Search USGSSearch

Geology topics

Gregory P. Meeker

Publications and source records attributed to Gregory P. Meeker.

At least 19 recordsLinked to original sources

Method to characterize inorganic particulates in lung tissue biopsies using field emission scanning electron microscopy

Humans accumulate large numbers of inorganic particles in their lungs over a lifetime. Whether this causes or contributes to debilitating disease over a normal lifespan depends on the type and concentration of the particles. We developed and tested a protocol for in situ characterization of the types and distribution of inorganic particles in biopsied lung tissue from three human groups using field emission scanning electron microscopy (FE-SEM) combined with energy dispersive spectroscopy (EDS). Many distinct particle types were recognized among the 13 000 particles analyzed. Silica, feldspars, clays, titanium dioxides, iron oxides and phosphates were the most common constituents in all samples. Particles were classified into three general groups: endogenous , which form naturally in the body; exogenic particles, natural earth materials; and anthropogenic particles, attributed to industrial sources. These in situ results were compared with those using conventional sodium hypochlorite tissue digestion and particle filtration. With the exception of clays and phosphates, the relative abundances of most common particle types were similar in both approaches. Nonetheless, the digestion/filtration method was determined to alter the texture and relative abundances of some particle types. SEM/EDS analysis of digestion filters could be automated in contrast to the more time intensive in situ analyses.

Toxicology Mechanisms and Methods

Geologic occurrences of erionite in the United States: an emerging national public health concern for respiratory disease

Erionite, a mineral series within the zeolite group, is classified as a Group 1 known respiratory carcinogen. This designation resulted from extremely high incidences of mesothelioma discovered in three small villages from the Cappadocia region of Turkey, where the disease was linked to environmental exposures to fibrous forms of erionite. Natural deposits of erionite, including fibrous forms, have been identified in the past in the western United States. Until recently, these occurrences have generally been overlooked as a potential hazard. In the last several years, concerns have emerged regarding the potential for environmental and occupational exposures to erionite in the United States, such as erionite-bearing gravels in western North Dakota mined and used to surface unpaved roads. As a result, there has been much interest in identifying locations and geologic environments across the United States where erionite occurs naturally. A 1996 U.S. Geological Survey report describing erionite occurrences in the United States has been widely cited as a compilation of all US erionite deposits; however, this compilation only focused on one of several geologic environments in which erionite can form. Also, new occurrences of erionite have been identified in recent years. Using a detailed literature survey, this paper updates and expands the erionite occurrences database, provided in a supplemental file (US_erionite.xls). Epidemiology, public health, and natural hazard studies can incorporate this information on known erionite occurrences and their characteristics. By recognizing that only specific geologic settings and formations are hosts to erionite, this knowledge can be used in developing management plans designed to protect the public.

Arizona;California;Colorado;Idaho;Montana;New Mexi

Linking geology and health sciences to assess childhood lead poisoning from artisanal gold mining in Nigeria

Background: In 2010, Médecins Sans Frontières discovered a lead poisoning outbreak linked to artisanal gold processing in northwestern Nigeria. The outbreak has killed approximately 400 young children and affected thousands more. Objectives: Our aim was to undertake an interdisciplinary geological- and health-science assessment to clarify lead sources and exposure pathways, identify additional toxicants of concern and populations at risk, and examine potential for similar lead poisoning globally. Methods: We applied diverse analytical methods to ore samples, soil and sweep samples from villages and family compounds, and plant foodstuff samples. Results: Natural weathering of lead-rich gold ores before mining formed abundant, highly gastric-bioaccessible lead carbonates. The same fingerprint of lead minerals found in all sample types confirms that ore processing caused extreme contamination, with up to 185,000 ppm lead in soils/sweep samples and up to 145 ppm lead in plant foodstuffs. Incidental ingestion of soils via hand-to-mouth transmission and of dusts cleared from the respiratory tract is the dominant exposure pathway. Consumption of water and foodstuffs contaminated by the processing is likely lesser, but these are still significant exposure pathways. Although young children suffered the most immediate and severe consequences, results indicate that older children, adult workers, pregnant women, and breastfed infants are also at risk for lead poisoning. Mercury, arsenic, manganese, antimony, and crystalline silica exposures pose additional health threats. Conclusions: Results inform ongoing efforts in Nigeria to assess lead contamination and poisoning, treat victims, mitigate exposures, and remediate contamination. Ore deposit geology, pre-mining weathering, and burgeoning artisanal mining may combine to cause similar lead poisoning disasters elsewhere globally.

Environmental Health Perspectives

Preparation and characterization of "Libby Amphibole" toxicological testing material

The U.S. Environmental Protection Agency (USEPA) began work in Libby, Mont. in 1999 when an Emergency Response Team was sent to investigate local concern and media reports regarding asbestos-contaminated vermiculite. Since that time, the site has been granted Superfund status and site remediation to a safe level of asbestos has been ongoing. The amphibole asbestos from the Vermiculite Mountain vermiculite deposit near Libby, Mont. (Libby amphibole) is unusual in the sense that it is currently not classified as one of the regulated six asbestos minerals—chrysotile (a serpentine mineral) and the amphibole minerals amosite (asbestiform cummingtonite-grunerite), crocidolite (asbestiform riebeckite), asbestiform anthophyllite, asbestiform tremolite, and asbestiform actinolite. The amphiboles from the Vermiculite Mountain vermiculite deposit, primarily winchite and richterite, are related to tremolite and in the past have been referred to as sodium-rich tremolite or soda tremolite (Larsen, 1942; Boettcher, 1966; Wylie and Verkouteren, 2000; Gunter and others, 2003; Meeker and others, 2003). The public health issues in Libby, Mont. have brought to light many of the inconsistencies in the literature regarding fiber characteristics, nomenclature, and toxicology. To better understand the toxicological characteristics of the Libby amphibole, investigators require a sufficient quantity of material representing the range of fibrous amphiboles present in the vicinity of Vermiculite Mountain to use in toxicology studies. The material collected in 2000 (Meeker and others, 2003) has been exhausted and a second collection and preparation effort, funded by the USEPA, was conducted in 2007. Both the 2000 (LA2000) and 2007 (LA2007) materials were generated to support research needs identified by the USEPA and the National Toxicology Program, and new in-vivo and in-vitro toxicology studies are underway. This Open-File Report describes the process of preparation and summarizes the chemistry and mineralogy of the LA2007 toxicological testing material.

Libby, Montana

The dispersion of fibrous amphiboles by glacial processes in the area surrounding Libby, Montana, USA

Mining operations began at a world-class vermiculite deposit at Vermiculite Mountain near Libby, Montana, circa 1920 and ended in 1990. Fibrous and asbestiform amphiboles intergrown with vermiculite ore are suspected to be a causative factor in an abnormally high number of cases of respiratory diseases in former mine and mill workers, and in residents of Libby. The question addressed in this report is whether some of the amphibole from Vermiculite Mountain could have been dispersed by Pleistocene glacial processes rather than by human activity after vermiculite mining began. The history of Pinedale glaciation in the Libby area provides a framework for estimating the presence and distribution of asbestiform amphiboles derived from Vermiculite Mountain and found in naturally occurring sediments of Glacial Lake Kootenai that underlie the Libby Valley area. There were two situations where sediments derived from Vermiculite Mountain were deposited into Glacial Lake Kootenai: (1) as lake-bottom sediments derived from meltwater flowing down Rainy Creek when the valley south of Vermiculite Mountain was free of ice but active ice still covered Vermiculite Mountain; and (2) as lake-bottom sediments eroded from the Rainy Creek outwash and re-deposited during a re-advance of the Purcell Trench Glacier lobe near Moyie Springs, Idaho.

Montana

Examination of Libby, Montana, Fill Material for Background Levels of Amphibole from the Rainy Creek Complex Using Scanning Electron Microscopy and X-Ray Microanalysis

Natural background levels of Libby-type amphibole in the sediment of the Libby valley in Montana have not, up to this point, been determined. The purpose of this report is to provide the preliminary findings of a study designed by both the U.S. Geological Survey and the U.S. Environmental Protection Agency and performed by the U.S. Geological Survey. The study worked to constrain the natural background levels of fibrous amphiboles potentially derived from the nearby Rainy Creek Complex. The material selected for this study was sampled from three localities, two of which are active open-pit sand and gravel mines. Seventy samples were collected in total and examined using a scanning electron microscope equipped with an energy dispersive x-ray spectrometer. All samples contained varying amounts of feldspars, ilmenite, magnetite, quartz, clay minerals, pyroxene minerals, and non-fibrous amphiboles such as tremolite, actinolite, and magnesiohornblende. Of the 70 samples collected, only three had detectable levels of fibrous amphiboles compatible with those found in the rainy creek complex. The maximum concentration, identified here, of the amphiboles potentially from the Rainy Creek Complex is 0.083 percent by weight.

Open-File Report

Estimated minimum discharge rates of the Deepwater Horizon spill— Interim report to the flow rate technical group from the Mass Balance Team

All of the calculations and results in this report are preliminary and intended for the purpose, and only for the purpose, of aiding the incident team in assessing the extent of the spilled oil for ongoing response efforts. Other applications of this report are not authorized and are not considered valid. Because of time constraints and limitations of data available to the experts, many of their estimates are approximate, are subject to revision, and certainly should not be used as the Federal Government's final values for assessing volume of the spill or its impact to the environment or to coastal communities. Each expert that contributed to this report reserves the right to alter his conclusions based upon further analysis or additional information. An estimated minimum total oil discharge was determined by calculations of oil volumes measured as of May 17, 2010. This included oil on the ocean surface measured with satellite and airborne images and with spectroscopic data (129,000 barrels to 246,000 barrels using less and more aggressive assumptions, respectively), oil skimmed off the surface (23,500 barrels from U.S. Coast Guard [USCG] estimates), oil burned off the surface (11,500 barrels from USCG estimates), dispersed subsea oil (67,000 to 114,000 barrels), and oil evaporated or dissolved (109,000 to 185,000 barrels). Sedimentation (oil captured from Mississippi River silt and deposited on the ocean bottom), biodegradation, and other processes may indicate significant oil volumes beyond our analyses, as will any subsurface volumes such as suspended tar balls or other emulsions that are not included in our estimates. The lower bounds of total measured volumes are estimated to be within the range of 340,000 to 580,000 barrels as of May 17, 2010, for an estimated average minimum discharge rate of 12,500 to 21,500 barrels per day for 27 days from April 20 to May 17, 2010.

Louisiana

Chemical and morphological comparison of erionite from Oregon, North Dakota, and Turkey

Erionite, a fibrous zeolite, occurs in pediment gravel deposits near Killdeer Mountain, North Dakota. Material from these pediment deposits has been excavated for use as roadbed throughout Dunn County, North Dakota. Erionite also occurs in the Cappadocian region of Turkey, where a link between malignant mesothelioma and inhalation of this mineral has been established. The U.S. Environmental Protection Agency (EPA), Region 8, requested that the U.S. Geological Survey (USGS) compare the chemistry and morphology of erionite collected from the Killdeer Mountains to those collected from villages in Turkey and from Rome, Oregon, which has also been linked to disease in animal studies.

Open-File Report

Spectroscopic and x-ray diffraction analyses of asbestos in the World Trade Center dust: Asbestos content of the settled dust

On September 17 and 18, 2001, samples of settled dust and airfall debris were collected from 34 sites within a 1-km radius of the WTC collapse site, including a sample from an indoor location unaffected by rainfall, and samples of insulation from two steel beams at Ground Zero. Laboratory spectral and x-ray diffraction analyses of the field samples detected trace levels of serpentine minerals, including chrysotile asbestos, in about two-thirds of the dust samples at concentrations at or below ~1 wt%. One sample of a beam coating material contained up to 20 wt% chrysotile asbestos. Analyses indicate that trace levels of chrysotile were distributed with the dust radially to distances greater than 0.75 km from Ground Zero. The chrysotile content of the dust is variable and may indicate that chrysotile asbestos was not distributed uniformly during the three collapse events.

New York

Environmental mapping of the World Trade Center area with imaging spectroscopy after the September 11, 2001 attack

The Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) was flown over the World Trade Center area on September 16, 18, 22, and 23, 2001. The data were used to map the WTC debris plume and its contents, including the spectral signatures of asbestiform minerals. Samples were collected and used as ground truth for the AVARIS mapping. A number of thermal hot spots were observed with temperatures greater than 700 °C. The extent and temperatures of the fires were mapped as a function of time. By September 23, most of the fires observed by AVIRIS had been eliminated or reduced in intensity. The mineral absorption features mapped by AVARIS only indicated the presence of serpentine mineralogy and not if the serpentine has asbestiform.

Book chapter

Materials characterization of dusts generated by the collapse of the World Trade Center

The major inorganic components of the dusts generated from the collapse of the World Trade Center buildings on September 11, 2001 were concrete materials, gypsum, and man-made vitreous fibers. These components were likely derived from lightweight Portland cement concrete floors, gypsum wallboard, and spray-on fireproofing and ceiling tiles, respectively. All of the 36 samples collected by the USGS team had these materials as the three major inorganic components of the dust. Components found at minor and trace levels include chrysotile asbestos, lead, crystalline silica, and particles of iron and zinc oxides. Other heavy metals, such as lead, bismuth, copper, molybdenum, chromium, and nickel, were present at much lower levels occurring in a variety of chemical forms. Several of these materials have health implications based on their chemical composition, morphology, and bioaccessibility.

Book chapter

Inorganic chemical composition and chemical reactivity of settled dust generated by the World Trade Center building collapse

Samples of dust deposited around lower Manhattan by the September 11, 2001, World Trade Center (WTC) collapse have inorganic chemical compositions that result in part from the variable chemical contributions of concrete, gypsum wallboard, glass fibers, window glass, and other materials contained in the buildings. The dust deposits were also modified chemically by variable interactions with rain water or water used in street washing and fire fighting. Chemical leach tests using deionized water as the extraction fluid show the dust samples can be quite alkaline, due primarily to reactions with calcium hydroxide in concrete particles. Calcium and sulfate are the most soluble components in the dust, but many other elements are also readily leached, including metals such as Al, Sb, Mo Cr, Cu, and Zn. Indoor dust samples produce leachates with higher pH, alkalinity, and dissolved solids than outdoor dust samples, suggesting most outdoor dust had reacted with water and atmospheric carbon dioxide prior to sample collection. Leach tests using simulated lung fluids as the extracting fluid suggest that the dust might also be quite reactive in fluids lining the respiratory tract, resulting in dissolution of some particles and possible precipitation of new phases such as phosphates, carbonates, and silicates. Results of these chemical characterization studies can be used by health scientists as they continue to track and interpret health effects resulting from the short-term exposure to the initial dust cloud and the longer-term exposure to dusts resuspended during cleanup.

New York

Preliminary analytical results for a mud sample collected from the LUSI Mud Volcano, Sidoarjo, East Java, Indonesia

On May 29, 2006, mud and gases began erupting unexpectedly from a vent 150 meters away from a hydrocarbon exploration well near Sidoarjo, East Java, Indonesia. The eruption, called the LUSI (Lumpur 'mud'-Sidoarjo) mud volcano, has continued since then at rates as high as 160,000 m3 per day. At the request of the United States Department of State, the U.S. Geological Survey (USGS) has been providing technical assistance to the Indonesian Government on the geological and geochemical aspects of the mud eruption. This report presents initial characterization results of a sample of the mud collected on September 22, 2007, as well as inerpretive findings based on the analytical results. The focus is on characteristics of the mud sample (including the solid and water components of the mud) that may be of potential environmental or human health concern. Characteristics that provide insights into the possible origins of the mud and its contained solids and waters have also been evaluated.

East Java

Leachate Geochemical Results for Ash and Burned Soil Samples from the October 2007 Southern California Wildfires

This report is the second release of leachate geochemical data included as part of a multidisciplinary study of ash and burned soil samples from the October 2007 wildfires in southern California. Geochemical data for the first set of samples were released in an Open-File Report (Plumlee and others, 2007). This study is a continuation of that work. The objectives of this leaching study are to aid in understanding the interactions of ash and burned soil with rainfall. For this study, 12 samples collected in early November 2007 were leached using the U.S. Geological Survey (USGS) Field Leach Test (FLT). Following leaching, sub-samples of the leachate were analyzed for pH and specific conductance. The leachate was then filtered, and aliquots were preserved for geochemical analysis. This report presents leachate geochemical data for pH, specific conductance, alkalinity, anions using ion chromatography (I.C.), cations using inductively coupled plasma?atomic mass spectrometry (ICP-MS), and mercury by continuous flow injection?cold vapor?atomic fluorescence (CVAFS).

Open-File Report

Petrology of the 2004-2006 Mount St. Helens lava dome -- implications for magmatic plumbing and eruption triggering

Eighteen years after dome-forming eruptions ended in 1986, and with little warning, Mount St. Helens began to erupt again in October 2004. During the ensuing two years, the volcano extruded more than 80×10 6 m 3 of gas-poor, crystal-rich dacite lava. The 2004-6 dacite is remarkably uniform in bulk-rock composition and, at 65 percent SiO 2 , among the richest in silica and most depleted in incompatible elements of the magmas erupted at Mount St. Helens during the past 500 years. Since shortly after the first spine of lava appeared, samples have been collected using a steel box dredge (“Jaws”) suspended 20-35 m below a helicopter and, occasionally, by hand sampling. As of the spring of 2006, 25 age-controlled samples have been collected from the seven spines of the new lava dome. Samples were obtained from both the interiors of spines and from their carapaces, which are composed of fault gouge and cataclasite 1-2 m thick. The dacite lava is crystal rich, with 40-50 percent phenocrysts. The groundmass is extensively crystallized to a cotectic assemblage of quartz, tridymite, and Na- and K-rich feldspar microlites, raising the total crystal content to more than 80 percent on a vesicle-free basis in all but the earliest erupted samples. Early samples and those collected from near the spine margin are more glassy and vesicular that those collected later and from the interior of the spines. Oxide thermobarometer determinations for the earliest erupted samples we collected cluster at temperatures of approximately 850&deg;C and at an oxygen fugacity one log unit above the nickel-nickel oxide (NNO) buffer curve. In contrast, samples from relatively glass-poor samples erupted in late 2004 and early 2005 have zoned oxides with apparent temperatures that range to greater than 950&deg;C. The higher temperatures in these microlite-rich rocks are attributed to latent heat evolved during extensive and rapid groundmass crystallization. Low volatile contents of matrix glasses and presence of tridymite and quartz in the high-silica rhyolite matrix glass indicate extensive shallow (<1 km) crystallization of the matrix, driven by degassing of water and solidifying the magma below the level of the vent. The mode of eruption of the dacite as a series of fault-gouge-mantled spines is explained by this process of extensive subvent degassing and solidification. Although the dacite from this eruption is more silica rich than 1980-86 dome rocks, most major and trace element concentrations of the 1980-86 and 2004-6 magma batches are similar, and magmatic gas emissions have been low and have had similar ratios to those of the 1980s, raising the possibility that the magma might be residual from the 1980–86 reservoir. However, titanium and chromium are enriched slightly relative to the most recent 1980-86 and Goat Rocks (A.D. 1800-1857) eruptive cycles, and heavy rare-earth-element abundances are slightly depleted relative to those erupted during the past 500 years at Mount St. Helens. These data suggest either addition of new gas-poor dacite magma or tapping of a region of the preexisting reservoir that was not erupted previously. A relatively low pressure of last phenocryst growth suggests that the magma was derived from near the apex of the Mount St. Helens magma reservoir at a depth of about 5 km. Viewed in the context of seismic, deformation, and gas-emission data, the petrologic and geochemical data can be explained by ascent of a geochemically distinct batch of magma into the apex of the reservoir during the period 1987-97, followed by upward movement of magma into a new conduit beginning in late September 2004. The question of new versus residual magma has implications for the long-term eruptive behavior of Mount St. Helens, because arrival of a new batch of dacitic magma from the deep crust could herald the beginning of a new long-term cycle of eruptive activity. It is also important to our understanding of what triggered the eruption and its future course. Two hypotheses for triggering are considered: (1) top-down fracturing related to the shallow groundwater system and (2) an increase in reservoir pressure brought about by recent magmatic replenishment. With respect to the future course of the eruption, similarities between textures and character of eruption of the 2004-6 dome and the long-duration (greater than 100 years) pre-1980 summit dome, along with the low eruptive rate of the current eruption, suggest that the eruption could continue sluggishly or intermittently for years to come.

Washington

Chemistry, mineralogy, and petrology of amphibole in Mount St. Helens 2004-2006 dacite

Textural, compositional, and mineralogical data are reported and interpreted for a large population of clinoamphibole phenocrysts in 22 samples from the seven successive dacite spines erupted at Mount St. Helens between October 2004 and January 2006. Despite the uniformity in bulk composition of magma erupted since 2004, there is striking textural and compositional diversity among amphibole phenocrysts and crystal fragments that have grown from, partly dissolved in, or been accidentally incorporated in the new dacite. This study demonstrates that magma erupted throughout the current dome-building episode is the end product of small-scale, thorough mixing of multiple generations of crystal-laden magma. The mixed amphibole population provides important clues to magma conditions within the dacite magma reservoir prior to ascent and, to some extent, the dynamics of mixing and ascent. The predominant amphibole in new dome rock ranges from moderate- to high-alumina tschermakite and magnesiohastingsite compositions. As substantiated by major- and trace-element geochemistry and barometry calculations, this compositional range of crystals, along with plagioclase, orthopyroxene, and iron-titanium oxide, is likely to have precipitated from dacite magma over a range of pressures and temperatures consistent with experimentally determined phase relations (~900&deg;C to ~800&deg;C between 100 MPa and ~350-400 MPa or ~4-km and 13.5-15-km depth). Along with traceelement characteristics, textural and compositional data help to distinguish some low-alumina magnesiohornblende crystals as xenocrysts. The diverse range in composition of amphibole in all samples of 2004-6 dacite, and the complex zonation observed in many phenocrysts, suggests a well-mixed source magma with components that are subjected to repeated heating and (or) pressurization within this pressure-temperature window. Amphibole textural and compositional diversity suggest dynamic conditions in the upper-reservoir zone, which has been tapped steadily during ~2 years of continuous and monotonous eruption. This well-mixed crystal mush is likely to have been subjected to repeated injection of hotter magma into cooler crystal-laden magma while simultaneously assimilating earlier generations of dacitic roof material and surrounding gabbroic rock. Decompression-related reaction rims around subhedral, rounded, resorbed, and fragmented amphibole phenocrysts, regardless of composition, indicate that this mixed-crystal assemblage was being broken, abraded, and dissolved in the magma as a result of mechanical mixing before and during early stages of ascent from conduit roots extending into a mushy cupola of the shallow reservoir. In the earliest lava samples (October 2004), amphiboles with <3-&mu;m rims associated with a glassier matrix than later samples suggest a slightly faster ascent rate consistent with the relatively high eruptive flux of the earliest phases of dome extrusion. Reaction rim widths of ~5 &mu;m on amphibole in all subsequently extruded lava result from a steady influx and upward transport of magma from 3.5-2.5-km to ~1-km depth at rates of ~600 to ~1,200 m/day, through a conduit less than 10 m in radius. Slower ascent rates inferred from volumetric-flux and matrixcrystallization parameters are explained by a widening of the conduit to greater than 60 m radius within 1 km of the surface.

Washington