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At least 1,765 records · Page 98Linked to original sources

The relation of geogenic contaminants to groundwater age, aquifer hydrologic position, water type, and redox conditions in Atlantic and Gulf Coastal Plain aquifers, eastern and south-central USA

Groundwater age distributions developed from carbon-14 (14C), tritium (3H), and helium-4 (4He) concentrations, along with aquifer hydrologic position, water type, and redox conditions, were compared to geogenic contaminants of concern (GCOC) from 252 public-supply wells in six Atlantic and Gulf Coastal Plain unconsolidated-sediment aquifers. Concentrations of one or more GCOCs in 168 (67%) wells exceeded MCLs (maximum contaminant levels), SMCLs (secondary MCLs), or HBSLs (health-based screening levels). Human-health benchmark thresholds (MCLs or HBSLs) were exceeded in 31 (12%) wells, and included 0.8% for fluoride (F), 2.4% for arsenic (As), 4% for lead-210 (210Pb), and 4.8% for polonium-210 (210Po). Values of pH increase with age and were outside the SMCL in 31% of wells (23% < 6.5 and 7.5% > 8.5, SMCL). Among GCOCs with concentrations that increased significantly with groundwater age, the frequency of sentry threshold exceedances (i.e., one-half of MCL, SMCL, or HBSL) included 40% for dissolved solids (DS), 12% for chloride (Cl), 3.6% for F, 4.4% for As, and 9.1% for 210Po. Iron (Fe) concentrations did not correlate with groundwater age but exceeded sentry thresholds in 29% of wells. Groundwater age, water types, redox, pH, and GCOCs varied because of unique hydrogeologic features of the aquifers (recharge locations and geometry). As expected, primarily confined aquifers had young, oxic, low to near-neutral pH water near the outcrop (recharge area), and older, reduced, high pH water deeper and farther along flow paths. However, unique aquifer hydrogeologic conditions, such as multiple-recharge zones produced anomalous patterns of young and old groundwater at varying depths and locations along flow paths. Evidence for this variability is seen in disequilibrium patterns in the progression of the chemical evolution of groundwater with hydrologic position. When hydrogeologic differences are considered, groundwater age combined with hydrologic-position data, can provide a strong basis for inferring potential occurrence of GCOCs.

Gulf Coastal Plain aquifers↗

Assessing the added value of antecedent streamflow alteration information in modeling stream biological condition

In stream systems, disentangling relationships between biology and flow and subsequent prediction of these relationships to unsampled streams is a common objective of large-scale ecological modeling. Often, streamflow metrics are derived from aggregating continuous streamflow records available at a subset of stream gages into long-term flow regime descriptors. Despite demonstrated value, shortcomings of these long-term approaches include spatial restriction to locations with long-term continuous flow records (commonly, biased toward larger systems) and omission of potentially ecologically important short-term (i.e., ≤1 year) antecedent streamflow information. We used long-term flow regime and short-term antecedent streamflow alteration information to evaluate relative performance in modeling stream fish biological condition. We compared results to understand whether short-term antecedent streamflow information improved models of fish biological condition. Results indicated that models incorporating short-term antecedent data performed better than those relying solely on long-term flow regime data (kappa statistic = 0.29 and 0.23, respectively) and improved prediction accuracy among stream sizes and in six of nine ecoregions. Additionally, models relying solely on short-term streamflow information performed similarly to those with only long-term streamflow information (kappa = 0.23). Incorporating short-term antecedent streamflow metrics may provide added ecological information not fully captured by long-term flow regime summaries in macroscale modeling efforts or perform similarly to long-term streamflow data when long-term data are not available.

Science of the Total Environment↗

Perfluoroalkyl and polyfluoroalkyl substances in groundwater used as a source of drinking water in the eastern United States

In 2019, 254 samples were collected from five aquifer systems to evaluate per- and polyfluoroalkyl substance (PFAS) occurrence in groundwater used as a source of drinking water in the eastern United States. The samples were analyzed for 24 PFAS, major ions, nutrients, trace elements, dissolved organic carbon (DOC), volatile organic compounds (VOCs), pharmaceuticals, and tritium. Fourteen of the 24 PFAS were detected in groundwater, with 60% and 20% of public-supply and domestic wells, respectively, containing at least one PFAS detection. Concentrations of tritium, chloride, sulfate, DOC, and manganese+iron; percent urban land use within 500 m of the wells; and VOC and pharmaceutical detection frequencies were significantly higher in samples containing PFAS detections than in samples with no detections. Boosted Regression Tree models that consider 57 chemical and land-use variables show that tritium concentration, distance to the nearest fire-training area, percentage of urban land use, and DOC and VOC concentrations are the top five predictors of PFAS detections, consistent with hydrologic position, geochemistry, and land use being important controls on PFAS occurrence in groundwater. Model results indicate it may be possible to predict PFAS detections in groundwater using existing data sources.

Glacial aquifer, Mississippi Embayment aquifer, So↗

New technique for quantification of elemental hg in mine wastes and its implications for mercury evasion into the atmosphere

Mercury in the environment is of prime concern to both ecosystem and human health. Determination of the molecular-level speciation of Hg in soils and mine wastes is important for understanding its sequestration, mobility, and availability for methylation. Extended X-ray absorption fine structure (EXAFS) spectroscopy carried out under ambient P-T conditions has been used in a number of past studies to determine Hg speciation in complex mine wastes and associated soils. However, this approach cannot detect elemental (liquid) mercury in Hg-polluted soils and sediments due to the significant structural disorder of liquid Hg at ambient-temperature. A new sample preparation protocol involving slow cooling through the crystallization temperature of Hg(0) (234 K) results in its transformation to crystalline α-Hg(0). The presence and proportion of Hg(0), relative to other crystalline Hg-bearing phases, in samples prepared in this way can be quantified by low-temperature (77 K) EXAFS spectroscopy. Using this approach, we have determined the relative concentrations of liquid Hg(0) in Hg mine wastes from several sites in the California Coast Range and have found that they correlate well with measured fluxes of gaseous Hg released during light and dark exposure of the same samples, with higher evasion ratios from samples containing higher concentrations of liquid Hg(0). Two different linear relationships are observed in plots of the ratio of Hg emission under light and dark conditions vs % Hg(0), corresponding to silica−carbonate- and hot springs-type Hg deposits, with the hot springs-type samples exhibiting higher evasion fluxes than silica−carbonate type samples at similar Hg(0) concentrations. Our findings help explain significant differences in Hg evasion data for different mine sites in the California Coast Range.

Environmental Science & Technology↗

Reference hydrologic networks II. Using reference hydrologic networks to assess climate-driven changes in streamflow

Reference hydrologic networks (RHNs) can play an important role in monitoring for changes in the hydrological regime related to climate variation and change. Currently, the literature concerning hydrological response to climate variations is complex and confounded by the combinations of many methods of analysis, wide variations in hydrology, and the inclusion of data series that include changes in land use, storage regulation and water use in addition to those of climate. Three case studies that illustrate a variety of approaches to the analysis of data from RHNs are presented and used, together with a summary of studies from the literature, to develop approaches for the investigation of changes in the hydrological regime at a continental or global scale, particularly for international comparison. We present recommendations for an analysis framework and the next steps to advance such an initiative. There is a particular focus on the desirability of establishing standardized procedures and methodologies for both the creation of new national RHNs and the systematic analysis of data derived from a collection of RHNs.

Hydrological Sciences Journal↗

Does influenza A affect body condition of wild mallard ducks, or vice versa?

Low pathogenic avian influenza (LPAI) viruses are well documented to circulate within wild waterfowl populations (Olsen et. al. 2006 ). It has been assumed that these infections are benign with no subsequent effects on life-history parameters. The study by Latorre-Margalef et al. (2009 ; hereafter L.-M. et al. ) represents an important step, as they attempt to test this assumption in wild birds. L.-M. et al. captured migrating mallards ( Anas platyrhynchos ) at a staging area and tested them for the presence of avian influenza A virus (IAV). They related IAV infection status to body mass and duration of time spent on the staging area. Overall, the study is well designed with impressive sample sizes and the analyses are carefully conducted and presented. However, in discussing these results, the authors assume causation based upon correlation and, although they acknowledge the possibility of immunosuppression during migration due to reduced energy stores, they do not discuss it as a possible explanation for their findings. Below, we consider several of the major findings by L.-M. et al. , providing alternative explanations for the results. Because the L.-M. et al. study design is correlational, it is not possible to use their data to distinguish between their interpretations and our alternative explanations.

Proceedings of the Royal Society B: Biological Sci↗

Algal bioassessment metrics for wadeable streams and rivers of Maine, USA

Many state water-quality agencies use biological assessment methods based on lotic fish and macroinvertebrate communities, but relatively few states have incorporated algal multimetric indices into monitoring programs. Algae are good indicators for monitoring water quality because they are sensitive to many environmental stressors. We evaluated benthic algal community attributes along a landuse gradient affecting wadeable streams and rivers in Maine, USA, to identify potential bioassessment metrics. We collected epilithic algal samples from 193 locations across the state. We computed weighted-average optima for common taxa for total P, total N, specific conductance, % impervious cover, and % developed watershed, which included all land use that is no longer forest or wetland. We assigned Maine stream tolerance values and categories (sensitive, intermediate, tolerant) to taxa based on their optima and responses to watershed disturbance. We evaluated performance of algal community metrics used in multimetric indices from other regions and novel metrics based on Maine data. Metrics specific to Maine data, such as the relative richness of species characterized as being sensitive in Maine, were more correlated with % developed watershed than most metrics used in other regions. Few community-structure attributes (e.g., species richness) were useful metrics in Maine. Performance of algal bioassessment models would be improved if metrics were evaluated with attributes of local data before inclusion in multimetric indices or statistical models.

Maine↗

Origin and identity of Fejervarya (Anura: Dicroglossidae) on Guam

We used morphological and molecular data to infer the identity and origin of frogs in the genus Fejervarya that have been introduced to the island of Guam. Mensural and meristic data were collected from 96 specimens from throughout their range on the island and a principal component analysis was used to investigate the distribution of these data in morphological space. We also amplified a fragment of the 16S ribosomal ribonucleic acid mitochondrial gene from 27 of these specimens and compared it to 63 published sequences of Fejervarya and the morphologically similar Zakerana. All examined Fejervarya from Guam are morphologically indistinguishable and share an identical haplotype. The molecular data identify them as Fejervarya cancrivora with a haplotype identical to F. cancrivora from Taiwan.

Guam↗

Assessing the Kansas water-level monitoring program: An example of the application of classical statistics to a geological problem

Geologists may feel that geological data are not amenable to statistical analysis, or at best require specialized approaches such as nonparametric statistics and geostatistics. However, there are many circumstances, particularly in systematic studies conducted for environmental or regulatory purposes, where traditional parametric statistical procedures can be beneficial. An example is the application of analysis of variance to data collected in an annual program of measuring groundwater levels in Kansas. Influences such as well conditions, operator effects, and use of the water can be assessed and wells that yield less reliable measurements can be identified. Such statistical studies have resulted in yearly improvements in the quality and reliability of the collected hydrologic data. Similar benefits may be achieved in other geological studies by the appropriate use of classical statistical tools.

The Compass: Earth Science Journal of Sigma Gamma ↗

Land cover

Documenting the distribution of land-cover types on the Arctic National Wildlife Refuge coastal plain is the foundation for impact assessment and mitigation of potential oil exploration and development. Vegetation maps facilitate wildlife studies by allowing biologists to quantify the availability of important wildlife habitats, investigate the relationships between animal locations and the distribution or juxtaposition of habitat types, and assess or extrapolate habitat characteristics across regional areas. To meet the needs of refuge managers and biologists, satellite imagery was chosen as the most cost-effective method for mapping the large, remote landscape of the 1002 Area. Objectives of our study were the following: 1) evaluate a vegetation classification scheme for use in mapping. 2) determine optimal methods for producing a satellite-based vegetation map that adequately met the needs of the wildlife research and management objectives; 3) produce a digital vegetation map for the Arctic Refuge coastal plain using Lands at-Thematic Mapper(TM) satellite imagery, existing geobotanical classifications, ground data, and aerial photographs, and 4) perform an accuracy assessment of the map.

Alaska, Northwest Territories, Yukon Territory↗

EAARL Coastal Topography-Maryland and Delaware, Post-Nor'Ida, 2009

These remotely sensed, geographically referenced elevation measurements of lidar-derived bare-earth (BE) and first-surface (FS) topography datasets were produced by the U.S. Geological Survey (USGS), St. Petersburg Coastal and Marine Science Center, St. Petersburg, FL. This project provides highly detailed and accurate datasets of a portion of the eastern Maryland and Delaware coastline beachface, acquired post-Nor'Ida (November 2009 nor'easter) on November 28 and 30, 2009. The datasets are made available for use as a management tool to research scientists and natural-resource managers. An innovative airborne lidar instrument originally developed at the NASA Wallops Flight Facility, and known as the Experimental Advanced Airborne Research Lidar (EAARL), was used during data acquisition. The EAARL system is a raster-scanning, waveform-resolving, green-wavelength (532-nanometer) lidar designed to map near-shore bathymetry, topography, and vegetation structure simultaneously. The EAARL sensor suite includes the raster-scanning, water-penetrating full-waveform adaptive lidar, a down-looking red-green-blue (RGB) digital camera, a high-resolution multispectral color-infrared (CIR) camera, two precision dual-frequency kinematic carrier-phase GPS receivers, and an integrated miniature digital inertial measurement unit, which provide for sub-meter georeferencing of each laser sample. The nominal EAARL platform is a twin-engine aircraft, but the instrument was deployed on a Pilatus PC-6. A single pilot, a lidar operator, and a data analyst constitute the crew for most survey operations. This sensor has the potential to make significant contributions in measuring sub-aerial and submarine coastal topography within cross-environmental surveys. Elevation measurements were collected over the survey area using the EAARL system, and the resulting data were then processed using the Airborne Lidar Processing System (ALPS), a custom-built processing system developed in a NASA-USGS collaboration. ALPS supports the exploration and processing of lidar data in an interactive or batch mode. Modules for presurvey flight-line definition, flight-path plotting, lidar raster and waveform investigation, and digital camera image playback have been developed. Processing algorithms have been developed to extract the range to the first and last significant return within each waveform. ALPS is used routinely to create maps that represent submerged or sub-aerial topography. Specialized filtering algorithms have been implemented to determine the 'bare earth' under vegetation from a point cloud of last return elevations. For more information about similar projects, please visit the Decision Support for Coastal Science and Management website.

Data Series↗

2010 Joint United States-Canadian Program to explore the limits of the Extended Continental Shelf aboard U.S. Coast Guard Cutter Healy--Cruise HLY1002

In August and September 2010, the U.S. Geological Survey, in cooperation with Natural Resources Canada, Geological Survey of Canada, conducted bathymetric and geophysical surveys in the Beaufort Sea and eastern Arctic Ocean aboard the U.S. Coast Guard Cutter Healy. The principal objective of this mission to the high Arctic was to acquire data in support of a delineation of the outer limits of the U.S. and Canadian Extended Continental Shelf in the Arctic Ocean, in accordance with the provisions of Article 76 of the United Nations Convention on the Law of the Sea. The Healy was accompanied by the Canadian Coast Guard icebreaker Louis S. St-Laurent. The scientific parties on board the two vessels consisted principally of staff from the U.S. Geological Survey (Healy), and the Geological Survey of Canada and the Canadian Hydrographic Service (Louis). The crew also included marine-mammal observers, Native-community observers, ice observers, and biologists conducting research of opportunity in the Arctic Ocean. Despite interruptions necessitated by three medical emergencies, the joint survey proved largely successful. The Healy collected 7,201 trackline-kilometers of swath (multibeam) bathymetry (47,663 square kilometers) and CHIRP subbottom data, with accompanying marine gravity measurements, and expendable bathythermograph data. The Louis acquired 3,673 trackline-kilometers of multichannel seismic (airgun) deep-penetration reflection data along 25 continuous profiles, as well as 34 sonobuoy refraction stations and 9,500 trackline-kilometers of single-beam bathymetry. The coordinated efforts of the two vessels resulted in seismic-reflection-profile data that were of much higher quality and continuity than if the data had been acquired with a single vessel alone. The equipment-failure rate of the seismic equipment aboard the Louis was greatly reduced when the Healy led as the ice breaker. When ice conditions proved too severe to deploy the seismic system, the Louis led the Healy, resulting in much improved quality of the swath bathymetric and CHIRP subbottom data in comparison with data collected either by the Healy in the lead or the Healy working alone. During periods when the Healy was operating alone (principally when the Louis was diverted for emergency medical evacuations or ship repairs), the Healy was able to deploy a piston-core-sampler (10 meters maximum potential recovery depending on configuration). The coring operations resulted in recovery of cores at five locations ranging from 2.4 to 5.7 meters in length from water depths ranging from 1,157 to 3,700 meters. One of these cores sited on the Alaskan margin recovered the first reported occurrence of methane hydrate from the Arctic Ocean. Ancillary science objectives, including ice observations and deployment of ice-monitoring buoys and water-column sampling to measure acidification of Arctic waters were successfully conducted. The water-column sampling included using 10 full-ocean-depth, water-sampling casts with accompanying conductivity-temperature-depth measurements. Except for the data deemed proprietary, data from the cruise have been archived and are available for download at the National Geophysical Data Center and at cooperating organizations. Outreach staff and guest teachers aboard the two vessels provided near-real-time connection between the research activities and the public through online blogs, web pages, and other media.

Open-File Report↗

Synthesis centers as critical research infrastructure

Demand for the opportunity to participate in a synthesis-center activity has increased in the years since the US National Science Foundation (NSF)–funded National Center for Ecological Analysis and Synthesis (NCEAS) opened its doors in 1995 and as more scientists across a diversity of scientific disciplines have become aware of what synthesis centers provide. The NSF has funded four synthesis centers, and more than a dozen new synthesis centers have been established around the world, some following the NSF model and others following different models suited to their national funding environment ( http://synthesis-consortium.org ). Scientific synthesis integrates diverse data and knowledge to increase the scope and applicability of results and yield novel insights or explanations within and across disciplines (Pickett et al. 2007 , Carpenter et al. 2009 ). The demand for synthesis comes from the pressing societal need to address grand challenges related to global change and other issues that cut across multiple societal sectors and disciplines and from recognition that substantial added scientific value can be achieved through the synthesis-based analysis of existing data. Demand also comes from groups of scientists who see exciting opportunities to generate new knowledge from interdisciplinary and transdisciplinary collaboration, often capitalizing on the increasingly large volume and variety of available data (Kelling et al. 2009 , Bishop et al. 2014 , Specht et al. 2015b ). The ever-changing nature of societal challenges and the availability of data with which to address them suggest there will be an expanding need for synthesis. However, we are now entering a phase in which government support for some existing synthesis centers has ended or will be ending soon, forcing those centers to close or develop new operational models, approaches, and funding streams. We argue here that synthesis centers play such a unique role in science that continued long-term public investment to maximize benefits to science and society is justified. In particular, we argue that synthesis centers represent community infrastructure more akin to research vessels than to term-funded centers of science and technology (e.g., NSF Science and Technology Centers). Through our experience running synthesis centers and, in some cases, developing postfederal funding models, we offer our perspective on the purpose and value of synthesis centers. We present case studies of different outcomes of transition plans and argue for a fundamental shift in the conception of synthesis science and the strategic funding of these centers by government funding agencies.

BioScience↗

Predicting the resilience and recovery of aquatic systems: a framework for model evolution within environmental observatories

Maintaining the health of aquatic systems is an essential component of sustainable catchmentmanagement, however, degradation of water quality and aquatic habitat continues to challenge scientistsand policy-makers. To support management and restoration efforts aquatic system models are requiredthat are able to capture the often complex trajectories that these systems display in response to multiplestressors. This paper explores the abilities and limitations of current model approaches in meeting this chal-lenge, and outlines a strategy based on integration of flexible model libraries and data from observationnetworks, within a learning framework, as a means to improve the accuracy and scope of model predictions.The framework is comprised of a data assimilation component that utilizes diverse data streams from sensornetworks, and a second component whereby model structural evolution can occur once the model isassessed against theoretically relevant metrics of system function. Given the scale and transdisciplinarynature of the prediction challenge, network science initiatives are identified as a means to develop and inte-grate diverse model libraries and workflows, and to obtain consensus on diagnostic approaches to modelassessment that can guide model adaptation. We outline how such a framework can help us explore thetheory of how aquatic systems respond to change by bridging bottom-up and top-down lines of enquiry,and, in doing so, also advance the role of prediction in aquatic ecosystem management.

Water Resources Research↗

Advancing process‐based watershed hydrological research using near‐surface geophysics: A vision for, and review of, electrical and magnetic geophysical methods

We want to develop a dialogue between geophysicists and hydrologists interested in synergistically advancing process based watershed research. We identify recent advances in geophysical instrumentation, and provide a vision for the use of electrical and magnetic geophysical instrumentation in watershed scale hydrology. The focus of the paper is to identify instrumentation that could significantly advance this vision for geophysics and hydrology during the next 3–5 years. We acknowledge that this is one of a number of possible ways forward and seek only to offer a relatively narrow and achievable vision. The vision focuses on the measurement of geological structure and identification of flow paths using electrical and magnetic methods. The paper identifies instruments, provides examples of their use, and describes how synergy between measurement and modelling could be achieved. Of specific interest are the airborne systems that can cover large areas and are appropriate for watershed studies. Although airborne geophysics has been around for some time, only in the last few years have systems designed exclusively for hydrological applications begun to emerge. These systems, such as airborne electromagnetic (EM) and transient electromagnetic (TEM), could revolutionize hydrogeological interpretations. Our vision centers on developing nested and cross scale electrical and magnetic measurements that can be used to construct a three‐dimensional (3D) electrical or magnetic model of the subsurface in watersheds. The methodological framework assumes a ‘top down’ approach using airborne methods to identify the large scale, dominant architecture of the subsurface. We recognize that the integration of geophysical measurement methods, and data, into watershed process characterization and modelling can only be achieved through dialogue. Especially, through the development of partnerships between geophysicists and hydrologists, partnerships that explore how the application of geophysics can answer critical hydrological science questions, and conversely provide an understanding of the limitations of geophysical measurements and interpretation.

Hydrological Processes↗

Integration of social and ecological sciences for natural resource decision making: Challenges and opportunities

The last 25 years have witnessed growing recognition that natural resource management decisions depend as much on understanding humans and their social interactions as on understanding the interactions between non-human organisms and their environment. Decision science provides a framework for integrating ecological and social factors into a decision, but challenges to integration remain. The decision-analytic framework elicits values and preferences to help articulate objectives, and then evaluates the outcomes of alternative management actions to achieve these objectives. Integrating social science into these steps can be hindered by failing to include social scientists as more than stakeholder-process facilitators, assuming that specific decision-analytic skills are commonplace for social scientists, misperceptions of social data as inherently qualitative, timescale mismatches for iterating through decision analysis and collecting relevant social data, difficulties in predicting human behavior, and failures of institutions to recognize the importance of this integration. We engage these challenges, and suggest solutions to them, helping move forward the integration of social and biological/ecological knowledge and considerations in decision-making.

Environmental Management↗

The Landsat 7 mission: terrestrial research and applications for the 21st century

The Landsat Earth observation approach introduced in 1972 created a new way of monitoring land cover and land use globally. The Landsat 7 mission, successfully launched on April 15, 1999, continues those observations and demonstrates significant progress in precise numerical radiometry, spectral differentiation, and seasonally repetitive monitoring. Substantial improvements in calibration procedures, both prior to launch and during normal operations, have also been made to ensure long-term stability in the acquired spectral radiometry. Landsat 7 data acquisitions are being driven by a long-term data acquisition plan that was designed to ensure that substantially cloud-free, seasonal coverage would be recorded and archived in the US for all land areas of the globe. NASA competitively selected a Landsat Science Team, consisting of representatives from US universities and government agencies, to exploit the Landsat 7 record for global change research. This team is addressing the technical and analytical means to process and analyze the core of this observation record, and for the first time in the history of the Landsat mission, the technical and operational aspects of the mission are being driven by the goals of the US science community. The expected outcome of these efforts is a rapid improvement in understanding the Earth system, as well as conceptual knowledge that will underpin significant advancements in the application of this technology for commercial, operational, educational, and research purposes. Pathways to achieve effective Landsat continuity in the early decades of the 21st century are also being given careful attention, and there is no question that the lessons learned from the Landsat 7 mission will strongly influence these next-generation sensor systems.

Remote Sensing of Environment↗