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Geology topics

C.E. Barker

Publications and source records attributed to C.E. Barker.

At least 37 records · Page 2Linked to original sources
USGS1995

Diagenesis of Upper Carboniferous rocks in the Ouachita foreland shelf in mid-continent USA: an overview of widespread effects of a Variscan-equivalent orogeny

Diagenesis of Upper Carboniferous foreland shelf rocks in southeastern Kansas took place at temperatures as high as 100-150?? C at a depth of less than 2 km. High temperatures are the result of the long distance (hundreds of kilometers) advection of groundwater related to collisional orogeny in the Ouachita tectonic belt to the south. Orogenic activity in the Ouachita area was broadly Late Carboniferous, equivalent to the Variscan activity of Europe. Mississippi Valley-type Pb-Zn deposits and oil and gas fields in the US midcontinent and elsewhere are commonly attributed to regional groundwater flow resulting from such collisional events. This paper describes the diagenesis and thermal effects in sandstone and limestone of Upper Carboniferous siliciclastic and limestone-shale cyclothems, the purported confining layer of a supposed regional aquifer. Diagenesis took place in early, intermediate, and late stages. Many intermediate and late stage events in the sandstones have equivalents in the limestones, suggesting that the causes were regional. The sandstone paragenesis includes siderite cement (early stage), quartz overgrowths (intermediate stage), dissolution of feldspar and carbonates, followed by minor Fe calcite, pore-filling kaolinite and sub-poikilotopic Ca ankerite (late stage). The limestone paragenesis includes calcite cement (early stage); megaquartz, chalcedony, and Fe calcite spar (intermediate stage); and dissolution, Ca-Fe dolomite and kaolinite (late stage). The Rm value of vitrinite shows a regional average of 0.6-0.7%; Rock-Eval TmaX suggests a comparable degree of organic maturity. The Th of aqueous fluid inclusions in late stage Ca-Fe-Mg carbonates ranges from 90 to 160?? and Tmice indicates very saline water (>200000 ppm NaCl equivalent); ??18O suggests that the water is of basinal origin. Local warm spots have higher Rm, Tmax, and Th. The results constrain numerical models of regional fluid migration, which is widely viewed as an artesian flow from recharge areas in the Ouachita belt across the foreland basin onto the foreland shelf area. Such models must account for heating effects that extend at least 500 km from the orogenic front and affect both supposed aquifer beds and the overlying supposed confining layer. Warm spots indicate either more rapid or more prolonged flow locally. Th and Tmice data show the highest temperatures coincided with high salinity fluids. ?? 1995 Springer-Verlag.

Geologische Rundschau↗
USGS1995

The minimal response to contact metamorphism by the Devonian Buchan Caves Limestone, Buchan Rift, Victoria, Australia

A 2.2 m thick, Late Eocene (?) dike that intruded the Devonian Buchan Caves Limestone, near Murrindal, Victoria, has produced a narrow contact aureole only centimeters wide in the adjacent host rock. Mean solid bitumen reflectance ranges from about 2.4 to 2.7% and shows little change up to 6 m away from the dike contact. Carbon and oxygen isotope values also show little change except at the dike contact. The most detectable response of the rock to contact metamorphism is the proportion of solid bitumen grains with finely granular mosaic structure increase towards the dike. Also under cathodoluminescence (CL) excitation, the host rock is initially observed to be recrystallized to a uniform bright orange color. By 1 cm away from the contact, however, CL shows preservation of sharp boundaries in finely zoned burial cements. A regional study of thermal maturation and a geothermometer based on solid bitumen reflectance indicate paleotemperatures near 200°C were widespread in the Buchan Rift during peak burial near the time of the Devonian Tabberabberan Deformation. The lack of response of the Buchan Caves Limestone to contact metamorphism is attributed to: (1) prior heating to near 200°C; and (2) the fact that the dike intruded into cool, near surface, low-porosity rocks which may have been in the vadose zone.

eastern Victoria↗
USGS1993

Coalbed methane potential of the Upper Cretaceous Mesaverde and Meeteetse formations, Wind River Reservation, Wyoming

The environments of deposition of the uppermost part of the Cody Shale and the Mesaverde and Meeteetse Formations of Late Cretaceous age were studied on outcrop in the Shotgun Butte area in the north-central part of the Wind River Reservation. A shoreface sandstone occurs in the lower part of the Mesaverde Formation at all localities studied, and is directly overlain by a coaly interval. Repetitive coarsening-upward cycles of mudstone, siltstone, and sandstone occur in the 200 ft interval of the upper part of the Cody Shale below the shoreface sandstone. These Cody sandstones are typically hummocky cross stratified with symmetrical ripples near the top, indicating that they are largely storm surge deposits that were later reworked. Channel-form sandstones from 10 to 20 ft thick, with abundant locally derived clayey clasts, occur in a 75 ft thick interval below the shoreface at one locality. These unusual sandstones are largely confined to a narrow area of the outcrop and grade laterally into more typical storm surge deposits. They may be unusually large storm surge channels created when high-energy flow conditions were localized to a limited area of the shelf. The Mesaverde Formation above the shoreface sandstone is divided into a middle member and the Teapot Sandstone Member. The lower part of the middle member is everywhere coaly. Erosional-based sandstones in this coaly interval are highly variable in thickness and architecture. Thin, single channel sandstone bodies were deposited by moderate to high sinuosity streams, and thick, multistory channel sandstone bodies were deposited by rapidly switching fluvial channel systems that remained relatively stationary for extended periods of time. The architecture of the fluvial channel sandstones in the overlying noncoaly interval appears to be highly variable as well, with complex multistory sandstones occurring at different stratigraphic levels at different localities. This distribution may be explained by long term stability of fluvial channel systems followed by major avulsion events. The Teapot Sandstone Member consists of fairly persistent to lenticular white multistory sandstone units that are as much as 85 ft thick and contain trough cross beds as much as 5 ft high. These sandstone units are interbedded with gray mudstones and carbonaceous shales. Paleosols are preserved at the tops of individual sandstones in the multistory units in some places. It is suggested that these sandstones were deposited largely by low-sinuosity to braided streams. The Meeteetse Formation consists of alternating coal and sandstone-rich intervals. The coal-rich intervals have relatively thin fluvial channel sandstones probably deposited by medium to high sinuosity streams whereas the sand-rich intervals have thick (to 105 ft) multistory fluvial channel sandstones possibly deposited by low-sinousity to braided streams.

Conference Paper↗
USGS1991

Implications for organic maturation studies of evidence of a geologically rapid increase and stabilization of vitrinite reflectance at peak temperature: Cerro Prieto geothermal system, Mexico

A short-term rapid heating and cooling of the rock in well M-94 below 1300 m was caused by a pulse of hot water passing through the edge of the Cerro Prieto, Mexico, geothermal system. Below 1300 m, the peak paleotemperatures were about 225-250 degrees C, but equilibrium well log temperatures indicate a decrease to 150-210 degrees C at present. This hot water pulse sharply increased vitrinite reflectance to levels comparable to those measured in the central part of the system, even though studies of apatite fission-track annealing indicate that the duration of heating was only 10{0}-10{1} yr in M-94, in contrast to 10{3}-10{4} yr in the central part of the system. These data indicate that sedimentary organic matter chemically reacts quickly to temperature increases of about 125 degrees C above ambient, even when the higher temperature existed for only 10{0}-10{1} yr. The quick change of the vitrinite reflectance geothermometer indicates that thermal maturation reactions can stabilize, after a geologically short period of heating, to a level consistent with peak temperature under moderate to high-temperature diagenesis in open, fluid-rich, geothermal systems. Cerro Prieto is one of the most intensively studied and well-known geothermal systems in the world. Thus, data from Cerro Prieto are a benchmark to compare with the predictions of published thermal maturation models such as those formulated by J. Karweil, N. V. Lopatin, and A. K. Burnham and J. J. Sweeney. These thermal maturation models inaccurately predict duration of heating at Cerro Prieto. The kinetic equations used in these models explicitly allow thermal maturation to continue indefinitely at peak temperature, which does not seem to be the case at Cerro Prieto.

Cerro Prieto fault↗
USGS1990

Fluid-inclusion technique for determining maximum temperature in calcite and its comparison to the vitrinite reflectance geothermometer

Theory, laboratory experiments, and empirical observation suggest that many aqueous fluid inclusions in calcite reequilibrate during overheating, and therefore some homogenization temperatures ( T h ) record a temperature close to the maximum reached by the rock. This characteristic suggests that aqueous fluid inclusions in calcite can be used to establish maximum temperature ( T peak ). To test this hypothesis, we have compiled fluid inclusion T peak , mean random vitrinite reflectance ( R m ), and present-day T peak from 46 diverse geologic systems that have been at T peak from 10 4 to 10 6 yr. Present T peak ranged from 65 to 345 °C, T h modes and means ranged from 59 to 350 °C, and R m data ranged from 0.4% to 4.6%, spanning the temperature and thermal maturity range associated with burial diagenesis, hydrothermal alteration, and low-grade metamorphism.

Geology↗
USGS1989

Kinky vitrinite reflectance well profiles: Evidence of paleopore pressure in low-permeability, gas-bearing sequences in Rocky Mountain foreland basins

Vitrinite reflectance (R m ) profiles of wells drilled in abnormally pressured, low-permeability gas-bearing sequences in Rocky Mountain foreland basins are commonly nonlinear with two or more nonparallel segments. These kinky profiles are most likely due to perturbations of the thermal gradient caused by contrasting heat transfer processes associated with the development of abnormally high pressures. We interpret the intersection of the shallow and intermediate R m segments to mark the approximate original boundary between normal-pressured, water-bearing rocks and underlying overpressured gas- and water-bearing rocks. The intersection of the intermediate and deep R m segments marks the approximate original boundary between overpressured gas- nd water-bearing rocks and underlying overpressured gas-bearing rocks. However, because overpressuring is a transient condition that eventually evolves into normal pressuring or underpressuring, these intersections may not coincide with the present top of abnormal pressuring. These segmented R m profiles occur in several Rocky Mountain basins of the United States and Canada.

Alberta, Colorado, Wyoming↗
USGS1988

Fluid inclusions in vadose cement with consistent vapor to liquid ratios, Pleistocene Miami Limestone, southeastern Florida

Vadose cements in the Late Pleistocene Miami Limestone contain regions with two-phase aqueous fluid inclusions that have consistent vapor to liquid (V-L) ratios. When heated, these seemingly primary inclusions homogenize to a liquid phase in a range between 75°C and 130°C (mean = 100° C ) and have final melting temperatures between −0.3° and 0.0°C. The original distribution of T h was broadened during measurements because of fluid inclusion reequilibration. The narrow range of T h in these fluid inclusions suggest unusually consistent V-L ratios. They occur with small, obscure, single phase liquid-filled inclusions, which infer a low temperature origin (less than 60°C), and contradict the higher temperature origin implied by the two phase inclusions. The diagenetic environment producing these seemingly primary fluid inclusions can be inferred from the origin of the host calcite enclosing them. The δ 18 O composition of these cements (−4 to−5.5%., PDB) and the fresh water in the fluid inclusions are consistent with precipitation from low-temperature meteoric water. The carbon-isotope composition of the vadose cements that contain only rare two-phase fluid inclusions are comparable to the host rock matrix (δ 13 C between 0 and +4%., PDB). Cements that contain common two-phase fluid-inclusions have a distinctly lighter carbon isotopic composition of −3 to −5%.. The carbon isotope composition of cements that contain common two-phase inclusions are about 6%. lighter than those of other vadose cements; models of early meteoric diagenesis indicate that this is the result of precipitation from water that has been influenced by soil gas CO 2 . Our hypothesis is that the primary fluid inclusions, those with consistent V-L ratios and the single-phase liquid inclusions, form at near-surface temperature (25°C) and pressure when consistent proportions of soil gas and meteoric water percolating through the vadose zone are trapped within elongate vacuoles. This study corroborates that T h measurements on two phase inclusions in vadose cements can be misleading evidence of thermal diagenesis, even if the measurements are well grouped.

Geochimica et Cosmochimica Acta↗
USGS1983

Influence of time on metamorphism of sedimentary organic matter in liquid-dominated geothermal systems, western North America

Temperature ( T in °C) and mean vitrinite reflectance ( R m in %) of sedimentary organic matter samples from six liquid-dominated geothermal systems plot about a line approximated by a regression equation of the form R m = 0.435 exp 0.00683 T . The reflectance data from these systems are strongly temperature-dependent, with a coefficient of determination ( r 2 ) of 0.8. Geologic evidence indicates that reaction duration ranges from 10 3 or 10 4 to 10 6 yr in these systems that appear to have near-maximum temperatures. The uncertainty in vitrinite reflectance and temperature determinations must account for a large part of the remaining variability not explained by the regression equation; therefore, the strong temperature dependence of R m indicates that after about 10 4 yr, reaction duration has little or no influence on metamorphism of organic matter in liquid-dominated geothermal systems. These data indicate that vitrinite reflectance can be used to determine the maximum temperature reached in hot sedimentary basins of moderate longevity.

Geology↗
USGS1983

A surface vitrinite reflectance anomaly related to Bell Creek oil field, Montana, U.S.A.

Vitrinite reflectance measurements from surface samples of mudrock and coal show anomalously high values over the Bell Creek oil field. The average vitrinite reflectance (Rm) increases to a maximum of 0.9 percent over the field against background values of about 0.3 percent. The Rm anomaly coincides with a geochemical anomaly indicated by diagenetic magnetite in surface rocks and a geobiologic anomaly indicated by ethane-consuming bacteria. These samples were taken from the Upper Cretaceous Hell Creek and Paleocene Fort Union Formations which form an essentially conformable sequence. The depositional environment is similar in both formations, and we expect little variation in the source and composition of the organic matter. The surface R m should be approximately constant because of a uniform thermal history across the field. Temperature studies over local oil fields with similar geology suggest the expected thermal anomaly would be less than 10?C (50?F), which is too small to account for the significantly higher rank over the field. Coal clinkers are rare in the vicinity of Bell Creek and an Rm anomaly caused by burning of the thin, discontinuous coal seams is unlikely. The limited topographic relief, less than 305 m (1,000 ft), over the shallow-dipping homoclinal structure and the poor correlation between Rm and sample locality elevation (r = -0.2) indicate that the Rm anomaly is not due to burial, deformation and subsequent erosion. We conjecture that activity by petroleum-metabolizing bacteria is a possible explanation of the Rm anomaly. Microseepage from oil reservoirs supports large colonies of these organisms, some of which can produce enzymes that can cleave hydrocarbon side-chains on the kerogen molecule. The loss of these side chains causes condensation of the ring structures (Stach and others, 1982) and consequently increases its reflectance. These data indicate that vitrinite reflectance may be a useful tool to explore for stratigraphic traps in the Powder River Basin. Further, the large variation of R across the Bell Creek area suggests that vitrinite reflectance data from surface samples should be interpreted with caution.

Open-File Report↗