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The Conterminous United States Mineral Assessment Program: Background information to accompany folio of geologic, geochemical, geophysical, and mineral resource maps of the Ajo and Lukeville 1° by 2° quadrangles, Arizona

Encompassing about 21,000 km 2 in southwestern Arizona, the Ajo and Lukeville 1° by 2° quadrangles have been the subject of mineral resource investigations utilizing field and laboratory studies in the disciplines of geology, geochemistry, geophysics, and Landsat imagery. The results of these studies are published as a folio of maps, figures, and tables, with accompanying discussions. Past mineral production has been limited to copper from the Ajo Mining District. In addition to copper, the quadrangles contain potentially significant resources of gold and silver; a few other commodities, including molybdenum and evaporites, may also exist in the area as appreciable resources. This circular provides background information on the mineral deposits and on the investigations and integrates the information presented in the folio. The bibliography cites references to the geology, geochemistry, geophysics, and mineral deposits of the two quadrangles.

Arizona↗

Water-resources activities of the U.S. Geological Survey in Missouri, fiscal year 1989

Water resources activities of the U.S. Geological Survey in Missouri consist of collecting hydrologic data and making interpretive studies. Hydrologic studies in Missouri are made through three basic types of projects: hydrologic data collection programs; local or areal hydrologic investigations; and statewide or regional studies. These projects are funded through cooperative joint-funding agreements with State and local agencies, transfer of funds from other Federal agencies, and direct Federal funds. The data and the results of the investigations are published or released by either the U.S. Geological Survey or by cooperating agencies. The report describes the hydrologic data collection programs and local or areal hydrologic investigations in Missouri for fiscal year 1989 and provides a list of selected water resources references for Missouri. (USGS)

Open-File Report↗

Geology of the Andover Granite and surrounding rocks, Massachusetts

Field and petrographic studies of the Andover Granite and surrounding rocks have afforded an opportunity for an explanation of its emplacement and crystallization. The investigation has contributed secondarily to an understanding of the geologic history of southeastern New England, particularly as it is revealed in the Lawrence, Wilmington, South Groveland, and Reading quadrangles of Massachusetts. The Andover Granite and Sharpners Pond Tonalite together comprise up to 90 percent of the Acadian(?) subalkaline intrusive series cropping out within the area of study. The subalkaline series locally invades a sequence of early to middle Paleozoic and possibly Precambrian metasedimentary and metavolcanic rocks. Much of the subalkaline series and most of the Andover Granite is confined between two prominent east-northeast trending faults or fault systems. The northern fault separates the mildly metamorphosed Middle Silurian(?) Merrimack Group on the north from a highly metamorphosed and thoroughly intruded Ordovician(?) sequence on the south. The southern 'boundary '' fault is a major structural discontinuity characterized by penetrative, diffuse shearing over a zone one-half mile or more in width. The magmatic nature of the Andover Granite is demonstrated by: (1) sharply crosscutting relationships with surrounding rocks; (2) the occurrence of tabular-shaped xenoliths whose long directions parallel the foliation within the granite and whose internal foliation trends at a high angle to that of the granite; (3) continuity with the clearly intrusive Sharpners Pond Tonalite; (4) the compositional uniformity of the granite as contrasted with the compositional diversity of the rocks it invades; (5) its modal and normative correspondence with (a) calculated norms of salic extrusives and (b) that of the ternary (granite) minimum for the system NaAlSi3O8-KAlSi3O8-SiO2. Orogenic granites, as represented by the Andover, contrast with post-orogenic granites, represented locally by the Peabody Granite, in their phase composition and texture. Unlike the Peabody, the Andover Granite is thought to have been thoroughly recrystallized through the unmixing of initially homogeneous phases with the concomitant development of extremely intricate, allotriomorphic textures. Textural relationships between potassium and plagioclase feldspars and among quartz and the two feldspars, suggest that the Andover Granite has evolved through exsolution of a single hypersolvus feldspar (or two coexisting subsolvus feldspars of only slightly disparate compositions) into discrete grains of plagioclase and potassium feldspar, much along the lines proposed by Tuttle (1952). A hypothesis is proposed for the origin of myrmekite whereby it is evolved indirectly through exsolution of a homogeneous, hypersolvus, calcalkali feldspar in the presence of a silica reservoir. Where the An 'molecule' is contained in the primary mix crystal, exsolution into potassium and plagioclase feldspar phases normally requires a paired exchange between Ca-Al and K-Si. Should the silicon requirements of the developing potassium feldspar be met by the matrix silica reservoir, the concomitantly evolving plagioclase may become stoichiometrically enriched in silicon and ultimately develop into myrmekite. Discrete unmixing of pure alkali feldspar proceeds through simple alkali ion exchange; ternary compostions high in An are more apt to fall initially in the two-feldspar field, thereby reducing the unmixing potential. General restriction of myrmekite to plagioclase of calcic albite to oligoclase composition is explained accordingly.

Open-File Report↗

Geologic map of the Palo Alto and part of the Redwood Point 7-1/2' quadrangles, San Mateo and Santa Clara Counties, California

The Palo Alto and southern part of the Redwood Point 7-1/2' quadrangles cover an area on the San Francisco peninsula between San Francisco Bay and the Santa Cruz Mountains. San Francisquito and Los Trancos Creeks, in the southeastern part of the map area, form the boundary between San Mateo and Santa Clara Counties. The area covered by the geologic map extends from tidal and marsh lands at the edge of the bay southward across a gently sloping alluvial plain to the foothills of the northern Santa Cruz Mountains. The foothills are separated from the main mass of the mountains by two northwest-striking faults, the San Andreas and Pilarcitos, that cross the southwest corner of the map area (fig. 1). The map and adjoining areas are here divided into three structural blocks juxtaposed along these faults, adopting the scheme of Nilsen and Brabb (1979): (1) the San Francisco Bay block lying east of the San Andreas Fault Zone; (2) the Pilarcitos block lying between the San Andreas and Pilarcitos Faults; and (3) the La Honda block that includes the main mass of the Santa Cruz Mountains lying west of the Pilarcitos Fault. The west boundary of the La Honda block is the Seal Cove-San Gregorio Fault. Pre-late Pleistocene Cenozoic rocks of the foothills have been compressed into northwest-striking folds, which have been overridden by Mesozoic rocks along southwest-dipping low-angle faults. Coarse- to fine-grained upper Pleistocene and Holocene alluvial and estuarine deposits, eroded from the foothills and composing the alluvial plain, are essentially undeformed. Most of the alluvial plain, including some parts of the marsh land that borders the bay, has been covered by residential and commercial developments, and virtually all of the remaining marsh land has been diked off and used as salt evaporating ponds. The map area includes parts of the municipalities of San Carlos, Redwood City, Atherton, Woodside, Portola Valley, Menlo Park, and East Palo Alto in San Mateo County; and Palo Alto, Stanford University, Los Altos, and Los Altos Hills in Santa Clara County (fig. 2). Much of the university land remains as undeveloped open space surrounded by densely urbanized lands. Geologic maps of all or part of the present map area have been prepared previously by Branner and others (1909), Thomas (1949), Dobbs and Forbes (1960), Dibblee (1966), Page and Tabor (1967), Pampeyan (1970a, 1970b), Beaulieu (1970), Helley and others (1979), and by numerous Stanford University students working on topical earth science problems. In addition, numerous engineering geologic studies have been conducted for site investigations relating to residential and commercial developments and, in particular, for construction of the Stanford Linear Accelerator Center (SLAC). The reports pertaining to SLAC are summarized in Skjei and others (1965) and more recently in a report by Earth Sciences Associates (1983). The interested reader is referred to Brabb and Pampeyan (1983), Brabb and others (1982), Wentworth and others (1985), Wieczorek and others (1985), Thomson and Evernden (1986), Brabb and Olson (1986), Youd and Perkins (1987), Perkins (1987), and Mark and Newman (1988) for information pertaining to geology, history, slope stability, seismic shaking, liquifaction potential, and faulting and seismicity in San Mateo County, some of which can be applied directly to northern Santa Clara County. Field work for the present geologic map was done in 1962-1964 and 1966 when SLAC and Interstate 280 were in early stages of construction. Only minor additions and revisions have been made since this mapping was first released (Pampeyan, 1970a; 1970b) as it was impractical to keep pace with accelerating urban development of the area. Geologic units of the flatlands area are largely adapted from Helley and Lajoie (1979).

California↗

Hydrogeologic data for the Upper Connecticut River Basin, Connecticut

This report contains geologic, ground-water, and quality-of-water data collected and compiled for a water resources investigation of the upper Connecticut River basin, Connecticut by the U.S. Geological Survey in financial cooperation with the Connecticut Department of Environmental Protection. These data, together with surface-water data, were collected at sites shown on plate A and are, with exceptions discussed below, presented herein. The interpretation of these data will be published separately in Connecticut Water Resources Bulletin No. 24. As defined for this investigation, the upper Connecticut River basin is a 508-square-mile area in north-central Connecticut (see front cover and plate A) drained by the Connecticut River and its tributaries including the Farmington River downstream from the community of Tariffville. The basin includes all or parts of the following 30 towns: Avon, Bloomfield, Bolton, Cromwell, East Granby, East Hampton, East Hartford, East Windsor, Ellington, Enfield, Farmington, Glastonbury, Hartford, Manchester, New Brltain, Newington, Plainville, Portland, Rocky Hill, Simsbury, Somers, South Windsor, Stafford, Suffield, Tolland, Vernon, West Hartford, Wethersfield, Windsor, and Windsor Locks. The data compiled for this investigation consist of those collected specifically for the study during the period July 1967 - December 1969 and those collected during previous investigations. Many records of wells and test holes in thus report were published in Connecticut Water Resources Bulletin No. 4. This report is out of print, therefore these previously published records, together with newer ones, are published in this report to provide a readily available source of ground-water information. Previously published well numbers have been retained and are those published in this report. However, test holes previously published as wells have been assigned test-hole numbers; the former well number Is noted in table 3.

Connecticut↗

Brookian structural plays in the National Petroleum Reserve, Alaska

As part of the U.S. Geological Survey assessment of undiscovered oil and gas resources in the National Petroleum Reserve-Alaska (NPRA), two structural plays were assessed in thrust-faulted and folded Upper Cretaceous rocks of the Brookian megasequence. These are the Brookian Topset Structural Play and the Torok Structural Play, located in the Brooks Range foothills and the southern part of the coastal plain, within the Tertiary-age frontal part of the Jurassic to Tertiary Brooks Range orogenic belt. A new regional structural interpretation, developed through regional seismic analyses, reconnaissance field investigations, and new thermal constraints, guided the geologic evaluation and risking of these plays. Volumetric parameters were derived from seismic reflection data, well data and oil and gas field analogs. The fundamental elements of the Brookian Topset Structural Play, exemplified by the undeveloped Umiat oil field, include: (1) reservoirs in Nanushuk Group and uppermost Torok Formation shallow-marine to nonmarine sandstones draped over anticlines caused by structural thickening in underlying Torok mudstones; (2) seals provided by overlying shale drapes in the Nanushuk, and locally by thrust faults; (3) Torok, gamma-ray-zone (GRZ) or pebble shale source rocks; (4) remigration of hydrocarbons from early formed (Late Cretaceous) stratigraphic traps disrupted by 60 Ma thrusting, into newly formed structural traps. The 60 Ma thrusting was probably accompanied by new generation and migration of natural gas resulting from late structural thickening and tectonic loading. Subsurface data from the Umiat field and other seismic reflection data within the play area indicate that the structural traps are commonly compartmentalized by thrust faults. The fundamental elements of the Torok Structural Play, exemplified by the undeveloped East Kurupa gas accumulation just south of NPRA, include: (1) reservoirs in lower Torok Formation basin-floor sandstones, and perhaps in small sandstone bodies intercalated with middle to upper Torok mudstones; (2) structural traps provided by folded sandstone bodies above thrust faults within a pervasively deformed passive-roof duplex beneath the foothills and a less-strongly deformed domain to the north; (3) seals provided by Torok mudstone, both stratigraphically above the sandstone bodies and smeared along bounding thrust faults; (4) Torok, GRZ, pebble shale, or Kingak Shale source rocks; (5) a migration and charging scenario similar to that of the Brookian Topset Structural Play. According to our estimates, the Brookian Topset Structural Play contains 137 million barrels of technically recoverable oil and 10.6 trillion cubic feet (TCF) of technically recoverable, non-associated natural gas, with both values representing the mean estimate (expected value). The Torok Structural Play contains about 35 million barrels of technically recoverable oil and 17.9 TCF of technically recoverable, nonassociated natural gas.

Open-File Report↗

Mineral resource potential map of the Pecos Wilderness, Santa Fe, San Miguel, Mora, Rio Arriba, and Taos Counties, New Mexico

The Pecos Wilderness covers approximately 348 sq mi in the Santa Fe and Carson National Forests, north-central New Mexico. The area investigated includes the wilderness and approximately 150 sq mi of adjacent territory. The additional area covers several RARE II Road less Areas that were classified by the U.S. Forest Service in 1979 as Proposed Wilderness and Further Planning Areas, but were not incorporated in the Pecos Wilderness by the New Mexico Wilderness Bill. For the purpose of this report the entire area is called the study area. The study area is at the southern end of the Sangre de Cristo Range. It is characterized by an axial line of alpine peaks that rise to more than 13,000 ft, flanked on the west and north by heavily wooded ridges and canyons that drain to the Rio Grande Valley, and on the southeast by a high dissected plateau of meadows and forest. The plateau is dissected by deep canyons of the Pecos River and its tributaries, and is bounded on the east by a scarp of about 3,000 ft. Partly forested ranch land lies below the base of the scarp to the east, and beyond that is prai-rie of the Great Plains. This map is based on geologic and geochemical studies and mine and prospect investigations that were done principally in 1977 and 1979-80 (U.S. Geological Survey, U.S. Bureau of Mines, and New Mexico Bureau of Mines and Mineral Resources, 1980; Lane, 1980; Moench and Robertson, 1980; Moench, Robertson, and Sutley, 1980; Moench and Erickson, 1980; Moench, Grambling, and Robertson, 1988; Moench, Sutley, and Erickson, 1988; Erickson, Sutley, and Moench, 1986). An aeromagnetic survey covering almost all of the Pecos Wilderness was flown in 1970. The resulting aeromagnetic map was published by Moench and others (1980) and interpreted in that report by Lindreth Cordell. Cordell found no correlation between magnetic features and geologic terraines having mineral resource potential.

New Mexico↗

The Montana lobe of the Keewatin ice sheet

Just south of the forty-ninth parallel and east of the Rocky Mountains is an area that is of much interest to glacialists. It is the area which lay between the Keewatin ice sheet and the mountain glaciers coming from the west. Although it has been known for nearly twenty years that the bodies of drift deposited by the ice coming from opposite directions were closely associated, little detailed field work has been done in this region. As early as 1881 Sir James Geikie prophesied that a careful study of the region would clear up many important points in glaciology. In 1885, Dr. T. C. Chamberlin and Prof E. D. Salisbury, in a reconnaissance of the region, determined roughly the course of the terminal moraine of the eastern ice sheet and obtained data concerning the character and extent of the mountain glaciation. In 1890 Mr. G. E. Culver, while a member of the military party under the command of Lieutenant Ahern, U. S. Army, gathered many data concerning the geology of the region, publishing the results of his investigations in the Transactions of the Wisconsin Academy of Sciences, in 1891. Doctor Dawson and Mr McConnell, of the Canadian Survey, have worked out the geology of the region north of the boundary line. Their reports are unusually complete, but the area to the south offers better opportunity for study, and somewhat different conclusions were reached from a study of that region. The work on which the following discussion is based was done during the field seasons of 1901, 1902, and 1903. During the first season the writer was accompanied by Mr. Bruce McLeish, then a student at the University of Chicago. The second year Mr. Porter Graves, of the Kansas City High School, rendered valuable assistance. The writer is most deeply indebted to Dr. T. C. Chamberlin and Prof. R. D. Salisbury, of the University of Chicago, for friendly interest shown while superintending the compiling of this manuscript. Professor Salisbury also personally directed a portion of the field work and made many practical suggestions. Thanks are also due Dr. G. K. Gilbert for careful criticism of the report. The area covered by this investigation lies along the eastern front of the Montana Rockies, between longitude 108° and 113° 40', and latitude 47° 15' and 49° 30'. Over the eastern and northern part of this area the ice from the northeast deposited its drift. Over the western part the ice from the Rockies pushed down the mountain valleys and, deploying on the plain, deposited large and well-defined terminal moraines. Extending from the Canadian line to the Missouri there is a strip of country, varying greatly in width, which the ice did not cover.

Montana↗

Testing the suitability of geologic frameworks for extrapolating hydraulic properties across regional scales

The suitability of geologic frameworks for extrapolating hydraulic conductivity ( K ) to length scales commensurate with hydraulic data is difficult to assess. A novel method is presented for evaluating assumed relations between K and geologic interpretations for regional-scale groundwater modeling. The approach relies on simultaneous interpretation of multiple aquifer tests using alternative geologic frameworks of variable complexity, where each framework is incorporated as prior information that assumes homogeneous K within each model unit. This approach is tested at Pahute Mesa within the Nevada National Security Site (USA), where observed drawdowns from eight aquifer tests in complex, highly faulted volcanic rocks provide the necessary hydraulic constraints. The investigated volume encompasses 40 mi 3 (167 km 3 ) where drawdowns traversed major fault structures and were detected more than 2 mi (3.2 km) from pumping wells. Complexity of the five frameworks assessed ranges from an undifferentiated mass of rock with a single unit to 14 distinct geologic units. Results show that only four geologic units can be justified as hydraulically unique for this location. The approach qualitatively evaluates the consistency of hydraulic property estimates within extents of investigation and effects of geologic frameworks on extrapolation. Distributions of transmissivity are similar within the investigated extents irrespective of the geologic framework. In contrast, the extrapolation of hydraulic properties beyond the volume investigated with interfering aquifer tests is strongly affected by the complexity of a given framework. Testing at Pahute Mesa illustrates how this method can be employed to determine the appropriate level of geologic complexity for large-scale groundwater modeling.

Nevada↗

Marine latitudinal diversity gradients, niche conservatism and out of the tropics and Arctic: Climatic sensitivity of small organisms

Aim The latitudinal diversity gradient (LDG) is a consequence of evolutionary and ecological mechanisms acting over long history, and thus is best investigated with organisms that have rich fossil records. However, combined neontological‐palaeontological investigations are mostly limited to large, shelled invertebrates, which keeps our mechanistic understanding of LDGs in its infancy. This paper aims to describe the modern meiobenthic ostracod LDG and to explore the possible controlling factors and the evolutionary mechanisms of this large‐scale biodiversity pattern. Location Present‐day Western North Atlantic. Taxon Ostracoda. Methods We compiled ostracod census data from shallow‐marine environments of the western North Atlantic Ocean. Using these data, we documented the marine LDG with multiple metrics of alpha, beta (nestedness and turnover) and gamma diversity, and we tested whether macroecological patterns could be governed by different environmental factors, including temperature, salinity, dissolved oxygen, pH and primary productivity. We also explored the geologic age distribution of ostracod genera to investigate the evolutionary mechanisms underpinning the LDG. Results Our results show that temperature and climatic niche conservatism are important in setting LDGs of these small, poorly dispersing organisms. We also found evidence for some dispersal‐driven spatial dynamics in the ostracod LDG. Compared to patterns observed in marine bivalves, however, dispersal dynamics were weaker and they were bi‐directional, rather than following the ‘out‐of‐the‐tropics’ model. Main conclusions Our detailed analyses revealed that meiobenthic organisms, which comprise two‐thirds of marine diversity, do not always follow the same rules as larger, better‐studied organisms. Our findings suggest that the understudied majority of biodiversity may be more sensitive to climate than well‐studied, large organisms. This implies that the impacts of ongoing Anthropocene climatic change on marine ecosystems may be much more serious than presently thought.

Journal of Biogeography↗

Methods for estimating selected low-flow frequency statistics and mean annual flow for ungaged locations on streams in Alabama

Streamflow data and statistics are vitally important for proper protection and management of the water quality and water quantity of Alabama streams. Such data and statistics are generally available at U.S. Geological Survey streamflow-gaging stations, also referred to as streamgages or stations, but are often needed at ungaged stream locations. To address this need, the U.S. Geological Survey, in cooperation with numerous Alabama State agencies and organizations, developed regional regression equations for estimating selected low-flow frequency statistics and mean annual flow for ungaged locations on streams in Alabama that are not substantially affected by tides, regulation, diversions, or other anthropogenic influences. A small percentage of the streamgages included in this study experience zero flows during certain periods; thus, the final low-flow frequency regression equations were developed by using weighted left-censored regression analyses to analyze the flow data in an unbiased manner, with weights based on number of years of record. The equations developed include the annual minimum 1- and 7-day average streamflows with a 10-year recurrence interval (referred to as the 1Q10 and 7Q10 flows), the annual minimum 7-day average streamflow with a 2-year recurrence interval (referred to as the 7Q2 flow), and the mean annual flow using data from 174 streamgages from Alabama and surrounding States. For the 1Q10, 7Q2, and 7Q10 low-flow frequency statistics, the regional regression equations are functions of drainage area, streamflow-variability index, mean annual precipitation, and percentage of the drainage basin located in the Piedmont and Southeastern Plains ecoregions. The mean annual flow regression equation is a function of drainage area, mean annual precipitation, and percentage of the drainage basin located in the Southeastern Plains ecoregion. For the mean annual flow regression equation, the average standard error of estimate was 11.2 percent. For the selected low-flow frequency equations, the average standard errors of estimate ranged from 18.1 to 38.8 percent. The regional regression equations developed from this investigation have been incorporated into the U.S. Geological Survey StreamStats application for Alabama. StreamStats ( https://streamstats.usgs.gov/ss/ ) is a web-based geographic information system application that delineates drainage basins at selected stream locations and then generates the needed basin characteristics for available regional regression equations. Along with the low-flow frequency equations developed in this investigation, the StreamStats application also has regional regression equations for estimating flood-frequency statistics at locations on rural and urban streams in Alabama.

Alabama↗

Memorandum describing the geology and ground-water conditions in the vicinity of Simpsonville, Maryland

This memorandum summarizes briefly the result of a study of the ground-water conditions of a small area near Simpsonville, Maryland, underlain chiefly by the Guilford granite (granite-pegmatite) of early Paleozoic or late Precambrian age. The records. of 15 wells and 5 sprints are given, as are t he sample-study legs of 3 test wells drilled at the site of a planned industrial labratory. A geologic map revised some-what from a published map by Cloos and Broedel is included (fig. 1). The study of the hydrology in the vicinity of Simpsonville was undertaken as a part of the ground-water investigations in cooperation with the Maryland Department of Geology, Mines and Water Resources. It provides ground-water data in addition to those already available, as a basis for a decision by the Maryland Water Resources Commission in regard to the application of an industrial laboratory to appropriate 200,000 gallons of ground water a day at a site about half a mile northwest of Simpsonville (approximately 12 miles southwest of Baltimore). Also, it supplements existing information on the occurrence of ground water in crystalline rocks of the type underlying the site, which are widespread in the Piedmont of Maryland and other States.

South Carolina↗

Estimation of dynamic geologic CO2 storage resources in the Illinois Basin, including effects of brine extraction, anisotropy, and hydrogeologic heterogeneity

Since the vast majority of carbon dioxide (CO 2 ) storage resources in the United States are in deep saline aquifers, optimizing the use of these saline storage resources could be crucial for efficient development of geologic CO 2 storage (GCS) resources and basin- or larger-scale deployment of GCS in the country. Maximum CO 2 injection rates can be enhanced by extracting brine from the CO 2 storage unit. However, disposal of the extracted brine is both a technological and economic challenge. The lowest-cost option would likely be reinjection of the extracted brine into another formation above or below the CO 2 storage unit. Therefore, it is important to estimate brine injectivity as it will constrain the potential to increase CO 2 injectivity at an injection site that has access to multiple geologic storage units where either CO 2 or brine can be injected. Using a simulation-optimization framework, coupled with a non-isothermal, multiphase CO 2 -water-salt equation-of-state module, we developed a computationally efficient method for evaluating optimization of simultaneous CO 2 injection, brine extraction, and brine (re)injection at hypothetical injection sites deployed across a geologic basin. The Illinois basin is ideal for testing our methodology because it contains multiple geologic storage units with seals in between them to isolate injection of CO 2 in one unit from interfering with the injection of either brine or CO 2 in another unit above or below it. In addition, we investigated the relative effects of variation in key geologic parameters as well as two reservoir structures (hydrogeologic heterogeneity/anisotropy and homogeneity/isotropy) on CO 2 injectivities and enhancement of CO 2 injectivity through extracting brine. Results suggest that permeability, depth, and especially thickness of the storage unit could be the most influential parameters determining CO 2 injectivity. They also suggest that only injecting CO 2 into the storage unit with the greatest injectivity, enhancing that unit’s injectivity by extracting brine, and disposing of the produced brine in other suitable units could maximize total CO 2 injectivity in limited regions of the basin. At the majority of simulated injection sites, however, we found that injecting CO 2 into all of the accessible and suitable storage units was more likely to maximize the CO 2 storage resource.

Illinois, Kentucky, Indiana↗

Evidence of nitrate attenuation in intertidal and subtidal groundwater in a subterranean estuary at a Cape Cod embayment, East Falmouth, Massachusetts, 2015–16

Nitrogen dynamics in intertidal and nearshore subtidal groundwater (subterranean estuary) adjacent to the Seacoast Shores peninsula, Falmouth, Massachusetts, were investigated during 2015–16 by the U.S. Geological Survey. The peninsula is a densely populated residential area with septic systems and cesspools that are substantial sources of nitrogen to groundwater. The study area is in the Eel River, an estuarine saltwater embayment connected to the ocean adjacent to the western shore of the peninsula, that was the subject of an earlier study by Colman and others (2018, https://doi.org/10.3133/sir20185095 ) on nitrogen transport and transformations in groundwater between onshore and offshore locations. The previous study documented the distribution of nitrate concentrations and nitrate attenuation reactions in fresh groundwater beneath the peninsula and the estuary. The current study extended those observations with more detailed sampling and analysis of shallow groundwater from wells near discharge sites beneath the estuary. The current field investigation included sampling of existing wells and installation and sampling of clusters of wells and temporary sampling points in the subterranean estuary, including (1) shallow transects 0.3 to 1.2 meters (m) deep extending from 1 to 13.5 m offshore and (2) deeper wells (from 1.83 to 4.88 m deep) extending from 4.3 to 14.3 m offshore. Measurements of hydraulic-head gradients 2–5 m below the sediment/water interface in the intertidal and nearshore subtidal zones indicated that groundwater flow generally was upwards (towards the estuary) under all tide conditions in October 2016. The magnitude of the gradient was greatest during low tide conditions, indicating that groundwater discharge likely decreased during high tides. Measurements of specific conductance in shallow groundwater in the subterranean estuary in three transects perpendicular to shore were consistent with the existence of saltwater flow cells (infiltration of overlying saline water, mixing with fresh groundwater, and discharge to the overlying saline water) in the intertidal and nearshore subtidal regions. The size of these flow cells was variable in space and time and dependent on the elevation of the tide (spring or neap). At this location in the Eel River subterranean estuary, and offshore to at least 13.5 m, offshore flow of fresh groundwater apparently prevented a deeper saltwater wedge from discharging to the surface. Nitrate concentrations in shallow groundwater (30 to 122 centimeters [cm] depth) were variable in space and time, ranging from not detectable to 600 micromoles per liter (μmol/L) (8.4 milligrams per liter as N), and were highest in June 2016 at depths from 61 to 122 cm below the sediment/water interface and from 4 to 9 m offshore. Nitrate generally was not detectable in saline shallow groundwater at 30-cm depth or at any depth from 30 to 122 cm from 10 to 13.5 m offshore. Dissolved oxygen concentrations were suboxic (less than 16 μmol/L) in 60 percent of the sampled subterranean groundwater beneath the intertidal and subtidal zones. In the remaining sites, the range of dissolved oxygen concentrations was from 18 to 272 μmol/L and the median concentration was 43 μmol/L. Evidence for microbial nitrate reduction (denitrification and possibly anammox) was provided by the distribution of the reaction product nitrogen gas (excess N 2 , or N 2MIC ), as determined from analysis of the dissolved nitrogen gas and argon gas (Ar) concentrations in groundwater samples. Excess nitrogen gas provided evidence for nitrate reduction in shallow groundwater below the subtidal and, to a lesser extent, intertidal zones adjacent to the Seacoast Shores peninsula. These zones, where evidence for nitrate reduction was detected, were in fresh and brackish groundwater near subtidal or intertidal saltwater cells where discharging fresh groundwater mixed with infiltrating saline water. Infiltrating seawater may have supplied organic carbon, one of several potential electron donors that are required for denitrification. Other potential electron donors, such as organic carbon, iron, manganese, hydrogen, methane, ammonium, elemental sulfur, or sulfide phases, may have been supplied by the estuarine sediments. Drainage from surface runoff near the shore also may have supplied organic carbon to fresh groundwater near the intertidal saltwater cell. The highest amounts of nitrate converted to excess nitrogen gas were estimated to be in the range of 230 to 430 μmol/L in nearly fresh groundwater near the subtidal saltwater cell at depths of 61 to 122 cm below the sediment/water interface and from 10 to 13.5 m offshore. Evidence of denitrification within 10 m of the shore was sparse (generally limited to less than 50 μmol/L of N 2 -N) despite the presence of high nitrate concentrations. The spatial distribution of estimated nitrate reduction in the intertidal and nearshore subtidal fresh and brackish groundwater may be related to local variability in the distribution of reactive electron donors in those zones. Variations in the amount of nitrate reduction to nitrogen gas were not clearly related to potential aqueous electron donors such as dissolved organic carbon, nor to potential reaction products such as alkalinity, but may have been controlled by combinations of aqueous and solid-phase reactants. The distribution of relatively shallow fresh groundwater containing nitrate could indicate potential nitrate discharge areas in the lower intertidal zone and uncertain locations farther offshore; however, the data did not extend all the way to the sediment/water interface or to the offshore freshwater limit. This study confirmed substantial loss of nitrate from some of the fresh and brackish groundwater in shallow subestuarine sediments prior to discharge but did not quantify how much nitrate eventually discharged to the estuary.

Massachusetts↗

Hydrology of a part of the Big Sioux drainage basin, eastern South Dakota

In 1960 the U.S. Geological Survey, in cooperation with the South Dakota State Water Resources Commission and the South Dakota State Geological Survey, started a program for the hydrogeologic investigation of glacial drift in selected drainage basins in eastern South Dakota. This program was designed to delineate water-bearing deposits of glacial-outwash sand and gravel, and to determine their water-yielding characteristics, particularly with regard to irrigation and industrial use. Investigations of this type will aid in planning the use and conservation of ground water for future agricultural and industrial growth in South Dakota. This report describes the part of the Big Sioux River drainage basin from Sioux Falls north to a U.S. Geological Survey gaging station 9M miles southeast of Brookings (see fig. 1). The drainage area, about 675 square miles, is in the southwestern part of the Coteau des Prairies section of the Central Lowland physiographic province, as defined by Flint (1955, p. 5). It includes the Big Sioux River valley in Moody and north-central Minnehaha Counties, and the uplands that drain into the valley, from Brookings, Lake, Moody, and Minnehaha Counties, South Dakota, and Pipestone and Lincoln Counties, Minnesota. This report is based on data from field and laboratory studies and from published and unpublished records of State and Federal agencies. The investigations included: (1) Delineating area of water-bearing glacial outwash deposits; (2) inventorying wells to locate areas of greatest ground-water potential; (3) examining samples from auger holes to define thickness, extent, and character of water-bearing deposits; (4) determining the altitudes of selected test holes and wells for use in preparing cross sections and watertable maps; (5) collecting and analyzing water samples to determine the chemical character of water; and (6) testing aquifers to determine the hydrologic properties of the water-bearing deposits. Data consisting of logs of wells and test holes, waterlevel measurements, chemical analyses of water, stream-runoff measurements, and determinations of the hydrologic properties of aquifers are contained in a separate report by Ellis and Adolphson (1968).

South Dakota↗

Progress report on the geology and ground-water hydrology of the Lower Missouri-Souris Unit; Part 1, Crosby-Mohall area, North Dakota

The Crosby-Mohall area covers about 2,700 square miles in the north- western part of North Dakota. This area is included in the 2,500,000-acre Missouri-Souris and Garrison Diversion irrigation projects,which are im portant units in the general plans for development of the water resources of the Missouri River Basin. Although the Crosby-Mohall area lies outside the drainage basin of the Missouri River, plans have been made for the irrigation of about 1,000,0)0 acres (equivalent to 1,560 square miles) of the most suitable land, with water brought by canal from the Missouri River in Montana. The studies that have been undertaken in the area by the Division of Ground Water of the United States Geological Survey form a part of the investigations which have been initiated by the Survey and several other bureaus of the Department of the Interior, especially the Bureau of Reclamation. The studies on which the present report is bas2 were made during the field seasons of 1945, 1946 and 1947, to obtain information on the occurrence, movement, quantity, and quality of the ground water. The report contains data on the several kinds of water-bearing materials, water analyses, and well logs; the records of fluctuation of water level in about 400 wells; and an inventory of 4,636 wells and test holes. Later studies for the whole of the Missouri-Souris Unit will supply additional data on ground-water levels and piezometric surfaces, more extensive information on quality of water, a complete inventory of wells, and further geologic information relating to ground-water supplies. Other work that is planned also includes the drilling of additional test holes and the analysis of water samples from representative wells throughout the area.

North Dakota↗

Assessment of nutrients, suspended sediment, and pesticides in surface water of the upper Snake River basin, Idaho and western Wyoming, water years 1991-95

A water-quality investigation of the upper Snake River Basin began in 1991 as part of the U.S. Geological Survey's National Water- Quality Assessment Program. As part of the investigation, intensive monitoring was conducted during water years 1993 through 1995 to assess surface-water quality in the basin. Sampling and analysis focused on nutrients, suspended sediments, and pesticides because of nationwide interest in these constituents. Concentrations of nutrients and suspended sediment in water samples from 19 sites in the upper Snake River Basin, including nine on the main stem, were assessed. In general, concentrations of nutrients and suspended sediment were smaller in water from the 11 sites upstream from American Falls Reservoir than in water from the 8 sites downstream from the reservoir where effects from land-use activities are most pronounced. Median concentrations of dissolved nitrite plus nitrate as nitrogen at the 19 sites ranged from less than 0.05 to 1.60 milligrams per liter; total phosphorus as phosphorus, less than 0.01 to 0.11 milligrams per liter; and suspended sediment, 4 to 72 milligrams per liter. Concentrations of nutrients and suspended sediment in the main stem of the Snake River, in general, increased downstream. The largest concentrations in the main stem were in the middle reach of the Snake River between Milner Dam and the outlet of the upper Snake River Basin at King Hill. Significant differences (p<0.05) in nutrient and suspended sediment concentrations were noted among groups of sites categorized by the quantity of agricultural land in their upstream drainage basins. Water samples collected from sites in drainage basins where agricultural land constituted less than 10 percent of the land use contained significantly smaller concentrations of nutrients and suspended sediment than samples from sites in drainage basins where agricultural land constituted more than 10 percent of the land use. Significant differences in nutrient and suspended sediment concentrations were inconsistent among groups representing 10 to 19 percent, 20 to 29 percent, and greater than 29 percent agricultural land use. Seasonal concentrations of dissolved nitrite plus nitrate, total phosphorus, and suspended sediment were significantly different among most of the agricultural land-use groups. Concentrations of dissolved nitrite plus nitrate were largest during the nonirrigation season, October through March. Concentrations of total phosphorus and suspended sediment, in general, were largest during high streamflow, April through June. Nutrient and suspended sediment inputs to the middle Snake reach were from a variety of sources. During water year 1995, springs were the primary source of water and total nitrogen to the river and accounted for 66 and 60 percent of the total input, respectively. Isotope and water-table information indicated that the springs derived most of their nitrogen from agricultural activities along the margins of the Snake River. Aquacultural effluent was a major source of ammonia (82 percent), organic nitrogen (30 percent), and total phosphorus (35 percent). Tributary streams were a major source of organic nitrogen (28 percent) and suspended sediment (58 percent). In proportion to its discharge (less than 1 percent), the Twin Falls sewage-treatment plant was a major source of total phosphorus (13 percent). A comparison of discharge and loading in water year 1995 with estimates of instream transport showed a good correlation (relative difference of less than 15 percent) for discharge, total organic nitrogen, dissolved nitrite plus nitrate, total nitrogen, and total phosphorus. Estimates of dissolved ammonia and suspended sediment loads correlated poorly with instream transport; relative differences were about 79 and 61 percent, respectively. The pesticides EPTC, atrazine, desethylatrazine, metolachlor, and alachlor were the most commonly detected in the upper Snake River Basin and accounted for about 75 percent of all pesticide detections. All pesticides detected were at concentrations less than 1 microgram per liter and below water-quality criteria established by the U.S. Environmental Protection Agency. In samples collected from two small agriculturally dominated tributary basins, the largest number and concentrations of pesticides were detected in May and June following early growing season applications. At one of the sites, the pesticide atrazine and its metabolite desethylatrazine were detected throughout the year. On the basis of 37 samples collected basinwide in May and June 1994, total annual subbasin applications and instantaneous instream fluxes of EPTC and atrazine showed logarithmic relations with coefficients of determination (R2 values) of 0.55 and 0.62, respectively. At the time of sampling, the median daily flux of EPTC was about 0.0001 percent of the annual quantity applied, whereas the median daily flux of atrazine was between 0.001 and 0.01 percent.

Idaho;Wyoming↗

Geologic map of science study area 2, north Kasei Valles, Mars (MTM 25072 Quadrangle)

This map is one in a series of 1:500,000-scale geologic maps initiated by the National Aeronautics and Space Administration to investigate areas of particular scientific interest on Mars. The north Kasei Valles area (fig. 1) merits detailed geologic study because it c ontains part of a large channel system whose age can be determined relative to geologic units that range in age from early intermediate (Early Hesperian) to the very late (Late Amazonian) periods of Martian history . Also, many geomorphic features in the map area suggest changes in water level and multiple erosional events associated with the Kasei Valles system. Later erosional events are indicative of spring sapping ; small-scale, ground-water runoff; and water-mobilized debris flow. Therefore, this large-scale mapping has increased our understanding of the history of hydrolo gic processes on Mars (Chapman and Scott, 1989). For these reasons, part of the area is a candidate site for a sample-return mission to the planet.

IMAP↗