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USGS2014

Marsh soils as potential sinks for Bacteroides fecal indicator bacteria, Waccamaw National Wildlife Refuge, Georgetown, SC, USA

A soil core collected in a tidal freshwater marsh in the Waccamaw National Wildlife Refuge (Georgetown, SC) exuded a particularly strong odor of cow manure upon extrusion. In order to test for manure and determine its provenance, we carried out microbial source tracking using DNA markers for Bacteroides, a noncoliform, anaerobic bacterial group that represents a broad group of the fecal population. Three core sections from 0-3 cm, 9-12 cm and 30-33 were analyzed for the presence of Bacteroides. The ages of core sediments were estimated using 210Pb and 137Cs dating. All three core sections tested positive for Bacteroides DNA markers related to cow or deer feces. Because cow manure is stockpiled, used as fertilizer, and a source of direct contamination in the Great Pee Dee River/Winyah Bay watershed, it is very likely the source of the Bacteroides that was deposited on the marsh. The mid-points of the core sections were dated as follows: 0-3 cm: 2009; 9-12 cm: 1999, and 30-33 cm: 1961. The presence of Bacteroides at different depths/ages in the soil profile indicates that soils in tidal freshwater marshes are, at the least, capable of being short-term sinks for Bacteroides and, may have the potential to be long-term sinks of stable, naturalized populations.

South Carolina↗

USGS2011

Environmental policy analysis, peer reviewed: Reservoir sediment cores show US lead declines

As a result of the Clean Air Act, lead (Pb) emissions to the atmosphere have been greatly reduced since the mid-1970s. As part of its National Water Quality Assessment, the U.S. Geological Survey has been using paleolimnological techniques to assess past trends in hydrophobic contaminants. In urban-suburban environments, reservoir sediment cores show prominent peaks in Pb distributions that correlate well with the rise and fall of leaded gasoline. However, Pb concentrations in sediments are approximately double those of baseline values prior to the 1950s and 1960s. It is apparent that significant concentrations of anthropogenic Pb still exist in soils and aquatic sediments and that it will take many years to reduce these concentrations to prepollution values, even if there are no new sources of Pb pollution.

Environmental Science & Technology↗

USGS1996

Summary of biological and contaminant investigations related to stream water quality and environmental setting in the Upper Colorado River basin, 1938-95

As part of the U.S. Geological Survey's National Water-Quality Assessment (NAWQA) program, an inventory of the biological and contaminant investigations for the Upper Colorado River Basin study unit was conducted. To enhance the sampling design for the biological component of the program, previous studies about the ecology of aquatic organisms and contaminants were compiled from computerized literature searches of biological data bases and by contacting other Federal, State, and local agencies. Biological and contaminant investigations that have been conducted throughout the basin since 1938 were categorized according to four general categories of biological investigations and two categories of contaminant investigations: algal communities, macroinvertebrate communities, fish communities, habitat characterization, contaminants in organism tissue, and contaminants in bed sediment. The studies were identified by their locations in two physiographic provinces, the Southern Rocky Mountains and the Colorado Plateau, and by the predominant land use in the area of the investigation. Studies on algal communities and contaminants in organism tissue and in bed sediment are limited throughout the basin. Studies on macroinvertebrate and fish communities and habitat characterization are the most abundant in the study unit. Natural and human factors can affect biological communities and their composition. Natural factors that affect background water-quality conditions are physiography, climate, geology, and soils. Algae, macroinvertebrates, and fish that are present in the Southern Rocky Mountains and the Colorado Plateau physiographic provinces vary with altitude and physical environment. Green algae and diatoms are predominant in the higher altitude streams, and blue-green, golden-brown, and green algae are predominant in the lower altitude streams. Caddisflies, mayflies, and stoneflies are the dominant macroinvertebrates in the higher altitudes, whereas aquatic worms, leeches, and dragonflies are more common at lower altitudes. Cold-water species, such as trout, are present at the higher altitudes, and warmer water species, such as catfish, carp, and suckers, are predominant at the lower altitudes. Human factors that affect water-quality conditions are mining, urbanization, agriculture, and hydrologic modifications. Mining areas can be depleted of organisms or contain a low diversity of species. Acid-tolerant algae, such as certain species of green algae and diatoms, and metal-tolerant caddisflies can be present in mining areas. Urbanized areas are located in the Southern Rocky Mountains and in the Colorado Plateau and contain species characteristic of the physiographic provinces. Agricultural areas contain species, such as blue-green algae, aquatic worms, suckers, and carp, that can tolerate organic enrichment, sedimentation, and lower concentrations of dissolved oxygen.

Water-Resources Investigations Report↗

USGS2014

Mercury concentrations and distribution in soil, water, mine waste leachates, and air in and around mercury mines in the Big Bend region, Texas, USA

Samples of soil, water, mine waste leachates, soil gas, and air were collected from areas mined for mercury (Hg) and baseline sites in the Big Bend area, Texas, to evaluate potential Hg contamination in the region. Soil samples collected within 300 m of an inactive Hg mine contained elevated Hg concentrations (3.8–11 µg/g), which were considerably higher than Hg in soil collected from baseline sites (0.03–0.05 µg/g) distal (as much as 24 km) from mines. Only three soil samples collected within 300 m of the mine exceeded the probable effect concentration for Hg of 1.06 µg/g, above which harmful effects are likely to be observed in sediment-dwelling organisms. Concentrations of Hg in mine water runoff (7.9–14 ng/L) were generally higher than those found in springs and wells (0.05–3.1 ng/L), baseline streams (1.1–9.7 ng/L), and sources of drinking water (0.63–9.1 ng/L) collected in the Big Bend region. Concentrations of Hg in all water samples collected in this study were considerably below the 2,000 ng/L drinking water Hg guideline and the 770 ng/L guideline recommended by the U.S. Environmental Protection Agency (USEPA) to protect aquatic wildlife from chronic effects of Hg. Concentrations of Hg in water leachates obtained from leaching of mine wastes varied widely from <0.001 to 760 µg of Hg in leachate/g of sample leached, but only one leachate exceeded the USEPA Hg industrial soil screening level of 31 µg/g. Concentrations of Hg in soil gas collected at mined sites (690–82,000 ng/m 3 ) were highly elevated compared to soil gas collected from baseline sites (1.2–77 ng/m 3 ). However, air collected from mined areas at a height of 2 m above the ground surface contained concentrations of Hg (4.9–64 ng/m 3 ) that were considerably lower than Hg in soil gas from the mined areas. Although concentrations of Hg emitted from mine-contaminated soils and mine wastes were elevated, persistent wind in southwest Texas disperses Hg in the air within a few meters of the ground surface.

Texas↗

USGS1996

Reconnaissance investigation of water quality, bottom sediment, and biota associated with irrigation drainage in the Vermejo Project area and the Maxwell National Wildlife Refuge, Colfax County, northeastern New Mexico, 1993

Based on findings of limited studies during 1989-92, a reconnaissance investigation was conducted in 1993 to assess the effects of the Vermejo Irrigation Project on water quality in the area of the project, including the Maxwell National Wildlife Refuge. This project was part of a U.S. Department of the Interior National Irrigation Water-Quality Program to determine whether irrigation drainage has caused or has the potential to cause significant harmful effects on human health, fish, and wildlife and whether irrigation drainage may adversely affect the suitability of water for other beneficial uses. For this study, samples of water, sediment, and biota were collected from 16 sites in and around the Vermejo Irrigation Project prior to, during the latter part of, and after the 1993 irrigation season (April, August-September, and November, respectively). No inorganic constituents exceeded U.S. Environmental Protection Agency drinking-water standards. The State of New Mexico standard of 750 micrograms per liter for boron in irrigation water was exceeded at three sites (five samples), though none exceeded the livestock water standard of 5,000 micrograms per liter. Selenium concentrations exceeded the State of New Mexico chronic standard of 2 micrograms per liter for wildlife and fisheries water in at least eight samples from five sites. Bottom-sediment samples were collected and analyzed for trace elements and compared to concentrations of trace elements in soils of the Western United States. Concentrations of three trace elements at eight sites exceeded the upper values of the expected 95-percent ranges for Western U.S. soils. These included molybdenum at one site, selenium at seven sites, and uranium at four sites. Cadmium and copper concentrations exceeded the National Contaminant Biomonitoring Program 85th percentile in fish from six sites. Average concentrations of selenium in adult brine flies (33.7 μ g/g dry weight) were elevated above concentrations in other invertebrates. Concentrations of other elements were below their respective toxicity levels. Plants, invertebrates, fish, and fish fillets were collected and analyzed. These analyses were compared to diagnostic criteria and to each other to determine the extent of bioaccumulation of trace elements. Plants contained larger dry weight concentrations of aluminum, arsenic, boron, chromium, iron, lead, magnesium, manganese, nickel, and vanadium than invertebrates and fish. Adult brine flies, gathered from playas, contained larger geometric mean dry weight concentrations of boron, magnesium, and selenium than other invertebrates. Of all samples collected, the largest mercury concentrations were found in fish fillets, although these concentrations were below levels of concern. Mercury and selenium bioaccumulation was evident in various habitats of the study area. Biological samples from Natural playa, an endemic wetland, and Half playa, a playa that receives additional water through seepage and irrigation delivery canals, generally had elevated concentrations of boron, iron, magnesium, and selenium than samples from reservoir and river sites. Selenium concentrations were lowest in biota from the two reservoir sites, although a wetland immediately downstream from the dam impounding Lake No. 13 (created by seepage from the reservoir) had elevated concentrations of selenium in biota. The geometric mean selenium concentration of whole-fish samples, except those from Lakes No. 13 and No. 14, exceeded the 5- μ g/g dry weight selenium concentration that demarcates the approximate lower limit of the threshold range of concentrations that have freen associated with adverse effects on piscine reproduction. Biota collected on and in the area around Maxwell National Wildlife Refuge contained concentrations of selenium that are in the lower range of threshold values that have been associated (dietarily) with risks of avian reproductive abnormalities. Bottom-sediment samples from two sites downstream from the irrigation project were collected and analyzed for 23 organic compounds (principally organochlorine pesticide residues). Three compounds were detected at the two sites: DDD was found at 0.2 microgram per kilogram, DDE was detected at 0.1 microgram per kilogram at both sites, and chlordane was detected at 1 microgram per kilogram. None of the 28 whole-fish and fillet samples analyzed for PCB and organochlorine pesticide residues contained any of the 23 organic compounds tested for at concentrations higher than the analytical reporting limit (less than 0.01 μ g/g wet weight). Concentrations of inorganic analytes were generally within established guidelines or expected concentrations for water, sediment, and biota. lirigation-return flows were found to be unrelated to adverse effects in biota.

New Mexico↗

USGS2000

Chemical characteristics of urban stormwater sediments and implications for environmental management, Maricopa County, Arizona

Investigations of the chemical characteristics of urban stormwater sediments in the rapidly growing Phoenix metropolitan area of Maricopa County, Arizona, showed that the inorganic component of these sediments generally reflects geologic background values. Some concentrations of metals were above background values, especially cadmium, copper, lead, and zinc, indicating an anthropogenic contribution of these elements to the sediment chemistry. Concentrations, however, were not at levels that would require soil remediation according to guidelines of the U.S. Environmental Protection Agency. Arsenic concentrations generally were above recommended values for remediation at a few sites, but these concentrations seem to reflect geologic rather than anthropogenic factors. Several organochlorine compounds no longer in use were ubiquitous in the Phoenix area, although concentrations generally were low. Chlordane, DDT and its decay products DDE and DDD, dieldrin, toxaphene, and PCBs were found at almost all sites sampled, although some of the pesticides in which these compounds are found have been banned for almost 30 years. A few sites showed exceptionally high concentrations of organochlorine compounds. On the basis of published guidelines, urban stormwater sediments do not appear to constitute a major regional environmental problem with respect to the chemical characteristics investigated here. At individual sites, high concentrations of organic compounds - chlordane, dieldrin, PCBs, and toxaphene - may require some attention. The possible environmental hazard presented by low-level organochlorine contamination is not addressed in this paper; however, high levels of toxicity in urban sediments are difficult to explain. Sediment toxicity varied significantly with time, which indicates that these tests should be evaluated carefully before they are used for management decisions.Investigations of the chemical characteristics of urban stormwater sediments in the rapidly growing Phoenix metropolitan area of Maricopa County, Arizona, showed that the inorganic component of these sediments generally reflects geologic background values. Some concentrations of metals were above background values, especially cadmium, copper, lead, and zinc, indicating an anthropogenic contribution of these elements to the sediment chemistry. Concentrations, however, were not at levels that would require soil remediation according to guidelines of the U.S. Environmental Protection Agency. Arsenic concentrations generally were above recommended values for remediation at a few sites, but these concentrations seem to reflect geologic rather than anthropogenic factors. Several organochlorine compounds no longer in use were ubiquitous in the Phoenix area, although concentrations generally were low. Chlordane, DDT and its decay products DDE and DDD, dieldrin, toxaphene, and PCBs were found at almost all sites sampled, although some of the pesticides in which these compounds are found have been banned for almost 30 years. A few sites showed exceptionally high concentrations of organochlorine compounds. On the basis of published guidelines, urban stormwater sediments do not appear to constitute a major regional environmental problem with respect to the chemical characteristics investigated here. At individual sites, high concentrations of organic compounds - chlordane, dieldrin, PCBs, and toxaphene - may require some attention. The possible environmental hazard presented by low-level organochlorine contamination is not addressed in this paper; however, high levels of toxicity in urban sediments are difficult to explain. Sediment toxicity varied significantly with time, which indicates that these tests should be evaluated carefully before they are used for management decisions.

Environmental Management↗

USGS2026

Tissue metal concentrations and toxicity in wild turkeys following chronic exposure to mining-contaminated soils in southeast Missouri, USA

The Big River watershed in southeast Missouri (SEMO) is a Superfund site with an extensive history of lead (Pb) and zinc (Zn) mining; cadmium (Cd) and other metals also occur in the ore and waste materials. We examined whether SEMO wild turkeys ( Meleagris gallopavo ) exposed to mining-contaminated floodplain soils and food resources in the Big River watershed had elevated metal concentrations in their tissues, indicating Pb poisoning and associated toxic effects. Compared to reference birds ( n = 15) harvested in northern Missouri, SEMO turkeys ( n = 23) had significantly elevated Pb concentrations in ventricular content, liver, kidney, bone and contour feathers. Liver and kidney from SEMO turkeys also contained significantly elevated Cd concentrations compared to reference birds. Grit (2.8–5.6 mm) from turkeys ( n = 1 reference; n = 6 SEMO) was within the size range of coarse sediments reported to contain toxic metal concentrations, and 63% of turkeys harvested within 4 km of the Big River floodplain had tissue concentrations that exceeded avian thresholds for Pb poisoning. Tissue concentrations of Pb were significant predictors of keel hemorrhage as well as reductions in testis weight and bone Zn concentration. These sublethal endpoints suggest that chronic metal exposure in SEMO turkeys may be inducing toxic effects at lower tissue metal concentrations than would be estimated by current avian toxicity thresholds. These findings highlight the need for decision makers to consider how metal contamination may affect local turkey health and abundance, and the need for data-driven guidance for the safe consumption of wild foods harvested in SEMO and other mining-affected sites.

Missouri↗

USGS1988

Geohydrology and susceptibility of major aquifers to surface contamination in Alabama; area 13

The geohydrology and susceptibility to surface contamination of the major aquifers in Area 13--Baldwin and Mobile Counties Alabama--are described. Within this area are two major aquifers. The Pliocene-Miocene aquifer occurs throughout the study area. The Alluvial-Coastal aquifer is found near the major rivers and coastal areas and overlies the Pliocene-Miocene aquifer. There is no continuous confining unit between these two aquifers, thus , they are hydraulically connected and act as a single hydrologic unit. The entire study area is susceptible to surface contamination. The sediments are highly permeable, which allows rapid infiltration of water. Areas around some of the large pumping centers are highly susceptible to contamination, not only because of permeable sediments and flat terrain, but also because of depressions created in the potentiometric surface by large withdrawals of water from the aquifers. These depressions act as funnels to direct groundwater flow toward pumping centers; this increases the possibility of a contaminant migrating into the groundwater system. Other areas of high susceptibility are regions characterized by flat terrain and highly permeable soils, which increase the rate of infiltration from the surface. (USGS)

Water-Resources Investigations Report↗

USGS2012

Hydrogeology, water chemistry, and transport processes in the zone of contribution of a public-supply well in Albuquerque, New Mexico, 2007-9

The National Water-Quality Assessment Program (NAWQA) of the U.S. Geological Survey began a series of groundwater studies in 2001 in representative aquifers across the Nation in order to increase understanding of the factors that affect transport of anthropogenic and natural contaminants (TANC) to public-supply wells. One of 10 regional-scale TANC studies was conducted in the Middle Rio Grande Basin (MRGB) in New Mexico, where a more detailed local-scale study subsequently investigated the hydrogeology, water chemistry, and factors affecting the transport of contaminants in the zone of contribution of one 363-meter (m) deep public-supply well in Albuquerque. During 2007 through 2009, samples were collected for the local-scale study from 22 monitoring wells and 3 public-supply (supply) wells for analysis of major and trace elements, arsenic speciation, nutrients, dissolved organic carbon, volatile organic compounds (VOCs), dissolved gases, stable isotopes, and tracers of young and old water. To study groundwater chemistry and ages at various depths within the aquifer, the monitoring wells were divided into three categories: (1) each shallow well was screened across the water table or had a screen midpoint within 18.3 m of the water level in the well; (2) each intermediate well had a screen midpoint between about 27.1 and 79.6 m below the water level in the well; and (3) each deep well had a screen midpoint about 185 m or more below the water level in the well. The 24-square-kilometer study area surrounding the "studied supply well" (SSW), one of the three supply wells, consists of primarily urban land within the MRGB, a deep alluvial basin with an aquifer composed of unconsolidated to moderately consolidated deposits of sand, gravel, silt, and clay. Conditions generally are unconfined, but are semiconfined at depth. Groundwater withdrawals for public supply have substantially changed the primary direction of flow from northeast to southwest under predevelopment conditions, to west to east under modern conditions. Analysis of age tracers indicates that groundwater from most sampled wells is dominated by old (pre-1950) water, ranging in mean age from about 4,000 years to more than 22,000 years, but includes a fraction of young (post-1950) recharge. Patterns in chemical and isotopic data are consistent with the conclusions that shallow groundwater in the area typically includes a fraction that evaporated prior to recharge and (or) flushed accumulated solutes out of the unsaturated zone during recharge, and that shallow groundwater has mixed to deeper parts of the aquifer, which receives recharge mainly by seepage from the Rio Grande. Among shallow and intermediate wells that produced water with a fraction of young recharge, that fraction ranged between 1.5 and 46 percent. Samples from the two deep wells had groundwater ages exceeding 18,000 years, with no fraction of young recharge. Two supply wells (including the SSW) had a fraction of young recharge, which ranged between about 3 and 11 percent, despite mean groundwater ages exceeding 10,000 years. The fraction of young recharge to the SSW varied seasonally, probably because seasonal pumping patterns affected local hydraulic gradients and (or) because of flow through the well bore when the SSW is not pumping. Well-bore flow data collected during winter (low-pumping season) indicated that about 61 percent of the water pumped from the SSW entered the well from the intermediate part of the aquifer, and that the remaining 39 percent entered from the deep part of the aquifer. Volatile organic compounds (VOCs) were detected in samples from most shallow and intermediate monitoring wells and from two of three supply wells, including the SSW. Detected VOCs were primarily chlorinated solvents or their degradation products. Many of the wells in which most of these VOCs were detected are located near known sites of solvent contamination that were targeted for sampling because trichloroethylene (TCE) and cis-1,2-dichloroethylene had been detected in the SSW, and several of these wells may have become contaminated at least partly because of enhanced vertical migration associated with the pumping of and (or) direct migration down deep well bores. Except for TCE in the sample from a shallow monitoring well, all detections of VOCs were at concentrations below Maximum Contaminant Levels (MCLs) set by the U.S. Environmental Protection Agency. Concentrations of all VOCs detected in the supply wells were less than one-tenth of the corresponding MCLs. However, the presence of VOCs in all but deep groundwater, including the detection of chloroform (a chlorination byproduct) in several shallow wells, indicates that groundwater in the study area commonly is affected by human activities, even to substantial depths. The only natural contaminant detected at concentrations near or above its MCL was arsenic, which has been detected at elevated concentrations across broad areas of the MRGB. Concentrations of arsenic, present primarily as arsenate, exceeded the MCL of 10 micrograms per liter (μg/L) in water from the two deep wells (one of which had the highest concentration, 35 μg/L), from one intermediate well, and from two supply wells, including the SSW. Water-quality and solid-phase data from this study are consistent with elevated arsenic concentrations in groundwater being related to pH-dependent desorption of arsenic from ferric oxyhydroxides in sediments in deep parts of the aquifer. Concentrations of nitrate ranged between 1.3 and 5.4 milligrams per liter (mg/L) in water from shallow wells screened across the water table, but were less than 0.9 mg/L in water from all but one deeper well. Nitrogen isotopes and chloride/bromide ratios for shallow wells were consistent with natural soil nitrogen. Nitrate concentrations and nitrogen isotopes indicated that denitrification is occurring at intermediate aquifer depths, and that the progress of the denitrification reaction typically is greatest for wells that include a fraction of groundwater associated with particular recharge sources or with known sites of contamination contributing organic compounds that can provide a carbon source for microbial respiration. Overall, hydrologic and chemical data from the study area indicate that young recharge is reaching the aquifer across broad areas and is migrating from shallow to intermediate depths of the aquifer as a result of mixing that is associated with human development of groundwater. Consequently, groundwater that human activities in the urban study area have affected is present at depths that are within the screened intervals of public-supply wells, resulting in detections of VOCs and implying greater vulnerability to anthropogenic contamination than might be assumed based on the dominantly old age of the regional groundwater. However, the fractions of old groundwater that public-supply wells produce substantially dilute the anthropogenic contaminants, while contributing natural contaminants (primarily arsenic) to the wells. Based on data from the SSW, vulnerability of public-supply wells to natural and anthropogenic contaminants in the area changes through time, including with seasonal changes in pumping stresses that alter the fractions of young and old water being contributed to wells.

New Mexico↗

USGS1999

Ground-water levels and flow directions in the glacial sediments and the Lockport Dolomite in southeastern Darke and northeastern Preble counties, Ohio, July 1998

During the summer of 1997, the U.S. Environmental Protection Agency (USEPA) began an emergency removal action at the Lewisburg Drum Site in northern Preble County, Ohio. The site is about 3 miles west-northwest of the village of Lewisburg. The USEPA removed about 1,200 drums of waste ink from the site, as well as 2,500 cubic yards of contaminated soil and 100,000 gallons of ground water. Because of the potential for off-site migration of ground-water contamination, USEPA sampled residential wells in the area; results from the samples collected by USEPA indicated that the quality of water in some privately owned wells may have been affected by contaminants from the site. However, the directions of ground-water flow in the area were not known. In 1998, the U.S. Geological Survey (USGS), in cooperation with the USEPA, measure water levels in the vicinity of the site. This map will aid in the interpretation of the water-quality data collected by USEPA.

Ohio↗

USGS2006

Arsenic speciation in arsenic-rich Brazilian soils from gold mining sites under anaerobic incubation

Background. Arsenic speciation in environmental samples is essential for studying toxicity, mobility and bio-transformation of As in aquatic and terrestrial environments. Although the inorganic species As(III) and As(V) have been considered dominant in soils and sediments, organisms are able to metabolize inorganic forms of arsenic into organo-arsenic compounds. Arsenosugars and methylated As compounds can be found in terrestrial organisms, but they generally occur only as minor constituents. We investigated the dynamics of arsenic species under anaerobic conditions in soils surrounding gold mining areas from Minas Gerais State, Brazil to elucidate the arsenic biogeochemical cycle and water contamination mechanisms. Methods. Surface soil samples were collected at those sites, namely Paracatu Formation, Banded Iron Formation and Riacho dos Machados Sequence, and incubated in CaCl2 2.5 mmol L-1 suspensions under anaerobic conditions for 1, 28, 56 and 112 days. After that, suspensions were centrifuged and supernatants analyzed for soluble As species by IC-ICPMS and HPLC-ICPMS. Results. Easily exchangeable As was mainly arsenite, except when reducible manganese was present. Arsenate was mainly responsible for the increase in soluble arsenic due to the reductive dissolution of either iron or manganese in samples from the Paracatu Formation and Riacho dos Machados Sequence. On the other hand, organic species of As dominated in samples from the Banded Iron Formation during anaerobic incubation. Discussion. Results are contrary to the expectation that, in anaerobic environments, As release due to the reductive dissolution of Fe is followed by As(V) reduction to As(III). The occurrence of organo-arsenic species was also found to be significant to the dynamics of soluble arsenic, mainly in soils from the Banded Iron Formation (BIF), under our experimental conditions. Conclusions. In general, As(V) and organic As were the dominant species in solution, which is surprising under anaerobic conditions in terrestrial environments. The unexpected occurrence of organic species of As was attributed to enrollment of ternary organic complexes or living organisms such as algae or cyanobacteria. Perspectives. These findings are believed to be useful for remediation strategies in mine-affected regions, as the organic As species are in general considered to be less toxic than inorganic ones and even As(V) is considered less mobile and toxic than As(III). ?? 2007 ecomed publishers (Verlagsgruppe Hu??thig Jehle Rehm GmbH).

Environmental Science and Pollution Research↗

USGS2006

The U.S. Geological Survey and City of Atlanta water-quality and water-quantity monitoring network

Population growth and urbanization affect the landscape, and the quality and quantity of water in nearby rivers and streams, as well as downstream receiving waters (Ellis, 1999). Typical impacts include: (1) disruption of the hydrologic cycle through increases in the extent of impervious surfaces (e.g., roads, roofs, sidewalks) that increase the velocity and volume of surface-water runoff; (2) increased chemical loads to local and downstream receiving waters from industrial sources, nonpoint-source runoff, leaking sewer systems, and sewer overflows; (3) direct or indirect soil contamination from industrial sources, power-generating facilities, and landfills; and (4) reduction in the quantity and quality of aquatic habitats. The City of Atlanta's monitoring network consists of 21 long-term sites. Eleven of these are 'fully instrumented' to provide real-time data on water temperature, pH, specific conductance, dissolved oxygen, turbidity (intended as a surrogate for suspended sediment concentration), water level (gage height, intended as a surrogate for discharge), and precipitation. Data are transmitted hourly and are available on a public Web site (http://ga.water.usgs.gov/). Two sites only measure water level and rainfall as an aid to stormwater monitoring. The eight remaining sites are used to assess water quality.

Georgia↗

USGS2020

Environmental contamination and unusual snake mortality in an urban national wildlife refuge

The National Wildlife Refuge (NWR) System protects ~150 million acres of land and water in the United States and provides habitat for >2,000 native vertebrates species. Although legally protected, wildlife populations within these refuges can be threatened by anthropogenic activities. The lack of knowledge about such threats has the potential to undermine biodiversity conservation. We investigated patterns of wildlife mortality among three NWRs in the northern U.S. Gulf Coast. Visual surveys (958 total search-hours) were conducted for live or dead amphibians and reptiles at Big Branch, Bogue Chitto, and Bayou Sauvage NWRs. An exceptionally high incidence of snake mortality (>800% above background, P < 0.001) was observed at one site (Haul Road, Bayou Sauvage NWR). Mortality affected seven species and recurred for 29 months. Intact carcasses were subject to histopathological examination and diagnostic testing. Cause of death was undetermined (n = 9) or attributed to various pathogens (n = 5). To investigate possible underlying causes of this unusual mortality, water exposure challenges and soil toxicological analyses (n = 6 and 11 sites, respectively) were conducted on samples from Bayou Sauvage NWR, given the known potential for anthropogenic contamination in the refuge. In a controlled experiment, survival of Anaxyrus fowlerii embryos exposed to water from Recovery Road (i.e., 250m from a landfill) and Haul Road was reduced 92% and 48%, respectively, compared to four reference sites in the refuge. Sediment analyses suggested at least seven distinct sources of contaminants in Bayou Sauvage NWR. Potential sources included a landfill, illegal dumping, vehicle emissions, pesticide migration, and an active hydrocarbon pipeline leak discovered 600 m from Haul Road. Synthesis and applications: Although further research is needed to determine whether the observed mortality and contamination are related, these collective findings suggest that anthropogenic factors may threaten the ecological integrity of one of the United States largest urban wildlife refuges. More broadly, our study highlights the critical need for species inventories, baseline data, and systematic monitoring in NWRs. Such information is essential to detecting and mitigating anthropogenic threats to biodiversity conservation in protected areas.

Louisiana↗

USGS2008

Environmental presence and persistence of pharmaceuticals: An overview

Emerging contaminants (ECs) in the environment – that is, chemicals with domestic, municipal, industrial, or agricultural sources that are not commonly monitored but may have the potential for adverse environmental effects – is a rapidly growing field of research. The use of “emerging” is not intended to infer that the presence of these compounds in the environment is new. These chemicals have been released into the environment as long as they have been in production or, in the case of hormones and other endogenous compounds, since the rise of animal life. What is emerging is the interest by the scientific and lay communities in the presence of these chemicals in the environment, the analytical capabilities required for detection, and the subtle effects that very small concentrations of these chemicals appear to have on aquatic biota. In December 2006, Environmental Science & Technology devoted an entire special issue (volume 40, number 23) to the topic of ECs, illustrating the increased interest in the subject. Within the EGs, one particular class that has seen a substantial increase in research over the past 10 years is pharmaceuticals and personal-care products (PPCPs). This increased research interest can be demonstrated by several means, including requests for proposals from funding agencies, but the clearest indication of a focused effort to understand the introduction, transformation, and potential health and environmental effects of PPCPs and ECs, in general, is the number of published reports. This increase can be shown by examining six environmental journals that regularly publish PPCP-related papers – Chemosphere , Environmental Science & Technology , Environmental Toxicology and Chemistry , Science of the Total Environment , Water Research , and Water Science and Technology . In 1998 there were 22 papers published on pharmaceuticals, antibiotics, or drugs in these 6 journals; by 2006, this number increased sixfold to 132 papers (Figure 1.1). This growth can be attributed to a number of factors. The presence of pharmaceuticals in surface-water samples from Europe and the United States was documented in several sentinel papers. These ground-breaking works encouraged other scientists to examine the rivers, streams, lakes, and reservoirs in their regions for such chemicals. In addition, the intense public attention paid to news reports on the environmental detections of these chemicals and possible effects of aquatic life has made this issue visible to the wastewater-treatment, drinking-water treatment, and regulatory communities. This has driven the funding bodies associated with these communities to fund studies or request proposals that address the presence, fate, and effects of PPCPs in aquatic systems. The release of the first comprehensive reconnaissance of pharmaceuticals and other wastewater contaminants in the United States provides an example of the intense media interest in this topic. Within 6 days on online publication of this study, 72 newspapers across the United States had published articles describing the results, either locally written or based on international media syndicate reports. There also was substantial concurrent coverage by local and national radio and television outlets, including the Cable News Network, ABC World News Tonight , and National Public Radio. A substantial fraction of these news stories may be attributable to press releases and media briefings prior to publication. However, the interest by television and print journalists in reporting the results of a peer-reviewed journal article to the general public was motivated by the recognition that describing the presence of PPCPs in water supplies would be of interest to the public. To better convey the results of the study published by Koplin et al. to the public, a separate general-interest fact sheet was published to summarize the important points of the study. Because PPCPs are commonly and widely used by individuals, there is likely a preexisting, personal identification with these compounds that does not occur for the wide range of other organic and inorganic contaminants whose presence in the environment has previously been described. This greater public “name recognition” makes itself known through the media to the regulatory and technical community and has prompted interest in sponsoring research that defines the composition and concentrations of PPCPs in potential sources and their fate and effects following relase into the environment. Independent of the drivers that potentially fuel the interest in studies of PPCPs, it is clear that PPCP research has grown beyond surface-water studies to examine issues such as: • Presence in other matrices, such as groundwater, landfill leachates, sediments, and biosolids. • Environmental transport and fate in surface water, groundwater, and soils amended with reclaimed water or biosolids. • PPCP source elucidation, such as wastewater treatment plant (WWTP) effluents, confined animal feeding operations (CAFOs), and aquaculture. • Removal during wastewater and drinking-water treatment. • Effects on aquatic ecosystems, terrestrial ecosystems, and human health. The chapters in this book provide an extensive examination of current environmental pharmaceutical research and are divided into three sections: “Occurrence and Analysis of Pharmaceuticals in the Environment,” “Environment Fate and Transformations of Veterinary Pharmaceuticals,” and “treatment of Pharmaceuticals in Drinking Water and Wastewater.” The purpose of this introductory overview chapter is to outline current (2004-2006) knowledge about the presence and concentration of PPCPs as described in the published literature. Previous reviews should be consulted for discussions on pre-2004 publications. Those reviews will provide the reader with a comprehensive introduction to the topic of PPCPs in the environment. This chapter describes the sources of PPCPs and other organic contaminants often associated with human wastewater into the environment, the range of concentrations present in various environmental compartments, and the potential routes of removal/sequestration. An overview of the sources and fate of veterinary pharmaceuticals will be discussed in Chapter 5, “Fate and Transport of Veterinary Medicines in the Soil Environment.”

Book chapter↗

USGS2009

Heavy metal distribution in soils near Palapye, Botswana: An evaluation of the environmental impact of coal mining and combustion on soils in a semi-arid region

Morupule Colliery near Palapye in eastern Botswana is the only coalmine in production in Botswana at present. Its coal is mainly used in the nearby coal-fired Morupule Power Station, which generates approximately 1,000 GWh of electricity per annum. After more than 30 years mining and more than 20 years of combustion, the sedimentation of outlet fly ash from the Morupule Power Station has increased concentrations of Cr, Ni, Zn and As by 13, 2.5, 16 and 5 ppm, respectively, in the fine portion (<53 ??m) of surface soils for approximately 9 km downwind. Elements that have higher concentrations in coal have stronger small-particle association during coal combustion and are less mobile in surface soils, thus showing stronger contaminations in surface soils around the coal-fired plant. Although the degree of contamination of Cr, Ni, Zn and As from coal combustion in the Palapye area at present is low, it is necessary to monitor concentrations of these elements in surface soils routinely in the future. This study also reveals moderate Pb and Zn contaminations in the Palapye area. The former is due to the use of leaded petroleum in motor vehicle traffic and the latter is mainly due to the use of galvanized iron sheets in construction. ?? 2009 Springer Science+Business Media B.V.

Environmental Geochemistry and Health↗

USGS2011

Assessment of soil-gas and soil contamination at the Old Metal Workshop Hog Farm Area, Fort Gordon, Georgia, 2009-2010

Soil gas and soil were assessed for contaminants at the Old Metal Workshop Hog Farm Area at Fort Gordon, Georgia, from October 2009 to September 2010. The assessment included delineating organic contaminants present in soil-gas and inorganic contaminants present in soil samples collected from the area estimated to be the Old Metal Workshop Hog Farm Area. This assessment was conducted to provide environmental contamination data to Fort Gordon personnel pursuant to requirements for the Resource Conservation and Recovery Act Part B Hazardous Waste Permit process. All soil-gas samplers contained total petroleum hydrocarbons above the method detection level. The highest total petroleum hydrocarbon mass detected was 121.32 micrograms in a soil-gas sampler from the western corner of the Old Metal Workshop Hog Farm Area along Sawmill Road. The highest undecane mass detected was 73.28 micrograms at the same location as the highest total petroleum hydrocarbon mass. Some soil-gas samplers detected toluene mass greater than the method detection level of 0.02 microgram; the highest detection of toluene mass was 0.07 microgram. Some soil-gas samplers were installed in areas of high-contaminant mass to assess for explosives and chemical agents. Explosives or chemical agents were not detected above their respective method detection levels for all soil-gas samplers installed. Inorganic concentrations in five soil samples collected did not exceed regional screening levels established by the U.S. Environmental Protection Agency. Barium concentrations, however, were up to eight times higher than the background concentrations reported in similar Coastal Plain sediments of South Carolina.

Open-File Report↗

USGS1996

Geohydrology of the shallow aquifers in the Denver metropolitan area, Colorado

The Denver metropolitan area is underlain by shallow layers of water-bearing sediments (aquifers) consisting of unconsolidated gravel, sand, silt, and clay. The depth to water in these aquifers is less than 20 feet in much of the area, and the aquifers provide a ready source of water to numerous shallow, small-capacity wells. The shallow depth to water also makes the aquifers susceptible to contamination from the land surface. Water percolating downward from residential, commercial, and industrial property, spills of hazardous materials, and leaks from underground storage tanks and pipelines can cause contaminants to enter the shallow aquifers. Wet basements, unstable foundation materials, and waterlogged soils also are common in areas of very shallow ground water. Knowledge of the extent, thickness, and water-table altitude of the shallow aquifers is incomplete. This, coupled with the complexity of development in this large metropolitan area, makes effective use, management, and protection of these aquifers extremely difficult. Mapping of the geologic and hydrologic characteristics of these aquifers would provide the general public and technical users with information needed to better use, manage, and protect this water resource. A study to map the geohydrology of shallow aquifers in the Denver metropolitan area was begun in 1994. The work was undertaken by the U.S. Geological Survey in cooperation with the U.S. Army-Rocky Mountain Arsenal, U.S. Department of Energy-Rocky Flats Field Office, Colorado Department of Public Health and Environment, Colorado Department of Natural Resources-State Engineers Office, Denver Water Department, Littleton-Englewood Wastewater Treatment Plant, East Cherry Creek Valley Water and Sanitation District, Metro Wastewater Reclamation District, Willows Water District, and the cities of Aurora, Lakewood, and Thornton. This report presents the results of a systematic mapping of the extent, thickness, and water-table altitude of the shallow aquifers in a 700-square-mile part of the greater Denver metropolitan area (fig. 1). The five sheets in this report (figs. 2-7) show (1) the thickness and extent of the unconsolidated sediments that overlie bedrock formations in the area, (2) the altitude and configuration of the buried bedrock surface, (3) the altitude of the water table and direction of ground-water movement, (4) the saturated thickness of the shallow aquifers, and (5) the depth to the water table in the shallow aquifers. The maps primarily are intended to indicate the general trends in altitude and thickness of the aquifers and are not intended to define conditions at specific sites.

Hydrologic Atlas↗

USGS1994

Estimates of soil ingestion by wildlife

Many wildlife species ingest soil while feeding, but ingestion rates are known for only a few species. Knowing ingestion rates may be important for studies of environmental contaminants. Wildlife may ingest soil deliberately, or incidentally, when they ingest soil-laden forage or animals that contain soil. We fed white-footed mice ( Peromyscus leucopus ) diets containing 0-15% soil to relate the dietary soil content to the acid-insoluble ash content of scat collected from the mice. The relation was described by an equation that required estimates of the percent acid-insoluble ash content of the diet, digestibility of the diet, and mineral content of soil. We collected scat from 28 wildlife species by capturing animals, searching appropriate habitats for scat, or removing material from the intestines of animals collected for other purposes. We measured the acid-insoluble ash content of the scat and estimated the soil content of the diets by using the soil-ingestion equation. Soil ingestion estimates should be considered only approximate because they depend on estimated rather than measured digestibility values and because animals collected from local populations at one time of the year may not represent the species as a whole. Sandpipers ( Calidris spp.), which probe or peck for invertebrates in mud or shallow water, consumed sediments at a rate of 7-30% of their diets. Nine-banded armadillo ( Dasypus novemcinctus , soil = 17% of diet), American woodcock ( Scolopax minor , 10%), and raccoon ( Procyon lotor , 9%) had high rates of soil ingestion, presumably because they ate soil organisms. Bison ( Bison bison , 7%), black-tailed prairie dog ( Cynomys ludovicianus , 8%), and Canada geese ( Branta canadensis , 8%) consumed soil at the highest rates among the herbivores studied, and various browsers studied consumed little soil. Box turtle ( Terrapene carolina , 4%), opossum ( Didelphis virginiana , 5%), red fox ( Vulpes vulpes , 3%), and wild turkey ( Meleagris gallopavo , 9%) consumed soil at intermediate rates. Ingested soil may be the principal means of exposure to some environmental contaminants or the principal source of certain minerals. Soil-ingestion estimates may be required for risk assessments of wildlife inhabiting contaminated sites and for computing budgets of those nutrients associated mainly with soil.

Colorado, Kansas, Louisiana, Maine, Maryland, Minn↗