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Fluorine

Fluorine compounds are essential in numerous chemical and manufacturing processes. Fluorspar is the commercial name for fluorite (isometric CaF 2 ), which is the only fluorine mineral that is mined on a large scale. Fluorspar is used directly as a fluxing material and as an additive in different manufacturing processes. It is the source of fluorine in the production of hydrogen fluoride or hydrofluoric acid, which is used as the feedstock for numerous organic and inorganic chemical compounds. The United States was the world’s leading producer of fluorspar until the mid-1950s. In the mid-1970s, the U.S. fluorspar mining industry began to decline because of foreign competition. By 1982, there was essentially only a single U.S. producer left, and that company ceased mining in 1996. Consumption of fluorspar in the United States peaked in the early 1970s, which was also the peak period of U.S. steel production. Since then, U.S. fluorspar consumption has decreased substantially; the United States has nonetheless increased its imports of downstream fluorine compounds, such as, in order of tonnage imported, hydrofluoric acid, aluminum fluoride, and cryolite. This combination of no U.S. production (until recently) and high levels of consumption has made the United States the world’s leading fluorspar-importing country, in all its various forms. The number of fluorspar-exporting countries has decreased substantially in recent decades, and, as a result, the United States has become dependent on just a few countries to supply its needs. In 2013, the United States imported the majority of its fluorspar from three countries, which were, in descending order of the amount imported, Mexico, China, and South Africa. Geologically, in igneous systems, fluorine is one of a number of elements that are “incompatible.” These incompatible elements become concentrated in the residual magma while the common silicates crystallize upon magma ascent and cooling, leading to relatively high fluorine concentrations in the more evolved or differentiated igneous rocks and in hydrothermal deposits associated with those evolved igneous rocks. In sedimentary rocks, fluorine’s highest concentrations are found in phosphorites because fluorine substitutes for hydroxyl ions in apatite, which leads to fluorine concentrations of, typically, from 2 to 4 weight percent in phosphorites. Because of the presence of fluorine, phosphate fertilizer manufacturers can produce a fluorosilicic acid byproduct. Most deposits mined for fluorine are hydrothermal, however, and consist of fluorine minerals that precipitated from hot water. Magmatic brines and brines from deep within sedimentary basins that have high concentrations of dissolved fluoride are the mineralizing fluids for various types of hydrothermal fluorspar deposits. Relatively dilute hydrothermal fluids that formed in some volcanic rocks can also transport sufficient fluoride to form a high-grade fluorspar deposit. Fluorite has low solubility in a common range of hydrothermal temperatures, particularly from about 160 degrees Celsius (°C) down to 60 °C. The increasing fluorite solubility below 60 °C partly explains why some water with exceptionally high levels of dissolved fluorine are found even at ambient temperatures in evaporitic lake basins in some East African Rift valleys in Kenya and Tanzania. The geologic conditions that led to the high concentrations there are known to exist in a number of other places in the world as well, including, perhaps, places in the Basin and Range province of the United States. Eight minerals or mineral groups have sufficient fluorine in their structures to be considered as possible ores of the element; they are bastnaesite (also spelled bastnäsite; and other fluorocarbonates), cryolite, sellaite, villiaumite, fluorite, fluorapatite (in phosphorites), various phyllosilicates, and topaz. Fluorite is currently the only mineral that is mined for fluorine, and nomineral except fluorite is likely to become a source of commercially produced fluorine as a primary product as long as supplies from relatively thick and high-grade fluorite deposits continue to be available. At least seven classes (which include one subclass) of hydrothermal fluorite deposits are recognized; they are classified according to their tectonic and (or) magmatic settings, as follows: (1) carbonatite-related fluorspar deposits; (2) alkaline-intrusion-related fluorspar deposits; (3) alkaline-volcanic-related epithermal fluorspar deposits; (4) Mississippi Valley-type fluorspar deposits (and a subclass of salt-related carbonate-hosted fluorspar deposits); (5) fluorspar deposits related to strongly differentiated granites; (6) subalkaline-volcanic-related epithermal fluospar deposits; and (7) fluorspar deposits that appear to be conformable within tuffaceous limy lacustrine sediments. An eighth class (not hydrothermal) is that of fluorspar deposits concentrated in soils and weathered zones; that is, residual fluorspar deposits. Generally, fluorspar deposits related to strongly differentiated granites have larger tonnages and lower grades than carbonatite-related fluorspar deposits, which, in turn, have larger tonnages and lower grades than fluorspar vein deposits from various other classes. The United States has a few identified resources of fluorspar, most notably the Klondike II property in the Illinois- Kentucky fluorspar district located about 8 kilometers southwest of Salem, Kentucky, which has a large vein that contains at least 1.6 million metric tons at a grade of 60 percent CaF 2 (Feytis, 2009). Additional fluorspar resources of lower grade but larger tonnage have been identified at Hicks Dome in the Illinois-Kentucky fluorspar district and at Lost River near the western tip of the Seward Peninsula in Alaska, along with a couple of dozen smaller, higher grade resources. Internationally, new mines that either opened before the beginning of 2013 or were scheduled to open soon after that time include the Nui Phao tungsten-fluorspar-bismuth-copper-gold deposit in northern Vietnam; the St. Lawrence project in Newfoundland, Canada, which is located in a well-known fluorspar district; the Bamianshan deposit, which is related to a strongly differentiated granite in northwestern Zhejiang Province, China, near some of that Province’s large, subalkaline-volcanic-related epithermal veins; and the Nokeng project in South Africa, which is also related to a strongly differentiated granite. Other deposits in northwestern Australia, Nevada (United States), Norway, South Africa, and Sweden have been identified and could be put into production within just a few years. Among undiscovered resources, an interesting possibility might be to produce a fluorine product from evaporitic, high-fluorine, high-pH sodium-carbonate brines like Lake Magadi (Kenya) and Lake Natron (Tanzania) in Africa’s Eastern Rift Valley. In addition, apparently conformable fluorspar deposits in tuffaceous limy lacustrine sediments, such as those in Italy, are likely to occur in similar young alkalic volcanic settings elsewhere in the world. Modern geophysical and geochemical exploration techniques have typically not been brought to bear in exploration for new fluorspar deposits, although such techniques are likely to be used in future exploration. The tendency for fluorine to dissolve in significant concentrations in water at low temperature allows both surface water and groundwater to be used as sampling media in geochemical exploration. Evolved granite-related fluorspar deposits may be particularly susceptible to geophysical exploration methods because crystalline rocks that form a basement to sedimentary sections can be approximately defined with gravity and magnetic methods, and magnetite-bearing skarns can be directly detected with magnetic surveys. Environmental considerations of fluorine mining focus especially on drinking water, where high fluorine concentrations can lead to tooth decay; dental and skeletal fluorosis; and bone and cartilage conditions, including genu valgum, which is the crippling bone deformity more commonly known as knock knee. Trace amounts of other elements in fluorspar ores are a concern at some deposits; for example, high beryllium concentrations in alkaline-volcanic-related epithermal deposits or high cadmium concentrations associated with Mississippi Valley-type and salt-related carbonate-hosted fluorspar deposits. Future research might include testing whether fluorine can be extracted economically from high-pH, sodium-carbonate brines and exploring for new occurrences of apparently conformable fluorspar deposits in tuffaceous limy lacustrine sediments outside of the Latium Region of Italy. Other promising new areas of research could be studies of fluorspar deposit fluid inclusion compositions by quadrupole mass spectrometry, by noble gas mass spectrometry on irradiated fluid inclusions, or by chlorine isotopes, while also measuring the chemistry of the same fluid inclusions either by bulk crush-and-leach methods or by laser ablation-inductively coupled plasma mass spectrometry. Advanced studies of fluid inclusion chemistry could be applied beneficially to some of the enigmatic large epithermal fluorspar veins at various places in the world, where they might determine those deposits’ possible relationships to igneous intrusions, or to dissolved salt, or to heated meteoric water in volcanic sections, or perhaps to all three. This knowledge could help focus new exploration.

Professional Paper↗

The Las Vegas Formation

The Las Vegas Formation was established in 1965 to designate the distinctive light-colored, fine-grained, fossil-bearing sedimentary deposits exposed in and around the Las Vegas Valley, Nevada. In a coeval designation, the sediments were subdivided into informal units with stratigraphic and chronologic frameworks that have persisted in the literature. Use of the Las Vegas Formation name over the past half century has been hampered because of the lack of a robust definition and characterization of the entire lithostratigraphic sequence, its geographic distribution, and chronology. This study evaluates and describes deposits attributed to the Las Vegas Formation with detailed stratigraphy, sedimentology, and field relations. A large suite of radiocarbon and luminescence ages facilitates revision and temporal expansion of the geochronology. In all, we characterize 17 informal geologic units within the formation, each dating to a unique period of geologic time, with stratigraphically ascending members X, A, B, D, and E and attendant beds in members B, D, and E. The age of the Las Vegas Formation spans at least the middle Pleistocene to early Holocene (from approximately 573 to 8.53 kilo-annum [thousands of years before present]) and is related to past episodes of groundwater discharge in the Las Vegas Valley. The contextual information derived from this new framework is dually noteworthy because the sediments entomb one of the most significant Pleistocene vertebrate faunas in the American Southwest, the Tule Springs local fauna, and represent a paleohydrologic system that responded dynamically to abrupt changes in climate throughout the late Quaternary. Characterizing the nature of these important deposits stabilizes the nomenclature, promotes the continued use of the informal units within the formation, and facilitates studies of similar deposits associated with desert wetland ecosystems elsewhere in the southwestern United States.

Nevada↗

Groundwater availability of the Williston Basin, United States and Canada

Executive Summary The Williston Basin of the Northern Great Plains is a sedimentary basin—a geologic bowl-like structure filled with layered sedimentary rocks dating as far back as the Paleozoic age. The basin, which is nationally important for the production of energy resources, spans Montana, North Dakota, and South Dakota in the United States, and Manitoba and Saskatchewan in Canada. The three uppermost principal aquifer systems are the glacial, lower Tertiary, and Upper Cretaceous aquifer systems. As deep as 3,000 feet (ft) at the center of the basin, these are the most accessible aquifer systems in the basin and are the primary sources of potable groundwater in much of this area. The glacial aquifer system consists of Quaternary-age unconsolidated till, silt, clay, outwash sand and gravel, and occasional cobbles and boulders. The lower Tertiary and Upper Cretaceous aquifer systems consist primarily of sandstone, siltstone, mudstone, shale, and coal. As energy demands have increased in the basin, horizontal drilling and hydraulic-fracturing have been used (especially since 2005) to develop previously inaccessible formations—namely, the Bakken and Three Forks Formations. The basin has yielded a large supply of domestic oil and natural gas since the 1950s, but the technologies required to extract those materials use large amounts of freshwater. The increasing freshwater demands of energy production in the Williston Basin, in addition to population growth, have led to a need for new tools to assess groundwater resources.

Williston Basin↗

The effects of management practices on grassland birds — An introduction to North American grasslands and the practices used to manage grasslands and grassland birds

The Great Plains of North America is defined as the land mass that encompasses the entire central portion of the North American continent that, at the time of European settlement, was an unbroken expanse of primarily herbaceous vegetation. The Great Plains extend from central Saskatchewan and Alberta to central Mexico and from Indiana to the Rocky Mountains. The expanses of herbaceous vegetation are often referred to as native prairie or native grasslands. Native grasslands share the characteristics of a general uniformity in vegetation structure, dominance by grasses and forbs, a near absence of trees and shrubs, annual precipitation ranging from 25 to 100 centimeters, extreme intra-annual fluctuations in temperature and precipitation, and a flat to rolling topography over which fires can spread. To the west of the Great Plains lie the sagebrush communities of the Great Basin, which extend from British Columbia and Saskatchewan to northern Arizona and New Mexico and from the eastern slopes of the Sierra Nevada and Cascade mountain ranges to western South Dakota. Sagebrush communities share similar characteristics to native grasslands, but their location east of the Rocky Mountains creates a more moderating influence from prevailing westerly winds that affect timing of peak precipitation and growth form of dominant vegetation. Native grasslands and sagebrush communities harbor a diverse array of grassland, wetland, and woodland plant and animal communities that are uniquely adapted to the natural forces of the Great Plains and Great Basin, namely the interactive forces of climate, fire, and grazing. The arrival of European settlers to North America brought profound change to native grassland and sagebrush communities, including the establishment of permanent towns and cities, the proliferation of cropland-based agricultural systems, and the suppression of wildfires. The near extirpation of bison by the 1860s paved the way for dramatic changes in the dominant grazers and a shift in the disturbance patterns that historically influenced vegetation structure. The greatest threat to native grasslands and sagebrush communities in modern times is their loss due to conversion to rowcrop agriculture and to urbanization. Concomitant with habitat loss is a precipitous decline in populations of bird species that evolved with, and are uniquely adapted to, the native grassland and sagebrush habitats. Avian population trends are linked strongly to agricultural land use. Besides outright loss of suitable breeding habitat, agricultural practices affect birds through factors such as pesticide exposure, habitat fragmentation, shifts in predator community composition, and occurrence of brood parasites. Bird populations face other stressors, such as loss of habitat to and behavioral avoidance of urbanized areas, roads, and infrastructure associated with energy production. Despite the many anthropogenic changes to North American grassland and sagebrush communities, some bird species are adaptable and opportunistic in their habitat selection and now utilize one or more human-created habitats. Human-created habitats include pastures, hayfields, agricultural terraces, crop buffer strips, field borders, grassed waterways, fencerows, road rights-of-way, airports, reclaimed coal mines, and planted wildlife cover. Fields of seeded grasslands enrolled in Federal long-term set-aside programs, such as the Conservation Reserve Program in the United States and the Permanent Cover Program in Canada, provide important nesting habitat for grassland bird species. The array of habitats used by birds makes habitat and avian management a complex undertaking, and the scale (for example, local, regional, international) at which management actions can be implemented are such that a universal approach to managing grasslands for the conservation of the entire suite of bird species does not exist. Experienced land managers recognize that it is impossible to manage for all bird species simultaneously, and thus, prioritization is necessary towards those habitats or bird species that the manager or management agency ranks highest for a specific region or management unit. The primary tools available for management are burning, grazing, mowing, herbicide application, and idling, but before choosing a particular practice, a manager will want to consider issues of seasonality, intensity, and frequency. Despite the thousands of studies that are cited in this compendium, much remains unknown about the effects of management practices on bird species. The series of species accounts in this compendium review the current state of knowledge regarding management of grassland and sagebrush bird species and summarize information on the effects of management practices on individual species. The accounts do not give definitive statements on the effects of management practices for any particular species, primarily because there are very few replicated studies in which identical management practices have been applied in the same geographical area with consistent results, which are elements necessary to provide concrete recommendations for the management of a particular species in a particular area. Documentation of the effects of management treatments on individual species through statistically sound methods that incorporate multiple years and locations will further scientists’ and land managers’ knowledge far more than 1–2-year studies that are limited in scope as well as time, but studies of that scope and breadth are rare.

Professional Paper↗

Kīlauea’s 2008–2018 summit lava lake—Chronology and eruption insights

The first eruption at Kīlauea’s summit in 25 years began on March 19, 2008, and persisted for 10 years. The onset of the eruption marked the first explosive activity at the summit since 1924, forming the new “Overlook crater” (as the 2008 summit eruption crater has been informally named) within the existing crater of Halemaʻumaʻu. The first year consisted of sporadic lava activity deep within the Overlook crater. Occasional small explosions deposited spatter and small wall-rock lithic pieces around the Halemaʻumaʻu rim. After a month-long pause at the end of 2008, deep sporadic lava lake activity returned in 2009. Continuous lava lake activity began in February 2010. The lake rose significantly in late 2010 and early 2011, before subsequently draining briefly in March 2011. This disruption of the summit eruption was triggered by eruptive activity on the East Rift Zone. Rising lake levels through 2012 established a more stable, larger lake in 2013, with continued enlargement over the subsequent 5 years. Lava reached the Overlook crater rim and overflowed on the Halemaʻumaʻu floor in brief episodes in 2015, 2016, and 2018, but the lake level was more commonly 20–60 meters below the rim during 2014–18. The lake was approximately 280×200 meters (~42,000 square meters) by early 2018 and formed one of the two largest lava lakes on Earth. A new eruption began in the lower East Rift Zone on May 3, 2018, causing magma to drain from the summit reservoir complex. The lava in Halemaʻumaʻu had drained below the crater floor by May 10, followed by collapse of the Overlook and Halemaʻumaʻu craters. The collapse region expanded as much of the broader summit caldera floor subsided incrementally during June and July. By early August 2018, the collapse sequence had ended, and the summit was quiet. The historical changes in May–August 2018 brought a dramatic end to the decade of sustained activity at Kīlauea’s summit. The unique accessibility of the 2008–18 lava lake provided new observations of lava lake behavior and open-vent basaltic outgassing. Data indicated that explosions were triggered by rockfalls from the crater walls, that the lake consisted of a low-density foamy lava, that cycles of gas pistoning were rooted at shallow depths in the lake, and that lake level fluctuations were closely tied to the pressure of the summit magma reservoir. Lava chemistry added further support for an efficient hydraulic connection between the summit and East Rift Zone. Notwithstanding the benefits to scientific understanding, the eruption presented a persistent hazard of volcanic air pollution (vog) that commonly extended far from Kīlauea’s summit.

Hawaii↗

Views of a century of activity at Kīlauea Caldera—A visual essay

The 2018 eruption of Kīlauea Volcano marked the end of the first sustained period of volcanic activity at Halemaʻumaʻu Crater in 94 years. The views of the lava lake (informally named “Overlook,” nestled within Halemaʻumaʻu) lasted for a decade and seemed timeless. But as we were recently reminded, the summit of Kīlauea is part of a dynamic system that has provided countless new views to observers over the centuries. This visual essay features a few of the many scenes recorded by early observers at the volcano, from the first visits by westerners in 1823 through the explosive eruption of 1924. The early images left by casual visitors, artists, and photographers raise many questions: What is shown? Where is this? Who captured the scene and when? How accurate is the portrayal? Where possible, we attempt to answer these questions and provide interpretations of the images featured. In 1912, the nature of observations at Kīlauea changed when Thomas A. Jaggar, Jr., and others occupied the Hawaiian Volcano Observatory on a full-time basis. They began a visual and written record of what they saw, heard, and experienced that has continued to this day. We describe some of the early work of these scientists and photographers, and showcase the results.

Hawaii↗

Tephra from Kīlauea’s 2008–2018 lava lake eruption—Proximal deposits and dispersal characteristics

A network of ten buckets was established early in the 2008–2018 summit eruption at Kīlauea to collect proximal tephra ejected from the new, informally named the “Overlook crater”; the buckets were emptied on most days of the eruption thereafter. This report summarizes the results of more than 2,400 different sampling intervals (most 1–3 days long) during the eruption, focusing on the physical and dispersal characteristics of the tephra deposits. The network was within about 300 meters south of the vent to capture tephra dispersed by the dominant northeast trade wind. The juvenile tephra mainly reflected spattering at the southeast (SE) sink, a downwelling area in the southeastern part of the lava lake in the Overlook crater that remained in the same area throughout the eruption, with admixtures of solid rock and secondary minerals derived from the wall of the crater. The proportion of juvenile material to lithic material ranged widely early in the eruption but was generally greater than 90 percent for the last 6 years of the eruption as lake level rose and the crater walls decreased in height and became more stable. The accumulation rate of tephra at each bucket was strongly dependent on the location of the bucket and reflects the interplay between lava lake level and wind direction and speed. The mass per unit area (m/a) of collected tephra was a maximum of about 97 kilograms per square meter for the entire eruption, equivalent to a thickness of about 75 millimeters. Thirty-two explosive events with a volcanic explosivity index of −2 to −4 deposited much of the tephra in the network. Fifteen of these rock-fall-induced events occurred within 6 days of one another. Pele’s hair, a volcanic glass predominantly associated with quieter activity at the vent in the final half of the eruption, was dispersed more than 60 kilometers downwind from the lava lake and formed a nearly continuous deposit near the Overlook crater. This eruption was probably the most frequently sampled long-lasting eruption in history, but most of the deposits are ephemeral. The collected samples, although generally of small mass, are retained by the Hawaiian Volcano Observatory and are available for detailed study.

Hawaii↗

The flora of the New Albany shale; Part 2, The Calamopityeae and their relationships

Material referable to Calamopitys americana, Calamopitys foerstei, Stenomyelon muratum, Kalymma lirata, Kalymma resinosa, and Kalymma auriculata, from the upper portion of the New Albany shale in central Kentucky, is described. All these species are based on the internal structure of stems and petioles. The suggestion is made that the genus Stenomyelon should be included in the family Calamopityeae rather than in a separate family. Relationships of the several species and genera belonging to the Calamopityeae are discussed, and it is recommended that the name Calamopitys be restricted to manoxylic forms (C. saturni Unger, etc.), that Eristophyton be used for the pycnoxylic species which have in the past been placed in Calamopitys, and that Sphenoxylon be adopted for the American species which has been called Calamopitys eupunctata. It is pointed out that the Calamopityeae may be divided, naturally, into two major groups-a manoxylic, protostelic group and a pycnoxylic, medullated group. Stenomyelon is probably in the lineage of the more primitive Calamopityeae, and Endoxylon is presumably the most advanced type now known.

Professional Paper↗

Pocoshock Creek Gneiss and redefinition of the Petersburg Granite, central-eastern piedmont of Virginia

The Petersburg Granite (sensu lato) was formerly interpreted to be a single late Paleozoic composite batholith in the central-eastern part of the Piedmont Physiographic Province of Virginia. Detailed mapping beginning in the mid 2000s resulted in the subdivision of these voluminous granitic rocks into five units—layered granitic gneiss, foliated granite, porphyritic granite, subidiomorphic (equigranular) granite, and pegmatitic granite. U-Pb zircon geochronology demonstrate that foliated granite and layered granitic gneiss currently assigned to the batholith are 100 million years (m.y.) older, and yield Silurian to Devonian ages (ca. 425 mega-annum (Ma) to ca. 403 Ma). We propose the name Pocoshock Creek Gneiss for these strongly foliated and layered gneisses. Geochronologic data also require redefinition of the Petersburg Granite (sensu stricto). Massive equigranular and porphyritic rock types of the Petersburg Granite (sensu stricto) are geochemically distinct from a subset of Pocoshock Creek Gneiss samples. Massive equigranular and porphyritic rock types are similar to another, more granitic subset of the Pocoshock Creek Gneiss, which indicates different magma sources for the Petersburg Granite (sensu stricto) and Pocoshock Creek Gneiss but also likely indicates assimilation of Pocoshock Creek Gneiss during late Paleozoic intrusion of these Petersburg Granite (sensu stricto) rock types. Equigranular granite southwest of Petersburg, Virginia is 15–20 m.y. older than porphyritic granite, massive granite, and monzodiorite (ca 300 Ma) near Richmond, Virginia. The Petersburg Granite (sensu stricto) consists of two regional plutons—the northern Richmond pluton and the southern DeWitt-Sutherland pluton. The DeWitt-Sutherland pluton of Early Pennsylvanian age is separated from Late Pennsylvanian to early Permian granite of the Richmond pluton by a map scale septum of Pocoshock Creek Gneiss. Geochemical analyses of 15 samples of Pocoshock Creek Gneiss are compared to other igneous suites throughout the Appalachian orogen. Whole rock geochemistry shows elevated average thorium and uranium values in porphyritic granite compared to massive equigranular granite and Pocoshock Creek Gneiss and suggest that homes and businesses built on that rock type of the Richmond pluton may be most at risk for uranium and (or) dissolved radon in groundwater or radon gas in confined spaces.

Professional Paper↗

The National Park Service stratotype inventory

Introduction An Inventory of Stratigraphic Origins within the National Park Service The geologic history of Earth is recorded in layers or bodies of rock that are classified in a hierarchical order with several different categories of geologic units, including: supergroup, group, formation, member, bed, supersuite, suite, or complex. Geologists analyze and classify rock types based on properties that include lithology, texture, thickness, sedimentary structures, fossils, geographic or geospatial distribution, and age. In instances where new geologic units are proposed, a stratotype is assigned to a designated section, locality, or area of well-exposed rock that displays diagnostic characteristics for identification and correlation. Stratotypes are also namesakes, in that formally recognized rock units are named for the places where they were first described, measured, and mapped. Thus, a vast majority of the stratigraphic nomenclature alludes to geographic or geologic features. Some particularly recognizable examples (and their stratotype assignments) include the Paleoproterozoic Vishnu Schist (Vishnu Canyon in Grand Canyon National Park, Arizona), the Early Cambrian Harpers Formation (Harpers Ferry National Historical Park, West Virginia), and the Late Cretaceous Whitney Granodiorite (Mount Whitney in Sequoia and Kings Canyon National Parks, California). Beginning in 2020, the National Park Service (NPS) began a systematic effort to document the occurrence of stratotypes exposed within, partially within, and near NPS administrative boundaries. The NPS stratotype inventory project represents an important component of a geologic resource inventory, as these designations are vital to our national geologic heritage (herein referred to as “geoheritage”) and possess significant scientific, historic, educational, cultural, and aesthetic values. The geoheritage significance of stratotypes is analogous to libraries and museums, in that they are geologic landmarks of Earth history and record the prodigious forces and evolving life forms that define our understanding of the planet. These designated exposures preserve knowledge, represent comparative geologic references where previous observations can be re-examined or reinterpreted, and can serve as valuable educational tools for future geoscientists (Brocx and others, 2019). The NPS stratotype inventory includes the following: Documentation of designated stratotype exposures to confirm their geospatial occurrence within, partially within, and near NPS administrative boundaries, compiled from published reports and maps; Compilation and visualization of the precise geographic locations of the stratotype exposures; and Recommendations that address potential land and resource management issues associated with NPS stratotypes. By achieving these goals, this project helps to raise awareness of stratotypes as a geologic resource by educating NPS staff and the public so that they may better understand, recognize, and protect these important park resources. The focused approach adopted for conducting the stratotype inventories throughout the NPS has centered on the 32 Inventory and Monitoring (I&M) networks established by the NPS during the late 1990s (for more information on each network, see https://www.nps.gov/im/networks.htm). The I&M networks represent groups or clusters of park units that are based on shared geography and natural resource characteristics. The Greater Yellowstone I&M Network, encompassing Bighorn Canyon National Recreation Area, Grand Teton National Park, John D. Rockefeller Jr. Memorial Parkway, and Yellowstone National Park, was used as the pilot network for initiating this stratotype inventory and was first published in November 2020 (Henderson and others, 2020). The 32d and final report on the Northeast Temperate I&M Network was published in October 2022 (Henderson and others, 2022). Currently, the NPS stratotype inventory project has identified more than 700 stratotypes within NPS administrative boundaries.

Professional Paper↗

Stratigraphic revision of the Neogene rocks of Saipan Island, Commonwealth of the Northern Mariana Islands

Geologic mapping in 2006 and 2007, and calcareous nannofossil biostratigraphy combined with comparative analysis of other published data, have resulted in a reinterpretation and revision of the ages and stratigraphic relationships of the Neogene lithostratigraphic units exposed on Saipan Island. These units, chiefly limestone and admixed volcaniclastic rocks, form much of the bedrock of Saipan Island. Stratigraphic revisions include a redefinition of the Tagpochau Limestone, restricting it to rocks of the newly named I Etdot, Tipo Poli, and Marpi Members. Other rocks, formerly included in the Tagpochau Limestone (the Donni Sandstone and the Machegit Conglomerate Members, and an informal transitional facies), are herein assigned to the newly defined Gloria Formation. The Gloria Formation comprises three members: the Machegit Conglomerate Member, the new As Teo Member, and the Donni Sandstone Member. The Tagpochau Limestone contains larger foraminifera that indicate an early Miocene (Aquitanian through middle Burdigalian) age, or a numerical range of about 23 to 18.7 Ma. Overlying the Tagpochau Limestone, both the Fina-sisu and the Gloria Formations are recognized herein to be distinctly younger than the Tagpochau Limestone and not correlative with any parts of that formation as had been previously thought. Basaltic lava flows in the Fina-sisu have yielded radiometric ages that indicate a middle Miocene age, whereas planktonic foraminifera recovered from interbedded sedimentary rock indicate a latest early Miocene age (Langhian). Assemblages of planktonic foraminifera and calcareous nannofossils recovered from the Gloria Formation indicate a latest Miocene age (Messinian) and a numerical age range of about 5.8 to 5.5 Ma. Additional studies could help to constrain the ages of these units more precisely because none of the biostratigraphic samples were taken in the context of measured stratigraphic sections. On an island dependent on groundwater, the revised stratigraphic understanding can inform the development of groundwater models and strategies for identifying water-well sites and targeting drilling depths for potable water. The new stratigraphic understanding can inform future interpretations of the geologic structure of Saipan Island and the Neogene tectonic history of Saipan Island and the Mariana subduction zone.

Professional Paper↗

Lake Bonneville: Geology of northern Utah Valley, Utah

Lake Bonneville was a vast Pleistocene lake that covered 20,000 square miles in northwestern Utah and had a maximum depth of about 1,000 feet. It was a body of water comparable in size to modern Lake Michigan. Surveys of the unconsolidated deposits in the Lake Bonneville basin utilize the same methods used in studies of hard rocks, namely: separation of the deposits into mappable units and contacts between formations; observations of lateral and vertical changes in lithology; and plotting of these data on the map.

Utah↗

Forest conditions in the Absaroka division of the Yellowstone Forest Reserve, Montana and the Livingston and Big Timber quadrangles

The tract of land here designated the Absaroka division of the Yellowstone Forest Reserve was originally the Absaroka Forest Reserve. By proclamation of January 29, 1903, this reserve was merged with the Teton and the Yellowstone forest reserves, the whole taking the name of the Yellowstone Forest Reserve. The western, northern, and eastern boundaries, as then established and as applicable to the Absaroka division, are as follows: "Beginning at the point where the range line between ranges nine (9) and ten (10) east, principal meridian, Montana, intersects the northern boundary of the Yellowstone National Park; thence northerly along said surveyed and unsurveyed range line, allowing for the proper offset on the first (1st) standard parallel south, to the southwest corner of section eighteen (18), township four (4) south, range ten (10) east; thence easterly to the southeast corner of said section; thence northerly to the northeast corner of section six (6); said township: thence easterly to the southeast corner of section thirty-two (32), township three (3) south, range ten (10) east; thence northerly to the northeast corner of section five (5), said township; thence easterly along the township line to the northeast corner of township three (3) south, range eleven (11) east; thence southerly to the southeast corner of said township; thence easterly along the surveyed and unsurveyed township line to the point for the south- west corner of township three (3) south, range fourteen (14) east; thence northerly along the surveyed and unsurveyed range line to the northwest corner of township two (2) south, range fourteen (14) east; thence easterly to the northeast corner of said township; thence southerly to the point for the southeast corner of said township; thence easterly to the point for the northeast corner of township three (3) south, range fifteen (15) east; thence southerly to the point for the southeast corner of said township; thence easterly along the surveyed and unsurveyed township line to the northwest corner of township four (4) south, range eighteen (18) east; thence southerly along the range line to its intersection with the first (1st) standard parallel south; thence easterly along said parallel to the northeast corner of township six (6) south, range eighteen (18) east; thence southerly along the surveyed and unsurveyed range line to the southwest corner of township seven (7) south, range nineteen (19) east; thence easterly to the northwest comer of township eight (8) south, range twenty (20) east; thence southerly to the southwest corner of said township; thence easterly to the southeast corner of said township; thence southerly along the range line to its intersection with the boundary line between the States of Montana and Wyoming." The southern boundary of the area discussed is west from the point where the eastern boundary of the reserve intersects the Montana- Wyoming line to the southeast corner of township 9 north, range 14 east; thence along the northern boundary line of the Yellowstone National Park to the point where said boundary line of the park intersects the range line between ranges 9 and 10 east, principal meridian. The total area, as above delineated, includes 1,334,400 acres.

Montana↗

Geology of Glacier National Park and the Flathead Region, Northwestern Montana

This report summarizes available data on two adjacent and partly overlapping regions in northwestern Montana. The first of these is Glacier National Park plus small areas east and west of the park. The second is here called, for convenience, the Flathead region; it embraces the mountains from the southern tip of Glacier Park to latitude 48 deg north and between the Great Plains on the east and Flathead Valley on the west. The fieldwork under the direction of the writer was done in 1948, 1949, 1950, and 1951, with some work in 1952 and 1953. The two regions together include parts of the Swan, Flathead, Livingstone, and Lewis Ranges. They are drained largely by branches of the Flathead River. On the east and north, however, they are penetrated by tributaries of the Missouri River and in addition by streams that flow into Canada. Roads and highways reach the borders of the regions; but there are few roads in the regions and only two highways cross them. The principal economic value of the assemblage of mountains described in the present report is as a collecting ground for snow to furnish the water used in the surrounding lowlands and as a scenic and wildlife recreation area. A few metallic deposits and lignitic coal beds are known, but these have not proved to be important and cannot, as far as can now be judged, be expected to become so. No oil except minor seeps has yet been found, and most parts of the two regions covered do not appear geologically favorable to the presence of oil in commercial quantities. The high, Hungry Horse Dam on which construction was in progress during the fieldwork now floods part of the Flathead region and will greatly influence the future of that region. The rocks range in age from Precambrian to Recent. The thickest units belong to the Belt series of Precambrian age, and special attention was paid to them. As a result, it is clear that at least the upper part of the series shows marked lateral changes within short distances. This fact introduces complexities into stratigraphic correlation and should be remembered wherever the series is studied. The stromatolites, or fossil algae, in the Belt series, although still imperfectly understood, give clues with respect to problems of ecology and stratigraphy. The subdivisions of the Belt series within the areas covered by the present report are, in ascending order, Altyn limestone, Appekunny argillite, Grinnell argillite, Siyeh limestone, and Missoula group. Local subdivisions of the Missoula group are possible in certain areas, and all the units just named are expected to be subdivided when detailed studies are undertaken. In the Glacier National Park and Flathead regions together, it is probable that between 25,000 and 30,000 feet of beds belonging to the Belt series, possibly more, are present. These consist largely of quartzitic argillite, quartzite, and carbonate rocks, mostly dolomitic. Small gabbroic and diabasic intrusive bodies and, at one horizon, basaltic lava are associated with the Belt series. Above the Belt series is a thick sequence of Cambrian, Devonian, and Carboniferous strata, in which limestone is dominant, followed by strata of Jurassic and Cretaceous age, largely limestone and shale and partly of terrestrial origin. Slightly consolidated gravel, sand, and silt of Tertiary age are preserved in some valleys and as erosional remnants on the plains close to the mountain border. Pleistocene and Recent glacial and fluviatile deposits are plentiful in mountain valleys and on the plains east of the mountains. Sufficient crustal movements took place during the latter part of Belt time to produce tension cracks that permitted some intrusion and related extrusion to occur. Broad crustal warping probably took place at intervals during the Paleozoic era, but these successive movements left little record other than the absence of sedimentary rock units that might otherwise have been deposited. The same can be said of much of the Me

Professional Paper↗

Synopsis of geologic and hydrologic results: Chapter A in Geological Survey research 1961

The Geological Survey is engaged in many different kinds of investigations in the fields of geology and hydrology. These investigations may be grouped into several broad, inter-related categories as follows: (a) Economic geology, including engineering geology (b) Regional geologic mapping, including detailed mapping and stratigraphic studies (c) Resource and topical studies (d) Ground-water studies (e) Surface-water studies (f) Quality-of-water studies (g) Field and laboratory research on geologic and hydrologic processes and principles. The Geological Survey also carries on investigations in its fields of competence for other Federal agencies that do not have the required specialized staffs or scientific facilities. Nearly all the Geological Survey's activities yield new data and principles of value in the development or application of the geologic and hydrologic sciences. The purpose of this report, which consists of 4 chapters, is to present as promptly as possible findings that have come to the fore during the fiscal year 1961 the 12 months ending June 30, 1961. The present volume, chapter A, is a synopsis of the highlights of recent findings of scientific and economic interest. Some of these findings have been published or placed on open file during the year; some are presented in chapters B, C, and D; still others have not been published previously. Only part of the scientific and economic results developed during the year can be presented in this synopsis. Readers who wish more complete or more detailed information should consult the bibliography of reports beginning on page A-156 of this volume, and the collection of short articles presented in the companion chapters as follows: Prof. Paper 424-B Articles 1 to 146 Prof. Paper 424-C Articles 147 to 292 Prof. Paper 424-D Articles 293 to 435 A list of investigations in progress in the Geologic and Water Resources Divisions with the names and addresses of the project leaders is given on pages A-110 to A-155 for those interested in work in progress in various areas or on special topics. During the fiscal year 1961, the services of the Geologic and Water Resources Divisions were utilized, or supported financially in part, by the many Federal and State agencies listed on pages A-106 to A-109. The Geological Survey has also cooperated from time to time with other agencies, and some of the work described in these chapters stems from work of previous years in cooperation with agencies not shown on the list. All cooperating agencies are identified where appropriate in the individual short articles in chapters B, C, and D, and they are mentioned in connection with some of the larger programs summarized in chapter A; because of space limitations, however, their contributions are mentioned in many of the short summary paragraphs contained in chapter A.

Professional Paper↗

Effects of urban development on direct runoff to East Meadow Brook, Nassau County, Long Island, New York

The study described in this report is concerned with the effects of intensive urban development on direct runoff to East Meadow Brook, a southward-flowing stream in central Nassau County, N.Y., during the period 1937-66. The specific objectives of the study were (a) to relate indices of urban development to increases in the volume of annual direct runoff to the stream; (b) to compare hydrograph features at different periods during the transition of the drainage basin from rural to urban conditions; and (c) to compare the rainfall-runoff relations for periods before and after urban development. Periods of housing and street construction in the drainage basin correspond to three distinct periods of increased direct runoff after the base period 1937-43-namely, 1944-51, 1952-59, and 1960-62. During each period, the average annual direct runoff increased because of an increase in the area served by storm sewers that discharged into East Meadow Brook. The amount of land served by sewers increased from about 570 acres in 1943 to about 3,600 acres in 1962, or about 530 percent. During this same period, the average annual direct runoff increased from about 920 acre-feet per year to about 3,400 acre-feet per year, or about 270 percent. The shape of direct-runoff unit hydrographs of East Meadow Brook also changed during the period of study. The average peak discharge of a 1-hour-duration unit hydrograph increased from 313 cubic feet per second, for storms in 1937-43, to 776 cubic feet per second, for storms in 1960-62, or about 2.5 times. In addition, the widths of the unit hydrographs for 1960-62 at values of 50 and 75 percent of the peak discharge were 38 and 28 percent, respectively, the comparable widths of the unit hydrographs for 1937-43. An analysis of the rainfall-runoff relations for both preurban and urban conditions indicates that the direct runoff for both periods increased with the magnitude of the storm. However, the direct runoff during a period of urbanized conditions (1964- 66) was from 1.1 to 4.6 times greater than the corresponding runoff during the preurban period 1937-43, depending on the size of the individual storm. The volume of direct runoff from the parts of the subarea equipped with storm sewers that discharged into East Meadow Brook is estimated to have been roughly 3,000 acre-feet per year in 1960-62, or about 20 percent of the precipitation on those parts of the area. The increase in direct runoff probably represents a loss of ground-water recharge. However, because data changes in evapo-transpiration are insufficient and because the effects of recharge basins are unknown, adequate quantitative estimates of groundwater recharge can not be made. On the basis of the present zoning regulations and on assumption that an additional 320 acres in the Hempstead subarea will be serviced by storm sewers that discharge into East Meadow Brook, direct runoff from the subarea is expected to increase in the future to an estimated 4,000-4,500 acre-feet per year.

New York↗

History of Snake River Canyon indicated by revised stratigraphy of Snake River Group near Hagerman and King Hill, Idaho

A discovery that debris left by the Bonneville Flood (Melon Gravel) overlies McKinney Basalt about 200 feet above the Snake River near King Hill requires that the stratigraphy of the Snake River Group be revised. In former usage, the McKinney Basalt and its immediately older companion, the Wendell Grade Basalt, were considered on the basis of equivocal field relations to be younger than the Melon Gravel and were assigned to the Recent. These lava flows are here reclassified as Pleistocene. The Bancroft Springs Basalt, which consists of both subaerial lava and pillow lava in a former Snake River canyon, was previously separated from the McKinney but is now combined with the McKinney. Accordingly, the name Bancroft Springs Basalt is here abandoned. This revised stratigraphy is first described from geomorphic relations of the McKinney Basalt near King Hill and is then discussed in the light of drainage changes caused by local lava flows during entrenchment of the Snake River. Near King Hill, a former Snake River canyon was completely filled by McKinney Basalt at the place called Bancroft Springs, hut the depth of this lava in the next several miles of the canyon downstream (along a route that approximately coincides with the present canyon) steadily decreased. This ancestral geomorphology is inferred from the former canyon route and, also, from the continuity in gradient of the McKinney lava surface downstream from Bancroft Springs. The drainage history recorded by various lava flows and river deposits of the Snake River Group indicates that the McKinney and Wendell Grade Basalts erupted after the Snake River canyon had reached its present depth of about 500 feet. The Snake River of that time, as far downstream as Bliss, flowed approximately along its present route. The Wood River of that time, however, skirted the north flank of Gooding Butte and joined the ancestral Snake at a junction, now concealed by lava, north of the present canyon about 3 miles west of Bliss. From that place the former Snake River canyon, also now concealed by lava, continued west to Bancroft Springs and thence along a route close to the present canyon to King Hill. To become entrenched in a canyon 500 feet deep, the Snake River downstream from Hagerman became progressively more incised while its upstream route was pushed south in several earlier canyons by intermittent lava flows. Distinctive gravel deposits help to establish the episodes of progressive canyon cutting and to determine the routes of ancestral drainage, including the former position of the Wood River. As canyon cutting continued, springs began to emerge where lavas had filled the earlier canyons. When the Snake River canyon eventually attained its approximate present depth, the Wendell Grade Basalt erupted near Shoshone and, as several tongues, spread west to the canyon rim opposite Hagerman. One tongue crossed the future route of the Wood River, and another covered an upland area of Sand Springs Basalt that had previously reached the canyon floor at Hagerman. The McKinney Basalt then erupted from McKinney Butte northeast of Bliss and spread southward as a subaerial flow, covering part of the Wendell Grade Basalt. It filled the ancestral Wood River canyon and the Snake River canyon of that time west of Bliss as far downstream as King Hill. The resulting dam of lava impounded a deep lake, which extended upstream in the canyon beyond Hagerman. Copious amounts of the McKinney spilled into this temporary lake and produced pillow lava. About 2 miles west of Bliss, pillow lava 500 feet thick completely fills the former canyon and is protected by rimrock of the subaerial McKinney Basalt. From Bliss, the pillow facies extends upstream as far as the McKinney rimrock - about 5 miles. Eruption of the McKinney Basalt diverted the Wood River to a course along the southeast edge of this lava flow. The temporary lake that was dammed by McKinney Basalt west of Bliss spilled along the sou

Idaho↗

Geologic history of the Colorado River: Chapter C in The Colorado River region and John Wesley Powell (Professional Paper 669)

John Wesley Powell clearly recognized that the spectacular features of the Colorado River - its many grand canyons - were dependent upon the structural history of the mountainous barriers crossed by the river. He conceived of three different historical relationships between rivers and structural features: (1) Newly uplifted land surfaces have rivers that flow down the initial slope of the uplift; these relationships he termed consequent. (2) A river may be older than an uplift that it crosses because it has been able to maintain its course by eroding downward as the uplift progresses; this relationship he named antecedent. (3) An uplifted block may have been buried by younger deposits upon which a river becomes established. The river, in cutting downward, uncovers the uplifted block and becomes incised into it; this relationship he called superimposed. The geologic history of the Colorado River involves all three relationships. In addition, although the position of the river course through a particular structural barrier may have been the result of superposition, the depth of the canyon at that point may be largely due to renewed uplift of the barrier; such deepening of the canyon, therefore, is due to antecedence. The problem of the Colorado River remains today very much as G. K. Gilbert stated it nearly 100 years ago: "How much is antecedent and how much is superimposed?" The question must be asked separately for each stretch of the river.

Colorado River↗