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At least 1,621 records · Page 90Linked to original sources

Occurrence and distribution of PFAS in sampled source water of public drinking-water supplies in the surficial aquifer in Delaware, 2018; PFAS and groundwater age-dating results

The U.S. Geological Survey, in cooperation with the Delaware Department of Natural Resources and Environmental Control and the Delaware Geological Survey, conducted a groundwater-quality investigation to (1) describe the occurrence and distribution of PFAS, and (2) document any changes in groundwater quality in the Columbia aquifer public water-supply wells in the Delaware Coastal Plain between 2000 and 2008 and between 2008 and 2018. Thirty public water-supply wells located throughout the Columbia aquifer of the Delaware Coastal Plain were sampled from August through November 2018. Groundwater collected from the wells was analyzed for the occurrence and distribution of 18 per- and polyfluorinated alkyl substances (PFAS) as well as groundwater age. Descriptive statistical analyses were performed to assess PFAS analytical results within the well network and the combined perfluorooctanoic acid (PFOA) and perfluorooctane sulfonate (PFOS) concentrations were compared to the U.S. Environmental Protection Agency’s (EPA) health advisory level (HAL) for informational purposes only and not for evidence of compliance or noncompliance with Federal regulations. The EPA’s HAL is a health-based reference level for public drinking water as supplied to customers and is not applied to source (raw) water. Groundwater-age data were compared for sites sampled in 2000, 2008, and 2018 to document any changes. All samples were analyzed for 18 PFAS using EPA Method 537 (modified). Forty-four percent of the analyzed PFAS were detected in the study well network. Sixteen of the sampled wells have one or more PFAS detections, and as many as eight different PFAS were found in a single sample. Wells with a higher number of PFAS detected (five or more) were in New Castle and Sussex Counties. The PFAS most frequently detected were PFOA, with 47 percent detection; perfluorohexanoic acid (PFHxA), with 33 percent detection; and PFOS and perfluorohexane sulfonate (PFHxS), with 27 percent detection each. PFAS concentrations were below 1,000 parts per trillion (ppt). Two wells exceeded the EPA’s lifetime-drinking water health advisory level of 70 ppt for combined concentrations of PFOA and PFOS. The average age of groundwater entering the screens of the supply wells sampled in 2018 ranged from 8.2 to 45.8 years, with a median groundwater age of 25.7 years. Groundwater age was positively correlated with well depth and negatively correlated with dissolved oxygen. Groundwater age and PFAS concentrations were negatively correlated in the Columbia aquifer. Data from the 23 resampled wells indicate a significant positive difference in the average modeled groundwater-sample-age results. The average groundwater age from samples collected in 2018 was generally 5 years older than the average groundwater age from samples collected in 2008. The same pattern was found during cycle two (2008) of this study, where the 2008 groundwater age was on average 7 years older than the samples collected in 2000. The distribution of groundwater sample ages among the 17 trend wells and during the three study cycles (2000, 2008, and 2018) indicates that sample-age medians were statistically different from zero; well-water sample-age data show a slight increase in groundwater sample age.

Delaware↗

Summary of ground-water and surface-water data for city of Pensacola and Escambia County, Florida

Hydrologic, geologic, and water-quality data collected in Escambia County, Florida, October 1962 through September 1980 are presented. The data were collected by the U.S. Geological Survey as part of a cooperative investigation with the city of Pensacola and Escambia County to provide information on the quality and quantity of water available from the sand-and-gravel aquifer and selected surface-water sites in Escambia County. Ground-water data include records of 440 wells, chemical and physical analyses of water quality for 325 wells, 6 long-term hydrographs, and 19 lithologic logs. Surface-water data include streamflow measurements and analyses of water collected at 9 sites. Maps of the county show the locations of the data-collection sites. (USGS)

Open-File Report↗

Ground-water movement and nitrate in ground water, East Erda area, Tooele County, Utah, 1997-2000

Nitrate was discovered in ground water in the east Erda area of Tooele County, Utah, in 1994. The U.S. Geological Survey, in cooperation with Tooele County, investigated the ground-water flow system and water quality in the eastern part of Tooele Valley to determine (1) the vertical and horizontal distribution of nitrate, (2) the direction of movement of the nitrate contamination, and (3) the source of the nitrate. The potentiometric surface of the upper part of the basin-fill aquifer indicates that the general direction of ground-water flow is to the northwest, the flow system is complex, and there is a ground-water mound probably associated with springs. The spatial distribution of nitrate reflects the flow system with the nitrate contamination split into a north and south part by the ground-water mound. The distribution of dissolved solids and sulfate in ground water varies spatially. Vertical profiles of nitrate in water from selected wells indicate that nitrate contamination generally is in the upper part of the saturated zone and in some wells has moved downward. Septic systems, mining and smelting, agriculture, and natural sources were considered to be possible sources of nitrate contamination in the east Erda area. Septic systems are not the source of nitrate because water from wells drilled upgradient of all septic systems in the area had elevated nitrate concentrations. Mining and smelting activity are a possible source of nitrate contamination but few data are available to link nitrate contamination with mining sites. Natural and agricultural sources of nitrate are present east of the Erda area but few data are available about these sources. The source(s) of nitrate in the east Erda area could not be clearly delineated in spite of considerable effort and expenditure of resources.

Utah↗

Water quality and hydrology of the Lac Vieux Desert watershed, Gogebic County, Michigan, and Vilas County, Wisconsin, 2002-04

Lac Vieux Desert is a prominent 6.6 square-mile lake that straddles the Michigan-Wisconsin border and forms the headwaters of the Wisconsin River. For generations, the Lac Vieux Desert Band of Lake Superior Chippewa Indians have used Lac Vieux Desert and the surrounding area for growing and harvesting wild rice, and hunting and fishing. The Lac Vieux Desert Band is concerned about the impact of lake-stage regulation on hydrology and ecology, and the impact on water quality of development along and near the shore, and recreational watercraft use and sport fishing. In 2005, the U.S. Geological Survey completed a water-resources investigation of the Lac Vieux Desert watershed in cooperation with the Lac Vieux Desert Band of Lake Superior Chippewa Indians. Water quality of Lac Vieux Desert is typical of many lakes in the northern United States. Trophic State Index calculations classify Lac Vieux Desert as a highly productive eutrophic lake. The pH of water in Lac Vieux Desert ranged from 6.5 to 9.5, and specific conductance ranged from 62 to 114 µs/cm. Chloride concentration was less than 1.5 mg/L, indicating little effect from septic-tank or road-salt input. Results indicate that the water can be classified as soft, with hardness concentrations reported as calcium carbonate ranging from 29 to 49 mg/L. Concentrations of calcium, magnesium, chloride, and other dissolved solids ranged from 47 to 77 mg/L. Alkalinity of Lac Vieux Desert ranged from 27 to 38 mg/L. Pervasive aquatic blooms, including a bloom noted during the September 2003 sampling, are apparently common in late summer. Biological productivity at Lac Vieux Desert does not appear to have changed appreciably between 1973 and 2004. In the current study, total phosphorus concentrations ranged from 0.01 to 0.064 mg/L and dissolved nitrite plus nitrate nitrogen concentrations ranged from at, or below detection limit to 0.052 mg/L. Overabundance of nutrients in Lac Vieux Desert, particularly nitrogen and phosphorus, could result in considerable degradation in lake-water quality. The estimated water balance includes the following inputs from the surrounding watershed: direct precipitation (35 percent); runoff, composed of streamflow and overland flow (50 percent); and ground-water flow (15 percent). Outputs from Lac Vieux Desert include streamflow into the Wisconsin River (68 percent) and evaporation from the lake surface (32 percent). Seasonal regulation of Lac Vieux Desert outflow results in an artificially high lake stage throughout the year, except from late winter to very early spring, prior to snowmelt and runoff. Regulation of Lac Vieux Desert outflow causes Wisconsin River streamflow to be artificially low during spring and summer and artificially high in fall and winter. Recent studies indicate that lake-level regulation over the past century may have affected wild rice growth and propagation in Lac Vieux Desert. As per licensing agreement between the Federal Energy Regulatory Commission and the Wisconsin Valley Improvement Company (operators of the dam at the outlet), the maximum lake level of Lac Vieux Desert was lowered about 0.8 feet to investigate the relation between lake-level regulation and propagation of wild rice from 2003 through 2012. Recent plantings of wild rice by the Lac Vieux Desert Band have been successful, indicating that suitable habitat and hydrologic regime were present in 2004-05.

Michigan, Wisconsin↗

Occurrence and distribution of organic chemicals and nutrients and comparison of water-quality data from public drinking-water supplies in the Columbia aquifer in Delaware, 2000-08

The U.S. Geological Survey, in cooperation with the Delaware Department of Natural Resources and Environmental Control and the Delaware Geological Survey, conducted a groundwater-quality investigation to (a) describe the occurrence and distribution of selected contaminants, and (b) document any changes in groundwater quality in the Columbia aquifer public water-supply wells in the Coastal Plain in Delaware between 2000 and 2008. Thirty public water-supply wells located throughout the Columbia aquifer of the Delaware Coastal Plain were sampled from August through November of 2008. Twenty-two of the wells in the sampling network for this project were previously sampled in 2000. Eight new wells were selected to replace wells no longer in use. Groundwater collected from the wells was analyzed for the occurrence and distribution of selected pesticides, pesticide degradates, volatile organic compounds, nutrients, and major inorganic ions. Nine of the wells were analyzed for radioactive elements (radium-226, radium-228, and radon). Groundwater-quality data were compared for sites sampled in both 2000 and 2008 to document any changes in water quality. One or more pesticides were detected in samples from 29 of the 30 wells. There were no significant differences in pesticide and pesticide degradate concentrations and similar compounds were detected when comparing sampling results from 2000 and 2008. Pesticide and pesticide degradate concentrations were generally less than 1 microgram per liter. Twenty-four compounds, 14 pesticides, and 10 pesticide degradates were detected in at least one sample; the pesticide degradates, metolachlor ethanesulfonic acid, deethylatrazine, and alachlor ethanesulfonic acid were the most frequently detected compounds, each found in more than 50 percent of samples. Almost 80 percent of the detected pesticides were agricultural herbicides, which reflects the prevalence and wide distribution of agriculture in sampled areas, as well the dominance of agricultural pesticides among the target analytes for this study. No concentration of a pesticide or pesticide degradate exceeded any regulatory standard. Dieldrin, an insecticide that has been banned for several decades, was detected at a concentration that exceeded a non-regulatory health-based screening level of 0.002 micrograms per liter at nine sites. Volatile organic compounds (VOCs) were generally detected at concentrations of less than 1 microgram per liter, although 7 of the 31 detected VOCs had concentrations greater than 1 microgram per liter. There were no significant differences in VOC concentrations from 2000 to 2008; however, among the resampled wells, the mean number of VOCs detected per well was significantly different over the 8-year period. The number of VOCs detected per well decreased in 73 percent of the resampled wells; the decrease ranged from one to eight fewer detections in 2008 than in 2000. Chloroform and methyl tert-butyl ether were the most frequently detected VOCs, at 90 percent and 63 percent, respectively, among the 30 wells. Solvents were the most frequently detected class of VOCs. All measured concentrations of VOCs in groundwater were below established standards for drinking water and below other health-based guidelines. There were no significant differences in nutrient or major-ion concentrations between 2000 and 2008, however, the medians of two field measurements, pH and dissolved oxygen, were significantly higher in 2008 than in 2000 in the resampled wells. Although pH and dissolved oxygen were higher, water was still acidic and predominantly oxic. Nitrate was the predominant nutrient species in the Columbia aquifer, with a 90-percent detection frequency. The median nitrate concentration in groundwater was 4.88 milligrams per liter, which was slightly lower than, but not significantly different from, the median of 5.23 milligrams per liter for the 2000 samples. Concentrations of nitrate exceeded the U.S. Environmental Protection Agency's Maximum Contaminant Level or Federal drinking-water standard of 10 milligrams per liter as nitrogen in samples from two wells. Eight of the 30 wells sampled had iron or manganese concentrations that exceeded the U.S. Environmental Protection Agency's Secondary Maximum Contaminant Level; nine samples exceeded the Health Advisory Limit set by the Delaware Division of Public Health of 20 milligrams per liter for sodium in drinking water. Two radiochemical isotopes, radium-226 and radon-222, were detected in all nine groundwater samples analyzed; five samples had detectable levels of radium-228 activity. None of the samples exceeded the U.S Environmental Protection Agency's Maximum Contaminant Level for radium or radon in drinking water. Although radioactive elements were more frequently detected in 2008 than in 2000, this increased detection frequency is more likely due to lower detection levels in 2008 than 2000. The average age of groundwater entering the screens of the production wells sampled in 2008 ranged from 6 to 35 years, with a median groundwater age of 22 years. Groundwater age was positively correlated with well depth and negatively correlated with dissolved oxygen. Data from the 22 resampled wells indicate a significant positive difference in the average modeled groundwater-sample-age results. The average groundwater age from samples collected in 2008 was generally 7 years older than the average groundwater age from samples collected in 2000.

Delaware↗

Variability in stream chemistry in relation to urban development and biological condition in seven metropolitan areas of the United States, 1999-2004

Beginning in 1999, the U.S. Geological Survey National Water Quality Assessment Program investigated the effects of urban development on stream ecosystems in nine metropolitan study areas across the United States. In seven of these study areas, stream-chemistry samples were collected every other month for 1 year at 6 to 10 sites. Within a study area, the sites collectively represented a gradient of urban development from minimally to highly developed watersheds, based on the percentage of urban land cover; depending on study area, the land cover before urban development was either forested or agricultural. The stream-chemistry factors measured in the samples were total nitrogen, total phosphorus, chloride, and pesticide toxicity. These data were used to characterize the stream-chemistry factors in four ways (hereafter referred to as characterizations)—seasonal high-flow value, seasonal low-flow value, the median value (representing a single integrated value of the factor over the year), and the standard deviation of values (representing the variation of the factor over the year). Aquatic macroinvertebrate communities were sampled at each site to infer the biological condition of the stream based on the relative sensitivity of the community to environmental stressors. A Spearman correlation analysis was used to evaluate relations between (1) urban development and each characterization of the stream-chemistry factors and (2) the biological condition of a stream and the different characterizations of chloride and pesticide toxicity. Overall, the study areas where the land cover before urban development was primarily forested had a greater number of moderate and strong relations compared with the study areas where the land cover before urban development was primarily agriculture; this was true when urban development was correlated with the stream-chemistry factors (except chloride) and when chloride and pesticide toxicity was correlated with the biological condition. Except for primarily phosphorus in two study areas, stream-chemistry factors generally increased with urban development, and among the different characterizations, the median value typically indicated the strongest relations. The variation in stream-chemistry factors throughout the year generally increased with urban development, indicating that water quality became less consistent as watersheds were developed. In study areas with high annual snow fall, the variation in chloride concentrations throughout the year was particularly strongly related to urban development, likely a result of road salt applications during the winter. The relations of the biological condition to chloride and pesticide toxicity were calculated irrespective of urban development, but the overall results indicated that the relations were still stronger in the study areas that had been forested before urban development. The weaker relations in the study areas that had been agricultural before urban development were likely the results of biological communities having been degraded from agricultural practices in the watersheds. Collectively, these results indicated that, compared with sampling a stream at a single point in time, sampling at regular intervals during a year may provide a more representative measure of water quality, especially in the areas of high urban development where water quality fluctuated more widely between samples. Furthermore, the use of "integrated" values of stream chemistry factors may be more appropriate when assessing relations to the biological condition of a stream because the taxa composition of a biological community typically reflects the water-quality conditions over time.

Scientific Investigations Report↗

The effectiveness of water-treatment systems for arsenic used in 11 homes in Southwestern and Central Ohio, 2013

In 2013, the U.S. Geological Survey and the Miami Conservancy District investigated the effectiveness of methods used to remove arsenic from drinking water at 11 homes in southwestern and central Ohio. The untreated (raw) ground-water had arsenic concentrations of 7.7–382 micrograms per liter (µg/L), and the median concentration was 30 µg/L. The pH was neutral to slightly alkaline, and redox conditions were strongly reducing, as indicated by high concentrations of iron. The predominant arsenic species was arsenite (As 3+ ), which is difficult to treat because it exists in water as an uncharged compound (H 3 AsO 3 ). The water-treatment systems included (1) seven single-tap reverse-osmosis systems, (2) two whole-house oxidation/filtration systems, and (3) two systems that included wholehouse anion exchange and single-tap reverse osmosis. All but one system included pretreatment by a water softener, and two systems included preoxidation to convert arsenite (As 3+ ) to arsenate (As 5+ ) before treatment by anion exchange. None of the treatment systems removed all of the arsenic from the drinking water. About one-half of the systems decreased the arsenic concentration to less than the maximum contamination level of 10 µg/L. The effectiveness of the systems varied widely; the percentage of arsenic removed ranged from 2 to 90 percent, and the median was 65 percent. At some sites, the low effectiveness of arsenic removal may have been related to system maintenance and(or) operation issues. At two sites, homeowners acknowledged that the treatment systems had not been maintained for several years. At two other sites, the treatment systems were being maintained, but the water-quality data indicated that one of the components was not working, unbeknownst to the homeowner. EPA research at a small number of sites in Ohio indicated that operation and maintenance of some arsenic-treatment systems was not always simple. Another factor that affected system effectiveness was the quality of the raw water. In general, the treatment systems were less effective at treating higher concentrations of arsenic. For five sites with raw-water arsenic concentrations of 10–30 µg/L, the systems removed 65–81 percent of the arsenic, and the final concentrations were less than the maximum contamination level. For three sites with higher raw-water arsenic concentrations (50–75 µg/L), the systems removed 22–34 percent of the arsenic; and the final concentrations were 4–5 times more than the maximum contamination level. Other characteristics of the raw water may have affected the performance of treatment systems; in general, raw water with the higher arsenic concentrations also had higher pH, higher concentrations of organic carbon and ammonia, and more reducing (methanogenic) redox conditions. For sites with raw-water arsenic concentrations of 10–30 µg/L, two types of systems (reverse osmosis and oxidation/filtration) removed similar amounts of arsenic, but the quality of the treated water differed in other respects. Reverse osmosis caused substantial decreases in pH, alkalinity, and concentrations of most ions. On the other hand, oxidation/filtration using manganese-based media caused a large increase of manganese concentrations, from less than 50 µg/L in raw water to more than 700 µg/L in outflow from the oxidation filtration units. It is not known if the results of this study are widely applicable; the number of systems sampled was relatively small, and each system was sampled only once. Further study may be warranted to investigate whether available methods of arsenic removal are effective/practical for residential use in areas like Ohio, were groundwater with elevated arsenic concentrations is strongly reducing, and the predominant arsenic species is arsenite (As 3+ ).

Ohio↗

Hydrogeology and groundwater geochemistry of till confining units and confined aquifers in glacial deposits near Litchfield, Cromwell, Akeley, and Olivia, Minnesota, 2014–18

Confined (or buried) aquifers of glacial origin overlain by till confining units provide drinking water to hundreds of thousands of Minnesota residents. The sustainability of these groundwater resources is not well understood because hydraulic properties of till that control vertical groundwater fluxes (leakage) to underlying aquifers are largely unknown. The U.S. Geological Survey, Iowa State University, Minnesota Geological Survey, and Minnesota Department of Health investigated hydraulic properties and groundwater flow through till confining units using field studies and heuristic MODFLOW simulations. Till confining units in the following late-Wisconsinan stratigraphic units (with locations in parentheses) were characterized: Des Moines lobe till of the New Ulm Formation (Litchfield, Minnesota), Superior lobe till of the Cromwell and Aitkin Formations (Cromwell, Minn.), and Wadena lobe till of the Hewitt Formation (hydrogeology field camp [HFC] near Akeley, Minn.). Pre-Illinoian till of the Good Thunder formation (Olivia, Minn.) was also characterized. Hydraulic and geochemical field data were collected from sediment cores and a series of five piezometer nests. Each nest consisted of five to eight piezometers screened at short vertical intervals in hydrostratigraphic units including (if present) surficial aquifers, till confining units, confined/buried aquifers, and underlying bedrock. Till hydraulic conductivity was estimated from slug tests (horizontal [ K h ]) and constant-rate aquifer tests in the confined aquifer (vertical [ K v ]). Travel times through the till were evaluated with Darcy’s law and stable isotope concentrations. A series of heuristic MODFLOW simulations were used to evaluate groundwater fluxes through till across the range of till hydraulic properties and pumping rates observed at the field sites. The field data demonstrated variability in hydraulic properties between and within till stratigraphic units horizontally and vertically. The variability in hydraulic properties within and between sites resulted in substantial differences in groundwater flux through till. A conceptual understanding that emerges from the vertical till profiles is that they are not homogeneous hydrostratigraphic units with uniform properties; rather, each vertical sequence is a heterogeneous mixture of glacial sediment with differing abilities to transmit water. Till thicknesses varied from 60 to 166 feet, and till textures ranged from a sandy loam (Hewitt Formation, HFC site) to a silt loam/clay loam (Good Thunder formation, Olivia site). Till Kh varied by one to three orders of magnitude within each piezometer nest. Four piezometer nests had downward hydraulic gradients ranging from 0.04 to 0.56, and one nest had a slight upward hydraulic gradient of 0.02. The Cromwell, HFC, and Litchfield 1 sites were examples of “leaky” tills with high Kv (0.001 to 1.1 feet per day [ft/d]) and geometric mean Kh (0.03 to 0.07 ft/d) and extensive vertical hydraulic connectivity between the confined aquifer and the overlying till. Estimated groundwater travel times through these sites ranged from 1 to 81 years, and two of these sites had tritium throughout their till profiles. The tills at the other two sites, Olivia and Litchfield 2, were effective confining units that had low Kv (0.001 to 0.0005 ft/d) and geometric mean Kh (0.0002 to 0.004 ft/d). The till piezometers at these sites had no drawdown response to short-term (up to 10 hours for Olivia and up to 5 days for Litchfield) high-capacity pumping from the confined aquifer. Estimated groundwater travel times through the tills at these sites ranged from 165 to nearly 1,800 years, and tritium was only detected in the upper one-third of these till profiles. Across all sites, the till vertical anisotropy (ratio of K h to K v ) ranged by four orders of magnitude from 0.05 at the Cromwell nest to 70 at the Litchfield 1 nest. Stable isotopes of oxygen and hydrogen indicate that groundwater throughout all five till profiles is younger than the last glacial advance into Minnesota at about 11,000 years ago. The heuristic modeling demonstrated that, for understanding sustainability of groundwater pumping from confined aquifers, knowledge of till hydraulic properties is just as important as knowledge of aquifer hydraulic properties. Substantial differences in groundwater fluxes into and through till were observed across hydrogeologic settings representative of the field sites. Over long periods of time (hundreds of years), pumping-induced hydraulic gradients are established in confined aquifer systems and, even in low hydraulic conductivity tills, these pumping-induced hydraulic gradients increase leakage into and through till compared to ambient conditions. In conclusion, groundwater flowing vertically downward through till confining units (leakage) replenishes water pumped from confined aquifers. Till hydraulic properties, such as those presented in this report, provide important information that can be used to quantify leakage rates through till. Till hydraulic properties are variable over short distances and profoundly affect leakage rates, demonstrating the importance of site-specific till hydraulic data for evaluating the sustainability of groundwater withdrawals from confined aquifers.

Minnesota↗

Water resources of the Lake Traverse Reservation, South and North Dakota, and Roberts County, South Dakota

In 1994, the U.S. Geological Survey, in cooperation with the Sisseton-Wahpeton Sioux Tribe; Roberts County; and the South Dakota Department of Environment and Natural Resources, Geological Survey Program, began a 6-year investigation to describe and quantify the water resources of the area within the 1867 boundary of the Lake Traverse Reservation and adjacent parts of Roberts County. Roberts County is located in extreme northeastern South Dakota, and the 1867 boundary of the Lake Traverse Reservation encompasses much of Roberts County and parts of Marshall, Day, Codington, and Grant Counties in South Dakota and parts of Richland and Sargent Counties in southeast North Dakota. This report includes descriptions of the quantity, quality, and availability of surface and ground water, the extent of the major glacial and bedrock aquifers and named outwash groups, and surface- and ground-water uses within the 1867 boundary of the Lake Traverse Reservation and adjacent parts of Roberts County. The surface-water resources within the 1867 boundary of the Lake Traverse Reservation and adjacent parts of Roberts County include rivers, streams, lakes, and wetlands. The Wild Rice and Bois de Sioux Rivers are tributaries of the Red River within the Souris-Red-Rainy River Basin; the Little Minnesota, Jorgenson, and North Fork Whetstone Rivers are tributaries of the Minnesota River within the Upper Mississippi River Basin, and the James and Big Sioux Rivers are tributaries within the Missouri River Basin. Several of the larger lakes within the study area have been developed for recreation, while many of the smaller lakes and wetlands are used for livestock watering or as wildlife production areas. Statistical summaries are presented for the water-quality data of six selected streams within the study area, and the dominant chemical species are listed for 17 selected lakes within the study area. The glacial history of the study area has led to a rather complex system of glacial aquifers. The boundaries of 11 aquifers and 6 named outwash groups were delineated based on hydrogeologic cross sections, water levels, and water-quality similarities/dissimilarities. The glacial aquifers include Coteau Lakes system, Big Sioux, Alta-mont, Revillo, James, Veblen system, Spiritwood, Hankinson, Rosholt, Milnor Channel, and Fairmount; the bedrock aquifer included in this report is the Dakota. Named outwash groups include the Prairie Coteau, Lonesome Lake, Marday, Eden, Roslyn, and Wilmot. A summary of the character-istics of each of the major aquifers and outwash groups and a summary of selected chemical analyses for each aquifer and outwash group are presented. All aquifers and outwash groups in the study area have either moderately hard or very hard water and are considered fresh to slightly saline. One or more water samples from some of the aquifers and outwash groups have a constituent that was above the recommended or mandatory limit for drinking water. Most aquifers and outwash groups have dissolved solids and sulfate contents above the recommended levels of 500 and 250 mg/L (milligrams per liter), respectively. The Dakota aquifer was the only one to have a mean chloride concentration above the recommended level of 250 mg/L. Nitrate concentrations greater than the mandatory limit of 10 mg/L were found in the Big Sioux aquifer and the Coteau Lakes and Veblen aquifer systems. Concentrations of arsenic greater than 10 ?g/L (micrograms per liter) were found in the Coteau Lakes and Veblen aquifer systems, and in the Rosholt and Fairmount aquifers. Municipalities and rural water systems currently provide most of the water used in the study area-nearly all of it from ground-water sources. Surface-water use is limited to livestock watering. About 55 percent of the total water used in Roberts County is for domestic purposes, with most domestic users served by a public supply system. Irrigation accounts for about 10 percent of the total water used. All

North Dakota, South Dakota↗

Hydrogeology of the unconsolidated sediments, water quality, and ground-water/surface-water exchanges in the Methow River Basin, Okanogan County, Washington

The U.S. Geological Survey, in cooperation with Okanogan County, investigated the hydrogeology of the unconsolidated sedimentary deposits in the Methow River Basin, the quality of surface and ground waters, and the exchanges between ground water and surface water. Alluvium (Qa) and glaciofluvial sediments (Qga) deposited during the Quaternary period constitute the primary aquifer in the Methow River Basin, which is used as a source of water for domestic and public-water supplies and for maintaining streamflow during seasonal dry periods. The sediments form a nearly continuous unit along the valley bottom from above the Lost River to the confluence of the Methow and Columbia Rivers, covering more than 45 square miles of the basin?s surface. There are no distinct units within the deposit that can be identified across or along the valley except for fragments of a possible lake bed near the town of Twisp. Ground-water levels in the unconsolidated aquifer are highest during the summer and lowest in the winter and early spring. Ground water and surface water, sampled during June and September 2001, generally were of high quality. Only two samples from domestic and municipal wells indicated the possibility of ground-water contamination from nitrate and arsenic concentrations. In both cases, potential contamination was isolated to an individual well. No trends in water quality were apparent when comparing the results of this investigation with previous studies. The flow of water between rivers and aquifers is important for regulating the availability of water resources for in-stream and out-of-stream uses in the Methow River Basin. Ground-water discharge from the unconsolidated aquifer to the Methow River from Lost River to Pateros ranged from an estimated 153,000 acre-ft in water year 2001 to 157,000 acre-ft in water year 2002. In contrast, ground-water discharge to the lower Twisp River from Newby Creek to near Twisp ranged from 4,700 acre-ft in water year 2001 to 9,200 acre-ft in water year 2002. The Methow and Twisp Rivers, among others in the basin, are major sources of recharge for the unconsolidated aquifer, particularly during high-flow periods in May and June. Aquifer recharge by both rivers increased with streamflow in water year 2002 compared to water year 2001 as indicated by daily losses of streamflow. Aquifer recharge by the Methow River from Lost River to Pateros was estimated to be 82,000 acre-ft in water year 2001 and 137,000 acre-ft in water year 2002. Aquifer recharge by the Twisp River from Newby Creek to near Twisp was estimated to be 2,000 acre-ft in water year 2001 and 6,400 acre-ft in water year 2002. Seepage from unlined irrigation canals also recharges the unconsolidated aquifer during the late spring and summer and may contribute as much 38,000 acre-ft annually to aquifer recharge in the basin. Some portion of this ground water returns to rivers as indicated by a seasonal increase in ground-water discharge in the Methow River from Winthrop to Twisp and in the lower Twisp River during late summer and early autumn. Although the increase is likely due primarily to irrigation canal seepage, however, fluvial recharge during the summer also may have contributed to the increase. The increased rate of ground-water discharge decays by January in both reaches.

Washington↗

Determination of hydraulic conductivity in three dimensions and its relation to dispersivity: Chapter D in Ground-water contamination by crude oil at the Bemidji, Minnesota, research site; US Geological Survey Toxic Waste--ground-water contamination study

Recent investigations suggest that dispersion in aquifers is scale dependent and a function of the heterogeneity of aquifer materials. Theoretical stochastic studies indicate that determining hydraulic-conductivity variability in three dimensions is important in analyzing the dispersion process. Even though field methods are available to approximate hydraulic conductivity in three dimensions, the methods are not generally used because of high cost of field equipment and because measurement and analysis techniques are cumbersome and time consuming. The hypothesis of this study is that field-determined values of dispersivity are scale dependent and that they may be described as a function of hydraulic conductivity in three dimensions. The objectives of the study at the Bemidji research site are to (1) determine hydraulic conductivity of the porous media in three dimensions, (2) determine field values of dispersivity and its scale dependence on hydraulic conductivity, and (3) develop and apply a computerized data-collection, storage, and analysis system for field use in comprehensive determination of hydraulic conductivity and dispersivity. Plans for this investigation involve a variety of methods of analysis. Hydraulic conductivity will be determined separately in the horizontal and vertical planes of the hydraulic-conductivity ellipsoid. Field values of dispersivity will be determined by single-well and doublet-well injection or withdrawal tests with tracers. A computerized data-collection, storage, and analysis system to measure pressure, flow rate, tracer concentrations, and temperature will be designed for field testing. Real-time computer programs will be used to analyze field data. The initial methods of analysis will be utilized to meet the objectives of the study. Preliminary field data indicate the aquifer underlying the Bemidji site is vertically heterogeneous, cross-bedded outwash. Preliminary analysis of the flow field around a hypothetical doublet-well tracer test indicates that the location of the wells can affect the field value of dispersivity. Preliminary analysis also indicates that different values of dispersivity may result from anisotropic conditions in tests in which observation wells are located at equal radial distances from either the injection or withdrawal well.

Water-Resources Investigations Report↗

Geohydrologic framework of the coastal plain aquifers of South Carolina

The U.S. Geological Survey is conducting a series of investigations of aquifers throughout the United States as a part of the RASA (Regional Aquifer System Analysis) program. These investigations provide a comprehensive regional understanding of groundwater resources throughout the Nation. The Coastal Plain aquifers in South Carolina are being studied as a part of this program. An important part of a description of the groundwater resources is the development of a geohydrologic framework. Such a framework delineates the aquifers through which groundwater flows and the confining units which retard the flow of groundwater between aquifers. The Coastal Plain of South Carolina is underlain by a wedge of sediments that thickens from its inner margin, the Fall Line, to the coast and consists of sand, silt, clay, and limestone of Late Cretaceous to Holocene age. These sediments are underlain by pre-Cretaceous rocks consisting of consolidated sedimentary rocks of Triassic age and a complex of metamorphic and igneous rocks similar to those found near the surface in the Piedmont province of the State. The geohydrologic framework that divides the sediments of the South Carolina Coastal Plain into the Coastal Plain aquifer system is delineated by eleven geohydrologic sections and four maps showing the configuration of the top or base of individual aquifers. Although flow within the Coastal Plain aquifer system is three dimensional, simplifying the system by dividing it into a framework of discrete hydrologic units can aid significantly in understanding the hydrology of the system. This framework is the basis for the aquifers used in potentiometric mapping, transmissivity mapping, geochemical analysis, and groundwater flow modeling for the South Carolina RASA program. (Lantz-PTT)

South Carolina↗

Water resources of southwestern Louisiana

In southwestern Louisiana large quantities of fresh water are available for agricultural, municipal, domestic, and industrial purposes. However, local and regional problems resulting from salt-water encroachment in the streams and persistent declines of the groundwater levels in certain areas during . drought periods have caused some concern regarding the future water supply of the region. · In order to appraise the situation, to provide hydrologic information basic to development of the area, and to provide a basis for sound plans for alleviating recurrent dry-year losses, a study of the ground-water resources of the area was begun in 1938 through cooperation with the Louisiana Geological Survey, Department of Conservation. An intensive investigation comprising ground-water, surface-water, and quality-of-water studies was authorized in 1948 in cooperation with the Louisiana Department of Public Works, and was completely under' way before the 1949 irrigation season. The studies were carried through the irrigation season of 1951.

Louisiana↗

Barkley Canyon gas hydrates: A synthesis based on two decades of seafloor observation and remote sensing

Barkley Canyon is one of the few known sites worldwide with the occurrence of thermogenic gas seepage and formation of structure-II and structure-H gas hydrate mounds on the seafloor. This site is the location of continuous seafloor monitoring as part of the Ocean Networks Canada (ONC) cabled observatory off the west coast off Vancouver Island, British Columbia, Canada. We combine repeat remotely operated vehicle (ROV) seafloor video observations, mapping with an autonomous underwater vehicle (AUV), ship-, ROV-, and AUV-based identification of gas flares, as well as seismic and Chirp data to investigate the distribution of fluid migration pathways. Geologically, the site with the prominent gas hydrate mounds and associated fluid seepage is covering an area of ∼0.15 km 2 and is situated on a remnant of a rotated fault block that had slipped off the steep flanks of the north-east facing canyon wall. The gas hydrate mounds, nearly constant in dimension over the entire observation period, are associated with gas and oil seepage and surrounded by debris of chemosynthetic communities and authigenic carbonate. The formation of gas hydrate at and near the seafloor requires additional accommodation space created by forming blisters at the seafloor that displace the regular sediments. An additional zone located centrally on the rotated fault block with more diffuse seepage (∼0.02 km 2 in extent) has been identified with no visible mounds, but with bacterial mats, small carbonate concretions, and clam beds. Gas venting is seen acoustically in the water column up to a depth of ∼300 m. However, acoustic water-column imaging during coring and ROV dives showed rising gas bubbles to much shallower depth, even <50 m, likely a result of degassing of rising oil droplets, which themselves cannot be seen acoustically. Combining all observations, the location of the gas hydrate mounds is controlled by a combination of fault-focused fluid migration from a deeper reservoir and fluid seepage along more permeable strata within the rotated slope block. Fluids must be provided continuously to allow the sustained presence of the gas hydrate mounds at the seafloor.

Barkley Canyon↗

Loss of coastal wetlands in Louisiana: Cooperative research to assess the critical processes

Erosion of the nation's shoreline and loss and deterioration of our coastal wetlands are widespread and serious problems that affect all regions of the US. As a result of natural and human-induced factors, the coastal plain of Louisiana, which contains 40% of the tidal wetlands in the conterminous 48 States, is undergoing the greatest amount of coastal erosion and wetlands loss in the nation. The barrier islands that provide a natural buffer for Louisiana's deltaic plain environments are experiencing erosion rates of 20m/yr, while wetlands losses are about 100km2/yr. In response to these problems and the lack of scientific understanding of the processes causing erosion and land loss, the US Geological Survey has, since 1986, conducted field investigations in Louisiana, working closely with the US Fish and Wildlife Service and other Federal and State agencies.

Biological Report - US Fish & Wildlife Service↗

Coastal plain pond water quality and mercury contend of biota of the Long Island Central Pine Barrens and Mashomack Preserve: Effects of atmospheric deposition and human development

Pine barrens are considered an imperiled ecosystem in the northeastern U.S. The Suffolk County Pine Barrens, once the second largest in the Northeast, were substantially reduced and fragmented by development during the 20th century. The coastal plain ponds being considered in this study occur in central Suffolk County within the Long Island Central Pine Barrens region. This highly unique natural environment, embedded with forests and woodlands, resulted from its glacial origins and a land use history that predates European colonization. Included in this study was The Nature Conservancy’s Mashomack Preserve, located on Shelter Island between Peconic Bay and Gardiner’s Bay. There are no freshwater ponds in the Mashomack Preserve, but this area was included with the Central Pine Barrens investigation, because Shelter Island has a similar geologic and land-use history that has resulted in a similarly unique low-nutrient forest and woodland ecosystem with extremely coarse-textured soils.

New York↗

Velocity mapping in the Lower Congo River: A first look at the unique bathymetry and hydrodynamics of Bulu Reach

The lower Congo River is one of the deepest, most powerful, and most biologically diverse stretches of river on Earth. The river&rsquo;s 270 m decent from Malebo Pool though the gorges of the Crystal Mountains to the Atlantic Ocean (498 km downstream) is riddled with rapids, cataracts, and deep pools. Much of the lower Congo is a mystery from a hydraulics perspective. However, this stretch of the river is a hotbed for biologists who are documenting evolution in action within the diverse, but isolated, fish populations. Biologists theorize that isolation of fish populations within the lower Congo is due to barriers presented by flow structure and bathymetry. To investigate this theory, scientists from the U.S. Geological Survey and American Museum of Natural History teamed up with an expedition crew from National Geographic in 2008 to map flow velocity and bathymetry within target reaches in the lower Congo River using acoustic Doppler current profilers (ADCPs) and echo sounders. Simultaneous biological and water quality sampling was also completed. This paper presents some preliminary results from this expedition, specifically with regard to the velocity structure andbathymetry. Results show that the flow in the bedrock controlled Bulu reach of the lower Congo is highly energetic. Turbulent and secondary flow structures can span the full depth of flow (up to 165 m), while coherent bank-to-bank cross-channel flow structures are absent. Regions of flow separation near the banks are isolated from one another and from the opposite bank by high shear, high velocity zones with depth-averaged flow velocities that can exceed 4 m/s.

Lower Congo River↗

Jordan aquifer of Iowa

Water demand for all uses in Iowa is increasing at an accelerated rate. Demand has increased from about 1,800 million gallons per day in 1955 to 3,500 million gallons per day in 1975 (MacKichan, 1957; Murray and Reeves, 1977). By the year 2020, water demand is expected to be eight times that in 1975 (Barnard and Dent, 1976). Historically, about 75 percent of the demand, excluding that required for power generation, has been met by withdrawals from the water-bearing zones (aquifers) in Iowa's ground-water reservoir. Because this percentage is expected to remain about the same, the anticipated future demands will require extensive withdrawals from the ground-water reservoir. The increasing stress on the ground-water system, which already is severely stressed in several places in the state, will create development and management problems that will require hydrologic information to solve. In order to provide this information, the lowa Geological Survey in cooperation with the U.S. Geological Survey has instituted a series of investigations to define, describe, and evaluate the major aquifers in Iowa's groundwater reservoir. Information from each investigation will be presented in atlas format.

Iowa↗