Preliminary report on methods of analysis for very small percentages of thorium, part 1
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A method is presented for the distillation and photometric estimation of the oil yield of oil-bearing shales. The oil shale is distilled in a closed test tube and the oil extracted with toluene. The optical density of the toluene extract is used in the estimation of oil content and is converted to percentage of oil by reference to a standard curve. This curve is obtained by relating the oil yields determined by the Fischer assay method to the optical density of the toluene extract of the oil evolved by the new procedure. The new method gives results similar to those obtained by the Fischer assay method in a much shorter time. The applicability of the new method to oil-bearing shale and phosphatic shale has been tested.
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The Fourmile area, Custer County, S. Dak., is in pre-Cambrian metamorphic rocks that surround the granitic core of the Black Hills. The area is on the upright limb of an overturned anticline that plunges about 30° S. 10° E. Three new formations of metamorphic rocks are described that have a total thickness of at least 7, 700 feet. The oldest of these formations, the Ruby Creek quartz-mica schist, is more than 6,500 feet thick. The overlying Raver formation, about 200 feet thick, is composed of thin beds of amphibolite and hornblende schist, lime-silicate rock, cordierite-biotite schist, microcline-biotite schist, and other types of rock. The youngest formation, the Ruddock quartz-mica-feldspar schist, is more than 1,000 feet thick. The presence of kyanite, staurolite, cordierite, and sillimanite in the rocks indicate that they have been subjected to high-grade metamorphism. About 420 pegmatites were mapped in the Ruby Creek quartz-mica--schist and the Ruddock quartz-mica-feldspar schist. A few thin pegmatites in the Raver formation were not mapped. Most of the pegmatites are concordant with the schistosity and relict (?) bedding of the enclosing metamorphic rocks. They are as much as 250 feet thick and range from 10 to 2,600 feet in length. Nine pegmatites are zoned and are classified as heterogeneous pegmatites. The remainder are homogeneous pegmatites that are poorly zoned. The major constituents of the pegmatites are plagioclase, quartz perthite, and muscovite. The accessory minerals are tourmaline, apatite, garnet, and biotite. Beryl was observed in 15 of the pegmatites. The heterogeneous pegmatites contain commercial deposits of potash feldspar, mica (sheet and scrap), and beryl.
The known uranium deposits of Grant county, N. Mex., are principally in the White Signal and Black Hawk districts. Both districts are within a northwesterly-trending belt of pre-Cambrian rocks, composed chiefly of granite with included gneisses, schists, and quartzites. Younger dikes and stocks intrude the pre-Cambrian complex. The White Signal district is on the southeast flanks of the Burro Mountains; the Black Hawk district is about 18 miles northwest of the town of White Signal. In the White Signal district the seconday uranium phosphates--autunite and torbernite--occur as fracture coatings and disseminations in oxidized parts of quartz-pyrite veins, and in the adjacent mafic dikes and granites; uraniferous limonite is common locally. Most of the known uraniferous deposits are less that 50 feet in their greatest dimension. The most promising deposits in the district are on the Merry Widow and Blue Jay claims. The richest sample taken from the Merry Widow mine contained more than 2 percent uranium and a sample from the Blue Jay property contained as much as 0.11 percent; samples from the other properties were of lower grade. In the Black Hawk district pitchblende is associated with nickel, silver, and cobalt minerals in fissure veins. The most promising properties in the Black Hawk district are the Black Hawk, Alhambra, and Rose mines. No uranium analyses from this district were available in 1951. There are no known minable reserves of uranium ore in either district, although there is some vein material at the Merry Widow mine of ore grade, if a market were available in the region.
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A regional study of the distribution of uranium, boron, tin, beryllium, niobium, lanthanum, lead, zirconium, lithium, and fluorine in 112 samples of Cenozoic volcanic rocks of predominately rhyolitic and dacitic composition has shown that the content of uranium has a significantly high positive correlation with that of niobium, beryllium, and fluorine, a lower but still significant positive correlation with lithium and tin, a significant negative correlation with boron and lanthanum, and no significant correlation with zirconium and lead. A study of the relation of content of the several elements to the geographic provenance shows significant variation with provenance for all these elements, except tin and lanthanum. On the basis of these variations and on patterns of consistency, five comagmatic provinces, one of which is divided into three sub-provinces, have been delimited, in part, on a map of the western United States. The patter of distribution of boron is significantly different from that of the other elements. The regional difference are perhaps best explained by structural control of the effectiveness of vertical transport.
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Field and laboratory studies of ground-water conditions in the carnotite-bearing Morrison formation in southwestern Colorado and southeastern Utah were undertaken to determine possible relations between ground waters and the carnotite deposits. The ore-bearing sandstone consists of lenticular sandstone strata, interbedded within discontinuous layers of mudstone; these strata were deposited in a stream environment. The porosity and permeability of the ore-bearing sandstone in one area are relatively low, porosity averaging about 15 percent and permeability ranging between 30 and 3300 millidarcys. Permeability studies in this same area show that sandstone classed as favorable for ore is slightly more permeable than and has nearly twice the transmissibility of sandstone classed as semifavorable; outcrop studies also suggest a lower transmissibility for sandstone that is unfavorable. Samples of water from the ore-bearing and associated strata show considerable variation in chemical charter. These water samples are generally low in uranium, vanadium, copper, and lead, most samples containing less than 1 part per million (ppm) of each metal. General geologic relations suggest that ground-water movement probably was active through the ore-bearing strata during their deposition and shortly afterward. Movement during this time probably occurred largely through the more permeable sand strata and in the general direction of initial dip and stream flow. During Cretaceous time, when several thousand feet of marine sediments accumulated over the Morrison, the water contained in the ore-bearing strata probably was immobile or nearly so and was protected from escape or contamination. Following Tertiary deformation and erosion, active ground-water circulation no doubt was restored, but because of the low permeability and the lenticular character and therefore low transmissibility of the ore-bearing sandstone, ground-water movement probably was slow. Faulting probably also influenced the direction and rate of ground-water movement during Tertiary time. Movement and localization of ground water would permit the concentration of metal-bearing solutions during Salt Wash and early Brushy Basin time in the beds that now contain ore deposits. It is more difficult to explain the formation of these deposits, which have a wide geographic distribution at a restricted stratigraphic position, from solutions circulating through the rocks at a later date. Whatever mode of origin is used to explain the deposits, geologists almost without exception, agree that the metals were transported by solutions that have migrated through the sediments for considerable distances. For this reason, a study of the horizontal and vertical transmissibility characteristics of all exposed sedimentary formations on the Colorado Plateau is planned.
The U.S. Geological Survey explored Outlaw Mesa for carnotite deposits from 1949 through 1951 with 1,302 diamond-drill holes that totaled 222,150 feet. Total production from Outlaw Mesa from 1914 through 1951 was about 30,000 short tons of carnotite ore, having an estimated grade of about 0.40 percent U3O8 and 1.7 percent V205. The known carnotite deposits are in a number of sandstone lenses in the upper part of the Salt Wash sandstone member of the Jurassic Morrison formation. The deposits are mainly impregnations of sandstone by carnotite and vanadium-bearing clay minerals. Commonly, the deposits are irregular tabular layers or pod-like or crescentic masses ("rolls") connected by thin layers of mineralized rock. The deposits and rolls have a dominant northeasterly trend. Useful criteria for recognizing-sandstone that might contain mineralized rock are: (1) thick, light-brown sandstone, (2) gray mudstone at the base of and in this sandstone, and (3) abundant carbonaceous material. The indicated and inferred reserves of carnotite-bearing material, and the pounds of contained U308 and V205 are summarized in table 1. Potential reserves, whose existence is based on geologic evidence alone, are estimated to total about 80,000 short tones, averaging about 0.35 percent U308 and 1.5percent V205. No further exploration by the Geological Survey is planned; however, additional drilling by private operators is recommended, particularly in ground underlain by mineralized rock.
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An area about 6 miles north of Sundance, in the Bear Lodge Mountains, in Crook County, Wyo., was examined during August 1950 for thorium, uranium, and rare-earth oxides and samples were collected. Uranium is known to occur in fluorite veins and iron-manganese veins and in the igneous rocks of Tertiary age that compose the core of the Bear Lodge Mountains. The uranium content of the samples ranges from 0.001 to 0.015 percent in those from the fluorite veins, from 0.005 to 0.018 percent in those from the iron-manganese veins, and from 0.001 to 0.017 percent in those from the igneous rocks. The radioactivity of the samples is more than that expected from the uranium content. Thorium accounts for most of this discrepancy. The thorium oxide content of samples ranges from 0.07 to 0.25 percent in those from the iron-manganese veins and from 0.07 to 0.39 percent in those from the sedimentary rocks, and from0.04 to 0.30 in those from the igneous rocks. Rare-earth oxides occur in iron-manganese veins and in zones of altered igneous rocks. The veins contain from 0.16 to 12.99 percent rare-earth oxides, and the igneous rocks, except for two localities, contain from 0.01 to 0.42 percent rare-earth oxides. Inclusions of metamorphosed sedimentary rocks in the intrusive rocks contain from 0.07 to 2.01 percent rare-earth oxides.