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At least 19 recordsLinked to original sources
USGS2009

The geochemistry of environmentally important trace elements in UK coals, with special reference to the Parkgate coal in the Yorkshire–Nottinghamshire Coalfield, UK

The Parkgate coal of Langsettian age in the Yorkshire–Nottinghamshire coalfield is typical of many coals in the UK in that it has a high sulphur (S) content. Detailed information on the distribution of the forms of S, both laterally and vertically through the seam, was known from previous investigations. In the present work, 38 interval samples from five measured sections of the coal were comprehensively analysed for major, minor and trace elements and the significance of the relationships established using both raw and centered log transformed data. The major elements are used to quantify the variations in the inorganic and organic coal components and determine the trace element associations. Pyrite contains nearly all of the Hg, As, Se, Tl and Pb and is also the major source of the Mo, Ni, Cd and Sb. The clays contain the following elements in decreasing order of association: Rb, Cs, Li, Ga, U, Cr, V, Sc, Y, Bi, Cu, Nb, Sn, Te and Th. Nearly all of the Rb is present in the clay fraction, whereas for elements such as V, Cu and U, a significant amount is thought to be present in the organic matter, based on the K vs trace element regression equations. Only Ge, and possibly Be, would appear to have a dominant organic source. The trace element concentrations are calculated for pyrite, the clay fraction and organic matter. For pyrite it is noted that concentrations agree with published data from the Yorkshire–Nottinghamshire coalfield and also that Tl concentrations (median of 0.33 ppm) in the pyrite are greater than either Hg or Cd. Unlike these elements, Tl has attracted less attention and possibly more information is needed on its anthropogenic distribution and impacts on man and the environment. A seawater source is thought to be responsible for the high concentrations of S, Cl and the non-detrital trace elements in the Parkgate coal. Indicative of the seawater control is the Th/U ratio, which expresses the detrital to non-detrital element contributions. Using other elements, similar ratios can be calculated, which in combination offer greater interpretative value.

Yorkshire–Nottinghamshire coalfield↗
USGS2016

A practical guide to the use of major elements, trace elements, and isotopes in compositional data analysis: Applications for deep formation brine geochemistry

In the geosciences, isotopic ratios and trace element concentrations are often used along with major element concentrations to help determine sources of and processes affecting geochemical variation. Compositional Data Analysis (CoDA) is a set of tools, generally attuned to major element data, concerned with the proper statistical treatment and removal of spurious correlations from compositional data. Though recent insights have been made on the incorporation of trace elements and stable isotope ratios to CoDA, this study provides a general approach to thinking about how radiogenic isotopes, stable isotopes, and trace elements fit with major elements in the CoDA framework. In the present study, we use multiple data sets of deep formation brines and compare traditional mixing models to their CoDA counterparts to examine fluid movement between reservoirs. Concentrations of individual isotopes are calculated using isotopic ratios and global mean isotopic abundances. One key result is that isotope parts (e.g. 18O, 17O, 16O, 2H, 1H, 87Sr, 86Sr) can simply be modelled by the major element concentration (H2O, Sr) in a clr-biplot as they are perfectly dependent. Another important result is that an ilr transformation of radiogenic isotope parts (e.g. 86Sr and 87Sr in 87Sr/86Sr) and trace elements can, like stable isotopes in delta notation, be treated as a linear function of the isotopic ratio or trace element concentration, scaled only by a constant. This implies that there are multiple situations in which an ilr transformation provides little additional insight for the analysis of trends: (1) any two parts with low log ratio variance (e.g. an isotope ratio), no matter their concentrations in the solution, (2) any low concentration parts (trace elements) or a ratio of a trace to a major element, no matter the variance of the elements, and (3) large positive ratios (major/trace) over a restricted range of variance. Similarly, a multivariate ilr transformation of a large data set with many parts will also be a simple perturbation if the balances are evenly split between parts. CoDA transformations, however, even if they do not provide new insight in some specific cases, will provide consistent interpretations for all types of data.

Conference Paper↗
USGS1992

A modular finite-element model (MODFE) for areal and axisymmetric ground-water-flow problems, Part 2: Derivation of finite-element equations and comparisons with analytical solutions

MODFE, a modular finite-element model for simulating steady- or unsteady-state, area1 or axisymmetric flow of ground water in a heterogeneous anisotropic aquifer is documented in a three-part series of reports. In this report, part 2, the finite-element equations are derived by minimizing a functional of the difference between the true and approximate hydraulic head, which produces equations that are equivalent to those obtained by either classical variational or Galerkin techniques. Spatial finite elements are triangular with linear basis functions, and temporal finite elements are one dimensional with linear basis functions. Physical processes that can be represented by the model include (1) confined flow, unconfined flow (using the Dupuit approximation), or a combination of both; (2) leakage through either rigid or elastic confining units; (3) specified recharge or discharge at points, along lines, or areally; (4) flow across specified-flow, specified-head, or head-dependent boundaries; (5) decrease of aquifer thickness to zero under extreme water-table decline and increase of aquifer thickness from zero as the water table rises; and (6) head-dependent fluxes from springs, drainage wells, leakage across riverbeds or confining units combined with aquifer dewatering, and evapotranspiration. The matrix equations produced by the finite-element method are solved by the direct symmetric-Doolittle method or the iterative modified incomplete-Cholesky conjugate-gradient method. The direct method can be efficient for small- to medium-sized problems (less than about 500 nodes), and the iterative method is generally more efficient for larger-sized problems. Comparison of finite-element solutions with analytical solutions for five example problems demonstrates that the finite-element model can yield accurate solutions to ground-water flow problems.

Techniques of Water-Resources Investigations↗
USGS2012

Distribution and geochemistry of selected trace elements in the Sacramento River near Keswick Reservoir

The effect of heavy metals from the Iron Mountain Mines (IMM) Superfund site on the upper Sacramento River is examined using data from water and bed sediment samples collected during 1996-97. Relative to surrounding waters, aluminum, cadmium, cobalt, copper, iron, lead, manganese, thallium, zinc and the rare-earth elements (REE) were all present in high concentrations in effluent from Spring Creek Reservoir (SCR), which enters into the Sacramento River in the Spring Creek Arm of Keswick Reservoir. SCR was constructed in part to regulate the flow of acidic, metal-rich waters draining the IMM Superfund site. Although virtually all of these metals exist in SCR in the dissolved form, upon entering Keswick Reservoir they at least partially converted via precipitation and/or adsorption to the particulate phase. In spite of this, few of the metals settled out; instead the vast majority was transported colloidally down the Sacramento River at least to Bend Bridge, 67 km from Keswick Dam. The geochemical influence of IMM on the upper Sacramento River was variable, chiefly dependent on the flow of Spring Creek. Although the average flow of the Sacramento River at Keswick Dam is 250 m 3 /s (cubic meters per second), even flows as low as 0.3 m 3 /s from Spring Creek were sufficient to account for more than 15% of the metals loading at Bend Bridge, and these proportions increased with increasing Spring Creek flow. The dissolved proportion of the total bioavailable load was dependent on the element but steadily decreased for all metals, from near 100% in Spring Creek to values (for some elements) of less than 1% at Bend Bridge; failure to account for the suspended sediment load in assessments of the effect of metals transport in the Sacramento River can result in estimates which are low by as much as a factor of 100.

California↗
USGS1992

Effect of membrane filtration artifacts on dissolved trace element concentrations

Among environment scientists, the current and almost universally accepted definition of dissolved constituents is an operational one-only those materials which pass through a 0.45-μm membrane filter are considered to be dissolved. Detailed laboratory and field studies on Fe and Al indicate that a number of factors associated with filtration, other than just pore size, can substantially alter “dissolved” trace element concentrations; these include: filter type, filter diameter, filtration method, volume of sample processed, suspended sediment concentration, suspended sediment grain-size distribution, concentration of colloids and colloidally-associated trace elements and concentration of organic matter. As such, reported filtered-water concentrations employing the same pore size filter may not be equal. Filtration artifacts may lead to the production of chemical data that indicate seasonal or annual “dissolved” chemical trends which do not reflect actual environmental conditions. Further, the development of worldwide averages for various dissolved chemical constituents, the quantification of geochemical cycles, and the determination of short- or long-term environmental chemical trends may be subject to substantial errors, due to filtration artifacts, when data from the same or multiple sources are combined. Finally, filtration effects could have a substantial impact on various regulatory requirements.

Georgia↗
USGS2017

Chemical elements in the environment: multi-element geochemical datasets from continental to national scale surveys on four continents

During the last 10-20 years, Geological Surveys around the world have undertaken a major effort towards delivering fully harmonized and tightly quality-controlled low-density multi-element soil geochemical maps and datasets of vast regions including up to whole continents. Concentrations of between 45 and 60 elements commonly have been determined in a variety of different regolith types (e.g., sediment, soil). The multi-element datasets are published as complete geochemical atlases and made available to the general public. Several other geochemical datasets covering smaller areas but generally at a higher spatial density are also available. These datasets may, however, not be found by superficial internet-based searches because the elements are not mentioned individually either in the title or in the keyword lists of the original references. This publication attempts to increase the visibility and discoverability of these fundamental background datasets covering large areas up to whole continents.

Applied Geochemistry↗
USGS2020

Focus areas for data acquisition for potential domestic resources of 11 critical minerals in the conterminous United States, Hawaii, and Puerto Rico—Aluminum, cobalt, graphite, lithium, niobium, platinum-group elements, rare earth elements, tantalum, tin, titanium, and tungsten

In response to a need for information on potential domestic sources of critical minerals, the Earth Mapping Resources Initiative (Earth MRI) was established to identify and prioritize areas for acquisition of new geologic mapping, geophysical data, and elevation data to improve our knowledge of the geologic framework of the United States. Phase 1 of Earth MRI concentrated on those geologic terranes favorable for hosting the rare earth elements (REEs). Phase 2 continued to address the REEs and also identified focus areas for potential domestic sources of 10 more of the 35 critical minerals on the U.S. critical minerals list (aluminum, cobalt, graphite, lithium, niobium, platinum-group elements, tantalum, tin, titanium, tungsten). This report describes the methodology, data sources, and summary results for mineral systems that host these 11 critical minerals in the conterminous United States, Hawaii, and Puerto Rico; Alaska is covered in a separate report. The mineral systems framework adopted for this study links critical mineral commodities to families of genetically related mineral deposit types. The mineral systems approach is an efficient approach, providing a simultaneous evaluation of geologic terranes through aggregation of genetically related mineral deposit types that are much larger than individual ore deposits. Geologic, geochemical, topographic, and geophysical mapping provided by Earth MRI will document geologic features that reflect the extent of individual mineral systems and provide information about critical mineral deposits that may not have been recognized previously. Each critical mineral commodity is discussed in terms of importance to the Nation’s economy, modes of occurrence, mineral systems, and deposit types along with maps and tables listing examples of focus areas for each critical mineral. Important mineral systems for these critical minerals include chemical weathering systems for aluminum (bauxite); placer systems for titanium and REEs; metamorphic systems for graphite; mafic magmatic systems for platinum-group elements and cobalt; lacustrine evaporite and porphyry tin systems for lithium; and copper-molybdenum-gold (Cu-Mo-Au) systems for tungsten. REEs occur in many different mineral systems. Focus areas were developed by scientists from the U.S. Geological Survey in collaboration with scientists from State geological surveys and other institutions. This first national-scale compilation of focus areas represents an initial step in addressing the Nation’s critical mineral needs by screening areas for acquisition of new data to provide the geologic framework necessary for identifying domestic sources of critical minerals.

Open-File Report↗
USGS2012

Strangways Crater, Northern Territory, Australia: Siderophile element enrichment and lithophile element fractionation

The Strangways Crater, Northern Territory, Australia (15°12′S, 133°35′ E ), has a central core, about 10 km in diameter, of shocked granitic gneiss and amphibolite, and some remnants of a melt rock sheet, surrounded by outer rings of quartzite and siltstone to a diameter of 20–25 km. Seven samples of melt rock (six granitic melts, one shale melt clast) and four samples of country rock (granitic gneiss, amphibolite, shale, quartzite) were analyzed by neutron-activation analysis: for Sc, Cr, Fe, Co, Zn, Rb, Zr, Sb, Cs, Ba, rare earth elements, Hf, Ta, Th, and U, the samples were analyzed instrumentally; and for Ni, Se, Pd, Ag, Cd, Re, Os, Ir, and Au, they were analyzed radiochemically. Siderophile elements are significantly enriched in the granitic melt rocks relative to country rocks; for example, the Ir enrichments range from 0.6 to 2.8 ppb. The low Ir/Ni ratio (∼0.16 relative to C1 chondrites) excludes a chondritic impacting body, and Cr enrichment argues against impact by an iron meteorite. The Strangways Crater may have been formed by the impact of an olivine-rich achondrite and melt rocks appear to contain about 3 wt.% of projectile material. The composition of the granitic melt rocks cannot be reproduced by any simple mixture of analyzed country rock types and chemical fractionation by selective shock melting appears to have taken place.

Journal of Geophysical Research Solid Earth↗
USGS1988

Optimisation of flame parameters for simultaneous multi-element atomic absorption spectrometric determination of trace elements in rocks

A study is described that identifies the optimum operating conditions for the accurate determination of Co, Cu, Mn, Ni, Pb, Zn, Ag, Bi and Cd using simultaneous multi-element atomic absorption spectrometry. Accuracy was measured in terms of the percentage recoveries of the analytes based on certified values in nine standard reference materials. In addition to identifying optimum operating conditions for accurate analysis, conditions resulting in serious matrix interferences and the magnitude of the interferences were determined. The listed elements can be measured with acceptable accuracy in a lean to stoicheiometric flame at measurement heights ???5-10 mm above the burner.

Journal of Analytical Atomic Spectrometry↗
USGS1969

Minor-element and revised major-element contents of some Mediterranean pantellerites and comendites

Optical emission spectrographic analysis of three pantellerites from Pantelleria and two comendites from Sardinia show high concentrations of B, Be, Ga, La, Mo, Nb, Sn, Y, Yb, and Zt and low contents of Ba, Co, Cr, Ni, Sr, and V. Minor-element trends of these specimens are very similar to those of pantellerites from southern Nevada and New Zealand and other peralkaline silicic rocks from various localities. Fluorine contents of the Pantellerian specimens range from 0.19 to 0.32 per cent by weight resulting in abnormally high Cl to F ratios. New analyses for MgO, Na 2 O, and K 2 O are almost identical with the values obtained by Zies. Revised major-element compositions and calculated glass-phase compositions for the three Pantellerian specimens are given.

Pantelleria, Sardinia↗
USGS2023

Outlining potential biomarkers of exposure and effect to critical minerals: Nutritionally essential trace elements and the rare earth elements

Emerging and low-carbon technologies and innovations are driving a need for domestic sources, sustainable use, and availability of critical minerals (CMs)—those vital to the national and economic security of the United States. Understanding the known and potential health effects of exposures to such mineral commodities can inform prudent and environmentally responsible handling and harvesting. We review the occurrence, use, predominant exposure pathways, and adverse outcome pathways (AOP) for human and fish receptors of those CMs that are nutritionally essential trace metals (specifically, cobalt, chromium, manganese, nickel, and zinc), as well as the rare earth elements. Biological responses to some elements having comparable biogeochemistry can sometimes be similar. Candidate quantifiable biomarkers for assessing potential AOP are conveyed.

Toxics↗
USGS2020

Focus areas for data acquisition for potential domestic resources of 11 critical minerals in Alaska—Aluminum, cobalt, graphite, lithium, niobium, platinum group elements, rare earth elements, tantalum, tin, titanium, and tungsten, chap. C of U.S. Geological Survey, Focus areas for data acquisition for potential domestic sources of critical minerals

Phase 2 of the Earth Mapping Resources Initiative (Earth MRI) focuses on geologic belts that are favorable for hosting mineral systems that may contain select critical minerals. Phase 1 of the Earth MRI program focused on rare earth elements (REE), and phase 2 adds aluminum, cobalt, graphite, lithium, niobium, platinum-group metals, tantalum, tin, titanium, and tungsten. This report describes the methodology and techniques utilized to define focus areas for future data acquisition in Alaska; the conterminous United States are covered in a separate report. Definition of focus areas relies on a mineral systems framework that considers geologic features that may influence or control the formation and preservation of a mineral deposit and links the critical commodities to genetically related processes. Mineral systems are therefore larger than any given deposit. Evaluation of these larger systems allows for a broader understanding of how and where critical minerals may move through geologic systems. Delineation of focus areas in Alaska was informed by statewide geological, geochemical, geophysical, and mineral occurrence datasets that are publicly available. Additionally, previously published prospectivity analyses for six different critical mineral-bearing deposit types help identify focus areas. A total of 74 focus areas prospective for the phase 2 critical minerals that occur in 12 different mineral systems were defined in Alaska. Identified focus areas may be used to guide future geologic, geochemical, and geophysical data in the State of Alaska.

Alaska↗
USGS2011

The future of rare earth elements—will these high-tech industry elements continue in short supply?

* REE will continue to find increasing use due to their unique properties. * There is a realistic possibility around 2015-2016 of sufficient REE capacity to meet demand under conditions of healthy price competition. * REE supplies will be tight and prices high for a few years. * There is significant downside risk that newly developed mines will not perform as planned.

Open-File Report↗