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Irving Friedman

Publications and source records attributed to Irving Friedman.

45 records · Page 3Linked to original sources
USGS1974

Fluid inclusion and light stable isotope study of the climax molybdenum deposits, Colorado

The Climax mine contains three molybdenite ore bodies and widespread late quartz-pyrite-sericite barren mineralization, each related to separate intrusive phases of the Climax stock. Alteration zones spatially related to each molybdenite ore body include a silica zone below, a potassium-silicate zone that approximately coincides with ore, and overlying quartz-sericite-pyrite-topaz, argillic, and propylite zones . Delta 18 O values of quartz range from +8.4 to 10.9 per mil; delta 18 O values of muscovite and sericite range from --0.8 to +7.5 per mil. Eight of ten sericite values are between +5.8 and +7.5. All of the quartz and most of the sericite is in isotopic equilibrium with a calculated water at 350 degrees C with delta 18 O values of +3.0 to 5.5 per mil. Delta 18 O values of K-feldspars range from --4.5 to +7.5 per mil. This wide range indicates partial reequilibration of the feldspar with later, isotopically light, waters. Two muscovites have delta D values of --146 and --91 per mil; sericite ranges from --168 to --116 per mil. The calculated delta D values of water at 275 degrees C in equilibrium with sericite are --144 to --92. This range is the same as that of fluid inclusions in ore samples.Kaolinite in the argillic zone has delta 18 O values of --0.9 to --2.2 and delta D values of --162 per mil. Calculated water at 250 degrees C in equilibrium with kaolinite delta 18 O values of --4.7 to -6 and delta D of about -130 per mil. The isotopic and fluid inclusion data best fit a model whereby the Climax ore bodies were formed from a hydrothermal fluid that originated by mixing light and heavy waters. The light water is isotopically similar to present-day meteoric water; the heavy water has the isotopic composition postulated for magmatic water, although it could be meteoric water that was heavier than present-day meteoric water.

Colorado↗
USGS1974

Continental depositon of Antarctic tillite indicated by carbon and oxygen isotopes

Freshwater deposition of the upper Paleozoic, Gondwana tillite in the Pensacola Mountains is indicated by low δ values of +4.9 to +6.1 permil δ0 1 8 (SMOW) and -1.8 to -15.9 permil δC 1 3 (PDB) in primary sedimentary calcite within the tillite. In contrast, Cambrian marine limestone from the Pensacola Mountains contains heavy isotopic abundances that are entirely characteristic of marine deposition.

Journal of Research of the U.S. Geological Survey↗
USGS1974

Isotopic composition of carbon and hydrogen in some Apollo 14 and 15 lunar samples

Isotopic composition of carbon and hydrogen in some Apollo 14 and 15 lunar samples was determined by use of a newly constructed combustion line that yields low blanks for CO 2 and H 2 . The results from combustion of fines and breccia from Apollo 14 lunar samples and of fines, breccia, and basalt from Apollo 15 were compared with data obtained by heating samples in vacuo to over 1,350°C. The two techniques gave similar results. Total carbon in the fines ranged from 51 to 110 p/m with a C 13 of +12 to -8 per mil (parts per thousand) PDB. The breccias contain 22 to 50p/mcarbon with a C 13 of -21 to -25 per mil. The crystalline rock (sample 15555) has a carbon content of about 7 p/m and a C 13 of -28 per mil. The total hydrogen in the fines ranges from 66 to 120 p/m with a (D/H) X 10 -6 of 39 to 90. The breccias contain 8 to 38p/mH 2 with a (D/H) X 10 -6 of 103 to 144. The crystalline rock contains about 2 p/m H 2 with a (D/H) X 10 -6 of about 140. Arguments are presented to show that the contamination by earth materials is not as serious a problem as has been proposed by previous authors.

Journal of Research of the U.S. Geological Survey↗
USGS1973

Notes on the bromine pentafluoride technique of oxygen extraction

The necessity to use a dry box when loading silicate samples into reaction vessels prior to fluorination is eliminated by the use of a simple loading technique. Data presented show the reproducibility of the fluorination reaction using this technique. Sodium fluoride, when added to saline waters prior to fluorination, improves the precision of the overall technique.

Journal of Research of the U.S. Geological Survey↗
USGS1970

Macusanite occurrence, age, and composition, Macusani, Peru

Macusanite, originally believed to be a type of tektite because of its sculpture, is shown to be related to sillar of the Macusani region, Peru. K-Ar measurements establish identical Pliocene ages (4.2 m.y.) for macusanite and sillar and relate these deposits to the extensive ash flows of the southern Andes. These rocks are unique for glassy rocks in that lithium, boron, and arsenic contents are very high; cesium, rubidium, tellurium, fluorine, and tin are higher than normal; zinc, copper, chromium, and zirconium are lower than normal; and high-alumina minerals such as andalusite are present.

Macusani↗
USGS1969

Carbon isotopes in pelites of the Precambrian Uncompahgre Formation, Needle Mountains, Colorado

Carbon isotopic ratios and weight percentages of carbon were measured in 15 samples of slate, phyllite, and schist of the approximately 1500- to 1600-m.y.-old Uncompahgre Formation of the Needle Mountains, southwestern Colorado. Rocks with less than 1 percent total carbon, all of which is reduced, have δC 13 values of −23 to −28 per mil, whereas those with 1 to 6.4 percent carbon have δC 13 from −29 to −31 per mil. In general, the slates and phyllites contain more carbon and isotopically lighter carbon than do the schists of higher metamorphic rank. Increasing loss of C 12 -enriched methane with increasing intensity of metamorphism is suggested to account for these differences.

Colroado↗