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Neogene hydrothermal Fe- and Mn-oxide mineralization of Paleozoic continental rocks, Amerasia Basin, Arctic Ocean

Rocks dredged from water depths of 1,605, 2,500, 3,300, and 3,400 m in the Arctic Ocean included Paleozoic continental rocks pervasively mineralized during the Neogene by hydrothermal Fe and Mn oxides. Samples were recovered in three dredge hauls from the Chukchi Borderland and one from Mendeleev Ridge north of Alaska and eastern Siberia, respectively. Many of the rocks were so pervasively altered that the protolith could not be identified, while others had volcanic, plutonic, and metamorphic protoliths. The mineralized rocks were cemented and partly to wholly replaced by the hydrothermal oxides. The Amerasia Basin, where the Chukchi Borderland and Mendeleev Ridge occur, supports a series of faults and fractures that serve as major zones of crustal weakness. We propose that the stratabound hydrothermal deposits formed through the flux of hydrothermal fluids along Paleozoic and Mesozoic faults related to block faulting along a rifted margin during minor episodes of Neogene tectonism and were later exposed at the seafloor through slumping or other gravity processes. Tectonically driven hydrothermal circulation most likely facilitated the pervasive mineralization along fault surfaces via frictional heating, hydrofracturing brecciation, and low- to moderate temperature Fe- and Mn-rich hydrothermal fluids, which mineralized the crushed, altered, and brecciated rocks.

Geochemistry, Geophysics, Geosystems

Comparative properties of saponitic fault gouge and serpentinite muds cored from mud volcanoes of the Mariana subduction zone

We obtained 12 core samples for physical and chemical characterization from three serpentinite mud volcanoes (Yinazao, Asùt Tesoru, and Fantangisña) located on the forearc of the Mariana subduction system, that were drilled during International Ocean Discovery Program Expedition 366. Two samples from the Fantangisña mud volcano are interpreted to be clay-rich fault gouges derived from the subduction channel. Their bulk compositions are intermediate between the serpentinites and oceanic basalts. The oceanic crustal materials in the gouges have been thoroughly metasomatized and the serpentinites extensively altered to the trioctahedral, Mg-rich smectite clays saponite and corrensite. The only relict phases in clasts of crustal rock are accessory Ti- and P-bearing minerals. The two fault gouge samples have lower frictional strengths ( μ < 0.2) than the serpentinites ( μ = 0.2–0.4), and their measured permeabilities are also somewhat lower. Their physical and compositional properties correspond to saponitic gouges from other faults that juxtapose serpentinite against crustal rocks, in particular gouges from the two creeping traces of the San Andreas Fault recovered in the core from the San Andreas Fault Observatory at Depth. The décollement beneath Fantangisña mud volcano is thus expected to be very weak and likely characterized by stable slip.

Geophysics, Geochemistry, Geosystems

Horizontal transport of Picture Gorge Basalt magma through the Monument Dike Swarm determined by magnetic fabric

Flood basalts of the mid-Miocene Columbia River Basalt Group (CRBG) cover 210,000 km 2 of Washington, Oregon, and Idaho. The source of CRBG melt is debated; widely spaced feeder dike swarms can be projected toward hypothetical sources near the Oregon-Idaho border. In this study, we use anisotropy of magnetic susceptibility (AMS) to track magma flow in the Monument dike swarm (MDS), the feeder dikes of the Picture Gorge Basalt (PGB). This small formation of the main-phase CRBG eruptions allows us to explore in detail the localized dynamics of a large igneous province feeder system, with implications for the larger CRBG picture. We measured the magnetic fabric of 205 oriented paleomagnetic specimens subsampled from 97 samples collected from 15 dikes of the MDS. Thermal demagnetization and hysteresis loops show that the magnetic minerals are a mixture of single domain and multidomain sized titanomagnetites. At three dikes, the paleodepth of sampling was determined to be shallow (<350 m). Magma flowing through dikes has been shown—in most cases— to acquire an anisotropic magnetic fabric with an AMS ellipsoid minimum axis perpendicular to the wall and maximum axis aligned in the direction of flow. Of 15 dikes, 12 show horizontal flow directions in the plane of the dike. Only one dike displayed imbricated fabrics, showing westward flow away from the Oregon-Idaho border. We conclude that magma flow in the MDS was sub-horizontal from a distal source.

Oregon

Mafic alkaline magmatism and rare earth element mineralization in the Mojave Desert, California: The Bobcat Hills connection to Mountain Pass

Occurrences of alkaline and carbonatite rocks with high concentrations of rare earth elements (REE) are a defining feature of Precambrian geology in the Mojave Desert of southeastern California. The most economically important occurrence is the carbonatite stock at Mountain Pass, which constitutes the largest REE deposit in the United States. A central scientific goal is to understand the genesis of the carbonatite ore body in the context of widespread REE-rich igneous activity. A swarm of mafic alkaline (shonkinite) dikes has been mapped and sampled at Bobcat Hills, 65 km southeast of the Mountain Pass mine. Whole-rock geochemistry and zircon geochronology demonstrate a clear affinity to the ca. 1.4 Ga Mountain Pass intrusive system. Bobcat Hills dikes have comparably high REE concentrations (La ∼1,000× chondritic) and an error-weighted mean 207 Pb/ 206 Pb zircon crystallization age of 1,426 ± 2 Ma (2 σ ). Unlike the alkaline intrusions at Mountain Pass, which have abundant inherited zircon from Paleoproterozoic basement rocks and crustally influenced oxygen isotope compositions (δ 18 O zircon = 6.5–7.5‰), the Bobcat Hills dikes lack any evidence of crustal assimilation and have oxygen isotope values that overlap a mantle range (Bobcat Hills average δ 18 O zircon = 5.6 ± 0.3‰). The dikes were a high-temperature, early center of mafic alkaline magmatism in the Mojave Desert that serve as a snapshot of melt generation from a spatially extensive, metasomatized mantle source. We propose that modification of the crust over many tens of Myr at Mountain Pass created an environment that favored crustal assimilation and enabled ascent of late-stage, REE-rich carbonatite magmas.

California

Regional variations in sea ice and primary productivity in the Bering Sea during Marine Isotope Stage 11

Marine Isotope Stage (MIS) 11 (424-374 ka) has long been an analog for Holocene climate, because it is the most recent interglacial period with similar orbital conditions. However, there is significant global and regional variability in the climate response to MIS 11 warmth. Here, we review sediment core records from across the Bering Sea to investigate changes in paleoceanographic conditions during Marine Isotope Stages 12-10. Sea ice was present over much of the Bering Sea during MIS 11, but today, none of the sites investigated are ever ice-covered. This suggests that sea ice regimes in the Bering Sea during MIS 11 were different to those of the Holocene. There are also regional differences in the response of sea ice to MIS 11 warming. At the Umnak Plateau, Southeastern Bering Sea, sea ice concentrations decline during deglaciation, but they remain high at the slope sites until Peak MIS 11. Sea ice re-advances over the Umnak Plateau during peak interglacial warmth, at the same time that it declines over the slope sites. Late MIS 11 is characterized by high concentrations of seasonal sea ice at the Umnak Plateau, whilst sea ice at the slope sites fluctuates between consolidated and unconsolidated ice cover. This east-west dichotomy may be explained by changes in the behavior of the Aleutian Low. Productivity increases dramatically during deglaciation due to increased upwelling and sea level rise bringing fresh nutrients into the oceans. This is characterized by increased diatom productivity, increased terrestrial carbon deposition, and laminations at all sites.

Alaska

Hydrothermal manganese-oxide mineralization of a carbonate ooze, Samoan hotspot region, South Pacific Ocean

Low-temperature hydrothermal manganese oxides occur throughout the global oceans. However, the hydrothermal replacement of a carbonate ooze by manganese oxides is described here for the first time. The 24 samples dredged from three locations around the Territory of American Samoa in the South Pacific Ocean include six samples with remnant carbonate and volcaniclastic sediments, which we refer to as “low Mn,” and 18 samples in which the mineralization is pervasive and has replaced most original sediment, termed “high Mn.” The 18 high-Mn samples exhibit a mean Mn content of 51 wt.%. Higher Li and Mn contents and lower Fe contents in the high-Mn samples indicate a hydrothermal origin and distinguish these samples from hydrogenetic ferromanganese crusts. Mn-oxide layers are up to 90 mm thick, some with columns to 44 mm long and 10 mm wide, the magnitude of which has not been described previously. Samples are composed of birnessite and 10 Å phyllomanganate minerals. Textures of the thickest Mn layers indicate mineralization below the seabed from ascending fluids during multiple hydrothermal pulses. Mineralization took place by complete to partial replacement and cementation of foraminiferal sediments intermixed with volcaniclastic sediments in varying amounts. Our results highlight the production of carbonate sediment-hosted hydrothermal Mn oxides from multiple hydrothermal sources within the Samoan volcanic chain. The potential extensive distribution on the regional scale of this newly described mineralization process and unique element enrichments raise questions about its broader distribution globally and potential importance to hydrothermal processes, element mass balance, and seabed mineral resources.

Geochemistry, Geophysics, Geosystems

Geochemical disequilibrium at the brittle-ductile transition

We investigate the microtextural, microchemical, and isotopic effects of late-stage ductile deformation in quartzite mylonites and kyanite–muscovite–quartz veins from the Raft River shear zone (Utah). Quartz microstructures record pervasive disequilibrium, expressed by unannealed features including undulatory extinction, deformation lamellae, and poorly defined fabrics, typical of waning deformation in shear zones. Microchemical disequilibrium is best preserved in kyanite quartzites, where CL-zoned kyanite records repeated fractures, overgrowth, and mineral precipitation, and in muscovite from muscovite-poor quartzite mylonites that shows minor-element zoning consistent with syn-deformational overgrowth on detrital cores. In contrast, muscovite from muscovite-rich kyanite quartzites exhibits minimal chemical zoning. These microchemical variations correlate with 40 Ar/ 39 Ar age systematics. Chemically zoned muscovite preserves variable single-step ages, including ∼150 Ma ages, reflecting retention of detrital cores. In contrast, syndeformational muscovite consistently yields Miocene ages, indicating recrystallization and new growth below argon closure temperatures that reset inherited isotopic signatures. Similar trends are observed in quartzite mylonites, where increasing quartz recrystallization and stronger crystallographic preferred orientations occur toward deeper structural levels. Together, these observations indicate increasing retrograde deformation and recrystallization with depth in the Raft River shear zone and demonstrate that strain-driven recrystallization exerts a first-order control on muscovite ages. We suggest that apparent thermochronologic gradients in retrograde shear zones may reflect recrystallization gradients rather than temperature gradients. Where cooling limits the thermal driving force for recrystallization, isotopic relics are preserved, and local deformation and fluid availability control re-equilibration. Consequently, isotopic disequilibrium—particularly in the 40 Ar/ 39 Ar system—may be the rule rather than the exception of retrograde tectonic environments.

Idaho, Utah

Using subducting plate motion to constrain Cascadia slab geometry and interface strength

Subduction zones are home to multiple geohazards driven by the evolution of the regional tectonics, including earthquakes, volcanic eruptions and landslides. Past evolution builds the present-day structure of the margin, while the present-day configuration of the system determines the state-of-stress in which individual hazardous events manifest. Regional simulations of subduction zones provide a tool to synthesize the tectonic history of a region and investigate how geologic features lead to variations in the state of stress across the subduction system. However, it is challenging to design regional models that provide a force-balance that is consistent with the large-scale motion of surrounding tectonic plates while also not over-constraining the solution. Here, we present new models for the Cascadia subduction zone that meet these criteria and demonstrate how the motion of the subducting Juan de Fuca plate can be used to determine the along-strike variations in the viscous (long-term) coupling across the plate boundary. All successful models require lower viscous coupling in the northern section of the trench compared to the central and southern sections. However, due to uncertainties in the geometry of the Cascadia slab, we find that there is a trade-off between along-strike variation in viscous coupling and slab shape. Better constraints on the slab shape, and/or use of other observations are needed to resolve this trade-off. The approach presented here provides a framework for further exploring how geologic features in the overriding plate and the properties of the plate boundary region affect the state-of-stress across this and other subduction zones.

Cascadia subduction zone

Radiogenic strontium- and uranium-isotope tracers of water-rock interactions and hydrothermal flow in the Upper Geyser Basin, Yellowstone Plateau Volcanic Field, USA

Natural radiogenic isotopes (primarily 87 Sr/ 86 Sr) from hot springs in the Upper Geyser Basin of the Yellowstone Plateau volcanic field and associated rocks were used to evaluate groundwater flow patterns, water-rock reactions, and the extent of mixing between various groundwater sources. Thermal waters have very low uranium concentrations and 234 U/ 238 U activity ratios near 1.0, which limit their utility as tracers in this reducing setting. Thermal waters have higher Sr concentrations (<22 ng/g) and a wide range of 87 Sr/ 86 Sr values that vary both temporally at individual discharge sites and between adjacent springs, indicating that conduits tap different subsurface reservoirs to varying degrees. Sr from local rhyolites have 87 Sr/ 86 Sr compositions that bound the range of values observed in groundwater throughout the basin. Non-boiling springs on the west flank of the basin discharge water with low 87 Sr/ 86 Sr consistent with flow through young volcanic rocks exposed at the surface. Boiling springs in the central basin have higher 87 Sr/ 86 Sr values reflecting interactions with older, more radiogenic volcanic rocks. Variability in upwelling thermal waters requires mixing with a low 87 Sr/ 86 Sr component derived from young lava or glacial sediments, or more likely, from deeper sources of hot groundwater circulating through buried Lava Creek Tuff having intermediate 87 Sr/ 86 Sr. Isotope data constrain basin-wide output of thermal water to 110–140 kg·s −1 . Results underscore the utility of radiogenic Sr isotopes as valuable tracers of hydrothermal flow patterns and improve the understanding of temperature-dependent water-rock reactions in one of the largest continental hydrothermal systems on Earth.

Wyoming

The systematics of stable hydrogen (δ2H) and oxygen (δ18O) isotopes and tritium (3H) in the hydrothermal system of the Yellowstone Plateau volcanic field, USA

To improve our understanding of hydrothermal activity on the Yellowstone Plateau volcanic field, we collected and analyzed a large data set of δ 2 H, δ 18 O, and the 3 H concentrations of circum-neutral and alkaline waters. We find that (a) hot springs are fed by recharge throughout the volcanic plateau, likely focused through fractured, permeable tuff units. Previous work had stressed the need for light δ 2 H water recharge restricted to the northern part of the plateau or recharge during past cold periods. However, new data from the Y-7 drill hole suggests that recharge is not restricted to a certain area or a cold period. (b) δ 18 O values of thermal waters in the geyser basins are shifted from the global meteoric water line by temperature-dependent water-rock reactions with higher subsurface temperatures resulting in a greater shift. (c) Large temporal variations in the isotopic composition of meteoric water recharge and small temporal variability in the isotopic composition of hot spring discharge implies that the volume of groundwater in, and around the Yellowstone caldera is substantially larger than the volume of annual water recharge. (d) Hot springs discharged through different rhyolitic units correlate with identifiable differences in δ 2 H and δ 18 O compositions, 3 H concentrations, and water chemistry that imply equilibration at different temperatures and travel along different flow paths. (e) Based on measured 3 H concentrations, we calculate that hot spring waters in the central part of the geyser basins mostly contain <2% post-1950 meteoric water, whereas waters discharged at the basin margins contain larger fractions of post-1950s meteoric water.

Wyoming

Apatite geo-thermochronology and geochemistry constrain Oligocene-Miocene growth and geodynamics of the northeastern Tibetan Plateau

Understanding the geodynamics of plateau evolution requires examining the spatial and temporal aspects of mountain building in the northeastern Tibetan Plateau, which are still under debate. Here we integrate apatite geo-thermochronological and geochemical data from the Oligocene-Miocene succession of the Xunhua Basin to elucidate the evolution of the regional topography. The results suggest sediment provenance changes, at ca. 28, 20 and 12 Ma, indicating topographic growth of the West Qinling, Laji Shan, and Jishi Shan source areas, respectively. Our findings reveal Oligocene-Miocene stepwise deformation and middle Miocene stress reorganization within the northeastern Tibetan Plateau. We attribute this to Oligocene lithospheric foundering beneath the south-central Tibetan Plateau and the middle Miocene initiation of sinistral strike-slip faults due to the underthrusting of India and North China. This study highlights the roles of lithospheric removal and continental underthrusting in plateau growth, and the value of multi-proxy apatite analyses in provenance studies.

Northeastern Tibetan Plateau

A joint Gaussian process model of geochemistry, geophysics, and temperature for groundwater TDS in the San Ardo Oil Field, California, USA

Decline in availability of fresh groundwater has expanded interest in brackish groundwater resources; however, the distribution of brackish groundwater is poorly understood. Water resources in sedimentary basins across the United States often overlie oil and gas development. Mapping of groundwater total dissolved solids (TDS) using data from oil well geophysical logs has become an important technique for identifying fresh and brackish groundwater. Existing geophysical log analysis methods use porosity and temperature to relate formation resistivity to TDS. Typically, natural geothermal gradients are used to estimate temperature at the location of collected resistivity. However, in thermally enhanced oil fields, steam is injected into the subsurface to mobilize high viscosity oil, creating variable temperature distributions. Furthermore, TDS derived from resistivity also depends on the fractions of dominant ions. Typically, chloride and bicarbonate fractions must be determined. It is also necessary to model TDS across many geologic units with heterogenous porosity distributions. Collectively, each quantity used to estimate TDS (resistivity, porosity, temperature, bicarbonate fraction) varies in space and time, and available data points are rarely collocated. Here, we present a new method of mapping groundwater TDS that continuously models each quantity together with a joint Gaussian process. This method enables mapping fresh and brackish water with practically available data. We apply this method to the San Ardo Oil Field in Monterey County, California, where steam injection occurs. In some areas of the aquifer system overlying the oil zone, the temperature is ∼75 °C, roughly twice the natural background value. Groundwater TDS is typically <1,500 mg/L in the aquifer and increases with depth to ∼9,000 mg/L in the oil-producing zone. A low-permeability clay layer delineates the fresh and brackish water, likely by inhibiting surface recharge from penetrating the deeper zones, allowing higher-TDS connate water to remain in place. Weaker lateral TDS trends may be controlled by recharge patterns associated with the Salinas River. Our model reveals with high certainty that groundwater has freshened in one localized part of the oil-producing zone and suggests with less certainty that more widespread freshening has also occurred. The lowering of TDS was possibly from decades of low-TDS steam injection and the associated fluid production and disposal operations.

California

Geophysical identification of potential groundwater – surface water interactions in the Bonita Peak Mining District, San Juan County, Colorado

This report includes the results and interpretation of geophysical investigations to aid in the location, identification, and conceptual site model (CSM) development of the near surface groundwater and surface water hydrology of the Upper Cement Creek and California Gulch of the Animas Rivers within the Bonita Peak Mining Districts (BPMD). Mine influenced water (MIW) from numerous mine adits within the BPMD has altered the geochemistry and ecology of these ground and surface waters. Many studies of varying scales have investigated the geology, hydrogeology, geochemistry, and aqueous chemistry of these adits and impacted areas. Field investigations using non-invasive geophysical methods were conducted in the summer of 2019 to aid in identifying potential groundwater inputs to these streams and further the CSM of the near surface within and along these streams. Two field deployments were completed in August and September of 2019. In August 2019, Phase 1 was completed using multifrequency electromagnetic induction (EMI) and thermal infrared imaging (TIR) to measure the bulk electrical conductivity, magnetic susceptibility, and the temperature response at known and suspected groundwater seeps into the Upper Cement Creek and California Gulch stretches of these alpine streams. Results and interpretation from Phase 1 were used to co-locate stretches of these streams for further detailed fiber optic distributed temperature system (FODTS) monitoring of the temperature dynamics for submeter identification of potential groundwater seeps during Phase 2. Phase 2 included additional EMI measurements, FODTS measurements, and repeated some Phase 1 measurements for improved data quality. All these data were used for the combined qualitative interpretation identifying seep locations. The data from both Phase 1 and Phase 2 are available in the USGS data release at: https://www.sciencebase.gov/catalog/item/5f18a30082cef313ed84879b. These data include detailed near-surface electrical conductivity and magnetic susceptibility mapping, discrete TIR imaging, and several kilometers of FODTS data. These data were georeferenced and used to identify potential groundwater seeps into these streams. The results indicate a complex near surface geophysical and hydrogeologic regime. Seeps are classified and spatially correlated to the EMI, TIR, and geochemical sampling results. This report is a thorough compilation of the geophysical field efforts in the summer of 2019, the data processing, and interpretations of these data. These data alone should not be used for final interpretations of the complex hydrogeology within these alpine systems. Rather, these data should be combined with other known data from various investigations to further refine the CSM and guide decisions for future investigations, watershed protective measures, and other site decisions. Geographical information system (GIS) layers of these results are available to project managers for such integration and combined interpretations.

Colorado

Stream sediment geochemistry in mineral exploration: A review of fine-fraction, clay-fraction, bulk leach gold, heavy mineral concentrate and indicator mineral chemistry

Stream sediment surveys support early-stage reconnaissance mineral exploration and regional assessment programmes, enhanced by recent improvements in analytical method detection limits, continuously improving mineral chemistry, and new approaches to the interpretation of geochemical data. Sediment surveys may be used to predict catchment basin lithology, mineralization type based on pathfinder geochemistry, and geological features based on indicator mineral chemistry. Sediment surveys that target a finer-fraction sediment sample led to the discovery of the La Colosa gold deposit, Colombia. The Batu Hijau porphyry Cu–Au deposit in Indonesia was discovered based on an anomalous clay-sized fraction sample 12 km downstream. In an arid region with poorly developed drainages and minor topographic relief, the Ag-base-metal Navidad District in Argentina was discovered with clay-fraction sediment geochemistry. Heavy mineral concentrate (HMC) sediment surveys that include mineral chemistry determinations have led to global diamond discoveries. HMC surveys contributed to discovery of the Ring of Fire Ni–Cu–PGE and chromite district, Ontario, Canada. Discoveries and geochemical mapping can assist advancement of the application of stream sediment geochemistry in those global areas for which lithologies and deposits are exposed. Stream sediment surveys continue to be one of the most cost-effective geochemical methods for covering large areas for mineral exploration.

Geochemistry: Exploration, Environment, Analysis

Geology and geochemistry of Ni-Co laterite occurrences of northern California and southern Oregon

Ni-Co laterite occurrences in the Klamath Mountains of southern Oregon and northern California contain Ni, Co, and Sc values comparable to global deposits. However, they are thin and limited in extent, often occurring as landslides and slumps. Olivine in the parent material contains Ni and Co and enstatite contains Sc. Through pervasive weathering, these elements where concentrated in Fe- and Mn-oxides. Unlike the mined Nickel Mountian deposit near Riddle, Oregon, these occurrences have no hydrous-Mg silicate minerals. Although the region experienced pervasive weathering in the Eocene, preservation of the laterite profiles was limited in the Klamath Mountains due to accelerated uplift and erosion compared to the Coast Range Provence.

Conference Paper

Geochemistry and thermometry of magnetite veins and replacements in iron ore deposits from the Iron Springs district, SW Utah, USA: Relation to magmatic and hydrothermal processes

Ore-genesis, texture, chemical compositions, and thermometry of magnetite were used to better evaluate the origins of iron ore deposits across the Iron Spring district, Utah. Trace element compositions, determined by LA-ICP-MS, were used to calculate temperatures based on X Mg numbers and characterize the trace element signatures of magmatic and hydrothermal magnetite. Magnetite occurs as coarser crystalline grains within veins, breccias, and cavities along with finer crystalline replacements. Magnetite is most commonly intergrown with apatite, phlogopite, and carbonate in veins, breccias, and cavities where apatite occurs separately from the other gangue minerals. The results using empirical trace element discrimination diagrams generally suggest that the magnetite is overall of hydrothermal origin regardless of textural variations or field relationships. The X Mg numbers of the magnetite in the magnetite-apatite ores, however, are suggestive of high temperature magmatic conditions; whereas those of vein, breccia, and replacement occurrences containing other gangue minerals are suggestive of lower temperature hydrothermal processes.

Utah

The use of fluorite geochemistry and machine learning to identify critical mineral systems

Fluorite (CaF 2 ) is a potential pathfinder to critical mineral and rare earth element (REE) deposits but its application has been limited to a narrow range of mineralization types. I show that fluorite is a robust recorder of mineralization fertility by applying statistical and machine-learning methods to a new global fluorite geochemical database. Distinct median rare earth and trace element patterns are observed among deposit types and genetic environments. Fluorite associated with carbonatites and REE deposits are relatively enriched in Sr and have minimal Eu anomalies. These characteristics define new bivariate discrimination diagrams that correctly identify 78% of carbonatite-related fluorite and 88% of fluorite from REE deposits. Random forest classifiers were developed for a wide range of mineralization types and genetic settings. Trained solely on rare earth element patterns, these models achieve accuracies of 77–79%. Higher classification accuracies (up to 88–96%) are obtained when including elements such as Sr, highlighting the significance of trace elements for optimal fluorite classification. The recognition of diagnostic fluorite compositional fingerprints, particularly in REE-fertile systems, underscores its potential as a pathfinder and indicator for critical mineral exploration in F-bearing environments.

Mineralium Deposita

Geochemistry and Soils of the Big Smoky Valley Fens, Nevada

Fens are groundwater-fed wetlands that can provide habitat for plants and animals. Due to anthropogenic activities and climate change, many fens around the world are at risk. This paper presents the results of a study of the hydrology and geochemistry of fens in Big Smoky Valley, central Nevada to support the Bureau of Land Management’s activities in the area. A water sample from the largest fen in the study area was analyzed for its water chemistry and compared to a nearby alluvial aquifer and hot spring. The high SiO 2 concentration of the fen sample implies that the fen water may originate from geothermal water. A soil core was taken to analyze radiocarbon age and soil type. A majority of the core was composed of silt and clay interlayered with water-filled voids. Changes in the character of the clay with depth suggest that there may have been changes in the depositional environment over time. Radiocarbon dating of Ruppia seeds showed longevity of the fen, with the minimum 14 C age of the core as 4,375±40 years. This paper provides reconnaissance-level information on the Big Smoky Valley fens, but further information would be needed to better understand the source of water to the fens or how the fen environment has changed over time with climate.

Nevada