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Mapping the resistivity structure of Walker Ridge 313 in the Gulf of Mexico using the marine CSEM method

A marine controlled source electromagnetic (CSEM) campaign was carried out in the Gulf of Mexico to further develop marine electromagnetic techniques in order to aid the detection and mapping of gas hydrate deposits. Marine CSEM methods are used to obtain an electrical resistivity structure of the subsurface which can indicate the type of substance filling the pore space, such as gas hydrates which are more resistive. Results from the Walker Ridge 313 study (WR 313) are presented in this paper and compared with the Gulf of Mexico Gas Hydrate Joint Industry Project II (JIP2) logging while drilling (LWD) results and available seismic data. The hydrate, known to exist within sheeted sand deposits, is mapped as a resistive region in the two dimensional (2D) CSEM inversion models. This is consistent with the JIP2 LWD resistivity results. CSEM inversions that use seismic horizons provide more realistic results compared to the unconstrained inversions by providing sharp boundaries and architectural control on the location of the resistive and conductive regions in the CSEM model. The seismic horizons include: 1) the base of the gas hydrate stability zone (BGHSZ), 2) the top of salt, and 3) the top and bottom of a fine grained marine mud interval with near vertical hydrate filled fractures, to constrain the CSEM inversion model. The top of salt provides improved location for brines, water saturated salt, and resistive salt. Inversions of the CSEM data map the occurrence of a ‘halo’ of conductive brines above salt. The use of the BGHSZ as a constraint on the inversion helps distinguish between free gas and gas hydrate as well as gas hydrate and water saturated sediments.

Louisiana

Characterizing sedimentary organic carbon in a hydrothermal spreading center, the Escanaba Trough

Sediments in critical marine mineral environments are of wide importance due to their preservation of both marine minerals and organic carbon (OC) stocks. However, OC storage and cycling is often overlooked in mineral system studies. This work characterizes sedimentary OC within the Escanaba Trough, a hydrothermal sulfide system off the coast of northern California. By utilizing ROV-based push coring, we collected sediments near and far from high temperature, low temperature, and inactive vents. We applied a multipronged organic geochemical approach, measuring bulk sediment, OC fractions of varying labilities, and biomarkers to tease apart the storage, source, and cycling of OC within this complex system. In contrast to past work indicating a primarily terrestrial source to deeper, Pleistocene sediments, our results suggest a primarily marine source in surface sediments at least 50 m away from active venting. Near active venting, we see evidence of locally produced chemosynthetic OC in addition to the background marine source. This chemosynthetic OC appears to be rapidly remineralized and supports more complex deep-sea food webs compared to hemipelagic sites. Still, the greatest contribution of labile OC was observed at inactive vent sites, which we suggest is due to hydrothermal fluid alteration of more labile OC at actively venting sites. Depending on fluid temperature, hydrothermally altered OC is either preserved in the sediments as petroleum or migrated with fluid flow. Considering inactive sites are those most likely to be targeted by potential mining, we suggest additional studies could verify if these results apply at other sedimented seafloor massive sulfide systems.

California

Editorial: From cold seeps to hydrothermal vents: Geology, chemistry, microbiology, and ecology in marine and coastal environments

This Research Topic compiles contemporary studies on cold seeps, hydrothermal vents, mud volcanoes, and related seafloor features that are associated with focused fluid emissions and the transfer of carbon, other chemical species, and sometimes heat from the geosphere to the ocean. Because these features sometimes tap fluids and gas originating kilometers below the seafloor, they provide an important window into deep processes that are otherwise inaccessible to scientists. At the shallow portion of their journey, migrating fluids nearing the seafloor contribute to a range of unique biological, physical, and chemical processes within the sediments themselves and at the sediment-water interface. Seafloor fluid emissions play a critical role in global biogeochemical cycles, ocean chemistry, and possibly even climate change. Seafloor leakage points often emit hydrocarbon gases (especially methane and CO 2 ) and are sometimes the loci for deposition of seafloor minerals that have economic value. A burgeoning area of research focuses on natural products generated at these features, seeking compounds with potential pharmaceutical or other applications. Multidisciplinary studies have become routine for characterization of seafloor fluid emission sites, attesting to the inseparability of geologic, physical, chemical, and biological processes in these settings. It is increasingly common for researchers to combine in a single research cruise: subbottom imaging and seafloor mapping; porewater and water column geochemistry and gas sampling; sediment retrieval for lithologic, biostratigraphic, and solid phase analyses; and studies of benthic and subseafloor communities at the microbial to macrofaunal scales. This multidisciplinary approach has the advantage of ensuring the spatial and temporal coincidence of surveys and samples, an important factor at highly dynamic seafloor fluid emission sites. In addition, researchers often use remotely operated vehicles (ROVs), autonomous underwater vehicles (AUVs), or human-occupied vehicles (HOVs) to record video of the seafloor, compile photomosaics, collect targeted samples, and survey with high-resolution geophysical near-seafloor systems, providing a degree of detail about seafloor fluid emission sites that is unprecedented compared to most areas of the deep ocean. While rarer, long-term cabled observatories or shorter-term deployments of portable observatories are also used at some loci for seafloor fluid flux and are particularly helpful for capturing temporal variations at these dynamic features. Here we summarize the Research Topic’s contribution to multidisciplinary seafloor emission studies in the categories of cold seeps, mud volcanoes, and hydrothermal vents. Figure 1 shows the geographic distribution of the studies in this Research Topic and key features referred to in this Introduction.

Frontiers in Earth Science

Relating systematic molecular and textural properties of graptolite pyrolyzed via gold tube hydrous pyrolysis: Implications for thermal proxies in lower Paleozoic marine shales

A series of gold tube pyrolysis experiments (72 h, 300–550 °C, 50 MPa) conducted on a graptolite-rich lower Paleozoic marine shale generated pyrolysis residues for a comprehensive evaluation of the molecular and structural variability of three types of graptolite periderm. Organic petrology, Raman spectroscopy, and field emission scanning electron microscopy (FE-SEM) with energy dispersive spectroscopy (EDS) were combined to evaluate the thermal evolution process. The three types of graptolite periderm, namely granular, non-granular, and nodular graptolite, were analyzed by Raman spectroscopy wherein point measurements were obtained after the maceral was identified and the location verified by organic petrology. Distinct thermal evolution pathways among non-granular, granular, and nodular graptolite periderms were recorded. The evolution patterns of the Raman parameters, particularly D1 and G bands, highlight the differences in geochemical composition of the graptolite periderm types and the alteration of molecular structure with increasing thermal maturity. Raman parameters D1 (position of the D1 peak), G-FWHM (full width at half maximum of the G peak), and ratios D1-FWHM/G-FWHM (full width at half maximum of the D1 peak ratioed to G-FWHM) and A D1 /A G (ratio of D1 and G peak intensities) showed effectiveness in assessing thermal maturity. Bireflectance with increasing gold tube pyrolysis temperature followed a hierarchy: non-granular > granular > nodular, reflecting different molecular alignment intensities. Qualitative FE-SEM evaluation showed that fine-grained mineral inclusions (primarily Fe-sulfide as determined via EDS) were associated with the graptolite populations, with granular graptolite containing greater amounts of coarser-grained (e.g., ∼300–1400 nm) mineral inclusions relative to non-granular and nodular graptolite, which contain finer-grained (e.g., ∼100–200 nm) inclusions difficult to resolve with optical microscopy. These findings are investigated to highlight the mechanisms that drive organic matter evolution within graptolite during thermal maturation, as well as to explore some of the limitations of using spectroscopic parameters as thermal maturity proxies.

International Journal of Coal Geology

Confocal laser-scanning microscopy (CLSM)-based thermal maturity of Tasmanites and progress in standardization of fluorescence microspectrometry

Evaluation of thermal maturity in vitrinite-free or vitrinite-deficient sediments via fluorescence microspectrometry can provide relevant information related to petroleum exploration and thermal history assessment. However, variation in spectral fluorescence properties of alginite macerals with increasing thermal maturity is largely underexplored. Here, authors of this study have applied confocal laser-scanning microscopy (CLSM) in conjunction with fluorescence microspectrometry to a maturity series of marine Upper Devonian Tasmanites algae from the Ohio Shale (Huron Member) and a single sample from the Marcellus Formation of the Appalachian Basin. Spectral fluorescence properties of Tasmanites were evaluated in relation to orientation, measurement location, and the number of measurements per sample, and were compared to published literature. Emission spectra of Tasmanites from continuous wave laser excitation (405 nm) were acquired from sections perpendicular and parallel to bedding and at different positions within individual Tasmanites bodies. The results showed a progressive red-shift in emission maxima (λ max ) in a large sample sized maturity series ( N = 19), e.g., 493 to 578 nm for the perpendicular section at middle position. Further, blue-shifted apex and mineral-adjacent positions within sections perpendicular to bedding were observed, with the latter being reported here for the first time. While blue-shift at apex positions can be attributed to mechanical deformation-induced reorientation of photoselected fluorophores, the blue-shifted mineral-adjacent positions could result from strain loading and development of a plastic deformation region at the mineral contact zone with Tasmanites . A decrease in standard deviation with increasing number of measured emission maxima is well-observed, and 15 to 20 individual measurements per sample appears sufficient for low standard deviation and coefficient of variance. CLSM-derived thermal maturity parameters indicated that a moderate positive correlation of red/green quotient (Q 650/500 ; R 2 = 0.67) with solid bitumen reflectance (BR o in %) exists. For reproducible results, the determination of λ max and Q 650/500 should be conducted exclusively in the middle position at perpendicular and parallel sections of the polished whole-rock pellets, where the lowest standard deviation in measurement was observed. These results strengthen the suitability and relevance of the CLSM technique in thermal maturity studies of dispersed organic matter (DOM) and contribute to the standardization of fluorescence microspectrometry methods in organic petrology investigation.

Kentucky, Ohio, Virginia, West Virginia

Deformed submarine terraces in Puget Sound, Pacific Northwest, indicate only one M >~7.5 earthquake on the Seattle fault zone in the past 11,000 yr

Submerged marine terraces in Puget Sound, deformed across the Seattle fault zone (SFZ), indicate that only one earthquake as large as M~7.5 has occurred in at least the past 11 kyr. Previous paleoseismic studies document a M~7.5 earthquake between 923–4 CE, which uplifted coastal marine terraces by as much as 8 m. We demonstrate that this earthquake was the only such event since ~11 ka by mapping and quantifying deformation of older marine terraces, now submerged in Puget Sound. The submerged terraces, attributed to a late-glacial sea-level lowstand, record both glacial isostatic rebound and tectonic deformation. Vertical offset of the ~11 ka terraces within the SFZ is comparable to that of the marine terraces uplifted in 923 CE, implying no additional large (M>~7.5) earthquake on the SFZ since ~11 ka. This result implies a longer recurrence interval than current hazard estimates, which assumes recurrence of M>7.1 events every 5 kyr. Our mapping of SFZ deformation since ~11 ka also supports fault segmentation and contiguous block uplift between the Seattle and Tacoma fault zones.

Washington

Evaluation of solid bitumen created from marine oil shale bituminite under hydrous and anhydrous pyrolysis conditions

To test the influence of environmental conditions on aromaticity of solid bitumen generated during petroleum generation, four organic-rich (26–36 wt% total organic carbon) oil shale samples collected from the Neoproterozoic–Lower Cambrian restricted marine Salt Range Formation in the upper Indus Basin, Pakistan, were pyrolyzed under hydrous and anhydrous conditions. Experiments used closed system batch reactors at subcritical water temperatures between 300 and 370°C for 72 h. Thermal conversion of bituminite in the Salt Range oil shales created a newly formed solid bitumen, similar to previous observations from experiments on the Eocene lacustrine Green River Formation Mahogany zone oil shale. Newly formed solid bitumen in the Salt Range Formation oil shales generally has higher reflectance (R o ) in hydrous residues compared to anhydrous experiments subjected to the same time-temperature conditions, also similar to prior observations. This finding supports the hypothesis that radical disproportionation is favored in the presence of hydrogen contributed by water, promoting aromatization in the solid bitumen residue with concomitant increased expulsion of saturated hydrocarbons. Indigenous solid bitumen (and vitrinite in a comparison sample) also shows higher reflectance values in hydrous versus anhydrous residues, indicating that additional aromatization in the presence of exogenous hydrogen occurs both in newly formed organic matter and in organic matter that is present throughout the experiment. Despite similarities in their bulk rock geochemical screening parameters, R o evolution shows different trajectories amongst the four Salt Range oil shales, suggesting as-yet undetermined differences in kinetic properties which are probably related to differences in a priori chemical composition. These results have implications for the use of solid bitumen reflectance (BR o ) as a thermal proxy, suggesting BR o values and appearance could vary as a function of the concentration of water. Variation in water concentration may be present at the reservoir or formation scale, but may also be present at a much finer scale in tight oil shales where permeability is several orders of magnitude lower than conventional reservoirs. Therefore, local variations in the presence of water potentially could explain substantial variation in BR o values and appearance in closely spaced source rock samples and even within an individual microscope field.

Journal of Analytical and Applied Pyrolysis

Insights on gas hydrate formation and growth within an interbedded sand reservoir from well logging at the Qiongdongnan Basin, South China Sea

Although variable well log resolution and its control on saturation estimation has been studied, it has not been directly applied to a specific location to explore the nature of gas hydrate within a sand reservoir. We applied in-situ measurements of resistivities, neutron porosity, and gamma ray at two sites in the Qiongdongnan Basin, South China Sea (QDN-W05–2021 and QDN-W08–2021) to investigate the reservoir parameters of a hydrate-bearing sand reservoir. Our results show that gas hydrate is distributed in 5 zones with a total thickness of 10.7 m and an average saturation of 69% at the QDN-W05–2021 site, while they are distributed in 2 zones with a total thickness of 4.3 m and an average saturation of 49% at the QDN-W08–2021 site. We found that variances in saturations estimated from lateral-extra deep button (RX), phase shift (P40H-P40L), and attenuation (A40H-A40L) resistivities within the laterally mapped continuous sand body were affected by the nature of gas hydrate occurrences. Results indicate gas hydrate forms and accumulates at the center of the sand layer and tends to be less or not present toward the top and base. Integrated with seismic data, the in-situ measurements provide insights in the evolution of a mushroom-shaped, hydrate-gas reservoir system. In the system, free gas is likely horizontally transported from the top-center of the gas chimney to the surrounding areas in the early stage dominated by a warm-gas environment, whereas hydrate forms in the opposite pathway starting from the surrounding areas in the following stage with temperature reducing. Our study suggests that high-resolution in-situ measurements not only are a tool to identify the physical properties, but also can be used to help explain the physical process of hydrate growth and accumulation.

Marine Geology

The Sedimentary Geochemistry and Paleoenvironments Project Phase 2 data release: An open data resource for the study of Earth's environmental history

Geochemical data from sedimentary rocks are the primary source of information regarding Earth's surface evolution through time, including its air and water envelopes and interactions with life and deep Earth processes. The Sedimentary Geochemistry and Paleoenvironments Project (SGP) is a scientific consortium centered around open data and community-driven development of cyberinfrastructure tools and resources for sedimentary geochemistry and Earth history. Here we describe the SGP Phase 2 data release, which focused on incorporating Paleoproterozoic and Mesoproterozoic (2500–1000 million years ago) data and better accommodating carbonate data. This data release was built through the involvement of >200 researchers worldwide in academia, government, and industry, and provides the largest available public data resource for our user community in the academic fields of geochemistry, sedimentology, tectonics, paleontology, Earth history, and paleoclimate, as well as the petroleum and minerals industries. The dataset now encompasses 126,006 samples and 4,132,371 geochemical analyses. In addition to direct entry by SGP Team Members, we have ingested and incorporated datasets from the Geoscience Australia OZCHEM database, the Alberta Geological Survey, and the Deep-Time Marine Sedimentary Element Database (DM-SED) compilation. This paper details sampling in the Phase 2 dataset with respect to age, geography, lithology, and other geological characteristics, documents access via our search website and API, discusses possible issues and/or biases in the dataset that could impact analyses, describes plans for governance and stewardship of data from Indigenous lands, and serves as the citable reference paper for the data release.

Chemical Geology

Tracking diagenetic alteration of magnetic susceptibility in thrust ridge and slope basin sediments of the Cascadia margin (ODP Sites 1249 and 1252; IODP Site U1325)

We investigated sediment core records from the Cascadia Margin (Ocean Drilling Program Sites 1249 and 1252 at Hydrate Ridge; Integrated Ocean Drilling Program Site U1325 offshore Vancouver Island) using a Zr/Rb heavy mineral proxy from X-ray fluorescence (XRF) core scanning to identify intervals of primary detrital magnetic susceptibility (κ) and predict intervals where diagenesis caused magnetite dissolution by hydrogen sulfide. We also measured total sulfur (TS) content, grain size distributions, total organic carbon (TOC) content, and the magnetic mineral assemblage to further constrain the role of diagenesis on κ. Understanding how κ can be used to better characterize the varied effects of detrital and diagenetic signals in marine settings is important for understanding biogeochemical cycling and records of paleoenvironmental change. The upper 100 m of slope basin Site 1252 contains multiple intervals (> 90 m total) of decreased κ correlated with elevated TS content, consistent with dissolution of magnetite and precipitation of pyrite, iron monosulfides, and/or elemental sulfur. Similarly at the other slope basin site, Site U1325, κ is lower and TS is elevated in the interval between 24 and 51 mbsf, due to sulfide formation. At both slope basin sites, these low κ intervals correspond with high TOC, suggesting the possibility that organoclastic sulfate reduction (OSR) is likely a major driver of diagenetic alteration of κ at these sites. High TS:TOC ratios at Site U1325 suggests anaerobic oxidation of methane (AOM) during sulfate-methane transition zone (SMTZ) migration may have contributed to alteration of κ. In contrast, within the upper 90 m of Site 1249, a methane seep site at the summit of Hydrate Ridge, κ is almost entirely altered by diagenetic processes, with much of the low κ explained by a high degree of iron sulfide formation, while some intervals are affected by precipitation of magnetic iron sulfides that maintain or even increase κ. The presence of abundant methane seepage and gas hydrate as well as chemosynthetic seafloor fauna at this site, suggests that sulfide is released to the water column and AOM, rather than OSR, drives diagenetic alteration of κ at this site. Overall, the slope basin sites show episodic variation of κ that is influenced by TOC content, likely driven by changes in marine primary productivity and sedimentation rate, while the seep site shows consistently altered κ with lower TS content and no correlation with TOC. Methane seep environments likely experience loss of hydrogen sulfide to the water column and oxidation of hydrogen sulfide by seafloor seep fauna, which limits the amount of solid phase sulfur (pyrite, iron monosulfides, elemental sulfur) that can be precipitated within the sediments. In contrast, the migration of a buried SMTZ at slope basin sites results in enhanced sulfur precipitation within the sediments. This integrated magnetic and geochemical approach reveals the diagenetic production pathway and residence time of sulfide with the sediment column ultimately controls the style and degree of diagenetic loss of κ in marine sediments. This approach works best in environments with unaltered reference intervals/sites, consistent magnetic mineralogy, and clay-to-silt grain sizes.

Cascadia margin, Pacific Ocean

Formation of vertical columnar seismic structures and seafloor depressions by groundwater discharge in the drowned Miami Terrace platform and overlying deep-water carbonates, southeastern Florida

The presence of vertical cross-formational fluid migration passageways within sedimentary basins can profoundly impact aquifer and reservoir fluid-flow and their identification is fundamental to informing management of subsurface fluid resources (groundwater, oil, gas). In an onshore and offshore southeastern part of Florida, 2D/3D seismic-reflection and bathymetry data document ∼153 vertical columnar structures composed of reflection disruptions up to 790 m in the height and averaging 360 m in diameter, and ∼219 subcircular to circular seafloor depressions up to 1334 m wide. Our study focuses on these features found within the offshore shallow-marine carbonate Miami Terrace platform, which drowned approximately at the end of the middle Miocene, and within overlying Plio-Quaternary deep-water carbonate slope and drift deposits. Most columnar structures are rooted in stratiform aquifers of the Miami Terrace platform and associated with faults or fault intersections produced by Eocene and circa late Miocene tectonics. The columns commonly terminate within the platform or as subcircular depressions along an amalgamated karstic and drowning unconformity at the platform top. The columns typically stretch upwards from a zone of deep karst cavity collapse through the Miami Terrace platform with upward decreasing sag on internal reflections. Following drowning and Plio-Quaternary partial burial of the Miami Terrace platform by deep-water deposits, the subcircular depressions and faults along the platform top were points of origin for a second phase of column growth upward into the deep-water deposits. The continuation of deep platform cavity collapse and column evolution produced pockmarks along paleo-seafloors within the deep-water deposits and at the present-day sea floor. The Plio-Quaternary pockmarks formed at water depths too deep to suggest an origin related to meteoric karst above or near sea level, but rather their formation is suggested to be related to cyclic sea level falls that drove increased groundwater head and density gradients, and seafloor discharge of offshore freshened groundwater sourced from the underlying platform. Plausibly, mixing of freshened groundwater and seawater at the seafloor discharge sites drove dissolution of the host deep-water deposits, which together with erosion by groundwater venting and current scouring formed the pockmarks. Seaward of the Plio-Quaternary seafloor pockmarks, at the late-middle Miocene upper slope of the Miami Terrace platform and along the regional karst/drowning unconformity is a slope-parallel band of ∼189 densely distributed subcircular seafloor depressions with diameters up to 1334 m at water depths up to ∼660 m. It is plausible that along the upper slope, faults and fractures produced by gravity-driven slope instability and possibly tectonics formed a dense network of fluid passageways that promoted upward artesian freshened groundwater flow to sites of discharge where mixing with seawater generated limestone dissolution and the depressions. But tectonic uplift may have forced emersion and initial meteoric sinkhole formation circa late Miocene with later enhancement by freshened groundwater discharge and bottom current erosion.

Florida

Seabed maps showing topography, ruggedness, backscatter intensity, sediment mobility, and the distribution of geologic substrates in quadrangle 2 of the Stellwagen Bank National Marine Sanctuary region offshore of Boston, Massachusetts

The U.S. Geological Survey, in cooperation with the National Marine Sanctuary Program of the National Oceanic and Atmospheric Administration, has conducted seabed mapping and related research in the Stellwagen Bank National Marine Sanctuary (SBNMS) region since 1993. The area being mapped using geophysical and geological data includes the SBNMS and the surrounding region, which totals approximately 3,700 square kilometers (km 2 ) and is subdivided into 18 quadrangles. The seabed is a glaciated terrain that is topographically and texturally diverse. Quadrangle 2, the subject of this scientific investigations map, has a mapped area of 209 km 2 and has water depths that range from about 19 meters (m) on the Stellwagen Bank crest to about 68 m in the Stellwagen Basin. Seven map types, each at a scale of 1:25,000, depict seabed topography, ruggedness, backscatter intensity, distribution of geologic substrates, sediment mobility, distribution of fine- and coarse-grained sand, and substrate mud content. These maps show the distribution of geologic substrates across the southwestern part of Stellwagen Bank, in Stellwagen Basin to the west and southwest of the bank, and in Little Stellwagen Basin and the western part of Race Point Channel to the south of the bank. Interpretations of multibeam sonar bathymetric and seabed backscatter imagery, photographs, video imagery, and grain-size analyses were used to create the geology-based maps. Data from 733 stations were analyzed, including 656 sediment samples. The geologic substrate maps of quadrangle 2 show the distribution of 19 geologic substrates that represent a wide range of textures, such as rippled and immobile sand, immobile muddy sand and sandy mud, sand that partially veneers gravel, and a boulder ridge. Mapped substrates are characterized by sediment grain-size composition, surface morphology, substrate layering, the mobility or immobility of substrate surfaces, and water depth range. This scientific investigations map portrays the major geological elements (substrates, topographic features, and processes) of environments in quadrangle 2. It is intended to provide a foundation for research into present and past sediment transport processes in a complex terrain, provide insights into the ecological requirements of invertebrate and vertebrate species that utilize the various substrates, and support seabed management in the region.

Massachusetts

Seabed maps showing topography, ruggedness, backscatter intensity, sediment mobility, and the distribution of geologic substrates in quadrangle 3 of the Stellwagen Bank National Marine Sanctuary region offshore of Boston, Massachusetts

The U.S. Geological Survey, in cooperation with the National Marine Sanctuary Program of the National Oceanic and Atmospheric Administration, has conducted seabed mapping and related research in the Stellwagen Bank National Marine Sanctuary (SBNMS) region since 1993. The area being mapped using geophysical and geological data includes the SBNMS and the surrounding region, which totals approximately 3,700 square kilometers (km 2 ) and is subdivided into 18 quadrangles. The seabed is a glaciated terrain that is topographically and texturally diverse. Quadrangle 3, the subject of this scientific investigations map, has a mapped area of 185 km 2 and has water depths that range from about 30 meters (m) on the Stellwagen Bank crest to about 135 m in a basin east of South Ninety Bank, which lies off the eastern margin of Stellwagen Bank. Seven map types, each at a scale of 1:25,000, depict seabed topography, ruggedness, backscatter intensity, distribution of geologic substrates, sediment mobility, distribution of fine- and coarse-grained sand, and substrate mud content. These maps show the distribution of geologic substrates on the southeastern part of Stellwagen Bank, on adjacent banks and basins in deeper water to the east, in the eastern part of Race Point Channel to the south of the bank, and on the northern slope of Cape Cod. Interpretations of multibeam sonar bathymetric and seabed backscatter imagery, photographs, video imagery, and grain-size analyses were used to create the geology-based maps. Data from 309 stations were analyzed, including 279 sediment samples. The geologic substrate maps of quadrangle 3 show the distribution of 21 geologic substrates that represent a wide range of textures, such as rippled sand, immobile sand, immobile muddy sand, sand that partially veneers gravel, and boulder ridges. Mapped substrates are characterized by sediment grain-size composition, surface morphology, substrate layering, the mobility or immobility of substrate surfaces, and water depth range. This scientific investigations map portrays the major geological elements (substrates, topographic features, and processes) of environments in quadrangle 3. It is intended to provide a foundation for research into present and past sediment transport processes in a complex terrain, provide insights into the ecological requirements of invertebrate and vertebrate species that use the various substrates, and support seabed management in the region.

Quadrangle 3 of the Stellwagen Bank National Marin

Seabed maps showing topography, ruggedness, backscatter intensity, sediment mobility, and the distribution of geologic substrates in quadrangle 5 of the Stellwagen Bank National Marine Sanctuary region offshore of Boston, Massachusetts

The U.S. Geological Survey, in cooperation with the National Marine Sanctuary Program of the National Oceanic and Atmospheric Administration, has conducted seabed mapping and related research in the Stellwagen Bank National Marine Sanctuary (SBNMS) region since 1993. The area being mapped using geophysical and geological data includes the SBNMS and the surrounding region, which totals approximately 3,700 square kilometers (km 2 ) and is subdivided into 18 quadrangles. The seabed is a glaciated terrain that is topographically and texturally diverse. Quadrangle 5, the subject of this scientific investigations map, has an area of 211 km 2 and has water depths that range from 23 meters (m) on the Stellwagen Bank crest to 105 m in the Stellwagen Basin. Seven map types, each at a scale of 1:25,000, depict seabed topography, ruggedness, backscatter intensity, distribution of geologic substrates, sediment mobility, distribution of fine- and coarse-grained sand, and substrate mud content. These maps show the distribution of geologic substrates on the crest and western flank of the south-central part of Stellwagen Bank and in Stellwagen Basin to the west. Interpretations of multibeam sonar bathymetric and seabed backscatter imagery, photographs, video imagery, and grain-size analyses were used to create the geology-based maps. Data from 729 stations were analyzed, including 620 sediment samples. The geologic substrate maps of quadrangle 5 show the distribution of 20 substrates that represent a wide range of textures, such as mobile and rippled sand, immobile sand, sand that partially veneers gravel, boulder ridges, and mud. Mapped substrates are characterized by sediment grain-size composition, surface morphology, substrate layering, the mobility or immobility of substrate surfaces, and water depth range. This scientific investigations map portrays the major geological elements (substrates, topographic features, and processes) of environments in quadrangle 5. It is intended to provide a foundation for research into present and past sediment transport processes in a complex terrain, provide insights into the ecological requirements of invertebrate and vertebrate species that utilize the various substrates, and to support seabed management in the region.

Massachusetts

Integrated stratigraphic and geochemical analysis of organic-rich intervals of the Lewis Shale in the eastern Washakie Basin, Wyoming

Geological studies in the Cretaceous Western Interior Seaway (KWIS) in North America reveal highly variable sedimentological conditions on its western shore caused by rapidly changing sea level and detrital input during the seaway’s closure. Here we examine a 601-foot (183 meters) continuous core through the lower part of the Maastrichtian Lewis Shale in the eastern Washakie Basin, Wyoming, through integrating stratigraphic and geochemical analyses to better understand organic matter deposition and preservation during the final marine transgression within the seaway. The core penetrates eight organic-rich flooding intervals (F1-F8) and a regional condensed section, informally known as the Asquith marker. The lower portions of the core record sediment input from a southern source, likely the Sierra Madre/Park Ranges, while the upper part records sediment input from a northern source, likely the Granite Mountains. This provenance transition is supported by regional stratigraphic analysis and changes in bulk mineral and trace metal composition. The Asquith marker and early flooding surfaces are enriched in oil-prone, marine organic matter deposited under dysoxic to euxinic conditions, whereas younger flooding surfaces show increased terrigenous input and poorer preservation conditions. The Asquith marker is identified as a prime oil-prone source rock. Although younger flooding surfaces also exhibit favorable source-rock properties, their generative potential is reduced due to increased clastic and terrigenous organic matter deposition caused by regression. These results emphasize the importance of sediment source variability, organic matter preservation, and changing redox conditions to provide insight into the sediment provenance and petroleum potential of the Lewis Shale in the context of the final transgression within the KWIS.

Colorado, Wyoming

Hydrogeologic framework and considerations for drilling and grouting of closed-loop geothermal bores in the Erie-Ontario Lowlands and Allegheny Plateau of New York State

The hydrogeologic framework at closed-loop geothermal sites in the Erie-Ontario Lowlands and Allegheny Plateau of central and western New York is the result of the complex interaction of bedrock geology, glacial geology, and groundwater hydrology, and the occurrence of petroleum and gas. Considerations for closed-loop geothermal bore installation include the thickness and character of glacial deposits, bedrock solubility and depth to competent rock, karst development, the distribution of highly permeable zones and their hydraulic heads, and the presence of saline water, gas, and oil. The hydrogeology of the Erie-Ontario Lowlands and Allegheny Plateau poses challenges to closed-loop geothermal bore drilling and casing; managing drill cuttings, discharge water, and gas; and grouting. The potential to encounter severe challenges typically increases with bore depth. This report highlights hydrogeologic considerations for closed-loop geothermal bore installation in New York’s Erie-Ontario Lowlands and Allegheny Plateau to help guide the efficient and safe development of geothermal resources in the regions.

New York

Shallow geologic framework of the Mississippi Sound and the potential for sediment resources

The Mississippi Sound, an estuarine environment located between the mainland and barrier islands bordering the northern Gulf of America (formerly the Gulf of Mexico), serves as a vital ecosystem for the States of Mississippi and Alabama. Spanning approximately 100 kilometers from east to west and covering 1,400 square kilometers, the sound is home to marine industry and ports, and its shallow and brackish waters sustain a diverse array of marine life. Barrier islands along the southern edge of the sound separate the microtidal estuary from the Gulf of America. This protection from gulf wave action mediates current flow within the sound, resulting in predominantly fine-grained sediment deposition along the seafloor. This study, conducted by the U.S. Geological Survey in cooperation with the U.S. Army Corps of Engineers, provides insight on fluvial and tidal processes spanning the past 5,000 years. The report synthesizes existing research to provide a comprehensive overview of the sound geology, from Pleistocene origins to present-day morphology, and utilizes high-resolution single channel seismic profiles and sediment data to identify and map sedimentary deposits and morphologic features at and below the seafloor. Despite its ecological significance, the Mississippi Sound faces environmental challenges, including water-quality issues, habitat degradation, storm-induced erosion, and the ongoing threats of sea-level rise and environmental changes. This study uses the present-day understanding of the sound's geology to inform coastal management decisions, hazard assessment, and potential mineral resources.

Louisiana, Mississippi

Spatial distribution of API gravity and gas/oil ratios for petroleum accumulations in Upper Cretaceous strata of the San Miguel, Olmos, and Escondido Formations of the south Texas Maverick Basin—Implications for petroleum migration and charge history

The Maverick Basin of south Texas is currently undergoing active exploration and production of gas and oil from tight sandstone reservoirs. The most productive tight sandstones in the basin are in the Upper Cretaceous San Miguel, Olmos, and Escondido Formations. These units are second only to the Eagle Ford Shale in terms of cumulative production volumes. The structural history of the Maverick Basin, from rifting to subsidence to exhumation, has had a profound effect on the characteristics of these reservoirs and the petroleum resources contained therein. This U.S. Geological Survey review of the production history of these strata reflects a recent shift from conventional production to horizontal drilling (unconventional) that exploits low permeability reservoirs in previously overlooked areas of existing oil and gas fields in southern Texas, typically outside of established field boundaries. To investigate the physical properties of the Maverick Basin hydrocarbon accumulations, this case study compiled American Petroleum Institute (API) gravity measurements and calculated cumulative gas/oil ratios (GOR) for thousands of producing wells from the San Miguel, Olmos, and Escondido Formations. Maps were generated from the compiled well production data to show the spatial heterogeneity of API gravity and GOR values for the three formations within the Maverick Basin and immediately outside the basin to the northeast. Within the Maverick Basin, the spatial patterns of API gravity values indicate lighter oils downdip towards the southern basin edge. GOR values indicative of wet and dry gases within the basin are seen interspersed, with values that correspond to black and heavy oils. Differences in the spatial patterns of the petroleum properties within the Maverick Basin are interpreted as effects of Eocene basin inversion caused by Laramide orogenic deformation, and the resulting reservoir exhumation of basin strata. East of the Maverick Basin, spatial distributions of API gravity and GOR values show progressively heavier oils updip to the northwest, grading to dry gases downdip to the southeast, which correlates to the oil and gas windows of the underlying Eagle Ford Shale. Correlation of API gravity and GOR values from the San Miguel, Olmos, and Escondido Formations with thermal maturity data from the Eagle Ford Shale suggests that the Eagle Ford Shale is the petroleum source, and that petroleum migration was approximately vertical for areas to the east of the Maverick Basin. The discontinuity of API gravity and GOR properties within the Maverick Basin implies a complex petroleum charge history, possibly involving the remigration of petroleum and the addition of petroleum from other source intervals in Mexico, to the southwest. Depressurization of exhumed, overpressured reservoirs of the San Miguel, Olmos, and Escondido Formations can explain the intermittent occurrence of gas production throughout the southern Maverick Basin by exsolution of gas from formation brines and the resulting dry gas flushing of hydrocarbon-charged reservoirs. The introduction of dry gas through flushing can, in turn, explain why the patterns of API gravity and GOR values are so dissimilar in the Maverick Basin. This process has implications for possible future production of unconventional resources from undiscovered tight-gas reservoirs in strata of the San Miguel, Olmos, and Escondido Formations, and a different approach to petroleum exploration may be needed in the Maverick Basin relative to exploration techniques applied in other basins within the northern Gulf of Mexico.

Texas