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At least 19 recordsLinked to original sources

Rodent repellency

In the course of studies involving more than 2,500 chemical repellents, it has been found that certain groups of- compounds containing nitrogen or sulfur are repellent to rats under the , test conditions and it appears probable that some of these compounds might be used for the protection of packaged goods against rodent attacks. Additional tests to determine optimum methods of application will be necessary before final evaluation of these compounds will be possible and extensive field trials will be required to establish the degree of protection which may be afforded by the use of these materials. Pending such final evaluation, it may be assumed that the results,to date offer a means of selecting the most promising types of'materials for further trial....On the basis of the test data, it appears that some amine derivative, such as a salt of some organic, acid, or a complex with trinitrobenzene or with a metallic salt of a dialkyl dithiocarbamic acid might offer promise of protection of packaging materials against rodent attacks....Protection might be obtained through the use of certain 'physical deterrents' such as plastics, waxes or drying oils.

Modern Packaging

Reproducibility starts at the source: R, Python, and Julia Packages for retrieving USGS hydrologic data

Much of modern science takes place in a computational environment, and, increasingly, that environment is programmed using R, Python, or Julia. Furthermore, most scientific data now live on the cloud, so the first step in many workflows is to query a cloud database and load the response into a computational environment for further analysis. Thus, tools that facilitate programmatic data retrieval represent a critical component in reproducible scientific workflows. Earth science is no different in this regard. To fulfill that basic need, we developed R, Python, and Julia packages providing programmatic access to the U.S. Geological Survey’s National Water Information System database and the multi-agency Water Quality Portal. Together, these packages create a common interface for retrieving hydrologic data in the Jupyter ecosystem, which is widely used in water research, operations, and teaching. Source code, documentation, and tutorials for the packages are available on GitHub. Users can go there to learn, raise issues, or contribute improvements within a single platform, which helps foster better engagement and collaboration between data providers and their users.

Water

Ratingcurve: A Python package for fitting streamflow rating curves

Streamflow is one of the most important variables in hydrology, but it is difficult to measure continuously. As a result, nearly all streamflow time series are estimated from rating curves that define a mathematical relationship between streamflow and some easy-to-measure proxy like water surface elevation (stage). Despite the existence of automated methods, most rating curves are still fit manually, which can be time-consuming and subjective. Although several automated methods exist, they vary greatly in performance because of the non-convex nature of the problem. In this work, we develop a parameterization of the segmented power law that works reliably with minimal data, which could serve operationally or as a benchmark for evaluating other methods. The model, along with test data and tutorials, is available as an open-source Python package called ratingcurve . The implementation uses a modern probabilistic machine-learning framework, which is relatively easy to modify so that others can improve upon it.

Hydrology

Geology and undiscovered resource assessment of the potash-bearing Central Asia Salt Basin, Turkmenistan, Uzbekistan, Tajikistan, and Afghanistan: Chapter AA in Global mineral resource assessment

Undiscovered potash resources in the Central Asia Salt Basin (CASB) of Turkmenistan, Uzbekistan, Tajikistan, and Afghanistan were assessed as part of a global mineral resource assessment led by the U.S. Geological Survey. The term “potash” refers to potassium-bearing, water-soluble salts derived from evaporite basins, where seawater dried up and precipitated various salt compounds; the word for the element “potassium” is derived from potash. Potash is produced worldwide at amounts exceeding 30 million metric tons per year, mostly for use in fertilizers. The term “potash” is used by industry to refer to potassium chloride, as well as potassium in sulfate, nitrate, and oxide forms. For the purposes of this assessment, the term “potash” refers to potassium ores and minerals and potash ore grades. Resource and production values are usually expressed by industry in terms of K 2 O (potassium oxide) or muriate of potash (KCl, potassium chloride). The CASB hosts significant discovered potash resources and originated in an inland sea during Late Jurassic time. Seawater flowed into the CASB, mostly from its extreme northwestern margin near the modern Caspian Sea, during several evaporation episodes that deposited at least five different packages of evaporites, with virtually all potash in the second and fourth packages. In this study, the CASB was subdivided into three tracts (permissive areas) for evaluation: the Amu Darya tract in the west, the Gissar tract in the center, and the Afghan-Tajik tract in the east. The Gissar and Amu Darya tracts were quantitatively assessed, whereas the Afghan‑Tajik tract was only qualitatively assessed because of the commonly extreme depth (as deep as 7 km) of the Jurassic salt, extensive deformation, and a lack of known potash deposits. Two approaches were used to estimate amounts of undiscovered potash in the CASB. Stratabound evaporite deposits in the Amu Darya tract were evaluated using an Adaptive Geometric Estimation (AGE) approach, which estimates in-place potash volumes and tonnages. The Gissar tract was evaluated by using the AGE approach for stratabound deposits and the three-part form of assessment of Singer and Menzie (2005) for discrete halokinetic deposits. In the three-part form of assessment, numbers of undiscovered deposits were estimated and combined with grade and tonnage models to probabilistically forecast the amount of undiscovered potash. The Amu Darya tract is estimated to contain 38 billion metric tons of undiscovered potash as K 2 O by using the AGE approach for stratabound deposits. The hybrid stratabound-halokinetic Gissar tract is estimated to contain between 1 and 16 billion metric tons of undiscovered potash as K 2 O. Chapter 1 of this report provides an overview of the history of the CASB and summarizes evaporite potash deposition, halokinesis, and dissolution processes that have affected the current distribution of potash-bearing salt in the CASB. Chapter 2 describes the Gissar tract, an uplifted region that contains a mix of stratabound and halokinetic potash deposits and all of the discovered and exploited potash deposits of the CASB. Chapter 3 describes the Amu Darya tract, where evaporite deposits remain flat-lying and undeformed since their original deposition. Chapter 4 describes the highly deformed and compressed Afghan-Tajik tract and what is known of the deeply-buried Jurassic salt. Chapter 5 describes the spatial databases included with this report, which contain a collection of CASB potash information. Appendixes A and B summarize descriptive models for stratabound and halokinetic potash-bearing salt deposits, respectively. Appendix C summarizes the AGE method used to evaluate the Gissar and Amu Darya tracts. Appendixes D and E contain grade and thickness data for the Gissar and Amu Darya tracts. Appendix F provides the SYSTAT script used to estimate undiscovered K2 O in a CASB tract. Appendix G provides a potash glossary, and appendix H provides biographies of assessment participants.

Scientific Investigations Report

SiteOpt: An open-source R-package for site selection and portfolio optimization

Conservation planning involves identifying and selecting actions to best achieve objectives for managing natural, social and cultural resources. Conservation problems are often high dimensional when specified as combinatorial or portfolio problems and when multiple competing objectives are considered at varying spatial and temporal scales. Although analytical techniques such as modern portfolio theory (MPT) have been developed to address these complex problems, open source computational platforms for executing these approaches are not readily available. We present a user-friendly R-package called SiteOpt for optimization of binary decisions while explicitly considering environmental or economic uncertainty and the risk tolerance of decision makers. We illustrate the package with spatially-explicit site selection problems (i.e. spatial conservation planning), including an option for divestment (i.e. selling assets), when accounting for future uncertainties in designing conservation areas. The tool is applicable to both spatial and non-spatial problems, such as budget allocation or species selection. Constraints for spatial design and spatial dependencies (e.g. connectivity among sites) can also be specified in SiteOpt. Users can optimize site selection based on two competing objectives by solving for the Nash bargaining solution. Importantly, by quantifying uncertainty and asset spatial correlation, a measure of risk can be included as one such objective to be traded off against portfolio benefits. Thus, SiteOpt can be used to explicitly manage risk in portfolio-based spatial optimization. This tool facilitates decisions in a variety of problem settings, including reserve selection, invasive species management, allocation of law enforcement activities for conservation, budget allocation and asset selection under uncertainty and risk.

Ecography

Tectonostratigraphy and major structures of the Georgian Greater Caucasus: Implications for structural architecture, along-strike continuity, and orogen evolution

Although the Greater Caucasus Mountains have played a central role in absorbing late Cenozoic convergence between the Arabian and Eurasian plates, the orogenic architecture and the ways in which it accommodates modern shortening remain debated. Here, we addressed this problem using geologic mapping along two transects across the southern half of the western Greater Caucasus to reveal a suite of regionally coherent stratigraphic packages that are juxtaposed across a series of thrust faults, which we call the North Georgia fault system. From south to north within this system, stratigraphically repeated ~5–10-km-thick thrust sheets show systematically increasing bedding dip angles (<30° in the south to subvertical in the core of the range). Likewise, exhumation depth increases toward the core of the range, based on low-temperature thermochronologic data and metamorphic grade of exposed rocks. In contrast, active shortening in the modern system is accommodated, at least in part, by thrust faults along the southern margin of the orogen. Facilitated by the North Georgia fault system, the western Greater Caucasus Mountains broadly behave as an in-sequence, southward-propagating imbricate thrust fan, with older faults within the range progressively abandoned and new structures forming to accommodate shortening as the thrust propagates southward. We suggest that the single-fault-centric “Main Caucasus thrust” paradigm is no longer appropriate, as it is a system of faults, the North Georgia fault system, that dominates the architecture of the western Greater Caucasus Mountains.

Geosphere

Sediment contributions from floodplains and legacy sediments to Piedmont streams of Baltimore County, Maryland

Disparity between watershed erosion rates and downstream sediment delivery has remained an important theme in geomorphology for many decades, with the role of floodplains in sediment storage as a common focus. In the Piedmont Province of the eastern USA, upland deforestation and agricultural land use following European settlement led to accumulation of thick packages of overbank sediment in valley bottoms, commonly referred to as legacy deposits. Previous authors have argued that legacy deposits represent a potentially important source of modern sediment loads following remobilization by lateral migration and progressive channel widening. This paper seeks to quantify (1) rates of sediment remobilization from Baltimore County floodplains by channel migration and bank erosion, (2) proportions of streambank sediment derived from legacy deposits, and (3) potential contribution of net streambank erosion and legacy sediments to downstream sediment yield within the Mid-Atlantic Piedmont. We calculated measurable gross erosion and deposition rates within the fluvial corridor along 40 valley segments from 18 watersheds with drainage areas between 0.18 and 155 km 2 in Baltimore County, Maryland. We compared stream channel and floodplain morphology from lidar-based digital elevation data collected in 2005 with channel positions recorded on 1:2400 scale topographic maps from 1959–1961 in order to quantify 44–46 years of channel change. Sediment bulk density and particle size distributions were characterized from streambank and channel deposit samples and used for volume to mass conversions and for comparison with other sediment sources. Average annual lateral migration rates ranged from 0.04 to 0.19 m/y, which represented an annual migration of 2.5% (0.9–4.4%) channel width across all study segments, suggesting that channel dimensions may be used as reasonable predictors of bank erosion rates. Gross bank erosion rates varied from 43 to 310 Mg/km/y (median = 114) and were positively correlated with drainage area. Measured deposition within channels accounted for an average of 46% (28–75%) of gross erosion, with deposition increasingly important in larger drainages. Legacy sediments accounted for 6–90% of bank erosion at individual study segments, represented about 60% of bank height at most exposures, and accounted for 57% (± 16%) of the measured gross erosion. Extrapolated results indicated that first- and second-order streams accounted for 62% (± 38%) of total streambank erosion from 1005 km 2 of northern Baltimore County. After accounting for estimated redeposition, extrapolated net streambank sediment yields (72 Mg/km 2 /y) constituted 70% of estimated average Piedmont watershed yields (104 Mg/km 2 /y). The results suggest that streambank sediments are a relatively large source of sediment from Piedmont tributaries to the Chesapeake Bay.

Maryland

Petrographic and geochemical evidence for the formation of primary, bacterially induced lacustrine dolomite: La Roda 'white earth' (Pliocene, Central Spain)

Upper Pliocene dolomites ('white earth') from La Roda, Spain, offer a good opportunity to evaluate the process of dolomite formation in lakes. The relatively young nature of the deposits could allow a link between dolomites precipitated in modern lake systems and those present in older lacustrine formations. The La Roda Mg-carbonates (dolomite unit) occur as a 3??5- to 4-m- thick package of poorly indurated, white, massive dolomite beds with interbedded thin deposits of porous carbonate displaying root and desiccation traces as well as local lenticular gypsum moulds. The massive dolomite beds consist mainly of loosely packed 1- to 2-??m-sized aggregates of dolomite crystals exhibiting poorly developed faces, which usually results in a subrounded morphology of the crystals. Minute rhombs of dolomite are sparse within the aggregates. Both knobbly textures and clumps of spherical bodies covering the crystal surfaces indicate that bacteria were involved in the formation of the dolomites. In addition, aggregates of euhedral dolomite crystals are usually present in some more clayey (sepiolite) interbeds. The thin porous carbonate (mostly dolomite) beds exhibit both euhedral and subrounded, bacterially induced dolomite crystals. The carbonate is mainly Ca-dolomite (51-54 mol% CaCO3), showing a low degree of ordering (degree of ordering ranges from 0??27 to 0??48). Calcite is present as a subordinate mineral in some samples. Sr, Mn and Fe contents show very low correlation coefficients with Mg/Ca ratios, whereas SiO2 and K contents are highly correlated. ??18O- and ??13C-values in dolomites range from -3??07??? to 5??40??? PDB (mean = 0??06, ?? = 1??75) and from -6??34??? to -0??39??? PDB (mean = -3??55, ?? = 1??33) respectively. Samples containing significant amounts of both dolomite and calcite do not in general show significant enrichment or depletion in 18O and 13C between the two minerals. The correlation coefficient between ??18O and ??13C for dolomite is extremely low and negative (r = -0??05), whereas it is higher and positive (r = 0??47) for calcite. The lacustrine dolomite deposit from La Roda is interpreted mainly as a result of primary precipitation of dolomite in a shallow, hydrologically closed perennial lake. The lake was supplied by highly saturated HCO3-/CO32- groundwater that leached dolomitic Mesozoic formations. Precipitation of dolomite from alkaline lake waters took place under a semi-arid to arid climate. However, according to our isotopic data, strong evaporative conditions were not required for the formation of the La Roda dolomite. A significant contribution by bacteria to the formation of the dolomites is assumed in view of both petrographic and geochemical evidence.

Sedimentology

U-Pb ages of detrital zircons from the Tertiary Mississippi River delta plain in central Louisiana: Insights into sediment provenance

The sources of the tremendous amount of Cenozoic siliciclastic sediment deposited in the Gulf of Mexico region remain debated because of a lack of definitive provenance-identifying characteristics. In an effort to build on prior provenance analysis, we present 101–160 single-grain detrital zircon U-Pb ages for each of 10 outcrop samples from Upper Paleocene to Upper Miocene sandstones from a ∼10,000 km2 swath of central Louisiana corresponding to the ancient Mississippi River Delta, the largest Cenozoic depocenter in the northern Gulf of Mexico region. Sample depositional age control is derived from biostratigraphy and/or regional lithostratigraphic correlation. U-Pb ages in each of the samples range from Cenozoic to Archean, and correspond to the ages of various geologic terranes that underlie the modern Mississippi River drainage basin. However, the prominence of various age distributions changes systematically through the Cenozoic stratigraphy, and pronounced shifts in the abundance of certain age distributions between stratal packages appear to be correlated to shifts in heavy mineral assemblages recorded across the northern Gulf of Mexico coastal plain. Comparison of coastal plain detrital zircon age distributions to age distributions from North American sedimentary cover and the ages of major North American crystalline basement rocks, aided by a sediment mixing model, illuminates the provenance of each of the stratal packages, and suggests that (1) the Mississippi River catchment has resembled its present configuration, at least in the east-west dimension, for much, if not all, of the Cenozoic, and (2) depositional episodes on the Louisiana coastal plain characterized by high sediment supply also corresponded to high proportions of sediment sourcing from the Sevier-Laramide region of the interior western United States. Sediment supply to the Louisiana coastal plain by the paleo–Mississippi River has generally been high during the Cenozoic, except for an anomalous low during the Middle Eocene, when the abundance of sediment derived from the Rocky Mountain region decreased dramatically relative to sediment derived from the Appalachian region.

Louisiana

Deposit model for heavy-mineral sands in coastal environments

This report provides a descriptive model of heavy-mineral sands, which are sedimentary deposits of dense minerals that accumulate with sand, silt, and clay in coastal environments, locally forming economic concentrations of the heavy minerals. This deposit type is the main source of titanium feedstock for the titanium dioxide (TiO 2 ) pigments industry, through recovery of the minerals ilmenite (Fe 2+ TiO 3 ), rutile (TiO 2 ), and leucoxene (an alteration product of ilmenite). Heavy-mineral sands are also the principal source of zircon (ZrSiO 4 ) and its zirconium oxide; zircon is often recovered as a coproduct. Other heavy minerals produced as coproducts from some deposits are sillimanite/kyanite, staurolite, monazite, and garnet. Monazite [(Ce,La,Nd,Th)PO 4 ] is a source of rare earth elements as well as thorium, which is used in thorium-based nuclear power under development in India and elsewhere. The processes that form coastal deposits of heavy-mineral sands begin inland. High-grade metamorphic and igneous rocks that contain heavy minerals weather and erode, contributing detritus composed of sand, silt, clay, and heavy minerals to fluvial systems. Streams and rivers carry the detritus to the coast, where they are deposited in a variety of coastal environments, such as deltas, the beach face (foreshore), the nearshore, barrier islands or dunes, and tidal lagoons, as well as the channels and floodplains of streams and rivers in the coastal plain. The sediments are reworked by waves, tides, longshore currents, and wind, which are effective mechanisms for sorting the mineral grains on the basis of differences in their size and density. The finest-grained, most dense heavy minerals are the most effectively sorted. The result is that heavy minerals accumulate together, forming laminated or lens-shaped, heavy-mineral-rich sedimentary packages that can be several meters and even as much as tens of meters thick. Most economic deposits of heavy-mineral sands are Paleogene, Neogene, and Quaternary in age; some are modern coastal deposits. Superimposed on these basic processes of ore formation are a multitude of contributing and modifying factors, such as the following: Strong, sustained wave action moves sand from offshore to the shore, where the sand and heavy minerals are sorted by size and density. Mineral sorting occurs mainly on the upper part of the hightide swash (wave) zone. Fine-grained sands and heavy minerals on the foreshore can be remobilized by winds, forming heavy mineral-rich sand dunes behind the beach. Longshore drift combined with the geomorphology of the coast exert strong influence on the location of the heavy-mineral sands deposits. Sea level changes are a function of climatic changes, such as ice ages. Rises in regional sea level (transgression) and lowering of sea level (regression) strongly influence the deposition and preservation of heavy-mineral sands. The majority of heavy-mineral sands accumulation appears related to seaward progradation of the shore during regression events. Local faulting may affect the geomorphology of the coast, which controls the distribution of heavy mineral deposition in a coastal basin. Heavy mineral grains appear to weather primarily after their deposition in the coastal plain; this weathering is caused by groundwaters, humic acids, and other intrabasinal fluids. This weathering can enhance the TiO 2 content of ilmenite. Iron is leached from ilmenite during weathering, which thereby upgrades the TiO 2 content of the ilmenite, forming leucoxene. The resulting deposits of heavy-mineral sands can be voluminous. Individual bodies of heavy mineral-rich sands are typically about 1 kilometer wide and more than 5 kilometers long. Many heavy-mineral sands districts extend for more than 10 kilometers and contain several individual deposits that are spread along an ancient or modern strandline. Reported thicknesses of economic deposits range from 3 to 45 meters. Individual ore deposits typically comprise at least 10 megatonnes of ore (the total size of the individual sand-silt body), whose overall heavy-mineral content is 2 to greater than 10 percent. Heavy-mineral sands deposits are relatively easy to mine because they are weakly to poorly consolidated, and they are relatively easy to process. From a geoenvironmental standpoint, mining of heavy mineral-sands generates little or no acid or solubilized metals. However, environmental and human health concerns related to such mining include potential effects on indigenous flora and fauna, effects on local hydrology, and issues related to processing and storing thorium-bearing monazite, owing to its radioactivity. Regional exploration for deposits of heavy-mineral sands can utilize the analyses of stream sediment samples for Ti, Hf, the rare earth elements, Th, and U, and geophysical surveys, particularly radiometric (gamma-ray spectrometry for K, U, and Th) and magnetic methods. Geophysical anomalies may be small, and surveys are generally more successful when conducted close to sources of interest.

Scientific Investigations Report

Insights and strategic opportunities from the USGS 2024 Per- and Polyfluoroalkyl Substances (PFAS) Interagency Workshop

Introduction In 2021, the U.S. Geological Survey (USGS) published Circular 1490 titled, “Integrated Science for the Study of Perfluoroalkyl and Polyfluoroalkyl Substances (PFAS) in the Environment: A Strategic Science Vision for the U.S. Geological Survey” (Tokranov and others, 2021). Circular 1490 was created to be a resource for USGS scientists prioritizing and planning research related to per- and polyfluoroalkyl substances (PFAS) and to be a guide for developing partnerships with other scientists, State and Federal agencies, and stakeholders engaged in PFAS research and management and mitigation of the environmental and human-health effects of PFAS. This USGS PFAS Strategic Science Vision document was intended to be the foundation for a “living strategic vision,” periodically providing updates on the state of USGS PFAS research, emerging PFAS data gaps and needs, and progress on interagency and stakeholder PFAS partnerships and priorities. To meet this objective, the USGS planned to host an Interagency and Stakeholder PFAS Workshop every 2–3 years. During September 10–12, 2024, the USGS hosted the first Interagency and Stakeholder PFAS Workshop in Reston, Virginia. The Workshop brought together experts from other Federal agencies (U.S. Environmental Protection Agency, National Institute of Environmental Health Sciences, Food and Drug Administration, Department of Defense [Air Force, Army]), State agencies (Washington Fish and Wildlife, Virginia Department of Transportation), and academia (Harvard University, University of Maryland) to address key challenges relating to the measurement and modeling of PFAS and the implications for environmental health. Participants engaged in in-depth discussions centered around six pivotal topics related to PFAS: (1) sampling protocols, methods and interpretation; (2) environmental sources, source apportionment, and occurrence; (3) environmental fate and transport; (4) human and wildlife exposure routes and risk; (5) bioconcentration, bioaccumulation, and biomagnification; and (6) ecotoxicology and effects. Each topic had three breakout sessions. A recurrent theme of workshop discussions was how data on a nationwide scale for PFAS occurrence in various environmental matrices, including air, water, food crops, biota, soil, and streambed sediment could help to advance scientific understanding. Participants noted significant geospatial data gaps, particularly in the midwestern and southern United States and the Pacific Northwest. PFAS data collection tends to be more robust along the eastern seaboard and in California. Participants stressed how enhancing the integration of large and small datasets across various agencies could help to support national scale understanding of PFAS. To address these gaps, attendees suggested leveraging datasets from Federal entities like the USGS and the U.S. Department of Defense, State agencies, and municipal utility services to develop predictive contaminant detection and transport models. Improved coordination between water quality programs and USGS research could help to facilitate access to valuable data, leading to comprehensive databases that inform PFAS point (wastewater treatment plants and landfills) and nonpoint (runoff from land, atmospheric deposition, food packaging) sources, environmental transport mechanisms, environmental detection and concentrations, potential exposure routes, and health effects on different biota, including humans. A specific request was made to develop a map demarking the depth of modern (1953 or later) groundwater, which is susceptible to surface-derived anthropogenic (that is, human-made) contamination, based on tritium-age dating. Emphasis was placed on incorporation of hydrology, groundwater flow paths, groundwater–surface water interactions, and landscape factors in predictive statistical models as a step to improve contaminant source identification and tracking. Molecular fingerprinting approaches garnered attention as techniques to link specific PFAS mixtures detected in a sample to environmental sources and levels in biota (Dávila-Santiago and others, 2022). Integrating data from abiotic (that is, water, soil, and air) and biotic (that is, living organisms) systems identified as a research opportunity. For example, understanding the composition of soils and sediments, which include a mixture of mineral, plant, and animal components, could advance understanding of exposure pathways. The discussions highlighted opportunities to explore and understand the potential redistribution and biotic exposures of PFAS from biosolid and wastewater treatment plant effluent land application practices, in addition to atmospheric releases and discharges from landfill and wastewater treatment plants. Participants identified research gaps surrounding how these sources may contribute to contamination and may affect surrounding ecosystems, including a better definition of anthropogenic background concentrations. Moving forward, the collection of co-occurrence data was noted as a means to improve understanding of complex mixtures and to leverage companion modeling efforts focused on areas with high and low contamination levels to identify areas of concern and unaffected resources. Participants emphasized how centralized USGS databases and the establishment of sample-metadata archives can help to ensure that samples are preserved and accessible for future research. In conclusion, the workshop participants identified opportunities to bridge data gaps and improve measurement techniques, modeling frameworks, databases, and communication, to enhance the understanding of PFAS and their effects on environmental and human health. Upon completion of the workshop, participants indicated an interest in developing strategic data collection, modeling, and analytical approaches to address these challenges.

Open-File Report

Development of small uncrewed aerial systems for multi-instrument geophysical data acquisition in active geothermal systems

Small Uncrewed Aerial Systems (sUAS) serve as critical platforms for geophysical data collection at an intermediate scale between lower resolution, regional datasets collected via crewed aerial surveys, and high resolution, but spatially sparse sampling of ground-based data collection methods. Advances in sensor design and sUAS capabilities have led to rapid advances in the amount and type of geophysical data that can be acquired using sUAS-based survey designs (Gavazzi et al., 2019). Here we showcase the utility of a single sUAS (the Matrice 600 Pro and accompanying sensor package) that collects magnetic, thermal infra-red (TIR) and gas (CO2, SO2, H2S, water vapor) data for use in geothermal resource exploration and monitoring, with case studies in eastern California and Iceland. The work highlights the flexibility of modern sUAS systems for single-team acquisition of multiple independent but coupled geophysical data which allow for a multidisciplinary approach to geothermal systems research. We summarize the workflows involved in collecting each dataset as well as several common issues encountered both during data collection and data processing.

Conference Paper

CMGTooL user's manual

During the past several years, the sediment transport group in the Coastal and Marine Geology Program (CMGP) of the U. S. Geological Survey has made major revisions to its methodology of processing, analyzing, and maintaining the variety of oceanographic time-series data. First, CMGP completed the transition of the its oceanographic time-series database to a self-documenting NetCDF (Rew et al., 1997) data format. Second, CMGP’s oceanographic data variety and complexity have been greatly expanded from traditional 2-dimensional, single-point time-series measurements (e.g., Electro-magnetic current meters, transmissometers) to more advanced 3-dimensional and profiling time-series measurements due to many new acquisitions of modern instruments such as Acoustic Doppler Current Profiler (RDI, 1996), Acoustic Doppler Velocitimeter, Pulse-Coherence Acoustic Doppler Profiler (SonTek, 2001), Acoustic Bacscatter Sensor (Aquatec, 1001001001001001001). In order to accommodate the NetCDF format of data from the new instruments, a software package of processing, analyzing, and visualizing time-series oceanographic data was developed. It is named CMGTooL. The CMGTooL package contains two basic components: a user-friendly GUI for NetCDF file analysis, processing and manipulation; and a data analyzing program library. Most of the routines in the library are stand-alone programs suitable for batch processing. CMGTooL is written in MATLAB computing language (The Mathworks, 1997), therefore users must have MATLAB installed on their computer in order to use this software package. In addition, MATLAB’s Signal Processing Toolbox is also required by some CMGTooL’s routines. Like most MATLAB programs, all CMGTooL codes are compatible with different computing platforms including PC, MAC, and UNIX machines (Note: CMGTooL has been tested on different platforms that run MATLAB 5.2 (Release 10) or lower versions. Some of the commands related to MAC may not be compatible with later releases of MATLAB). The GUI and some of the library routines call low-level NetCDF file I/O, variable and attribute functions. These NetCDF exclusive functions are supported by a MATLAB toolbox named NetCDF, created by Dr. Charles Denham . This toolbox has to be installed in order to use the CMGTooL GUI. The CMGTooL GUI calls several routines that were initially developed by others. The authors would like to acknowledge the following scientists for their ideas and codes: Dr. Rich Signell (USGS), Dr. Chris Sherwood (USGS), and Dr. Bob Beardsley (WHOI). Many special terms that carry special meanings in either MATLAB or the NetCDF Toolbox are used in this manual. Users are encouraged to read the documents of MATLAB and NetCDF for references.

Open-File Report

High-resolution sequence stratigraphy of lower Paleozoic sheet sandstones in central North America: The role of special conditions of cratonic interiors in development of stratal architecture

Well-known difficulties in applying sequence stratigraphic concepts to deposits that accumulated across slowly subsiding cratonic interior regions have limited our ability to interpret the history of continental-scale tectonism, oceanographic dynamics of epeiric seas, and eustasy. We used a multi-disciplinary approach to construct a high-resolution stratigraphic framework for lower Paleozoic strata in the cratonic interior of North America. Within this framework, these strata proved readily amenable to modern sequence stratigraphic techniques that were formulated based on successions along passive margins and in foreland basins, settings markedly different from the cratonic interior. Parasequences, parasequence stacking patterns, systems tracts, maximum flooding intervals, and sequence-bounding unconformities can be confidently recognized in the cratonic interior using mostly standard criteria for identification. The similarity of cratonic interior and foreland basin successions in size, geometry, constituent facies, and local stacking patterns of nearshore parasequences is especially striking. This similarity indicates that the fundamental processes that establish shoreface morphology and determine the stratal expression of retreat and progradation were likewise generally the same, despite marked differences in tectonism, physiography, and bathymetry between the two settings. Our results do not support the widespread perception that Paleozoic cratonic interior successions are so anomalous in stratal geometries, and constitute such a poor record of time, that they are poorly suited for modern sequence stratigraphic analyses. The particular arrangement of stratal elements in the cratonic interior succession we studied is no more anomalous or enigmatic than the variability in architecture that sets all sedimentary successions apart from one another. Thus, Paleozoic strata of the cratonic interior are most appropriately considered as a package that belongs in a continuum of variable stratigraphic packages reflecting variable controls such as subsidence and shelf physiography. Special conditions of exceptionally slow subsidence rate, shallow bathymetry, and nearly flat regional shelf gradient are manifest mostly by the presence of individual systems tracts of relatively long duration that extend for much greater distances across depositional strike than those that characterize successions deposited in more dynamic tectonic and physiographic settings. These results suggest that if other cratonic interior successions are as anomalous as reported, a low sediment supply may have played a primary role in development of their apparently condensed stratal architecture. The results also lead us to suggest that a nonvegetated lower Paleozoic landscape played a relatively insignificant role in the development of what are commonly perceived to be enigmatic stratigraphic features of sheet sandstones, particularly their widespread yet thin geometry, and a scarcity of shale and siltstone. ?? 2007 Geological Society of America.

Geological Society of America Bulletin

User’s Guide to planetary image analysis and geologic mapping in ArcGIS Pro

Geologic maps are valuable tools in planetary science. Though planetary geologic maps are similar to terrestrial (Earthbased) geologic maps, the nature of planetary exploration introduces unique challenges for geologic mappers. Terrestrial geologic mappers prepare products from field-based observation, often comparing or refining those with aerial and (or) orbital images. Planetary geologic mapping relies almost exclusively on remote observations, which are made by orbiting spacecraft. Therefore, with a few exceptions for locations with rovers, landers, or crewed surface missions, planetary geologic mappers are not able to observe their map area in detail or at smaller scales. As a result, they must interpret and describe their map features differently than those used in terrestrial geologic maps. For example, terrestrial geologic mappers commonly divide units by lithology (rock type) or grain size. However, planetary geologic mappers often do not have detailed enough information to know what type of rock or grain size is present, and instead must divide the planet’s surface into geologic units using differences in tone, color, and surface texture (at multiple scales). Cross-cutting relationships, where apparent, can provide excellent—and often crucial—observations for identifying and subdividing geologic units using orbital datasets. The process of creating planetary maps has evolved over time, from original hand-drawn maps created during the early 1800s through the late 1900s, to the fully digital products created today. Modern-day planetary geologic mapping uses Geographic Information Systems (GIS) software and tools to visualize data, delineate units and landforms, and accurately convey spatial relationships to a map user using cartographic features represented by points, lines, and polygons. This tutorial was written to familiarize both new and experienced planetary geologic mappers with ArcGIS Pro, a commonly used GIS software package developed by Esri. This tutorial introduces new planetary geologic mappers to fundamental concepts and best practices in planetary geologic mapping. For mappers with experience using ArcMap (a previous version of ArcGIS), this tutorial will help to familiarize users with new changes in layout and functionality, so current projects may be migrated into the ArcGIS Pro environment. No prior knowledge is required, although a general familiarity with geology, GIS, and planetary science is recommended. This tutorial includes links to helpful glossaries of common GIS terms and other GIS and planetary science resources in appendix 1. For additional information on planetary geologic mapping, see the U.S Geological Survey (USGS) Astrogeology NASA Planetary Geologic Mapping Program website and the Planetary Mapping Guidelines. Numerous ArcGIS tutorials are also available from Esri’s Tutorials page, through the Esri Academy catalog, and Esri’s ArcGIS Pro Resources page.

Techniques and Methods

Photomosaics and logs associated with study of West Napa Fault at Ehlers Lane, north of Saint Helena, California

The West Napa Fault has previously been mapped as extending ~45 kilometers (km) from northern Vallejo to southern Saint Helena, California, dominantly running along the western edge of Napa Valley. A zone of fault strands (some previously unmapped) along a ~15-km section of the fault ruptured during the 2014 magnitude 6.0 South Napa earthquake, illustrating the need for further investigation of this little-studied structure. Based on light detection and ranging (lidar) topography and field examination, the fault zone likely extends an additional 10 km or more northward past Saint Helena. In this vicinity, geomorphology suggests two fault strands, one along the range front and another associated with a line of rounded hills that rise 5–10 meters above the middle of the valley. In 2017, we excavated two trenches across an apparent fault scarp on the east side of one elongate hill near Ehlers Lane north of Saint Helena. Examination of the walls revealed three main sedimentary packages. The oldest package, weakly lithified alluvial fan gravels with local sand and silt layers, is tilted 25°–35° to the west. Overlying these tilted strata are two younger sets of strata. On the west side, underlying the crest of the scarp, are alluvial fan gravels with local sand and silt lenses, potentially tilted a few degrees to the west. On the east side, deposited against the scarp, are much finer grained (dominantly fine sand to silt) subhorizontal fluvial strata, likely overbank deposits from the Napa River. We obtained age control on the two younger units through a combination of radiocarbon, infrared-stimulated luminescence, and obsidian hydration dating, establishing that they are latest Pleistocene to modern in age. Although there are no prominent unconformities within the alluvial fan sediments, sample dating indicates there are two generations, one in the 10–20 thousand year (ka) age range and one in the <3 ka age range. Owing to a general lack of well-defined laterally continuous alluvial fan units, it is difficult to distinguish contacts between the two generations except in the immediate proximity of dated samples. The river sediments approximately span the Holocene. No faults were apparent in either trench, indicating that any fault related to the observed surface deformation has not ruptured to the surface at this site during the Holocene and is likely blind.

California

Abandonment of the Upper Devonian Greenland Gap Group and Scherr Formation and revision of the Upper Devonian Brallier and Foreknobs Formations in the central Valley and Ridge Province

This study revises the lithostratigraphic framework of the Upper Devonian interval traditionally assigned to the Greenland Gap Group across the central Appalachian Valley and Ridge Province. The work aims to modernize and standardize lithostratigraphic nomenclature, establish a new reference section and demonstrate how the revised stratigraphy improves edge-matching of 1:24,000 scale geologic maps and supports compilation mapping at scales of 1:100,000 and larger. The revision eliminates the names Greenland Gap Group, Scherr Formation and the Minnehaha Springs Member of the Scherr Formation; reassigns all strata previously designated as Scherr Formation by Dennison (1970) to the upper Brallier Formation; and abandons the basal Mallow Member of the Foreknobs Formation, placing its strata within the upper Brallier as originally defined by Butts (1918). The contact between the Brallier and Foreknobs formations is placed at the base of the first mappable, ridge-forming package of fine- to coarse-grained, cross-bedded, sandstone beds, often containing rounded quartz pebbles with minor interbeds of shale and siltstone. This contact may be gradational in places but, even in absence of good exposure, can usually be distinguished topographically in recently produced lidar-derived imagery as having elevated relief due to the presence of more resistant, compositionally mature coarse-grained sandstone-rich strata. Applying this criterion for mapping the contact between the Brallier and Foreknobs formations has resulted in reconciliation of mismatches of geologic contacts along several 7.5-minute quadrangle boundaries in the states of Virginia, West Virginia, Maryland and Pennsylvania. A new reference section at Baker, West Virginia showcases the contacts between the Harrell Shale, Brallier Formation, Foreknobs Formation and Hampshire Formation. A digital outcrop model of the reference section is provided for future preservation.

Maryland, Pennsylvania, Virginia, West Virginia

Strain partitioning in southeastern Alaska: Is the Chatham Strait Fault active?

A 1200 km-long transform plate boundary passes through southeastern Alaska and northwestern British Columbia and represents one of the most seismically active, but poorly understood continental margins of North America. Although most of the plate motion is accommodated by the right-lateral Queen Charlotte–Fairweather Fault (QCFF) System, which has produced at least six M > 7 earthquakes since 1920, seismic hazard ass essments also include the Chatham Strait Fault (CSF) as a potentially active, 400 km-long strike slip fault that cuts northward through southeastern Alaska, connecting with the Eastern Denali Fault. Nearly the entire length of the CSF is submerged beneath Chatham Strait and Lynn Canal and has never been systematically imaged using high-resolution marine geophysical approaches. In this study we present an integrated analysis of new marine seismic reflectiondata ac quired across Lynn Canal and tectonic block modeling constrained by data from continuous and campaign GPS sites. Seismic profiles cross the CSF at twelve locations spanning ∼50 km of fault length; they reveal thick (up to 300 m) packages of glaciomarine sedimentary facies emplaced on an unconformity su rface that formed during the Last Glacial Maximum (LGM). Localized warping of post-LGM stratigraphy (∼13.9 kyr B.P. to present) appears to correlate with sediment drape on basement topography and current-controlled deposition. There is no evidence for an active fault along the axis of Lynn Canal in the seismic reflection data. Crustal block models constrained by GPS data allow, but do not require, a maximum slip rate o f 2–3 mm/yr along the CSF; higher slip rates on the CSF result in significant misfit to GPS data in the surrounding region. Based on the combined marine geophysical and GPS observations, it is plausible that the CSF has not generated resolvable coseismic deformation in the last ∼13 ka and that the modern slip-rate is <1 mm/yr. We propose that models for strain transfer between the QCFF and the Denali Fault, and seismic hazard maps in general, may need to be reevaluated.

Alaska