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C.E. Barker

Publications and source records attributed to C.E. Barker.

At least 19 recordsLinked to original sources

The influence of extractable organic matter on vitrinite reflectance suppression: A survey of kerogen and coal types

The vitrinite reflectance suppression literature shows that while bitumen impregnation of the vitrinite group is often invoked as a significant contributor to suppression, its existence is not often supported by petrological evidence. This study examines bitumen impregnation as a factor in vitrinite suppression by comparing the vitrinite reflectance of source rock and coal samples before and after solvent-extraction. Bitumen, often defined as organic matter soluble or extractable in certain organic solvents, should be removed by Soxhlet method solvent extraction using chloroform. Removing the extractable bitumen should restore the suppressed reflectance to its true higher value. However, the solvent extracted samples averaged 0.014% Rv less than that of the unextracted samples. We conclude from these results and from other published data that reflectance suppression by bitumen impregnation in the vitrinite maceral group, above the huminite stage of gelification, is seemingly a rare phenomenon and whose effect on suppressing vitrinite reflectance is typically negligible. ?? 2006.

International Journal of Coal Geology

Coalbed gas in the Mecsek Basin, Hungary

Information about the presence and recovery of coalbed gas during underground mining and attempts to recover the gas as an energy source, plus new data about gas storage capacity, petrography, maturity, and other coal quality factors, indicate that the coals of the Mecsek Basin may contain large quantities of coalbed gas that is largely methane. Two preliminary estimates of the total gas content of the coalfield are 0.28e+11 m3 (almost 1 trillion cubic feet) and 1.13e+11 m3 (nearly 4 trillion cubic feet). Although much more information is needed about gas contents, permeabilities and other reservoir factors, the available geologic information may be sufficient to identify target areas for exploration. Efforts required to evaluate production potential are warranted. ?? 2003 Elsevier Science B.V. All rights reserved.

International Journal of Coal Geology

Depositional sequence stratigraphy and architecture of the cretaceous ferron sandstone: Implications for coal and coalbed methane resources - A field excursion

This Field Excursion will visit outcrops of the fluvial-deltaic Upper Cretaceous (Turonian) Ferron Sandstone Member of the Mancos Shale, known as the Last Chance delta or Upper Ferron Sandstone. This field guide and the field stops will outline the architecture and depositional sequence stratigraphy of the Upper Ferron Sandstone clastic wedge and explore the stratigraphic positions and compositions of major coal zones. The implications of the architecture and stratigraphy of the Ferron fluvial-deltaic complex for coal and coalbed methane resources will be discussed. Early works suggested that the southwesterly derived deltaic deposits of the the upper Ferron Sandstone clastic wedge were a Type-2 third-order depositional sequence, informally called the Ferron Sequence. These works suggested that the Ferron Sequence is separated by a type-2 sequence boundary from the underlying 3rd-order Hyatti Sequence, which has its sediment source from the northwest. Within the 3rd-order depositional sequence, the deltaic events of the Ferron clastic wedge, recognized as parasequence sets, appear to be stacked into progradational, aggradational, and retrogradational patterns reflecting a generally decreasing sediment supply during an overall slow sea-level rise. The architecture of both near-marine facies and non-marine fluvial facies exhibit well defined trends in response to this decrease in available sediment. Recent studies have concluded that, unless coincident with a depositional sequence boundary, regionally extensive coal zones occur at the tops of the parasequence sets within the Ferron clastic wedge. These coal zones consist of coal seams and their laterally equivalent fissile carbonaceous shales, mudstones, and siltstones, paleosols, and flood plain mudstones. Although the compositions of coal zones vary along depositional dip, the presence of these laterally extensive stratigraphic horizons, above parasequence sets, provides a means of correlating and defining the tops of depositional parasequence sets in both near-marine and non-marine parts of fluvial-deltaic depositional sequences. Ongoing field studies, based on this concept of coal zone stratigraphy, and detailed stratigraphic mapping, have documented the existence of at least 12 parasequence sets within the Last Chance delta clastic wedge. These parasequence sets appear to form four high frequency, 4th-order depositional sequences. The dramatic erosional unconformities, associated with these 4th-order sequence boundaries, indicate that there was up to 20-30 m of erosion, signifying locally substantial base-level drops. These base-level drops were accompanied by a basin ward shift in paleo-shorelines by as much as 5-7 km. These 4th-order Upper Ferron Sequences are superimposed on the 3rd-order sea-level rise event and the 3rd-order, sediment supply/accommodation space driven, stratigraphie architecture of the Upper Ferron Sandstone. The fluvial deltaic architecture shows little response to these 4th-order sea-level events. Coal zones generally thicken landward relative to the mean position of the landward pinch-out of the underlying parasequence set, but after some distance landward, they decrease in thickness. Coal zones also generally thin seaward relative to the mean position of the landward pinch-out of the underlying parasequence set. The coal is thickest in the region between this landward pinch-out and the position of maximum zone thickness. Data indicate that the proportion of coal in the coal zone decreases progressively landward from the landward pinch-out. The effects of differential compaction and differences in original pre-peat swamp topography have the effect of adding perturbations to the general trends. These coal zone systematics have major impact on approaches to exploration and production, and the resource accessment of both coal and coalbed methane.

Brigham Young University Geology Studies

A comparison of vitrinite reflectance measurements made on whole-rock and dispersed organic matter concentrate mounts

A comparison of mean-random vitrinite reflectance (R(v-r)) values calculated from measurements on polished whole-rock and on concentrates of dispersed organic matter (DOM) mounts of the same samples generally show little difference. Compared to measurements on DOM mounts, R(v-r) measurements by the same microscopist on corresponding whole-rock samples are up to a few tenths of a percent lower over the range of 0.6-3.2% R(v-r) and have a slightly higher standard deviation. Whole-rock mounts have an advantage over DOM mounts in the identification of first-cycle vitrinite and differentiation of solid bitumen from vitrinite.

Conference Paper

The minimal response to contact metamorphism by the Devonian Buchan Caves Limestone, Buchan Rift, Victoria, Australia

A 2.2 m thick, Late Eocene (?) dike that intruded the Devonian Buchan Caves Limestone, near Murrindal, Victoria, has produced a narrow contact aureole only centimeters wide in the adjacent host rock. Mean solid bitumen reflectance ranges from about 2.4 to 2.7% and shows little change up to 6 m away from the dike contact. Carbon and oxygen isotope values also show little change except at the dike contact. The most detectable response of the rock to contact metamorphism is the proportion of solid bitumen grains with finely granular mosaic structure increase towards the dike. Also under cathodoluminescence (CL) excitation, the host rock is initially observed to be recrystallized to a uniform bright orange color. By 1 cm away from the contact, however, CL shows preservation of sharp boundaries in finely zoned burial cements. A regional study of thermal maturation and a geothermometer based on solid bitumen reflectance indicate paleotemperatures near 200°C were widespread in the Buchan Rift during peak burial near the time of the Devonian Tabberabberan Deformation. The lack of response of the Buchan Caves Limestone to contact metamorphism is attributed to: (1) prior heating to near 200°C; and (2) the fact that the dike intruded into cool, near surface, low-porosity rocks which may have been in the vadose zone.

eastern Victoria