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Sediment accumulation on the Southern California Bight continental margin during the twentieth century
Sediment discharged into the portion of the Southern California Bight extending from Santa Barbara to Dana Point enters a complex system of semi-isolated coastal cells, narrow continental shelves, submarine canyons, and offshore basins. On both the Santa Monica and San Pedro margins, 210 Pb accumulation rates decrease in an offshore direction (from ??0.5 g cm -2 yr -1 to 0.02 g cm -2 yr -1 ), in concert with a fining in sediment grain size (from 4.5?? to 8.5??), suggesting that offshore transport of wave-resuspended material occurs as relatively dilute nepheloid layers and that hemiplegic sedimentation dominates the supply of sediment to the outer shelf, slope, and basins. Together, these areas are effectively sequestering up to 100% of the annual fluvial input. In contrast to the Santa Monica margin, which does not display evidence of mass wasting as an important process of sediment delivery and redistribution, the San Pedro margin does provide numerous examples of failures and mass wasting, suggesting that intraslope sediment redistribution may play a more important role there. Basin deposits in both areas exhibit evidence of turbidites tentatively associated with both major floods and earthquakes, sourced from either the Redondo Canyon (San Pedro Basin) or Dume Canyon (Santa Monica Basin). On the Palos Verdes shelf, sediment-accumulation rates decrease along and across the shelf away from the White's Point outfall, which has been a major source of contaminants to the shelf deposits. Accumulation rates prior to the construction of the outfall were ??0.2 g cm -2 yr -1 and increased 1.5-3.7 times during peak discharges from the outfall in 1971. The distal rate of accumulation has decreased by ??50%, from 0.63 g cm -2 yr -1 during the period 1971-1992 to 0.29 g cm -2 yr -1 during the period 1992-2003. The proximal rate of accumulation, however, has only decreased ??10%, from 0.83 g cm -2 yr -1 during the period 1971-1992 to 0.73 g cm -2 yr -1 during the period 1992-2003. Effluent-affected sediment layers on the Palos Verdes shelf can be identified in seabed profiles of naturally occurring 238 U, which is sequestered in reducing sediments. The Santa Clara River shelf, just north and west of the Santa Monica and San Pedro margins, is fine-grained and flood-dominated. Core profiles of excess 210 Pb from sites covering the extent of documented major flood deposition exhibit evidence of rapidly deposited sediment up to 25 cm thick. These beds are developing in an active depocenter in water depths of 30-50 m at an average rate of 0.72 g cm -2 yr -1 . Budget calculations for annual and 50-yr timescale sediment storage on this shelf shows that 20%-30% of the sediment discharge is retained on the shelf, leaving 70%-80% to be redistributed to the outer shelf, slope, Santa Barbara Basin, and Santa Monica Basin. ?? 2009 The Geological Society of America.
Late Pleistocene to Holocene sedimentation and hydrocarbon seeps on the continental shelf of a steep, tectonically active margin, southern California, USA
Small, steep, uplifting coastal watersheds are prolific sediment producers that contribute significantly to the global marine sediment budget. This study illustrates how sedimentation evolves in one such system where the continental shelf is largely sediment-starved, with most terrestrial sediment bypassing the shelf in favor of deposition in deeper basins. The Santa Barbara-Ventura coast of southern California, USA, is considered a classic area for the study of active tectonics and of Tertiary and Quaternary climatic evolution, interpretations of which depend upon an understanding of sedimentation patterns. High-resolution seismic-reflection data over >570 km 2 of this shelf show that sediment production is concentrated in a few drainage basins, with the Ventura and Santa Clara River deltas containing most of the upper Pleistocene to Holocene sediment on the shelf. Away from those deltas, the major factor controlling shelf sedimentation is the interaction of wave energy with coastline geometry. Depocenters containing sediment 5-20 m thick exist opposite broad coastal embayments, whereas relict material (bedrock below a regional unconformity) is exposed at the sea floor in areas of the shelf opposite coastal headlands. Locally, natural hydrocarbon seeps interact with sediment deposition either to produce elevated tar-and-sediment mounds or as gas plumes that hinder sediment settling. As much as 80% of fluvial sediment delivered by the Ventura and Santa Clara Rivers is transported off the shelf (some into the Santa Barbara Basin and some into the Santa Monica Basin via Hueneme Canyon), leaving a shelf with relatively little recent sediment accumulation. Understanding factors that control large-scale sediment dispersal along a rapidly uplifting coast that produces substantial quantities of sediment has implications for interpreting the ancient stratigraphic record of active and transform continental margins, and for inferring the distribution of hydrocarbon resources in relict shelf deposits.
Seismic stratigraphic framework of the continental shelf offshore Delmarva, U.S.A.: Implications for Mid-Atlantic Bight evolution since the Pliocene
Understanding how past coastal systems have evolved is critical to predicting future coastal change. Using over 12,000 trackline kilometers of recently collected, co-located multi-channel boomer, sparker and chirp seismic reflection profile data integrated with previously collected borehole and vibracore data, we define the upper (< 115 m below mean lower low water) seismic stratigraphic framework offshore of the Delmarva Peninsula, USA. Twelve seismic units and 11 regionally extensive unconformities (U1-U11) were mapped over 5900 km 2 of North America's Mid-Atlantic continental shelf. We interpret U3, U7, U9, U11 as transgressive ravinement surfaces, while U1,2,4,5,6,8,10 are subaerial unconformities illustrating distinct periods of lower sea-level. Based on areal distribution, stratigraphic relationships and dating results (Carbon 14 and amino acid racemization estimates) from earlier vibracore and borehole studies, we interpret the infilled channels as late Neogene and Quaternary courses of the Susquehanna, Potomac, Rappahannock, York, James rivers and tributaries, and a broad flood plain. These findings indicate that the region's geologic framework is more complex than previously thought and that Pleistocene paleochannels are abundant in the Mid-Atlantic. This study synthesizes and correlates the findings of other Atlantic Margin studies and establishes a large-scale Quaternary framework that enables more detailed stratigraphic analysis in the future. Such work has implications for inner continental shelf systems tract evolution, the relationship between antecedent geology and modern coastal systems, assessments of eustacy, glacial isostatic adjustment, and other processes and forcings that play a role in passive margin evolution.
The Continental Margins Program in Georgia
From 1984 to 1993, the Georgia Geologic Survey (GGS) participated in the Minerals Management Service-funded Continental Margins Program. Geological and geophysical data acquisition focused on offshore stratigraphic framework studies, phosphate-bearing Miocene-age strata, distribution of heavy minerals, near-surface alternative sources of groundwater, and development of a PC-based Coastal Geographic Information System (GIS). Seven GGS publications document results of those investigations. In addition to those publications, direct benefits of the GGS's participation include an impetus to the GGS's investigations of economic minerals on the Georgia coast, establishment of a GIS that includes computer hardware and software, and seeds for additional investigations through the information and training acquired as a result of the Continental Margins Program. These addtional investigations are quite varied in scope, and many were made possible because of GIS expertise gained as a result of the Continental Margins Program. Future investigations will also reap the benefits of the Continental Margins Program.From 1984 to 1993, the Georgia Geologic Survey (GGS) participated in the Minerals Management Service-funded Continental Margins Program. Geological and geophysical data acquisition focused on offshore stratigraphic framework studies, phosphate-bearing Miocene-age strata, distribution of heavy minerals, near-surface alternative sources of groundwater, and development of a PC-based Coastal Geographic Information System (GIS). Seven GGS publications document results of those investigations. In addition to those publications, direct benefits of the GGS's participation include an impetus to the GGS's investigations of economic minerals on the Georgia coast, establishment of a GIS that includes computer hardware and software, and seeds for additional investigations through the information and training acquired as a result of the Continental Margins Program. These additional investigations are quite varied in scope, and many were made possible because of GIS expertise gained as a result of the Continental Margins Program. Future investigations will also reap the benefits of the Continental Margins Program.
Rifting history and structural development of the continental margin north of Alaska
Seismic-reflection profiles in the Alaskan Beaufort Sea and onshore geology indicate that the continental margin north of Alaska is of Atlantic type. Rifting appears to have begun in earliest Jurassic time, about 190 to 185 m.y. ago, when crustal extension created a rift-valley system beneath the Beaufort shelf and part of the adjacent coastal plain. Subsequent crustal warming caused rift-margin uplift and erosion, created a breakup unconformity, and initiated breakup and seafloor spreading in the Canada Basin about 125 m.y. ago. Subsequent cooling caused rapid subsidence of the margin, which was followed by vigorous progradation of the present continental terrace of the Beaufort Sea beginning in Albian time.
Transgressive systems tract development and incised-valley fills within a quaternary estuary-shelf system: Virginia inner shelf, USA
High-frequency Quaternary glacioeustasy resulted in the incision of six moderate- to high-relief fluvial erosion surfaces beneath the Virginia inner shelf and coastal zone along the updip edges of the Atlantic continental margin. Fluvial valleys up to 5 km wide, with up to 37 m of relief and thalweg depths of up to 72 m below modern mean sea level, cut through underlying Pleistocene and Mio-Pliocene strata in response to drops in baselevel on the order of 100 m. Fluvially incised valleys were significantly modified during subsequent marine transgressions as fluvial drainage basins evolved into estuarine embayments (ancestral generations of the Chesapeake Bay). Complex incised-valley fill successions are bounded by, or contain, up to four stacked erosional surfaces (basal fluvial erosion surface, bay ravinement, tidal ravinement, and ebb-flood channel-base diastem) in vertical succession. These surfaces, combined with the transgressive oceanic ravinement that generally caps incised-valley fills, control the lateral and vertical development of intervening seismic facies (depositional systems). Transgressive stratigraphy characterizes the Quaternary section beneath the Virginia inner shelf where six depositional sequences (Sequences I-VI) are identified. Depositional sequences consist primarily of estuarine depositional systems (subjacent to the transgressive oceanic ravinement) and shoreface-shelf depositional systems; highstand systems tract coastal systems are thinly developed. The Quaternary section can be broadly subdivided into two parts. The upper part contains sequences consisting predominantly of inner shelf facies, whereas sequences in the lower part of the section consist predominantly of estuarine facies. Three styles of sequence preservation are identified. Style 1, represented by Sequences VI and V, is characterized by large estuarine systems (ancestral generations of the Chesapeake Bay) that are up to 40 m thick, have hemicylindrical wedge geometries, and occur within large, coast-oblique trending depressions (paleo-estuaries). Style 1 is dominated by fluvial through estuary-mouth depositional systems (Seismic Facies 1-4). Style 2 sequence preservation, represented by Sequences III and II, is dominantly an inner shelf and shoreface succession with a seaward-thickening tabular wedge geometry that does not exceed 15 m in thickness. These shoreface and inner shelf depositional systems of the upper transgressive systems tract (Seismic Facies 9) and highstand systems tract (Seismic Facies 7 and 11) are not associated with paleo-estuaries. Style 3 sequence preservation is represented by Sequence 1, the Holocene Sequence. It consists of lower transgressive systems tract fluvial-estuarine, lagoonal, and tidal-inlet fill deposits (Seismic Facies 1-6, and 8) overlain by upper transgressive systems tract shelf and shoreface sands (Seismic Facies 9). Style 3 has a crenulated wedge geometry, and is thickest beneath and seaward of the modern Chesapeake Bay mouth. It thins northward and landward onto Late Pleistocene interfluvial highs on the basinward side of the southern Delmarva Peninsula.
Late Neogene and Quaternary evolution of the northern Albemarle Embayment (mid-Atlantic continental margin, USA)
Seismic surveys in the eastern Albemarle Sound, adjacent tributaries and the inner continental shelf define the regional geologic framework and provide insight into the sedimentary evolution of the northern North Carolina coastal system. Litho- and chronostratigraphic data are derived from eight drill sites on the Outer Banks barrier islands, and the Mobil #1 well in eastern Albemarle Sound. Within the study area, parallel-bedded, gently dipping Miocene beds occur at 95 to > 160 m below sea level (m bsl), and are overlain by a southward-thickening Pliocene unit characterized by steeply inclined, southward-prograding beds. The lower Pliocene unit consists of three seismic sequences. The 55–60 m thick Quaternary section unconformably overlies the Pliocene unit, and consists of 18 seismic sequences exhibiting numerous incised channel-fill facies. Shallow stratigraphy (< 40 m bsl) is dominated by complex fill patterns within the incised paleo-Roanoke River valley. Radiocarbon and amino-acid racemization (AAR) ages indicate that the valley-fill is latest Pleistocene to Holocene in age. At least six distinct valley-fill units are identified in the seismic data. Cores in the valley-fill contain a 3–6 m thick basal fluvial channel deposit that is overlain by a 15 m thick unit of interlaminated muds and sands of brackish water origin that exhibit increasing marine influence upwards. Organic materials within the interlaminated deposits have ages of 13–11 cal. ka. The interlaminated deposits within the valley are overlain by several units that comprise shallow marine sediments (bay-mouth and shoreface environments) that consist of silty, fine- to medium-grained sands containing open neritic foraminifera, suggesting that this area lacked a fronting barrier island system and was an open embayment from ∼10 ka to ∼4.5 ka. Seismic data show that initial infilling of the paleo-Roanoke River valley occurred from the north and west during the late Pleistocene and early Holocene. Later infilling occurred from the south and east and is characterized by a large shoal body (Colington Island and Shoals) and adjacent inlet fill. Establishment of a continuous barrier island system across the bay-mouth resulted in deposition of the latest phase of valley-fill, characterized by estuarine organic-rich muds.
Eel River margin source-to-sink sediment budgets: revisited
The Eel River coastal margin has been used as a representative source-to-sink sediment dispersal system owing to its steep, high-sediment yield river and the formation of sedimentary strata on its continental shelf. One finding of previous studies is that the adjacent continental shelf retains only ~25% of the Eel River fine-grained sediment (less than 63 μm) discharged over time scales of both individual floods and the 20th century, thus suggesting that the Eel shelf trapping-efficiency is uniquely lower than other similar systems. Here I provide data and analyses showing that sediment discharge relationships in the Eel River have varied strongly with time and include substantial decreases in suspended-sediment concentrations during the latter 20th century. Including these trends in margin-wide sediment budgets, I show that previous Eel River sediment discharge rates were overestimated by a factor of two. Thus, revised sediment budgets shown here reveal that the Eel shelf retained ~50% of the discharged river fine-grained suspended sediment during intensively sampled events of 1995–97 and over the 20th century. In light of this, hypotheses about high rates of sediment export away from the primary shelf depocenter should be reevaluated.
Stratigraphy of the Mississippi-Alabama shelf and the Mobile River incised-valley system
The Mobile River incised-valley system located in the northern Gulf of Mexico occupies an area from southern Alabama through Mobile Bay to the outer Mississippi-Alabama continental shelf. During the Wisconsinan regression, this incised-valley system was fluvially eroded and extended across the exposed shelf to a shelf-margin delta complex. The last postglacial transgression drowned the entrenched alluvial valleys and reworked the alluvial fill and estuarine deposits to form shoals on the middle shelf. As the postglacial transgression slowed. Mobile Bay was formed. Mobile Bay is a large estuarine system protected by barrier islands. This paper documents the late Quaternary history of the Mobile River incised valley and fill. Mobile Bay is a large (> 1000 km 2 ) microtidal estuary in southern Alabama that receives drainage through the Mobile River system. The Mobile River catchment is the fourth largest in the United States and terminates at the bayhead delta of Mobile Bay. The bay is a classic example of a wave-dominated, drowned, fluvial incised valley. During the middle-late Wisconsinan, glacial maximum, relative sea level was approximately 120 m lower than present. The Mobile River incised valley was a conduit for drainage from the catchment to the shelf margin. The sediment carried by the fluvial system during this lowstand passed through the Mobile River incised valley, across the exposed shelf and was deposited on the shelf margin as deltaic lobes. Rapid sea-level rise forced coastal-plain shorelines landward across the present mid-continental shelf. Transgression of the estuary mouth left a series of estuary-mouth-bar deposits that were reworked and overlie alluvial fill. These sand-rich deposits were submerged by the continuing transgression and reworked to form shoals As the Holocene sea-level rise slowed, the Mobile River incised valley became an estuarine depocenter. In the present alluvial valley, lowstand deposits are overlain by estuarine sediments deposited during the initial flooding of the valley and subsequent formation of Mobile Bay. During the present highstand, longshore sediment transport formed a spit across much of the bay mouth, creating a restricted estuary into which a bayhead delta has prograded. Late Holocene deposits in Mobile Bay consists predominantly or lagoonal sediments with bayhead-delta deposits encroaching into the northern end of the bay. The Holocene incised-valley fill (estuarine facies) underlying Mobile Buy fit well into the conceptual facies model of a microtidal wave-dominated estuary. The model does not fit as well, however, with the rapidly transgressed shelf portion of the incised valley. The down dip section does not contain a clearly identifiable (from seismic profiles) estuarine facies; the valley fill is primarily fluvial and is overlain by marine shoals. In the Mobile River incised valley, the distal portion of the valley was rapidly drowned, allowing the thin estuarine facies to be reworked. The proximal portion was drowned more slowly, leaving the estuarine facies intact. Thus, the single incised valley contains two very different types of fill.
Sediments and the sea floor of the continental shelves and coastal waters of the United States—About the usSEABED integrated sea-floor-characterization database, built with the dbSEABED processing system
Since the second half of the 20th century, there has been an increase in scientific interest, research effort, and information gathered on the geologic sedimentary character of the continental margins of the United States. Data and information from thousands of sources have increased our scientific understanding of the character of the margin surface, but rarely have those data been combined and integrated. Initially, the U.S. Geological Survey (USGS), in cooperation with the Institute of Arctic and Alpine Research at the University of Colorado Boulder, created the usSEABED database to provide surficial sea-floor-characterization data for USGS assessments of marine-based aggregates and for studies of sea-floor habitat. Since then, the USGS has continued to build up the database as a nationwide resource for many uses and applications. Previously published data derived from the usSEABED database have been released as three USGS data series publications containing data covering the U.S. Atlantic margin, the Gulf of Mexico and Caribbean regions, and the Pacific coast. An updated USGS data release unifies the three publications, incorporates additional data and sources including data from Alaska, Hawaii, and U.S. overseas territories, and provides revised output files that fix known errors and add known or inferred sampling dates. This report accompanies the data release and contains information on the methodology and products of the usSEABED database.
Global physical controls on estuarine habitat distribution during sea levelchange: Consequences for genetic diversification through time
Determining the extrinsic (physical) factors controlling speciation and diversification of species through time is of key interest in paleontology and evolutionary biology. The role of sea-level change in shaping species richness patterns of marginal marine species has received much attention, but with variable conclusions. Recent work combining genetic data and Geographical Information Systems (GIS)-based habitat modeling yielded a framework for how geomorphology of continental margins mediates genetic connectivity of populations during sealevel change. This approach may ultimately yield insights on how distinct lineages, species, and biodiversity accumulate in coastal settings. Here, we expand this GIS work globally to different geomorphic settings to model estuarine habitat in a larger geographic framework and test how tectonic setting, oceanographic setting, climate, and margin age affect habitat distribution during sea-level change. In addition, independent of estuaries we explore paleobiologic (e.g. Olsson, 1961) and neontolologic effects of sea-level change on evolution, and test the relation between overall shelf area and species richness using data of 1721 fish species. We find 82% global reduction of estuarine habitat abundance at lowstand relative to highstand, and find large habitats change in size much more than small habitats. Consistent with prior work, narrow continental margins have significantly less habitat at highstand and lowstand than wide margins, and narrow margins significantly associate with fore-arc settings, effectively linking tectonic setting to habitat abundance. Surprisingly, narrow margins host greater species richness, a finding which violates the canonical species-area relation. This finding can be explained if: 1) the physical isolation imposed by narrow margins facilitates the formation of new species over time; 2) the sizestability of small habitats, which disproportionately occur on narrow margins, accumulate and retain species extirpated in the more variable habitats on wide margins; or 3) the smaller habitats on narrow margins facilitate greater species richness through greater habitat heterogeneity. These results are generally at odds with prior interpretations, but the combination of richness data and population genetic principles offer a different perspective on these long-studied questions. Finally, we emphasize that the nuance of Pleistocene-Holocene sea level oscillations should be more explicitly considered in genetic studies.
usSEABED: Gulf of Mexico and Caribbean (Puerto Rico and U.S. Virgin Islands) offshore surficial sediment data release
Over the past 50 years there has been an explosion in scientific interest, research effort and information gathered on the geologic sedimentary character of the United States continental margin. Data and information from thousands of publications have greatly increased our scientific understanding of the geologic origins of the shelf surface but rarely have those data been combined and integrated. This publication is the first release of the Gulf of Mexico and Caribbean (Puerto Rico and U.S. Virgin Islands) coastal and offshore data from the usSEABED database. The report contains a compilation of published and previously unpublished sediment texture and other geologic data about the sea floor from diverse sources. usSEABED is an innovative database system developed to bring assorted data together in a unified database. The dbSEABED system is used to process the data. Examples of maps displaying attributes such as grain size and sediment color are included. This database contains information that is a scientific foundation for the USGS Marine Aggregate Resources and Processes Assessment and Benthic Habitats projects, and will be useful to the marine science community for other studies of the Gulf of Mexico and Caribbean continental margins. This publication is divided into ten sections: Home, Introduction, Content, usSEABED (data), dbSEABED (processing), Data Catalog, References, Contacts, Acknowledgments and Frequently Asked Questions. Use the navigation bar on the left to navigate to specific sections of this report. Underlined topics throughout the publication are links to more information. Links to specific and detailed information on processing and those to pages outside this report will open in a new browser window.
Allostratigraphy of the U.S. middle Atlantic continental margin; characteristics, distribution, and depositional history of principal unconformity-bounded upper Cretaceous and Cenozoic sedimentary units
Publication of Volumes 93 and 95 ('The New Jersey Transect') of the Deep Sea Drilling Project's Initial Reports completed a major phase of geological and geophysical research along the middle segment of the U. S. Atlantic continental margin. Relying heavily on data from these and related published records, we have integrated outcrop, borehole, and seismic-reflection data from this large area (500,000 km^2 ) to define the regional allostratigraphic framework for Upper Cretaceous and Cenozoic sedimentary rocks. The framework consists of 12 alloformations, which record the Late Cretaceous and Cenozoic depositional history of the contiguous Baltimore Canyon trough (including its onshore margin) and Hatteras basin (northern part). We propose stratotype sections for each alloformation and present a regional allostratigraphic reference section, which crosses these basins from the inner edge of the coastal plain to the inner edge of the abyssal plain. Selected supplementary reference sections on the coastal plain allow observation of the alloformations and their bounding unconformities in outcrop. Our analyses show that sediment supply and its initial dispersal on the middle segment of the U. S. Atlantic margin have been governed, in large part, by hinterland tectonism and subsequently have been modified by paleoclimate, sea-level changes, and oceanic current systems. Notable events in the Late Cretaceous to Holocene sedimentary evolution of this margin include (1) development of continental-rise depocenters in the northern part of the Hatteras basin during the Late Cretaceous; (2) the appear ance of a dual shelf-edge system, a marked decline in siliciclastic sediment accumulation rates, and widespread acceleration of carbonate production during high sea levels of the Paleogene; (3) rapid deposition and progradation of thick terrigenous delta complexes and development of abyssal depocenters during the middle Miocene to Quaternary interval; and (4) deep incision of the shelf edge by submarine canyons, especially during the Pleistocene. Massive downslope gravity flows have dominated both the depositional and erosional history of the middle segment of the U. S. Atlantic Continental Slope and Rise during most of the last 84 million years. The importance of periodic widespread erosion is recorded by well-documented unconformities, many of which can be traced from coastal-plain outcrops to coreholes on the continental slope and lower continental rise. These unconformities form the boundaries of the 12 allostratigraphic units we formally propose herein. Seven of the unconformities correlate with supercycle boundaries (sequence boundaries) that characterize the Exxon sequence-stratigraphy model.
Continuing evolution of the Pacific-Juan de Fuca-North America slab window system-A trench-ridge-transform example from the Pacific Rim
Many subduction margins that rim the Pacific Ocean contain complex records of Cenozoic slab-window volcanism combined with tectonic disruption of the continental margin. The series of slab windows that opened beneath California and Mexico starting about 28.5 Ma resulted from the death of a series of spreading ridge segments and led to piecewise destruction of a subduction regime. The timing and areal extent of the resultant slab-window volcanism provide constraints on models that depict the subsequent fragmentation and dispersal of the overlying continental margin. The initial Pioneer slab window thermally weakened the overlying western Transverse Ranges and California Borderlands region starting about 28.5 Ma. A second thermal pulse occurred in the same region starting about 19 Ma during growth of the Monterey slab window. This additional heating, combined with the capture of a partially subducted Monterey plate fragment by the Cocos plate, initiated the pulling apart and rotation of the adjacent continental margin. Similarly, the capture of Guadalupe and Magdalena plate fragments by the Pacific plate and initiation of the Guadalupe-Magdalena slab window about 12.5 Ma are coeval with Baja California pulling away from the Mexico continental margin, with the break along the Comondú arc, in crust already thermally weakened by about 10 My of volcanism. In coastal California, distributed crustal extension and subsidence accompanied the new transform plate boundary, and continued until the slab windows cooled and plate motion coalesced along a through-going system of strike-slip faults. The transform boundary continues to evolve, and forward modeling predicts an instability with the current configuration as a result of convergence between the Sierra Nevada and Peninsular Ranges batholiths, starting about 2 My in the future. The instability may be resolved by a shift in the locus of transform motion from the San Andreas fault to the eastern California shear zone, or by breaking off another fragment of the Mojave or southern Sierra Nevada crustal blocks and translating it northward.
Zirconium and hafnium
Zirconium and hafnium are corrosion-resistant metals that are widely used in the chemical and nuclear industries. Most zirconium is consumed in the form of the main ore mineral zircon (ZrSiO 4 , or as zirconium oxide or other zirconium chemicals. Zirconium and hafnium are both refractory lithophile elements that have nearly identical charge, ionic radii, and ionic potentials. As a result, their geochemical behavior is generally similar. Both elements are classified as incompatible because they have physical and crystallochemical properties that exclude them from the crystal lattices of most rock-forming minerals. Zircon and another, less common, ore mineral, baddeleyite (ZrO 2 ), form primarily as accessory minerals in igneous rocks. The presence and abundance of these ore minerals in igneous rocks are largely controlled by the element concentrations in the magma source and by the processes of melt generation and evolution. The world’s largest primary deposits of zirconium and hafnium are associated with alkaline igneous rocks, and, in one locality on the Kola Peninsula of Murmanskaya Oblast, Russia, baddeleyite is recovered as a byproduct of apatite and magnetite mining. Otherwise, there are few primary igneous deposits of zirconium- and hafnium-bearing minerals with economic value at present. The main ore deposits worldwide are heavy-mineral sands produced by the weathering and erosion of preexisting rocks and the concentration of zircon and other economically important heavy minerals, such as ilmenite and rutile (for titanium), chromite (for chromium), and monazite (for rare-earth elements) in sedimentary systems, particularly in coastal environments. In coastal deposits, heavy-mineral enrichment occurs where sediment is repeatedly reworked by wind, waves, currents, and tidal processes. The resulting heavy-mineral-sand deposits, called placers or paleoplacers, preferentially form at relatively low latitudes on passive continental margins and supply 100 percent of the world’s zircon. Zircon makes up a relatively small percentage of the economic heavy minerals in most deposits and is produced primarily as a byproduct of heavy-mineral-sand mining for titanium minerals. From 2003 to 2012, world zirconium mineral concentrates production increased by more than 40 percent, and Australia and South Africa were the leading producers. Global consumption of zirconium mineral concentrates generally increased during the same time period, largely as a result of increased demand in developing economies in Asia and the Middle East. Global demand weakened in 2012, causing a decrease in world production of zirconium mineral concentrates and delaying the development of several new mining projects. Global consumption is expected to increase in the future, however, as demand from the ceramics, chemicals, and metals industries increases (driven by renewed growth in developing economies) and demand for zirconium and hafnium metal increases (driven by the construction and operation of new nuclear powerplants). The behaviors of zirconium and hafnium in the environment are very similar to one another in that most zirconium- and hafnium-bearing minerals have limited solubility and reactivity. Anthropogenic sources of zirconium, and likely hafnium, are from industrial zirconium-containing byproducts and emissions from the processing of sponge zirconium, and exposure to the general population from these sources is small. Zirconium and hafnium are likely not essential to human health and generally are considered to be of low toxicity to humans. The main exposure risks are associated with industrial inhalation and dermal exposure. Because of the low solubility of zirconium and hafnium, ecological health concerns in the aquatic environment and in soils are minimal. Heavy-mineral-sand mining may lead to increased erosion rates when the mining is managed improperly. In addition, surface mining requires removal of the overlying organic soil layer and produces waste material that includes tailings and slimes. The soil removal and mining activity disturbs the surrounding ecosystem and alters the character of the landscape. Dry mineral separation processes create high amounts of airborne dust, whereas wet mineral separation processes do not. In operations that restore the landscape to pre-mining conditions, the volume of waste and the impact on the landscape may be relatively temporary.
Cruise report; RV Coastal Surveyor Cruise C1-99; multibeam mapping of the Long Beach, California continental shelf; April 12 through May 19, 1999
The greater Los Angeles area of California is home to more than 10 million people. This large population puts increased pressure on the adjacent offshore continental shelf and margin with activities such as ocean disposal for dredged spoils, explosive disposal, waste-water outfall, and commercial fishing. The increased utilization of the shelf and margin in this area has generated accelerated multi-disciplinary research efforts in all aspects of the environment of the coastal zone. Prior to 1996 there were no highly accurate base maps of the continental shelf and slope upon which the research activities could be located and monitored. In 1996, the United States Geological Survey (USGS) Pacific Seafloor Mapping Project began to address this problem by mapping the Santa Monica shelf and margin (Fig. 1) using a state-of-the-art, high-resolution multibeam sonar system (Gardner, et al., 1996; 1999). Additional seafloor mapping in 1998 provided coverage of the continental margin from south of Newport to the proximal San Pedro Basin northwest of Palos Verdes Peninsula (Gardner, et al., 1998) (Fig. 1). The mapping of the seafloor in the greater Los Angeles continental shelf and margin was completed with a 30-day mapping of the Long Beach shelf in April and May 1999, the subject of this report. The objective of Cruise C-1-99-SC was to completely map the broad continental shelf from the eastern end of the Palos Verdes Peninsula to the narrow shelf south of Newport Beach, from the break in slope at about 120-m isobath to the inner shelf at about the 10-m isobath. Mapping the Long Beach shelf was jointly funded by the U.S. Geological Survey and the County of Orange (CA) Sanitation District and was conducted under a Cooperative Agreement with the Ocean Mapping Group from the University of New Brunswick (OMG/UNB). The OMG/UNB contracted with C&C Technologies, Inc. of Lafayette, LA for use of the RV Coastal Surveyor and the latest evolution of high-resolution multibeam sonars, a dual Kongsberg Simrad EM3000D.
Phytoplankton primary production in the world's estuarine-coastal ecosystems
Estuaries are biogeochemical hot spots because they receive large inputs of nutrients and organic carbon from land and oceans to support high rates of metabolism and primary production. We synthesize published rates of annual phytoplankton primary production (APPP) in marine ecosystems influenced by connectivity to land – estuaries, bays, lagoons, fjords and inland seas. Review of the scientific literature produced a compilation of 1148 values of APPP derived from monthly incubation assays to measure carbon assimilation or oxygen production. The median value of median APPP measurements in 131 ecosystems is 185 and the mean is 252 g C m −2 yr −1 , but the range is large: from −105 (net pelagic production in the Scheldt Estuary) to 1890 g C m −2 yr −1 (net phytoplankton production in Tamagawa Estuary). APPP varies up to 10-fold within ecosystems and 5-fold from year to year (but we only found eight APPP series longer than a decade so our knowledge of decadal-scale variability is limited). We use studies of individual places to build a conceptual model that integrates the mechanisms generating this large variability: nutrient supply, light limitation by turbidity, grazing by consumers, and physical processes (river inflow, ocean exchange, and inputs of heat, light and wind energy). We consider method as another source of variability because the compilation includes values derived from widely differing protocols. A simulation model shows that different methods reported in the literature can yield up to 3-fold variability depending on incubation protocols and methods for integrating measured rates over time and depth. Although attempts have been made to upscale measures of estuarine-coastal APPP, the empirical record is inadequate for yielding reliable global estimates. The record is deficient in three ways. First, it is highly biased by the large number of measurements made in northern Europe (particularly the Baltic region) and North America. Of the 1148 reported values of APPP, 958 come from sites between 30 and 60° N; we found only 36 for sites south of 20° N. Second, of the 131 ecosystems where APPP has been reported, 37% are based on measurements at only one location during 1 year. The accuracy of these values is unknown but probably low, given the large interannual and spatial variability within ecosystems. Finally, global assessments are confounded by measurements that are not intercomparable because they were made with different methods. Phytoplankton primary production along the continental margins is tightly linked to variability of water quality, biogeochemical processes including ocean–atmosphere CO 2 exchange, and production at higher trophic levels including species we harvest as food. The empirical record has deficiencies that preclude reliable global assessment of this key Earth system process. We face two grand challenges to resolve these deficiencies: (1) organize and fund an international effort to use a common method and measure APPP regularly across a network of coastal sites that are globally representative and sustained over time, and (2) integrate data into a unifying model to explain the wide range of variability across ecosystems and to project responses of APPP to regional manifestations of global change as it continues to unfold.