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Determining the minimum instream flow for hydro peaking projects

A new analytical technique is available for quantifying and predicting the effect that a proposed hydro peaking operation, or a change in an existing project's operation, will have on physical habitat for aquatic populations downstream of the project. The technique, known as the dual flow analysis, is based on elements of the US Fish and Wildlife Service's Physical Habitat Simulation System (PHABSIM). PHABSIM is used to calculate the physical habitat for aquatic organisms in a stream. The assumption behind the development of this technique is that if the effects of a proposed project on physical habitat are known, one can better understand the effects on aquatic organisms. Thus, a defensible selection of an instream flow requirement can be made. The technique was developed as a result of a joint study by the US Fish and Wildlife Service and Niagara Mohawk Power Corp. at the 26.4-MW Bennetts Bridge and the 7.8-MW Lighthouse Hill developments on the Salmon river in upstate New York.

Hydro Review

Wind-wave climate changes and their impacts

Wind-waves have an important role in Earth system dynamics through air–sea interactions and are key drivers of coastal and offshore hydro-morphodynamics that affect communities, ecosystems, infrastructure and operations. In this Review, we outline historical and projected changes in the wind-wave climate over the world’s oceans, and their impacts. Historical trend analysis is challenging owing to the presence of temporal inhomogeneities from increased numbers and types of assimilated data. Nevertheless, there is general agreement over a consistent historical increase in mean wave height of 1–3 cm yr −1 in the Southern and Arctic Oceans, with extremes increasing by >10 cm yr −1 for the latter. By 2100, mean wave height is projected to rise by 5–10% in the Southern Ocean and eastern tropical South Pacific, and by >100% in the Arctic Ocean. By contrast, reductions in mean wave height up to 10% are expected in the North Atlantic and North Pacific, with regional variability and uncertainty for changes in extremes. Differences between 1.5 °C and warmer worlds reveal the potential benefit of limiting anthropogenic warming. Resolving global-scale climate change impacts on coastal processes and atmospheric–ocean–wave interactions requires a step-up in observational and modeling capabilities, including enhanced spatiotemporal resolution and coverage of observations, more homogeneous data products, multidisciplinary model improvement, and better sampling of uncertainty with larger ensembles.

Nature Reviews Earth & Environment

Estimating basin scale evapotranspiration (ET) by water balance and remote sensing methods

Evapotranspiration (ET) is an important hydrological process that can be studied and estimated at multiple spatial scales ranging from a leaf to a river basin. We present a review of methods in estimating basin scale ET and its applications in understanding basin water balance dynamics. The review focuses on two aspects of ET: (i) how the basin scale water balance approach is used to estimate ET; and (ii) how ‘direct’ measurement and modelling approaches are used to estimate basin scale ET. Obviously, the basin water balance-based ET requires the availability of good precipitation and discharge data to calculate ET as a residual on longer time scales (annual) where net storage changes are assumed to be negligible. ET estimated from such a basin water balance principle is generally used for validating the performance of ET models. On the other hand, many of the direct estimation methods involve the use of remotely sensed data to estimate spatially explicit ET and use basin-wide averaging to estimate basin scale ET. The direct methods can be grouped into soil moisture balance modelling, satellite-based vegetation index methods, and methods based on satellite land surface temperature measurements that convert potential ET into actual ET using a proportionality relationship. The review also includes the use of complementary ET estimation principles for large area applications. The review identifies the need to compare and evaluate the different ET approaches using standard data sets in basins covering different hydro-climatic regions of the world.

Hydrological Processes

Hydro-climatic data network (HCDN): A U.S. Geological Survey streamflow data set for the United States for the study of climate variations, 1874-1988

Records of streamflow can provide an account of climatic variation over a hydrologic basin. The ability to do so is conditioned on the absence of confounding factors that diminish the climate signal. A national data set of streamflow records that are relatively free of confounding anthropogenic influences has been developed for the purpose of studying the variation in surface-water conditions throughout the United States. Records in the U.S. Geological Survey (USGS) National Water Storage and Retrieval System (WATSTORE) data base for active and discontinued streamflow gaging stations through water year 1988 (that is, through September 30, 1988) were reviewed jointly with data specialists in each USGS District office. The resulting collection of stations, each with its respective period of record satisfying the qualifying criteria, is called the Hydro-Climatic Data Network, or HCDN. The HCDN consists of 1,659 sites throughout the United States and its territories, totaling 73,231 water years of daily mean discharge values. For each station in the HCDN, information necessary for its identification, along with any qualifying comments about the available record and a set of descriptive watershed characteristics are provided in tabular format in this report, both on paper and on computer disk (enclosed). For each station in the HCDN, the appropriate daily mean discharge values were compiled, and statistical characteristics, including monthly mean discharges and annual mean, minimum and maximum discharges, were derived. The discharge data values are provided in a companion report.

Open-File Report

Toward a resilience-based conservation strategy for wetlands in Puerto Rico: Meeting challenges posed by environmental change

Designing conservation strategies in human-dominated landscapes is challenging, owing to complex human-natural systems and evolving societal values. To meet this challenge, a robust, adaptive strategy should have a process for flexible implementation of incremental actions. We describe a hypothetical example for the Rio Grande de Arecibo watershed and coastal wetlands in Puerto Rico to address the first component. The process begins by identifying shared stakeholder objectives. This process benefits from a review of foundational research and knowledge base that includes global forcings and vulnerability of resources of interest. Forcings include climate change and pervasive urban sprawl. We focus on two taxonomic groups with differing life histories but strong dependence on water resource dynamics, another resource valued by humans. We stipulate objectives and multiple actions, but focus on those pertaining to hydro-management as the common thread in our example. We advanced two decision contexts of contrasting complexity, illustrated links between objectives and actions, and highlighted trade-offs triggered by varying resource valuation. Our focus was to highlight various components necessary to frame a resilience-based strategy, but we cannot overemphasize the importance of accommodating institutional and stakeholder changing priorities and values to ensure its successful implementation.

Puerto Rico

Drivers of Holocene sea-level change in the Caribbean

We present a Holocene relative sea-level (RSL) database for the Caribbean region (5°N to 25°N and 55°W to 90°W) that consists of 499 sea-level index points and 238 limiting dates. The database was compiled from multiple sea-level indicators (mangrove peat, microbial mats, beach rock and acroporid and massive corals). We subdivided the database into 20 regions to investigate the influence of tectonics and glacial isostatic adjustment on RSL. We account for the local-scale processes of sediment compaction and tidal range change using the stratigraphic position (overburden thickness) of index points and paleotidal modeling, respectively. We use a spatio-temporal empirical hierarchical model to estimate RSL position and its rates of change in the Caribbean over 1-ka time slices. Because of meltwater input, the rates of RSL change were highest during the early Holocene, with a maximum of 10.9 ± 0.6 m/ka in Suriname and Guyana and minimum of 7.4 ± 0.7 m/ka in south Florida from 12 to 8 ka. Following complete deglaciation of the Laurentide Ice Sheet (LIS) by ∼7 ka, mid-to late-Holocene rates slowed to < 2.4 ± 0.4 m/ka. The hierarchical model constrains the spatial extent of the mid-Holocene highstand. RSL did not exceed the present height during the Holocene, except on the northern coast of South America, where in Suriname and Guyana, RSL attained a height higher than present by 6.6 ka (82% probability). The highstand reached a maximum elevation of +1.0 ± 1.1 m between 5.3 and 5.2 ka. Regions with a highstand were located furthest away from the former LIS, where the effects from ocean syphoning and hydro-isostasy outweigh the influence of subsidence from forebulge collapse.

Quaternary Science Reviews

Development of new information to inform fish passage decisions at the Yale and Merwin hydro projects on the Lewis River, Washington—Final report, 2018

The reintroduction of extirpated salmonids to historically occupied areas is becoming increasingly common as a conservation and recovery strategy. Often, reintroductions are implemented after the factors that originally led to species extirpation have been reduced, eliminated, or mitigated. For anadromous Oncorhynchus spp. (Pacific salmon) and O. mykiss (steelhead), addressing barriers to migration, which have been a primary factor in the decline and extirpation of many populations, has been an integral component of recovery efforts. Mitigation has included barrier removal, developing fish passage opportunities, and (or) actively trapping and hauling juvenile and adult anadromous salmonids around barriers. With any reintroduction, there are a number of concerns regarding the ecological impact of the reintroduction efforts. Three of the main tenets to consider when assessing reintroductions are (1) the potential benefits if reintroduction is successful, (2) the biological risk through interactions of reintroduced strains with existing populations, and (3) the factors potentially limiting a successful reintroduction. This report focuses on information and data to address the second and third factors as they apply to the upper Lewis River in Washington. The upper Lewis River historically contained wild populations of O. tshawytscha (Chinook salmon), O. kisutch (coho salmon), and steelhead. These populations were extirpated after completion of hydropower facilities on Lake Merwin in 1932, Yale Lake in 1953, and Swift Reservoir in 1958, which prevented fish from migrating to and from ocean environments. However, recent licenses issued by the Federal Energy Regulatory Commission require the installation and operation of an upstream fish passage facility at Lake Merwin and a downstream fish passage facility at Swift Reservoir. The licenses were developed in consultation with the National Marine Fisheries Service and the U.S. Fish and Wildlife Service. The overarching goal of this fish reintroduction project is to establish viable, self-sustaining, naturally reproducing, harvestable populations of spring Chinook salmon, winter steelhead, and coho salmon at levels higher than minimum viable populations. This report uses a combination of field data and existing information to address six key objectives related to the reintroduction in order to inform decisions about passage at the Yale Lake and Lake Merwin hydropower projects. The objectives are (1) a review of information relevant to anadromous fish reintroduction and full fish passage; (2) a habitat assessment of tributaries to Swift Reservoir, Yale Lake, and Lake Merwin; (3) a field study to assess adult potential for spawning success; (4) an assessment of juvenile production and outmigration success; (5) a Lake Merwin predator impact study; and (6) a set of studies assessing interactions between anadromous and resident fish.

Washington

USGS Hydro-Climatic Data Network 2009 (HCDN-2009)

The U.S. Geological Survey's (USGS) Hydro-Climatic Data Network (HCDN) is a subset of all USGS streamgages for which the streamflow primarily reflects prevailing meteorological conditions for specified years. These stations were screened to exclude sites where human activities, such as artificial diversions, storage, and other activities in the drainage basin or the stream channel, affect the natural flow of the watercourse. In addition, sites were included in the network because their record length was sufficiently long for analysis of patterns in streamflow over time. The purpose of the network is to provide a streamflow dataset suitable for analyzing hydrologic variations and trends in a climatic context. When originally published, the network was composed of 1,659 stations (Slack and Landwehr, 1992) for which the years of primarily "natural" flow were identified. Since then data from the HCDN have been widely used and cited in climate-related hydrologic investigations of the United States. The network has also served as a model for establishing climate-sensitive streamgage networks in other countries around the world. After nearly two decades of use without undergoing a systematic revalidation, questions have arisen as to whether many of the original stations still maintain their climate-sensitive status or even remain operational, as some are known to have closed. Some watersheds had been altered to the point that stations no longer meet the minimal disturbance criteria set forth in the original HCDN report. In addition, some sites that did not qualify as HCDN sites in 1988 (the last year of data evaluation) because their records were too short now have sufficiently long streamflow records for climate-sensitivity studies. Accordingly, a review of the existing network was initiated in 2009 in order to drop old stations and add new ones as appropriate.

Fact Sheet

Epigenetic, diplogenetic, syngenetic, and lithogene deposits

Much of the disagreement over " epigenetic " And " Syngenetic " Deposits Is Semantic; Some Ores And altered rocks are in part syngenetic and in part epigenetic and for them the term " diplogenetic " is proposed. All these terms are primarily time terms related to the contemporaneity of the deposit and the enclosing rock, but in a secondary sense they are space terms; they do not, however, imply process of formation or source of the chemical constituents. Process or source terms such as "magmatic," "hydro-thermal," "sedimentary" are generally satisfactory, but the process term "lateral secretion" is now vague in meaning. A more precise term is needed for the process of mobilization of elements from a solid rock and their transportation and redeposition elsewhere; for this process I propose the term " lithogene " ("stone-born"), to stress the source and process as do "magmatic" and "sedimentary." Such deposits could be derived from syngenetic , diplogenetic , or epigenetic deposits through the action of metamorphic, hydrothermal, supergene or other solutions. If one wishes, however, to emphasize the distance the mobilized elements have moved from the source rock, the resulting deposit can be described best as a locally derived lithogene deposit ("lateral secretion"), or as a regionally derived lithogene deposit ("product of regional metamorphism"). The classification of many deposits such as epigenetic replacement bodies of magnetite in limestone, and syngenetic gold in recent placers is not controversial; however, where large parts of the mineral deposit are made up both of syngenetic elements and introduced elements, the term " diplogenetic " is appropriate. Examples include mineral deposits in which syngenetic cations are united with epigenetic anions, as in fluorite replacements in limestones, or where the reverse relationship holds and epigenetic cations are united to syngenetic sulfur or other anions-as may be true of certain black cupriferous shales of the Mansfeld type. Guides for distinguishing the various types of mineral deposits are discussed at length and include: mineralogy; texture; isotopic composition of hydrogen, carbon, oxygen, sulfur, and perhaps other elements; form; age relations; alteration; zoning; position and quantitative adequacy of supposed source rocks; lithology; structural geology; paleogeography; and regional geologic relations. The criteria developed are used in a critical review of several examples of controversial deposits -including the African Copper-belt deposits and those of the graphitic schists of Fenno-Scandia.

Economic Geology

Aquatic organism passage at road-stream crossings&mdash;synthesis and guidelines for effectiveness monitoring

Restoration and maintenance of passage for aquatic organisms at road-stream crossings represents a major management priority, involving an investment of hundreds of millions of dollars (for example, U.S. Government Accounting Office, 2001). In recent years, passage at hundreds of crossings has been restored, primarily by replacing barrier road culverts with bridges or stream simulation culverts designed to pass all species and all life stages of aquatic life and simulate natural hydro-geomorphic processes (U.S. Forest Service, 2008). The current situation has motivated two general questions: 1. Are current design standards for stream simulation culverts adequately re-establishing passage for aquatic biota? and 2. How do we monitor and evaluate effectiveness of passage restoration? To address the latter question, a national workshop was held in March 2010, in Portland, Oregon. The workshop included experts on aquatic organism passage from across the nation (see table of participants, APPENDIX) who addressed four classes of methods for monitoring effectiveness of aquatic organism passage&mdash;individual movement, occupancy, demography, and genetics. This report has been written, in part, for field biologists who will be undertaking and evaluating the effectiveness of aquatic organism passage restoration projects at road-stream crossings. The report outlines basic methods for evaluating road-stream crossing passage impairment and restoration and discusses under what circumstances and conditions each method will be useful; what questions each method can potentially answer; how to design and implement an evaluation study; and points out the fundamental reality that most evaluation projects will require special funding and partnerships among researchers and resource managers. The report is organized into the following sections, which can be read independently: 1. Historical context: In this section, we provide a brief history of events leading up to the present situation involving aquatic organism passage as a useful context for the issues covered herein. 2. Importance of connectivity for aquatic organisms: In this section, we provide background information regarding the movement characteristics of aquatic organisms and their vulnerability to passage impairment, and the importance of connectivity for a broad diversity of aquatic vertebrates and invertebrates. This section should be useful for practitioners in selecting what species to monitor in relation to aquatic organism passage. 3. Methods for evaluating aquatic organism passage: In this section, we present a range of perspectives on alternatives for assessing and monitoring aquatic organism passage impairment and the effectiveness of passage restoration actions, including the following methods: Individual Movement, Occupancy Models, Abundance (Demography), and Molecular Genetic Markers. 4. Relevance, strengths, and limitations of the four methods: In this section, we discuss the utility of each of the methods as a tool for assessing and quantifying passage impairment and restoration effectiveness. 5. Guidelines for selecting a method: In this section, we review some fundamental criteria and guidelines to consider when selecting a method for monitoring in the context of answering three important questions that should be addressed when developing a plan for evaluating aquatic organism passage. 6. Study and monitoring design considerations: In this section, we discuss four key design elements that need to be considered when developing a monitoring design for assessing passage impairment and restoration. The basic objectives of the report are to: 1. Review the movement characteristics of five groups of aquatic organisms that inhabit streams and to assess their general vulnerability to passage impairment at road-stream crossings; 2. Review four methods for monitoring aquatic organism passage impairment and the effectiveness of actions to restore passage at road-stream crossing structures; 3. Assess the relevance, strengths, and limitations of each method as a monitoring tool; 4. Identify and discuss guidelines that will be useful for selecting a monitoring method; and 5. Discuss what we have identified as the four key elements that need to be considered when developing a monitoring design for assessing passage impairment and restoration at road-stream crossings.

Open-File Report

An evaluation of selected extraordinary floods in the United States reported by the U.S. Geological Survey and implications for future advancement of flood science

Thirty flood peak discharges determine the envelope curve of maximum floods documented in the United States by the U.S. Geological Survey. These floods occurred from 1927 to 1978 and are extraordinary not just in their magnitude, but in their hydraulic and geomorphic characteristics. The reliability of the computed discharge of these extraordinary floods was reviewed and evaluated using current (2007) best practices. Of the 30 flood peak discharges investigated, only 7 were measured at daily streamflow-gaging stations that existed when the flood occurred, and 23 were measured at miscellaneous (ungaged) sites. Methods used to measure these 30 extraordinary flood peak discharges consisted of 21 slope-area measurements, 2 direct current-meter measurements, 1 culvert measurement, 1 rating-curve extension, and 1 interpolation and rating-curve extension. The remaining four peak discharges were measured using combinations of culvert, slope-area, flow-over-road, and contracted-opening measurements. The method of peak discharge determination for one flood is unknown. Changes to peak discharge or rating are recommended for 20 of the 30 flood peak discharges that were evaluated. Nine floods retained published peak discharges, but their ratings were downgraded. For two floods, both peak discharge and rating were corrected and revised. Peak discharges for five floods that are subject to significant uncertainty due to complex field and hydraulic conditions, were re-rated as estimates. This study resulted in 5 of the 30 peak discharges having revised values greater than about 10 percent different from the original published values. Peak discharges were smaller for three floods (North Fork Hubbard Creek, Texas; El Rancho Arroyo, New Mexico; South Fork Wailua River, Hawaii), and two peak discharges were revised upward (Lahontan Reservoir tributary, Nevada; Bronco Creek, Arizona). Two peak discharges were indeterminate because they were concluded to have been debris flows with peak discharges that were estimated by an inappropriate method (slope-area) (Big Creek near Waynesville, North Carolina; Day Creek near Etiwanda, California). Original field notes and records could not be found for three of the floods, however, some data (copies of original materials, records of reviews) were available for two of these floods. A rating was assigned to each of seven peak discharges that had no rating. Errors identified in the reviews include misidentified flow processes, incorrect drainage areas for very small basins, incorrect latitude and longitude, improper field methods, arithmetic mistakes in hand calculations, omission of measured high flows when developing rating curves, and typographical errors. Common problems include use of two-section slope-area measurements, poor site selection, uncertainties in Manning’s n -values, inadequate review, lost data files, and insufficient and inadequately described high-water marks. These floods also highlight the extreme difficulty in making indirect discharge measurements following extraordinary floods. Significantly, none of the indirect measurements are rated better than fair, which indicates the need to improve methodology to estimate peak discharge. Highly unsteady flow and resulting transient hydraulic phenomena, two-dimensional flow patterns, debris flows at streamflow-gaging stations, and the possibility of disconnected flow surfaces are examples of unresolved problems not well handled by current indirect discharge methodology. On the basis of a comprehensive review of 50,000 annual peak discharges and miscellaneous floods in California, problems with individual flood peak discharges would be expected to require a revision of discharge or rating curves at a rate no greater than about 0.10 percent of all floods. Many extraordinary floods create complex flow patterns and processes that cannot be adequately documented with quasi-steady, uniform one-dimensional analyses. These floods are most accurately described by multidimensional flow analysis. Within the U.S. Geological Survey, new approaches are needed to collect more accurate data for floods, particularly extraordinary floods. In recent years, significant progress has been made in instrumentation for making direct discharge measurements. During this same period, very little has been accomplished in advancing methods to improve indirect discharge measurements. Greater use of paleoflood hydrology could fill many shortcomings of U.S. Geological Survey flood science today, such as enhanced knowledge of flood frequency. Additional links among flood runoff, storm structure, and storm motion would provide more insight to flood hazards. Significant improvement in understanding flood processes and characteristics could be gained from linking radar rainfall estimation and hydrologic modeling. Additionally, more could be done to provide real-time flood-hazard warnings with linked rainfall/runoff and flow models. Several important recommendations are made to improve the flood-documentation capability of the U.S. Geological Survey. When very large discharges are measured by current meter or hydroacoustics, water-surface slope should be measured as well. This measurement would allow validation of roughness values that can significantly extend the discharge range of verified Manning’s n for 1-dimensional and 2-dimensional flow analyses. At least two of the floods investigated may have had flow so unstable that large waves affected the interpretation of high-water marks. Instability criteria should be considered for hydraulic analysis of large flows in high-gradient, smooth channels. The U.S. Geological Survey needs to modernize its toolbox of field and office practices for making future indirect discharge measurements. These practices could include, first and foremost, a new peak-flow file database that allows greater description and interpretation of flow events, such as stability criteria in high-gradient, smooth channels, debris flow documentation, and details of flood genesis (hurricane, snowmelt, rain-on-snow, dam failure, and the like). Other modernized practices could include (a) establishment of calibrated stream reaches in chronic flash flood basins to expedite indirect computation of flow; (b) development of process-based theoretical rating curves for streamflow-gaging stations; (c) adoption of step-backwater models as the standard surface-water modeling tool for U.S. Geological Survey field offices; (d) development and support for multidimensional flow models capable of describing flood characteristics in complex terrain and high-gradient channels; (e) greater use of the critical-depth method in appropriate locations; (f) deployment of non-contact instruments to directly measure large floods, rather than attempting to reconstruct them; (g) increased use of paleoflood hydrology; and (h) assurance that future collection of hydro-climatic data meets the needs of more robust watershed models.

Scientific Investigations Report

Wildland fire ash: Production, composition and eco-hydro-geomorphic effects

Fire transforms fuels (i.e. biomass, necromass, soil organic matter) into materials with different chemical and physical properties. One of these materials is ash, which is the particulate residue remaining or deposited on the ground that consists of mineral materials and charred organic components. The quantity and characteristics of ash produced during a wildland fire depend mainly on (1) the total burned fuel (i.e. fuel load), (2) fuel type and (3) its combustion completeness. For a given fuel load and type, a higher combustion completeness will reduce the ash organic carbon content, increasing the relative mineral content, and hence reducing total mass of ash produced. The homogeneity and thickness of the ash layer can vary substantially in space and time and reported average thicknesses range from close to 0 to 50 mm. Ash is a highly mobile material that, after its deposition, may be incorporated into the soil profile, redistributed or removed from a burned site within days or weeks by wind and water erosion to surface depressions, footslopes, streams, lakes, reservoirs and, potentially, into marine deposits. Research on the composition, properties and effects of ash on the burned ecosystem has been conducted on material collected in the field after wildland and prescribed fires as well as on material produced in the laboratory. At low combustion completeness (typically T < 450 °C), ash is organic-rich, with organic carbon as the main component. At high combustion completeness (T > 450 °C), most organic carbon is volatized and the remaining mineral ash has elevated pH when in solution. It is composed mainly of calcium, magnesium, sodium, potassium, silicon and phosphorous in the form of inorganic carbonates, whereas at T > 580 °C the most common forms are oxides. Ash produced under lower combustion completeness is usually darker, coarser, and less dense and has a higher saturated hydraulic conductivity than ash with higher combustion completeness, although physical reactions with CO 2 and when moistened produce further changes in ash characteristics. As a new material present after a wildland fire, ash can have profound effects on ecosystems. It affects biogeochemical cycles, including the C cycle, not only within the burned area, but also globally. Ash incorporated into the soil increases temporarily soil pH and nutrient pools and changes physical properties such as albedo, soil texture and hydraulic properties including water repellency. Ash modifies soil hydrologic behavior by creating a two-layer system: the soil and the ash layer, which can function in different ways depending on (1) ash depth and type, (2) soil type and (3) rainfall characteristics. Key parameters are the ash's water holding capacity, hydraulic conductivity and its potential to clog soil pores. Runoff from burned areas carries soluble nutrients contained in ash, which can lead to problems for potable water supplies. Ash deposition also stimulates soil microbial activity and vegetation growth. Further work is needed to (1) standardize methods for investigating ash and its effects on the ecosystem, (2) characterize ash properties for specific ecosystems and wildland fire types, (3) determine the effects of ash on human and ecosystem health, especially when transported by wind or water, (4) investigate ash's controls on water and soil losses at slope and catchment scales, (5) examine its role in the C cycle, and (6) study its redistribution and fate in the environment.

Earth-Science Reviews