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USGS2008

Relative age of interior layered deposits in southwest Candor Chasma based on high-resolution structural mapping

High‐resolution topography generated from stereo HiRISE (High‐Resolution Imaging Science Experiment) imagery reveals the meter‐scale structure of interior layered deposits (ILD) in southwest Candor Chasma. This study seeks to determine the age of the local ILD relative to any normal faults that can be attributed to chasma formation. The study area is located near the contact of these ILD and the wall rock and is in an area where chasma‐forming normal faults have been proposed. We find that while normal faults are found in the study area, these faults are not sufficiently large nor appropriately located or oriented to accommodate the roughly northeast‐southwest extension that is required for normal faults that can be attributed to chasma formation. Additionally, bedding exposed in the local ILD generally dips toward the center of Candor Chasma, consistent with sediment deposition in a preexisting basin. Further, pit craters of Tithonia Catena, presumed to predate or be contemporaneous with the formation of west Candor Chasma, do not cut into the ILD within the study area. These independent lines of evidence support a postchasma age for the ILD exposed within the study area. Chasma‐related normal faults may exist within these ILD at depth but are not exposed at the surface. Approximately 2 km of conformable stratigraphy is exposed in the study area, and therefore at least several kilometers of the local ILD were deposited subsequent to any chasma‐related normal faulting that may have occurred in this part of Candor Chasma.

Journal of Geophysical Research E: Planets↗
USGS2008

Spirit Mars Rover Mission to the Columbia Hills, Gusev Crater: Mission overview and selected results from the Cumberland Ridge to Home Plate

This paper summarizes the Spirit rover operations in the Columbia Hills of Gusev Crater from sols 513 to 1476 and provides an overview of selected findings that focus on synergistic use of the Athena Payload and comparisons to orbital data. Results include discovery of outcrops (Voltaire) on Husband Hill that are interpreted to be altered impact melt deposits that incorporated local materials during emplacement. Evidence for extensive volcanic activity and aqueous alteration in the Inner Basin is also detailed, including discovery and characterization of accretionary lapilli and formation of sulfate, silica, and hematite‐rich deposits. Use of Spirit's data to understand the range of spectral signatures observed over the Columbia Hills by the Mars Reconnaissance Orbiter's Compact Reconnaissance Imaging Spectrometer (CRISM) hyperspectral imager (0.4–4 μ m) is summarized. We show that CRISM spectra are controlled by the proportion of ferric‐rich dust to ferrous‐bearing igneous minerals exposed in ripples and other wind‐blown deposits. The evidence for aqueous alteration derived from Spirit's data is associated with outcrops that are too small to be detected from orbital observations or with materials exposed from the shallow subsurface during rover activities. Although orbital observations show many other locations on Mars with evidence for minerals formed or altered in an aqueous environment, Spirit's data imply that the older crust of Mars has been altered even more extensively than evident from orbital data. This result greatly increases the potential that the surface or shallow subsurface was once a habitable regime.

Journal of Geophysical Research E: Planets↗
USGS2009

Thorium abundances on the Aristarchus plateau: Insights into the composition of the Aristarchus pyroclastic glass deposits

Thorium (Th) data from the Lunar Prospector gamma ray spectrometer (LP‐GRS) are used to constrain the composition of lunar pyroclastic glass deposits on top of the Aristarchus plateau. Our goal is to use forward modeling of LP‐GRS Th data to measure the Th abundances on the plateau and then to determine if the elevated Th abundances on the plateau are associated with the pyroclastic deposits or with thorium‐rich ejecta from Aristarchus crater. We use a variety of remote sensing data to show that there is a large, homogenous portion of the pyroclastics on the plateau that has seen little or no contamination from the Th‐rich ejecta of Aristarchus crater. Our results show that the uncontaminated pyroclastic glasses on Aristarchus plateau have an average Th content of 6.7 ppm and ∼7 wt % TiO 2 . These Th and Ti values are consistent with Th‐rich, intermediate‐Ti yellow glasses from the lunar sample suite. On the basis of this information, we use petrologic equations and interelement correlations for the Moon to estimate the composition of the source region from which the Aristarchus glasses were derived. We find that the source region for the Aristarchus glasses contained high abundances of heat‐producing elements, which most likely served as a thermal driver for the prolonged volcanic activity in this region of the Moon.

Journal of Geophysical Research E: Planets↗
USGS2009

Constraints on deep moonquake focal mechanisms through analyses of tidal stress

[1] A relationship between deep moonquake occurrence and tidal forcing is suggested by the monthly periodicities observed in the occurrence times of events recorded by the Apollo Passive Seismic Experiment. In addition, the typically large S wave to P wave arrival amplitude ratios observed on deep moonquake seismograms are indicative of shear failure. Tidal stress, induced in the lunar interior by the gravitational influence of the Earth, may influence moonquake activity. We investigate the relationship between tidal stress and deep moonquake occurrence by searching for a linear combination of the normal and shear components of tidal stress that best approximates a constant value when evaluated at the times of moonquakes from 39 different moonquake clusters. We perform a grid search at each cluster location, computing the stresses resolved onto a suite of possible failure planes, to obtain the best fitting fault orientation at each location. We find that while linear combinations of stresses (and in some cases stress rates) can fit moonquake occurrence at many clusters quite well; for other clusters, the fit is not strongly dependent on plane orientation. This suggests that deep moonquakes may occur in response to factors other than, or in addition to, tidal stress. Several of our inferences support the hypothesis that deep moonquakes might be related to transformational faulting, in which shear failure is induced by mineral phase changes at depth. The occurrence of this process would have important implications for the lunar interior. Copyright 2009 by the American Geophysical Union.

Journal of Geophysical Research E: Planets↗
USGS2009

Moon meteoritic seismic hum: Steady state prediction

We use three different statistical models describing the frequency of meteoroid impacts on Earth to estimate the seismic background noise due to impacts on the lunar surface. Because of diffraction, seismic events on the Moon are typically characterized by long codas, lasting 1 h or more. We find that the small but frequent impacts generate seismic signals whose codas overlap in time, resulting in a permanent seismic noise that we term the "lunar hum" by analogy with the Earth's continuous seismic background seismic hum. We find that the Apollo era impact detection rates and amplitudes are well explained by a model that parameterizes (1) the net seismic impulse due to the impactor and resulting ejecta and (2) the effects of diffraction and attenuation. The formulation permits the calculation of a composite waveform at any point on the Moon due to simulated impacts at any epicentral distance. The root-mean-square amplitude of this waveform yields a background noise level that is about 100 times lower than the resolution of the Apollo long-period seismometers. At 2 s periods, this noise level is more than 1000 times lower than the low noise model prediction for Earth's microseismic noise. Sufficiently sensitive seismometers will allow the future detection of several impacts per day at body wave frequencies. Copyright 2009 by the American Geophysical Union.

Journal of Geophysical Research E: Planets↗
USGS2009

Characterization of phyllosilicates observed in the central Mawrth Vallis region, Mars, their potential formational processes, and implications for past climate

Mawrth Vallis contains one of the largest exposures of phyllosilicates on Mars. Nontronite, montmorillonite, kaolinite, and hydrated silica have been identified throughout the region using data from the Compact Reconnaissance Imaging Spectrometer for Mars (CRISM). In addition, saponite has been identified in one observation within a crater. These individual minerals are identified and distinguished by features at 1.38-1.42, ???1.91, and 2.17-2.41 ??m. There are two main phyllosilicate units in the Mawrth Vallis region. The lowermost unit is nontronite bearing, unconformably overlain by an Al-phyllosilicate unit containing montmorillonite plus hydrated silica, with a thin layer of kaolinite plus hydrated silica at the top of the unit. These two units are draped by a spectrally unremarkable capping unit. Smectites generally form in neutral to alkaline environments, while kaolinite and hydrated silica typically form in slightly acidic conditions; thus, the observed phyllosilicates may reflect a change in aqueous chemistry. Spectra retrieved near the boundary between the nontronite and Al-phyllosilicate units exhibit a strong positive slope from 1 to 2 ??m, likely from a ferrous component within the rock. This ferrous component indicates either rapid deposition in an oxidizing environment or reducing conditions. Formation of each of the phyllosilicate minerals identified requires liquid water, thus indicating a regional wet period in the Noachian when these units formed. The two main phyllosilicate units may be extensive layers of altered volcanic ash. Other potential formational processes include sediment deposition into a marine or lacustrine basin or pedogenesis. Copyright 2009 by the American Geophysical Union.

Journal of Geophysical Research E: Planets↗
USGS2009

Identification of hydrated silicate minerals on Mars using MRO-CRISM: Geologic context near Nili Fossae and implications for aqueous alteration

[1] The Noachian terrain west of the Isidis basin hosts a diverse collection of alteration minerals in rocks comprising varied geomorphic units within a 100,000 km 2 region in and near the Nili Fossae. Prior investigations in this region by the Observatoire pour l'Minéralogie, l'Eau, les Glaces, et l'Activité (OMEGA) instrument on Mars Express revealed large exposures of both mafic minerals and iron magnesium phyllosilicates in stratigraphic context. Expanding on the discoveries of OMEGA, the Compact Reconnaissance Imaging Spectrometer for Mars (CRISM) aboard the Mars Reconnaissance Orbiter (MRO) has found more spatially widespread and mineralogically diverse alteration minerals than previously realized, which represent multiple aqueous environments. Using CRISM near-infrared spectral data, we detail the basis for identification of iron and magnesium smectites (including both nontronite and more Mg-rich varieties), chlorite, prehnite, serpentine, kaolinite, potassium mica (illite or muscovite), hydrated (opaline) silica, the sodium zeolite analcime, and magnesium carbonate. The detection of serpentine and analcime on Mars is reported here for the first time. We detail the geomorphic context of these minerals using data from high-resolution imagers onboard MRO in conjunction with CRISM. We find that the distribution of alteration minerals is not homogeneous; rather, they occur in provinces with distinctive assemblages of alteration minerals. Key findings are (1) a distinctive stratigraphy, in and around the Nili Fossae, of kaolinite and magnesium carbonate in bedrock units always overlying Fe/Mg smectites and (2) evidence for mineral phases and assemblages indicative of low-grade metamorphic or hydrothermal aqueous alteration in cratered terrains. The alteration minerals around the Nili Fossae are more typical of those resulting from neutral to alkaline conditions rather than acidic conditions, which appear to have dominated much of Mars. Moreover, the mineralogic diversity and geologic context of alteration minerals found in the region around the Nili Fossae indicates several episodes of aqueous activity in multiple distinct environments.

Journal of Geophysical Research E: Planets↗
USGS2010

Seasonal H2O and CO2 ice cycles at the Mars Phoenix landing site: 1. Prelanding CRISM and HiRISE observations

The condensation, evolution, and sublimation of seasonal water and carbon dioxide ices were characterized at the Mars Phoenix landing site from Martian northern midsummer to midspring (L s ∼ 142° – L s ∼ 60°) for the year prior to the Phoenix landing on 25 May 2008. Ice relative abundances and grain sizes were estimated using data from the Compact Reconnaissance Imaging Spectrometer for Mars and High Resolution Imaging Science Experiment aboard Mars Reconnaissance Orbiter and a nonlinear mixing model. Water ice first appeared at the Phoenix landing site during the afternoon in late summer (L s ∼ 167°) as an optically thin layer on top of soil. CO 2 ice appeared after the fall equinox. By late winter (L s ∼ 344°), the site was covered by relatively pure CO 2 ice (∼30 cm thick), with a small amount of ∼100 μ m diameter water ice and soil. As spring progressed, CO 2 ice grain sizes gradually decreased, a change interpreted to result from granulation during sublimation losses. The combined effect of CO 2 sublimation and decreasing H 2 O ice grain sizes allowed H 2 O ice to dominate spectra during the spring and significantly brightened the surface. CO 2 ice disappeared by early spring (L s ∼ 34°) and H 2 O ice by midspring (L s ∼ 59°). Spring defrosting was not uniform and occurred more rapidly over the centers of polygons and geomorphic units with relatively higher thermal inertia values.

Journal of Geophysical Research E: Planets↗
USGS2010

Silica in a Mars analog environment: Ka u Desert, Kilauea Volcano, Hawaii

Airborne Visible/Near-Infrared Imaging Spectrometer (AVIRIS) data acquired over the Ka u Desert are atmospherically corrected to ground reflectance and used to identify the mineralogic components of relatively young basaltic materials, including 250-700 and 200-400 year old lava flows, 1971 and 1974 flows, ash deposits, and solfatara incrustations. To provide context, a geologic surface units map is constructed, verified with field observations, and supported by laboratory analyses. AVIRIS spectral endmembers are identified in the visible (0.4 to 1.2 ??m) and short wave infrared (2.0 to 2.5 ??m) wavelength ranges. Nearly all the spectral variability is controlled by the presence of ferrous and ferric iron in such minerals as pyroxene, olivine, hematite, goethite, and poorly crystalline iron oxides or glass. A broad, nearly ubiquitous absorption feature centered at 2.25 ??m is attributed to opaline (amorphous, hydrated) silica and is found to correlate spatially with mapped geologic surface units. Laboratory analyses show the silica to be consistently present as a deposited phase, including incrustations downwind from solfatara vents, cementing agent for ash duricrusts, and thin coatings on the youngest lava flow surfaces. A second, Ti-rich upper coating on young flows also influences spectral behavior. This study demonstrates that secondary silica is mobile in the Ka u Desert on a variety of time scales and spatial domains. The investigation from remote, field, and laboratory perspectives also mimics exploration of Mars using orbital and landed missions, with important implications for spectral characterization of coated basalts and formation of opaline silica in arid, acidic alteration environments. Copyright 2010 by the American Geophysical Union.

Journal of Geophysical Research E: Planets↗
USGS2009

Aeolian dunes as ground truth for atmospheric modeling on Mars

Martian aeolian dunes preserve a record of atmosphere/surface interaction on a variety of scales, serving as ground truth for both Global Climate Models (GCMs) and mesoscale climate models, such as the Mars Regional Atmospheric Modeling System (MRAMS). We hypothesize that the location of dune fields, expressed globally by geographic distribution and locally by dune centroid azimuth (DCA), may record the long-term integration of atmospheric activity across a broad area, preserving GCM-scale atmospheric trends. In contrast, individual dune morphology, as expressed in slipface orientation (SF), may be more sensitive to localized variations in circulation, preserving topographically controlled mesoscale trends. We test this hypothesis by comparing the geographic distribution, DCA, and SF of dunes with output from the Ames Mars GCM and, at a local study site, with output from MRAMS. When compared to the GCM: 1) dunes generally lie adjacent to areas with strongest winds, 2) DCA agrees fairly well with GCM modeled wind directions in smooth-floored craters, and 3) SF does not agree well with GCM modeled wind directions. When compared to MRAMS modeled winds at our study site: 1) DCA generally coincides with the part of the crater where modeled mean winds are weak, and 2) SFs are consistent with some weak, topographically influenced modeled winds. We conclude that: 1) geographic distribution may be valuable as ground truth for GCMs, 2) DCA may be useful as ground truth for both GCM and mesoscale models, and 3) SF may be useful as ground truth for mesoscale models. Copyright 2009 by the American Geophysical Union.

Journal of Geophysical Research E: Planets↗
USGS2010

A comparison of Martian north and south polar cold spots and the long‐term effects of the 2001 global dust storm

In the 1970s, Viking and Mariner observed areas in the polar regions of Mars with winter brightness temperatures below the expected kinetic temperatures for CO 2 ice sublimation. These areas have since been termed “cold spots” and have been identified as surface deposits of CO 2 atmospheric condensates and, occasionally, active CO 2 storms. Three Mars years of data from the Mars Global Surveyor Thermal Emission Spectrometer were used to observe autumn and winter cold spot activity. In this study, cold spots that occur near and on the southern perennial cap were compared to those found near or on the northern perennial cap. On the southern perennial cap, cold spots associated with topographic features (induced by orographic lifting) were less common than cold spots independent of topography, similar to the north. However, the cold spots in the south lasted longer than those observed in the north. There is also evidence that cold spot formation in the south was affected by the global dust storm of 2001, even though the dust storm occurred during the southern spring and summer seasons. Prior to the dust storm, the amount of overall cold spot activity closer to the perennial cap increased and the average CO 2 grain size for most of the cold spots increased as well. Following the dust storm, the majority of cold spots in the south increased in size and duration but they did not form north of 62°S latitude, whereas, in other years, cold spots formed as far north as 48°S.

Journal of Geophysical Research E: Planets↗
USGS2010

Crater population and resurfacing of the Martian north polar layered deposits

Present‐day accumulation in the north polar layered deposits (NPLD) is thought to occur via deposition on the north polar residual cap. Understanding current mass balance in relation to current climate would provide insight into the climatic record of the NPLD. To constrain processes and rates of NPLD resurfacing, a search for craters was conducted using images from the Mars Reconnaissance Orbiter Context Camera. One hundred thirty craters have been identified on the NPLD, 95 of which are located within a region defined to represent recent accumulation. High Resolution Imaging Science Experiment images of craters in this region reveal a morphological sequence of crater degradation that provides a qualitative understanding of processes involved in crater removal. A classification system for these craters was developed based on the amount of apparent degradation and infilling and where possible depth/diameter ratios were determined. The temporal and spatial distribution of crater degradation is interpreted to be close to uniform. Through comparison of the size‐frequency distribution of these craters with the expected production function, the craters are interpreted to be an equilibrium population with a crater of diameter D meters having a lifetime of ∼30.75 D 1.14 years. Accumulation rates within these craters are estimated at 7.2 D −0.14 mm/yr, which corresponds to values of ∼3–4 mm/yr and are much higher than rates thought to apply to the surrounding flat terrain. The current crater population is estimated to have accumulated in the last ∼20 kyr or less.

Journal of Geophysical Research E: Planets↗
USGS2010

Bathymetry and absorptivity of Titan's Ontario Lacus

Ontario Lacus is the largest and best characterized lake in Titan's south polar region. In June and July 2009, the Cassini RADAR acquired its first Synthetic Aperture Radar (SAR) images of the area. Together with closest approach altimetry acquired in December 2008, these observations provide a unique opportunity to study the lake's nearshore bathymetry and complex refractive properties. Average radar backscatter is observed to decrease exponentially with distance from the local shoreline. This behavior is consistent with attenuation through a deepening layer of liquid and, if local topography is known, can be used to derive absorptive dielectric properties. Accordingly, we estimate nearshore topography from a radar altimetry profile that intersects the shoreline on the East and West sides of the lake. We then analyze SAR backscatter in these regions to determine the imaginary component of the liquid's complex index of refraction (κ). The derived value, κ = (6.1 −1.3 +1.7 ) × 10 −4 , corresponds to a loss tangent of tan Δ = (9.2 −2.0 +2.5 ) × 10 −4 and is consistent with a composition dominated by liquid hydrocarbons. This value can be used to test compositional models once the microwave optical properties of candidate materials have been measured. In areas that do not intersect altimetry profiles, relative slopes can be calculated assuming the index of refraction is constant throughout the liquid. Accordingly, we construct a coarse bathymetry map for the nearshore region by measuring bathymetric slopes for eleven additional areas around the lake. These slopes vary by a factor of ∼5 and correlate well with observed shoreline morphologies.

Journal of Geophysical Research E: Planets↗
USGS2010

Thin-skinned deformation of sedimentary rocks in Valles Marineris, Mars

Deformation of sedimentary rocks is widespread within Valles Marineris, characterized by both plastic and brittle deformation identified in Candor, Melas, and Ius Chasmata. We identified four deformation styles using HiRISE and CTX images: kilometer-scale convolute folds, detached slabs, folded strata, and pull-apart structures. Convolute folds are detached rounded slabs of material with alternating dark- and light-toned strata and a fold wavelength of about 1 km. The detached slabs are isolated rounded blocks of material, but they exhibit only highly localized evidence of stratification. Folded strata are composed of continuously folded layers that are not detached. Pull-apart structures are composed of stratified rock that has broken off into small irregularly shaped pieces showing evidence of brittle deformation. Some areas exhibit multiple styles of deformation and grade from one type of deformation into another. The deformed rocks are observed over thousands of kilometers, are limited to discrete stratigraphic intervals, and occur over a wide range in elevations. All deformation styles appear to be of likely thin-skinned origin. CRISM reflectance spectra show that some of the deformed sediments contain a component of monohydrated and polyhydrated sulfates. Several mechanisms could be responsible for the deformation of sedimentary rocks in Valles Marineris, such as subaerial or subaqueous gravitational slumping or sliding and soft sediment deformation, where the latter could include impact-induced or seismically induced liquefaction. These mechanisms are evaluated based on their expected pattern, scale, and areal extent of deformation. Deformation produced from slow subaerial or subaqueous landsliding and liquefaction is consistent with the deformation observed in Valles Marineris.

Journal of Geophysical Research E: Planets↗
USGS2010

Properties and distribution of paired candidate stony meteorites at Meridiani Planum

The Mars Exploration Rover Opportunity investigated four rocks, informally dubbed Barberton, Santa Catarina, Santorini, and Kasos, that are possible stony meteorites. Their chemical and mineralogical composition is similar to the howardite, eucrite, and diogenite group but with additional metal, similar to mesosiderite silicate clasts. Because of their virtually identical composition and because they appear to represent a relatively rare group of meteorites, they are probably paired. The four rocks were investigated serendipitously several kilometers apart, suggesting that Opportunity is driving across a larger population of similar rock fragments, maybe a meteorite strewn field. Small amounts of ferric Fe are a result of weathering. We did not observe evidence for fusion crusts. Four iron meteorites were found across the same area. Although mesosiderites are stony irons, a genetic link to these irons is unlikely. The stony meteorites probably fell later than the irons. The current atmosphere is sufficiently dense to land such meteorites at shallow entry angles, and it would disperse fragments over several kilometers upon atmospheric breakup. Alternatively, dispersion by spallation from an impacting meteoroid may have occurred. Santa Catarina and a large accumulation of similar rocks were found at the rim of Victoria crater. It is possible that they are associated with the impactor that created Victoria crater, but our limited knowledge about their distribution cannot exclude mere coincidence.

Journal of Geophysical Research E: Planets↗
USGS2010

Mineralogy and chemistry of cobbles at Meridiani Planum, Mars, investigated by the Mars Exploration Rover Opportunity

Numerous loose rocks with dimensions of a few centimeters to tens of centimeters and with no obvious physical relationship to outcrop rocks have been observed along the traverse of the Mars Exploration Rover Opportunity. To date, about a dozen of these rocks have been analyzed with Opportunity's contact instruments, providing information about elemental chemistry (Alpha Particle X‐ray Spectrometer), iron mineralogy and oxidation states (Mössbauer Spectrometer) and texture (Microscopic Imager). These “cobbles” appear to be impact related, and three distinct groups can be identified on the basis of chemistry and mineralogy. The first group comprises bright fragments of the sulfate‐rich bedrock that are compositionally and texturally indistinguishable from outcrop rocks. All other cobbles are dark and are divided into two groups, referred to as the “Barberton group” and the “Arkansas group,” after the first specimen of each that was encountered by Opportunity. Barberton group cobbles are interpreted as meteorites with an overall chemistry and mineralogy consistent with a mesosiderite silicate clast composition. Arkansas group cobbles appear to be related to Meridiani outcrop and contain an additional basaltic component. They have brecciated textures, pointing to an impact‐related origin during which local bedrock and basaltic material were mixed.

Journal of Geophysical Research E: Planets↗
USGS2010

Spirit Mars Rover Mission: Overview and selected results from the northern Home Plate Winter Haven to the side of Scamander crater

This paper summarizes Spirit Rover operations in the Columbia Hills, Gusev crater, from sol 1410 (start of the third winter campaign) to sol 2169 (when extrication attempts from Troy stopped to winterize the vehicle) and provides an overview of key scientific results. The third winter campaign took advantage of parking on the northern slope of Home Plate to tilt the vehicle to track the sun and thus survive the winter season. With the onset of the spring season, Spirit began circumnavigating Home Plate on the way to volcanic constructs located to the south. Silica‐rich nodular rocks were discovered in the valley to the north of Home Plate. The inoperative right front wheel drive actuator made climbing soil‐covered slopes problematical and led to high slip conditions and extensive excavation of subsurface soils. This situation led to embedding of Spirit on the side of a shallow, 8 m wide crater in Troy, located in the valley to the west of Home Plate. Examination of the materials exposed during embedding showed that Spirit broke through a thin sulfate‐rich soil crust and became embedded in an underlying mix of sulfate and basaltic sands. The nature of the crust is consistent with dissolution and precipitation in the presence of soil water within a few centimeters of the surface. The observation that sulfate‐rich deposits in Troy and elsewhere in the Columbia Hills are just beneath the surface implies that these processes have operated on a continuing basis on Mars as landforms have been shaped by erosion and deposition.

Journal of Geophysical Research E: Planets↗
USGS2010

Regional and grain size influences on the geochemistry of soil at Gusev Crater

Congruous with earlier work, Martian soil along the Spirit Rover's traverse at Gusev crater can be divided into three broad groups by size: fines (<150 μ m), sand, and a mix of various grain sizes. The key chemical observation is greater homogeneity in fines relative to the other two, consistent with regional‐ and global‐scale sampling of chemical compositions by finer particle sizes. The mix class is generally more heterogeneous as are samples from the Columbia Hills within each class. Variation in the trace element Ni is consistent with a CI contribution not exceeding 3%, while that of Ti is compatible with Fe‐Ti oxide enrichment not exceeding 3%. Physical mixing models are poorly supported. Among many potential binary and three‐component mixing models, only two show some consistency with the soil data: typical fines with the opaline Si end‐member identified at Home Plate and typical fines with sulfates (bearing a variable mix of Ca, Fe, and Mg cations). We also infer that binary mixing transcends classes, contrasting strongly with terrestrial sediments, and that mixing trends are consistent with significant nonmixing contributions, perhaps including localized chemical alteration. The decoupling between chemistry and grain size classes also suggests that processes linking composition with grain size, such as heavy mineral sorting, may have been minimal or absent entirely. The primary exception to this is the correlation between Cl and Si, Cl‐S, and Al‐Si, which is strongest in the fines class.

Journal of Geophysical Research E: Planets↗