a lack of experimental constraints on orthopyroxene stability at > 1200 ℃ and 0.01–5 kbar. Based on the presence of large oikocrystic orthopyroxenes completely enclosing rounded olivine chadacrysts, we suggest that these harzburgitic xenoliths formed through the reaction of intruding melts with olivine mush piles within the Mauna Loa edifice at ~ 3 km depth below the summit, with no need for a deeper storage reservoir. The predominance of pre-eruptive shallow storage means that there is more chance of detecting reservoir destabilization with geophysical monitoring techniques compared to a scenario where melts are supplied from sub-Moho reservoirs.

Hawaii↗
USGS2025

Crustal to mantle melt storage during the evolution of Hawaiian volcanoes

As the Pacific Plate migrates over the mantle plume below Hawaiʻi, magma flux decreases, resulting in changes in eruptive volume, style, and composition. It is thought that melt storage becomes deeper and ephemeral with the transition from highly voluminous tholeiitic (shield stage) to the less voluminous alkaline (post-shield and rejuvenation stages) magmatism. To quantitatively test this, we applied high-precision fluid inclusion barometry via Raman spectroscopy to samples from representative volcanoes of different evolutionary stages. This suggests an evolution from shield-stage shallow magma storage (~1 to 2 kilometers) for Kīlauea to a post-shield stage that includes crustal magma storage within the volcanic edifice (~2 kilometers) and deeper storage below the Moho (~20 to 27 kilometers) for Haleakalā. The rejuvenation stage (Diamond Head) displays mantle-dominated storage (~22 to 30 kilometers). High melt fluxes likely form stable conduits from the mantle to a shallow reservoir in the shield volcanoes. As melt flux decreases, the Moho becomes the boundary controlling melt stagnation and evolution.

Hawaii↗
USGS2025

Rhenium-osmium and oxygen isotope homogeneity during the 2022 Mauna Loa eruption and implications for basaltic magma storage

Mauna Loa is one of the largest and most active volcanoes on Earth. The most recent eruption of Mauna Loa started on 27 November 2022, lasted for 13 days, and was preceded by the longest repose time of 38 years in its modern history. In this contribution, new trace- and highly siderophile-element (HSE: Os, Ir, Ru, Pt, Pd, Re) abundances, 187 Re- 187 Os, and 18 O/ 16 O data are reported for the 2022 lavas. These lavas have a limited range of MgO (6.2 ± 0.1 wt.%) and Ni (83 ± 2 µg/g), with a broader range of Re (0.3 to 1.3 ng/g) and consistent Os (0.031 to 0.080 ng/g) contents. They have 187 Os/ 188 Os ratios (0.1345 to 0.1385) which are, on average, more radiogenic than Mauna Loa picrites (0.1331 to 0.1349) and are similar in composition to more differentiated Mauna Loa tholeiite lavas (0.1340 to 0.1381). The oxygen isotope compositions of glassy samples are 5.35 ± 0.15‰ ( n = 13) and span a range in δ 18 O of + 5.0 to + 5.5‰, with an average composition 0.2 to 0.3‰ lower than MORB. The δD value is − 81 ± 11‰ ( n = 5) at very low (0.03 ± 0.015 wt.%) H 2 O concentrations. The 2022 Mauna Loa eruption is similar in terms of δ 18 O but contrasts in terms of 187 Os/ 188 Os variability, with the recent longer-lived eruptions on La Palma (Canary Islands; 85 days) in 2021 and on the Reykjanes Peninsula (Iceland) that began in 2021 and are still ongoing. Initial lavas were more fractionated for both the Canary Islands and Iceland eruptions, producing more radiogenic Os isotope compositions than later erupted products. The 2022 Mauna Loa eruption showed no such trends. The limited range in isotope compositions of the 2022 Mauna Loa lavas and their strongly fractioned HSE patterns reflect long-term storage, crystal fractionation, and assimilation of related basaltic volcanic edifice materials by the parent magma beneath the volcano prior to eruption triggering. Eruption of differentiated and homogeneous tholeiite lavas at the summit caldera and high on the volcano’s flank, with emplacement of accumulative picrites lower on the volcano, are consistent with neutral buoyancy arguments.

Hawaii↗
USGS2025

Chemical and isotopic fractionation during melt inclusion formation

Melt inclusions are used to study the origin and evolution of magmas. The extent to which they represent equilibrium melt compositions, however, critically hinges on the ratio of crystal growth rate to diffusion rate in melts. If the rate of crystal growth is limited by the supply of nutrients and the dissipation of unwanted components, the trapped melt will be depleted in compatible elements and enriched in incompatible elements. Despite widespread recognition of the potential for melt inclusions to trap disequilibrium compositions, their identification remains a challenge. Here, we demonstrate how stable isotopes provide a solution to this problem. Melt inclusions in basaltic tephra from Kīlauea volcano, Hawai‘i, display Mg isotope fractionation up to 0.49‰ ( 26 Mg/ 24 Mg) relative to bulk rock. These observations indicate that kinetic processes, such as chemical diffusion, are at play, as equilibrium mineral-melt isotope fractionation at high temperatures is an order of magnitude smaller. We propose that the heavy Mg isotopic compositions of the melt inclusions were generated by the faster diffusion and thus preferential incorporation of 24 Mg by the growing olivine, leaving the slower diffusant ( 26 Mg) behind. The incompatible elements (e.g., Ca, Ti, and K) are predicted to display similarly large fractionations when boundary layer effects are significant. These findings show that stable isotopes can be a useful tool in identifying disequilibrium compositions in melt inclusions.

Geology↗