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At least 19 recordsLinked to original sources
USGS1970

Study and interpretation of the chemical characteristics of natural water

The chemical composition of natural water is derived from many different sources of solutes, including gases and aerosols from the atmosphere, weathering and erosion of rocks and soil, solution or precipitation reactions occurring below the land surface, and cultural effects resulting from activities of man. Some of the processes of solution or precipitation of minerals can be closely evaluated by means of principles of chemical equilibrium including the law of mass action and the Nernst equation. Other processes are irreversible and require consideration of reaction mechanisms and rates. The chemical composition of the crustal rocks of the earth and the composition of the ocean and the atmosphere are significant in evaluating sources of solutes in natural fresh water. The ways in which solutes are taken up or precipitated and the amounts present in solution are influenced by many environmental factors, especially climate, structure and position: of rock strata, and biochemical effects associated with life cycles of plants and animals, both microscopic and macroscopic. Taken all together and in application with the further influence of the general circulation of all water in the hydrologic cycle, the chemical principles and environmental factors form a basis for the developing science of natural-water chemistry. Fundamental data used in the determination of water quality are obtained by the chemical analysis of water samples in the laboratory or onsite sensing of chemical properties in the field. Sampling is complicated by changes in composition of moving water and the effects of particulate suspended material. Most of the constituents determined are reported in gravimetric units, usually milligrams per liter or milliequivalents per liter. More than 60 constituents and properties are included in water analyses frequently enough to provide a basis for consideration of the sources from which each is generally derived, most probable forms of elements and ions in solution, solubility controls, expected concentration ranges and other chemical factors. Concentrations of elements that are commonly present in amounts less than a few tens of micrograms per liter cannot always be easily explained, but present information suggests many are controlled by solubility of hydroxide or carbonate or by sorption on solid particles. Chemical analyses may be grouped and statistically evaluated by averages, frequency distributions, or ion correlations to summarize large volumes of data. Graphing of analyses or of groups of analyses aids in showing chemical relationships among waters, probable sources of solutes, areal water-quality regimen, and water-resources evaluation. Graphs may show water type based on chemical composition, relationships among ions, or groups of ions in individual waters or many waters considered simultaneously. The relationships of water quality to hydrologic parameters, such as stream discharge rate or ground-water flow patterns, can be shown by mathematical equations, graphs, and maps. About 75 water analyses selected from the literature are tabulated to illustrate the relationships described, and some of these, along with many others that are not tabulated, are also utilized in demonstrating graphing and mapping techniques. Relationships of water composition to source rock type are illustrated by graphs of some of the tabulated analyses. Activities of man may modify water composition extensively through direct effects of pollution and indirect results of water development, such as intrusion of sea water in ground-water aquifiers. Water-quality standards for domestic, agricultural, and industrial use have been published by various agencies. Irrigation project requirements for water quality are particularly intricate. Fundamental knowledge of processes that control natural water composition is required for rational management of water quality.

Water Supply Paper↗
USGS1959

Study and interpretation of the chemical characteristics of natural water

The chemical composition of natural water is derived from many different sources of solutes, including gases and aerosols from the atmosphere, weathering and erosion of rocks and soil, solution or precipitation reactions occurring below the land surface, and cultural effects resulting from activities of man. Some of the processes of solution or precipitation of minerals can be closely evaluated by means of principles of chemical equilibrium including the law of mass action and the Nernst equation. Other processes are irreversible and require consideration of reaction mechanisms and rates. The chemical composition of the crustal rocks of the earth and the composition of the ocean and the atmosphere are significant in evaluating sources of solutes in natural fresh water. The ways in which solutes are taken up or precipitated and the amounts present in solution are influenced by many environmental factors, especially climate, structure and position: of rock strata, and biochemical effects associated with life cycles of plants and animals, both microscopic and macroscopic. Taken all together and in application with the further influence of the general circulation of all water in the hydrologic cycle, the chemical principles and environmental factors form a basis for the developing science of natural-water chemistry. Fundamental data used in the determination of water quality are obtained by the chemical analysis of water samples in the laboratory or onsite sensing of chemical properties in the field. Sampling is complicated by changes in composition of moving water and the effects of particulate suspended material. Most of the constituents determined are reported in gravimetric units, usually milligrams per liter or milliequivalents per liter. More than 60 constituents and properties are included in water analyses frequently enough to provide a basis for consideration of the sources from which each is generally derived, most probable forms of elements and ions in solution, solubility controls, expected concentration ranges and other chemical factors. Concentrations of elements that are commonly present in amounts less than a few tens of micrograms per liter cannot always be easily explained, but present information suggests many are controlled by solubility of hydroxide or carbonate or by sorption on solid particles. Chemical analyses may be grouped and statistically evaluated by averages, frequency distributions, or ion correlations to summarize large volumes of data. Graphing of analyses or of groups of analyses aids in showing chemical relationships among waters, probable sources of solutes, areal water-quality regimen, and water-resources evaluation. Graphs may show water type based on chemical composition, relationships among ions, or groups of ions in individual waters or many waters considered simultaneously. The relationships of water quality to hydrologic parameters, such as stream discharge rate or ground-water flow patterns, can be shown by mathematical equations, graphs, and maps. About 75 water analyses selected from the literature are tabulated to illustrate the relationships described, and some of these, along with many others that are not tabulated, are also utilized in demonstrating graphing and mapping techniques. Relationships of water composition to source rock type are illustrated by graphs of some of the tabulated analyses. Activities of man may modify water composition extensively through direct effects of pollution and indirect results of water development, such as intrusion of sea water in ground-water aquifiers. Water-quality standards for domestic, agricultural, and industrial use have been published by various agencies. Irrigation project requirements for water quality are particularly intricate. Fundamental knowledge of processes that control natural water composition is required for rational management of water quality.

Water Supply Paper↗
USGS1985

Study and interpretation of the chemical characteristics of natural water

The chemical composition of natural water is derived from many different sources of solutes, including gases and aerosols from the atmosphere, weathering and erosion of rocks and soil, solution or precipitation reactions occurring below the land surface, and cultural effects resulting from human activities. Broad interrelationships among these processes and their effects can be discerned by application of principles of chemical thermodynamics. Some of the processes of solution or precipitation of minerals can be closely evaluated by means of principles of chemical equilibrium, including the law of mass action and the Nernst equation. Other processes are irreversible and require consideration of reaction mechanisms and rates. The chemical composition of the crustal rocks of the Earth and the composition of the ocean and the atmosphere are significant in evaluating sources of solutes in natural freshwater. The ways in which solutes are taken up or precipitated and the amounts present in solution are influenced by many environmental factors, especially climate, structure and position of rock strata, and biochemical effects associated with life cycles of plants and animals, both microscopic and macroscopic. Taken together and in application with the further influence of the general circulation of all water in the hydrologic cycle, the chemical principles and environmental factors form a basis for the developing science of natural-water chemistry. Fundamental data used in the determination of water quality are obtained by the chemical analysis of water samples in the laboratory or onsite sensing of chemical properties in the field. Sampling is complicated by changes in the composition of moving water and by the effects of particulate suspended material. Some constituents are unstable and require onsite determination or sample preservation. Most of the constituents determined are reported in gravimetric units, usually milligrams per liter or milliequivalents per liter. More than 60 constituents and properties are included in water analyses frequently enough to provide a basis for consideration of the sources from which each is generally derived, the most probable forms of elements and ions in solution, solubilitycontrols, expected concentration ranges, and other chemical factors. Mechanisms that control concentrations of elements commonly present in amounts less than a few tens of micrograms per liter cannot always be easily ascertained, but present information suggests that many are controlled by solubility of their hydroxides or carbonates or by sorption on solid particles. Many dissolved organic compounds can now be specifically determined. Chemical analyses may be grouped and statistically evaluated by means, medians, frequency distributions, or ion correlations to summarize large volumes of data. Graphing of analyses or of groups of analyses aids in showing chemical relationships among water, probable sources of solutes, areal water-quality regimen, temporal and spatial variation, and water-resources evaluation. Graphs may show water type based on chemical composition, relationships among ions, or groups of ions in individual waters or many waters considered simultaneously. The relationships of water quality to hydrogeologic characteristics, such as stream discharge rate or ground-water flow patterns, can be shown by mathematical equations, graphs, and maps. About 80 water analyses selected from the literature are tabulated to illustrate the relationships described, and some of these, along with many others that are not tabulated, are also used in demonstrating graphing and mapping techniques. Relationships of water composition to source rock type are illustrated by graphs of some of the tabulated analyses. Human activities may modify water composition extensively through direct effects of pollution and indirect results of water development, such as intrusion of seawater in groundwater aquifers. Water-quality standards for domestic, agricultural, and industrial use have been published by various agencies. Irrigation project requirements for water quality are particularly intricate. Fundamental knowledge of processes that control natural-water composition is required for rational management of water quality.

Water Supply Paper↗
USGS2022

Hyperspectral remote sensing of white mica: A review of imaging and point-based spectrometer studies for mineral resources, with spectrometer design considerations

Over the past ~30 years, hyperspectral remote sensing of chemical variations in white mica have proven to be useful for ore deposit studies in a range of deposit types. To better understand mineral deposits and to guide spectrometer design, this contribution reviews relevant papers from the fields of remote sensing, spectroscopy, and geology that have utilized spectral changes caused by chemical variation in white micas. This contribution reviews spectral studies conducted at the following types of mineral deposits: base metal sulfide, epithermal, porphyry, sedimentary rock hosted gold deposits, orogenic gold, iron oxide copper gold, and unconformity-related uranium. The structure, chemical composition, and spectral features of white micas, in this contribution defined as muscovite, paragonite, celadonite, phengite, illite, and sericite, are given. Reviewed laboratory spectral studies determined that shifts in the position of the white mica 2200 nm combination feature of 1 nm correspond to a change in Al oct content of approximately ±1.05%. Many of the reviewed spectral studies indicated that a shift in the position of the white mica 2200 nm combination feature of 1 nm was geologically significant. A sensitivity analysis of spectrometer characteristics; bandpass, sampling interval, and channel position, is conducted using spectra of 19 white micas with deep absorption features to determine minimum characteristics required to accurately measure a shift in the position of the white mica 2200 nm combination feature. It was determined that a sampling interval < 16.3 nm and bandpass <17.5 nm are needed to achieve a root mean square error (RMSE) of 2 nm, whereas a sampling interval < 8.8 nm and bandpass <9.8 nm are needed to achieve a RMSE of 1 nm. For comparison, commonly used imaging spectrometers HyMap, AVIRIS-Classic, SpecTIR®'s AisaFENIX 1K, and HySpex tm SWIR 384 have 2.1, 1.2, 0.96, and 0.95 nm RMSE in determining the position of the 2200 nm white mica combination feature, respectively. An additional sensitivity analysis is conducted to determine the effect of signal to noise ratio (SNR) on the RMSE of the position of the white mica 2200 nm combination feature, using spectra of 18 white micas with deep absorption features. For a spectrometer with sampling interval and bandpass of 1 nm, we estimate that RMSEs of 1 and 1.5 nm are achievable with spectra having a minimum SNR of approximately 246 and 64, respectively. For a spectrometer with sampling interval and bandpass of 5 nm, we estimate that RMSEs of 1 and 1.5 nm are attainable with spectra having a minimum SNR of approximately 431 and 84, respectively. When using a spectrometer with a sampling interval 8.8 nm and a bandpass of 9.8 nm, a RMSE of 1 is only achievable with convolved, noiseless reference spectra. For the 8.8_9.8 nm spectrometer, spectra with SNR of 250 and 100 result in RMSE of 1.1 and 1.3, respectively. Therefore, fine spectral resolution characteristics achieve RMSEs better than 1 nm for high SNR spectra while spectrometers with coarse spectral resolution have larger RMSE, perform well with noisy data, and are useful for white mica studies if RMSE of 1.1 to 1.5 nm is acceptable.

Remote Sensing of Environment↗
USGS2014

Bile salts as semiochemicals in fish

Bile salts are potent olfactory stimuli in fishes; however the biological functions driving such sensitivity remain poorly understood. We provide an integrative review of bile salts as semiochemicals in fish. First, we present characteristics of bile salt structure, metabolism, and function that are particularly relevant to chemical communication. Bile salts display a systematic pattern of structural variation across taxa, are efficiently synthesized, and are stable in the environment. Bile salts are released into the water via the intestine, urinary tract, or gills, and are highly water soluble. Second, we consider the potential role of bile salts as semiochemicals in the contexts of detecting nearby fish, foraging, assessing risk, migrating, and spawning. Lastly, we suggest future studies on bile salts as semiochemicals further characterize release into the environment, behavioral responses by receivers, and directly test the biological contexts underlying olfactory sensitivity.

Chemical Senses↗
USGS2007

Role of chemotaxis in the transport of bacteria through saturated porous media

Populations of chemotactic bacteria are able to sense and respond to chemical gradients in their surroundings and direct their migration toward increasing concentrations of chemicals that they perceive to be beneficial to their survival. It has been suggested that this phenomenon may facilitate bioremediation processes by bringing bacteria into closer proximity to the chemical contaminants that they degrade. To determine the significance of chemotaxis in these processes it is necessary to quantify the magnitude of the response and compare it to other groundwater processes that affect the fate and transport of bacteria. We present a systematic approach toward quantifying the chemotactic response of bacteria in laboratory scale experiments by starting with simple, well-defined systems and gradually increasing their complexity. Swimming properties of individual cells were assessed from trajectories recorded by a tracking microscope. These properties were used to calculate motility and chemotaxis coefficients of bacterial populations in bulk aqueous media which were compared to experimental results of diffusion studies. Then effective values of motility and chemotaxis coefficients in single pores, pore networks and packed columns were analyzed. These were used to estimate the magnitude of the chemotactic response in porous media and to compare with dispersion coefficients reported in the field. This represents a compilation of many studies over a number of years. While there are certainly limitations with this approach for ultimately quantifying motility and chemotaxis in granular aquifer media, it does provide insight into what order of magnitude responses are possible and which characteristics of the bacteria and media are expected to be important.

Advances in Water Resources↗
USGS2022

GW/SW-MST: A groundwater/surface-water method selection tool

Groundwater/surface-water (GW/SW) exchange and hyporheic processes are topics receiving increasing attention from the hydrologic community. Hydraulic, chemical, temperature, geophysical, and remote sensing methods are used to achieve various goals (e.g., inference of GW/SW exchange, mapping of bed materials, etc.), but the application of these methods is constrained by site conditions such as water depth, specific conductance, bed material, and other factors. Researchers and environmental professionals working on GW/SW problems come from diverse fields and rarely have expertise in all available field methods; hence there is a need for guidance to design field campaigns and select methods that both contribute to study goals and are likely to work under site-specific conditions. Here, we present the spreadsheet-based GW/SW-Method Selection Tool (GW/SW-MST) to help practitioners identify methods for use in GW/SW and hyporheic studies. The GW/SW-MST is a Microsoft Excel-based decision support tool in which the user selects answers to questions about GW/SW-related study goals and site parameters and characteristics. Based on user input, the tool indicates which methods from a toolbox of 32 methods could potentially contribute to achieving the specified goals at the site described.

Groundwater↗
USGS2024

Development of high surface area organosilicate nanoparticulate thin films for use in sensing hydrophobic compounds in sediment and water

The scope of this study was to apply advances in materials science, specifically the use of organosilicate nanoparticles as a high surface area platform for passive sampling of chemicals or pre-concentration for active sensing in multiple-phase complex environmental media. We have developed a novel nanoporous organosilicate (NPO) film as an extraction phase and proof of concept for application in adsorbing hydrophobic compounds in water and sediment. We characterized the NPO film properties and provided optimization for synthesis and coatings in order to apply the technology in environmental media. NPO films in this study had a very high surface area, up to 1325 m 2 /g due to the high level of mesoporosity in the film. The potential application of the NPO film as a sorbent phase for sensors or passive samplers was evaluated using a model hydrophobic chemical, polychlorinated biphenyls (PCB), in water and sediment. Sorption of PCB to this porous high surface area nanoparticle platform was highly correlated with the bioavailable fraction of PCB measured using whole sediment chemistry, porewater chemistry determined by solid-phase microextraction fiber methods, and the Lumbriculus variegatus bioaccumulation bioassay. The surface-modified NPO films in this study were found to highly sorb chemicals with a log octanol-water partition coefficient (K ow ) greater than four; however, surface modification of these particles would be required for application to other chemicals.

Biosensors↗
USGS1987

Remote sensing investigations at a hazardous-waste landfill

In 1976 state licensed landfilling of industrial chemicals was begun above an abandoned, underground coal mine in Illinois. Five years later organic chemical pollutants were discovered in a monitoring well, suggesting migration 100 to 1000 times faster than predicted by laboratory tests. Remote sensing contributed to the determination of the causes of faster-than-predicted pollutant migration at the hazardous-waste landfill. Aerial and satellite imagery were employed to supplement field studies of local surface and groundwater hydrology, and to chronicle site history. Drainage impediments and depressions in the trench covers collected runoff, allowing rapid recharge of surface waters to some burial trenches. These features can be more effectively identified by photointerpretation than by conventional field reconnaissance. A ground-based, post-sunset survey of the trench covers that showed that a distinction between depressions which hold moisture at the surface from freely-draining depressions which permit rapid recharge to the burial trenches could be made using thermal infrared imagery.In 1976 state licensed landfilling of industrial chemicals was begun above an abandoned, underground coal mine in Illinois. Five years later organic chemical pollutants were discovered in a monitoring well, suggesting migration 100 to 1000 times faster than predicted by laboratory tests. Remote sensing contributed to the determination of the causes of faster-than-predicted pollutant migration at the hazardous-waste landfill. Aerial and satellite imagery were employed to supplement field studies of local surface and groundwater hydrology, and to chronicle site history. Drainage impediments and depressions in the trench covers collected runoff, allowing rapid recharge of surface waters to some burial trenches.

Photogrammetric Engineering and Remote Sensing↗
USGS2017

USGS Spectral Library Version 7

We have assembled a library of spectra measured with laboratory, field, and airborne spectrometers. The instruments used cover wavelengths from the ultraviolet to the far infrared (0.2 to 200 microns [μm]). Laboratory samples of specific minerals, plants, chemical compounds, and manmade materials were measured. In many cases, samples were purified, so that unique spectral features of a material can be related to its chemical structure. These spectro-chemical links are important for interpreting remotely sensed data collected in the field or from an aircraft or spacecraft. This library also contains physically constructed as well as mathematically computed mixtures. Four different spectrometer types were used to measure spectra in the library: (1) Beckman™ 5270 covering the spectral range 0.2 to 3 µm, (2) standard, high resolution (hi-res), and high-resolution Next Generation (hi-resNG) models of Analytical Spectral Devices (ASD) field portable spectrometers covering the range from 0.35 to 2.5 µm, (3) Nicolet™ Fourier Transform Infra-Red (FTIR) interferometer spectrometers covering the range from about 1.12 to 216 µm, and (4) the NASA Airborne Visible/Infra-Red Imaging Spectrometer AVIRIS, covering the range 0.37 to 2.5 µm. Measurements of rocks, soils, and natural mixtures of minerals were made in laboratory and field settings. Spectra of plant components and vegetation plots, comprising many plant types and species with varying backgrounds, are also in this library. Measurements by airborne spectrometers are included for forested vegetation plots, in which the trees are too tall for measurement by a field spectrometer. This report describes the instruments used, the organization of materials into chapters, metadata descriptions of spectra and samples, and possible artifacts in the spectral measurements. To facilitate greater application of the spectra, the library has also been convolved to selected spectrometer and imaging spectrometers sampling and bandpasses, and resampled to selected broadband multispectral sensors. The native file format of the library is the SPECtrum Processing Routines (SPECPR) data format. This report describes how to access freely available software to read the SPECPR format. To facilitate broader access to the library, we produced generic formats of the spectra and metadata in text files. The library is provided on digital media and online at https://speclab.cr.usgs.gov/spectral-lib.html . A long-term archive of these data are stored on the USGS ScienceBase data server ( https://dx.doi.org/10.5066/F7RR1WDJ ).

Data Series↗
USGS1980

Lunar remote sensing and measurements

Remote sensing and measurements of the Moon from Apollo orbiting spacecraft and Earth form a basis for extrapolation of Apollo surface data to regions of the Moon where manned and unmanned spacecraft have not been and may be used to discover target regions for future lunar exploration which will produce the highest scientific yields. Orbital remote sensing and measurements discussed include (1) relative ages and inferred absolute ages, (2) gravity, (3) magnetism, (4) chemical composition, and (5) reflection of radar waves (bistatic). Earth-based remote sensing and measurements discussed include (1) reflection of sunlight, (2) reflection and scattering of radar waves, and (3) infrared eclipse temperatures. Photographs from the Apollo missions, Lunar Orbiters, and other sources provide a fundamental source of data on the geology and topography of the Moon and a basis for comparing, correlating, and testing the remote sensing and measurements. Relative ages obtained from crater statistics and then empirically correlated with absolute ages indicate that significant lunar volcanism continued to 2.5 b.y. (billion years) ago-some 600 m.y. (million years) after the youngest volcanic rocks sampled by Apollo-and that intensive bombardment of the Moon occurred in the interval of 3.84 to 3.9 b.y. ago. Estimated fluxes of crater-producing objects during the last 50 m.y. agree fairly well with fluxes measured by the Apollo passive seismic stations. Gravity measurements obtained by observing orbiting spacecraft reveal that mare basins have mass concentrations and that the volume of material ejected from the Orientale basin is near 2 to 5 million km 3 depending on whether there has or has not been isostatic compensation, little or none of which has occurred since 3.84 b.y. ago. Isostatic compensation may have occurred in some of the old large lunar basins, but more data are needed to prove it. Steady fields of remanent magnetism were detected by the Apollo 15 and 16 subsatellites, and the lunar dipole field was revised to no more than 6x 10 19 gauss. High-resolution mapping of fields of weak remanent magnetism (to 0.1 gamma) was made possible by the Apollo plasma and energetic-particle experiment. Although the causes of remanent magnetism are poorly understood, correlations with geologic units suggest the results may ultimately have farreaching significance to lunar history. Maria are much less structured by strong surface magnetic anomalies than the highlands. The strongest anomalies are associated with ejecta of farside basins, plains materials filling pre-Imbrian craters, and other old Imbrian to pre-Imbrian units. The high remanent fields could be due to cooling of ejecta units in an ancient magnetic field, lunar regolith maturity, extensive reworking and disruption of a magnetized layer, or simply surface roughness. Orbital geochemical experiments have shown that lunar high lands have larger Al: Si ratios and smaller Mg: Si ratios than maria. These two ratios are inversely related on a regional basis. With the exception of fresh craters, albedo and Al : Si ratios vary directly, showing that compositional differences as well as exposure of fresh materials are responsible for high albedos. Statistically treated data show that geologic contacts and compositional boundaries are concentric and can be roughly matched. Some craters on mare material have penetrated the mare fill, bringing highland-type materials to the surface. Natural radioactivity from thorium, potassium, and uranium is inversely correlated with elevation. Mare regions are enriched in iron, titanium, and magnesium relative to the highlands. Orbital bistatic-radar results provide estimates of surface roughness at two scale lengths (about 30 m and 250 m), which agree with visual estimates of roughness. The dielectric constant of the lunar surface, where sampled, is uniform to 13-cm radar and near 3. Slope frequency distributions measured by the radar vary and

Professional Paper↗
USGS2003

Imaging spectroscopy: Earth and planetary remote sensing with the USGS Tetracorder and expert systems

Imaging spectroscopy is a tool that can be used to spectrally identify and spatially map materials based on their specific chemical bonds. Spectroscopic analysis requires significantly more sophistication than has been employed in conventional broadband remote sensing analysis. We describe a new system that is effective at material identification and mapping: a set of algorithms within an expert system decision‐making framework that we call Tetracorder. The expertise in the system has been derived from scientific knowledge of spectral identification. The expert system rules are implemented in a decision tree where multiple algorithms are applied to spectral analysis, additional expert rules and algorithms can be applied based on initial results, and more decisions are made until spectral analysis is complete. Because certain spectral features are indicative of specific chemical bonds in materials, the system can accurately identify and map those materials. In this paper we describe the framework of the decision making process used for spectral identification, describe specific spectral feature analysis algorithms, and give examples of what analyses and types of maps are possible with imaging spectroscopy data. We also present the expert system rules that describe which diagnostic spectral features are used in the decision making process for a set of spectra of minerals and other common materials. We demonstrate the applications of Tetracorder to identify and map surface minerals, to detect sources of acid rock drainage, and to map vegetation species, ice, melting snow, water, and water pollution, all with one set of expert system rules. Mineral mapping can aid in geologic mapping and fault detection and can provide a better understanding of weathering, mineralization, hydrothermal alteration, and other geologic processes. Environmental site assessment, such as mapping source areas of acid mine drainage, has resulted in the acceleration of site cleanup, saving millions of dollars and years in cleanup time. Imaging spectroscopy data and Tetracorder analysis can be used to study both terrestrial and planetary science problems. Imaging spectroscopy can be used to probe planetary systems, including their atmospheres, oceans, and land surfaces.

Journal of Geophysical Research E: Planets↗
USGS1975

Thermal-infrared spectra and chemical analyses of twenty-six igneous rock samples

Emittance spectra in the 7.5 μm to 14 μm wavelength region and chemical compositions of 26 igneous rocks are reported. Experimental measurements on the rocks were made under simulated daytime field conditions. Some surface silicate contaminants, such as clayey silt, significantly altered the spectral emittance of a fresh sample, whereas, for these samples, hydrous and anhydrous ferric oxide weathering products did not mask important silicate spectral information. In the 11.75 μm to 13.75 μm wavelength region, the mean emittance of all the silicate samples was0.956 ± 0.008, except for periodtite, which had an average emittance of 0.895. This region of uniform emittance should be useful in remote sensing experiments for the separation of the effects of temperature and chemical composition on the spectral emittance of silicate rocks.

Remote Sensing of Environment↗
USGS2009

Use of land surface remotely sensed satellite and airborne data for environmental exposure assessment in cancer research

In recent years, geographic information systems (GIS) have increasingly been used for reconstructing individual-level exposures to environmental contaminants in epidemiological research. Remotely sensed data can be useful in creating space-time models of environmental measures. The primary advantage of using remotely sensed data is that it allows for study at the local scale (e.g., residential level) without requiring expensive, time-consuming monitoring campaigns. The purpose of our study was to identify how land surface remotely sensed data are currently being used to study the relationship between cancer and environmental contaminants, focusing primarily on agricultural chemical exposure assessment applications. We present the results of a comprehensive literature review of epidemiological research where remotely sensed imagery or land cover maps derived from remotely sensed imagery were applied. We also discuss the strengths and limitations of the most commonly used imagery data (aerial photographs and Landsat satellite imagery) and land cover maps.

Journal of Exposure Science and Environmental Epid↗
USGS2024

National-scale remotely sensed lake trophic state from 1984 through 2020

Lake trophic state is a key ecosystem property that integrates a lake’s physical, chemical, and biological processes. Despite the importance of trophic state as a gauge of lake water quality, standardized and machine-readable observations are uncommon. Remote sensing presents an opportunity to detect and analyze lake trophic state with reproducible, robust methods across time and space. We used Landsat surface reflectance data to create the first compendium of annual lake trophic state for 55,662 lakes of at least 10 ha in area throughout the contiguous United States from 1984 through 2020. The dataset was constructed with FAIR data principles (Findable, Accessible, Interoperable, and Reproducible) in mind, where data are publicly available, relational keys from parent datasets are retained, and all data wrangling and modeling routines are scripted for future reuse. Together, this resource offers critical data to address basic and applied research questions about lake water quality at a suite of spatial and temporal scales.

Scientific Data↗
USGS2002

Lake Pontchartrain Basin: Bottom sediments and related environmental resources

Lake Pontchartrain is the largest estuary southern Louisiana. It is an important recreational, commercial, and environmental resource for New Orleans and southwestern Louisiana. This publication is part of a 5-year cooperative program led by the USGS on the geological framework and sedimentary processes of the Lake Pontchartrain Basin. This presentation is divided into two main parts: - Scientific Research and Assessments - Multimedia Tools and Regional Resources The scientific sections include historical information on the area; shipboard, field, and remote sensing studies; and a comprehensive sediment database with geological and chemical discussions of the region. The multimedia and resources sections include Geographic Information System (GIS) tools and data, a video demonstrating vibracore sampling techniques in Lake Pontchartrain, and abstracts from four Basics of the Basin symposia.

Louisiana↗
USGS1977

The Aristarchus-Harbinger region of the moon: Surface geology and history from recent remote-sensing observations

The region including the Aristarchus Plateau and Montes Harbinger is probably the most diverse, geologically, of any area of comparble size on the Moon. This part of the northwest quadrant of the lunar near side includes unique dark mantling material; both the densest concentration and the largest of the sinuous rilles; apparent volcanic vents, sinks, and domes; mare materials of various ages and colors; one of the freshest large craters (Aristarchus) with ejecta having unique colors and albedos; and three other large craters in different states of flooding and degradation (krieger, Herodotus, and Prinz). The three best-authenticated lunar transient phenomena were also observed here. This study is based principally on photographic and remote sensing observations made from Earth and Apollo orbiting space craft. Results include (1) delineation of geologic map units and their stratigraphic relationships; (2) discussion of the complex interrelationships between materials of volcanic and impact origin, including the effects of excavation, redistribution and mixing of previously deposited materials by younger impact craters; (3) deduction of physical and chemical properties of certain of the geologic units, based on both the remote-sensing information and on extrapolation of Apollo data to this area; and (4) development of a detailed geologic history of the region, outlining the probable sequence of events that resulted in its present appearance. A primary concern of the investigation has been anomalous red dark mantle on the Plateau. Based on an integration of Earth- and lunar orbit-based data, this layer seems to consist of fine-grained, block-free material containing a relatively large fraction of orange glass. It is probably of pyroclastic origin, laid down at some time during the Imbrian period of mare flooding. ?? 1977 D. Reidel Publishing Company.

The Moon↗
USGS2025

Confluence of time and space: An innovation for quantifying dynamics of hydrologic floodplain connectivity with remote sensing and GIS

Hydrologic connectivity is a crucial determinant of aquatic ecosystem services, governing the exchange of nutrients, sediments, chemicals, and biota. Various indices and metrics exist for quantifying hydrologic connectivity across diverse environments and scales. However, existing methodologies often fail to adequately capture lateral connectivity between floodplain lakes and streams across vast, low-relief, multi-lake floodplain systems. This study introduces a novel approach for quantifying lateral hydrologic connectivity specifically tailored for floodplain lakes connecting to streams within the expansive floodplain of the Lower Mississippi River. This approach centers on the spatial and temporal intersection of lakes and streams, leveraging remote sensing and GIS data to estimate nine distinct metrics of hydrologic connectivity. To assess the reliability of the method, the study estimated connectivity metrics for 92 randomly selected floodplain lakes, comprising 53 lakes connected to large streams (Strahler order >7), 13 lakes connected to medium (order 4-6) streams, and 26 lakes connected to small (order 1-3) streams. As expected, there was significant variability in hydrologic connectivity across different stream size classes. The outlined approach contributes valuable insights into the hydrologic connectivity of floodplain lakes and offers a generalizable framework applicable to other floodplains. Its versatility makes it a practical tool for understanding connectivity requirements for biota and facilitating applications in conservation and water resources management. Thus, this work represents a meaningful step toward advancing our understanding of lateral hydrologic connectivity dynamics in complex aquatic ecosystems.

Arkansas, Illinois, Kentucky, Louisiana, Mississip↗