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Reduction of red bed sedimentary rocks in connection with energy metal ore formation: A case study from the Sinbad seep, Mesa County, Colorado

The Paradox Basin’s Sinbad seep is a modern analog for ancient bleaching of red bed sediments by introduced alkaline, reducing brines. This bleaching, involving reductive alteration of former red beds, is essential ground preparation that enables the altered rocks to trap Cu, U, and V from later oxidized fluids, forming ore deposits. Study of Sinbad thus offers insights into these metallic mineralization processes in the Paradox and other sedimentary basins. The Sinbad seep occurs where shallow groundwater interacts with organic-rich petroleum source rocks, flows up a fault, and discharges into Salt Creek. Ratios of Na/Cl, Na/Br, and Cl/Br, plus high sulfate concentrations, indicate that the salinity of the seep water originated from dissolution of halite and gypsum during topographically driven flow of meteoric water across a diapir of the Pennsylvanian Paradox Formation, rather than from deep basinal brines. In contact with the organic-rich shales of the Paradox, these SO 4 -rich waters become reduced through bacterial reduction, producing H 2 S. The waters react with red beds of the Permian Cutler Formation, causing pervasive bleaching. The bleaching at Sinbad is characterized by iron-conservative reduction of ferric iron in diagenetic hematite and detrital ilmenite and magnetite to Fe sulfides. The ferrous iron is retained in these sulfides likely as sorbed Fe. Associated alteration includes precipitation of quartz and feldspar overgrowths, partial dissolution of detrital quartz and feldspar caused by pressure solution, formation of clay and authigenic rutile, and precipitation of carbonate and gypsum. The Fe sulfides rapidly degenerate to a mixture of jarosite and iron oxides on weathering at the surface. Among the major-oxide elements and most trace elements, there is no statistical difference between unbleached and bleached samples. The exceptions are uranium and sulfur, which are somewhat greater in bleached samples. Fission track radiography illuminates that uranium is preferentially concentrated in iron oxide cements, iron sorbed into detrital clasts, and finely disseminated iron oxide in illite cement in bleached samples. A leaching experiment suggests that uranium may be more easily available for mobilization from rocks that have undergone bleaching alteration, making them potential U sources. In addition, bleached rocks form effective traps for U, V, and some Cu mineralization.

Colorado

Tracing metal sources and groundwater flow paths in the Upper Animas River watershed using rare earth elements and stable isotopes

Groundwater flow paths and processes that govern metal mobility and transport are difficult to characterize in mountainous bedrock watersheds. Despite the difficulty in holistic characterization, conceptual understanding of subsurface hydrologic and geochemical processes is key to developing remediation plans for locations affected by acid mine drainage, such as the Upper Animas River watershed in southwestern Colorado, USA. Stable isotopes of water and rare earth elements were utilized to evaluate groundwater flow and metal sources within this complex catchment. Stable isotope samples collected from draining mine adits and springs display systematic spatial variation wherein sample sites at higher elevations have greater seasonal variability than sites at lower elevations. The Upper Cement Creek watershed, where multiple draining mines are present, displays the lowest seasonal variation in stable isotopic signatures, potentially indicating the presence of a large, well-mixed volume of groundwater storage or interbasin groundwater flow. Rare earth elements display statistically significant variation between different alteration styles in the catchment. Overprinting of regional propylitic alteration is evident based on enrichment of middle rare earth elements in acidic springs and mines that are not spatially associated with surficial exposures of acid generating alteration styles. Europium anomaly and middle rare earth enrichment signatures from two flooded mine tunnels on opposite sides of a watershed divide indicate connections to the same subsurface flooded mine workings.

Colorado

Review: The hydrogeology of critical mineral resources relevant to the energy transition

Attaining the goals of the international treaty on climate change (the Paris Agreement) will greatly increase the demand for the critical minerals required to implement clean-energy technologies. This poses both challenges and opportunities to the hydrogeologic community from several perspectives. Here, important insights that the hydrogeological sciences have to offer for mineral exploration, mineral production, and addressing environmental issues related to mining and mine decommissioning are summarized. This study focuses on copper, cobalt, lithium, and rare earths to represent the broad spectrum of critical minerals and illustrate their relevance by referring to projected demands and production rates. The current understanding of the hydrogeologic processes that form major deposits of these minerals are then summarized. Ore is defined as the naturally occurring material from which minerals of economic value can be extracted, where most ore deposits are the products of complex hydrogeologic couplings between fluid flow, heat transport, solute transport, chemical reactions, and mechanical deformation. Exploration models for the discovery of deeper, hidden deposits are potentially informed by hydrogeologic theory and hydrogeochemical processes. Hydrogeologic understanding and methods are also essential to production and recovery. Longstanding challenges are mine dewatering and (conversely) mine water supply, as well as mineral-extraction practices such as spoil heap leaching and in situ mining. New challenges arise from element extraction from subsurface brines. Finally, the quantity of water use and potential environmental impacts of mining on water quality are at the core of ‘social license’: the approval and acceptance of society to mining activities.

Hydrogeology Journal

Future water constraints on United States lithium mining under climate change

Lithium is necessary for low-carbon technologies that combat climate change, but lithium extraction is water-intensive. Changes in temperature and precipitation arising from climate change are altering water distribution, which could further strain supplies for new mines and industry, farms, and households. Here we explored how climate change, water use, and mining siting could impact lithium mining in the United States. We analyzed whether there would be sufficient water available to support the single existing and 22 proposed U.S. lithium mines at mid-century under four socioeconomic-climate scenarios and five climate models. Though dependent on socioeconomic-climate scenario, climate model, and lithium deposit type, available water supply in most subbasins would likely be unable to support new mines’ water demands, or even non-mining water demands from other sectors. Water scarcity could hinder the ability of the United States to produce enough lithium to meet domestic demand thereby necessitating higher imports.

conterminous United States

Uranium—Deposits, production and resources, market dynamics, and supply chain risks

Introduction Interest in nuclear power for the generation of electricity has risen with the increase in the need for more diverse baseload power, enhanced energy security, and the development of new technologies, such as small modular reactors (SMRs), which could provide power for remote areas, industrial applications, and artificial intelligence (AI) data centers. In 2024, the U.S. Department of Energy received $2.7 billion in congressional funding to bolster the domestic uranium production and nuclear fuel supply chain and address reliance on imports from foreign suppliers. In 2025, the U.S. Government issued several Executive and Secretary’s orders aimed at revitalizing the U.S. nuclear sector. If SMRs are to be as widely deployed in the United States and worldwide as envisioned, demand for uranium (nuclear reactor fuel) will likely increase. After the Fukushima nuclear accident in 2011, the market spot price of uranium began a decline, followed by a decrease in U.S. and global uranium exploration and mine development expenditures that led to a uranium supply deficit until 2020, when prices started to recover, prompting a resurgence in uranium exploration and development. In January of 2024, the uranium spot price rose to a 17-year high $106 (U.S. dollars) per pound of U3O8 (triuranium oxide, commonly known as “yellowcake”), which is expected to increase uranium exploration, mine development, and uranium production domestically and worldwide.

Fact Sheet

Vegetation cover and composition in environments surrounding uranium mines in the Grand Canyon ecosystem, Northern Arizona

Mining uranium from breccia-pipe deposits in the greater Grand Canyon region has occurred since the mid-1900s. However, possible ecosystem contamination with harmful levels of radionuclides may have occurred due to mining activities in the 21st century. In response, a 20-year Federal moratorium on new mining claims in the Grand Canyon watershed was initiated in 2012, to allow time to evaluate the potential effects of uranium exploration and mining on human health, wildlife, and water resources. This moratorium, nor the 2023 designation of the “Baaj Nwaavjo I’tah Kukveni–Ancestral Footprints of the Grand Canyon National Monument,” precludes operation or development of mining claims predating 2012. Vegetation is a core ecosystem component that may be affected by uranium mining (for instance, through uptake and storage of radionuclides from the air or soil) or may act as a vector of exposure to wildlife, livestock, and humans (for instance, via their consumption of contaminated plant tissues). To provide baseline information about the plant communities associated with uranium mines in the Grand Canyon region, the U.S. Geological Survey surveyed an approximately 200-meter-wide buffer surrounding four breccia-pipe deposits, each in a unique stage of mine development, and at one reference area (a livestock water tank) that underwent ground disturbance but contains no mineral deposits. We sectioned the buffer zones into 0.65–4.52 hectare plots, within which we (1) inventoried all plant species, (2) measured percent cover of plant species, plant functional groups, and ground surface types (dark cyanobacteria, lichen, moss, bedrock, rock, embedded litter, duff, plant bases, and bare soil) using line-point intercept, and (3) measured length and frequency of gaps between perennial plant canopies using canopy gap intercept. We found that plant composition at the mines and the reference area differed from one another but were all characteristic of expected regional vegetation patterns. We provide this data summary as potential baseline information for future research and management efforts.

Arizona

The geology of Canadian potash: A critical mineral for feeding the world

Potash, potassium-bearing water-soluble salt, is the primary global economic source of potassium. Potash is recognized as a critical mineral in Canada as it is the largest source of potassium used in fertilizers. It is essential for global agricultural productivity and food security. Canada is the world’s largest potash exporter with vast deposits in the widely mined Prairie Evaporite of Saskatchewan, which formed in the epicontinental Elk Point Basin during the Middle Devonian. Potash is also found in the Windsor Group of Atlantic Canada where it formed in a series of tectonically active basins during the Mississippian that have undergone substantial post-depositional subsurface alteration and deformation. Potash deposits were mined in New Brunswick up until 2016. Both deposits are salt giants, recording times in the geologic record of extensive and long-lasting evaporite genesis under arid conditions in restricted seas. This paper reviews the geological and economic significance of Canadian potash, including (1) the genesis of each deposit, (2) diagenetic, erosional, and tectonic modification, and (3) exploration and mining in each basin. Underdeveloped regions, possible undiscovered resources, environmental considerations, and the importance of sustainable practices in light of climate change and socioeconomic risks are also addressed.

Facets

Ages and trace element fertility of porphyry-related mineralization in the Philipsburg polymetallic district, Montana, with a comparison to Butte

The Philipsburg mining district is a Mo-Cu porphyry system with associated Cordilleran polymetallic veins. Geochronology was employed to date the porphyry (~66 Ma, U/Pb in zircon) and molybdenite mineralization from the veins (~76 Ma, Re-Os). Age results suggest that the two-mineralization events model proposed by Lund et al. (2018) for the Butte district can be applied to the Philipsburg deposit. Furthermore, common fertility indicators from zircon trace elements were analyzed with variable success to characterize the existing Mo-Cu mineralization of the Philipsburg porphyry. This raises concerns about the benefits of this method and/or the importance of sampling, which could impact exploration for similar porphyry deposits.

Montana

Rare earth elements on the Moon

Rare earth elements (REEs) are a scarce but vital resource for our modern economies and lifestyles. Since the late 1990s, China has supplied the vast majority of the world’s refined REEs. Increasing global demand has broadened the search for REE deposits to unconventional places, including the Moon. Although most lunar rocks have very low REE concentrations, Apollo samples showed that one type of lunar rock containing potassium (K), REEs, and phosphorus (P)—known by the acronym KREEP—has high concentrations of REEs. Data from orbiting satellites have identified locations where substantial deposits of KREEP are likely. The viability of mining these deposits depends on the evolution of REE economics, the development of the Earth-Moon infrastructure, and the findings from future lunar mineral exploration missions.

Fact Sheet

Combining scanning electron microscopy, X-ray diffraction, and X-ray fluorescence to characterize shear zones at the Pogo gold deposit, Alaska

This study employs a multi-method analytical approach to characterize the mineralogical, geochemical, and textural properties of fault rocks from the Pogo gold mine in the Yukon-Tanana Upland, central Alaska. Specifically, we examine cataclasites, to document the structural and geochemical evolution of shear zones and their associations with gold mineralization. To investigate the shear zone, we integrate portable X-ray fluorescence (pXRF), scanning electron microscopy-based automated mineralogy (SEM-AM), X-ray diffraction (XRD), and high-resolution micro-X-ray fluorescence (micro-XRF) mapping. These methods collectively provide insights into bulk and trace element chemistry, mineralogical composition, and deformation-related textures across multiple scales. Handheld pXRF enables rapid geochemical screening, guiding SEM-AM and XRD analyses to ensure consistent mineralogical interpretation. X-ray diffraction identifies and quantifies crystalline phases, while SEM-AM produces high-resolution mineral maps, revealing mineral abundances, grain-scale textures, and gold associations. Micro-XRF mapping further refines our understanding by showing visual trace element distributions at sub-millimetre resolution. By integrating these techniques, we improve our understanding of the nature and geochemistry of Pogo shear zones, their role in gold mineralization, and support metallurgical processing strategies. This approach enhances exploration models and resource characterization for structurally complex gold deposits.

Alaska

Production of mineral commodities and geospatial map of the mineral industries and related infrastructure of China

As part of the U.S. Geological Survey’s (USGS) mission to distribute global mineral information and analyze supply chains, this study provides a comprehensive review of the global significance of China’s mineral production and capacity in 2023. Of 77 mineral commodities in the USGS dataset, China produced 74 and was the world’s first-ranked producer for 39 of the 74. Compared to the high share of global mineral production, including up to 98 percent of global gallium production, the country’s share of global mineral reserves was relatively small, ranging from 20 percent (zinc ore) to 52 percent (tungsten ore). China’s imports of metal ores, slag, and ash accounted for 64 percent of global imports of such commodities by value. The country’s exports of base metals and articles of base metal accounted for 17 percent of the global exports. To help nongeographic information system users assess the spatial distribution of mineral mines, processing facilities, and ports for trades in China, this study created a geospatial (also called “georeferenced”) portable document format (GeoPDF) map. In addition, the GeoPDF contains mineral resource tracts (such as antimony, copper, potash, coal, and oil and gas), exploration sites, and energy infrastructure based on the preexisting USGS data.

Open-File Report

Earth Mapping Resources Initiative protocols—Sampling hard-rock mine waste and perpetual mine water sources

Supporting the overarching goal to evaluate critical minerals nationwide, the mine waste characterization effort in the U.S. Geological Survey (USGS) Earth Mapping Resources Initiative has created a series of protocols to standardize sampling carried out under this effort by the participating State geological surveys and their cooperators. The protocols are based on published, reviewed methods that can be deployed in the field. The protocols include (1) collecting and processing composite samples of mine and mill waste, including tailings, waste rock, gangue, heap leach piles, ore stockpiles, slag, or other mineralized and processed materials and (2) collecting and preserving water samples from perpetual or long-term mine water sources. The protocols also specify information to document on field sheets and detail the collection of geospatial data. The analytical methods used by the USGS and USGS contract laboratories are described in this report, including the data delivery pathway for USGS-derived data.

Scientific Investigations Report

Critical minerals in mine waste

Introduction Critical minerals are commodities with vulnerable supply chains that play a vital role in supporting the United States’ economy, national defense and security, emerging technologies, and energy independence. The prosperity of our Nation depends on generating a resilient supply of domestic critical minerals; mine waste may be an untapped source of these commodities. Mine waste from centuries of legacy mining persist on the landscape and may contain critical minerals and other valuable commodities previously deemed uneconomic to recover. At modern mines, the financial viability of recovering byproduct critical minerals, which are not the primary target, may be marginal and can ultimately destine them to mine waste. Further, mine waste can be a liability for the mining company or, at legacy mines, the taxpayer because of its effect on the landscape. The U.S. Geological Survey (USGS) has several initiatives to evaluate critical mineral resources in various types of waste. This factsheet highlights studies of mine waste carried out by USGS scientists at the Geology, Energy & Minerals Science Center in collaboration with other science centers funded through the USGS Mineral Resources Program. Recovery of critical minerals from mine waste can aid in remediation efforts and increase domestic supply of vital mineral resources.

Fact Sheet

Footprints of past mining in Alaska (USA) derived from high-resolution satellite imagery

Mapping the land area used for mining in the past is essential for guiding the remediation of affected landscapes and assessing the resource potential of related waste products. Despite significant recent progress delineating footprints of active and inactive mining globally, the known inventory of such mine lands remains incomplete. Here, I describe a new map dataset of footprints of land surface disturbance and waste at sites of past mining in Alaska (USA) based on visual interpretation of satellite imagery. This dataset maps 6–14 times the area of previous regional and global mine footprint maps in Alaska and is the first in the region to explicitly delineate mine waste landforms (e.g., tailings piles). The data are publicly available from the U.S. Geological Survey under a “no rights reserved” Creative Commons (CC0) license agreement.

Alaska

Drone-based radiometric surveys provide high-resolution mine waste characterization

Airborne radiometric surveys use passive geophysical techniques to characterize geochemical variations at or near earth’s surface. These methods have been used for a variety of mapping applications, including mineral resource evaluation. However, detailed characterization of smaller geologic targets, including mine waste features, requires flying at lower altitudes and with tighter line spacing than is feasible with traditional aircraft. Here, a small uncrewed aircraft system (sUAS) equipped with a radiometric sensor was used to acquire high-resolution gamma-spectrometry over small mine waste features and a low-grade stockpile in southwestern New Mexico. The sUAS radiometric system mapped local variability within each survey area and revealed ~2–10 m wide zones where radioelements K, Th, and U may be elevated 2–10× the surrounding material. Additionally, the sUAS radiometric data revealed radioelement variability across survey sites, which correlated reasonably well with variability seen in geochemical samples at each survey site, even though samples collected from individual sites showed high local variability. The sUAS data characterized local heterogeneity within mine waste and other small geologic targets at scales of a few meters to tens of meters, which is not possible with traditional crewed aircraft, and with continuity of coverage that is not possible with ground surveys, thus filling a key gap in geophysical survey spatial resolution.

New Mexico

Estimating the hypothetical endowment of critical minerals and other commodities in porphyry copper mine waste in the Four Corners states, USA

Society is fundamentally dependent upon commodities that are used in end-use products for the aerospace, defense, energy, telecommunication, and transportation sectors, resulting in centuries of mining to supply these commodities and materials. Waste from these mining operations can remain on the landscape indefinitely, but there is a lack of national understanding of the distribution and scale of such waste features. The renewable energy transition will continue to increase demand for critical minerals and will result in increasing volumes of mine waste on the Earth’s surface. Reprocessing mine waste can reduce environmental risks and recover needed commodities to match growing demand for societal growth. Therefore, understanding the approximate abundance of commodities that may be available for recovery within mine waste features can be an important piece of domestic critical mineral supply.

Arizona, Colorado, New Mexico, Utah