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The Moon Mineralogy Mapper (M3) imaging spectrometer for lunar science: Instrument description, calibration, on‐orbit measurements, science data calibration and on‐orbit validation

The NASA Discovery Moon Mineralogy Mapper imaging spectrometer was selected to pursue a wide range of science objectives requiring measurement of composition at fine spatial scales over the full lunar surface. To pursue these objectives, a broad spectral range imaging spectrometer with high uniformity and high signal-to-noise ratio capable of measuring compositionally diagnostic spectral absorption features from a wide variety of known and possible lunar materials was required. For this purpose the Moon Mineralogy Mapper imaging spectrometer was designed and developed that measures the spectral range from 430 to 3000 nm with 10 nm spectral sampling through a 24 degree field of view with 0.7 milliradian spatial sampling. The instrument has a signal-to-noise ratio of greater than 400 for the specified equatorial reference radiance and greater than 100 for the polar reference radiance. The spectral cross-track uniformity is >90% and spectral instantaneous field-of-view uniformity is >90%. The Moon Mineralogy Mapper was launched on Chandrayaan-1 on the 22nd of October. On the 18th of November 2008 the Moon Mineralogy Mapper was turned on and collected a first light data set within 24 h. During this early checkout period and throughout the mission the spacecraft thermal environment and orbital parameters varied more than expected and placed operational and data quality constraints on the measurements. On the 29th of August 2009, spacecraft communication was lost. Over the course of the flight mission 1542 downlinked data sets were acquired that provide coverage of more than 95% of the lunar surface. An end-to-end science data calibration system was developed and all measurements have been passed through this system and delivered to the Planetary Data System (PDS.NASA.GOV). An extensive effort has been undertaken by the science team to validate the Moon Mineralogy Mapper science measurements in the context of the mission objectives. A focused spectral, radiometric, spatial, and uniformity validation effort has been pursued with selected data sets including an Earth-view data set. With this effort an initial validation of the on-orbit performance of the imaging spectrometer has been achieved, including validation of the cross-track spectral uniformity and spectral instantaneous field of view uniformity. The Moon Mineralogy Mapper is the first imaging spectrometer to measure a data set of this kind at the Moon. These calibrated science measurements are being used to address the full set of science goals and objectives for this mission.

Journal of Geophysical Research E: Planets

Stability of Mg-sulfates at-10C and the rates of dehydration/rehydration processes under conditions relevant to Mars

We report the results of low temperature (−10°C) experiments on the stability fields and phase transition pathways of five hydrous Mg-sulfates. A low temperature form of MgSO 4 ·7H 2 O (LT-7w) was found to have a wide stability field that extends to low relative humidity (∼13% RH at −10°C). Using information on the timing of phase transitions, we extracted information on the reaction rates of five important dehydration and rehydration processes. We found that the temperature dependencies of rate constants for dehydration processes differ from those of rehydration, which reflect differences in reaction mechanisms. By extrapolating these rate constants versus T correlations into the T range relevant to Mars, we can evaluate the possibility of occurrence of specific processes and the presence of common Mg-sulfate species present on Mars in different periods and locations. We anticipate in a moderate obliquity period, starkeyite and LH-MgSO 4 ·H 2 O should be two common Mg-sulfates at the surface, another polymorph MH-MgSO 4 ·H 2 O can exist at the locations where hydrothermal processes may have occurred. In polar regions or within the subsurface of other regions, meridianiite (coexisting with water ice, near 100% RH) and LT-7w (over a large RH range) are the stable phases. During a high obliquity period, meridianiite and LT-7w should exhibit widespread occurrence. The correlations of reaction rates versus temperature found in this study imply that dehydration and rehydration of hydrous Mg-sulfates would always be slower than the sublimation and crystallization of water ice, which would be supported by mission observations from Odyssey and by Mars Exploration Rovers.

Journal of Geophysical Research E: Planets

Characterization of previously unidentified lunar pyroclastic deposits using Lunar Reconnaissance Orbiter Camera (LROC) data

We used a Lunar Reconnaissance Orbiter Camera (LROC) global monochrome Wide-angle Camera (WAC) mosaic to conduct a survey of the Moon to search for previously unidentified pyroclastic deposits. Promising locations were examined in detail using LROC multispectral WAC mosaics, high-resolution LROC Narrow Angle Camera (NAC) images, and Clementine multispectral (ultraviolet-visible or UVVIS) data. Out of 47 potential deposits chosen for closer examination, 12 were selected as probable newly identified pyroclastic deposits. Potential pyroclastic deposits were generally found in settings similar to previously identified deposits, including areas within or near mare deposits adjacent to highlands, within floor-fractured craters, and along fissures in mare deposits. However, a significant new finding is the discovery of localized pyroclastic deposits within floor-fractured craters Anderson E and F on the lunar farside, isolated from other known similar deposits. Our search confirms that most major regional and localized low-albedo pyroclastic deposits have been identified on the Moon down to ~100 m/pix resolution, and that additional newly identified deposits are likely to be either isolated small deposits or additional portions of discontinuous, patchy deposits.

Journal of Geophysical Research E: Planets

Spatial distribution of damage around faults in the Joe Lott Tuff Member of the Mount Belknap Volcanics, Utah: A mechanical analog for faulting in pyroclastic deposits on Mars

Volcanic ash is thought to comprise a large fraction of the Martian equatorial layered deposits and much new insight into the process of faulting and related fluid flow in these deposits can be gained through the study of analogous terrestrial tuffs. This study identifies a set of fault-related processes that are pertinent to understanding the evolution of fault systems in fine-grained, poorly indurated volcanic ash by investigating exposures of faults in the Miocene-aged Joe Lott Tuff Member of the Mount Belknap Volcanics, Utah. The porosity and granularity of the host rock are found to control the style of localized strain that occurs prior to and contemporaneous with faulting. Deformation bands occur in tuff that was porous and granular at the time of deformation, while fractures formed where the tuff lost its porous and granular nature due to silicic alteration. Non-localized deformation of the host rock is also prominent and occurs through compaction of void space, including crushing of pumice clasts. Significant off-fault damage of the host rock, resembling fault pulverization, is recognized adjacent to one analog fault and may reflect the strain rate dependence of the resulting fault zone architecture. These findings provide important new guidelines for future structural analyses and numerical modeling of faulting and subsurface fluid flow through volcanic ash deposits on Mars.

Utah

Overview of spirit microscopic imager results

This paper provides an overview of Mars Exploration Rover Spirit Microscopic Imager (MI) operations and the calibration, processing, and analysis of MI data. The focus of this overview is on the last five Earth years (2005–2010) of Spirit 's mission in Gusev crater, supplementing the previous overview of the first 450 sols of the Spirit MI investigation. Updates to radiometric calibration using in‐flight data and improvements in high‐level processing are summarized. Released data products are described, and a table of MI observations, including target/feature names and associated data sets, is appended. The MI observed natural and disturbed exposures of rocks and soils as well as magnets and other rover hardware. These hand‐lens‐scale observations have provided key constraints on interpretations of the formation and geologic history of features, rocks, and soils examined by Spirit . MI images complement observations by other Spirit instruments, and together show that impact and volcanic processes have dominated the origin and evolution of the rocks in Gusev crater, with aqueous activity indicated by the presence of silica‐rich rocks and sulfate‐rich soils. The textures of some of the silica‐rich rocks are similar to terrestrial hot spring deposits, and observations of subsurface cemented layers indicate recent aqueous mobilization of sulfates in places. Wind action has recently modified soils and abraded many of the rocks imaged by the MI, as observed at other Mars landing sites.

Journal of Geophysical Research E: Planets

Orbital and in-situ investigation of periodic bedrock ridges in Glen Torridon, Gale Crater, Mars

Wind has been the dominant agent of landscape modification on Mars for the past ~3 billion years. Among the diversity of features formed by aeolian abrasion on the surface of Mars are periodic bedrock ridges (PBRs), a relatively recently recognized class of erosional bedforms on Mars for which Earth analogues are rare. Gale crater, the field site for NASA’s Mars Science Laboratory Curiosity rover since it landed there in 2012, contains a diverse and extensive record of aeolian deposition and erosion. This study focuses on a series of periodic, linear bedrock ridges that occur within the Fe/Mg-smectite clay-bearing Glen Torridon region of Aeolis Mons (informally Mount Sharp). During Curiosity’s exploration of the Glen Torridon region between sols ~2300-3080, the rover drove through this field of ridges, providing the first opportunity for the in situ observation of these enigmatic erosional features. This study characterizes the Glen Torridon ridges using orbiter and rover data to determine their morphology, spatial distribution, compositional and material properties, and association with other aeolian features in the area. Based on these observations, the Glen Torridon ridges are interpreted to be consistent with an origin as wind-eroded periodic bedrock ridges carved during the most recent exhumation of Mount Sharp into the present-day mound. Although there is evidence for multidirectional winds in the Glen Torridon region based on the orientation of modern ripples, megaripples, TARs and other bedrock indicators, the consistent orientation of the Glen Torridon ridges, coupled with morphologic asymmetries within the ridges, support formation and elongation of the Glen Torridon PBRs forms parallel to a net regional northerly wind direction in and around Gale crater.

Journal of Geophysical Research E: Planets

Mars Science Laboratory CheMin data from the Glen Torridon region and the significance of lake-groundwater interactions in interpreting mineralogy and sedimentary history

The Glen Torridon (GT) region is positioned in terrains with strong clay mineral signatures, as inferred from orbital spectroscopy. The GT campaign confirmed orbital distinctions with in situ measurements by the Mars Science Laboratory rover, Curiosity , and the CheMin X-ray diffraction instrument with of some of the highest clay mineral abundances to date. Additionally, GT is unique because of distinct phase identifications for the first time by CheMin, including: (i) Fe-carbonates, and (ii) a novel peak in the XRD patterns of some GT samples, with an interplanar spacing of at 9.2 Å. Fe-carbonates have been previously suggested from other instruments onboard, but this is the first definitive reporting by CheMin of multiple samples with Fe-carbonate. This new phase has never been observed in Gale crater with the CheMin instrument and may be a new mineral for Mars, but discrete identification still remains enigmatic because no single phase on Earth is able to account the mineralogical, geochemical, and sedimentological constraints in the GT region. Here, we modeled XRD profiles and propose an interstratified clay mineral, specifically greenalite-minnesotaite (G-M), as a reasonable candidate. The coexistence of Fe-carbonate and Fe-rich clay minerals in the GT samples, supports a conceptual model of a lacustrine groundwater mixing environment in the ancient Gale crater lake. Groundwater interaction with percolating lake waters in the sediments is common in terrestrial lacustrine settings, and the diffusion of two distinct water bodies within the subsurface can create a geochemical gradient and unique mineral front in the sediments. Ultimately, the proximity to this mixing zone controlled the secondary minerals preserved in the Jura, Knockfarril Hill, and Glasgow members of the Mt. Sharp group exposed in GT.

Journal of Geophysical Research E: Planets

Bedrock geochemistry and alteration history of the clay-bearing Glen Torridon region of Gale crater, Mars

Glen Torridon is a topographic trough located on the slope of Aeolis Mons, Gale crater, Mars. It corresponds to what was previously referred to as the “clay-bearing unit”, due to the relatively strong spectral signatures of clay minerals (mainly ferric smectites) detected from orbit. Starting in January 2019, the Curiosity rover explored Glen Torridon for more than 700 sols (Martian days). The objectives of this campaign included acquiring a detailed understanding of the geologic context in which the clay minerals were formed and determining the intensity of aqueous alteration experienced by the sediments. Here, we present the major-element geochemistry of the bedrock as analyzed by the ChemCam instrument. Our results reveal that the two main types of bedrock exposures identified in the lower part of Glen Torridon are associated with distinct chemical compositions (K-rich and Mg-rich), for which we are able to propose mineralogical interpretations. Moreover, the topmost stratigraphic member exposed in the region displays a stronger diagenetic overprint, especially at two locations close to the unconformable contact with the overlying Stimson formation, where the bedrock composition significantly deviates from the rest of Glen Torridon. Overall, the values of the Chemical Index of Alteration determined with ChemCam are elevated by Martian standards, suggesting the formation of clay minerals through open system weathering. However, there is no indication that the alteration was stronger than in some terrains previously visited by Curiosity , which in turn implies that the enhanced orbital signatures are mostly controlled by non-compositional factors.

Journal of Geophysical Research E: Planets

New craters on Mars: An updated catalog

We present a catalog of new impacts on Mars. These craters formed in the last few decades, constrained with repeat orbital imaging. Crater diameters range from 58 m down to <1 m. For each impact, we report whether it formed a single crater or a cluster (58% clusters); albedo features of the blast zone (88% halos; 64% linear rays; 10% arcuate rays; majority dark-toned; 4% light-toned; 14% dual-toned); and exposures of ice (4% definite; 2% possible). We find no trends in the occurrences of clusters with latitude, elevation, or impact size. Albedo features do not depend on atmospheric fragmentation. Halos are more prevalent at lower elevations, indicating an atmospheric pressure dependence; and around smaller impacts, which could be an observational bias. Linear rays are more likely to form from larger impacts into more consolidated material and may be enhanced by lower atmospheric pressure at higher elevations. Light- and dual-toned blast zones occur in specific regions and more commonly around larger impacts, indicating excavation of compositionally distinct material. Surfaces covered with bright dust lacking cohesion are favored to form detectable surface features. The slope of the cumulative size frequency distribution for this data set is 2.2 for diameters >8 m (differential slope 2.9), significantly shallower than the slope of new lunar craters. We believe that no systematic biases exist in the Martian data set sufficient to explain the discrepancy. This catalog is complete at the time of writing, although observational biases exist, and new discoveries continue.

Journal of Geophysical Research E: Planets

Enhanced visualization for the interpretation of Magellan radar data: Supplement to the Magellan special issue

The differences of radar data from more familiar photographic images, coupled with the unique geologic characteristics of Venus's surface, can make interpretation of the standard Magellan data products difficult for both planetary scientists and nonspecialists. We describe a set of digital processing techniques for transforming individual remote‐sensing datasets in order to make the information they contain more apparent, and for combining multiple datasets of diverse resolution and information content into synthetic images that allow the viewer to explore correlations among the data. The creation of derived data products by techniques like those we describe is becoming increasingly widespread and important, both for scientific research and for use in educational and media presentations. We apply our processing techniques to Magellan synthetic aperture radar images, altimetry, and microwave emissivity measurements of four areas that exemplify some of the most important styles of geologic activity on Venus.

Journal of Geophysical Research E: Planets

Galileo observations of Post-Imbrium lunar craters during the first Earth-Moon flyby

Copernican‐age craters are among the most conspicuous features seen on the far side and western limb of the Moon in the Galileo multispectral images acquired in December 1990. Among the new morphologic observations of far‐side craters are bright rays, continuous ejecta deposits, and dark rings associated with probable impact‐melt veneers. These observations suggest that the mapped age assignments of several large far‐side craters (Ohm, Robertson, and possibly Lowell and Lenz) need revision. New crater size‐frequency measurements on Lunar Orbiter images suggest the following age reassignments: Hausen (170 km diameter), Pythagoras (120 km), and Bullialdus (61 km) from Eratosthenian to Upper Imbrian, and Carpenter (60 km) and Harpalus (39 km) from Copernican to Eratosthenian. Colors and albedos of craters (away from impact‐melt veneers) are correlated with their geologic emplacement ages as determined from counts of superposed craters; these age‐color relations are used to estimate the emplacement age (time since impact event) for other Copernican‐age craters. These age‐color relations indicate a probable Copernican age for 27 far‐side or western limb craters larger than 10 km diameter that were not previously mapped as Copernican. The apparent deficiency of Copernican craters on the far side compared with the near side in published geologic maps is not present in our data. Age‐color trends differ between mare and highland regions and between the interiors and continuous ejecta of the craters. Similar trends are established for color and albedo versus soil‐maturity indices for the returned lunar samples, with distinct trends for mare and highland soils. However, the mare versus highland offsets are reversed in the two comparisons. These relations can be explained by variations in regolith thicknesses and rates of mixing with relatively fresh, crystalline ejecta. Therefore, the soil‐maturity trends represent longer geologic time periods in regions with thinner regoliths, such as the maria.

Journal of Geophysical Research E: Planets

Impact crater outflows on Venus: Morphology and emplacement mechanisms

Many of the 932 impact craters discovered by the Magellan spacecraft at Venus are associated with lobate flows that originate at or near the crater rim. They extend for several to several hundred kilometers from the crater, and they commonly have a strong radar backscatter. A morphologic study of all identifiable crater outflows on Venus has revealed that many individual flows each consist of two areas, defined by distinct morphologic features. These two areas appear to represent two stages of deposition for each flow. The part of the flow that is generally deposited closest to the crater tends to be on the downrange side of the crater, flows in the downrange direction, and it is interpreted to be a late-stage ejecta. In many cases, this proximal part of the flow is too thin to completely bury the large blocks in subjacent ejecta deposits. Dendritic channels, present in many proximal flows, appear to have drained liquid from the proximal part in the downhill direction, and they debouch to feed the outer part of the flows. This distal part flows downhill, fills small grabens, and is ponded by ridges, behavior that mimics that of volcanic lava flows. The meandering and dendritic channels and the relation of the distal flows to topography strongly suggest that the distal portion is the result of coalescence and slow drainage of impact melt from the proximal portion. Impact melt forms a lining to the transient crater and mixes turbulently with solid clasts, and part of this mixture may be ejected to form the proximal part of the flow during the excavation stage of crater development. A statistical study of the Venusian craters has revealed that, in general, large craters produced by impacts with relatively low incidence angles to the surface are more likely to produce flows than small craters produced by higher-angle impacts. The greater flow production and downrange focusing of the proximal flows with decreasing incidence angle indicate a strong control of the flows by the impactor flight direction, and a high downrange velocity imparted to the proximal flow material in lower angle impacts. On the Moon, small flows interpreted to be composed of impact melt are observed atop the ejecta of large, fresh craters; on Earth, melt-rich suevite deposits form the uppermost layer of ejecta of some fresh craters. These features, albeit much smaller, may be analogous to the flows on Venus. Numerical models have predicted that larger volumes of impact melt would be produced on Venus than on the cooler terrestrial bodies due to high atmospheric and target temperatures, perhaps 3 times the volume produced on the Moon for a given crater diameter.

Journal of Geophysical Research E: Planets

Coupling of volatile transport and internal heat flow on Triton

Recently Brown et al. (1991) showed that Triton's internal heat source could amount to 5–20% of the absorbed insolation on Triton, thus significantly affecting volatile transport and atmospheric pressure. Subsequently, Kirk and Brown (1991a) used simple analytical models of the effect of internal heat on the distribution of volatiles on Triton's surface, confirming the speculation of Brown et al. that Triton's internal heat flow could strongly couple to the surface volatile distribution. To further explore this idea, we present numerical models of the permanent distribution of nitrogen ice on Triton that include the effects of sunlight, the two‐dimensional distribution of internal heat flow, the coupling of internal heat flow to the surface distribution of nitrogen ice, and the finite viscosity of nitrogen ice. From these models we conclude that: (1) The strong vertical thermal gradient induced in Triton's polar caps by internal heat‐flow facilitates viscous spreading to lower latitudes, thus opposing the poleward transport of volatiles by sunlight, and, for plausible viscosities and nitrogen inventories, producing permanent caps of considerable latitudinal extent; (2) It is probable that there is a strong coupling between the surface distribution of nitrogen ice on Triton and internal heat flow; (3) Asymmetries in the spatial distribution of Triton's heat flow, possibly driven by large‐scale, volcanic activity or convection in Triton's interior, can result in permanent polar caps of unequal latitudinal extent, including the case of only one permanent polar cap; (4) Melting at the base of a permanent polar cap on Triton caused by internal heat flow can significantly enhance viscous spreading, and, as an alternative to the solid‐state greenhouse mechanism proposed by Brown et al. (1990), could provide the necessary energy, fluids, and/or gases to drive Triton's geyser‐like plumes; (5) The atmospheric collapse predicted to occur on Triton in the next 20 years (Spencer, 1990) may be plausibly avoided because of the large latitudinal extent expected for permanent polar caps on Triton.

Journal of Geophysical Research E: Planets

Topography of Valles Marineris: Implications for erosional and structural history

Compilation of a simplified geologic/geomorphic map onto digital terrain models of the Valles Marineris permitted an evaluation of elevations in the vicinity of the troughs and the calculation of depth of troughs below surrounding plateaus, thickness of deposits inside the troughs, volumes of void spaces above geologic/geomorphic units, and volumes of deposits. The central troughs north Ophir, north and central Candor, and north Melas Chasmata lie as much as 11 km below the adjacent plateaus. In Ophir and Candor Chasmata, interior layered deposits reach 8 km in elevation. If the deposits are lacustrine and if all troughs were interconnected, lake waters standing 8 km high would have spilled out of Coprates Chasma onto the surrounding plateaus having surface elevations of only 4–5 km. In this case, interior deposits above about 4 km in the central troughs would not be lacustrine. They could be volcanic. On the other hand, the troughs may not have been interconnected at the time of interior‐deposit emplacement; they may have formed isolated ancestral basins. The existence of such basins is supported by independent structural and stratigraphic evidence. The ancestral basins may have eventually merged, perhaps through renewed faulting, to form northern subsidiary troughs in Ophir and Candor Chasmata and the Coprates/north Melas/Ius graben system. The peripheral troughs are only 2–5 km deep, shallower than the central troughs. They may have formed from a combination of erosional collapse and structural activity. Chaotic terrain is seen in the peripheral troughs near a common contour level of about 4 km on the adjacent plateaus, which supports the idea of release of water under artesian pressure from confined aquifers. The layered deposits in the peripheral troughs may have formed in isolated depressions that harbored lakes and predated the formation of the deep outflow channels. If these layered deposits are of volcanic origin, they may have been emplaced beneath ice in the manner of table mountains. Areal and volumetric computations show that erosion widened the troughs by about one‐third and that deposits occupy one‐sixth of the interior space. Even though the volume eroded is larger than the volume deposited, topographic and geologic considerations imply that material eroded from trough walls was probably part of the interior layered deposits but not their sole source. Additional material may have come from subterranean piping, from reworking of local disintegration products on the floors, such as chaotic materials, or from eolian influx. But overall it is likely that the additional material is volcanic and that it forms mostly the upper, more diversely bedded layers of the interior deposits.

Journal of Geophysical Research E: Planets

Gravity survey of the Mount Toondina impact structure, South Australia

Gravity and seismic reflection data, together with geologic mapping, indicate that the Mount Toondina feature in South Australia is best interpreted as an eroded 4-km-diameter impact structure consisting of a ring structural depression surrounding a pronounced central uplift. Beds at the center of the structure within the central uplift have been raised as much as 200 m from depth and deformed by convergent flow. Seismic reflection data indicate that deformation extends to depths of only ≈800 m; at greater depths the reflectors are nearly flat lying, indicating little or no deformation. Gravity data show residual anomalies of +1.0 mGal coincident with the central uplift and a −0.5 Mgal low associated with the ring structural depression. Modeling of the gravity data indicates that relatively high-density material occurs within the central uplift, whereas the ring depression is filled with low-density material. The deformation at Mount Toondina is typical of a complex impact crater; the 4-km diameter is consistent with the expected threshold size for complex craters formed in weak to moderate strength sedimentary rocks.

South Australia

Modeling of fluidized ejecta emplacement over digital topography on Venus

The FLOW computer model of McEwen and Malin (1989) modified for application to the study of Venus fluidized ejecta blankets (FEBs) demonstrates that relatively low viscosities, yield strengths, and initial velocities are required to duplicate the observed flow paths of the outflow materials. The model calculates the velocities and simulated flow paths of gravity flows over Magellan topography. The model is formulated to determine flow movements from initial conditions, gravitational acceleration, and resistance to motion as described by Coulomb, viscous, and turbulent resistance forces. Successful duplication of observed FEB flow paths has been achieved for the FEB craters Addams, Isabella, and Cochran. When used as a simple energy‐line model, the model requires low coefficients of friction to extend FEBs to near their observed termini in the synthetic aperture radar (SAR) imagery, although the resulting straight flow lines do not follow the observed flow paths well. For Bingham flow, the model requires low values of viscosity and yield strength which are more similar to pyroclastic or debris flows than basaltic lavas. Flows of 100‐m depth require 1 to 2 orders of magnitude higher values of both viscosity and yield strength than 10‐m‐deep flows. The complicated nature of the flow lines for the low velocity model suggests that FEBs were probably emplaced under variably laminar and turbulent flow conditions, where underlying topography influenced both the direction and energy of flow materials.

Journal of Geophysical Research E: Planets

Detection and monitoring of H2O and CO2 ice clouds on Mars

We have developed an observational scheme for the detection and discrimination of Mars atmospheric H 2 O and CO 2 clouds using ground-based instruments in the near infrared. We report the results of our cloud detection and characterization study using Mars near IR images obtained during the 1990 and 1993 oppositions. We focused on specific wavelengths that have the potential, based on previous laboratory studies of H 2 O and CO 2 ices, of yielding the greatest degree of cloud detectability and compositional discriminability. We have detected and mapped absorption features at some of these wavelengths in both the northern and southern polar regions of Mars. Compositional information on the nature of these absorption features was derived from comparisons with laboratory ice spectra and with a simplified radiative transfer model of a CO 2 ice cloud overlying a bright surface. Our results indicate that both H 2 O and CO 2 ices can be detected and distinguished in the polar hood clouds. The region near 3.00 μm is most useful for the detection of water ice clouds because there is a strong H 2 O ice absorption at this wavelength but only a weak CO 2 ice band. The region near 3.33 μm is most useful for the detection of CO 2 ice clouds because there is a strong, relatively narrow CO 2 ice band at this wavelength but only broad “continuum” H 2 O ice absorption. Weaker features near 2.30 μm could arise from CO 2 ice at coarse grain sizes, or surface/dust minerals. Narrow features near 2.00 μm, which could potentially be very diagnostic of CO 2 ice clouds, suffer from contamination by Mars atmospheric CO 2 absorptions and are difficult to interpret because of the rather poor knowledge of surface elevation at high latitudes. These results indicate that future ground-based, Earth-orbital, and spacecraft studies over a more extended span of the seasonal cycle should yield substantial information on the style and timing of volatile transport on Mars, as well as a more detailed understanding of the role of CO 2 condensation in the polar heat budget.

Journal of Geophysical Research E: Planets