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Erin E. Marsh

Publications and source records attributed to Erin E. Marsh.

28 records · Page 2Linked to original sources
USGS2013

Nickel-cobalt laterites: A deposit model

Nickel-cobalt (Ni-Co) laterite deposits are supergene enrichments of Ni±Co that form from intense chemical and mechanical weathering of ultramafic parent rocks. These regolith deposits typically form within 26 degrees of the equator, although there are a few exceptions. They form in active continental margins and stable cratonic settings. It takes as little as one million years for a laterite profile to develop. Three subtypes of Ni-Co laterite deposits are classified according to the dominant Ni-bearing mineralogy, which include hydrous magnesium (Mg)-silicate, smectite, and oxide. These minerals form in weathering horizons that begin with the unweathered protolith at the base, saprolite next, a smectite transition zone only in profiles where drainage is very poor, followed by limonite, and then capped with ferricrete at the top. The saprolite contains Ni-rich hydrous Mg-silicates, the Ni-rich clays occur in the transition horizon, and Ni-rich goethite occurs in the limonite. Although these subtypes of deposits are the more widely used terms for classification of Ni-Co laterite deposits, most deposits have economic concentrations of Ni in more than one horizon. Because of their complex mineralogy and heterogeneous concentrations, mining of these metallurgically complex deposits can be challenging. Deposits range in size from 2.5 to about 400 million tonnes, with Ni and Co grades of 0.66–2.4 percent (median 1.3) and 0.01–0.15 percent (median 0.08), respectively. Modern techniques of ore delineation and mineralogical identification are being developed to aid in streamlining the Ni-Co laterite mining process, and low-temperature and low-pressure ore processing techniques are being tested that will treat the entire weathered profile. There is evidence that the production of Ni and Co from laterites is more energy intensive than that of sulfide ores, reflecting the environmental impact of producing a Ni-Co laterite deposit. Tailings may include high levels of magnesium, sulfate, and manganese and have the potential to be physically unstable.

Scientific Investigations Report↗
USGS2012

Mineral potential tracts for orogenic, Carlin-like, and epithermal gold deposits in the Islamic Republic of Mauritania, (phase V, deliverable 68): Chapter H1 in Second projet de renforcement institutionnel du secteur minier de la République Islamique de Mauritanie (PRISM-II)

In 1996, at the request of the Government of the Islamic Republic of Mauritania, a team of U.S. Geological Survey (USGS) scientists produced a strategic plan for the acquisition, improvement and modernization of multidisciplinary sets of data to support the growth of the Mauritanian minerals sector and to highlight the geological and mineral exploration potential of the country. In 1999, the Ministry of Petroleum, Energy, and Mines of the Islamic Republic of Mauritania implemented a program for the acquisition of the recommended basic geoscientific information, termed the first Projet de Renforcement Institutionnel du Secteur Minier (Project for Institutional Capacity Building in the Mining Sector, PRISM-I). As a result of the PRISM-I efforts, a great deal of new geological, geophysical, geochemical, remote sensing, and hydrological data became available for evaluation and synthesis. However, the Ministry of Petroleum, Energy, and Mines recognized that additional work was required to extract the full benefit of the data before it could be of greatest use to the international community and of benefit to the Mauritanian minerals and development sector. To achieve this benefit, the Ministry of Petroleum, Energy, and Mines implemented a second Projet de Renforcement Institutionnel du Secteur Minier (PRISM-II) in 2006 to consolidate, synthesize, and interpret all of the existing data, create a new 1:1,000,000 scale geologic map, and define the mineral resource potential of the country. A consortium in which the USGS was the lead scientific agency carried out the majority of the PRISM-II work. In 2008, the USGS Mauritania Minerals Project was interrupted due to political changes in Mauritania. PRISM-II work resumed in 2011, and was completed in 2013 with the delivery of over 40 separate written reports and plates, an access file containing the Mauritanian National Mineral Deposits Database, and an interactive GIS containing all of the multi-disciplinary data and interpretive areas of mineral resource potential in Mauritania. This report contains the USGS results of the PRISM-II Mauritania Minerals Project and is presented in cooperation with the Ministry of Petroleum, Energy, and Mines of the Islamic Republic of Mauritania. The Report is composed of separate chapters consisting of multidisciplinary interpretive reports with accompanying plates on the geology, structure, geochronology, geophysics, hydrogeology, geochemistry, remote sensing (Landsat TM and ASTER), and SRTM and ASTER digital elevation models of Mauritania. The syntheses of these multidisciplinary data formed the basis for additional chapters containing interpretive reports on 12 different commodities and deposit types known to occur in Mauritania, accompanied by countrywide mineral resource potential maps of each commodity/deposit type. The commodities and deposit types represented include: (1) Ni, Cu, PGE, and Cr deposits hosted in ultramafic rocks; (2) orogenic, Carlin-like, and epithermal gold deposits; (3) polymetallic Pb-Zn-Cu vein deposits; (4) sediment-hosted Pb-Zn-Ag deposits of the SEDEX and Mississippi Valley-type; (5) sediment-hosted copper deposits; ( 6) volcanogenic massive sulfide deposits; (7) iron oxide copper-gold deposits; (8) uranium deposits; (9) Algoma-, Superior-, and oolitic-type iron deposits; (10) shoreline Ti-Zr placer deposits; (11) incompatible element deposits hosted in pegmatites, alkaline rocks, and carbonatites, and; (12) industrial mineral deposits. Additional chapters include the Mauritanian National Mineral Deposits Database are accompanied by an explanatory text and the Mauritania Minerals Project GIS that contains all of the interpretive layers created by USGS scientists. Raw data not in the public domain may be obtained from the Ministry of Petroleum, Energy, and Mines in Nouakchott, Mauritania.

Open-File Report↗
USGS2011

The Kharapeh orogenic gold deposit: Geological, structural, and geochemical controls on epizonal ore formation in West Azerbaijan Province, Northwestern Iran

The Kharapeh gold deposit is located along the northwestern margin of the Sanandaj–Sirjan Zone (SSZ) in the West Azerbaijan province, Iran. It is an epizonal orogenic gold deposit formed within the deformed zone between central Iran and the Arabian plate during the Cretaceous–Tertiary Zagros orogeny. The deposit area is underlain by Cretaceous schist and marble, as well as altered andesite and dacite dikes. Structural analysis indicates that the rocks underwent tight to isoclinal recumbent folding and were subsequently co-axially refolded to upright open folds during a second deformation. Late- to post-tectonic Cenozoic granites and granodiorites occur northeast of the deposit area. Mineralization mainly is recognized within NW-trending extensional structures as veins and breccia zones. Normal faults, intermediate dikes, and quartz veins, oriented subparallel to the axial surface of the Kharapeh antiform, indicate synchronous extension perpendicular to the fold axis during the second folding event. The gold-bearing quartz veins are >1 km in length and average about 6 m in width; breccia zones are 10–50 m in length and ≤1 m in width. Hydrothermal alteration mainly consists of silicification, sulfidation, chloritization, sericitization, and carbonatization. Paragenetic relationships indicate three distinct stages—replacement and silicification, brecciation and fracture filling, and cataclastic brecciation—with the latter two being gold-rich. Fluid inclusion data suggest mineral deposition at temperatures of at least 220–255°C and depths of at least 1.4–1.8 km, from a H 2 O–CO 2 ±CH 4 fluid of relatively high salinity (12–14 wt.% NaCl equiv.), which may reflect metamorphism of passive margin carbonate sequences. Ore fluid δ 18 O values between about 7‰ and 9‰ suggest no significant meteoric water input, despite gold deposition in a relatively shallow epizonal environment. Similarities to other deposits in the SSZ suggest that the deposit formed as part of a diachronous gold event during the middle to late Tertiary throughout the SSZ and during the final stages of the Zagros orogeny. The proximity of Kharapeh to the main tectonic suture of the orogen, well-developed regional fold systems with superimposed complex fracture geometries, and recognition of nearby volcanogenic massive sulfide systems that suggest a region characterized by sulfur- and metal-rich crustal rocks, collectively indicate an area of the SSZ with high favorability for undiscovered gold resources.

West Azerbaijan Province↗
USGS2011

Ni-Co laterite deposits

Nickel-cobalt (Ni-Co) laterite deposits are an important source of nickel (Ni). Currently, there is a decline in magmatic Ni-bearing sulfide lode deposit resources. New efforts to develop an alternative source of Ni, particularly with improved metallurgy processes, make the Ni-Co laterites an important exploration target in anticipation of the future demand for Ni. This deposit model provides a general description of the geology and mineralogy of Ni-Co laterite deposits, and contains discussion of the influences of climate, geomorphology (relief), drainage, tectonism, structure, and protolith on the development of favorable weathering profiles. This model of Ni-Co laterite deposits represents part of the U.S. Geological Survey Mineral Resources Program's effort to update the existing models to be used for an upcoming national mineral resource assessment.

Open-File Report↗
USGS2007

Book review: Geology of gem deposits

Geology of Gem Deposits is the most recent addition to the classic short course volumes published by the Mineralogical Association of Canada. Although not as comprehensive as the title might imply, this volume does contain overview papers devoted (in varying degrees) to the geology of diamond, beryl, corundum, chrysoberyl, tanzanite and tsarvorite, topaz, and jade deposits, as well as gem-bearing pegmatites and colored gemstones of Canada. Individually, most of the chapters provide robust overviews of the gems they cover. However, as presented, these papers do not make a well-organized and cohesive volume. The content, structure, and organization of each of these papers vary significantly. Despite this shortcoming, a number of the chapters cover relevant geologic information, making the book an important contribution for economic geologists interested in the exploration and geology of gem deposits.

Economic Geology↗
USGS2007

Regional Fluid Flow and Basin Modeling in Northern Alaska

The foothills of the Brooks Range contain an enormous accumulation of zinc (Zn) in the form of zinc sulfide and barium (Ba) in the form of barite in Carboniferous shale, chert, and mudstone. Most of the resources and reserves of Zn occur in the Red Dog deposit and others in the Red Dog district; these resources and reserves surpass those of most deposits worldwide in terms of size and grade. In addition to zinc and lead sulfides (which contain silver, Ag) and barite, correlative strata host phosphate deposits. Furthermore, prolific hydrocarbon source rocks of Carboniferous and Triassic to Early Jurassic age generated considerable amounts of petroleum that may have contributed to the world-class petroleum resources of the North Slope. Deposits of Zn-Pb-Ag or barite as large as those in the Brooks Range are very rare on a global basis and, accordingly, multiple coincident favorable factors must be invoked to explain their origins. To improve our understanding of these factors and to contribute to more effective assessments of resources in sedimentary basins of northern Alaska and throughout the world, the Mineral Resources Program and the Energy Resources Program of the U.S. Geological Survey (USGS) initiated a project that was aimed at understanding the petroleum maturation and mineralization history of parts of the Brooks Range that were previously poorly characterized. The project, titled “Regional Fluid Flow and Basin Modeling in Northern Alaska,” was undertaken in collaboration with industry, academia, and other government agencies. This Circular contains papers that describe the results of the recently completed project. The studies that are highlighted in these papers have led to a better understanding of the following: The complex sedimentary facies relationships and depositional settings and the geochemistry of the sedimentary rocks that host the deposits (sections 2 and 3). The factors responsible for formation of the barite and zinc deposits (sections 4 and 5). The geochemical indicators or exploration tools that might be used to locate other large deposits of similar character in the Red Dog district and elsewhere (section 6). The isotopic compositions of barite and sulfide deposits (sections 7 and 8) The distribution and nature of phosphate and metalliferous oil shale localities (sections 9 and 10). The architecture, kinematics, and timing of the complex thrust systems that disrupted and redistributed the Carboniferous and younger rocks; these studies are necessary in order to make a realistic palinspastic reconstruction of the basin (sections 11 and 12). The nature and extent of the petroleum system sourced from Mississippian rocks (section 13).

Circular↗
USGS2007

Geology and origin of epigenetic lode gold deposits, Tintina Gold Province, Alaska and Yukon

More than 50 million ounces of lode gold resources have been defined in the previous 15 years throughout accreted terranes of interior Alaska and in adjacent continental margin rocks of Yukon. The major deposits in this so-called Tintina Gold Province formed around 105 to 90 million years ago in east-central Alaska and Yukon, and around 70 million years ago in southwestern Alaska, late in the deformational history of their host rocks. All gold deposits studied to date formed from CO 2 -rich and 18 O-rich crustal fluids, most commonly of low salinity. The older group of ores includes the low-grade intrusion-related gold systems at Fort Knox near Fairbanks and those in Yukon, with fluids exsolved from fractionating melts at depths of 3 to 9 kilometers and forming a zoned sequence of auriferous mineralization styles extending outward to the surrounding metasedimentary country rocks. The causative plutons are products of potassic mafic magmas generated in the subcontinental lithospheric mantle that interacted with overlying lower to middle crust to generate the more felsic ore-related intrusions. In addition, the older ores include spatially associated, high-grade, shear-zonerelated orogenic gold deposits formed at the same depths from upward-migrating metamorphic fluids; the Pogo deposit is a relatively deep-seated example of such. The younger gold ores, restricted to southwestern Alaska, formed in unmetamorphosed sedimentary rocks of the Kuskokwim basin within 1 to 2 kilometers of the surface. Most of these deposits formed via fluid exsolution from shallowly emplaced, highly evolved igneous complexes generated mainly as mantle melts. However, the giant Donlin Creek orogenic gold deposit is a product of either metamorphic devolatilization deep in the basin or of a gold-bearing fluid released from a flysch-melt igneous body.

Alaska, Yukon↗
USGS2004

The late cretaceous Donlin Creek gold deposit, Southwestern Alaska: Controls on epizonal ore formation

The Donlin Creek gold deposit, southwestern Alaska, has an indicated and inferred resource of approximately 25 million ounces (Moz) Au at a cutoff grade of 1.5 g/t. The ca. 70 Ma deposit is hosted in the Late Cretaceous Kuskokwim flysch basin, which developed in the back part of the arc region of an active continental margin, on previously accreted oceanic terranes and continental fragments. A hypabyssal, mainly rhyolitic to rhyodacitic, and commonly porphyritic, 8- × 3-km dike complex, part of a regional ca. 77 to 58 Ma magmatic arc, formed a structurally competent host for the mineralization. This deposit is subdivided into about one dozen distinct prospects, most of which consist of dense quartz ± carbonate veinlet networks that fill north-northeast–striking extensional fractures in the northeast-trending igneous rocks. The sulfide mineral assemblage is dominated by arsenopyrite, pyrite, and, typically younger, stibnite; gold is refractory within the arsenopyrite. Sericitization, carbonatization, and sulfidation were the main alteration processes. Fluid inclusion studies of the quartz that hosts the resource indicate dominantly aqueous ore fluids with also about 3 to 7 mol percent CO 2 ± CH 4 and a few tenths to a few mole percent NaCl + KCl. The gold-bearing fluids were mainly homogeneously trapped at approximately 275° to 300°C and at depths of 1 to 2 km. Some of the younger stibnite may have been deposited by late-stage aqueous fluids at lower temperature. Measured δ 18 O values for the gold-bearing quartz range between 11 and 25 per mil; the estimated δ 18 O fluid values range from 7 to12 per mil, suggesting a mainly crustally derived fluid. A broad range of measured δ D values for hydrothermal micas, between –150 and –80 per mil, is suggestive of a contribution from devolatilization of organic matter and/or minor amounts of mixing with meteoric fluids. Gold-associated hydrothermal sulfide minerals are characterized by δ 34 S values mainly between –16 and –10 per mil, with the sulfur derived from diagenetic pyrite and organic matter within the flysch basin. A smaller group of δ 34 S measurements, which shows values as depleted as –27 per mil, suggests a different local sulfur reservoir in the basin for the later hydrothermal episode dominated by stibnite. Initial ϵ Nd of –8.7 to –3.1 and 87 Sr/ 86 Sr measurements of 0.706 to 0.709 for the ore-hosting dikes also indicate a crustal reservoir for some of the Late Cretaceous magmatism. Overlapping lead isotope data for these intrusive rocks and for sulfide minerals suggest a crustal contribution for the lead in both. Copper- and gold-bearing stockwork veinlets in hornfels occur at Dome, a prospect located at the northern end of the Donlin Creek deposit. These stockworks are cut by the younger auriferous gold veins that define the main Donlin Creek gold mineralization. Highly saline, gas-rich, heterogeneously trapped fluids deposited the stockworks at temperatures approximately 100°C hotter than those of the main gold-forming event at Donlin Creek. The genetic relationship of the Dome prospect to the main Donlin Creek gold resource is equivocal. The epizonal Donlin Creek deposit shows affinities to the gold systems interpreted by various workers as orogenic or intrusion related; it shows important differences from typical epithermal and Carlin-like deposits. The ore-forming fluids were derived by either broad-scale metamorphic devolatilization above rising mantle melts or exsolution from a magma that was dominated by a significant flysch melt component.

Economic Geology↗
USGS2004

Nature of hydrothermal fluids at the shale-hosted Red Dog Zn-Pb-Ag deposits, Brooks Range, Alaska

The Red Dog Zn-Pb-Ag district in the western Brooks Range, northern Alaska, contains numerous shale-hosted Zn-Pb sulfide and barite deposits in organic-rich siliceous mudstone and shale, chert, and carbonate rocks of the Carboniferous Kuna Formation. The giant Red Dog shale-hosted deposits consist of a cluster of four orebodies (Main, Qanaiyaq, Aqqaluk, and Paalaaq) that lie within distinct thrust panels that offset a single ore deposit during the Mesozoic Brookian orogeny. These Zn-Pb-Ag-barite orebodies contain one of the world's largest reserves and resources of zinc. Fluid inclusions in samples of vein sphalerite, which accounts for about 20 percent of the ore in the Main deposit, and quartz that composes the bulk of the extensive silicification in the ore deposit, were studied by microthermometry, Raman spectrometry, and ion chromatography. The study of fluid inclusions in the vein sphalerite was limited by the intense postore deformation of the ore deposits. However, four primary aqueous fluid inclusion assemblages in vein sphalerite yield temperatures of homogenization of 115&deg; to 120&deg;C, 123&deg; to 127&deg;C, 110&deg; to 120&deg;C and 175&deg; to 180&deg;C. More abundant final-melting temperatures indicate that the fluid inclusions in sphalerite have salinities of about 14 to 19 wt percent NaCl equiv. The fluid inclusion electrolyte data show that the ore fluid responsible for the vein sphalerite derived its salinity from the evaporation of seawater. Considering the salinity of the fluid inclusions together with the electrolyte data, it is possible that the evaporative brine was initially about 30 wt percent saline fluid and that it mixed with a more dilute fluid somewhere along its flow path. The temperature, salinity, and electrolyte composition of vein sphalerite in the Red Dog deposits are remarkably similar to those characteristics in sphalerite veins near the Century zinc deposit, Australia. Together, these data compose the majority of information on the temperature and composition of sphalerite in deposits of this type. On the basis of data describing fluid inclusions in sphalerite and the geologic setting of the ore deposits, a "reflux brine" model is suggested for the Red Dog deposits. In this model, brines were produced in evaporative environments in supratidal carbonate facies of the Lisburne Group less than 100 km from the Red Dog deposits. These reflux brines may have infiltrated the underlying rocks of Endicott Group or fractured metasedimentary basement rocks. In the absence of a local heat source at the Red Dog deposits, the temperature of the ore fluids (~100&deg; to <200&deg;C) requires that the fluids circulated at depths between ~ 2.4 and 7.4 km. In the Red Dog area, the metalliferous fluids ascended into the organic-rich rocks of the Kuna Formation, probably along zones of active extensional faults or breaches in the shale aquitards overlying the aquifers in the Endicott Group. Fluid inclusions were also studied in the abundant quartz that constitutes the majority of the silica rock in the ore deposits. This postore quartz extensively replaced barite and was traditionally thought to be part of the main ore event. Primary fluid inclusion assemblages contain two-phase aqueous inclusions, single-phase inclusions of dense methane, or both. Primary assemblages that contain single-phase, dense-methane inclusions together with two-phase aqueous inclusions yield consistent homogenization temperatures that provide unequivocal evidence for the coeval trapping of immiscible gas and aqueous fluids. The densities of the methane inclusions, together with the temperature of homogenization of coexisting aqueous fluid inclusions, show that these fluid inclusions were trapped between pressures of 800 and 3,400 bars and temperatures between 187&deg; and 214&deg;C. The pressures obtained provide unequivocal evidence that the quartz formed after ore deposition in the Carboniferous because such high fluid pressures could only have been produced from thrust loading during the Mesozoic Brookian orogeny. The observed large variation in pressure is best explained by transient fluid pressures from hydrostatic to lithostatic conditions during thrust loading. The 3,400 bars pressure corresponds with about 12 km of lithostatic burial, whereas the lower pressures (800 bars) correspond with about 8 km of hydrostatic pressure. Because of their low salinity (0-5 wt % NaCl equiv) the electrolyte compositions of the quartz fluid inclusions do not constrain their origin.

Alaska↗